U.S. patent application number 10/980179 was filed with the patent office on 2005-05-05 for hard disk drive.
Invention is credited to Amo, Mina, Ito, Yutaka, Matsumoto, Hiroyuki, Nakakawaji, Takayuki, Shoda, Mitsuhiro, Sonoda, Koji, Tani, Hiroshi.
Application Number | 20050095461 10/980179 |
Document ID | / |
Family ID | 28046047 |
Filed Date | 2005-05-05 |
United States Patent
Application |
20050095461 |
Kind Code |
A1 |
Matsumoto, Hiroyuki ; et
al. |
May 5, 2005 |
Hard disk drive
Abstract
A magnetic disk to which is applied a first lubricating agent
formed as 1 (where p=0 or an integer of at least 1, q=0 or an
integer of at least 1, and X=1-5), and over which is applied a
second lubricating agent formed as
HOCH.sub.2CF.sub.2(OC.sub.2F.sub.4).sub.p(OCF.sub.2).sub.qOCF.sub.2CH.sub.-
2OH (where p=0 or an integer of at least 1, q=0 or an integer of at
least 1.
Inventors: |
Matsumoto, Hiroyuki;
(Chigasaki, JP) ; Tani, Hiroshi; (Ninomiya,
JP) ; Shoda, Mitsuhiro; (Odawara, JP) ;
Sonoda, Koji; (Oume, JP) ; Nakakawaji, Takayuki;
(Kitaibaraki, JP) ; Amo, Mina; (Hitachi, JP)
; Ito, Yutaka; (Takahagi, JP) |
Correspondence
Address: |
ANTONELLI, TERRY, STOUT & KRAUS, LLP
1300 NORTH SEVENTEENTH STREET
SUITE 1800
ARLINGTON
VA
22209-9889
US
|
Family ID: |
28046047 |
Appl. No.: |
10/980179 |
Filed: |
November 4, 2004 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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10980179 |
Nov 4, 2004 |
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10347912 |
Jan 22, 2003 |
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6816341 |
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10347912 |
Jan 22, 2003 |
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09897401 |
Jul 3, 2001 |
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6665147 |
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Current U.S.
Class: |
428/841.3 ;
360/135; 428/218; 428/336; 428/843.3; G9B/33.047 |
Current CPC
Class: |
G11B 33/148 20130101;
G11B 5/012 20130101; Y10T 428/24355 20150115; C10M 107/38 20130101;
G11B 33/1446 20130101; C10M 105/74 20130101; C10M 107/48 20130101;
Y10T 428/24992 20150115; Y10T 428/265 20150115 |
Class at
Publication: |
428/694.0BF ;
428/336; 360/135; 428/218 |
International
Class: |
G11B 005/82 |
Foreign Application Data
Date |
Code |
Application Number |
Jan 22, 2002 |
JP |
2002-012291 |
Jul 5, 2000 |
JP |
2000-208228 |
Claims
What is claimed is:
1. A magnetic disk to which is applied a first lubricating agent
formed as 8(where p=0 or an integer of at least 1, q=0 or an
integer of at least 1, and X=1-5), and over which is applied a
second lubricating agent formed as
HOCH.sub.2CF.sub.2(OC.sub.2F.sub.4).sub.p(OCF.sub.2).sub.qOCF.s-
ub.2CH.sub.2OH (where p=0 or an integer of at least 1, q=0 or an
integer of at least 1).
2. A magnetic disk as described in claim 1 wherein an average
molecular weight of the second lubricating agent is no more than
2,400 and no less than 600.
3. A magnetic disk as described in claim 1 wherein a proportion of
the second lubricating agent is less than that of the first
lubricating agent.
4. A magnetic disk as described in claim 1 wherein the first
lubricating agent is applied with a thickness in a range of
approximately 1.0-1.8 nm.
5. A magnetic disk as described in claim 1 wherein the average
molecular weight of the first lubricating agent is roughly in a
range of 1,500-6,500.
6. A magnetic disk as described in claim 1 wherein the average
molecular weight of the first lubricating agent is roughly in a
range of 3,500-6,500.
7. A magnetic disk as described in claim 1 wherein the magnetic
disk is formed by stacking a glass substrate, a seed layer, a base
layer, a lower magnetic layer, a non-magnetic intermediate layer,
an upper magnetic layer, and a protective layer.
8. A magnetic disk to which is applied a first lubricating agent
formed as 9(where p=0 or an integer of at least 1, q=0 or an
integer of at least 1, 10(where p=0 or an integer of at least 1,
q=0 or an integer of at least 1.
9. A magnetic disk as described in claim 8 wherein an average
molecular weight of the second lubricating agent is no more than
2,400 and no less than 600.
10. A magnetic disk as described in claim 8 wherein a proportion of
the second lubricating agent is less than that of the first
lubricating agent.
11. A magnetic disk as described in claim 8 wherein the first
lubricating agent is applied with a thickness in a range of
approximately 1.0-1.8 nm,
12. A magnetic disk as described in claim 8 wherein the average
molecular weight of the first lubricating agent is roughly in a
range of 1,500-6,500.
13. A magnetic disk as described in claim 8 wherein the average
molecular weight of the first lubricating agent is roughly in a
range of 3,500-6,500.
14. A magnetic disk as described in claim 8 wherein the magnetic
disk is formed by stacking a glass substrate, a seed layer, a base
layer, a lower magnetic layer, a non-magnetic intermediate layer,
an upper magnetic layer, and a protective layer.
Description
CROSS-REFERENCES TO RELATED APPLICATIONS
[0001] This application is a continuation of U.S. application Ser.
No. 10/347,912, filed Jan. 22, 2003, which is a
continuation-in-part of U.S. application Ser. No. 09/897,401, filed
Jul. 3, 2001, now U.S. Pat. No. 6,664,147, which claims priority
from Japanese Patent Application No. 2000-208228, filed Jul. 5,
2000. This application is related to and claims priority from
Japanese Patent Application No. 2002-12291, filed Jan. 22, 2002,
and copending with U.S. application Ser. No. 10/689,599, filed Oct.
22, 2003, which is a continuation of U.S. application Ser. No.
09/897,401, filed Jul. 3, 2001, now U.S. Pat. No. 6,665,147. The
entire disclosures of these applications are incorporated herein by
reference.
BACKGROUND OF THE INVENTION
[0002] The present invention relates to a hard disk drive that uses
a magnetic recording medium in which at least a magnetic layer and
a protective layer are formed on a magnetic disk substrate, and a
liquid lubricating agent with a perfluoroether structure is applied
to the surface thereof. The present invention also relates to a
hard disk drive with a mechanism for supplying a lubricating agent
into the device in the form of a gas.
[0003] The recording densities in hard disk drives has been
steadily increasing at a significant rate. Recently, recording
densities of 20 gigabits per square inch (Gbit/inch.sup.2) have
been announced. A requirement for achieving these high densities is
to reduce the distance between the magnetic head and the magnetic
recording layer of the magnetic disk as much as possible.
Currently, this distance must be no more than 20 nm.
[0004] To reduce this distance as much as possible, the surface
roughness of the magnetic disk must be reduced as much as possible.
Therefore, there has been a transition from the contact start/stop
(CSS) systems, where the magnetic head is in contact with the
magnetic disk when the disk is not spinning and the magnetic head
flies up due to air currents when the magnetic disk begins
spinning, to load/unload (U/UL) systems, where the magnetic head is
retracted away from the magnetic disk (unloaded) when the disk is
stopped and is loaded on to the magnetic disk when the magnetic
disk begins spinning. In U/UL systems, anti-sliding characteristics
can be relaxed somewhat. However, the hard disk drive must be able
to withstand impacts from load-on operations as well as sudden
irregularities in head orientation that can occur even in normal
operations.
[0005] Improvements in the protective layer and lubricating layer
on magnetic disks are being made in order to minimize frication and
damage caused by contact between the head and the magnetic disk.
For example, in Japanese laid-open patent publication number Hei
8-319491, a perfluoro polyether with a phosphazene ring group is
used in a lubricating agent to improve its properties. In Japanese
laid-open patent publication number Hei 10-143836, a polyphenoxy
cyclotriphosphazene is mixed with a perfluoro polyether at a weight
ratio of 0.01-1. In Japanese laid-open patent publication number
2001-187796, a lubricating agent contains at least 30% perfluoro
polyether having a phosophezene ring group. The object of these
technologies is to improve wear resistance in magnetic disks,
reduce head debris, reduce friction, reduce decomposition of the
lubricating agent, or the like.
[0006] With regard to decomposition of the lubricating agent, it is
believed that hydrogen fluoride (HF) is generated due to thermal
decomposition from friction heat or decomposition due to Lewis
acid, and that this HF causes a chain reaction that leads to
decomposition of the lubricating agent. Japanese laid-open patent
publication number Hei 10-143839 states that lubricating agents
decompose due to exoelectrons generated by friction between the
magnetic head and the magnetic disk.
[0007] Lubricating agents are supplied so that splattering of the
lubricating agent due to rotation and heat can be reduced. In
conventional technologies that supply lubricating agents to hard
disk drives in the form of a gas, the lubricating agent supply
source is placed within the head disk assembly. This conventional
technology did not take into account the material and absorption
properties of the supplied lubricating agent, the material and
absorption properties of the lubricating layer formed on the
magnetic disk, and the combinations of these elements. As a result,
some lubricating agents are not able to prevent debris on the
magnetic head, thus leading to reduced reliability. Furthermore,
with some lubricating agents, corrosive outgas in the hard disk
drive could generate a deposit on the magnetic head element that
corrodes the metal in the element.
[0008] Also, absorption properties of the lubricating agent can
vary depending on the type and characteristics of the protective
layer of the magnetic disk. With diamond-like carbon (DLC) layers
in particular, the absorption of the lubricating agent is less than
that of carbon layers formed by sputtering, making it difficult to
support the supplied lubricating agent on the magnetic disk and
leading to reduced wear prevention.
SUMMARY OF THE INVENTION
[0009] When mixing two types of lubricating agents, e.g., a
lubricating agent containing phosphazene and another lubricating
agent, the combination must at least be evaluated based on
compatibility, head debris, friction, and the like.
[0010] Magnetic heads used in magnetic disks are generally formed
from a reproducing element that uses the Magneto-Resistive effect
and a magnetic induction recording element. The recording element
is formed from a coil generating a magnetic field and a magnetic
pole that induces the magnetic field. The recording element records
signals by sending a current of approximately a few dozen mA to the
coil. The reproducing element receives a bias current. The
reproducing element plays back signals by detecting changes in
resistance resulting from the magnetic field. This bias current is
between a few and a few dozen mA. Recording and reproducing
frequencies increase with the recording density. With a 3.5 inch
hard disk drive having a recording density of 20 Gbit/inch.sup.2,
the frequency reaches approximately 300 MHz. When recording at such
high frequencies, the recording element generates heat due to
electrical resistance and impedance resistance, becoming very hot.
The heat that is generated depends on the element structure, but
can reach 200-250 degrees Centigrade. Heat generation increases
when the recording frequency increases. The reproducing element
also generates heat in a similar manner. The layer thickness of the
reproducing element is on the order of submicrons, and the track
width decreases as the recording density increases. As a result,
heat generation increases with higher recording densities.
[0011] Friction heat causes the lubricating agent of a magnetic
disk to decompose. However, it has not been clearly pointed out
that heat from the recording or reproducing element in the head
leads to the decomposition of the lubricating agent on the slider
surface near the recording/reproducing element of the head,
resulting in reduced reliability in the hard disk drive. We have
studied the causes of reduced reliability in hard disk drives and
have discovered that reduced reliability is caused by decomposition
and transfer of the lubricating agent due to heat from the
recording and reproducing elements in the head.
[0012] This will be described in more detail. Lubricating agent
adhered to the slider surface near the recording and reproducing
elements is decomposed by heat from the recording or reproducing
element. This creates hydrogen fluoride (HF), causing lubricating
agent with a higher concentration of HF to be adhered to the
magnetic disk surface. The lubricating agent adhered to the
magnetic disk surface corrodes the magnetic layer and the like of
the magnetic disk. As a result, a protrusion formed on the magnetic
disk surface, which undergoes volume expansion due to this
corrosion, is adhered. The magnetic disk surface forming the
protrusion comes into contact with the magnetic head, leading to
wear on the protective layer, the magnetic layer, and the like. In
the worst case, this can lead to loss of data recorded on the
magnetic layer, resulting in secondary errors in which data
recorded on the magnetic layer is erased.
[0013] The present invention provides a hard disk drive that
overcomes the loss of reliability in hard disk drives caused by
these secondary errors.
[0014] More specifically, the present invention provides a hard
disk drive including: a magnetic disk to which is applied a first
lubricating agent formed as 2
[0015] (where p=0 or an integer of at least 1, q=0 or an integer of
at least 1, and X=1-5) or 3
[0016] (where p=0 or an integer of at least 1, q=0 or an integer of
at least 1, and X=1-5); a spindle motor spinning the magnetic disk;
a magnetic head reading information recorded on the magnetic disk;
an arm supporting the magnetic head; a voice coil motor positioning
the arm on the magnetic disk; a circuit processing a signal read by
the magnetic head; and a mechanism for supplying a second
lubricating agent formed as
HOCH.sub.2CF.sub.2(OC.sub.2F.sub.4).sub.p(OCF.sub.2).sub.qOCF.sub.2CH.sub.-
2OH
[0017] (where p=0 or an integer of at least 1 and q=0 or an integer
of at least 1) into the device.
[0018] According to another aspect, the present invention provides
a hard disk drive including: a magnetic disk to which is applied a
first lubricating agent formed as 4
[0019] (where p=0 or an integer of at least 1, q=0 or an integer of
at least 1, and X=1-5) or 5
[0020] (where p=0 or an integer of at least 1, q=0 or an integer of
at least 1, and X=1-5), and over which is applied a second
lubricating agent formed as
HOCH
.sub.2CF.sub.2(0C.sub.2F.sub.4).sub.p(OCF.sub.2).sub.qOCF.sub.2CH.sub-
.2OH
[0021] (where p=0 or an integer of at least 1 and q=0 or an integer
of at least 1) into the device; a spindle motor spinning the
magnetic disk; a magnetic head reading information recorded on the
magnetic disk; an arm supporting the magnetic head; a voice coil
motor positioning the arm on the magnetic disk; and a circuit
processing a signal read by the magnetic head.
BRIEF DESCRIPTION OF THE DRAWINGS
[0022] FIG. 1 is a simplified drawing showing a cross-section
structure of a magnetic disk according to embodiment 1.
[0023] FIG. 2 is a simplified drawing of a structure of a magnetic
disk.
[0024] FIG. 3 is a drawing comparing numbers of secondary errors as
they relate to following time in embodiments 1, 2 and comparative
example 1.
[0025] FIG. 4 is a drawing comparing lubricating layer thicknesses
before and after a test in embodiments 1, 2 and comparative example
1.
[0026] FIG. 5 is a drawing comparing the number of secondary errors
as they relate to following time in embodiment 3 and comparative
example 2.
[0027] FIG. 6 is a drawing showing how the number of secondary
errors depends on molecular weight.
[0028] FIG. 7 is a drawing comparing lubricating layer thicknesses
before and after a test in embodiment 4 and comparative example
3.
[0029] FIG. 8 is a drawing showing the relationship between the
proportion of chemical formula (1) and secondary errors.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0030] An example of the advantages of the present invention will
be described using an embodiment. A glass substrate marketed for
magnetic disks is suitable as a non-magnetic magnetic disk
substrate. In order to reflect the surface roughness of a substrate
surface, a magnetic disk medium which surface roughness (Ra) was
approximately 0.8 nm, was prepared.
[0031] Embodiment 1
[0032] FIG. 1 is a simplified drawing of the layer structure of a
magnetic disk according to embodiment 1. After washing a glass
substrate 1, a disk sputtering device (Intevac Corp.'s MDP-250) is
used to form a seed layer 2, a base layer 3, a lower magnetic layer
4, a non-magnetic intermediate layer 5, an upper magnetic layer 6,
and a protective layer 7, as shown in the figure. The seed layer 2
is sputtered using a NiTa alloy target to form a layer that is
approximately 30 nm thick. The thickness of the seed layer was
measured using X-ray spectrometry. After it is formed, the seed
layer is heated at approximately 260 degrees Centigrade and exposed
for approximately 3.5 seconds to an Ar--O.sub.2 gas. The CrTi alloy
base layer 3 is formed over the seed layer 2 with a thickness of
approximately 5 nm. The base magnetic layer is formed as a CoCrPt
alloy magnetic layer with a thickness of approximately 3.5 nm. The
intermediate layer is formed Ru layer with a thickness of
approximately 0.5 nm. The upper magnetic layer 6 is formed as a
CoCrPtB alloy layer with a thickness of approximately 15 nm. The
protective layer 7 is formed with a thickness of approximately 3.5
nm over the upper magnetic layer 6. An example of this protective
layer 7 is a DLC (diamond-like carbon) layer formed using CVD
(chemical vapor deposition) or IBD (ion beam deposition). The
thickness of the protective layer 7 is measured using X-ray
reflection. To improve accuracy in the thickness measurement,
quantizing is done by forming a 5 nm Cr layer over the protective
layer 7. The X-ray reflection quantization of layer thickness was
performed using Rigaku Denki Kogyo Corp.'s SLX2000.TM. with an
[CuK.sub.alpha1] X-ray. Using Sumitomo-3M Corp.'s HFT7100 as a
solvent, a lubricating agent solution as shown in chemical formula
(1) was created. The magnetic disk was dipped into this lubricating
agent solution to form the lubricating layer 8. The perfluoro
polyether backbone chain in the lubricating agent based on chemical
formula (1) has a number-average molecular weight of approximately
2,000. An FTIR measurement of the lubricating layer showed a
thickness of approximately 1.5 nm. 6
[0033] (where p=0 or an integer of 1 or more, q=0 or an integer of
1 or more, X=1-5).
[0034] Embodiment 2
[0035] A magnetic disk was created in a manner similar to that used
in embodiment 1. However, a lubricating agent as shown in chemical
formula (2) was used. The perfluoro polyether backbone chain in the
lubricating agent based on chemical formula (2) has a
number-average molecular weight of approximately 2,000. An FTIR
measurement of the lubricating layer showed a thickness of
approximately 1.5 nm. 7
COMPARATIVE EXAMPLE 1
[0036] A magnetic disk was created in a manner similar to that used
in embodiment 1. However, a lubricating agent as shown in chemical
formula (3) was used. Five types of lubricating agents were used,
with number-average molecular weights of 1,000, 2,000, 3,000,
4,000, and 6,000, as measured using NMR (nuclear magnetic
resonance). FTIR measurements of the lubricating layer thicknesses
showed that each had a thickness of approximately 1.5 nm.
HOCH.sub.2CF.sub.2(OC.sub.2F.sub.4).sub.p(OCF.sub.2).sub.qOCF.sub.2CH.sub.-
2OH [Chemical formula 3]
[0037] (where p=0 or an integer of 1 or more and q=0 or an integer
of 1 or more).
[0038] The magnetic disks from embodiment 1, embodiment 2, and
comparative example 1 were installed in a 3.5 inch hard disk drive
(magnetic disk device). A simplified drawing of the hard disk drive
is shown in FIG. 2.
[0039] The disk device includes: a spindle motor 10 for spinning a
magnetic disk 9; an arm 12 for supporting a magnetic head 11 used
to record information to the magnetic disk 9 and/or to read
information recorded on the magnetic disk 9; a voice coil motor 13
for aligning the arm 12; a circuit 14 for processing information
recorded on the magnetic disk 9 and read by the magnetic head 11
and information to be written to the magnetic disk 9; a mechanism
for supplying the lubricating agent to the device (in this case, a
dust filter 15); and the like. An approximately 1.0 mg drop of the
lubricating agent indicated by chemical formula (3) and having a
number-average molecular weight of 2,000 was applied to the dust
filter 15, which was placed at a predetermined position to supply
the lubricating agent to the device. The magnetic disks from the
embodiments and the comparative examples were installed. The hard
disk drive was operated at a speed of approximately 10,000 rpm
(rotations per minute), with a recording density of approximately
20 Gbit/inch.sup.2, a head flying height of approximately 15 nm,
and a test environment temperature of approximately 50 degrees
Centigrade.
[0040] The heads of the hard disk drive was fixed at a radial
position of 38 mm so that they continuously followed a fixed
recording track. The number of secondary errors was monitored, and
the results are shown in FIG. 3.
[0041] As shown in FIG. 3, there were no secondary errors in
embodiment 1 and embodiment 2. Thus, secondary errors were reduced
and reliability was improved by applying perfluoropolyether
lubricating agents having the molecular structures shown in
chemical formula (1) and (2) to magnetic disks and using a hard
disk drive equipped with a mechanism for supplying a lubricating
agent shown in chemical formula (3) with a number-average molecular
weight of 2,000. With comparative example 1, however, the number of
secondary errors increased over time. As a result, it was found
that secondary errors took place and the number increased over time
when the same lubricating agent as shown in chemical formula (3)
was applied to a magnetic disk.
[0042] This hard disk drive was taken apart after it was operated
for 465 hours, and FTIR measurements were made of the lubricating
layer thicknesses on the installed magnetic disks. FIG. 4 shows the
changes in lubricating layer thickness before and after the
test.
[0043] For example, the lubricating layer thickness of the magnetic
disk from embodiment 1 was initially approximately 1.5 nm but
increased to approximately 1.8 nm after the test. This indicates
that the lubricating agent indicated by chemical formula (3) that
was applied to the dust filter 15 adhered to the magnetic disk and
increased the thickness. From this result, it can be postulated
that the lubricating layer on the magnetic disk consists of
approximately 1.5 nm of the lubricating agent indicated by the
chemical formula (1) and approximately 0.3 nm of the lubricating
agent indicated by the chemical formula (3). In this case, the
lubricating agent from the chemical formula (1) would make up
approximately 83% of the entire lubricating layer. The values shown
in FIG. 4 show the proportions of lubricating agents on the
magnetic disks before the test. After the test, the lubricating
agent proportion was approximately 70-90% compared to before the
test for embodiment 1, embodiment 2, and comparative example 1.
These results show that the frequency of secondary errors can be
reduced by forming the lubricating layer on the magnetic disk ahead
of time as a mixture of the lubricating agents shown in chemical
formula (1) and (2) and the lubricating agent shown in chemical
formula (3) with a number-average molecular weight of 2,000, and by
setting the proportion of the mixture to be the same as that of the
lubricating layer after the test.
[0044] Embodiment 3
[0045] A magnetic disk was produced in the same manner as
embodiment 2. An FTIR measurement showed that the lubricating layer
had a thickness of approximately 1.5 nm. A drop of approximately
1.0 mg of lubricating agent as shown in chemical formula (3) with a
number-average molecular weight of 1,000 was applied to the dust
filter 15, which was placed at a predetermined position in a 3.5
inch hard disk drive. In another 3.5 inch hard disk drive, a drop
of 1.0 mg of the lubricating agent with a number-average molecular
weight of 1,000 was applied to the dust filter 15 placed at a
predetermined position. The magnetic disk from embodiment 3 was
installed in the hard disk drives. A test was conducted in a manner
similar to those for embodiment 1 and 2.
COMPARATIVE EXAMPLE 2
[0046] A magnetic disk was created in a manner similar to that used
in embodiment 3. However, a lubricating agent as shown in chemical
formula (3) was used. Three types of lubricating agents were used,
with number-average molecular weights of 3,000, 4,000, and 6,000,
and 1.0 mg drops were applied to the dust filters 15 placed at
predetermined positions in three hard disk drives, and the disks
from the comparative example 2 were installed in these devices. A
test was conducted in a manner similar to those for embodiment 1
and 2.
[0047] FIG. 5 shows test results for the embodiment 3 and the
comparative example 2.
[0048] These test results show that the frequency of secondary
errors increases significantly as the molecular weight of the
lubricating agent increases. FIG. 6 shows the results illustrated
using the molecular weights of the lubricating agents as a
parameter.
[0049] As FIG. 6 shows, secondary errors are less frequent with
lower molecular weights. In particular, almost no secondary errors
take place at molecular weights of 2,400 and less. Since a
molecular weight that is too low can impede the function of the
lubricating agent, e.g., because there is too much evaporation, so
an average molecular weight of at least approximately 600 is
preferable. Based on the test results for embodiments 1, 2, 3 and
comparative examples 1, 2, a highly reliable hard disk drive can be
achieved by supplying the hard disk drive with a lubricating agent
as shown in chemical formula (3) and with a number-average
molecular weights of at least approximately 600 and no more than
approximately 2,400 and by forming the lubricating layer on the
magnetic disks with a lubricating agent as shown in chemical
formula (1) or chemical formula (2).
[0050] Next, the lubricating layer thickness of the hard disk
drives from the embodiment 3 was measured after the test. It was
found that the magnetic disk installed in the hard disk drive with
the lubricating agent having a number-average molecular weight of
1,000 had a layer thickness of approximately 1.75 nm. The magnetic
disk installed in the hard disk drive with the number-average
molecular weight of 2,000 had a layer thickness of approximately
1.86 nm. As a result, it was determined that the proportions of the
lubricating agent shown in chemical formula (2) were approximately
86% and 81% respectively. Thus, it is believed that few secondary
errors take place in magnetic disks with lubricating layers formed
by mixing a lubricating agent from chemical formula (1) or (2) with
a lubricating agent from chemical formula (3) with a number-average
molecular weight of approximately 600-2,400.
[0051] Embodiment 4
[0052] Magnetic disks were made in a manner similar to that of
embodiment 2. However, the lubricating layer thicknesses were set
to 1.0, 1.2, 1.5, and 1.8 nm.
[0053] Comparative embodiment 3
[0054] Magnetic disks were made in a manner similar to that of
embodiment 2. However, the lubricating layer thicknesses were set
to 0.4, 0.6, and 0.8 nm.
[0055] Two types of 3.5-type hard disk drives were prepared, one in
which a 1.0 mg drop of lubricating agent as shown in chemical
formula (3) with a number-average molecular weight of 1,000 was
applied to the dust filter 15 placed at a predetermined position in
the device, the other in which a 1.0 mg drop of lubricating agent
as shown in chemical formula (3) with a number-average molecular
weight of 2,000 was applied to the dust filter 15 placed at a
predetermined position in the device. The magnetic disks from the
embodiment 4 and the comparative example 3 were installed in these
hard disk drives. The hard disk drive was operated at a speed of
approximately 10,000 rpm, with a recording density of approximately
20 Gbit/inch.sup.2, a head flying height of approximately 15 nm,
and a test environment temperature of approximately 50 degrees
Centigrade. A test was performed 500 hours and the numbers of
secondary errors were compared. Also, the lubricating layer
thicknesses before and after the test were compared.
[0056] FIG. 7 shows lubricating layer thickness comparisons from
before and after the test. FIG. 8 shows the relationship between
the proportion of the lubricating agent shown in chemical formula
(2) in the lubricating layer after the test and the number of
secondary errors.
[0057] FIG. 7 shows that the lubricating layer thicknesses
increased after the test. The thicknesses were not dependent on the
initial lubricating layer thickness and were about 1.8 nm. The
samples with lower initial layer thicknesses had smaller
proportions of the lubricating agent from chemical formula (2).
Also, FIG. 8 shows that there were no secondary errors when the
proportion of the chemical formula (2) was approximately 50% or
less, i.e., the proportion of the lubricating agent from the
chemical formula (3) was approximately 50% or more. In other words,
it was found that there were no secondary errors if the proportion
of the lubricating agent from the chemical formula (3) was less
than the proportion of the lubricating agent from the chemical
formula (2). Based on these results, a highly reliable hard disk
drive with no secondary errors can be achieved with a lubricating
layer containing a lubricating agent shown in chemical formula (1)
or chemical formula (2) and a lubricating agent shown in chemical
formula (3), where the average molecular weight is at least
approximately 600 and no more than approximately 2,400 and the
proportion of the lubricating agent shown in chemical formula (3)
is no more than approximately 50%.
[0058] Looking at these points from another perspective, this means
that secondary errors do not take place if the initial layer
thickness is at least approximately 1.0 nm. The test results show
that the thickness of the lubricating layer from chemical formula
(3) together with the lubricating agent from chemical formula (1)
or (2) tends to not go over approximately 1.8 nm. In other words,
applying a lubricating agent from chemical formula (1) or (2) at a
thickness of more than approximately 1.8 nm may prevent the
lubricating agent from chemical formula (3) from being adhered.
Thus, it would be preferable for the lubricating agent from
chemical formula (1) or (2) to be approximately 1.0 nm-1.8 nm.
COMPARATIVE EXAMPLE 4
[0059] A magnetic disk was made in a manner similar to that of
embodiment 1. However, a lubricating agent applied to the magnetic
disk is formed approximately 70% from a lubricating agent shown in
chemical formula (2) and approximately 30% from a lubricating agent
shown in chemical formula (4) with an average molecular weight of
3,000. The lubricating agent layer thickness was approximately 1.5
nm. This magnetic disk was installed in a magnetic disk with a
mechanism for supplying a lubricating agent with an average
molecular weight of 2,000. A following test was performed and
secondary errors were studied.
R1-(CF.sub.2CF.sub.2O).sub.p--(CF.sub.2O).sub.q--R2
R1, R2=HO--(CH.sub.2CH.sub.2O).sub.r--CH.sub.2CF.sub.2O-- [Chemical
formula 4]
[0060] [As a result, after 500 hours of testing, there were 24
errors, thus showing decreased reliability compared to the magnetic
disks from the embodiments. Thus, it is believed that secondary
errors do not take place when chemical formula (1) or (2) and
chemical formula (3) with an average molecular weight of
approximately 600-2,400 are combined in the lubricating agent and
when the proportion of the lubricating agent from chemical formula
(1) or (2) is at least approximately 50%.
[0061] In the lubricating agents applied to the magnetic disks in
the embodiments, the molecular weight of the backbone chain of the
lubricating agent shown in chemical formula (1) or (2) was 2,000.
However, the present invention is not restricted to this molecular
weight, and similar advantages can be obtained if the lubricating
agent has an average molecular weight in the range of 1,500-6,500.
In general, aggregation in the lubricating layer decreases with
higher molecular weights in the lubricating agent, so a high
molecular weight of about 3,500-5,500 is believed to be suitable
for stable head flight.
[0062] As indicated by the embodiments, a magnetic disk that uses a
mixed lubricating layer combining a lubricating agent as shown in
chemical formula (1) or (2) with a lubricating agent shown in
chemical formula (3) with an average molecular weight of 600-2400,
with the proportion of the lubricating agent shown in chemical
formula (3) being at least 50%, works well with a hard disk drive
with a mechanism for supplying a lubricating agent as shown in
chemical formula (3) with an average molecular weight of 600-2,400.
The reliability of the resulting hard disk drive is significantly
improved.
[0063] A magnetic disk with an ultrathin-layer protecting layer
with a layer thickness of 1.0-5.0 nm according to the present
invention provides superior recording/reproducing performance, dust
resistance, and wear resistance.
* * * * *