U.S. patent application number 11/105975 was filed with the patent office on 2005-10-27 for tissue paper with protruding lotion deposits.
Invention is credited to Anast, John Matthew, Butz, Dirk, Kleinwaechter, Joerg, Warner, Ronald Ray.
Application Number | 20050238682 11/105975 |
Document ID | / |
Family ID | 34967194 |
Filed Date | 2005-10-27 |
United States Patent
Application |
20050238682 |
Kind Code |
A1 |
Anast, John Matthew ; et
al. |
October 27, 2005 |
Tissue paper with protruding lotion deposits
Abstract
A paper tissue and products made from paper tissue, such as
paper handkerchiefs, facial tissues, bath and cosmetic tissues,
paper tissue wipes of any kinds and the like. The invention also
relates to tissue paper including deposits of lotions on the
surface of the tissue paper that protrude a significant height
above the average plan of the tissue.
Inventors: |
Anast, John Matthew;
(Fairfield, OH) ; Warner, Ronald Ray; (Cincinnati,
OH) ; Kleinwaechter, Joerg; (Hofheim Am Tanus,
DE) ; Butz, Dirk; (Hofheim Am Tanus, DE) |
Correspondence
Address: |
THE PROCTER & GAMBLE COMPANY
INTELLECTUAL PROPERTY DIVISION
WINTON HILL TECHNICAL CENTER - BOX 161
6110 CENTER HILL AVENUE
CINCINNATI
OH
45224
US
|
Family ID: |
34967194 |
Appl. No.: |
11/105975 |
Filed: |
April 14, 2005 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
60565104 |
Apr 23, 2004 |
|
|
|
Current U.S.
Class: |
424/402 ;
162/135; 162/158 |
Current CPC
Class: |
D21H 25/02 20130101;
D21H 23/22 20130101; D21H 27/02 20130101; D21H 19/10 20130101; D21C
7/14 20130101 |
Class at
Publication: |
424/402 ;
162/135; 162/158 |
International
Class: |
D21H 021/14 |
Claims
What is claimed is:
1. A paper tissue having first and second opposed surfaces,
comprising a lotion on at least one surface of said paper tissue,
said lotion being present in substantially discrete protruding
deposits onto said first surface, wherein said paper tissue has a
bulk of equal or less than 5.2 cm.sup.3/g of tissue wherein said
protruding deposits have an average height of at least 30
.mu.m.
2. A paper tissue of claim 1 wherein said deposits have an average
height of at least 35 .mu.m.
3. A paper tissue of claim 2 wherein said deposits have an average
height of at least 38 .mu.m.
4. A paper tissue of claim 1 wherein a ratio R is defined by 3 R =
Lotion basis weight of the protruding deposits ( g / sqm ) lotion
basis weight of the tissue ( g / sqm ) and said ratio R is larger
than 0.005.
5. A paper tissue of claim 4 wherein said ratio R is larger than
0.01.
6. A paper tissue of claim 1 wherein said paper tissue comprised at
least 2 protruding deposits per square cm of tissue.
7. A paper tissue of claim 1 wherein said lotion is detected by
osmium tetroxide staining.
8. A paper tissue of claim 1 wherein said lotion is detected by
scanning IR spectroscopy.
9. A paper tissue of claim 1 wherein said lotion comprises at least
30% SEFOSE 1618 S.RTM. and preferably at least 10% stearyl
alcohol.
10. A paper tissue of claim 1 wherein the lotion basis weight on
said tissue is equal or less than 9 g/sqm.
11. A paper tissue of claim 1 wherein the ratio R.sub.2 is defined
as 4 R 2 = Area of the protruding deposits measured at the
threshold value of claim 1 ( mm ^ 2 ) Area of the tissue ( mm ^ 2 )
* Lotion weight of the tissue ( g / sqm ) and R.sub.2 is at least
0.0005.
Description
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] This application claims the benefit of U.S. Provisional
Application Ser. No. 60/565,104 filed on Apr. 23, 2004.
FIELD OF THE INVENTION
[0002] The present invention relates to paper tissues, and products
made from paper tissues. More particularly, the present invention
relates to a tissue including lotion deposits having a significant
height above the average plane of the tissue surface.
BACKGROUND OF THE INVENTION
[0003] Paper tissues sometimes called paper webs or sheets,
tissues, tissue layers, paper plies or paper tissue webs, and
products made there from, such as paper handkerchiefs, paper
kitchen towel or bath tissue, toilet paper or facial tissues, find
extensive use in modem society and are well known in the art.
[0004] Paper tissues are generally made by the layering of
cellulose fibers, in a wet form, onto a screen, with the addition
of various additives or other ingredients, followed by a drying
step. Other process steps, before, during or after the
above-mentioned paper making steps are targeted at giving the
desired properties to the tissue. Converting steps are aimed at
creating a finished product from the paper tissue(s).
[0005] Products made from paper tissues can be made by the
association of multiple layers of paper tissues, also called plies,
or can comprise a single paper tissue layer (single ply products).
Those plies can be combined and held together in multiple ways to
form the finished product, for example by embossing of the
multi-ply structure or/and by gluing. The finished products are
herein referred to as paper tissue products. Finished products made
of more than one ply have internal tissue (or ply) surfaces,
inwardly orientated, and 2 external surfaces, outwardly
orientated.
[0006] It has long been recognised that important physical
attributes of these paper tissues are their strength and
thickness/bulkiness, their softness and smoothness, and their
absorbency. Softness and smoothness relate to the tactile sensation
perceived by the consumer when holding a particular product,
rubbing it across the skin, or crumpling it within the hands.
[0007] Relatively thick and yet soft disposable paper products,
namely in the form of paper handkerchiefs, are known. For example,
Tempo.TM., sold by The Procter & Gamble Company, is a multi-ply
paper product experienced as thick and soft and having a caliper of
about 0.3 mm. A high calliper conveys the idea of high dry and wet
strength to the consumer. A high wet strength, also referred to as
wet burst strength, in particular prevents tearing or bursting
which for a paper handkerchief in turn results in contamination of
the user's hand with mucus or other body fluids. A common way to
enhance the smoothness of the tissue surface is to calender the
material. Another way to improve the sensation of smoothness
perceived by the users of paper tissue products, such as
handkerchiefs, is to complement the composition of the paper tissue
with some additives during the paper-making phase and/or during the
converting phase. Those additives can have the effect of
smoothening the paper tissue in a way that makes the user feel it
more soft or smooth. Alternatively or additionally some additives
have an effect on the skin of the user touching or using the paper
tissue product, e.g. smoothening of the skin, hydration of the
skin, This later effects are usually obtained through a partial
transfer of the additives onto the skin during usage, thus
prolonging the effect of the additives on the skin beyond the
period of contact between the paper-tissue product and skin.
[0008] Smoothening lotions are usually of hydrophobic nature or
contain hydrophobic compounds. The presence of the lotion at the
surface of the paper tissue can have adverse effects on the
properties of the paper tissue: First, the masking of the
hydrophilic tissue surface by an hydrophobic lotion can reduce the
absorbency of tissue or the speed of absorbency. This present a
undesirable effect for the user. For example, one a paper
handkerchief, the nasal mucus can take a longer time to be absorbed
by a lotioned paper tissue than by a non lotioned one. Second, the
lotion can migrate from tissue the surface thru the paper tissue
structure making the paper tissue less hydrophilic and making less
lotion available at the surface to deliver the smoothening benefits
to the skin. A traditional way to respond to that expected
migration of the lotion over time is to use a relatively high
amount of lotion to insure a certain availability of the lotion on
the surface of the tissue, even after extended storage. In turn
this creates an excess of lotion on the freshly produced paper
tissues thus triggering a negative greasy feeling during use (and
reducing further more the absorbency of the paper tissue). Third,
lotions that are coating the fibers are less susceptible to be
released by the tissue during use and thus less transferable to the
skin of the user. Further yet, there is an economic advantage at
utilizing a reduced amount of lotion of the tissues, due to the
relatively high cost of the lotion raw materials.
[0009] Accordingly, there is a need to provide a paper tissue
exhibiting, a relatively high amount of lotion available at the
surface of the tissue in the form of discrete deposits protruding a
significant height from the surface of the tissue.
[0010] Further, there is a need for improved smoothening benefits
of the tissue, improved absorbency of paper tissues, and improved
transferability of the lotion to the users skin, without having one
improvement being detrimental to the other.
SUMMARY OF THE INVENTION
[0011] In order to solve the issues related to the prior art, the
present invention provides a paper tissue having first and second
opposed surfaces wherein the tissue includes a lotion on at least
one surface of the paper tissue. The lotion is present in
substantially discrete protruding deposits on the first surface,
wherein the paper tissue has a bulk of equal or less than 5.2
cm.sup.3/g of tissue wherein the protruding deposits have an
average height of at least 30 .mu.m.
BRIEF DESCRIPTION OF THE DRAWINGS
[0012] FIG. 1 is a representation of the elevations at the surface
of the tissue of example 1. The tissue is treated with 2.1 g/sqm of
lotion.
[0013] FIG. 2 is a representation of the tissue surface of tissue
example 1, treated with the formulation of example 1 at 2.1 g/sqm,
showing the height of the protruding deposits in grey values. White
areas are protruding.
DETAILED DESCRIPTION OF THE INVENTION
[0014] The present invention provides a paper tissue exhibiting a
high level of surface smoothness and softness, high absorbency, a
high strength and a high bulkiness. These apparently competing
characteristics have been combined by following the concept of the
present invention.
[0015] A "lotion" a composition added to the tissue preferably at
the converting phase in order to improved its softness/smoothness
and have smoothening effect on the skin. Some of the lotion can
transfer from the tissue to the user's skin upon use of the paper
tissue article. It thus induces a longer term smoothening effect on
the skin. Lotion can be called alternatively smoothening or
softening lotion or composition.
[0016] The lotion may comprise softening/debonding agents,
emollients, immobilizing agents and mixtures thereof. Suitable
softening/debonding agents include quaternary ammonium compounds,
polysiloxanes, and mixtures thereof. Suitable emollients include
propylene glycol, glycerine, triethylene glycol, spermaceti or
other waxes, petrolatum fatty acids, fatty alcohols and fatty
alcohol ethers having from 12 to 28 carbon atoms in their fatty
acid chain, mineral oil, namely silicone oil e.g. dimethicone and
isopropyl palmitrat, and mixtures thereof. Suitable immobilizing
agents include waxes, fatty alcohols, fatty acids, e.g. ceresin
wax, microcrystalline wax, petroleum waxes, fisher tropsh waxes,
paraffin waxes, stearyl alcohol and paraffins, polyhydroxy fatty
acid esters, polyhydroxy fatty acid amides, and mixtures thereof.
In most cases the lotions contain at least one immobilizing agent
and an emollient. Lotions can be emulsions or dispersions. Other
optional components include perfumes, antibacterial actives,
antiviral actives, disinfectants, pharmaceutical actives, film
formers, deodorants, opacifiers, astringents, solvents and the
like. Particular examples of lotion components include camphor,
thymol, menthol, chamomile extracts, aloe vera, calendula
officinalis.
[0017] "Protruding deposit" means a protruding deposit is defined
as a deposition of lotion on the paper tissue that protrudes (in
some embodiments, at least 25 micrometers) above the average plane
of the tissue surface.
[0018] "Average height of protruding deposits" means average of the
height of each data point (provided by the method described
thereafter) that are at least 25 micrometers above the average
plane of the tissue surface.
[0019] The terms "paper tissue", "paper tissue web", "tissue web",
"tissue", "paper" and "web" are used interchangeably in this
document. The present invention is useful with tissue paper in
general, including but not limited to conventionally felt-pressed
tissue paper; high bulk pattern densified tissue paper; and high
bulk, uncompacted tissue paper and through-air dried paper. The
tissue paper can be of a homogenous or multi-layered construction;
and tissue paper products made therefrom can be of a single-ply or
multi-ply construction. The tissue paper preferably has a basis
weight of between about 10 g/m.sup.2 and about 65 g/m.sup.2, and
bulk of about 5.2 cm3/g or less (preferably equal or less than 5.0
cm3/g). More preferably, the basis weight will be about 40
g/m.sup.2 or less. Conventionally pressed tissue paper and methods
for making such paper are well known in the art. Such paper is
typically made by depositing a papermaking furnish on a foraminous
forming wire, often referred to in the art as a Fourdrinier wire.
Once the furnish is deposited on the forming wire, it is referred
to as a web. The web is dewatered by pressing the web and drying at
elevated temperature. The dewatered web is then further pressed and
dried by a steam drum apparatus known in the art as a Yankee dryer.
Applicable wood pulps include chemical pulps, such as Kraft,
sulfite, and sulfate pulps, as well as mechanical pulps including,
for example, groundwood, thermomechanical pulp and chemically
modified thermomechanical pulp. In addition to papermaking fibers,
the papermaking furmish used to make tissue paper structures can
have other components or materials added thereto as can be or later
become known in the art. The types of additives desirable will be
dependent upon the particular end use of the tissue sheet
contemplated. For example, in products such as toilet paper, paper
towels, facial tissues and other similar products, high wet
strength is a desirable attribute. Thus, it is often desirable to
add to the papermaking furnish chemical substances known in the art
as "wet strength" resins. A general dissertation on the types of
wet strength resins utilized in the paper art can be found in TAPPI
monograph series No. 29, Wet Strength in Paper and Paperboard,
Technical Association of the Pulp and Paper Industry (New York,
1965). Paper tissue of the present invention can have a moisture
content of between 0 and 20% (w/w) but it has been found that best
results are obtained with a moisture level of at least 4%
(w/w).
[0020] The paper tissue of the present invention can be formed from
a unique layer of material or can be a multi-layered tissue paper
web. The terms "multi-layered tissue paper web, multi-layered paper
web, multi-layered web, multi-layered paper sheet and multi-layered
paper product" are all used interchangeably in the art to refer to
sheets of paper prepared from two or more layers of aqueous paper
making furnishes which are preferable comprised of different fiber
types, the fibers typically being relatively long softwood and
relatively short hardwood fibers as used in tissue paper making.
The layers are preferable formed from the deposition of separate
streams of dilute fiber slurries upon one or more endless
foraminous surfaces. If the layers are initially formed on separate
foraminous surfaces, the layers can subsequently combined when wet
to form a multi-layered tissue paper web.
[0021] The "paper tissue products" of this invention are the
finished products such a kitchen towels or paper handkerchiefs,
made out of one or multiple plies of the above described paper
tissues. Each ply of a multiply paper product can be made of
diverse material or been manufactured in diverse ways at the paper
making or converting steps. As used herein, the term "single-ply
tissue product" means that it is comprised of one ply of tissue;
the ply can be substantially homogeneous in nature or it can be a
multi-layered tissue paper web. As used herein, the term "multi-ply
tissue product" means that it is comprised of more than on ply of
tissue. The plies of a multi-ply tissue product can be
substantially homogeneous in nature of they can be multi-layered
tissue paper webs. "Lotion basis weight of the protruding deposits"
is the concentration of lotion, expressed in grams per square
meter, within the protruding deposits of lotion on the tissue. This
is an average value of the deposits measured. The lotion basis
weight of the protruding deposits is determined as described in the
method below.
[0022] "Density of the protruding deposits" is the average number
of protruding lotion deposits per area of tissue, expressed in
sqcm.sup.-1.
[0023] "Lotion basis weight of the tissue" is the overall
concentration of lotion, expressed in grams per square meter, of
lotion on the tissue (also referred as total or overall basis
weight or concentration). The basis weight can be measured by any
standard method, e.g. solvent extraction, or deducted from the
process conditions (amount of lotion deposited on the tissue
divided by the total area of the tissue).
[0024] It is desirable to provide a smooth tissue that comprises a
lotion able to be transferred easily into the skin of the tissue
user. According to the present invention, the careful selection the
distribution of the lotion on the tissue, as multitude of discrete
deposits, can enhance the transferability of the lotion from the
tissue onto the skin of the user. It is believed that protruding
deposing having a significant height above the average plan of the
tissue surface will have a higher transferability to the skin of
the user and thus will contribute best to the general smoothness of
the tissue. It has been found that deposits protruding at least 25
.mu.m above the average plan of the tissue surface are most
beneficial. Preferably the deposits protrude at least 30 .mu.m, 35
.mu.m or at least 50 .mu.m. The beneficial effects have been best
observed when the protruding deposits are applied on the tissue
paper of limited bulk (i.e. less than 5.2 cm.sup.3/g, or 5.0
cm.sup.3/g).
[0025] Also the total basis weight of lotion on the tissue is equal
or less than 9 g/sqm, less than 6 g/sqm, less than 4.5 g/sqm, 3.0
g/sqm and most preferably less than 2 g/sqm.
[0026] In some embodiments, a ratio R is considered: 1 R = Lotion
basis weight of the protruding deposits ( g / sqm ) lotion basis
weight of the tissue ( g / sqm )
[0027] The beneficial effects are observed when R is greater than
0.005. R can also be 0.01, 0.02, 0.05, 0.1, 0.2, or 0.3 in
preferred embodiments.
[0028] It has been observed that the beneficial effects are obtain
in some embodiments when the density of protruding deposits is at
least 1, 3, 5 or 10 per sqcm of tissue.
[0029] In some embodiments, the lotion can be visualized by osmium
tetroxide staining, described herein. In other embodiments, the
lotion can be visualized by Infrared spectroscopy (IR
spectroscopy), which method is referenced herein.
[0030] In such embodiments, the total basis weight of lotion on the
tissue is generally at least 0.3 g/sqm, 0.6 g/sqm, 1.0 g/sqm, 1.5
g/sqm or 2.5 g/sqm In some embodiments, it has been found that
relatively large area of the tissue covered by deposits of
relatively large height (or elevation) is are preferred. This
delivers a product with a higher lotion transferability. This can
be expressed by the ratio R.sub.2, wherein 2 R 2 = Area of the
protruding deposits measured at the threshold value of claim 1 ( mm
^ 2 ) Area of the tissue ( mm ^ 2 ) * Lotion weight of the tissue (
g / sqm )
[0031] R.sub.2 is at least 0.005, 0.001, at least 0.05 or at least
0.08.
[0032] In some embodiments, the invention is related to a multiply
tissue product. When the multiply tissue product comprises 2 plies,
it has been found that the invention works well when at least one
of the external surfaces (outwardly orientated surfaces) has more
lotion than its corresponding internal surface (inwardly orientated
surfaces). This can be determined by scanning electron microscopy.
When the multiply tissue product has at least 3 plies, it has been
found that the lotion transferability is suitable when at least
60%, at least 70% at least 80% or at least 90% of the lotion is
located one of the outer plies. Indeed, the lotion present on the
inner ply(ies) contributes much less in the transfer of the lotion
to the users skin.
Lotion
[0033] The present invention as described here particularly focuses
on smoothening lotion. It should be noted that any type of
additives or compound could be applied by the described process, as
long as the physical characteristics (e.g. melting point,
viscosity), and the application temperature are adjusted to obtain
the desired distribution pattern of the applied additives or
compounds at the surface of the paper tissue. These additives or
compounds could include: hydration lotion, soap, moisturizers,
sun-protection, make-up removal ingredients, anti-aging,
disinfectants, or more generally additives/compounds in the
cosmetic and therapeutic fields, detergents, soaps, waxes, cleaning
additives and more generally compounds for the cleaning,
maintenance, protection and treatment of objects, surfaces or
mechanical parts.
[0034] Lotions are in most instances of heterogeneous composition.
They may contain solids, crystalline gel structures, polymeric
material below glass point, a multiplicity of phases (such as oily
and water phase) and/or emulsified components. It may be difficult
to determine precisely the melting temperature of the lotion, i.e.
difficult to determine the, temperature of transition between the
liquid form, the quasi-liquid from, the quasi-solid form and the
solid form. The terms melting temperature, melting point,
transition point and transition temperature are used
interchangeably in this document and have the same meaning.
[0035] For the purpose of this invention it is considered that not
only the melting temperature relates to the definition of the form
or state of the lotion (liquid, solid, quasi-liquid, quasi-solid),
but also its Theological properties. For the purpose of this
invention, it is defined that liquid or quasi-liquid lotion are
able to flow, move, and migrate, for example under the force
encountered during the process of application. Solid or quasi-solid
lotions are not able to flow freely and are somewhat immobilized at
their location. For example a lotion will be said liquid or
quasi-liquid if it can be fed onto the rotating surfaces and
expulsed there from under the used process conditions. A lotion
will be said solid or semi-solid if it does not significantly
freely migrates from the surface into the inner structure of the
tissue at room temperature, i.e. 23.degree. C. until the product is
usually used.
[0036] The lotion may comprise a surface treating agent.
Nonlimiting examples of suitable surface treating agents that may
be included in the lotion can be selected from the group consisting
of: polymers such as polyethylene and derivatives thereof,
hydrocarbons, waxes, oils, silicones (polysiloxanes), quaternary
ammonium compounds, fluorocarbons, substituted C.sub.10-C.sub.22
alkanes, substituted C.sub.10-C.sub.22 alkenes, in particular
derivatives of fatty alcohols and fatty acids(such as fatty acid
amides, fatty acid condensates and fatty alcohol condensates),
polyols, derivatives of polyols (such as esters and ethers), sugar
derivatives (such as ethers and esters), polyglycols (such as
polyethyleneglycol) and mixtures thereof.
[0037] The lotion may comprise oils and/or emollients and/or waxes
(any and all of which may be a transferable agent) and/or
immobilizing agents. In one example, the lotion comprises from
about 10% to about 90% of an oil and/or liquid emollient and from
about 10% to about 50% of immobilizing agent and/or from about 0%
to about 60% of petrolatum and optionally the balance of a
vehicle.
[0038] The lotion may be heterogeneous. They may contain solids,
gel structures, polymeric material, a multiplicity of phases (such
as oily and water phase) and/or emulsified components. It may be
difficult to determine precisely the melting temperature of the
lotion, i.e. difficult to determine the temperature of transition
between the liquid form, the quasi-liquid from, the quasi-solid
form and the solid form. The terms melting temperature, melting
point, transition point and transition temperature are used
interchangeably in this document and have the same meaning.
[0039] The lotion may be semi-solid, of high viscosity so they do
not substantially flow without activation during the life of the
product or gel structures.
[0040] The lotion may be shear thinning and/or they may strongly
change their viscosity around skin temperature to allow for
transfer and easy spreading on a user's skin.
[0041] The lotion may be in the form of emulsions and/or
dispersions.
[0042] In one example of a lotion, the lotion has a water content
of less than about 20% and/or less than 10% and/or less than about
5% or less than about 0.5%.
[0043] In another example, the lotion may have a solids content of
at least about 15% and/or at least about 25% and/or at least about
30% and/or at least about 40% to about 100% and/or to about 95%
and/or to about 90% and/or to about 80%.
[0044] Nonlimiting examples of suitable oils and/or emollients
include glycols (such as propylene glycol and/or glycerine),
polyglycols (such as triethylene glycol), petrolatum, fatty acids,
fatty alcohols, fatty alcohol ethoxylates, fatty alcohol esters and
fatty alcohol ethers, fatty acid ethoxylates, fatty acid amides and
fatty acid esters, hydrocarbon oils (such as mineral oil),
squalane, fluorinated emollients, silicone oil (such as
dimethicone) and mixtures thereof.
[0045] Immobilizing agents include agents that are may prevent
migration of the emollient into the paper tissue such that the
emollient remain primarily on the surface of the paper tissue
and/or sanitary tissue product and/or on the surface treating
composition on a surface of the paper tissue and/or sanitary tissue
product and facilitate transfer of the lotion to a user's skin.
Immobilizing agents may function as viscosity increasing agents
and/or gelling agents.
[0046] Nonlimiting examples of suitable immobilizing agents include
waxes (such as ceresin wax, ozokerite, microcrystalline wax,
petroleum waxes, fisher tropsh waxes, silicone waxes, paraffin
waxes), fatty alcohols (such as cetyl and/or stearyl alcohol),
fatty acids and their salts (such as metal salts of stearic acid),
mono and polyhydroxy fatty acid esters, mono and polyhydroxy fatty
acid amides, silica and silica derivatives, gelling agents,
thickeners and mixtures thereof.
[0047] In one example, the lotion comprises at least one
immobilizing agent and at least one emollient.
[0048] In one example, the lotion comprises a sucrose ester of a
fatty acid.
[0049] The lotion may be comprise a transferable agent and thus be
considered a transferable lotion. A transferable lotion comprises
at least one transferable agent that is capable of being
transferred to an opposing surface such as a user's skin upon use.
In one example, at least 0.1% of the transferable lotion present on
the user contacting surface transfers to the user's skin during
use. The amount of transferable composition that transfers to a
user's skin during use can be determined by known methods such as
by tape stripping the skin 3 times, after use of the paper tissue
and/or sanitary tissue product by the user, with Tegaderm Tapes,
available from 3M, and analyzing the tapes for the transferable
composition or a component within the transferable composition
assuming all components of the transferable composition transfer
equally.
[0050] Other optional components that may be included in the lotion
include vehicles, perfumes, especially long lasting and/or enduring
perfumes, antibacterial actives, antiviral actives, disinfectants,
pharmaceutical actives, film formers, deodorants, opacifiers,
astringents, solvents, cooling sensate agents, and the like.
Particular examples of lotion components include camphor, thymol,
menthol, chamomile extracts, aloe vera, calendula officinalis,
alpha bisalbolol, Vitamin E, Vitamin E acetate.
[0051] In one example, the lotion is present on the surface of the
paper tissue and/or sanitary tissue product and/or on the surface
treating composition present on the surface of the paper tissue
and/or sanitary tissue product at a level of at least about 0.5
g/m.sup.2 and/or at least about 1.0 g/m.sup.2 and/or at least about
1.5 g/m.sup.2 per user contacting surface. In another example, the
lotion is present on the surface of the paper tissue and/or
sanitary tissue product and/or on the surface treating composition
present on the surface of the paper tissue and/or sanitary tissue
product at a level of from about 0.5 g/m.sup.2 and/or from about
1.0 g/m.sup.2 and/or from about 1.5 g/m.sup.2 to about 10 g/m.sup.2
and/or to about 8 g/m.sup.2 and/or to about 6 g/m.sup.2 per user
contacting surface.
[0052] As used herein a "vehicle" is a material that can be used to
dilute and/or emulsify agents forming the surface treating
composition and/or lotion to form a dispersion/emulsion. A vehicle
may be present in the surface treating composition and/or lotion,
especially during application of the surface treating composition
and/or to the paper tissue. A vehicle may dissolve a component
(true solution or micellar solution) or a component may be
dispersed throughout the vehicle (dispersion or emulsion). The
vehicle of a suspension or emulsion is typically the continuous
phase thereof. That is, other components of the dispersion or
emulsion are dispersed on a molecular level or as discrete
particles throughout the vehicle.
[0053] Suitable materials for use as the vehicle of the present
invention include hydroxyl functional liquids, including but not
limited to water. In one example, the lotion comprises less than
about 20% and/or less than about 10% and/or less than about 5%
and/or less than about 0.5% w/w of a vehicle, such as water. In one
example, the surface treating composition comprises greater than
about 50% and/or greater than about 70% and/or greater than about
85% and/or greater than about 95% and/or greater than about 98% w/w
of a vehicle, such as water.
[0054] It has been found that a suitable lotion of the present
invention has a water content of less than 20%, less than 10%, less
than 5% or less than 0.5%.
EXAMPLE 1 of Lotion Formulation
[0055] It has been found that the present invention is of
particular efficacy when the lotion has the following composition
(in weight/weight percent):
1 Stearyl Alcohol CO1897* 30% SEFOSE 1618S** 50% Mineral oil
(Carnation)*** 20% *Available from Procter&Gamble Chemicals,
Cincinnati, USA **Sucrose esters of fatty alcohols, available from
Procter&Gamble Chemicals, Cincinnati, USA ***Available from
Crompton Corporation
EXAMPLE 2 of Lotion Formulation
[0056] It has been found that the present invention is of
particular efficacy when the lotion has the following composition
(in weight/weight percent):
2 Stearyl Alcohol CO1897* 40% Petrolatum (Snowwhite V28EP)** 30%
Mineral oil (Carnation)** 30% *Available from Procter&Gamble
Chemicals, Cincinnati, USA **Available from Crompton
Corporation
EXAMPLE 3 of Lotion Formulation
[0057] It has been found that the present invention is of
particular efficacy when the lotion has the following composition
(in weight/weight percent):
3 Stearyl Alcohol CO1897* 20% SEFOSE 1618S** 80% *Available from
Procter&Gamble Chemicals, Cincinnati, USA **Sucrose esters of
fatty alcohols, available from Procter&Gamble Chemicals,
Cincinnati, USA
[0058] All three formulations have been applied to the tissue
described in paper tissue example 1 at add on levels between 1.5
g/sqm and 6 g/sqm on each side.
[0059] Process conditions and equipment are described in US patent
application titled "Paper tissue with high lotion transferability"
by J. Kleinwaeschter, D. Butz, C. Marcott and G. Di Girolamo.
Data
[0060]
4 Formulation 1 Formulation 2 Formulation 3 Lotion basis weight 2.1
g/sqm 3 g/sqm 2.1 g/sqm of the tissue Density of deposits 10 2.7
3.7 (sqcm) Ratio R 0.27 0.04 0.06 Mean deposit volume 6.8 4.6 6.4
(mm.sup.3/1000) Ratio R.sub.2 (smq/g) 0.0084 0.0013 0.0022
Paper Tissue Example 1
[0061] The tissue paper used in the following examples is a
conventional wet pressed, homogeneous, dry creped tissue paper with
a basis weight of about 15.4 g/sqm. The paper web has a composition
of about 40% Northern Softwood Kraft and 60% Eucalyptus. Following
the papermaking, four sheets of paper are combined together in an
off line combining operation. The pre-combined 4-ply parent roll is
subsequently converted into a 4-ply tissue product. The 4-ply
parent roll is unwound and subjected to calandering between two
smooth steel calender rolls followed by high pressure embossing to
achieve ply bonding. The majority of the tissue paper remains
unaffected by the high pressure embossing. Finally the tissue was
cut in machine direction, followed by cutting in cross direction
into sheets of approximately 21 cm.times.21 cm, folded, stacked
into stacks of 9 sheets and packed into individual pocket packs.
The 4-ply paper tissue product obtained by the above described
process had a basis weight of approximately 60 g/sqm (not including
any lotion applied), a thickness of 0.27 mm, a bulk of 4.5 cm3/g, a
machine direction strength of 1280 g/in, a cross direction strength
of 610 g/in, and a wet burst of about 200 g. It contained a wet
strength agent and a dry strength agent.
Paper Tissue Example 2
[0062] The tissue paper used in the following examples is a
conventional wet pressed, layered, dry creped tissue paper with a
basis weight of about 14.6 g/sqm. The outer layer contains about
100% Eucalyptus fiber whereas the inner layer is composed of a
furnish mix of about 85% Northern Softwood Kraft, 10% CTMP and
about 5% Eucalyptus fiber. Both layers are of about equal basis
weight (symmetrical layer split). Following the papermaking, four
sheets of paper are combined together in an off line combining
operation. The pre-combined 4-ply parent roll is subsequently
converted into a 4-ply tissue product. The 4-ply parent roll is
unwound and subjected to calendering between two smooth steel
calender rolls followed by high pressure embossing to achieve ply
bonding. The majority of the tissue paper remains unaffected by the
high pressure embossing. Finally the tissue was cut in machine
direction, followed by cutting in cross direction into sheets of
approximately 21 cm.times.21 cm, folded, stacked into stacks of 9
sheets and packed into individual pocket packs. The 4-ply paper
tissue product obtained by the above described process has a basis
weight of approximately 60 g/sqm (not including any lotion
applied), a thickness of 0.27 mm, a bulk of 4.5 cm3/g, a machine
direction strength of 1180 g/in, a cross direction strength of 560
g/in, and a wet burst of about 200 g. It contains a wet strength
agent and a dry strength agent.
Methods
[0063] Bulk of the tissue paper: The bulk of the tissue is defined
as the reciprocal value of the density (in g/cm3). See column 13,
lines 61-67 of U.S. Pat. No. 5,059,282 (Ampulski et al), issued
Oct. 22, 1991 which describes how the density of tissue paper is
measured. The paper is equilibrated at 23 degrees Celsius and 50%
(=/-2%) relative humidity for at least 2 hours prior to
measurement.
[0064] Average lotion add-on level by solvent extraction (basis
weight of lotion on the tissue): A representative sample of about
2g of the lotion treated tissue is extracted by Accellerated
Solvent Extraction (ASE) using a model ASE 200, available from
Dionex Corp., USA. The following conditions are used: 11 ml
extraction cell, solvent mixture: 50 % Acetone/n-Hexane;
temperature: 100.degree. C. (heat and static 5 minutes); pressure:
1000 PSI; two cycles with 100% flush. The solvent is evaporated and
the residue is determined gravimetrically. The lotion add on is
then calculated as
Average lotion=Weight of the extract in [r].times.Basis weight of
the sample in [g/sqm] add on in g/sqm Weight of the sample before
extraction in [g]
[0065] Osmium Staining: A square sample of tissue of about 4
cm.times.4 cm is cut from a flat, unembossed and unfolded area of
the tissue product to be analyzed ( a smaller area can be used if
needed). All tissue samples are placed in open containers
equidistant from an open container of 10 ml of a 4% OSO.sub.4
solution (in water) under a glass staining dome in a hood. The
vapor staining is done typically for 24 hours. The duration of
staining is not very critical and can be longer or shorter
depending on the affinity of the lotion for osmium and the desired
level of "blackness". Staining is stopped when the best possible
contrast in the sample between lotion spots and substrate is
reached. Because paper fibers will slowly pick up the osmium stain
and darken, there is point in the staining process where the lotion
will no longer react but the paper fibers will continue to do so,
reducing the contrast between lotion and fibers.
[0066] Sample Preparation for Surface Analysis: The sample tissue
is placed on a 2 inch.times.3 inch (about 5 cm.times.7.6 cm) glass
slide with the surface that is to be analyzed, facing up. The edges
of the ply were carefully taped to the slide to produce a flat
sheet.
[0067] Surface Analysis: The mounted samples described above were
analyzed by a GFM Primos optical 3D measuring system (Teltow,
Germany) which is based on the digital stripe projection technique.
The system has a field of view of 2.7.times.2.1 cm and a detector
containing 1300.times.1000 pixels. The operating software was
Primos version 4.074. If possible the full field view should be
used, only if the sample does not contain a large enough flat,
unfolded and unembossed area should a smaller field of view is to
be used for analysis. The system produces a grayscale camera image
(GS image) for each sample analyzed as well as a 3D surface height
image (3D image) calibrated in microns. The GS image was exported
from the Primos software as a BMP image for further processing. The
3D image was processed using the Primos software Align function
which removes tilt and exported as a Fringe File Version 1 format
(FD3).
[0068] Surface Data Image Analysis: Both the GS image (BMP) and the
3D image (FD3) were imported into MatLab (MathWorks, Natick, Mass.,
USA) for all further image processing. Functions from the MatLab
Image Processing Toolbox v4.2 add-on were used in the processing of
the data. The 3D image was smoothed with an averaging convolution
filter of kernel size 151 and the resulting image subtracted from
the original 3D image. This corrected the image for any wrinkles or
curvature in the sample arising from the mounting procedure. The
resulting image was then smoothed slightly with a median filter of
kernel size 5 to remove any high frequency noise from the
measurement. These operations produced an image with the mean plane
of the surface at zero height (m3D). The image was then thresholded
to eliminate any data that fell below 25 microns above the mean
plane (mt3D).
[0069] Correlation of the data with lotioned areas:
[0070] (a) Osmium Staining
[0071] The GS image of the osmium stained sample was smoothed with
an averaging convolution filter of kernel size 151 and the
resulting image subtracted from the original GS image. This
corrected the image for uneven illumination characteristic of the
Primos system. The resulting image was then smoothed slightly with
a median filter of kernel size 5 to remove any high frequency noise
from the measurement. This image was then scaled from (min, max) to
(0,1) and a thresholding operation applied so that values below
0.30 were set to a binary 1 and values above or equal to 0.30 were
set to zero. This binary mask (BM) shows 1's where there is darkly
stained lotion and zeros everywhere else.
[0072] (b) Scanning Infrared Spectroscopy
[0073] If the staining method is not appropriate to identify
lotioned areas, other methods to identify lotioned areas can be
used, preferably infrared scanning spectroscopy. This may be
appropriate in case staining does not allow to separate the areas
with a high amount of lotion (these are the areas that may protrude
from the surface) from the rest of the surface area, e.g. if the
lotion material does not stain or does not stain enough for
differentiating it from the background, or, e.g. if the substrate
itself stains. An appropriate method to identify lotioned areas by
IR scanning spectroscopy is described in described in US patent
application titled "Paper tissue with high lotion transferability"
by J. Kleinwaeschter, D. Butz, C. Marcott and G. Di Girolamo. In
this method it is described how to measure the local lotion basis
weight in an area of 25 .mu.m.times.25 .mu.m of a sample with an
area of 0.5 cm.times.0.5 cm or larger.
[0074] Preferably a sample of at least 1 cm.times.1 cm is used. The
file containing the local lotion basis weight can be exported as a
8 bit greyscale bitmap file and transformed into the desired binary
mask BM, using an image analysis program, e.g. AnalySIS (available
from Soft Imaging GmbH, Germany) as described in the US patent
application cited above, by setting all pixels with a local lotion
basis weight of 10 g/sqm to "1" in the binary mask BM and all other
points to "0". Appropriate fudicial marks within the image can be
used to register the binary mask with the 3D height image.
[0075] To eliminate any data points that were not identified as
lotion (dark area) in the binary mask (BM), the resulting 3D image
in the paragraph above (mt3D) was multiplied pixel by pixel with
the binary mask (BM). Areas of the resulting image not indicated as
lotion in BM became zero. Area regions less than 0.10 mm2 (225
pixels) were removed from the final image. A border of one half the
largest kernel size used (151/2=75) was removed from all sides of
the image to eliminate invalid data resulting from the convolution
operations, producing the final composite image (FC).
[0076] Data points in FC that were not zero, were projected onto
the mean plane (in image FC the mean plane is at zero) and the area
calculated by summing the calibrated pixels. The volume above the
mean plane was also determined by summing the projected area pixels
times each pixels actual height above the mean plane. The separate
area and volume regions were recorded for each sample and the
total, mean, and standard deviation for the areas and volumes
calculated. The measurement field of view was used to further
calculate the lotion coverage area fraction and lotion volume per
area of sample.
[0077] The lotion basis weight of the protruding deposits (in
g/sqm) is obtained from the mean volume of the deposits per area
multiplied by the density of the lotion.
[0078] The ratio R is then calculated by dividing the lotion basis
weight of the deposits (in g/sqm) by the lotion basis weight of the
tissue (in g/sqm).
[0079] All documents cited herein are, in their relevant part,
incorporated herein by reference; the citation of any document is
not to be construed as an admission that it takes away
patentability of the present invention.
[0080] While particular embodiments of the present invention have
been illustrated and described, it would be obvious to those
skilled in the art that various other changes and modifications can
be made without departing from the spirit and scope of the
invention. It is therefore intended to cover in the appended claims
all such changes and modifications that are within the scope of
this invention.
* * * * *