U.S. patent application number 11/047730 was filed with the patent office on 2005-08-04 for method and apparatus for forming microstructures on polymeric substrates.
Invention is credited to Clark, Barry, Gasiorowski, Paul, Hennessey, Michael, Strand, David.
Application Number | 20050167885 11/047730 |
Document ID | / |
Family ID | 32069449 |
Filed Date | 2005-08-04 |
United States Patent
Application |
20050167885 |
Kind Code |
A1 |
Hennessey, Michael ; et
al. |
August 4, 2005 |
Method and apparatus for forming microstructures on polymeric
substrates
Abstract
Methods and apparatus for forming microstructures in the surface
of polymeric web materials for use as optical memory substrates.
The microstructures may be formed by laminating a hot stamper to a
web of material with a selective time/temperature profile. The
stamper may be heated to melt flow the surface of the web and
stabilize before separation. The stamper may be carried by a
support that is independent of the press. The web of polymeric
material may be provided with a flow enhancer to improve image
formation. Also described herein are methods and apparatus for
making optical memory modules, such as disks, which include novel
stampers, coating applicators, and finishing systems.
Inventors: |
Hennessey, Michael; (South
Lyon, MI) ; Strand, David; (Bloomfield Township,
MI) ; Clark, Barry; (Ortonville, MI) ;
Gasiorowski, Paul; (Davisburg, MI) |
Correspondence
Address: |
ENERGY CONVERSION DEVICES, INC.
2956 WATERVIEW DRIVE
ROCHESTER HILLS
MI
48309
US
|
Family ID: |
32069449 |
Appl. No.: |
11/047730 |
Filed: |
February 2, 2005 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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11047730 |
Feb 2, 2005 |
|
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10185246 |
Jun 26, 2002 |
|
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60300997 |
Jun 26, 2001 |
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Current U.S.
Class: |
264/295 |
Current CPC
Class: |
Y10T 83/4838 20150401;
Y10S 425/81 20130101; B29L 2017/00 20130101; B29C 2035/0811
20130101; Y10T 156/12 20150115; B29C 59/026 20130101; Y10T 156/1304
20150115; B29L 2017/005 20130101; B29C 2059/023 20130101; B29C
59/04 20130101 |
Class at
Publication: |
264/295 |
International
Class: |
B29C 033/00 |
Claims
What is claimed is:
1. A method of making a stamper for use in a continuous web forming
process comprising the steps of: providing a stamper with a
transferable image; curving the stamper; and increasing the
thickness of the stamper.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] The present invention relates to, and is entitled to the
benefit of the earlier filing date and priority of, U.S.
Provisional Patent Application No. 60/300997, filed Jun. 26, 2001,
the disclosure of which is herein incorporated by reference.
FIELD OF THE INVENTION
[0002] The present invention relates generally to methods and
apparatus for making optical memory. More particularly, the present
invention pertains to forming substrates for optical memory and for
making optical disks using continuous feed or roll-to-roll
systems.
BACKGROUND OF THE INVENTION
[0003] Optical memory disks, such as CD (compact disks), CD-R,
CD-RW; DVD (digital versatile disks), DVD-R, DVD-ROM, DVD-RAM,
DVD+RW, DVD-RW, PD (phase change disks) and MO (magneto optical),
etc., are typically manufactured by initially forming a substrate
and then depositing one or more thin film layers upon the
substrate. Substrates for optical memory are usually formed with a
series of grooves and/or pits arranged as concentric tracks or as a
continuous spiral. The grooves and pits may be used for things such
as laser beam tracking, address information, timing, error
correction, data, etc. Substrates used for optical disks are
typically formed by injection molding, where a molten polymeric
material is injected into a disk shaped mold with one surface
having the patterned microstructure to be replicated. The patterned
microstructure is typically provided by an exchangeable insert,
commonly referred to as a stamper. The injection molding process is
comprised of a series of precisely timed steps, which include
closing the mold, injecting the molten polymer, providing a
controlled reduction in peak injection pressure, cooling,
center-hole formation, opening the mold and removing the replicated
disk and associated sprue. Following the molding process, disk
substrates are typically coated with one or more thin film layers.
Thereafter, substrates may be coated with various insulating and/or
protective layers, bonding adhesive, decorative artwork, labels,
etc.
[0004] Although injection-molding methods, such as those described
above, can provide high quality optical memory disks with
acceptable levels of birefiingence and flatness, the rate of disk
production is only in the neighborhood of several seconds. About
60% of this time is attributable to the molding step, and the rest
is taken up by the need to open the mold, remove the disk and
sprue, and then close the mold before the next cycle can begin.
Furthermore, present attempts to improve production rate by using
various novel de-molding techniques or by using multi-cavity molds
have had only limited success.
[0005] Besides lower than desired production rates, injection
molding requires complex closed-loop control over numerous
parameters. For example, mold and polymer temperature, press clamp
force, injection profile and hold time all have competing and
often-opposed influences on birefringence, flatness, and on the
accuracy of the replicated features. It should also be noted that
molding difficulty increases as the thickness of the replicated
disk decreases. So where standard CD substrates, which are
approximately 1.2 mm thick, do not require the use of specialized
techniques, such as increasing the molding cavity cross-section
during the main injection phase, injection-compression molding,
coining, "bump molding", etc., standard DVD substrates, which are
approximately 0.6 mm thick, do in order to simultaneously meet
birefringence and flatness specifications.
[0006] The trend in future optical memory products is toward
thinner substrates and/or smaller disks. Directly manufacturing
these products via injection molding may not be practical.. For
small diameter disks (i.e. 5-8 cm.), such as the ones used in
Personal Digital Assistants (PDA's) and Digital Electronic Cameras,
disturbances caused by center gating can influence the quality of
the innermost tracks on the disk. These disturbances are associated
with local turbulence, shear, and packing variation near the center
gate in the mold and can produce locally poor flatness and high
birefringence. As the minimum track diameter is reduced, these
problems may be exemplified.
[0007] To speed-up the rate of manufacturing, a number of methods
for manufacturing optical memory using continuous web processes
have been proposed. These methods are built on the concept of
forming a microstructure pattern on a continuous web of material by
passing the web between a roller and a stamper.
[0008] To date, there have been two types of continuous web
processes proposed. These processes include "in-line" and
"off-line" methods. In-line continuous web processes integrate web
extrusion with microstructure pattern formation in the same
process, while off-line continuous web processes carry out web
formation on pre-fabricated web material which is manufactured on
another production line. The goal of in-line formation is to
contact the web with a stamper immediately after web extrusion and
while the web is still hot. Examples of in-line processes include
those described in U.S. Pat. Nos. 5,137,661; 4,790,893; 5,433,897;
5,368,789; 5,281,371; 5,460,766; 5,147,592; and 5,075,060, the
disclosures of which are herein incorporated by reference. The
integration of web extrusion and web formation requires that a disk
manufacturer not only engage in the business of producing optical
disks but also in web extrusion. This makes the overall system a
highly complex process, at a point in the process where it may not
be desirable. Furthermore, because the disk manufacturer may not
enjoy the same economies of scale that a plastic web manufacturer
does, the cost per unit for disks formed with in-line processes may
be higher than that for off-line processes. Thus, the present
inventors propose that off-line processing not only offers the
opportunity for improved throughput, reduced cost and complexity,
and shorter start-up time, but for increased process flexibility as
well.
[0009] One method of web formation, which may be used for in-line
processes for optical memory production, is proposed by Kime, U.S.
Pat. No. 6,007,888, entitled "Directed Energy Assisted In Vacuo
Micro Embossing" which issued Dec. 28, 1999, the disclosure of
which is herein incorporated by reference. Kime discloses a
continuous manufacturing process using directed energy assisted
micro embossing. The patent describes a directed energy source used
to heat web material and a stamper before they are pressed together
by a pair of nip rollers.
[0010] Although Kime is well regarded for what it teaches, when
increasingly higher density data devices are formed, a number of
factors not normally at issue arise. For example, the preset
inventors have found that unavoidable variation in web surface
texture and web thickness exist and can interfere with fine
microstructure reproduction. These variations result in locally,
non-uniform contact pressure between the web and stamper. In a
process where the web is softened to form the microstructures,
simply increasing the average contact pressure fails to adequately
solve this problem, as excessively high contact pressure may result
in a distorted image of the surface due to elastic rebound within
the web material after. pressure is removed. Stamper web relative
movement can also cause `smearing`. Smearing distorts the shape of
the data tracks and/or pits on a microscopic scale. These
distortions can interfere with tracking and can also increase
read-back error rates. Accordingly, there is a need for a method
and/or apparatus, which accommodates the negative effects produced
by variations in web surface texture and web thickness.
[0011] In order to accurately replicate stamper microstructure,
many have tried to keep the. stamper in contact with the web long
enough for the displaced polymer to relax and the substrate cool.
However, it was found by the present inventors that simply
increasing contact time is not an acceptable solution due to the
resultant increase in warp. As may be appreciated, a warped disk
produces significant read problems. Warp related problems become
even a greater problem with writeable disks, where the quality of
the recording can be degraded and compounds the detrimental
influence of warp during read-back. Accordingly, there is a need
for a continuous method for producing optical memory and/or
apparatus which limits warp during substrate formation.
SUMMARY OF THE INVENTION
[0012] In response to the foregoing issues, the present invention
provides a method and/or apparatus for the continuous manufacturing
of optical memory or optical memory substrates, and/or optical
disks which includes supplying a web of material to a substrate
forming apparatus.
[0013] In one aspect of the present invention there is provided a
method for forming polymeric material by limiting the thermal load
to the web.
[0014] In another aspect of the present invention there is provided
a method for forming polymeric material by melt forming
microstructures on the surface of a web of material.
[0015] In another aspect of the present invention there is provided
a method of forming microstructures on the surface of polymeric
material with an inductively heated stamper.
[0016] In another aspect of the present invention there is provided
a method of forming microstructures on the surface of a web of
polymeric material by providing a web of polymeric material with a
surface having a flow enhancer; and forming microstructures on the
surface of the polymeric material with a heated stamper.
[0017] In another aspect of the present, invention there is
provided a method of making a stamper for use in a continuous web
forming process which includes providing a stamper with a
transferable image; curving the stamper; and increasing the
thickness of the stamper after it is curved.
[0018] In another aspect of the present invention there is provided
a method of forming polymeric material by providing a stamper with
limited thermal expansion/contraction during web formation. In a
preferred aspect hereof, the stamper has a lower coefficient of
thermal expansion than nickel. In another preferred aspect hereof,
the stamper has a limited temperature change during contact with
the web.
[0019] In another aspect of the present invention there is provided
an apparatus for forming microstructures on the surface of
polymeric material which includes:
[0020] a web feed; a device for web forming, the device for web
forming having a stamper and a set of nip rollers which form a nip
zone in communication with the web feed, the stamper being carried
by a support that is detached from the nip rollers.
[0021] In another aspect of the present invention there is provided
an apparatus for use in making optical memory which includes: a web
feed; a stamper for forming polymeric material, the stamper being
carried on a loop and in communication with the web feed; a web
cutter for sectioning web material after forming; and a collector
for accumulating for sections of web material after cutting.
[0022] In another aspect of the present invention there is provided
a method of forming microstructures on the surface of polymeric
material for use in optical memory which includes the steps of:
providing a roll of polymeric web material with a removable layer
of softer material; and forming the web with a heated stamper; and
re-rolling the formed polymeric material.
[0023] In another aspect of the present invention there is provided
an apparatus for use in making optical memory which includes: a web
feed; a stamper for forming polymeric material, the stamper being
carried on a loop and in communication with the web feed; a web
cutter for segmenting web material after forming; an accumulator
for receiving sections of web material after cutting; an indexer
for making registration holes in sections of web material; a
masking station for covering sections of web material after
forming; and at least one coating applicator for applying thin film
to sections of web material after masking.
[0024] In another aspect of the present invention there is provided
a web sectioning station for use in making optical memory from a
continuous web process which includes: a platform for supporting
sections of formed web material; a plurality of optical positioning
sensors for centering the image of formed web material on a die
path; and a die for cutting web supported on the platform.
[0025] In another aspect of the present invention there is provided
a method of forming polymeric material for use in optical making
memory by providing a nip zone with enough compliance so as to take
into consideration variations in the surface and the thickness of
the web.
[0026] In another aspect of the present invention there is provided
a method of forming microstructures on the surface of polymeric
material for use in optical memory, which includes the steps of:
providing a web of polymeric material; providing a heated stamper;
and pressing the heated stamper and the substrate between a set of
nip rollers, wherein at least one of the nip rollers has a
compliant outer surface with a hardness of 80 shore D or less.
[0027] In another aspect of the present invention, there is
provided a system for making optical memory disks, which includes
one or more of the following: a coating(s) applicator(s), a web
cutting device(s), a cassette accumulating device, a web indexer, a
take-up roll, and other components which can produce a finished
optical memory disks or a partially finished disks.
[0028] In another aspect of the present invention there is provided
a method for coating embossed optical memory substrates by masking
sections of web material prior to coating.
BRIEF DESCRIPTION OF THE DRAWINGS
[0029] In order to assist in the understanding of the various
aspects of the present invention and various embodiments thereof,
reference is now be made to the appended drawings, in which like
reference numerals refer to like elements. The drawings are
exemplary only, and should not be construed as limiting the
invention.
[0030] FIG. 1 is a perspective view of an apparatus for forming web
material for use in optical memory in accordance with the present
invention;
[0031] FIG. 2 is a perspective view of another apparatus for
forming web material in accordance with the present invention;
[0032] FIG. 3 is a graphical view of a Time vs. Temperature profile
for web surface, melt forming in accordance with the present
invention.
[0033] FIG. 4 is a side, plan view of an apparatus for forming web
material in accordance with the present invention;
[0034] FIG. 5 is a side view of a continuous web, optical memory
production line in accordance with the present invention;
[0035] FIG. 6 is a side view of a system for coating optical memory
substrate in accordance with the present invention;
[0036] FIG. 7 is a side view of a system for finishing optical
memory in accordance with the present invention;
[0037] FIG. 8 is a perspective view of a system for finishing
optical memory production in accordance with the present
invention;
[0038] FIG. 9 is a side view of a system for holing web material in
accordance with the present invention;
[0039] FIG. 10 is a side view of a system for optical memory
production in accordance with the present invention;
[0040] FIG. 11 is a top, plan view of a system for finishing
optical memory by masking in accordance with the present
invention;
[0041] FIG. 12 is a side view of a system for coating web material
in accordance with the present invention;
[0042] FIG. 13 is a perspective view of a stamper surface and a web
surface after embossing in accordance with the present
invention.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
[0043] Reference is now made in more detail to the various aspects
and several embodiments of the present invention(s).
[0044] Referring now to FIG. 1, depicted therein is a device for
forming optical memory in accordance with the present invention.
The device includes a web payoff device, or simply a web payoff
(not shown), a web path in which web material 12 travels, and a web
forming apparatus disposed in the web path. The web forming
apparatus 10 includes a stamper 14. The stamper carries a
microstructure image for forming web. The stamper is carried by a
support 28 and may be heated by any suitable heating device 18
and/or may also be heated by a drum or roller 22 in thermal contact
with the stamper.
[0045] A pressure roller 20 and a backing roller 22 may be disposed
in the web path to press the stamper into the surface of web
material. The pressure roller and the backing roller form a nip
zone 16. As shown, the nip zone 16 includes the narrowest region
between the pressure roller 20 and the backing roller 22. In
practice though, the nip zone 16 may be provided by any means
suitable for pressing the stamper and the web material
together.
[0046] The stamper is any tool suitable for leaving an impression
in web material or optical memory substrate. The stamper is
preferably a disk shaped embossing tool, although in alternative
embodiments the stamper could have any shape, such an oblate disk,
oval, rectangle, triangle, irregular, etc. The stamper preferably
has fine features for producing microstructures in optical memory
substrates, such as grooves and/or pits. The fine features may
range from greater than several microns to 0.01 microns or less in
width, length and depth. FIG. 13 shows an AFM magnified perspective
view of a stamper surface having fine features and a web surface
which has been embossed with the hot stamper to incorporate the
fine features into the surface of optical quality web material.
[0047] The stamper is preferably formed of a rigid material that
can be heated to a peak process temperature while maintaining the
ability to both form a microstructure on the surface of the web and
to easily transfer energy to the interface between the stamper and
web of polymeric material upon contact. Representative stamper
materials include, nickel, chrome, cobalt, copper, iron, zinc,
etc., and various alloys of these metals. The stamper may be
composed of a single monolithic material, or of multiple layers of
the same material or of different materials. The stamper is
preferably comprised of a 0.1 to 1.0 mm thick plate of material,
and is more preferably is comprised of an approximately 0.3
mm.+-.0.1 mm thick plate of material. As shown in FIG. 1, the
stamper is flat. It is also appreciated that in alternative
embodiments, the stamper may be curved. A curved stamper allows the
stamper to easily travel a curved path, such as a repeating loop on
a drum, which is particularly useful for a continuous process.
[0048] In a preferred embodiment of the present invention, a curved
stamper is preferentially formed to reduce elliptical image
distortion. It has been found that simply bending a flat stamper to
the shape of a carrier or drum can introduce elliptical distortion
along the direction of curvature. The amount of ellipticity is
related to the radius of curvature (for example, the radius of the
drum or path of travel) and the thickness of the stamper at the
time it is curved. It has also been found that stretching,
compressing-and/or elastically displacing the web material
introduces image distortion which must be compensated for. A useful
stamper preferably has micro-structural images with optimally
compensating distortion so that the stamper is suitable for use in
making optical memory disks. A curved stamper with optimally
compensating distortion may be made by any suitable method, such as
by altering the initial shape of the image and then forming the
altered image on a curved stamper. However, to take advantage of
current production systems for making flat stampers, a curved
stamper is preferably made by imaging the optimally compensating
microstructure pattern on a thin, flat stamper, then curving the
stamper. After the stamper is curved, the thickness of the stamper
is increased to bring the curved stamper to the desired thickness.
By curving and then increasing the thickness of the curved stamper,
the stamper may be preferentially formed to optimize image
pre-distortion when used with a curved carrier while still meeting
the necessary thermal and mechanical requirements. For example, an
optimally compensating microstructure pattern is formed on a
relatively thin workpiece (such as 0.1 mm or less in thickness).
The relatively thin work piece is then curved to a desired radius
of curvature (such as 1-10 inches and more preferably 1-5 inches)
and then built up to the desired stamper thickness. The thickness
of the curved stamper may be built-up by any suitable method, such
as plating, bonding, soldering, coating, etc. The final stamper
thickness is preferably 0.2 mm or greater and more preferably about
0.3 mm. The stamper thickness is preferably built-up on the back of
the stamper, e.g. the side opposite the microstructure side.
Forming the work piece to the shape of the curved carrier while it
is relatively thin directly reduces undesired bending distortion on
the image side of the stamper surface. Subsequent material addition
to the rear surface of the pre-curved stamper permits mechanical
and thermal characteristics to be changed without concern about
excessive bending distortion. Additionally, in embodiments where
the stamper is formed to be used with a curved carrier, a layered
construction may additional provide other benefits, such as reduced
distortion of the stamper upon heating and cooling or by changing
the blank side to influence the lubricity of the stamper/drum
interface as discussed in more detail herein below.
[0049] It has been found that image `smearing` can occur from a
differential motion between the stamper and the web during
embossing. The present invention addresses problems, such as
smearing, by providing a continuous web process for making optical
memory, which includes a web forming apparatus adapted for reduced
dimensional variation at the stamper/web interface. Although pure
monolithic nickel stampers may work in conjunction with one or more
of the embodiments of the present invention, it has been found that
pure monolithic nickel stampers do not necessarily have optimum
thermal expansion/contraction characteristics. Further, heat
transfer from the stamper to other components of the web forming
apparatus can have an impact on stamper contraction. Therefore, a
preferred web forming apparatus provides limited thermal
contraction of the stamper during contact with the web. In a
preferred embodiment hereof, the web forming apparatus is adapted
to provide less than 0.5%, more preferably less than 0.1% and more
preferably less than 0.01% stamper contraction during web
contact.
[0050] In a preferred embodiment hereof, stamper dimensional
variation is limited by providing the stamper with a coefficient of
thermal expansion (and contraction) substantially matched to the
thermal response of the stamper/web interface. In certain
circumstances, particularly when a very hot stamper is contacted to
a cooler web or cooler press, the contact can cause the hot stamper
to cool quickly and contract. The contraction is so great that
image distortion can occur. By adjusting the thermal
expansion/contraction properties of the stamper, reduced
stamper/web differential motion upon stamper contact can be
provided to improve image formation. In accordance with a preferred
embodiment hereof, the stamper has a thermal contraction less than
that of pure nickel or that of conventional nickel stampers.
Thermal expansion/contraction is preferably less than 1%, more
preferably less than 0.1% and more preferably less than 0.01% over
web contact. Reduced thermal expansion and/or contraction may be
provided by any suitable means, such as by forming the stamper from
a material having a low coefficient of thermal expansion, or by
forming the stamper as a multi-layered structure, etc. Reduced
thermal expansion may be provided by making the stamper from an
alloy, a ceramic, or coating the stamper with a different material
having a low coefficient of thermal expansion. For example, a
stamper may be made by coating a conventional nickel stamper with
another metal, a metal alloy or a ceramic having a lower
coefficient of thermal expansion. By selecting materials with a low
coefficient of thermal expansion, a stamper with substantially no
measurable relative contraction during web contact can be
provided.
[0051] In another embodiment hereof, stamper dimensional variation
may be reduced by limiting heat loss from the stamper to components
of the web forming apparatus or the web or both. Heat loss may be
limited in a number of ways including: providing a bias heat to the
stamper backing roller; insulating the stamper from press
components; and reducing the stamper contact time with the web.
Particularly when the stamper is independently heated from the
press or backing roller, heat can be drawn from the stamper into
the backing roller to cause contraction of the stamper. By
providing a bias heat to the stamper backing roller, heat transfer
from the stamper can be limited to reduced thermal contraction of
the stamper. Alternatively or additionally, the stamper may be
thermally insulated from the backing roller. The stamper may be
thermally insulated from the backing roller by any suitable means,
such as coating the stamper with an insulator, coating the backing
roller with an insulator, etc. Preferably heat loss from the
stamper to the stamper backing roller is less than 50%, more
preferably less than 10%, and more preferably to less than 1%.
[0052] It has been found that by decreasing the time of contact
between the heated stamper and the web, reduced dimensional
variation can be achieved by limiting heat loss from the bulk of
the stamper. The decrease in stamper temperature or stamper bulk
temperature is preferably 50.degree. C. or less, more preferably
25.degree. C. or less and more preferably 10.degree. C. or less.
Decreased contact time may be effected by increasing the speed of
the web and/or increasing the speed of the loop on which the
stamper is carried. However, it may be beneficial to also increase
the amount of heat carried by the stamper when increasing speed so
as to carry enough energy to melt flow the surface of the web as
desired. The longitudinal (web motion direction) contact of the web
with the stamper in the nip zone is preferably short in both length
and time. The web preferably travels at a rate of 3 to 30 inches
per second. The contact time between the stamper and the web is
preferably 300 milliseconds or less, and more preferably 20
milliseconds or less. The contact time is most preferably 10
milliseconds or less, but is preferably greater than 0.5
millisecond. Particularly when the stamper and web are pressed
together in a nip or nip zone, the length of longitudinal contact
is preferably 20 mm or less, and more preferably 5 mm or less. By
limiting contact (such as the length and/or time) of the web and
the stamper, reduced substrate warp may be realized.
[0053] The stamper can be carried through the nip zone by any
suitable means. Referring again to FIG. 1, the stamper 14 is
carried through the nip zone 16 by a support 28. The support may be
a web, sheet, chain, belt, pallets, "ferris wheel configuration" ,
carriage, hoop, rails, drum, roll, etc. The support 28 is
preferably a closed loop for repeatedly passing the stamper 14
through the nip zone 16. As shown in FIG. 1, the support 28 is a
flat sheet. In alternative embodiments, such as those shown in
FIGS. 2 and 4, the support 28 may be a carriage.
[0054] The stamper may be compressed against the web by any
suitable press or pressing device. The device for pressing is
preferably a set of rollers which form a pinch point or nip. The
press preferably delivers a pressure of 500 PLI (pounds per lineal
inch) or less to the stamper/web contact zone. The nipping pressure
is preferably in the range of 50 PLI to 300 PLI.
[0055] As shown in FIGS. 1, 2, and 4, the pressure roller 20 and
the backing roller 22 provide a nip zone 16 for pressing the
stamper and the web together. Particularly where the stamper and
web are pressed together by a rounded press such as drums, the
length of longitudinal contact is preferably 20 mm or less, more
preferably 5 mm or less and more preferably 1-2 mm. The pressure
roller 20 and the backing roller 22 are preferably drums or rollers
constructed of rigid material, such as metals, alloys, ceramics,
etc. The pressure roller 20 and the backing roller 22 preferably
have a smooth finish. In a preferred embodiment, the backing roller
22 is coated with a material selected to effect an influence upon
the time/temperature profile of the stamper/web interface (as
described above) and/or to influence the lubricity of the
stamper/drum interface, and/or to provide a compliant surface.(as
described below). The characteristics of the backing roller should
prevent debris generation when contacting the stamper.
Representative coating materials include chrome, cobalt, nickel,
iron, steel, stainless steel, molybdenum, titanium, zirconium,
zirconium oxide, silicon nitride, titanium nitride, synthetic
diamond (DLC), Teflon or a Teflon filled matrix of the above or
similar materials. The pressure roller 20 and the backing roller 22
are preferably rotatable. The rollers may be free rolling or may be
rotated by one or more drives 24 and 26. The drives 24 and 26 are
preferably independent of each other. If the backing roller 22 is
heated with a bias temperature, it is preferably operated cooler
than the peak process temperature achieved at the web/stamper
interface side of the stamper 14. By actively controlling the
temperature of the backing roller, improved microstructure
reproduction may be achieved by limiting the heat transfer from the
stamper to the backing roller.
[0056] A preferred method of forming web with a stamper and a set
of nip rollers includes balancing stamper bending distortion
against web stretching distortion by increasing nip pressure to
counteract down-web stamper bending distortion and decreasing nip
pressure to counteract cross-web or web displacement distortion.
For example, a 55 shore D nipping roller is used with an 8" nip
drum having a curved stamper. By varying the nipping force between
600 and 900 lbs, one can balance ellipticity between cross-web and
down-web to improve image quality.
[0057] Although the apparatus disclosed herein may have wide
application in forming web material of all kinds, the web material
is preferably a polymeric material of suitable optical, mechanical
and thermal properties for making optical memory disks. Preferably,
the web material is a thermoplastic polymer, such as polycarbonate,
poly methyl methacrylate, polyolefin, polyester, poly vinyl
chloride, polysulfone, cellulosic substances, etc. The web material
preferably has a refractive index suitable for use in optical
memory disks (for example, 1.45 to 1.65). The web thickness is
preferably about 0.05 mm to about 1.2 mm, depending upon the
intended application. The web 12 is preferably wide enough for
replicating one, two, three, four, or more images across the web.
The web material may contain one or more additives, such as
antioxidants, UV absorbers, UV stabilizers, fluorescent or
absorbing dyes, anti-static additives, release agents, fillers,
plasticizers, softening agents, surface flow enhancers, etc. The
web material is preferably a prefabricated roll formed "off-line",
which may be supplied to the substrate forming apparatus at ambient
temperature or may be supplied to the system at ambient
temperature. Supplying the web material in the form of a roll to
the system at ambient temperature allows for greater process
flexibility and efficiency.
[0058] To form an impression, the stamper is heated with a heater
before contacting the web. The heater may be any suitable heating
device, such as a directed energy source, inductive heating source,
conductive heating source, radiating heating source, etc., or any
combination or equivalent. The stamper is, preferably,
independently heated from the other elements of the system,
including the nip, web, rollers, etc. The stamper is preferably
heated just before it is carried to the nip zone. Preferably, the
backing drum is also heated.
[0059] Heating is preferably supplied by an induction heating coil
that produces direct resistive heating of the stamper. The
induction heating coil is preferably made with a conductive
material, such as copper, aluminum, silver, etc. The induction
heating coil may be comprised of a series of contoured conductors
which are coupled to a suitable source of energy. The induction
heating coil is preferably water cooled. The induction heating coil
is preferably placed adjacent to the stamper so as to generate
resistive heating in the stamper when the induction heating coil is
energized. The induction heating coil is preferably placed within 1
mm to 50 mm of the stamper. As the stamper is heated by the
induction heating coil it can be raised to a temperature sufficient
to melt flow the surface of the web. The amount and uniformity of
coupling to the stamper can be selected by adjusting the size and
geometry of the induction coil; by appropriately selecting the
materials of the stamper; and by changing the distance between the
stamper and the induction heating coil. As shown in the FIGS. 1, 2
and 4, the induction heating coil 18 is disposed up-stream from the
replication zone and adjacent to the path of the stamper.
[0060] During embossing, web warp can result from excessive
shrinkage and/or sub-surface annealing of the web material. Even
minor amounts of substrate warp can be problematic for optical
memory devices. The present invention contemplates several methods
for reducing the likelihood of warp. These methods include one or
more of the following: controlling the stamper/web interface
temperature vs. time relationship as the web moves through the nip
zone, shortening the total processing time at a temperature above
the glass transition temperature, Tg, and/or limiting the depth to
which the web is heated above Tg. Web warp may also be reduced by
altering the web wrap angle, and/or additionally heating the web on
both sides. Each of these methods may be used separately of in
combination to improve replica image formation and to reduce
warp.
[0061] In accordance with the present invention, there is provided
a method of forming polymeric web substrates by melt flowing the
surface of the web. Melt flow formation is a process wherein the
surface of the web material is heated to a melt, displaced and then
allowed to stabilize. As may be noted, forming polymeric substrates
by interface surface melt flow is different than traditional
compression relaxation methods. In melt flow, as the stamper
impinges upon the web, the surface of the web is heated to such a
degree that the material melts and locally flows. The combination
of material displacement and local flow allows the web surface to
rapidly and accurately conform to the shape of the microstructure
pattern on the stamper. Before stamper separation occurs, the web
surface is allowed to stabilize. In comparison, compression
relaxation processes use force to distort and displace material for
a time, at a temp below the melting or flow temp, that allows for
relaxation of the strain generated in the web by the compressive
forces. By using melt flow formation, instead of compression
relaxation, the time needed for image formation can be greatly
shorted so as to limit bulk heating of the web.
[0062] In a preferred embodiment of a method for melt flow
formation, the surface of the stamper is provided at melt flow
temperature (Tf) or above. Momentarily raising the stamper/web
interface temperature to Tf or above allows rapid, stress free
formation of the web surface to the shape of the microstructures of
the stamper. While the stamper/web interface should be hot enough
to cause the surface of the web to melt and flow, it should not be
so hot that the entire cross section of the web is melted. The web
is preferably melt flowed from the interface surface down to a
depth of 0.2 mm or less, more preferably down to a depth of 0.1 mm
or less, more preferably still down to a depth of 0.05 mm or less,
and most preferably down to a depth of 1 .mu.m or less. Limiting
the process thermal penetration depth to a minimum, such as to the
depth of the structures being formed, can minimize sub-surface
displacement and subsurface annealing of the material to reduce
distortion and warp.
[0063] The melt flow time/temperature profile may be provided in a
number of ways, including balancing stamper peak temperature with
stamper thermal properties, adjusting the initial temperature and
thermal response of the web, adjusting the initial temperature and
thermal response of the stamper/web interface, and/or altering the
thermal characteristics of the rollers that form the nip zone. FIG.
3 exemplifies a time/temperature profile of a method of melt
forming in accordance with a preferred embodiment of the present
invention. As shown, the temperature of the web surface (y-axis)
during embossing is taken over time (x-axis). Within the contact
time, the temperature of the web surface is ramped from near
ambient or Tcold (point A of the graph) to at or above Tf (point B
of the graph) and is then [quickly] cooled to stabilize the image
before the stamper separates from the web. Alternatively, the web
may be preheated to above ambient, or to even above Tg before
contacting the stamper to the web. Preferably the web surface
temperature is dropped to Tf or below before the stamper separates
from the web (shown by point C of the graph).
[0064] The stamper is preferably separated from the web at an
interface temperature below the melt-flow temperature of the web
(e.g. at a temperature less than Tf). It should be generally noted
that interface cooling rate may be affected by a number of
conditions, including: thermal conduction into the web, the thermal
characteristics of the web/stamper interface, thermal conductivity
of the stamper, supplying one or more insulating layers, and by
active interface temperature control. The stamper is preferably
separated at a temperature higher than the glass transition
temperature Tg. Due to the low formation stress associated with
melt forming, the processed surface of the web is able to maintain
its microstructure after separating from the stamper while
continuing to cool.
[0065] Although not desiring to be bound by theory, polymer
response to a displacing force involves a viscous component and an
elastic component. At Tf the viscous component dominates, and at
Tcold (a temperature below Tg) the elastic component dominates.
Above Tg (the glass transition temperature) a transition occurs
where the increase in free volume allows rotational or
translational molecular motion to take place. This freedom allows
molecules to move past one another, causing viscous behavior to
become more dominant. Embossing polymeric material at Ts or Tsoft
(a temperature below Tf but above Tg) requires substantial
relaxation of strain before stamper separation. In comparison,
various embodiments of the present invention contemplate embossing
the disk substrate at Tf or above, and cooling the stamper/web
laminate to below Tf, but not necessarily below Tg, before
separation. The optimum temperature points reached in various
embodiments of the present invention permit the microstructures in
the web to stabilize sufficiently after separation so as to hold
their shape, while at the same time avoiding microscopic and
macroscopic distortion related to stamper shrinkage. The melt
forming process of the present invention tends to eliminate polymer
relaxation time constraints associated with traditional "hot
embossing" by providing a low viscosity interface at the stamper.
Melt forming also improves process tolerance to web thickness and
texture variation by reforming the surface. Melt forming can also
take advantage of the increased surface mobility and rapid
re-stabilization of the surface before stamper/web separation. By
controlling the time/temperature profile of the stamper/web
interface, microstructures on the stamper may be transferred to the
web with reduced defects, such as micro-smearing, track shape
distortion, and warp. An additional benefit derived from a short
time/high temperature thermal profile is a limited thermal
penetration depth into the web material. A limited thermal
penetration can aid in reducing sub-surface annealing of the
polymer which has been found to be a contributor to total warp.
Faster melt forming can lower the overall thermal load delivered to
the web. A lowered thermal load can reduce the depth of thermal
penetration. While it is possible to reduce average thermal
exposure by modifying the shape of the time/temperature profile to
achieve extremely high peak temperature at the surface followed by
a rapid cooling, this approach may have a practical limit imposed
by the instability of certain polymers to excessively high peak
temperature.
[0066] Although a wide range of temperature vs. time profiles can
be achieved through the appropriate selection of materials,
excessively high peak temperature is still undesirable. It has been
found that melt flow formation may be more easily provided if the
difference between Tf and Tg can be temporarily reduced without
compromising the bulk physical properties of the web polymer.
Applicants have discovered that the selective application of a flow
enhancer to the surface of the web prior to melt forming may reduce
the required melt-forming peak temperature without compromising the
bulk physical properties of the web polymer. To accommodate
increasingly better flow dynamics without the undesired
consequences of over heating, it has been found that additives to
the web surface or surface region to temporarily enhance flow
characteristics may be used.
[0067] The web material is preferably provided with a flow
enhancer. The flow enhancer may be any material or composition
added to the web that provides enhanced flow characteristics over
the basic web material under melt-flow conditions. The flow
enhancer is preferably a substance that effectively decreases the
melt-flow temperature of the surface and/or is a substance that
increases the cooling rate of the surface. The flow enhancer is
preferably provided in an amount sufficient to reduce the dynamic
viscosity of the web at a.given temperature. Flow enhancer is
preferably provided at 0.1 to 1.0% by weight in the surface region
of the web. Accordingly, the web material preferably has at least
enough flow enhancer to lower Tf below reported values for dry or
flow enhancer free material and is preferably provided in an amount
sufficient to lower normal peak process temperature by 5% to 50%.
By providing an amount of flow enhancer sufficient to modify the
melt flow characteristics of the web, improved optical memory
quality microstructures can be produced by melt forming.
[0068] The flow enhancer is preferably provided on or in the web
surface down to a depth. The flow enhancer is preferably provided
to a depth of the features being produced or just below the
features being produced. The flow enhancer is preferably provided
to a depth of at least 0.003 .mu.m. The flow enhancer may be
provided throughout the entire cross-section of the web, but is
preferably provided to the top 50% or less, more preferably to the
top 10% or less. The flow enhancer is preferably provided from the
surface to a depth of 1 .mu.m, and more preferably provided from
the surface to a depth of 3 .mu.m. In a preferred application, only
the first 1.5 .mu.m of the surface region has flow enhancer.
[0069] Water has been found to be a particularly useful flow
enhancer. Not only has water been found to be an effective flow
enhancer, but water can beneficially alter the time/temperature
profile at the web/stamper interface by actively cooling the web
surface to create an impediment to continued heat transfer from the
stamper. Further, it is believed that water's high heat of
vaporization can enhance rapid cooling at the stamper/web interface
to reduce image stabilization time. Traditionally, water present in
web materials during hot embossing is highly problematic, as water
trapped in the web can vaporize and create gas bubbles. These
bubbles typically form at the interface between the web and
stamper, creating concave depressions in the web surface. These gas
bubbles in turn degrade the optical quality of the final product.
Typical solutions to the water problem have been to either remove
the water by drying the web or by processing the web at relatively
low temperatures (below Tg). The applicants have discovered that
the presence of water in the surface of the web during melt forming
can actually be beneficial, as the right amount of water can not
only improve the quality of the microstructures transferred to the
web, but can do so without the formation of water vapor bubbles.
Prevention of damaging water volatilization may be achieved by
providing a short process time with a shallow depth of thermal
penetration. Because the efficacy of the melt-forming process is
enhanced by the presence of water, peak process temperature can be
reduced. The reduction in peak temperature requirements further
reduces thermal penetration, thereby resulting in less warp. Water
is preferably provided in an amount of about 0.1 to 0.4 percent by
weight of web material. To provide a preferred amount of water in
the surface of the web, moisture may be added, removed, or both. In
some cases, the web may be dried prior to embossing. In other
instances, the web may be subjected to a water surface treatment
prior to embossing. In other cases, it may be necessary to surface
condition the web by first drying the web and then treating the
pre-dried web with water just prior to embossing.
[0070] It is also appreciated that although water is a preferred
substance, other flow enhancers may also be used. Other flow
enhancers, include plasticizers, resin emulsions, and release
agents that are applied to the surface or integrated with the
surface of the web in proper amounts. Preferred flow enhancers may
include one or more compounds selected from the chemical families
of fatty esters and fatty acids. A preferred flow enhancer includes
the fatty ester, pentaerythrithitol tetrastearate. The flow
enhancer may be supplied to the web by any suitable means, such as
dipping, coating, spray application, a fine mist, absorption,
immersion in a wetter augmented bath, vaporization chamber,
addition to the initial plastic resins, addition to the initial
extrusion raw materials, etc. The flow enhancer is preferably
applied in a way that provides an even coating of material on the
surface of the web material. Preferably the flow enhancer provides
properties suitable for temporarily lowering effective web Tf
during the melt-forming process, and/or, as a result of process
conditions, results in a permanent increase in web surface Tg.
[0071] To achieve preferred temperature profiles during web
formation, the rollers or drums that form the nip zone may be
adapted with thermal transfer properties sufficient to maintain
proper heating and cooling of the web/stamper interface, such as
active or passive heating or cooling. Referring to FIG. 4, the
rollers 20 and 22 may be thermally conductive and provided with an
outer layer 21 and an insulator layer 23 (respectively) which are
selected so that there is just enough thermal insulation to allow
the web surface to cool to below its melt flow temperature (Tf),
but not necessarily below its glass transition temperature (Tg), by
the time the stamper 14 separates from the web 12. If either the
outer layer 21 or the insulator layer 23 is overly insulating, the
web surface may not cool sufficiently to fully stabilize by the
time the stamper 14 is separated from the web, allowing the
microstructure to change shape. If the outer layer 21 or the
insulator layer 23 is under insulated, the stamper 14 may cool so
much that it shrinks before it comes out of contact with the web,
resulting in smearing of the microstructure and distortion of the
shape of the tracks.
[0072] In a preferred embodiment of a method for forming polymeric
web material, the web is also heated on the side opposite that
where microstructures are formed, e.g. on the `blank side`. Heating
on the `blank-side` of the web allows for counteracting residual
warping forces from post anneal cooling. Heat may be provided to
the blank side by any suitable heating device. Heat is preferably
provided by either radiant heat or may be provided to the web by a
heated roller configured to counteract the thermal penetration
depth resulting from stamper contact. The blank side of the web may
be heated prior to entering the process nip zone, such as by
radiant heat or conductive heat, or may be heated in the process
nip zone simultaneously with microstructure formation. The blank
side is preferably heated in an amount sufficient to balance
sub-surface annealing created on the stamper side. The blank side
may also be heated in the same way as the stamper is heated, such
as by induction heating. This approach may be extended to effect
the simultaneous melt forming of both sides of the web.
[0073] In practice, web material can be delivered to the nip zone
by any suitable web feed means. The means for feeding is preferably
a device suitable for continuously delivering web material to the
stamper along the web path, such as a sheet feed, folded material
feed, roll feed, web extruder, etc. The web feed is preferably a
roll feed, such as one shown at 300 in FIGS. 5 and 9 for feeding
pre-manufactured rolls of polymeric web material to the nip zone.
The-roll of polymeric web material preferably includes a removable
film or protective layer of material, such as a softer plastic film
layer on the web. By using web having a softer protective layer,
the web may be rolled, unrolled; and re-rolled with minimal to no
surface scratching, which could otherwise affect the use of the web
for optical memory devices.
[0074] The web feed may be complimented by a web take-up device,
such as a take-up roll, for collecting the web after processing or
after formation. Alternatively to using a take-up roll, the web may
be cut into sections after formation (such as described below) or
may be further processed into completed or partially completed
optical memory disks.
[0075] The web formation apparatus is preferably adapted to
accommodate variations in web tension so that the web is neither
over-taunt nor over-slacked. An over-taught web could result in the
web breaking while an over-slacked web could cause jamming or other
problems. Furthermore, tension control across the nip zone should
be controlled to reduce sub-surface material displacement and
ellipticity of the reproduced image. To accommodate variations in
web tension, the system may be provided with one or more tension
rollers. Tension rollers are generally known in material handling
operations and may be used to control web speed and tension.
[0076] Tension may be controlled across the nip zone, at the nip
in-feed, at the nip out-feed, and otherwise across the system.
Tension at the nip in-feed is preferably near 0 to neutral. The
system may also have one or more guide rollers (not shown) for
guiding the web in the web path, for altering the angle of the web
into and out of the nip zone and for changing direction of the web.
Preferably, there is at least one guide and/or tension roller for
directing the web into the process nip zone, and at least one guide
and/or tension roller used to direct the web out of the nip zone.
These guide and/or tension rollers may serve the additional purpose
of establishing the process nip zone in-feed and out-feed contact
and separation angle between the web and stamper. The guide roller
on the side exiting the nip zone preferably allows an initial
web/stamper separation angle of about 900.degree..+-.1.degree.. The
guide roller preferably guides the web away from the stamper
immediately after exiting the nip.
[0077] Referring to FIG. 1, 2, and 4, the heated stamper 14 is
carried into the nip zone 16 by a support 28. The stamper 14 is
preferably temporarily laminated to the web 12 as a result of free
float through the nip zone. The support 28 is preferably
independent of, or detached from, the nip rollers, 20 and 22, and
any components thereof. The independence of the support 28 may
allow the stamper 14 to substantially free float on the web 12 as
it becomes temporarily laminated thereto in the process nip zone
16. By laminating the stamper to the web with an independent
support, a stamper with more than one degree and more preferably
more than 2 degrees of freedom of movement may be realized. By
having more than one degree of freedom, the stamper 14 can better
accommodate and conform to roller pressure-induced distortions
within the web 12 during the melt forming process and more
completely accommodate web texture and thickness variations.
[0078] Referring now to FIG. 2, depicted therein is a web forming
system in accordance with a preferred embodiment of the present
invention which includes a web forming apparatus 10 having a
special support that decreases the angle in which the stamper
enters the nip zone 16. The system includes a web feed 42, a web
path 44 in communication with the web feed 42, and a nip or a nip
zone 16 disposed in the web path 44 and a stamper 14. The stamper
14 is carried by a set of "hoops" 118, 128 which forms the support
that follows the web path 44 through the nip zone 16 and carries
the stamper 14 between the pressure and backing rollers, 20 and 22.
The support is preferably detached from the pressure and backing
rollers, 20 and 22, and preferably results in the temporary
lamination of the stamper 14 to the surface of the web 12 in the
nip zone 16. As shown, the hoops form a carriage 114 for the
stamper to ride on. The carriage 114 provides means for
independently carrying the stamper through the nip zone 16. By
independently carrying the stamper 14 into and through the nip
zone, better thermal management of the process can be provided.
Additionally, by independently carrying the stamper 14 through the
nip zone, the stamper may be kept more nearly flat, thereby
reducing ellipticity caused by forming a curved stamper in the
shape of a small diameter carrier drum.
[0079] As shown, the carriage 114 is supported around the backing
roller 22 on a plurality of rollers 30, 32, 34. The rollers 30, 32,
34, permit free rotation of the rails 118, 128. The stamper 14 may
be connected between and supported by the rails 118, 128 by any
suitable means. The rails are preferably separated by a distance
equal to the width (cross web) of the backing roller 20 so that
only the stamper (as opposed to the rails) contacts the backing
roller during operation. The rails 118, 128 preferably have a
circumference substantially greater than that of the backing roller
22. The ratio of the circumference of the rails to the backing
roller is preferably at least 5:4, and more preferably a ratio of
about 13:8 or greater. Rails with a large circumference may aid in
keeping the stamper flatter through the nip zone 16.
[0080] In operation, the backing roller 22 engages the back of the
stamper 14 to guide the stamper into contact with the web 12 while
the pressure roller 20 presses the web into the front of the
stamper. The roller surfaces are preferably selected to provide the
necessary contact uniformity, to optimize nip zone dynamic shape
and to balance pressure distribution to minimize overall image
distortion. The pressure roller and/or the backing roller
preferably include compliant surfaces. A pressure roller and/or
backing roller with a compliant surface can provide a stamper with
enough flexibility so as to accommodate web thickness variations to
improve image formation. The compliant material is preferably
between 0.05 and 0.5 inches thick and more preferably approximately
0.125.+-.0.1 inches thick. The compliant material 21 is preferably
selected to have a hardness rating of less than 80 shore D and
preferably between 90 shore A and 60 shore D. The backing roller 22
may also include a layer of compliant material 23 which may be the
same as or different from (in thickness, compliance, resiliency,
lubricity, and/or heat transfer characteristics) the compliant
material of the pressure roller. If both rollers have compliant
surfaces, the surfaces are preferably adapted such that the
combined characteristics optimize pressure and heat transfer
uniformity without introducing pressure, shearing, and/or velocity
instabilities into the stamper/web laminate. Preferred compliant
materials include, but are not limited to, nitrile, EPDM, Kapton,
epoxides, filled epoxides, Teflon, and Teflon infused polymer,
metal or ceramic matrixes. It is also appreciated that any material
with compliance and heat transfer properties suitable for melt
forming an optical memory microstructure with less than .+-.0.8
degrees of radial deviation, and less than .+-.0.3 degrees of
tangential deviation may be used.
[0081] With reference to FIG. 5, a preferred embodiment of a system
for manufacturing optical memory media 200 is shown. The system 200
includes a web pay-off 300, web material forming apparatus 10, a
coating(s) applicator 400, a web cutting device 500, and a cassette
loading or accumulating device 600. The system 200 may be used to
process a continuous web 12 of material to produce finished optical
memory storage media, such as optical disks.
[0082] As shown in FIG. 5, a roll 310 of web material 12 is
provided by a web pay-off device 300. The web material 12 may be of
any width and thickness that is useful for manufacturing optical
memory substrates. The roll 310 may be interchangeably mounted on a
reel 320 contained in the pay-off device 300. The web material 12
dispensed from the roll 310 may be run through one or more
guide/tension rollers 330 to the forming apparatus 10.
[0083] As various embodiments of substrate forming apparatus have
been discussed previously, it is appreciated that any of the
embodiments of web forming apparatus, which have been previously
discussed, could be used with the system 200 described herein. The
forming apparatus 10 receives web material from the web pay-off
device 300. The disk substrate forming apparatus 10 is used to form
a pattern of microstructures into the web material. After the
microstructures are formed in the web material, the material may be
further processed to more fully complete the manufacture of an
optical memory device. To process the web material further, the
material may be sent to a coating application 400.
[0084] Various coatings may be applied to the web material in
either a continuous manner, such as to the web before sectioning
into strips of web material, or after sectioning by batch. The
coating applicator 400 may include one or more coating units 410,
412, etc., used to apply coatings to the web 12. The coating units
may be capable of maintaining a vacuum surrounding the web 12 and
applying a coating using a one or more coating processes, such as
CVD, PVD, PCVD, PECVD, PML, LML, sputtering, or other deposition
process.
[0085] Table 1 below identifies example processes, coatings, and
coating thickness that may be used to form desired coatings on
phase change, optical memory substrates.
1TABLE 1 Coating Step Process Coating Thickness (nm) 1 Microwave
PECVD Dielectric anti-reflective 60-150 2 Sputter Chalcogenide
20-25 3 Microwave PECVD Dielectric 20-25 4 Sputter Aluminum 60-150
5 PML/LML Acrylate 5,000-7,000
[0086] A coating unit 410 may be used to apply a dielectric
anti-reflective coating in the range of aproximately 500 to 2000
angstroms thick and more preferably in the range of 60 to 150
nanometers thick. The dielectric coating may be comprised of any
suitable material such as silicon dioxide, silicon nitride,
titanium oxide, zinc sulfide, silicon oxide, germanium nitride,
geranium oxide, silica, alumina, combinations of the above, and the
like. Preferably, the dielectric anti-reflective coating has an
index of refraction of about 2.2. For this reason, silicon nitrite,
which can be deposited with an index of refraction of about 1.9,
and titanium oxide, which can be deposited with an index of
refraction of about 2.3, may be preferred.
[0087] Although any type of deposition process may be used to apply
the dielectric anti-reflective layer, in a preferred embodiment,
microwave PECVD process is used. Examples of microwave PECVD
processes and systems that may be used for coating include those
disclosed in U.S. Pat. Nos. 5,411,591; 5,562,776; 5,567,241;
5,670,224; 6,186,090; and 6,209,482, the disclosure of each of
which is incorporated by reference herein. Microwave PECVD
processes such as those disclosed in the above-referenced patents
may be preferred over other deposition techniques because of the
speed at which the deposition can be carried out. An increase in
deposition rates may also allow a reduction in the overall length
of the deposition chamber required for coating. Reduction in the
deposition chamber length can greatly decrease the costs associated
with the deposition process.
[0088] A memory layer coating unit 412 may be used to apply a phase
change memory material coating. The memory material coating
preferably includes a chalcogenide alloy in the range of
approximately 4 to 30 nanometers thick, and more preferably
approximately 20 to 25 nanometers thick. Although any type of
deposition process may be used to apply the chalcogenide alloy
coating, in a preferred embodiment it is sputtered onto the web
12.
[0089] A second dielectric coating unit 414 may be used to apply a
second dielectric coating in the range of approximately 150 to 2000
angstroms thick, and more preferably approximately 20-25 nanometers
thick. Suitable dielectric materials include those described above.
Although any type of deposition process may be used to apply the
second dielectric layer, in a preferred embodiment, a microwave
PECVD process is used.
[0090] A coating unit 416 for depositing a reflective or heat
dissipation material may be used to apply a thin layer of a metal,
such as aluminum or the like, in the range of approximately 1 to
1000 nanometers thick, and more preferably approximately 60 to 150
nanometers thick to the substrate. Although any type of deposition
process may be used to apply any suitable material coating, in a
preferred embodiment the reflective or heat dissipating layer is
sputtered or evaporated onto the web 12.
[0091] A coating unit 418 may be used to apply a protective
coating. The protective coating is preferably 1,000 to 7,000
nanometers thick. The protective coating may be formed of any
suitable, optically transparent material, such as a thermosetting
resin, uv resin, acrylate, etc. In a preferred embodiment, a
Polymer Multi-Layer or Liquid Multi-Layer (PML/LML) process is used
to provide the acrylate coating. A PML process involves the vacuum
flash evaporation of monomer fluids to produce a liquid film
condensate, which is then radiation cross-linked to form a solid
film. A LML process involves the vacuum coating of the monomer
liquid directly onto the substrate by means such as extrusion,
gravure rollers, spraying, etc., and subsequently radiation cross
linking monomers in the thin liquid coating. LML processes may
require coatings in excess of 10 micrometers, and accordingly, PML
may be preferred for the formation of an acrylate coating.
[0092] Isolation of the vacuum deposition chambers of each of the
coating units 410, 418, etc., from each other, from web formation,
and from the payoff devices, may be achieved by any suitable
isolation device, such as gas gates, etc.
[0093] The materials for and thickness of the two dielectric
coatings should be chosen carefully to fulfill several functions in
the finished optical disk. These dielectric coatings may protect
the phase change coating from exposure to oxygen or water vapor,
which could oxidize the phase change material and alter its
properties. The dielectric coatings may also be used to provide
good contrast and to aid the laser beam that is used to "write" on
the disk to be absorbed primarily in the phase change coating. The
dielectric layers may also affect the thermal characteristics of
the optical disk. The second dielectric coating between the phase
change coating and the aluminum coating is selected to be thermally
conductive enough to prevent overheating the laser targeted areas
of the phase change coating, but not so thermally conductive as to
provide excessive heat loss to the aluminum coating. Finally, the
dielectric coatings provide rigid supports for the phase change
material sandwiched between them when it is heated by a laser.
[0094] It is appreciated that the above-referenced microwave PECVD
processes for the application of the dielectric coatings may cause
build up of dielectric material on the lens that isolates the
microwave source from the PECVD chamber. In order to facilitate
continuous web processing, an innovative method that effectively
replaces the lens on a continuous basis has been developed.
[0095] With reference to FIG. 6, a web 12 of material used to
produce optical disks is coated with material in a deposition
chamber 440 of a coating unit 410. The deposition chamber 440
includes an aperture 442. A reel-to-reel web of polyester 420, or
other flexible, microwave transparent material, may be used to
shield the lens between the microwave source 430 and the deposition
chamber 440. The microwave transparent web may be continuously or
intermittently drawn from a first reel 422, past the aperture 442,
and onto a second reel 424. Opposing rollers 426, or other means,
may be provided to create a seal at the intersection of the
aperture 442 and the polyester web 420. The polyester web 420 may
be repeatedly wound back and forth past the aperture 442 during
PECVD operation until the build up of material (such as dielectric
coating material) on the surface 421 mandates its replacement. Use
of the polyester web 420 to provide the microwave "window" into the
deposition chamber 440 may greatly increase the life of the
window.
[0096] The foregoing discussion of the coatings that may be used to
produce a phase change optical memory storage device is intended to
be exemplary only. It is appreciated that the coating system may be
used to apply any number of different coatings, in different
orders, and different thicknesses, in order to produce a wide
variety of optical memory storage devices, such as those discussed
in the background section of this application. Accordingly, the
detailed discussion of phase change memory devices should not limit
the scope of the present application.
[0097] Again with reference to FIG. 5, after coating, the web 12
exits the coating applicator 400 and enters a web cutting or
sectioning device 500. The web cutting device 500 may be any device
suitable for separating web into sections or strips 510 that are
some multiple of disks, such as one or more in length or width. The
web cutting device may include a rotary cutter for sectioning the
web. The web cutting device may also include a system for removing
dust or debris produced by the cutter, such as ionized air and
vacuum.
[0098] After the strips 510 are formed they may be collected or
accumulated into bins or removable cassettes 610 with an
accumulating device 600. By collecting disks into an accumulator,
line speed can be increased and by collecting sections of web in
removable cassettes, sections of web can be finished either offline
or on multiple lines. Disk finishing may also be done directly from
the web or from a continuous roll of embossed and coated
material.
[0099] Disk finishing requires precise formation of the outer
(outer diameter, o.d.) and center portions (inner diameter, i.d.)
of the replicated substrate and disk microstructure. Disk finishing
may include any of a wide variety of operations, such as punching,
cutting, milling, or other means of forming the i.d. and o.d. of
disks.
[0100] With reference to FIG. 7, shown therein is a disk finishing
system 800 in accordance with a preferred embodiment of present
invention. The disk finishing system may be adapted for accepting
strips 510 from the accumulator 610. At the initiation of the disk
finishing system, strips 510 of web can be unloaded from cassettes
onto a conveyor. The strips may be conveyed to a rough cut or
squaring station 820. At the squaring station, the strips 510 can
be cut into smaller shapes, such as squares 822 that contain only a
single disk microstructure. After the strips 510 are cut into
squares 822, the squares may then be conveyed to a separator ring
embossing station 830, where an elevated ridge of substrate
material (i.e., a disk separator ring) may be formed. The separator
ring allows stacked disks to be easily separated when stacked
together and prevents scuffing damage to the microstructure. After
formation of the separator ring on the disk substrates, each may be
sent to center hole punching or blanking station 840 and then to a
scrap (material outside of the disk) removal station 850. After the
center hole and the scrap around the disk are removed, the
individual, semi-finished disks may be stacked at a stacking
station 852.
[0101] With reference to FIG. 8, depicted therein is a preferred
web sectioning station which may include a device 842 for centering
the microstructure pattern of a disk substrate. The device 842 may
include a table or platform 844 that is disposed above the web 12
on which the disk substrate microstructure pattern 13 has been
formed. The table 844 may be selectively translatable in the x and
y directions by a motorized assembly (not shown). Optical sensors
846 may be supported by the table and directed orthogonally toward
the web 12. The optical sensors 846 may provide detection signals
to a control unit 848. The detection signals received by the
control unit 848 may be used to control centering and translation
of the table 844. The table 844 is translated so that each of the
optical sensors 846 is located directly above the edge of the
microstructure pattern 13 on the disk substrate. Once the table 844
is centered above the microstructure pattern, a punch unit 860
carried in the center of the table 844 may be used to form the
center hole (i.d.) and/or (o.d.) of the memory device.
[0102] A preferred embodiment of a punch unit is shown in FIG. 9 at
860. The punch unit 860 may include a staged center die 862, a
silicone pad 864, a spring 866, and a die button 868. The die may
be constructed of any suitable material. The die may include one or
more stages. Preferably, each stage has a depth suitable for
cleanly piercing polymeric substrate. The spring 866 may be
disposed to bias the pad downward to clamp the web 12 between the
pad 864 and the die button 868. The staged center die 862 may then
be pressed down through the web 12 to form a center hole therein.
The stages formed in the center die 862 can reduce the likelihood
of forming a center hole with a jagged or irregular edge.
[0103] Referring now to FIG. 10 is an alternative embodiment of a
system for forming optical memory 200, in which like reference
numerals refer to like elements shown in the other drawing figures.
As shown in FIG. 10, the web pay-off device 300 may include a
splicing unit 340 for providing continuous web pay off from
multiple rolls 310 of web material.
[0104] The system, as exemplified by FIG. 10 may be particularly
useful for the production of optical substrates for DVDs. As noted
previously, DVDs are produced by joining two disks together. The
surface of the information carrying disk that is bonded to the
opposing disk is the same surface that may have one or more
coatings applied to it. The coatings, however, are not conducive to
the formation of a mechanically robust, hermetically sealed bond
between the information carrying disk and the opposing disk.
Accordingly, there is a need to leave portions of the information
carrying disk, namely the outer edge of the perimeter and the inner
perimeter, uncoated. As such, a system for masking portions of the
substrates before coating may be used to form disk substrates with
uncoated outer and inner regions which are useful in bonded memory
devices.
[0105] In accordance with a preferred embodiment of the system for
masking portions of the substrates before coating, there may be
provided an indexing system so that edges of memory devices can be
accurately formed. Substrate indexing may be provided by one or
more pre-punch and post punch stations, items 900 and 950 of FIG.
10, respectively. Indexing allows accurate disk removal,
accumulating and coating of web material.
[0106] For example, FIG. 11, shows a disk substrate 13 at various
stages of formation, A, B, C, and D, representing the evolution of
the disk substrate as it passes through various processing
stations. At stage A, the pre-punch station 900 (FIG. 10) may put a
center hole 15 and one or more registration holes 17 in the web.
The center hole 15 may be formed by any means, such as a punch unit
as shown in FIG. 9, by melting, drilling, cutting, etc. The center
hole 15 may have a diameter that is the same as or less than the
final center hole in a finished optical disk. If the diameter of
the center hole 15 is less than that required for a finished
optical disk, it may be enlarged at a later processing stage. Like
the center hole 15, the registration holes 17 may be formed by any
means, such as a sprocket punch. The registration holes may or may
not extend entirely through the web 12. Preferably, the center hole
15 is precisely equidistant from each of the registration holes 17
so that the relationship of the registration holes to the center
hole is known.
[0107] With continued reference to stage A, after the center hole
15 and the registration holes 17 are formed in the web 12, the web
passes to the web forming apparatus 10. The forming apparatus 10
may be equipped with means for engaging the registration holes 17,
such as pegs or keys. By engaging the registration holes, the
forming apparatus 10 can register the stamper with the web 12 so
that the microstructure pattern is positioned precisely around the
center hole 15.
[0108] With reference to stage B of FIG. 11, after the
microstructure pattern is formed on the web 12, the disk substrate
13 is sent to the post-punch station 950 (FIG. 10). At the
post-punch station 950 a central plug 952 may be inserted into the
center hole 15. The central plug 952 may be constructed of any
suitable material. The central plug 952 may be fastened to the disk
substrate 13 in any suitable way. The central plug 952 is larger
than the center hole 15 so that it masks an inner perimeter region
954 of the disk substrate 19. The masked inner perimeter region 954
is preferably fixed to have a width of approximately that of
conventional media.
[0109] With reference to stage C of FIG. 11, an outer mask 956 may
be applied over the disk substrate 13 while it is at the post-punch
station 950. The outer mask 956 may be registered to the web 12 by
engaging the registration holes 17 of the web. The outer mask 956
may be constructed of any suitable material. The outer mask 956 may
be fastened to the disk substrate 13 in any suitable way. The
diameter of the interior opening 957 in the outer mask 956 is less
than the final diameter of the disk substrate 13, so that it masks
an outer perimeter region 958 of the disk substrate. The masked
outer perimeter region 958 may preferably have a width of
approximately 1/2 to 3 mm, and more preferably of approximately 1
mm.
[0110] After the plug 952 and the outer mask 956 are in place, the
disk substrate 13 may be conveyed from the post-punch station 950
to the web cutting device 500 where the web 12 can be cut into
strips 510 of a suitable length and/or width. The strips 510 may be
accumulated for further processing by batch or may be immediately
transferred to a coating applicator 400. At the coating applicator
400, the strips may be placed into tracks disposed along the inside
cylindrical surface of a rotating drum portion 450. The strips 510
may be loaded into the drum 450 so that the masked surfaces of the
disk substrates 13 are exposed to the drum interior or coating
stream. The drum may be sealed, by any suitable device during
coating.
[0111] The drum 450 of the coating applicator 400 may be arranged
to rotate orthogonally to the direction of the web 12 pay off.
Arranging the drum orthogonally to the direction of the Web pay-off
allows web strips 510 to be linearly advanced directly into the
drum 450. The side of the drum 450 opposite the web cutting device
500 may be open to allow one or more coating units 410 to be
inserted therein. The coating units 410 may be mounted on an
internal wall capable of being sealed in the drum 450. Once the
wall on which the coating units 410 are mounted is closed, the drum
can be rotated about its axis so that the web strips 510 disposed
along the inner wall of the drum are transported through various
coating zones defined by the coating units 410. A side view of the
drum 450 and the deposition chamber 440 defined thereby is shown in
FIG. 12. In order to carry out the coating process with a
drum-shaped coating apparatus 400, it maybe necessary to cool the
drum 450 or the substrate in the drum. One method of cooling
the-drum 450 is to include a waterjacket 460 around the outside of
the drum. The use of a waterjacket allows control over the
temperature of the drum and over web strips disposed inside of the
drum.
[0112] With continued reference to FIG. 11, after the disk
substrate 13 is coated, the plug 952 and the outer mask 956 may be
removed. The disk substrate 13 then appears as shown in stage D,
including coatings on the surface with the exception of the outer
perimeter region 958 and the inner perimeter region 954. The strips
web that reach stage D may then be sent to a finishing line, such
as one discussed above in connection with FIG. 7. The finishing
station for disk substrates that reach stage D, however, may
require an additional station to bond the information carrying
substrate to an opposing substrate (such as a blank or embossed
material).
[0113] An alternative embodiment of the drum-shaped coating
apparatus 400 is to have the coating apparatus 400 rotate in line
with the web pay off direction. As a result, the disk substrates,
in strip or web form, may be loaded directly onto the drum 450 as
it rotates.
[0114] The embodiments of the invention(s) disclosed heretofore may
be used with or without melt forming. While melt forming
contemplates forming microstructures into the surface of the web
during a very brief period of time (on the order of tens of
milliseconds, preferably less), several of the embodiments of the
preceding may be useful with other replication processes. While the
invention has been illustrated in detail in the drawings and the
foregoing description, the same is to be considered as illustrative
and not restrictive in character as the present invention and the
concepts herein may be applied to any formable material. It will be
apparent to those skilled in the art that variations and
modifications of the present invention can be made without
departing from the scope or spirit of the invention. For example,
the dimensions of the optical substrates, and the microstructures
formed therein can be varied without departing from the scope and
spirit of the invention. The materials used to construct the
various elements used in the embodiments of the invention, such as
the pressure and backing rollers, the stamper, the stamper support,
and the heater, may be varied without departing from the intended
scope of the invention. Furthermore, it is appreciated that the
support for the stamper and the backing roller could be integrated
so as to provide one structure. The stamper may then be separated
from the backing roller with an insulator. Still further, it is
appreciated that the present invention extends to embodiments that
use optical memory substrates in any form, be that web, sheet, or
otherwise. Further more, by using one or more of the embodiments
described above in combination or separately, it is possible to
make optical memory disks with less than .+-.0.8 degrees radial
deviation, and less than .+-.0.3 degrees tangential deviation, with
a birefringence of less than 100 nm double pass, more preferably
less than 90 nm double pass, and still more preferably less than 60
nm retardation, double pass, through 1.2 mm, or less, of web
material. Thus, it is intended that the present invention cover all
such modifications and variations of the invention, that come
within the scope of the appended claims and their equivalents.
* * * * *