U.S. patent application number 11/095575 was filed with the patent office on 2005-10-13 for iridescent cosmetic composition and use thereof.
This patent application is currently assigned to L'OREAL. Invention is credited to Arnaud-Sebillotte, Laurence, Guillou, Veronique.
Application Number | 20050226831 11/095575 |
Document ID | / |
Family ID | 8858981 |
Filed Date | 2005-10-13 |
United States Patent
Application |
20050226831 |
Kind Code |
A1 |
Arnaud-Sebillotte, Laurence ;
et al. |
October 13, 2005 |
Iridescent cosmetic composition and use thereof
Abstract
The subject of the present invention is an iridescent
composition for topical application, comprising at least one
water-soluble surfactant and an aqueous dispersion of particles of
polymer, the said particles having a mean size in numerical terms
ranging from about 50 to 300 nm, the quantity of particles of
polymer being at least 3% by weight of active material relative to
the total weight of the composition. The composition according to
the invention has a very attractive visual appearance by virtue of
its iridescent colour. The invention also relates to the uses of
the composition of the invention in the cosmetic field, in
particular for the treatment, protection, care, removal of make-up
from and/or cleansing of the skin, the lips and/or the hair, and/or
for the application of make-up to the skin and/or the lips.
Inventors: |
Arnaud-Sebillotte, Laurence;
(L'Hay-les-Roses, FR) ; Guillou, Veronique;
(Antony, FR) |
Correspondence
Address: |
OBLON, SPIVAK, MCCLELLAND, MAIER & NEUSTADT, P.C.
1940 DUKE STREET
ALEXANDRIA
VA
22314
US
|
Assignee: |
L'OREAL
Paris
FR
|
Family ID: |
8858981 |
Appl. No.: |
11/095575 |
Filed: |
April 1, 2005 |
Related U.S. Patent Documents
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
|
|
11095575 |
Apr 1, 2005 |
|
|
|
10182704 |
Aug 7, 2002 |
|
|
|
10182704 |
Aug 7, 2002 |
|
|
|
PCT/FR02/00128 |
Jan 14, 2002 |
|
|
|
Current U.S.
Class: |
424/63 |
Current CPC
Class: |
A61Q 5/02 20130101; A61K
2800/413 20130101; A61K 8/8152 20130101; A61Q 1/14 20130101; A61Q
19/001 20130101; B82Y 5/00 20130101; A61K 8/8147 20130101; A61K
8/06 20130101; A61K 8/60 20130101; A61K 8/375 20130101; A61K 8/8117
20130101; A61K 8/39 20130101; A61K 8/44 20130101; A61K 8/463
20130101; A61Q 1/04 20130101; A61Q 19/00 20130101; A61Q 17/04
20130101; A61Q 1/02 20130101; A61K 8/8123 20130101; A61K 8/87
20130101; A61Q 19/10 20130101; A61Q 5/00 20130101; A61K 2800/436
20130101 |
Class at
Publication: |
424/063 |
International
Class: |
A61K 007/021; A61K
009/48 |
Foreign Application Data
Date |
Code |
Application Number |
Jan 18, 2001 |
FR |
01/00682 |
Claims
1. An iridescent composition for topical application comprising at
least one water-soluble surfactant and monodisperse particles of
polymer in aqueous dispersion, said particles having a mean size of
from 50 to 300 nm and the quantity of said particles is at least 3%
by weight relative to the total weight of the composition wherein
said surfactant has an HLB equal to or greater than 11, wherein the
polymer particles comprise at least one anionic polymer and wherein
the quantity of surfactant is from 0.5 to 50% by weight relative to
the total weight of the composition.
2. The composition according to claim 1, wherein the dispersion
and/or the composition exhibits a colorimetric difference ranging
from 2 to 100.
3. The composition according to claim 1, wherein the turbidity is
greater than 100.
4. The composition according to claim 1, wherein the viscosity is
from 0.01 Pas to 10 Pas.
5. The composition according to claim 1, wherein the surfactant is
chosen from the group consisting of nonionic surfactants, anionic
surfactants, zwitterionic surfactants, amphoteric surfactants, and
mixtures thereof.
6. The composition according to claim 1, wherein the surfactant is
chosen from the group consisting of optionally oxyalkylenated
esters of polyols and of fatty acids, optionally oxyalkylenated
esters of polyethylene glycols and of fatty acids, optionally
oxyalkylenated derivatives of fatty alcohol and of polyols,
carboxylates, acyl sarcosinates, optionally oxyethylenated alkyl
sulphates, optionally oxyethylenated alkyl ether sulphates,
sulphonates, taurates, N-acyl-N-methyltaurates, N-acylglutamates,
isethionates, N-acylisethionates, N-acylglycinates,
sulphosuccinates, alkyl sulphoacetates, phosphates, alkyl
phosphates, anionic derivatives of alkyl polyglycoside,
polypeptides, soaps, betaines, N-alkylamidobetaines, derivatives of
N-alkylamidobetaines, glycine derivatives, sultaines, alkyl
polyaminocarboxylates, alkyl amphoacetates, and mixtures
thereof.
7. The composition according to claim 1, wherein the polymer
particles comprise a polymer obtained from one or more monomers
chosen from the group consisting of styrene, butadiene, ethylene,
acrylonitrile, chloroprene, vinylidene chloride, isoprene,
isobutylene, vinyl chloride, acrylic acid, methacrylic acid,
vinylacetic acid, maleic acid, crotonic ac itaconic acid, esters of
acrylic acid, esters of methacrylic acid, esters of vinylacetic
acid, esters of maleic acid, esters of crotonic acid, esters of
itaconic acid, and mixtures thereof.
8. (canceled)
9. The composition according to claim 8, wherein the polymer
particles comprise homopolymers of acrylic acid, copolymers of
acrylic acid, styrene derivatives, fluorinated derivatives,
silicone-based derivatives, or diisocyanate derivatives.
10. The composition according to claim 1, wherein the polymer
particles are chosen from the group consisting of particles of
acrylic acid/ethyl acrylate copolymer, particles of styrene/butyl
acrylate/methyl methacrylate/methacrylic acid hybrid copolymer, and
mixtures thereof.
11. The composition according to claim 1, wherein the quantity of
polymer particles is from 3 to 50% relative to the total weight of
the composition.
12. (canceled)
13. The composition according to claim 1, wherein further
comprising at least one active agent.
14. The composition according to claim 1, wherein further
comprising 30 to 96.5% by weight of water relative to the total
weight of the composition.
15. The composition according to claim 1, wherein further
comprising one or more solvents chosen from the group consisting of
alcohols comprising 1 to 8 carbon atoms, polyols, sugars and
mixtures thereof.
16. A cosmetic composition suitable for topical application
comprising the composition of claim 1.
17. (canceled)
18. A method for the cosmetic treatment of the skin, the scalp, the
hair and/or the lips, comprising applying the cosmetic composition
according to claim 16 to the skin the scalp, the hair and/or the
lips.
19. The composition according to claim 11, wherein the quantity of
polymer particles is from 3.5 to 40% by weight relative to the
total weight of the composition.
20. The composition according to claim 1, wherein the quantity of
surfactant is from 2 to 40% by weight relative to the total weight
of the composition.
Description
REFERENCE TO PRIOR APPLICATIONS
[0001] This application claims priority to U.S. application Ser.
No. 10/182,704 filed Aug. 7, 2002, and to French patent application
01/00682 filed Jan. 18, 2001.
FIELD OF THE INVENTION
[0002] The subject of the invention is an iridescent composition
for topical application, comprising at least one water-soluble
surfactant and an aqueous dispersion of particles of polymer, the
said particles having a mean size in numerical terms ranging from
about 50 to 300 nm, and the uses of the said composition, in
particular for the treatment, protection, care, removal of make-up
from and/or cleansing of the skin, the lips and/or the hair, and/or
as make-up for the skin and/or the lips.
BACKGROUND OF THE INVENTION
[0003] Care and/or cleansing compositions for the skin are
generally in the form of transparent or white products depending on
their constituent, ingredients. To make them more attractive, it is
possible to colour them by adding various colouring agents thereto.
These colouring agents may be, for example, pigments such as
lacquers, inorganic pigments or pearlescent pigments, or soluble
colorants. However, the colours obtained are often unstable to
light.
[0004] To obtain iridescent coloured effects, it is possible to use
pearlescent pigments with a variety of colours. However, most
often, the iridescent effect obtained with these pearlescent
pigments is fairly weak, and, in addition, these pigments are
difficult to disperse and to maintain in suspension, in particular
in cleansing compositions which are often quite fluid. The
incorporation of such pigments is therefore delicate and the
reproducibility of the effect obtained is not certain.
[0005] It has therefore been sought to design products having an
iridescent effect without incorporating pearlescent pigments.
[0006] The Applicant has found, surprisingly, that the combination
of polymers, in the form of particles in dispersion (in emulsion or
in latex form), with surfactants, in particular anionic or nonionic
surfactants, allows the production of products with an iridescent
appearance, which are very attractive for consumers without having
the technical difficulties of suspension of the particles.
[0007] Indeed, compositions containing a colouring system, which is
obtained from colloidal crystalline networks in the medium, giving
an iridescent colour without the addition of pigments or colorants,
are known from the document WO-00/47167. However, to obtain such an
effect, the medium has to have a relatively low ionic strength and
a conductance (the conductance is the product of the conductivity
of the composition times the measuring cell constant) of less than
2.5 .mu..OMEGA..sup.-1, which limits the addition of ionic
additives such as ionic surfactants and certain active agents.
However, in cosmetic compositions and in particular in cleansing
compositions, it is often necessary to introduce ionic compounds
into the medium. In addition, it may be advantageous to introduce
surfactants into a composition, for example, to solubilize therein
perfumes and active agents, or as agents for removing make-up from
the skin.
[0008] The need therefore remains for an iridescent composition
which can retain this iridescent character regardless of the
conductance and the ionic strength of its constituent medium.
SUMMARY OF THE INVENTION
[0009] The Applicant has found, surprisingly, that the
disadvantages of the prior art could be remedied using at least 3%
by weight of active material of an aqueous dispersion of
monodisperse particles of polymer, having a mean particle size in
numerical terms ranging from about 50 to 300 nm, and combining
water-soluble surfactants therewith.
[0010] Accordingly, the subject of the present invention is an
iridescent composition for topical application comprising at least
one water-soluble surfactant and monodisperse particles of polymer
in aqueous dispersion, the said particles having a mean size in
numerical terms ranging from 50 to 300 nm and the quantity of the
said particles being at least 3% by weight of active material
relative to the total weight of the composition.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0011] "Mean size in numerical terms" refers to the mean diameter
in numerical terms of the preferably spherical particles of polymer
of the dispersion, this size being the original size of the
particles before they are mixed with other constituents. Indeed,
the size of the particles may be different before and after their
incorporation into a composition, because, as described below, the
particles may consist of polymer comprising a monomer which is
soluble or which swells in alkaline media, such that the particles
of polymer may swell in water or alkaline media after incorporation
into the composition for topical application.
[0012] The size of the particles is measured by means of the
Brookhaven 90Plus particle size analyser. The measurements are
carried out at 90.degree..
[0013] Moreover, the quantity of particles in the present
application is indicated by weight of active material, that is to
say by weight of dry matter content of particles of polymers.
[0014] The composition of the invention is characterized by its
iridescent effect and it has the advantage of having this
iridescent effect, regardless of the value of its conductance
(expressed in ohm.sup.-1 or in Siemens).
[0015] Macroscopically, the iridescent effect results in variations
in colour which are perceived by an observer who would be moving
around the surface of the product illuminated by a fixed light
beam. By contrast, a product is not iridescent when the observer
does not see a change in colour during their movement.
[0016] The iridescent effect may be measured by means of a
goniometer, the principle of which is to measure the colour by
varying the geometric conditions of observations (angles of
illumination and of detection of the reflected light). The method
of measurement used here and described in greater detail below is
inspired by that described in "Colour effects from thin film
designs" by Roger Phillips, Mike Nofi and Robert Slusser (Flex
Products Inc 2793 Northpoint Parkway Santa Rosa Calif. 95407).
[0017] Method of Measurement:
[0018] The samples, at the temperature of 23.degree. C., fill a
vessel 5 mm in height. Their top surface is placed in the plane of
measurement of a spectrophotogoniometer. The spectra are measured
as a reflexion at 400-760 nm in steps of 5 nm. The spectra are
recorded at an angle of illumination set at 55.degree. and at
angles of detection placed successively at the following values:
90.degree. (scattering), 100, 110, 120, 130 and 140.degree.. This
path simulates the variations perceived by an observer who would be
moving around the surface of the product illuminated by a fixed
light beam.
[0019] The different spectra-thus obtained are processed in order
to obtain the calorimetric parameters L*a*b* in the CIELAB space
(reference: ceramic bore MINOLTA Number 20231050 at the
illumination D65 Y=94.1, x=0:3157, y=0.3331). The colourpath is
obtained by joining in the plane of abscissa a* and of ordinate b*,
the coordinates of the colorimetric values calculated. a* varies
from green to red and b* varies from blue to yellow. When a* is
negative, the colour possesses a dominant green; when it is
positive, the colour possesses a dominant red. When b* is negative,
the colour possesses a dominant blue; when it is positive, the
colour possesses a dominant yellow. The colorimetric difference is
equal to the square root of the sum of the squares of the
differences in the values a and b relative to the first measurement
(detection angle of 90 degrees, a measurement close to that
obtained with a conventional colorimeter such as the chromameter
MINOLTA CR300).
[0020] Thus, a composition has an iridescent appearance when the
colorimetric difference for this composition or for the dispersion
of particles of polymer which it contains is greater than 2, and
preferably varies from 2 to 100, preferably from 3 to 60 for an
angle of illumination of 55.degree. and an angle of detection of
between 100 and 140.degree. as described above. The incident light
is characterized by a beam having a diameter of 8 mm, an angular
resolution of 1.3 degrees, a wavelength of 250 to 800 nm and a 1 nm
type resolution.
[0021] A product which does not possess an iridescent effect is
characterized, for example, by differences varying from 0.1 to 1
under the same measurement conditions.
[0022] The composition of the invention is also characterized by
its turbidity, that is to say its opacity. The turbidity measures
the opacity of a product. The NTU (Nephelometric Turbidity Units)
are the units of measurement of the turbidity of a composition. The
measurement of turbidity may be carried out, for example, with a
turbidimeter model 2100P from the company HACH, the tubes used for
the measurement being identified by the references AR397A cat
24347-06. The measurements are carried out at room temperature
(20.degree. C. to 25.degree. C). The higher the turbidity, the
greater the opacity of the product. The composition of the
invention is generally translucent to opaque and it preferably has
a turbidity greater than 100.
[0023] Moreover, the composition according to the invention
generally has a viscosity ranging from 0.1 poise to 100 poises
(0.01 Pa.s to 10 Pa.s), preferably from 4 to 70 poises (0.4 to 7
Pa.s) and more preferably from 5 to 30 poises (0.5 to 3 Pa.s), this
viscosity being measured at about 25.degree. C. with a Rheomat 180
apparatus using a 2, 3, 4 or 5 rotor depending on the viscosity
range, at 200 s.sup.-1.
[0024] The composition of the invention is a composition for
topical, and in particular cosmetic, use, and, as such, it contains
a physiologically acceptable medium, that is to say a medium
compatible with the skin, the hair, the nails and/or the mucous
membranes (lips). In addition, it preferably has a pH compatible
with the skin, that is to say preferably ranging from 3 to 8 and,
even better, from 5 to 7. This pH value may depend on the type of
polymer used.
[0025] The polymer particles used in the composition of the
invention should be monodisperse, that is to say that the results
of measurements of the diameter of the particles are statistically
distributed around a mean and according to a single Gaussian curve.
The variation relative to the mean should not exceed 10% per 100%
of particles. This means that the particles practically all have
the same size. This size ranges from 50 to 300 nm, preferably from
90 to 230 nm and even better from 100 to 200 nm. The size of the
particles is measured by means of the Brookhaven 90Plus particle
size analyser. The measurements are carried out at 90.degree..
[0026] The particles consist of polymers. They become suspended or
dispersed in water, in latex or emulsion form. Latexes are aqueous
dispersions of particles of polymers, as described in "An
introduction to polymer colloids" by F. CANDAU and R. H. OTTEWILL,
Kluwer Academic Publishers, March 1989. The term polymer is
understood here to mean both homopolymers obtained from a single
type of monomer and copolymers obtained from several types (two or
more) of monomers. These polymers may be either associative
polymers (that is to say possessing a hydrophobic part and a
hydrophilic part) or nonassociative polymers (that is to say
hydrophilic or water-soluble). They are dispersible in water and
may exhibit swelling in alkaline media (or alkaline-swelling) or
not. The polymers may be of any type: nonionic, anionic, cationic,
zwitterionic or amphoteric.
[0027] The particles which can be used in the composition of the
invention preferably consist of ionic polymers and even better
anionic polymers. These polymers are dispersible in water and
preferably exhibit alkaline-swelling. The preferred polymers
possess at least one monomer soluble in alkaline media, such as
monomers of acrylic, methacrylic, vinylacetic, maleic, crotonic and
itaconic acids. They may contain another monomer such as styrene,
butadiene, ethylene, acrylonitrile, chloroprene, vinylidene
chloride, isoprene, isobutylene, vinyl chloride, and esters of
acrylic, methacrylic, vinylacetic, maleic, crotonic and itaconic
acids and mixtures thereof.
[0028] Thus, the polymer particles may be chosen, for example, from
the particles consisting of the following anionic polymers:
[0029] 1) homopolymers of acrylic acid, such as those of the
dispersions (in aqueous emulsion) marketed under the names MIRACARE
XC 96/36, MIRACARE XC 96/37 and MIRACARE XC 96/52 (acrylic
nanolatex) by the company RHODIA CHIMIE.
[0030] 2) copolymers of acrylic acid and of other monomers, such as
those of the dispersions marketed under the names NEOCRYL PD-723-B
(particle size: 114 nm), NEOCRYL XK 90 (particle size: 109 nm),
NEOCRYL XK 53 (particle size: 96 nm) by the company AVECIA RESINS;
ECOCRYL VS 301 (particle size: 150 nm) by the company ATOCHEM;
NEOCRYL XK-75 (particle size: 102 nm) (aqueous emulsion of an
acrylic acid/butyl methacrylate/methyl methacrylate/butyl acrylate
copolymer) by the company AVECIA RESINS; MIRACARE XC 97-8 to 13
(acrylic/methyl methacrylate/butyl acrylate/methacrylic acid
copolymer and derivatives in nonionic aqueous nanoemulsion) by the
company RHODIA CHIMIE, ACRYSOL 33 (or ACULYN 33) (acrylic
acid/ethyl acrylate copolymer) (particle size: 110 nm) by the
company ROHM & HAAS.
[0031] 3) styrene derivatives, such as those of the dispersions
marketed under the name SETALUX 6801 AQ 24 (styrene/butyl
acrylate/methyl methacrylate/methacrylic acid hybrid copolymer)
(particle size: 186 nm) by the company AKZO NOBEL; under the name
RHODOPAS GS 125 (particle size: 170 nm) by the company RHONE
POULENC, under the names NEOCRYL XK 61 (anionic acrylic/styrene
copolymer) (particle size: 76 nm), NEOCRYL A 1079 (styrene/acrylate
copolymer) (particle size: 115 nm) by the company AVECIA RESINS;
under the name RK-3-59A-PMN (mixture of two styrene/acrylic
polymers (nucleus/envelope)) (particle size: 116 nm) by the company
ROHM-HAAS, under the name DOW LATEX 432 (styrene/acrylate
copolymer) (particle size: 145 nm) by the company LAMBERT-RIVIERE,
under the name SCX 8060 (particle size: 116 nm) by the company
JOHNSON POLYMER France.
[0032] 4) fluorinated derivatives, such as those of the dispersions
marketed under the references LUMIFLON E-3029 (anionic aqueous
dispersion containing 50% of hydroxylated fluorinated polymer)
(particle size: 100 nm) and LUMIFLON FE-3000 (anionic aqueous
dispersion containing 50% of hydroxylated fluorinated polymer
(particle size: 150 nm) by the company ASAHI GLASS.
[0033] 5) silicone-based derivatives, such as that of the
dispersion marketed under the reference HYCAR 26348
(acrylates/acrylonitrogen/siloxa- ne copolymer) (particle size: 133
nm) by the company GOODRICH.
[0034] 6) diisocyanate derivatives, such as that of the dispersion
marketed under the reference NEOPAC E-106 (urethane/acrylate
copolymer (and) methylpyrrolidone (and) triethylamine) (particle
size: 98 nm) by the company AVECIA RESINS.
[0035] According to a preferred embodiment of the invention,
particles of acrylic acid/ethyl acrylate copolymer, particles of
styrene/butyl acrylate/methyl methacrylate/methacrylic acid hybrid
copolymer, that is to say the dispersions sold under the names
ACRYSOL 33 or ACULYN 33 by the company ROHM & HAAS and SETALUX
6801 AQ 24 by the company AKZO NOBEL, and mixtures thereof are
used. These dispersions are characterized by their colorimetric
difference. When the polymer dispersion "ACULYN 33" is used, it is
preferable that the composition has a pH value ranging from 3 to
6.3.
1 Appearance of Maximum the raw colorimetric Size of Raw Material
material difference the particles ACULYN 33 Iridescent 12.5 110.2
.+-. 2.4% white milk SETALUX 6801 Iridescent 11.1 167.7 .+-. 1.8%
AQ 24 white milk Comparative Example: Non- Less than 1 252.2 .+-.
13.5% SYNTHALEN iridescent with two W2000 .RTM. white milk
populations of of 3V SA sizes, one centered around 167 nm and the
other around 370 nm
[0036] As shown in the table above, the particles of SYNTHALEN
W2000 are not monodisperse, that is to say that their size is not
homogeneous and comprises several Gaussian curves. The comparative
results presented later show that this polymer dispersion is not
appropriate for obtaining an iridescent effect, whereas the two
dispersions "ACULYN 33" and "SETALUX 6801 AQ 24" which are
monodisperse allow iridescent compositions to be obtained.
[0037] The quantity of particles of polymer in the composition of
the invention depends on the polymer used. It may range, for
example, from 3 to 50%, preferably from 3.5 to 40% and even better
from 4 to 30% by weight (of active material or dry matter) relative
to the total weight of the composition.
[0038] The composition according to the invention contains at least
one water-soluble surfactant. The surfactant used may be chosen
from nonionic, anionic, zwitterionic and amphoteric water-soluble
surfactants and mixtures thereof. The expression "water-soluble
surfactant" is understood to mean any surfactant soluble in water
at room temperature (about 25.degree. C.). Such surfactants
generally have an HLB (Hydrophilic Lipophilic Balance) value equal
to or greater than 11.
[0039] The total quantity of surfactant(s) may range, for example,
by weight of active material, from 0.5 to 50% by weight, preferably
from 2 to 40% by weight and even better from 3 to 30% by weight
relative to the total weight of the composition.
[0040] As surfactants which can be used in the composition of the
invention, there may be mentioned for example:
i) Nonionic Surfactants
[0041] There may be used as nonionic surfactants, esters of polyols
and of fatty acids, esters of polyethylene glycols and of fatty
acid, derivatives of fatty alcohols and of polyols (ethers), and
oxyalkylenated (oxyethylenated and/or oxypropylenated) derivatives
of these compounds.
ii) Anionic Surfactants
[0042] There may be used, for example, as anionic surfactants,
carboxylates (sodium 2-(2-hydroxyalkyloxy)acetate), derivatives of
amino acids (N-acylglutamates, N-acylglycinates, acylsarcosinates),
alkyl sulphates, alkyl ether sulphates and their oxyethylenated
derivatives, sulphonates, isethionates, N-acylisethionates,
taurates and N-acyl-N- methyltaurates, sulphosuccinates, alkyl
sulphoacetates, phosphates and alkyl phosphates, polypeptides,
anionic derivatives of alkyl polyglycoside (acyl-D-galactoside
uronate), soaps of fatty acids, and mixtures thereof.
iii) Amphoteric and Zwitterionic Surfactants
[0043] There may be used, for example, as amphoteric and
zwitterionic surfactants, betaines, N-alkylamidobetaines and their
derivatives, glycine derivatives, sultaines, alkyl
polyaminocarboxylates, alkyl amphoacetates, and mixtures
thereof.
[0044] It is also possible to use a mixture of two or more of these
surfactants.
[0045] It is possible to choose in particular the surfactant from
those indicated in the following list which is not exhaustive:
2 Surfactants (CTFA names and tradenames) HLB Ethoxylated
triglyceride (CIRRASOL ALN-WY) 11 Glycerol monostearate (RHEODOL
SEM) 11 Glyceryl stearate (AND) PEG-100 stearate (ICI) (ARLACEL
165) 11 PEG alkyl ether (NOIGEN ET 115) 11 POE glyceryl cocoate
(GLYCEROX HE) 11 POE sorbitan trioleate (RHEODOL TW-0320) 11 POE-10
monostearate (NIKKOL MYS-10) 11 POE-20 POP-6 decyltetradecylether
(NIKKOL PEN-4620) 11 POE-20 sorbitan trioleate (ALKAMULS PSTO-20)
11 POE-20 sorbitan trioleate (MONTANOX 85) 11 POE-20 sorbitan
trioleate (NIKKOL TO-30) 11 POE-20 sorbitan trioleate (POLYSORBATE
85) (TO-55-F) 11 POE-20 sorbitan trioleate (RHEODOL SUPER TW-0320)
11 POE-20 sorbitan trioleate (TWEEN 85) 11 POE-30 hydrogenated
castor oil (NIKKOL HCO-30) 11 POE-30 sorbitan tristearate (NIKKOL
TS-30) 11 POE-8 glyceryl monolaurate (GLYCEROX L8) 11 Saccharose
mono/distearate (SUCRO ESTER WE 11) 11 PEG-8 stearate (ICI) (MYRJ
45) 11.1 POE-8 stearate (SIMULSOL M 45) 11.1 POE sorbitol oleate
(SORBON TR 843) 11.2 (EUMULGIN C8) 11.4 Alkylaryl sulphonate (ATLAS
G 3300B) 11.4 POE sorbitol hexaoleate (ATLAS G-1096) 11.4 POE
sorbitol oleate laurate (ATLOX 1045 A) 11.4 POE-6 tridecyl alcohol
(RENEX 36) 11.4 Di-POE-8 alkyl ether phosphate (NIKKOL DDP-8) 11.5
Ethoxylated alcohol (BEROL 087) 11.5 PEG monooleate (ABLUNOL 400
MO) 11.5 PEG monooleate (NISSAN NONION O-4) 11.5 PEG-400 monooleate
(PGE-400-MO) 11.5 PEG-400 monostearate (PGE-400 MS) 11.5 POE-30
sorbitol tetraoleate (NIKKOL GO-430) 11.5 POE-7 cetyl ether (NIKKOL
BC-7) 11.5 Sorbitol POE-55 hexaoleate (SORBETH 55HO) 11.5 Tri-POE-8
alkyl ether phosphate (NIKKOL TDP-8) 11.5 PEG monostearate (ABLUNOL
400 MS) 11.6 PEG-400 monooleate (RADIASURF 7403) 11.7 (SYNPERONIC
91/5) 11.8 OE castor oil (ABLUNOL CO 30) 11.8 POE monooleate (IONET
MO-400) 11.8 POE polyol fatty acid esters (RHEODOL 440) 11.8
Coceth-7 (NIOX KG-83) 11.9 PEG-400 stearate (RADIASURF 7413) 11.9
POE cetyl ether (NISSAN NONION P-208) 11.9 (SYNPERONIC 87K) 12
(SYNPERONIC BD100) 12 Citric ester of monoglycerides(IMWITOR 369)
12 Decaglycerin monolinoleate (NIKKOL DECAGLYN 1-LN) 12 Decagycerin
distearate (NIKKOL DECAGLYN 2-S) 12 Ethylene glycol mono/distearate
(TEGIN G) 12 Glycerol mono/distearate (TEGIN 4433) 12 Glycerol
mono/distearate (TEGIN SPECIAL) 12 Glycerol mono/distearate (TEGIN)
12 Glycerol mono/distearate + autres nonioniques (TEGINACID) 12
Glyceryl mono/distearate et fatty alcohol sulfates 12 (TEGINACID
SPECIAL) PEG alkyl ether (NOIGEN ET 127) 12 PEG oleic acid ester
(NOIGEN ES 120) 12 PEG oleyl ether (NOIGEN ET 120) 12 PEG-400
monolaurate (PGE-400-ML) 12 PG mono/distearate (TEGIN P) 12 POE-30
POP-6 decyltetradecylether (NIKKOL PEN-4630) 12 Polysorbate
21/POE-4 sorbitan monolaurate (ML-55-F-4) 12 Fatty alcohol
polyglycol ether (AKYPOROX RO 90) 12.1 POE alkyl ether (ABLUNOL LA
7) 12.1 POE lauryl ether (NISSAN NONION K-207) 12.1 OE castor oil
(EMULPON EL 33) 12.2 Pareth-45-8 (NIOX KQ-81) 12.2 POE alkylaryl
ether (EMULGEN 910) 12.2 Alkylaryl PG ether (MARLOWET ISM) 12.3
C12-C14 alcohol polyglycol ether (MARLIPAL 14/70) 12.3 PG-600
oleate (ETHYLAN A6) 12.3 PEG-10 tallow amine (ETILENOX LM-11) 12.4
POE-10 oleyl alcohol (BRIJ 96) 12.4 POE-10 oleyl alcohol (SIMULSOL
96) 12.4 POE-10 stearyl alcohol (BRIJ 76) 12.4 POE-10 stearyl
alcohol (SIMULSOL 76) 12.4 POE-35 hydrogenated castor oil (CRODURET
35) 12.4 (SYNPERONIC A9) 12.5 Alkylaryl polyether alcohol (TRITON
X-155-90%) 12.5 Decaglycerin monoisostearate (NIKKOL DECAGLYN 1-IS)
12.5 Decaglycerin monostearate (NIKKOL DECAGLYN 1-S) 12.5 Fatty
alcohol polyglycol ether carboxylic acid (AKYPO LF 1) 12.5 Oleth-10
(NOIOX KJ-32) 12.5 POE alkyl aryl ether (NISSAN DISPANOL N-100)
12.5 POE sorbitan esters of mixed fatty and resin acids 12.5 (ATLAS
G-8936CJ) POE-10 phytosterol (NIKKOL BPS-10) 12.5 POE-40 castor oil
(NIKKOL CO-40TX) 12.5 POE-40 hydrogenated castor oil (NIKKOL
HCO-40) 12.5 POE-40 sorbitol tetraoleate (NIKKOL GO-440) 12.5
POE-5,5 alkyl ether alcohol (SYNTHENS KMA 55) 12.5 POE-POP cethyl
ether (NIKKOL BPC-44) 12.5 C16-C18 alcohol polyglycol ether
(MARLIPAL 1618/10) 12.6 Coceth-8 (NIOX KG-82) 12.6 OE fatty alcohol
(BEROL 065) 12.6 Oleyl/cetyl alcohol polyglycol ether (EUMULGIN ET
10) 12.6 OE isotridecanol (NIOX KP-69) 12.7 C13-oxoalcohol
polyglycol ether (MARLIPAL 013/80) 12.8 OE branched fatty alcohol
(LAUROPAL X 1107) 12.8 OE fatty oxoalcohol (NIOX KQ-55) 12.8 OE
saturated linear fatty alcohol (NIOX KL-16) 12.8 PEG monostearate
(NISSAN NONION S-15) 12.8 POE laurate (ATLAS G-2127) 12.8 POE
lauryl alcohol (ATLAS G-3707) 12.8 (ARQUAD T-2C-50) 12.9 Alkyl
polyethoxyether (NIOX BD-63) 12.9 C12-C14 alcohol polyglycol ether
(MARLIPAL 24/80) 12.9 POE dioleate (IONET DO-1000) 12.9 POE-10
cetyl alcohol (BRIJ 56) 12.9 POE-40 hydrogenated castor oil
(CRODURET 40) 12.9 Polyoxyethylene cetyl ether (NISSAN NONION
P-210) 12.9 Alkyl aryl ethoxylated (ETHYLAN BKL 130) 13 Citric
ester of monoglyceride (IMWITOR 370) 13 Fatty alcohol polyglycol
ether (MULSIFAN RT 19) 13 Hexaglycerin monolaurate (NIKKOL HEXAGLYN
1-L) 13 OE fatty alcohol (LAUROPAL 0207L) 13 OE fatty oxoalcohol
(NIOX KQ-20) 13 OE technical castor oil (EUMULGIN RT 40) 13 PEG
alkyl ether (NOIGEN ET 135) 13 PG laurate (CHIMIPAL APG 400) 13
POE-60 sorbitol tetrastearate (NIKKOL GS-460) 13 Sucrose fatty acid
ester (DK ESTER F 140) 13 C16-C18 alcohol polyglycol monolaurate
13.1 (NISSAN NONION L-4) PEG monolaurate (ABLUNOL 400 ML) 13.1 POE
alkylaryl ether (EMULGEN 810) 13.1 POE lauryl ether (PEGNOL L-8)
13.1 Anionic and nonionic surfactant (ATLOX 4851 B) 13.2 OE fatty
alcohol (LAUROPAL 9) 13.2 PEG-400 monolaurate (RADIASURF 7423) 13.2
PEG-600 monooleate (RADIASURF 7404) 13.2 PEG-600 monostearate
(RADIASURF 7414) 13.2 POE lauryl ether (NISSAN NONION DN-209) 13.2
C13-oxoalcohol polyglycol ethers (MARLIPAL 13/90) 13.3 PEG-4
sorbitan monolaurate (ICI) (TWEEN 21) 13.3 POE alkyl ether (ABLUNOL
LA 9) 13.3 POE laurate (ATLAS G2109) 13.3 POE sorbitan monolaurate
(RHEODOL TW-L106) 13.3 POE-5 sorbitan monolaurate (MONTANOX 21)
13.3 C12-C14 alcohol polyglycol ether (MARLIPAL 14/90) 13.4
Ceteareth-12 (NIOX KJ-71) 13.4 Fatty alcohol polyglycol ether
(DEHYDOL TA 12) 13.4 Nonionic and anionic (ABLUMUL AG-AH) 13.4 POE
mono coco-fatty acid ester (VALUE 1209C) 13.4 Decaglicerin
monooleate (NIKKOL DECAGLYN 1-O) 13.5 Di-POE-10 alkyl ether
phosphate (NIKKOL DDP-10) 13.5 OE amide (ETHOMID HT/15) 13.5 OE
castor oil (EMULPON EL 40) 13.5 OE fatty alcohol (BEROL 048) 13.5
OE fatty alcohol (BEROL 185) 13.5 PEG glycol monooleate (ABLUNOL
600 MO) 13.5 PEG monooleate (NISSAN NONION O-6) 13.5 PEG-600
monooleate (PGE-600-MO) 13.5 PEG-600 monostearate (PGE-600-MS) 13.5
POE-50 hydroxygenated castor oil (NIKKOL HCO-50) 13.5 POE-cethyl
ether (NIKKOL BC-10TX) 13.5 Quaternary ammonium (ARQUAT S-2C-50)
13.5 Amino acid (ARMEEN SZ) 13.6 Amino acid (ARMEEN Z) 13.6 OE
castor oil (ABLUNOL CO 45) 13.6 OE fatty acid (CIRRASOL ALN-TF)
13.6 OE fatty acid (CIRRASOL ALN-TS) 13.6 PEG monostearate (ABLUNOL
600 MS) 13.6 PEG monostearate (NISSAN NONION S-6) 13.6 POE alkyl
ether (ATLOX 4991) 13.6 POE alkyl ether (ATLOX 4995) 13.6 POE fatty
alcohol ether (EMULGEN 420) 13.6 POE monooleate (VALUE 1414) 13.6
C13-oxoalcohol polyglycol ether (MARLIPAL 013/100) 13.7 Nonionic
(ATLOX 5325) 13.7 C12 alcohol polyglycol ether (MALILPAL 129) 13.8
PEG palmitate (NISSAN NONION P-6) 13.8 POE polyol fatty acid esters
(RHEODOL 450) 13.8 C12-C14 alcohol polyglycol ether (MARLIPAL
14/100) 13.9 Nonionic and anionic (ABLUMUL AG-KP3) 13.9 OE
cetostearyl alcohol (ATLAS G-4822) 13.9 POE fatty alcohol
polyglycol ether (EMULGEN 320 P) 13.9 POE-11 C13-C15 alcohol (RENEX
711) 13.9 Alkyl aryl polyether (TRITON CF-10) 14 Fatty alcohol
ether sulfosuccinate (REWOPOL SB FA 50) 14 OE amides (ETHOMID O/15)
14 PEG lauryl ether (NOIGEN ET 147) 14 PEG oleic acid ester (NOIGEN
ES 140) 14 PEG oleyl ether (NOIGEN ET 140) 14 POE alkyl ether
(ATLOX 804) 14 POE-15 glyceryl monolaurate (GLYCEROX L 15) 14
POE-24 cholesterol (SOLULAN C-24) 14 POE-60 castor oil (NIKKOL
CO-60TX) 14 POE-60 sorbitol tetraoleate (NIKKOL GO-460) 14
Saccharose monopalmitate (SUCRO ESTER WE 15) 14 Ceteareth-14 (NIOX
KJ-61) 14.1 POE cetyl ether (NISSAN NONION P-213) 14.1 POE lauryl
ether (NISSAN NONION K-211) 14.1 C12-C14 alcohol polyglycol ether
(MARLIPAL 24/110) 14.2 Fatty alcohol polyglycol ether carboxylic
acid (AKYPO LF 6) 14.2 OE alcohol (QUIMIPOL EA 2512) 14.2 POE fatty
alcohol ether (Emulgen 220) 14.2 POE oleyl ether (NISSAN NONION
E-215) 14.2 POE stearyl ether (NISSAN NONION S-215) 14.2 Quaternary
ammonium (ARQUAD T-50) 14.2 Free acid of complex organic phosphate
ester 14.4 (PLYSURF A216B) OE fatty alcohol (LAUROPAL 11) 14.4 OE
fatty alcohol (LAUROPAL 1150) 14.4 PEG-12 cocamine (ETILENOX KM-54)
14.4 POE alkyl ether (ABLUNOL LA 12) 14.4 POE castor oil (ARLATONE
285) 14.4 POE cetyl ether (PEGNOL C-14) 14.4 POE hydrogenated
castor oil (ARLATONE 289) 14.4 POE triglyceride (ATLAS G-1285) 14.4
POE triglyceride (ATLAS G-1289) 14.4 POE triglyceride (ATLOX 1285)
14.4 C13 oxoalcohol polyglycol ethers (MARLIPAL 013/120) 14.5
Decaglycerin monomyristate (NIKKOL DECAGLYN 1-M) 14.5 OE ethylene
diamine POP (ALKATRONIC EDP 38-4) 14.5 POE-10 oleyl ether (NIKKOL
BO-10TX) 14.5 POE-12 tridecyl alcohol (RENEX 30) 14.5 POE-60
hydrogenated castor oil (NIKKOL HCO-60) 14.5 POE-9 lauryl ether
(NIKKOL BL-9EX) 14.5 (SYNPERONIC 91/10) 14.6 C12-C14 alcohol
polyglycol ether (MARLIPAL 24/120) 14.6 Fatty alcohol ethylene
oxide condensate 14.6 (EMPILAN KA 1080) OE fatty amines (ETHOMEEN
S/12) 14.6 OE-OP (NEWPOL PE-88) 14.6 OE fatty oxoalcohol (NIOX
KQ-57) 14.7 POE-60 hydrogenated castor oil (CRODURET 60) 14.7
(SYNPERONIC 13/12) 14.8 OE-OP (NEWPOL PE-78) 14.8 PEG monolaurate
(ABLUNOL 600 ML) 14.8 POE lauryl ether (PEGNOL L-12) 14.8 (PLYSURF
A217E) 14.9 Fatty alcohol OE (CIRRASOL ALN-WF) 14.9 OE fatty amines
(ETHOMEEN T/12) 14.9 OE-OP (NEWPOL PE-68) 14.9 PEG-20 sorbitan
monostearate (ICI) (1204) (TWEEN 60) 14.9 POE sorbitan monostearate
(IONET T-60C) 14.9 POE sorbitan monostearate (NISSAN NONION ST-221)
14.9 POE-16 cetyl alcohol (ATLAS G-3816) 14.9 POE-20 sorbitan
monolaurate (ALKAMULS PSMS-20) 14.9 POE-20 sorbitan monooleate
(RADIAMULS SORB 2157) 14.9 POE-20 sorbitan monostearate (EMASOL
S-120) 14.9 POE-20 sorbitan monostearate (MONTANOX 60) 14.9 POE-20
sorbitan monostearate (NIKKOL TS-10) 14.9 Ethoxylated
polyoxypropylene glycols 15 (ALKATRONIC PGP 18-4) OE (PEPOL B-184)
15 OE fatty alcohol (BEROL 07) 15 OE sorbitan ester (SORBANOX AOM)
15 OE sorbitan ester (SORBANOX AST) 15 OE-20 methyl glucoside
sesquistearate (GLUCAMATE SSE-20) 15 Oleth-18 (NOIOX KJ-23) 15
Oleth-20 (AMEROXOL OE-20) 15 PEG oleyl ether (NOIGEN ET 157) 15
PEG-20 sorbitan monooleate (ICI) (TWEEN 80) 15 PEG-20 stearate (ICI
(MYRJ 49) 15 PEG-600 monolaurate (PGE-600-ML) 15 POE sorbitan
monolaurate (ABLUNOL T 80) 15 POE sorbitan-20 monooleate (ALKAMULS
PSMO-20) 15 POE-20 sorbitan monoisotearate (NIKKOL TI-10) 15 POE-20
sorbitan monooleate (ATLAS G-4905) 15 POE-20 sorbitan monooleate
(TWEEN 80) 15 POE-20 sorbitan monooleate (MONTANOX 80) 15 POE-20
stearate (MYRJ 49) 15 POE-20 stearate (SIMULSOL M 49) 15 POE-25
monostearate (NIKKOL MYS-25) 15 POE-80 hydrogenated castor oil
(NIKKOL HCO-80) 15 Sucrose fatty acid esters (DK ESTER F 160) 15
Sucrose monococoate (CRODESTA SL 40) 15 Tri POE-10 alkyl ether
phosphate (NIKKOL TDP-10) 15 C16-C18 alcohol polyglycol ether
(MALIPAL 1618/18) 15.1 Nonionic and anionic (ABLUMOL AG-420) 15.2
PEG alkyl ether (ABLUNOL LA 16) 15.2 PEG monooleate (ABLUNOL 1000
MO) 15.2 PEG monostearate (ABLUNOL 1000 MS) 15.2 POE lauryl ether
(NISSAN NONION K-215) 15.2 C13 oxoalcohol polyglycol ethers
(MARLIPAL 013/150) 15.3 Ceteareth-20 (NIOX EO-41) 15.3 Oleth-20
(ICI) (2101) (BRIJ 98) 15.3 Oleth-20 (SIMULSOL 98) 15.3 POE cetyl
ether (PEGNOL C-18) 15.3 POE fatty alcohol ether (EMULGEN 120) 15.3
POE oleyl ether (NISSAN NONION E-220) 15.3 POE sorbitan
monopalmitate (NISSAN NONION S-220) 15.3 POE sorbitan monostearate
(SORBON T-60) 15.3 Steareth-20 (BRIJ 78) 15.3 Steareth-20 (SIMULSOL
78) 15.3 Fatty alcohol polyglycol ether (DEHYDOL TA-20) 15.5
PEG-1000 monostearate (PGE-1000-MS) 15.5 POE sorbitan monolaurate
(ABLUNOL T40) 15.5 POE sorbitan monooleate (RHEODOL TW-0120) 15.5
POE-15 cetyl ether (NIKKOL BC-15TX) 15.5 POE-20 ceto/stearyl ether
(CETOMACROGOL 1000 BP) 15.5 POE-20 phytosterol (NIKKOL BPS-20) 15.5
Quaternary ammonium (ARQUAD S-50) 15.5 Steareth-21 (ICI) (BRIJ 721)
15.5 POE lauryl ether (PEGNOL L-15) 15.6 POE-20 sorbitan
monopalmitate (MONTANOX 40) 15.6 POE-20 sorbitan monopalmitate
(TWEEN 40) 15.6 Ceteth-20 (BRIJ 58) 15.7 Isohexadeceth-20
(arlasolve 200) 15.7 POE cetyl ether (PEGNOL C-20) 15.7 POE
monostearate (IONET MS-1000) 15.7 POE sorbitan monooleate
(RADIASURF 7157) 15.7 POE sorbitan monopalmitate (SORBON T-40) 15.7
Quaternary ammonium (ARQUAD 18-50) 15.7 C13 oxoalcohol polyglycol
ether (MARLIPAL 013/170) 15.8 Quaternary ammonium (ARQUAD 16-50)
15.8 Noionic (EMULGATOR E2568) 16 OE-OP ethylene diamine
(ALKATRONIC EDP 8-4) 16 Oleth-15 (NIKKOL BO-15TX) 16 PEG lauryl
ether (NOIGEN ET 160) 16 PEG oleic acid ester (NOIGEN ES 160) 16
POE sorbitan monolaurate (RADIASURF 7137) 16 POE triglyceride
(ATLAS G-1288) 16 POE-20 sorbitan monopalmitate (MP-55-F) 16 POE-30
stearate (MYRJ 51) 16 POE-30 stearic acid (SIMULSOL M 51) 16
(PLYSURF A219B) 16.2 (SYNPERONIC 13/18) 16.2 (SYMPERONIC A20) 16.2
C16-C18 alcohol polyglycol ether (MARLIPAL 1618/25) 16.2 POE lauryl
ether (NISSAN NONION K-220) 16.2 POE-100 hydrogenated castor oil
(CRODURET 100) 16.3 (SYNPERONIC 13/20) 16.4 POE-20 sorbitan
monolaurate (RADIAMULS SORB 2137) 16.4 PEG-1500 monostearate
(RADIASURF 7417) 16.5 POE lauryl ether (PEGNOL L-20) 16.5 POE-100
hydrogenated castor oil (NIKKOL HCO-100) 16.5 POE-20 behenyl ether
(NIKKOL BB-20) 16.5 POE-POP cetyl ether (NIKKOL PBC-34) 16.5
Quaternary ammonium (ARQUAD C-33W) 16.5 POE oleyl ether (NISSAN
NONION E-230) 16.6 Ceteareth-30 (NIOX EO-42) 16.7 PEG monostearate
(NISSAN NONION S-15,4) 16.7 POE sorbitan monolaurate (ABLUNOL T 20)
16.7 POE sorbitan monolaurate (IONET T-20C) 16.7 POe-20 sorbitan
monolaurate (EMASOL L-120) 16.7 POE-20 sorbitan monolaurate
(MONTANOX 20) 16.7 POE-20 sorbitan monolaurate (TWEEN 20) 16.7
Laureth-23 (BRIJ 35) 16.9 PEG-40 stearate (ICI) (MYRJ 52) 16.9
POE-20 sorbitan monolaurate (NIKKOL TL-10) 16.9 POE-40 stearic acid
5SIMULSOL M 52) 16.9 PPG PEG (EPAN U 105) 16.9 Decaglycerin
monolaurate (NIKKOL DECAGLYN 1-L) 17 PEG lauryl ether (NOIGEN ET
170) 17 POE-20 cetyl ether (NIKKOL BC-20TX) 17 POE-20 oleyl ether
(NIKKOL BO-20) 17 POE-23 lauryl ether (AMEROXOL LE-23) 17 POE-40
glyceryl monolaurate (GLYCEROX L 40) 17 POE-40 stearate (RS-55-40)
17 C12-C14 alcohol polyglycol ether (MARLIPAL 24/300) 17.4 POE
alkyl amine (PEGNOL OA-400) 17.4 POE alkylaryl ether (emulgen 935)
17.5 POE sorbitol oleate (SORBON TR 814) 17.5 POE triglyceride
(ATLAS G1295) 17.5 Sodium N-decyl diphenyl oxide disulfonate
(DOWFAX 3B2) 17.8 OE fatty amine (ETHMEEN C/15) 17.9 PEG-50
stearate (ICI) (MYRJ 53) 17.9 POE-50 stearate (MYRJ 53) 17.9 OE
monodiglyceride of caprylic/capric acids (SOFTIGEN 767) 18 PEG
alkyl ether (NOIGEN ET 187) 18 PEG oleyl ether. (NOIGEN ET 180) 18
POE-200 castor oil (ETOCAS 200) 18 POE-200 hydrogenated castor oil
(CRODURET 200)
18 POE-23 cetyl ether (NIKKOL BC-23) 18 POE-30 behenyl ether
(NIKKOL BB-30) 18 POE-30 phytosterol (NIKKOL NPS-30) 18 POE-45
monostearate (NIKKOL MYS-45) 18 POE-50 oleyl ether (NIKKOL BO 50)
18 POE-55 monostearate (NIKKOL MYS-55) 18 Sodium lauryl ether
sulfate (REWOPOL NL 3-S 70) 18 PEG monostearate (NISSAN NONION
NS-250) 18.2 POE alkylaryl ether (EMULGEN 950) 18.2 Amine oxide
(AROMOX C/12-W) 18.4 OE fatty diamine (ETHODUOMEEN T/25) 18.5
POE-100 stearate (RS-55-100) 18.5 POE-25 cetyl ether (NIKKOL
BC-25TX) 18.5 Amine OXIDE (AROMOX DMMCD-W) 18.7 PEG-100 stearate
(ICI) (MYRJ 59) 18.8 POE-100 stearate (SIMULSOL M 59) 18.8
Steareth-100 (BRIJ 700) 18.8 steareth-100 (ICI) (BRIJ 700) 18.8 POE
alkylaryl ether (EMULGEN 985) 18.9 OE amide (ETHOMIDVHT/60) 19 OE
fatty amine (ETHOMEEN S/15) 19 PEG distearate (NISSAN NONION
DS-60HN) 19 PEG fatty acid ester (ABLUNOL 6000 MS) 19 PEG lauryl
ether (NOIGEN ET 190S) 19 PEG oleyl ether (NOIGEN ET 190S) 19
POE-21 lauryl ether (NIKKOL BL-21) 19 OE fatty amine (ETHOMEEN
C/25) 19.3 POE-25 lauryl ether (NIKKOL BL-25) 19.5 POE-30 cetyl
ether (nikkol bc-30tx) 19.5 GE fatty amine (ETHOMEEN HT/25) 19.7
PEG distearate (NOIGEN DS601) 20 PEG lauryl ether (NOIGEN YX 500)
20 PEG lauryl ether (NOIGN YX 400) 20 PEG oleyl ether -NOIGEN O
100) 20 POE-40 cetyl ether (NIKKOL BC-40TX) 20 OE POP (ALKATRONIC
PGP 40-7) 22 OE POP (ALKATRONIC PGP 23-7) 24 PPG PEG (EPAN U 108)
26 OE POP (ALKATRONIC PGP 33-8) 27 OE POP ethylene diamine
(ALKATRONIC EDP 28-7) 27 OE POP (ALKATRONIC PGP 23-8) 28 OE POP
(ALKATRONIC PGP 18-8) 29
[0046] The physiologically acceptable medium of the composition of
the invention comprises water. The quantity of water may range from
30 to 96.5%, preferably from 40 to 95% by weight relative to the
total weight of the composition. It may contain, in addition to
water, one or more solvents chosen from lower alcohols comprising
from 1 to 8 carbon atoms, such as ethanol; polyols such as
glycerin; glycols such as butylene glycol, isoprene glycol,
propylene glycol, polyethylene glycols such as PEG-8; sorbitol;
sugars such as glucose, fructose, maltose, lactose, sucrose; and
mixtures thereof. The quantity of solvent(s) in the composition of
the invention may range from 0.5 to 30% by weight and preferably
from 5 to 20% by weight relative to the total weight of the
composition.
[0047] The composition of the invention may also contain customary
additives in the cosmetic field, such as mattifying inorganic or
organic fillers, active agents, preservatives, gelling agents,
plasticizers, antioxidants, perfumes, odor absorbers, antifoaming
agents, sequestrants (EDTA), acidic or basic pH regulators, or
buffers, pigments and pearlescent agents (in a quantity such that
this does not disrupt the desired effect), polymers, fatty
materials made compatible with the aqueous medium, such as oils or
waxes, in so far as the additive does not impair the properties
sought for the composition of the invention. The quantities of
these various additives are those conventionally used in the fields
considered, and for example from 0.01 to 20% of the total weight of
the composition.
[0048] As active agents, it is possible to incorporate any active
agent normally used in the cosmetic and dermatological fields, such
as water-soluble or fat-soluble vitamins or provitamins, for
example vitamins A (retinol), C (ascorbic acid), B3 or PP
(niacinamide), B5 (panthenol), E (tocopherol), K1, beta-carotene,
and the derivatives of these vitamins and in particular their
esters; hormones or derivatives such as DHEA and 7.alpha.-hydroxy
DHEA; antiseptics; antiseborrhoeics; antimicrobials such as benzoyl
peroxide, salicylic acid, triclosan, azelaic acid, niacinamide
(vit. PP); moisturizers such as glycerin, hyaluronic acid,
pyrrolidonecarboxylic acid (PCA) and its salts, sodium pidolate,
serine, xylitol, trehalose, ectoin, ceramides, urea; keratolytic
and antiageing agents such as alpha-hydroxy acids such as glycolic
acid, citric acid, lactic acid, beta-hydroxy acids such as
salicylic acid, coenzyme Q10; sunscreens; optical brighteners;
slimming agents such as caffeine, theophylline, theobromine,
anti-inflammatory agents such as 18-.beta.-glycyrrhetinic acid and
ursolic acid. It is also possible to use a mixture of two or more
of these active agents. The active agent(s) may be, for example,
present in a concentration ranging from 0.01 to 20%, preferably
from 0.1 to 10% and even better from 0.5 to 5% of the total weight
of the composition.
[0049] The composition of the invention may be provided in any of
the galenic forms normally used in the cosmetic and dermatological
fields. It is generally provided in the form of a gel and is
prepared according to the customary methods, that is to say by
mixing the surfactant and the polymer in the aqueous medium and
adjusting the pH if necessary.
[0050] The composition according to the invention may comprise an
oily phase (or fatty phase) comprising at least one oil, provided
that it is solubilized in the medium, for example by forming a
microemulsion. The oil(s) may be chosen from oils of plant origin
(jojoba, avocado, sesame, sunflower, maize, soyabean, safflower,
grapeseed), mineral oils (petroleum jelly, hydrogenated or
nonhydrogenated isoparaffins, isohexadecane, squalane), synthetic
oils (parleam, isopropyl myristate; cetearyl octanoate,
polyisobutylene, ethylhexyl palmitate, alkyl benzoates), volatile
or nonvolatile silicone oils such as polydimethylsiloxanes (PDMS)
and cyclodimethylsiloxanes or cyclomethicones, and fluorinated or
fluorosilicone oils, as well as mixtures of these oils. The oily
phase may contain, in addition, other fatty constituents such as
fatty alcohols such as stearyl alcohol, cetyl alcohol and the
mixture thereof (cetearyl alcohol); fatty acids; waxes; silicone
gums. The oily phase may be present in a quantity ranging, for
example, from 0.01 to 20% by weight relative to the total weight of
the composition.
[0051] The composition according to the invention finds application
in a large number of treatments, in particular cosmetic treatments,
of the skin, including the scalp, the hair, the nails and/or the
mucous membranes, in particular for the care, cleansing and/or
application of make-up to and/or protection, from the sun, of the
skin, the hair and/or the lips or the mucous membranes. It may be
used, for example, as products for cleansing or removing make-up
from the face (including the eyes and the lips) or the body, as
care products for the face, for example for treating the signs of
ageing or for moisturizing or nourishing the skin, as antisun
products for protecting the skin or the hair from UV radiation, as
hair products.
[0052] Accordingly, the subject of the present invention is the
cosmetic use of the composition as defined above, for the
treatment, protection, care, removal of make-up from and/or
cleansing of the skin, the lips and/or the hair, and/or the
application of make- up to the skin and/or the lips.
[0053] The subject of the present invention is also a method for
the cosmetic treatment of the skin, including the scalp, the hair
and/or the lips, characterized in that a cosmetic composition as
defined above is applied to the skin, the hair and/or the lips.
[0054] The following examples illustrate the invention. A.M. means
therein "as active material". The quantities are indicated as a
percentage by weight unless otherwise stated.
EXAMPLE 1
Gel for Cleansing of or Removing Make-Up from the Face
[0055]
3 ACUYLN 33 .RTM. from ROHM-HAAS 5% A.M. Sodium lauryl ether
sulphate (TEXAPON N702 6% A.M. PATE from HENKEL, at 70% of A.M. in
water) Glycerin 3% Preservatives qs Sodium hydroxide at 10% qs pH
Water qs 100%
[0056] Procedure: The water, the glycerin, the surfactant and the
preservatives are mixed at room temperature (about 20.degree. to
25.degree. C.). The ACUYLN 33 is added thereto and the mixture is
homogenized. The pH is adjusted to 5.85 with sodium hydroxide.
[0057] An iridescent gel of pH 5.85 is obtained. This gel has a
viscosity at T0, measured using a No. 3 or 4 rotor (Rheomat RM180
at room temperature, that is to say at about 25.degree. C., at 200
s.sup.-1), of 4.8 poises (0.48 Pa.s).
COMPARATIVE EXAMPLE 1
[0058] ACUYLN 33 is replaced, in Example 1, with an equivalent
quantity of SYNTHALEN W2000 (3V SA) (5% by weight of A.M.).
A Noniridescent Colourless Transparent Gel is Obtained
EXAMPLE 2
Gel for Removing Make-up from or Cleansing the Face
[0059]
4 ACUYLN 33 .RTM. from ROHM-HAAS 5% A.M. Sucrose laurate (at 70% of
monoester) 13% A.M. (SISTERNA L70-C from SISTERNA at 40% of A.M. in
water) Glycerin 3% Preservatives qs Sodium hydroxide qs pH Water qs
100%
The Procedure is the Same as that of Example 1
[0060] An iridescent gel of pH 5.76 is obtained. This gel has a
viscosity at T0, measured using a No. 3 or 4 rotor (Rheomat RM180
at room temperature, that is to say at about 25.degree. C., at 200
s.sup.-1), of 2.5 poises (0.25 Pa.s).
COMPARATIVE EXAMPLE 2
[0061] ACUYLN 33 is replaced, in Example 2, with an equivalent
quantity of SYNTHALEN W2000 (3V SA) (5% by weight of A.M.).
A Noniridescent Colourless Gel is Obtained.
EXAMPLE 3
Gel for Removing Make-Up from or Cleansing the Face
[0062]
5 SETALUX 6801 AQ64 (AKZO NOBEL) 15% A.M. Sodium lauryl ether
sulphate (TEXAPON N702 6% A.M. PATE from HENKEL, at 70% of A.M. in
water) Glycerin 3% Preservatives qs Sodium hydroxide qs pH Water qs
100%
The Procedure is the Same as that of Example 1
[0063] An iridescent translucent gel of pH 6.7 is obtained. This
gel has a viscosity at T0, measured using a No. 3 or 4 rotor
(Rheomat RM180 at room temperature, that is to say at about
25.degree. C., at 200 s.sup.-1), of 6 poises (0.6 Pa.s), and it has
a conductance, measured using the type CD78 conductimeter from
TACUSSEL at 25.degree. C. of 6075 .mu..OMEGA..sup.-1.
COMPARATIVE EXAMPLE 3
[0064] ACULYN 33 is replaced, in Example 3, with an equivalent
quantity of an aqueous dispersion of silica, that is the product
marketed by the company Ikeda under the name Opalesque 1015, a 15%
dispersion in water of silica particles having a size of about 100
mn, that is the product marketed by the company Ikeda under the
name Opalesque 1030, a 30% dispersion in water of silica particles
having a size of about 100 nm.
In Both Cases, a Noniridescent White Liquid is Obtained
EXAMPLE 4
Make-Up-Removing Gel for the Face
[0065]
6 ACULYN 33 .RTM. from ROHM-HAAS 5% A.M. Magnesium laureth-8
sulphate (and) magnesium laureth 0.3% A.M. sulphate (and) sodium
oleth sulphate (and) magnesium oleth sulphate (EMPICOL BSD 52
.RTM.) from ALBRIGHT & WILSON* (at 52% of A.M. in water)
Disodium cocoamphodiacetate (MIRANOL C2M 0.5% A.M. CONC NP .RTM.)
from RHODIA CHIMIE (at 38% of A.M. in water) Hexylene glycol 5%
Glycerin 3% Preservatives qs Sodium hydroxide qs pH 6 Water qs
100%
The Procedure is the Same as that of Example 1
[0066] An iridescent translucent gel of pH 6 is obtained whose
colours vary from blue, green, yellow, to orange depending on the
orientation. This gel has a viscosity, after 10 minutes, measured
with a No. 3 or 4 rotor (Rheomat RM180 at room temperature, that is
to say at about 25.degree. C., at 200 s.sup.-1), of 15 poises (1.5
Pa.s).
EXAMPLE 5
Make-Up-Removing Gel for the Face
[0067]
7 SETALUX 6801 AQ64 from AKZO NOBEL 18% A.M. Magnesium laureth-8
sulphate (and) 0.3% A.M. magnesium laureth sulphate (and) sodium
oleth sulphate (and) magnesium oleth sulphate (EMPICOL BSD 52
.RTM.) from ALBRIGHT & WILSON* (at 52% of A.M. in water)
Disodium cocoamphodiacetate (MIRANOL 0.5% A.M. C2M CONC NP .RTM.)
from RHODIA CHIMIE (at 38% of A.M. in water) Hexylene glycol 5%
Glycerin 3% Preservatives qs Sodium hydroxide qs pH 7.5 Water qs
100%
The Procedure is the Same as that of Example 1
[0068] An iridescent milky fluid gel of pH 7.5 is obtained whose
colours vary from blue to green depending on the orientation. This
gel has a viscosity, after 10 minutes, measured with a No. 3 or 4
rotor (Rheomat RM180 at room temperature, that is to say at about
25.degree. C., at 200 s.sup.-1), of 4 poises (0.4 Pa.s).
EXAMPLE 6
Anti-Inflammatory Gel
[0069]
8 ACULYN 33 .RTM. from ROHM-HAAS 5% A.M. POE (20) sorbitan
monooleate (HLB 15) TWEEN 80 .RTM. from the company UNIQEMA with 4%
HLB 15 Ursolic acid from the company CRODAROM 0.4% Glycerin 3%
Preservatives qs Sodium hydroxide qs pH 6 Water qs 100 g
The Procedure is the Same as that of Example 1.
[0070] An iridescent translucent gel of pH 6 is obtained whose
colours vary from blue, green, yellow, to orange depending on the
orientation. This gel has a viscosity, after 10 minutes, measured
with a No. 3 or 4 rotor (Rheomat RM 180 at room temperature, that
is to say at about 25.degree. C., at 200 s.sup.-1), of 15 poises
(1.5 Pa.s).
* * * * *