U.S. patent application number 11/395749 was filed with the patent office on 2006-10-19 for synergistic, crop plant-compatible herbicidal compositions comprising herbicides from the group of the benzoylpyrazoles.
This patent application is currently assigned to Bayer CropScience GmbH. Invention is credited to Dieter Feucht, Erwin Hacker, Hans Philipp Huff.
Application Number | 20060234862 11/395749 |
Document ID | / |
Family ID | 36572124 |
Filed Date | 2006-10-19 |
United States Patent
Application |
20060234862 |
Kind Code |
A1 |
Huff; Hans Philipp ; et
al. |
October 19, 2006 |
Synergistic, crop plant-compatible herbicidal compositions
comprising herbicides from the group of the benzoylpyrazoles
Abstract
Synergistic, crop plant-compatible herbicidal compositions
comprising herbicides from the group of the benzoylpyrazoles What
is described are herbicidal compositions comprising A) a compound
from the group of the benzoylpyrazoles, B) at least one further
herbicide and C) at least one safener as herbicides which are
active against monocotyledonous and/or dicotyledonous harmful
plants. Compared to the herbicides applied individually, these
compositions have superior activity and are at the same time highly
compatible with crop plants.
Inventors: |
Huff; Hans Philipp;
(Eppstein, DE) ; Hacker; Erwin; (Hochheim, DE)
; Feucht; Dieter; (Eschborn, DE) |
Correspondence
Address: |
CONNOLLY BOVE LODGE & HUTZ, LLP
P O BOX 2207
WILMINGTON
DE
19899
US
|
Assignee: |
Bayer CropScience GmbH
Frankfurt am Main
DE
|
Family ID: |
36572124 |
Appl. No.: |
11/395749 |
Filed: |
March 31, 2006 |
Current U.S.
Class: |
504/111 |
Current CPC
Class: |
A01N 37/40 20130101;
A01N 37/40 20130101; A01N 43/42 20130101; A01N 43/56 20130101; A01N
43/56 20130101; A01N 2300/00 20130101; A01N 2300/00 20130101; A01N
2300/00 20130101; A01N 43/42 20130101 |
Class at
Publication: |
504/111 |
International
Class: |
A01N 25/32 20060101
A01N025/32 |
Foreign Application Data
Date |
Code |
Application Number |
Apr 1, 2005 |
DE |
10 2005 014 944.8 |
Claims
1. A herbicidal composition, comprising an effective amount of A)
the herbicide of the formula (A) or an agriculturally customary
salt thereof (component (A)), ##STR2## B) at least one herbicide
(component (B)) selected from the group consisting of atrazine,
bromoxynil, ioxynil, isoproturon, MCPA, 2,4-DP, mecoprop, dicamba,
fluroxypyr, clodinafop-propargyl, fenoxaprop-P-ethyl, tralkoxydim,
pinoxaden and diflufenican, and C) at least one safener selected
from the group consisting of mefenpyr-diethyl, cloquintocet-mexyl
and
4-cyclopropyl-aminocarbonyl-N-(2-methoxybenzoyl)benzenesulfonamide.
2. The herbicidal composition as claimed in claim 1, which
comprises the component (A), two of the components (B) and one
component (C).
3. The herbicidal composition as claimed in claim 1 or 2, which
comprises the components (A), (B) and (C) in a weight ratio of
x:y:z, wherein x y and z are independently 1 to 200.
4. The herbicidal composition as claimed in claim 3, wherein x, y
and z are independently 1 to 100.
5. The herbicidal composition as claimed in claim 1, additionally
comprising formulating agents customary in crop protection.
6. The herbicidal composition as claimed in claim 1, additionally
comprising fertilizers.
7. The herbicidal composition as claimed in claim 1, additionally
comprising adjuvants.
8. A method for controlling unwanted vegetation, which comprises
applying the components (A), (B) and (C), defined according to
claim 1, jointly or separately to the plants, to parts of plants,
to plant seeds or to the area on which the plants grow.
9. The method as claimed in claim 8 wherein said unwanted
vegetation comprises harmful plants in crops of useful plants.
10. The method as claimed in claim 9 wherein said unwanted
vegetation comprises harmful plants in crops of monocotyledonous
plants.
11. The method as claimed in claim 9, wherein the plant crops are
genetically modified, or obtained by mutation or selection.
12. (canceled)
13. The herbicidal composition as claimed in claim 2 which
comprises the components (A), (B) and (C) in a weight ratio of
x:y:z, wherein x, y and z are independently 1 to 200.
14. The herbicidal composition as claimed in claim 13 which
comprises the components (A), (B) and (C) in a weight ratio of
x:y:z, wherein x, y and z are independently 1 to 100.
15. The method as claimed in claim 10 wherein the plant crops are
genetically modified, or obtained by mutation or selection.
16. A method for controlling unwanted vegetation, which comprises
applying the components (A), (B) and (C), defined according to
claim 2, jointly or separately to the plants, to parts of plants,
to plant seeds or to the area on which the plants grow.
17. The method as claimed in claim 16, wherein said unwanted
vegetation comprises harmful plants in crops of useful plants.
18. The method as claimed in claim 17, wherein said unwanted
vegetation comprises harmful plants in crops of monocotyledonous
plants.
19. The method as claimed in claim 18, wherein the plant crops are
genetically modified, or obtained by mutation or selection.
20. The method as claimed in claim 17, wherein the plant crops are
genetically modified, or obtained by mutation or selection.
Description
[0001] Synergistic, crop plant-compatible herbicidal compositions
comprising herbicides from the group of the benzoylpyrazoles
[0002] The invention relates to the technical field of crop
protection compositions which can be used against unwanted
vegetation and which comprise, as active compounds, a combination
of at least two herbicides and one safener.
[0003] More specifically, it relates to herbicidal compositions
which comprise, as active compound, a herbicide from the group of
the benzoylpyrazoles in combination with at least one further
herbicide and one safener.
[0004] Herbicides-of the abovementioned group of the
benzoylpyrazoles are known from numerous documents. Thus, EP-A 0
203 428, U.S. Pat. No. 4,643,757, WO 97/23135 and WO 01/74785
describe a number of benzoylpyrazoles having herbicidal action.
[0005] However, the use of the benzoylpyrazoles known from these
publications frequently entails disadvantages in practice. Thus,
the herbicidal activity of the known compounds is not always
sufficient, or, if the herbicidal activity is sufficient, then
undesired damage to the useful plants is observed.
[0006] The effectiveness of herbicides depends inter alia on the
type of herbicide used, its application rate, the formulation, the
harmful plants to be controlled in each case, climatic and soil
conditions, etc. A further criterion is the persistency or the rate
at which the herbicide is degraded. Changes in the susceptibility
of harmful plants to an active compound which may occur on
prolonged use or in specific geographical regions may also have to
be taken into account. Such changes manifest themselves by a more
or less pronounced loss in activity and can only be compensated to
a limited extent by higher herbicide application rates.
[0007] One way to improve the application profile of a herbicide
may be the combination of the active compound with one or more
other active compounds. Combinations of herbicidally effective
benzoyl derivatives with other herbicides are known from WO
03/043422. However, when a number of active compounds are applied
in combination, it is not uncommon for phenomena of physical and
biological incompatibility to occur, for example insufficient
stability of a joint formulation, decomposition of an active
compound or antagonism of the active compounds. What is desired
are, in contrast, active compound combinations having a favorable
activity profile, high stability and, if possible, synergistically
enhanced activity, thus permitting the application rate to be
reduced, compared with the individual application of the active
compounds to be combined.
[0008] Owing to the large number of possible influencing factors,
there is virtually no individual active compound which has all the
desired properties for different requirements, in particular with
respect to the species of harmful plants and the climatic zones.
Furthermore, there is the permanent object to achieve the effect
using more and more reduced herbicide application rates. A lower
application rate reduces not only the amount of active compound
required for the application, but generally also reduces the amount
of formulation auxiliaries required. Both reduce the economic
expense and improve the ecological compatibility of the herbicide
treatment.
[0009] As is the case with many other herbicidally active
compounds, benzoylpyrazoles, too, in particular in combination with
other herbicides, are not always sufficiently compatible with (i.e.
not selective enough in) some important crop plants, such as corn,
rice or cereal, so that their use is highly restricted. As a
consequence, in some crops, they cannot be employed or only be
employed at application rates which are so low that the desired
broad herbicidal activity against harmful plants is not ensured.
Specifically, many of the herbicides mentioned cannot be employed
entirely selectively against harmful plants in corn, rice, cereal,
sugar cane and some other crops.
[0010] To overcome these disadvantages, it is known to employ
herbicidally active compounds in combination with what is known as
a safener or antidote. Thus, for example, WO 03/043423 describes
various combinations of benzoylpyrazoles with a large number of
safeners.
[0011] A safener is understood as meaning a compound which
compensates for, or reduces, the phytotoxic properties of a
herbicide with regard to useful plants, without substantially
reducing the herbicidal activity against harmful plants.
[0012] Finding a safener for a specific group of herbicides remains
a difficult task since the mechanisms by which a safener reduces
the harmful action of herbicides are not known in detail. The fact
that a compound in combination with a specific herbicide acts as a
safener therefore allows no conclusions to be drawn as to whether
such a compound also has a safener action with other groups of
herbicides. Thus, it has emerged when safeners are used for
protecting the useful plants from herbicide damage that the
safeners may still exhibit certain disadvantages in many cases.
These include: [0013] the safener reduces the activity of the
herbicides against the harmful plants, [0014] the
useful-plant-protecting properties are insufficient, [0015] the
spectrum of the useful plants in which the safener/herbicide is to
be employed is not sufficiently wide in combination with a given
herbicide, [0016] a given safener cannot be combined with a
sufficiently large number of herbicides.
[0017] It is an object of the present invention to provide
herbicidal compositions having properties which are improved
compared to the prior art.
[0018] The invention provides selected herbicidal compositions
comprising an effective amount of [0019] A) the herbicide of the
formula (A) or an agriculturally customary salt thereof (component
(A)), ##STR1## [0020] B) at least one herbicide (component (B))
from one of the groups [0021] B1inhibitors of the photosynthesis
electron transport: [0022] atrazine (B1.1), bromoxynil (B1.2),
ioxynil (B1.3), isoproturon (B1.4); [0023] B2 synthetic auxins:
[0024] MCPA (B2.1), 2,4-DP (B2.2), mecoprop (B2.3), dicamba (B2.4),
fluroxypyr (B2.5); [0025] B3 inhibitors of fatty acid biosynthesis:
[0026] clodinafop-propargyl (B3.1), fenoxaprop-P-ethyl (B3.2),
tralkoxydim (B3.3), pinoxaden (B3.4); [0027] B4 inhibitors of the
fatty acid biosynthesis/carotinoid biosynthesis: [0028]
diflufenican (B4.1); and [0029] C) an amount, acting as an
antidote, of at least one safener C1 to C3 (component (C):
mefenpyr-diethyl (C1), cloquintocet-mexyl (C2),
4-cyclopropyl-aminocarbonyl-N-(2-methoxybenzoyl)benzenesulfonamide
(C3)), where these compositions comprise the components (A), (B)
and (C) in a weight ratio of x:y:z, where x, y and z in each case
independently of one another may assume values of from 1 to 200,
preferably from 1 to 100.
[0030] Hereinbelow, the terms "component (A)" and "herbicide (A)"
are to be understood as having the same meaning. This applies
analogously to the terms "component (B)" and "herbicide (B)" and
also "component (C)" and "safener (C)".
[0031] The herbicide (A) is known from WO 01/74785. The safener
(C3) is known from EP 1 019 368. Pinoxaden is the compound with the
IUPAC name
"8-(2,6-diethyl-p-tolyl)-1,2,4,5-tetrahydro-7-oxo-7H-pyrazolo[1,2-d][1,4,-
5]oxadiazepin-9-yl 2,2-dimethylpropionate" and is known, for
example, from WO 99/47525. The disclosure of the abovementioned
publications is incorporated into the present description by way of
reference. The chemical structures of the other active compounds
referred to above by their common names are known, for example,
from "The Pesticide Manual"13th edition, 2003, British Crop
Protection Council. If, in the context of this description, the
short form of the common name of an active compound is used, this
embraces in each case all customary derivatives, such as the esters
and salts, and isomers, in particular optical isomers, especially
the commercial form or forms. If the common name refers to an ester
or salt, this also includes in each case all other customary
derivatives, such as other esters and salts, the free acids and
neutral compounds, and isomers, in particular optical isomers,
especially the commercial form or forms. The given chemical
compound names refer to at least one of the compounds embraced by
the common name, frequently to a preferred compound.
[0032] In a preferred embodiment, the herbicidal compositions
according to the invention are synergistically active and at the
same time highly compatible with crop plants. The synergistic
actions. and the high compatibility with crop plants can be
observed, for example, when the components (A), (B) and (C) are
applied together; however, they can frequently also be observed
when the active compounds are applied at different times
(splitting). It is also possible to apply the individual herbicides
and safeners or the herbicide/safener combinations in a plurality
of portions (sequential application), for example pre-emergence
applications followed by post-emergence applications or early
post-emergence applications followed by medium or late
post-emergence applications. Preference is given here to the joint
or almost simultaneous application of the active compounds of the
herbicide combination according to the invention.
[0033] The synergistic effects permit a reduction of the
application rates of the individual active compounds, a higher
efficacy at the same application rate, the control of species which
are as yet uncontrolled (gaps), an extension of the period of
application and/or a reduction in the number of individual
applications required and--as a result for the user--weed control
systems which are more advantageous economically and
ecologically.
[0034] The invention also encompasses herbicidal compositions
which, in addition to the components (A), (B) and (C), also
comprise one or more further agrochemically active compounds of a
different structure, such as herbicides, insecticides, fungicides
or safeners. The preferred conditions illustrated above and below
also apply to these herbicidal compositions.
[0035] The invention also encompasses herbicidal compositions
which, in addition to the components (A), (B) and (C), also
comprise fertilizers, such as ammonium sulfate, ammonium nitrate,
urea, potassium nitrate and mixtures thereof. The preferred
conditions illustrated above and below also apply to these
herbicidal compositions.
[0036] The invention furthermore also embraces herbicidal
compositions which, in addition to components (A), (B) and (C),
also comprise adjuvants, such as emulsifiers, dispersants, mineral
and vegetable oils and mixtures thereof. The preferred conditions
illustrated above and below also apply to these herbicidal
compositions.
[0037] Of particular interest are herbicidal
compositions-comprising one or more of the following combinations
of three compounds (A+B+C): [0038] (A+B1.1+C1), (A+B1.2+C1),
(A+B1.3+C1), (A+B1.4+C1), [0039] (A+B2.1+C1), (A+B2.2+C1),
(A+B2.3+C1), (A+B2.4+C1), [0040] (A+B2.5+C1), (A+B3.1+C1),
(A+B3.2+C1), (A+B3.3+C1), [0041] (A+B3.4+C1), (A+B4.1+C1), [0042]
(A+B1.1+C2), (A+B1.2+C2), (A+B1.3+C2), (A+B1.4+C2), [0043]
(A+B2.1+C2), (A+B2.2+C2), (A+B2.3+C2), (A+B2.4+C2), [0044]
(A+B2.5+C2), (A+B3.1+C2), (A+B3.2+C2), (A+B3.3+C2), [0045]
(A+B3.4+C2), (A+B4.1+C2), [0046] (A+B1.1+C3), (A+B1.2+C3),
(A+B1.3+C3), (A+B1.4+C3), (A+B2.1+C3), (A+B2.2+C3), (A+B2.3+C3),
(A+B2.4+C3), [0047] (A+B2.5+C3), (A+B3.1+C3), (A+B3.2+C3),
(A+B3.3+C3), [0048] (A+B3.4+C3), (A+B4.1+C3),
[0049] In a further preferred embodiment, the herbicidal
compositions according to the invention comprise the herbicide (A),
two different components (B) and one safener (C).
[0050] Among-these, particular preference is given to herbicidal
compositions comprising one or more of the following combinations
of four compounds (A+B+B+C): [0051] (A+B1.1+B1.2+C1),
(A+B1.1+B1.3+C1), (A+B1.1+B1.4+C1), [0052] (A+B1.1+B2.1+C1),
(A+B1.1+B2.2+C1), (A+B1.1+B2.3+C1), [0053] (A+B1.1+B2.4+C1),
(A+B1.1+B2.5+C1), (A+B1.1+B3.1+C1), [0054] (A+B1.1+B3.2+C1),
(A+B1.1+B3.3+C1), (A+B1.1+B3.4+C1), [0055] (A+B1.1+B4.1+C1),
(A+B1.1+B1.2+C2), (A+B1.1+B1.3+C2), [0056] (A+B1.1+B1.4+C2),
(A+B1.1+B2.1+C2), (A+B1.1+B2.2+C2), [0057] (A+B1.1+B2.3+C2),
(A+B1.1+B2.4+C2), (A+B1.1+B2.5+C2), [0058] (A+B1.1+B3.1+C2),
(A+B1.1+B3.2+C2), (A+B1.1+B3.3+C2), [0059] (A+B1.1+B3.4+C2),
(A+B1.1+B3.4+C2), (A+B1.1+B4.1+C2), [0060] (A+B1.1+B1.2+C3),
(A+B1.1+B1.3+C3), (A+B1.1+B1.4+C3), [0061] (A+B1.1+B2.1+C3),
(A+B1.1+B2.2+C3), (A+B1.1+B2.3+C3), [0062] (A+B1.1+B2.4+C3),
(A+B1.1+B2.5+C3), (A+B1.1+B3.1+C3), [0063] (A+B1.1+B3.2+C3),
(A+B1.1+B3.3+C3), (A+B1.1+B3.4+C3), [0064] (A+B1.1+B4.1+C3), [0065]
(A+B1.2+B1.3+C1), (A+B1.2+B1.4+C1), (A+B1.2+B2.1+C1), [0066]
(A+B1.2+B2.2+C1), (A+B1.2+B2.3+C1), (A+B1.2+B2.4+C1), [0067]
(A+B1.2+B2.5+C1), (A+B1.2+B3.1+C1), (A+B1.2+B3.2+C1), [0068]
(A+B1.2+B3.3+C1), (A+B1.2+B3.4+C1), (A+B1.2+B4.1+C1), [0069]
(A+B1.2+B1.3+C2), (A+B1.2+B1.4+C2), (A+B1.2+B2.1+C2), [0070]
(A+B1.2+B2.2+C2), (A+B1.2+B2.3+C2), (A+B1.2+B2.4+C2), [0071]
(A+B1.2+B2.5+C2), (A+B1.2+B3.1+C2), (A+B1.2+B3.2+C2), [0072]
(A+B1.2+B3.3+C2), (A+B1.2+B3.4+C2), (A+B1.2+B4.1+C2), [0073]
(A+B1.2+B1.3+C3), (A+B1.2+B1.4+C3), (A+B1.2+B2.1+C3), [0074]
(A+B1.2+B2.2+C3), (A+B1.2+B2.3+C3), (A+B1.2+B2.4+C3), [0075]
(A+B1.2+B2.5+C3), (A+B1.2+B3.1+C3), (A+B1.2+B3.2+C3), [0076]
(A+B1.2+B3.3+C3), (A+B1.2+B3.4+C3), (A+B1.2+B4.1+C3), [0077]
(A+B1.3+B1.4+C1), (A+B1.3+B2.1+C1), (A+B1.3+B2.2+C1), [0078]
(A+B1.3+B2.3+C1), (A+B1.3+B2.4+C1), (A+B1.3+B2.5+C1), [0079]
(A+B1.3+B3.1+C1), (A+B1.3+B3.2+C1), (A+B1.3+B3.3+C1), [0080]
(A+B1.3+B3.4+C1), (A+B1.3+B4.1+C1), (A+B1.3+B1.4+C2), [0081]
(A+B1.3+B2.1+C2), (A+B1.3+B2.2+C2), (A+B1.3+B2.3+C2), [0082]
(A+B1.3+B2.4+C2), (A+B1.3+B2.5+C2), (A+B1.3+B3.1+C2), [0083]
(A+B1.3+B3.2+C2), (A+B1.3+B3.3+C2), (A+B1.3+B3.4+C2), [0084]
(A+B1.3+B4.1+C2), (A+B1.3+B1.4+C3), (A+B1.3+B2.1+C3),
(A+B1.3+B2.2+C3), (A+B1.3+B2.3+C3), (A+B1.3+B2.4+C3), [0085]
(A+B1.3+B2.5+C3), (A+B1.3+B3.1+C3), (A+B1.3+B3.2+C3), [0086]
(A+B1.3+B3.3+C3), (A+B1.3+B3.4+C3), (A+B1.3+B4.1+C3), [0087]
(A+B1.4+B2.1+C1), (A+B1.4+B2.2+C1), (A+B1.4+B2.3+C1), [0088]
(A+B1.4+B2.4+C1), (A+B1.4+B2.5+C1), (A+B1.4+B3.1+C1), [0089]
(A+B1.4+B3.2+C1), (A+B1.4+B3.3+C1), (A+B1.4+B3.4+C1), [0090]
(A+B1.4+B4.1+C1), (A+B1.4+B2.1+C2), (A+B1.4+B2.2+C2), [0091]
(A+B1.4+B2.3+C2), (A+B1.4+B2.4+C2), (A+B1.4+B2.5+C2), [0092]
(A+B1.4+B3.1+C2), (A+B1.4+B3.2+C2), (A+B1.4+B3.3+C2), [0093]
(A+B1.4+B3.4+C2), (A+B1.4+B4.1+C2), (A+B1.4+B2.1+C3), [0094]
(A+B1.4+B2.2+C3), (A+B1.4+B2.3+C3), (A+B1.4+B2.4+C3), [0095]
(A+B1.4+B2.5+C3), (A+B1.4+B3.1+C3), (A+B1.4+B3.2+C3), [0096]
(A+B1.4+B3.3+C3), (A+B3.4+B3.3+C3), (A+B1.4+B4.1+C3), [0097]
(A+B2.1+B2.2+C1), (A+B2.1+B2.3+C1), (A+B2.1+B2.4+C1), [0098]
(A+B2.1+B2.5+C1), (A+B2.1+B3.1+C1), (A+B2.1+B3.2+C1), [0099]
(A+B2.1+B3.3+C1), (A+B2.1+B3.4+C1), (A+B2.1+B4.1+C1), [0100]
(A+B2.1+B2.2+C2), (A+B2.1+B2.3+C2), (A+B2.1+B2.4+C2), [0101]
(A+B2.1+B2.5+C2), (A+B2.1+B3.1+C2), (A+B2.1+B3.2+C2), [0102]
(A+B2.1+B3.3+C2), (A+B2.1+B3.4+C2), (A+B2.1+B4.1+C2), [0103]
(A+B2.1+B2.2+C3), (A+B2.1+B2.3+C3), (A+B2.1+B2.4+C3), [0104]
(A+B2.1+B2.5+C3), (A+B2.1+B3.1+C3), (A+B2.1+B3.2+C3), [0105]
(A+B2.1+B3.3+C3), (A+B2.1+B3.4+C3), (A+B2.1+B4.1+C3), [0106]
(A+B2.2+B2.3+C1), (A+B2.2+B2.4+C1), (A+B2.2+B2.5+C1), [0107]
(A+B2.2+B3.1+C1), (A+B2.2+B3.2+C1), (A+B2.2+B3.3+C1), [0108]
(A+B2.2+B3.4+C1), (A+B2.2+B4.1+C1), (A+B2.2+B2.3+C2), [0109]
(A+B2.2+B2.4+C2), (A+B2.2+B2.5+C2), (A+B2.2+B3.1+C2), [0110]
(A+B2.2+B3.2+C2), (A+B2.2+B3.3+C2), (A+B2.2+B3.4+C2), [0111]
(A+B2.2+B4.1+C2), (A+B2.2+B2.3+C3), (A+B2.2+B2.4+C3), [0112]
(A+B2.2+B2.5+C3), (A+B2.2+B3.1+C3), (A+B2.2+B3.2+C3), [0113]
(A+B2.2+B3.3+C3), (A+B2.2+B3.4+C3), (A+B2.2+B4.1+C3), [0114]
(A+B2.3+B2.4+C1), (A+B2.3+B2.5+C1), (A+B2.3+B3.1+C1), [0115]
(A+B2.3+B3.2+C1), (A+B2.3+B3.3+C1), (A+B2.3+B3.4+C1), [0116]
(A+B2.3+B4.1+C1), (A+B2.3+B2.4+C2), (A+B2.3+B2.5+C2), [0117]
(A+B2.3+B3.1+C2), (A+B2.3+B3.2+C2), (A+B2.3+B3.3+C2), [0118]
(A+B2.3+B3.4+C2), (A+B2.3+B4.1+C2), (A+B2.3+B2.4+C3), [0119]
(A+B2.3+B2.5+C3), (A+B2.3+B3.1+C3), (A+B2.3+B3.2+C3), [0120]
(A+B2.3+B3.3+C3), (A+B2.3+B3.4+C3), (A+B2.3+B4.1+C3), [0121]
(A+B2.4+B2.5+C1), (A+B2.4+B3.1+C1), (A+B2.4+B3.2+C1), [0122]
(A+B2.4+B3.3+C1), (A+B2.4+B3.4+C1), (A+B2.4+B4.1+C1), [0123]
(A+B2.4+B2.5+C2), (A+B2.4+B3.1+C2), (A+B2.4+B3.2+C2), [0124]
(A+B2.4+B3.3+C2), (A+B2.4+B3.4+C2), (A+B2.4+B4.1+C2), [0125]
(A+B2.4+B2.5+C3), (A+B2.4+B3.1+C3), (A+B2.4+B3.2+C3), [0126]
(A+B2.4+B3.3+C3), (A+B2.4+B3.4+C3), (A+B2.4+B4.1+C3), [0127]
(A+B2.5+B3.1+C1), (A+B2.5+B3.2+C1), (A+B2.5+B3.3+C1), [0128]
(A+B2.5+B3.4+C1), (A+B2.5+B4.1+C1), (A+B2.5+B3.1+C2), [0129]
(A+B2.5+B3.2+C2), (A+B2.5+B3.3+C2), (A+B2.5+B4.1+C2), [0130]
(A+B2.5+B3.1+C3), (A+B2.5+B3.2+C3), (A+B2.5+B3.3+C3), [0131]
(A+B2.5+B3.4+C3), (A+B2.5+B4.1+C3), [0132] (A+B3.1+B3.2+C1),
(A+B3.1+B3.3+C1), (A+B3.1+B4.1+C1), [0133] (A+B3.1+B3.2+C2),
(A+B3.1+B3.3+C2), (A+B3.1+B3.4+C2), [0134] (A+B3.1+B4.1+C2),
(A+B3.1+B3.2+C3), (A+B3.1+B3.3+C3), [0135] (A+B3.1+B3.4+C3),
(A+B3.1+B4.1+C3), [0136] (A+B3.2+B3.3+C1), (A+B3.2+B4.1+C1),
(A+B3.2+B3.3+C2), [0137] (A+B3.2+B3.4+C2), (A+B3.2+B4.1+C2),
(A+B3.2+B3.3+C3), [0138] (A+B3.2+B3.4+C3), (A+B3.2+B4.1+C3), [0139]
(A+B3.3+B4.1+C1), (A+B3.3+B4.1+C2), (A+B3.4+B4.1+C2), [0140]
(A+B3.3+B4.1+C3).
[0141] For the herbicidal compositions according to the invention,
application rates in the range from 1 to 2000 g, preferably from 10
to 1000 g, particularly preferably from 10 to 300 g, of
active-ingredient per hectare (ai/ha) of the component (A) and from
1 to 2000 g, preferably from 1 to 1000 g, particularly preferably
from 5 to 500 g, of the component (B) and from 1 to 1000 g,
preferably from 1 to 500 g, particularly preferably from 5 to 250
g, of the component (C) are generally required.
[0142] The weight ratios of the components (A) to (B) on the one
hand and (A+B) to (C) on the other hand can be varied within wide
ranges. The ratio of the components (A) to (B) is preferably in the
range from 1:100 to 100:1, particularly preferably in the range
from 1:50 to 50:1, especially in the range from 1:20 to 20:1. The
ratio of the components (A+B) to (C) is preferably in the range
from 1:10 to 50:1, in particular in the range from 1:5 to 20:1. The
ranges mentioned above also apply to the case where the herbicidal
compositions according to the invention comprise more than one
component (B) and/or component (C). In this case, the numbers
mentioned apply to the sum of the individual values of the
components (B) or (C).
[0143] Optimum weight ratios may depend on the particular field of
application, on the weed spectrum and on the active compound
combination used and can be determined in preliminary
experiments.
[0144] The compositions according to the invention can be employed
for the selective control of annual and perennial monocotyledonous
and dicotyledonous harmful plants in crops of cereals (for example
barley, oats, rye, wheat), corn and rice and in crops of transgenic
useful plants or crops of useful plants selected by classical means
which are resistant to the active compounds (A) and (B). Likewise,
they can be employed for controlling unwanted harmful plants in
plantation crops such as oil palm, coconut palm, Indian-rubber
tree, citrus, pineapple, cotton, coffee, cocoa and the like, and
also in fruit production and viticulture. Owing to their good
compatibility, they are particularly suitable for use in cereals
and corn, especially cereals.
[0145] The compositions according to the invention act against a
broad spectrum of weeds. They are suitable for example, for
controlling annual and perennial harmful plants such as, for
example, from the species Abutilon, Alopecurus, Avena, Chenopodium,
Cynodeo, Cyperus, Digitaria, Echinochloa, Elymus, Galium, Ipomoea,
Kochia, Lamium, Matricaria, Polygonum, Scirpus, Setaria, Sorghum,
Veronica, Viola and Xanthium.
[0146] A further advantage of the compositions according to the
invention is their excellent action against many harmful plants
which have now become resistant to sulfonylureas, such as, for
example, Kochia.
[0147] The invention also provides a method for controlling
unwanted vegetation, which comprises applying the herbicide (A) and
one or more herbicides (B) and one or more safeners (C) to the
harmful plants, to parts of the harmful plants or to the area under
cultivation.
[0148] The herbicidal compositions according to the invention are
also distinguished by the fact that the effective dosages of the
components (A) and (B) used in the combinations are reduced with
respect to an individual dosage, so that it is possible to reduce
the required active compound application rates (synergistic
effect). At the same time, the compatibility with crop plants is
more pronounced by the presence of the safener (C) than in the case
of a combination of the safener (C) with the herbicide (A) or a
herbicide (B). The synergistic effects permit the application rate
to be reduced, a broader spectrum of broad-leaved weeds and weed
grasses to be controlled, a more rapid onset of the herbicidal
action, a longer persistency, better control of the harmful plants
by only one application, or few applications, and widening of the
period of time within which the product can be used. These
properties are required in weed control practice to keep
agricultural crops free from unwanted competing plants and thus to
ensure and/or to increase quality and quantity of the yields. These
novel combinations markedly surpass the prior art with respect to
the described properties.
[0149] The herbicidal compositions according to the invention can
either be present as mixed formulations of the herbicides (A) and
(B) and the safener (C), if appropriate together with other
customary formulation auxiliaries, which mixed formulations are
then applied in the usual manner in the form of a dilution with
water, or else they can be prepared in the form of so-called tank
mixes by joint dilution with water of the components which are
formulated separately, or partly separately.
[0150] The herbicidal compositions according to the invention can
be formulated in various ways, depending on the prevailing
biological and/or physicochemical parameters. Suitable general
possibilities for formulations are, for example: wettable powders
(WP), emulsifiable concentrates (EC), aqueous solutions (SL),
emulsions (EW) such as oil-in-water and water-in-oil emulsions,
sprayable solutions or emulsions, oil suspension concentrate (SC),
oil- or water-based dispersions, suspoemulsions, dusts (DP), seed
dressing products, granules for soil application or for
broadcasting or water-dispersible granules (WG), water-dispersible
granules (WDG), water-emulsifiable granules (WEG), ULV
formulations, microcapsules or waxes.
[0151] The individual types of formulation are known in principle
and are described, for example, in: Winnacker-Kuchler, "Chemische
Technologie" [Chemical Technology], Vol. 7, C. Hauser Verlag
Munich, 4th Ed. 1986; van Valkenburg, "Pesticides Formulations",
Marcel Dekker N.Y., 1973; K. Martens, "Spray Drying Handbook", 3rd
Ed. 1979, G. Goodwin Ltd. London. The formulation auxiliaries
required, such as inert materials, surfactants, solvents and other
additives, are also known and are described, for example, in:
Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd
Ed., Darland Books, Caldwell N.J.; H. v. Olphen, "Introduction to
Clay Colloid Chemistry"; 2nd-Ed., J. Wiley & Sons, N.Y.;
Marsden, "Solvents Guide", 2nd Ed., Interscience, N.Y.
1950McCutcheon's, "Detergents and Emulsifiers Annual", MC Publ.
Corp., Ridgewood N.J.; Sisley and Wood, "Encyclopedia of Surface
Active Agents", Chem. Publ. Co. Inc., N.Y. 1964; Schonfeldt,
"Grenzflachenaktive Athylenoxidaddukte" [Surface-active ethylene
oxide adducts], Wiss Verlagsgesellschaft, Stuttgart 1976;
Winnacker-Kuchler, "Chemische Technologie" [Chemical Technology],
Vol. 7, C. Hauser Verlag Munich, 4th Ed. 1986.
[0152] Based on these formulations, it is also possible to prepare
combinations with other pesticidally active substances, such as
other herbicides, fungicides or insecticides, and also safeners,
fertilizers and/or growth regulators, for example in the form of a
ready mix or tank mix.
[0153] Wettable powders are preparations which are uniformly
dispersible in water and which, besides the active compound, also
comprise ionic or nonionic surfactants (wetting agents,
dispersants), for example polyethoxylated alkylphenols,
polyethoxylated fatty alcohols or fatty amines, alkanesulfonates or
alkylbenzene-sulfonates, sodium lignosulfonate, sodium
2,2'-dinaphthylmethane-6,6'-disulfonate, sodium
dibutylnaphthalenesulfonate or else sodium oleoylmethyltaurinate,
in addition to a diluent or an inert substance.
[0154] Emulsifiable concentrates are prepared by dissolving the
active compound in an organic solvent, for example butanol,
cyclohexanone, dimethylformamide, xylene or else higher-boiling
aromatics or hydrocarbons, with the addition of one or more ionic
or nonionic surfactants (emulsifiers). Examples of emulsifiers
which can be used are: calcium alkylarylsulfonates, such as calcium
dodecylbenzenesulfonate, or nonionic emulsifiers, such as fatty
acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol
polyglycol ethers, propylene oxide/ethylene oxide condensates,
alkyl polyethers, sorbitan fatty acid esters, polyoxyethylene
sorbitan fatty acid esters or polyoxyethylene sorbitol esters.
[0155] Dusts are obtained by grinding the active compound with
finely divided solid materials, for example talc, natural clays,
such as kaolin, bentonite and pyrophyllite, or diatomaceous
earth.
[0156] Granules can be prepared either by spraying the active
compound onto absorptive, granulated inert material, or by applying
active compound concentrates to the surface of carriers, such as
sand, kaolinite or granulated inert material, with the aid of
binders, for example polyvinyl alcohol,-sodium polyacrylate or else
mineral oils. Suitable active compounds can also be granulated in
the manner customary for the preparation of fertilizer granules, if
desired as a mixture with fertilizers. Water-dispersible granules
are, in general, prepared by processes such as spray-drying,
fluidized-bed granulation, disk granulation, mixing using
high-speed mixers, and extrusion without solid inert material.
[0157] The agrochemical preparations generally comprise from 0.1 to
99 percent by weight, in particular from 0.2 to 95% by weight, of
components (A), (B) and (C), the following concentrations being
customary, depending on the type of formulation: in wettable
powders, the active compound concentration is, for example,
approximately 10 to 95% by weight, the remainder to 100% by weight
being composed of customary formulation components. In the case of
emulsifiable concentrates, the active compound concentration can
be, for example, from 5 to 80% by weight. Formulations in the form
of dusts in most cases comprise from 5 to 20% by weight of active
compound, sprayable solutions approximately 0.2 to 25% by weight of
active compound. In the case of granules, such as dispersible
granules, the active compound content depends partly on whether the
active compound is in liquid or solid form and on which granulation
auxiliaries and fillers are used. In general, the content in the
water-dispersible granules amounts to between 10 and 90% by weight.
In addition, the active compound formulations mentioned comprise,
if appropriate, the tackifiers, wetting agents, dispersants,
emulsifiers, preservatives, antifreeze agents, solvents, fillers,
colorants, carriers, antifoams, evaporation inhibitors and pH or
viscosity regulators which are customary in each case.
[0158] For use, the formulations, which are in commercially
available form, are, if appropriate, diluted in a customary manner,
for example using water in the case of wettable powders,
emulsifiable concentrates, dispersions and water-dispersible
granules. Preparations in the form of dusts, soil granules,
granules for spreading and sprayable solutions are conventionally
not diluted any further with other inert substances prior to
use.
[0159] The active compounds can be applied to the plants, to parts
of plants, to plant seeds or to the area under cultivation (tilled
soil), preferably to the green plants and parts of the plants and,
if desired, additionally to the tilled soil.
[0160] A possible use is the joint application of the active
compounds in the form of tank mixes, where the concentrated
formulations of the individual active compounds, in the form of
their optimal formulations, are mixed jointly with water in the
tank, and the spray mixture obtained is applied.
[0161] A joint herbicidal formulation of the herbicidal
compositions according to the invention has the advantage that it
can be applied more easily because the amounts of the components
have already been adjusted with respect to one another to the
correct ratio. Moreover, the auxiliaries of the formulation can be
selected to suit each other in the best possible way, while a tank
mix-of various formulations may result in undesirable combinations
of auxiliaries.
A. FORMULATION EXAMPLES
[0162] a) A dust (WP) is obtained by mixing 10 parts by weight of
an active compound/active compound mixture and 90 parts by weight
of talc as inert substance and comminuting the mixture in a hammer
mill.
[0163] b) A wettable powder (WG) which is readily dispersible in
water is obtained by mixing 25 parts by weight of an active
compound/active compound mixture, 64 parts by weight of
kaolin-containing quartz as inert substance, 10 parts by weight of
potassium lignosulfonate and 1 part by weight of sodium
oleoylmethyltaurinate as wetting agent and dispersant, and grinding
the mixture in a pinned-disk mill.
[0164] c) A dispersion concentrate which is readily dispersible in
water is obtained by mixing 20parts by weight of an active
compound/active compound mixture with 6parts by weight of
alkylphenol polyglycol ether (Triton X 207), 3 parts by weight of
isotridecanol polyglycol ether (8 EO) and 71parts by weight of
paraffinic mineral oil (boiling range for example approximately 255
to 277.degree. C.) and grinding the mixture in a ball mill to a
fineness of below 5 microns.
[0165] d) An emulsifiable concentrate (EC) is obtained from 15
parts by weight of an active compound/active compound mixture, 75
parts by weight of cyclohexanone as solvent and 10 parts by weight
of ethoxylated nonylphenol as emulsifier.
[0166] e) Water-dispersible granules are obtained by mixing [0167]
75 parts by weight of an active compound/active compound mixture,
[0168] 10 parts by weight of calcium lignosulfonate, [0169] 5 parts
by weight of sodium lauryl sulfate, [0170] 3 parts by weight of
polyvinyl alcohol and [0171] 7 parts by weight of kaolin, grinding
the mixture in a pinned-disk mill and granulating the powder in a
fluidized bed by spraying on water as granulation liquid.
[0172] f) Water-dispersible granules are also obtained by
homogenizing and precomminuting, in a colloid mill, [0173] 25 parts
by weight of an active compound/active compound mixture, [0174] 5
parts by weight of sodium 2,2'-dinaphthylmethane-6,6'-disulfonate,
[0175] 2 parts by weight of sodium oleoylmethyltaurinate, [0176] 1
part by weight of polyvinyl alcohol, [0177] 17 parts by weight of
calcium carbonate and [0178] 50 parts by weight of water,
subsequently grinding the mixture in a bead mill and atomizing and
drying the resulting suspension in a spray tower by means of a
single-substance nozzle.
B. BIOLOGICAL EXAMPLES
[0178] 1. Herbicidal Post-Emergence Action
[0179] Seeds of monocotyledonous and dicotyledonous weed and crop
plants are place into sandy loam in wood fiber pots or in plastic
pots, covered with soil and cultivated in a greenhouse, including
during the vegetation period outdoors outside of the greenhouse,
under good growth conditions. 2-3 weeks after sowing, the test
plants are treated at the one- to three-leaf stage. The test
compounds, formulated as wettable powders (WP) or liquid (EC) are,
in various dosages with a water application rate of 300 l/ha
(converted), with added wetting agent (0.2 to 0.3%), sprayed onto
the plants and the surface of the soil. 3 to 4 weeks after the
treatment of the test plants, the effect of the preparations is
rated visually in comparison to untreated controls (herbicidal
effect in percent (%): 100% effect=plants have died, 0% effect=like
control plants).
Use of Safeners
[0180] If it is additionally to be tested as to whether safeners
can improve the plant compatibility of test substances in the case
of crop plants, the following options are used for applying the
safener: [0181] seeds of the crop plants are, before sowing,
dressed with the safener substance (the amount of safener is stated
in percent, based on the weight of the seed) [0182] before the
application of the test substances, the crop plants are sprayed
with the safener at a certain application rate per hectare (usually
1 day before the application of the test substances)
[0183] the safener is applied together with the test substance as a
tank mix (the amount of safener is stated in g/ha or as a ratio,
based on the herbicide).
[0184] By comparing the effect of the test substances on crop
plants without or with safener treatment, it is possible to assess
the effect of the safener substance. TABLE-US-00001 TABLE 1 Value
Activity against according Component Dosage [g of a.i./ha] STEME to
Colby A 37.5 50% B1.2 140 70% C1 9.4 0% A + B1.2 + C1 37.5 + 140 +
9.4 100% 85%
[0185] TABLE-US-00002 TABLE 2 Value Activity against according
Component Dosage [g of a.i./ha] STEME to Colby A 37.5 50% B4.1 75
70% C1 9.4 0% A + B4.1 + C1 37.5 + 75 + 9.4 99% 85%
[0186] TABLE-US-00003 TABLE 3 Component Dosage [g of a.i./ha]
Damage of summer wheat A 300 15% B1.2 1680 25% A + B1.2 + C1 300 +
1680 + 75 5%
[0187] TABLE-US-00004 TABLE 4 Herbicidal effect against Component
Dosage [g of a.i./ha] AMARE CHEAL A + B 1.2 + C1 25 + 140 + 18.8
85% 85% B3.2 46 0% 0% A + B 1.2 + C1 + B3.2 25 + 140 + 18.8 + 46
90% 90%
[0188] Tables 1 and 2 each state the herbicidal activities of the
herbicides A, B1.2 and B4.1, those of the safener and those of the
mixtures according to the invention (A+B1.2+C1) and (A+B4.1+C1),
respectively. Here, it is found that the herbicidal activities of
the compositions according to the invention (100% and 99%,
respectively) exceed the expected values according to Colby (in
each case 85%) which are calculated using the formula below (cf. S.
R. Colby; in Weeds 15 (1967) pp. 20-22): E = A + B - A .times. B
100 ##EQU1##
[0189] Here, the figures denote:
[0190] A, B=effect of the component A and B, respectively, in
percent
[0191] E=expected value in percent
[0192] The results of table 3 show that the damage of the
compositions according to the invention to crop plants is
insignificant even at a very high dosage. Table 4 shows the results
of the use of a special embodiment, according to which the
composition according to the invention comprises a second herbicide
of group B. At the stated dosage, the composition comprising the
active compounds A, B1.2 and C1 has a herbicidal activity of in
each case 85% against AMARE and CHEAL, which is in each case
increased to 90% by adding the second herbicide B3.2 which, at the
stated dosage, does not display any herbicidal activity against
AMARE and CHEAL.
* * * * *