U.S. patent application number 10/429883 was filed with the patent office on 2004-11-11 for lead outlet structure of secondary battery in sheet type.
Invention is credited to Fujiya, Naoko, Konno, Shinichi, Ozawa, Kazunori, Takasaki, Takao.
Application Number | 20040224227 10/429883 |
Document ID | / |
Family ID | 33566311 |
Filed Date | 2004-11-11 |
United States Patent
Application |
20040224227 |
Kind Code |
A1 |
Ozawa, Kazunori ; et
al. |
November 11, 2004 |
Lead outlet structure of secondary battery in sheet type
Abstract
The present invention is a lead outlet structure of a secondary
battery in sheet type, which comprises; an internal electrode pair
in sheet type which is obtained by stacking alternately sheets of
cathode electrode and sheets of anode electrode with separator
between them, a flexible envelope form package that contains inside
hermetically this internal electrode pair and electrolyte, a pair
of internal leads that are respectively connected with separately
each of cathode electrode and each of anode electrode of the
internal electrode pair inside the envelope form package, a pair of
external leads that are provided on the outside of the
above-mentioned envelope form package corresponding to each of the
above-mentioned internal leads with the above-mentioned envelope
form package in between, and a pair of connecting means, one side
of which is connected to each of the internal leads inside the
above-mentioned envelope form package and the other side is
connected to each of the external leads on the outside of the
envelope form package as well so that each of the internal leads
and each of the external leads are electrically connected, and
which is light, thin and flexible, and is capable to be a compact
and light weight product and can attain a relatively large capacity
secondary battery.
Inventors: |
Ozawa, Kazunori; (Tokyo,
JP) ; Takasaki, Takao; (Tokyo, JP) ; Fujiya,
Naoko; (Tokyo, JP) ; Konno, Shinichi;
(Yonezawa-shi, JP) |
Correspondence
Address: |
BIRCH STEWART KOLASCH & BIRCH
PO BOX 747
FALLS CHURCH
VA
22040-0747
US
|
Family ID: |
33566311 |
Appl. No.: |
10/429883 |
Filed: |
May 6, 2003 |
Current U.S.
Class: |
429/211 |
Current CPC
Class: |
H01M 50/528 20210101;
Y02P 70/50 20151101; H01M 50/543 20210101; H01M 50/129 20210101;
H01M 10/0525 20130101; H01M 50/121 20210101; H01M 50/124 20210101;
Y02E 60/10 20130101; H01M 50/193 20210101; H01M 50/172 20210101;
H01M 50/178 20210101; H01M 10/0413 20130101; H01M 50/54 20210101;
H01M 50/55 20210101; H01M 10/0585 20130101; H01M 50/553 20210101;
H01M 50/116 20210101; H01M 50/119 20210101; H01M 50/183 20210101;
H01M 50/186 20210101; H01M 50/136 20210101 |
Class at
Publication: |
429/211 |
International
Class: |
H01M 002/24 |
Claims
What is claimed is:
1. A lead outlet structure of a secondary battery in sheet type,
which comprises; an internal electrode pair in sheet type which is
obtained by stacking alternately sheets of cathode electrode and
sheets of anode electrode with separator between them, a flexible
envelope form package that contains inside hermetically this
internal electrode pair and electrolyte, a pair of internal leads
that are respectively connected with separately each of cathode
electrode and each of anode electrode of the internal electrode
pair inside the envelope form package, a pair of external leads
that are provided on the outside of the above-mentioned envelope
form package corresponding to each of the above-mentioned internal
leads with the above-mentioned envelope form package in between,
and a pair of connecting means, one side of which is connected to
each of the internal leads inside the above-mentioned envelope form
package and the other side is connected to each of the external
leads on the outside of the envelope form package as well so that
each of the internal leads and each of the external leads are
electrically connected.
2. A lead outlet structure of a secondary battery in sheet type
according to claim 1, wherein sealing parts are installed between
internal leads and an envelope form package and/or between external
leads and the envelope form package in order to seal penetrating
holes of the envelope form package, which a connecting means goes
through.
3. A lead outlet structure of a secondary battery in sheet type
according to claim 1 or 2, wherein internal leads and external
leads, which are connected by a connecting means, are made of the
same material.
4. A lead outlet structure of a secondary battery in sheet type
according to one of claim 1, 2 or 3, wherein a connecting means is
made of the same material at least as the internal leads.
5. A lead outlet structure of a secondary battery in sheet type
according to one of claim 1 to 4, wherein a connecting means is a
rivet that connects an internal lead and the corresponding external
lead.
6. A lead outlet structure of a secondary battery in sheet type
according to one of claim 2 to 5, wherein among sealing parts, at
least a sealing part installed between internal leads and a
envelope form package is made of synthetic resin which has chemical
resistance.
7. A lead outlet structure of a secondary battery in sheet type
according to claim 6, wherein at least a sealing part installed
between internal leads and a envelope form package is made of
polypropylene, polyethylene or ionomar.
8. A lead outlet structure of a secondary battery in sheet type
according to one of claim 1 to 7, wherein a pair of external leads
is provided on the same surface of a envelope form package.
9. A lead outlet structure of a secondary battery in sheet type
according to one of claim 1 to 8, wherein a secondary battery is a
lithium ion secondary battery with large capacity of more than 5
Ah.
Description
BACKGROUND OF THE INVENTION
[0001] 1. Field of the Invention
[0002] The present invention relates to a lead outlet structure of
secondary battery in sheet type. For example, the present invention
relates to, it is not limited to them though, a lead outlet
structure of a large capacity secondary battery in sheet type for
an electric vehicle, a UPS (uninterrupted power supply) a road
leveling and so on.
[0003] 2. Description of the Related Art
[0004] One of secondary batteries that have higher capacity or more
energy per volume or weight and have higher energy density is, for
example, a lithium ion rechargeable battery that is a secondary
battery with non-aqueous electrolyte, is composed of lithium or
lithium alloy. This lithium ion battery has advantages such as no
memory effect, little self-discharge and so on, therefore, it is
widely used for video camera recorders, audio equipment, portable
computers, mobile phones, various electric equipment, communication
devices, optical equipment and audio equipment.
[0005] This lithium ion secondary battery generally composes of an
electrode pair, a battery housing which encloses this electrode
pair and seals inside with electrolyte, and a cathode lead and an
anode lead those are connected from each of cathode electrode and
anode electrode of the electrode pair to each of cathode terminal
and anode terminal which are incorporated on the battery housing,
where the electrode pair consists of sheets of cathode electrode
that consists of a sheet of cathode collector and cathode active
material coated on it, sheets of anode electrode that consists of a
sheet of anode collector and anode active material coated on it and
a separator that is stacked between them.
[0006] During charging, a lithium goes out of cathode active
material and gets into electrolyte as an ion, then gets into anode
active material, while during discharging, this lithium ion gets
out of anode material and gets into electrolyte and goes back into
cathode material.
[0007] Since it can accomplish its high energy density, lithium ion
secondary battery like this is expected to use, for example, as a
large capacity secondary battery for electric vehicle use. And a
plenty of development and proposal have been conducted in this area
so far.
[0008] Not only relatively small secondary batteries used for
electric equipment, communication devices, optical equipment, audio
devices and so on, but also larger secondary batteries for electric
vehicles, are requested to be smaller in size, lighter in weight,
thinner in thickness and free in shape.
[0009] Therefore, conventionally in regard of a battery housing, a
flexible envelope form package of three layer laminated film that
is composed of an inner layer of thermoplastic resin such as
polyethylene or polypropylene which are stable with electrolyte and
suitable for heat-sealing, a middle layer of metal foil that is
flexible and strong such as aluminum foil and an external layer of
insulating resin such as polyamide resin, which shows good
electrical insulation.
[0010] Light, thin, and flexible lithium ion secondary batteries in
sheet type are proposed to be obtained by inserting an internal
electrode pair in sheet type and electrolyte into the
above-mentioned envelope form package.
[0011] And as indicated in FIG. 5 and FIG. 6, this conventional
lithium ion secondary battery in sheet type B consists of an
internal electrode pair 1 in sheet type that is generally composed
of cathode electrode 1a in sheet type, anode electrode 1b in sheet
type and separator 1c stacked between them and a flexible envelope
form package 2 that is made of laminated film which has an internal
layer 2a of thermoplastic resin, a middle layer 2b of metal foil
and an external layer 2c of insulating resin, which contains the
above-mentioned internal electrode pair 1 and electrolyte inside.
And also inside this envelope form package 2, each of cathode
electrode la and each of anode electrode 1b are connected to a pair
of cathode lead 3a and anode lead 3b, respectively. In addition,
this pair of cathode lead 3a and anode lead 3b goes hermetically
through heat sealed portion 4 of the envelope form package 2 and is
fixed to this heat sealed portion. And the projected external
portions of the cathode lead 3a and anode lead 3b out of the heat
sealed portion 4 are used as terminals or external leads.
[0012] In this structure of electrode leads, the surface between
the envelope from package 2, the cathode lead 3a and the anode lead
3b, which are extended, as external leads or terminals, to the
outside of the envelope form package 2 is adhered by heat-sealing
of inner layer 2a of thermoplastic resin of the envelope form
package 2. And adhesion strength between these cathode lead 3a and
anode lead 3b and an envelope form package 2 is not sufficient,
especially the larger the capacity becomes, the heavier the cell
becomes inevitably, consequently adhesion between a cathode lead 3a
and an anode lead 3b, and an envelope form package 2 becomes
unreliable with heat seal only. And if material of a cathode lead
3a is aluminum as in normal case, the adhesion strength on this
aluminum cathode lead 3a becomes more unreliable, then heat sealed
portion between the cathode lead 3a and the envelope form package 2
may have an opening and in some cases, water may go inside through
this opening and may produce hydrogen fluoride, then the battery
may deteriorate or the electrolyte may go out of the envelope form
package 2.
[0013] Moreover, when capacity becomes larger and as a result large
drain is desired, the section area of leads that is conducted from
the inside electrode pair (cathode electrode and anode electrode)
through the envelope form package to the outside is also required
to be large. Then the larger this section area is, the more
frequently the above-mentioned problems occur. For this reason a
sheet type lithium ion battery in an envelope form package with
capacity of more than 3 Ah is considered to be difficult to
achieve, although it is expected to contribute to smaller or
lighter equipment, machines, or automobiles with these lighter,
thinner, flexible and versatile characteristics.
SUMMARY OF THE INVENTION
[0014] Then after the inventors of the present invention examined
wholeheartedly lead outlet structures of electrode which can
construct a relatively large capacity, preferably more than 5 Ah,
batteries without spoiling advantages such as light, thin, flexible
characteristics as secondary batteries in sheet type have, using an
envelope form package of three layer laminated film like this, they
completed the present invention by finding that an envelope form
package between each of the internal leads and the external leads
are fixed firmly and hermetically by connecting between the pair of
internal leads that is respectively connected to each of the
cathode electrode and the anode electrode of the electrode pair
inside the envelope form package and the pair of the external leads
provided on the outside surface of the envelope form package,
through the envelope form package by a pair of connecting means,
whose one end is connected to each of the internal leads inside the
envelope form package and the other end at the same time is
connected to each of the external leads outside the envelope form
package, and by electrically connecting each of the internal leads
and each of the external leads by this pair of connecting
means.
[0015] Hence, an objective of the present invention is to provide a
lead outlet structure of a secondary battery in sheet type, which
accomplishes a relatively large capacity secondary battery as a
secondary battery in sheet type, which uses an envelope form
package as a battery housing and at the same time it can be light,
thin and flexible
[0016] The present invention is a lead outlet structure of
secondary battery in sheet type, which comprises; an internal
electrode pair in sheet type which is obtained by stacking
alternately sheets of cathode electrode and sheets of anode
electrode with separator between them, a flexible envelope form
package that contains inside hermetically this internal electrode
pair and electrolyte, a pair of internal leads that are
respectively connected with separately each of cathode electrode
and each of anode electrode of the internal electrode pair inside
the envelope form package, a pair of external leads that are
provided on the outside of the above-mentioned envelope form
package corresponding to each of the above-mentioned internal leads
with the above-mentioned envelope form package in between, and a
pair of connecting means, one side of which is connected to each of
the internal leads inside the above-mentioned envelope form package
and the other side is connected to each of the external leads on
the outside of the envelope form package as well so that each of
the internal leads and each of the external leads are electrically
connected.
[0017] An envelope form package in the present invention is not
limited to something special, as far as it has practical strength
to be a battery housing of a secondary battery in sheet type and at
the same time it is stable with electrolyte that is contained
inside. One example is a flexible envelope form package that has
three layer laminated film that consists of; an internal layer of
thermoplastic resin that are stable with electrolyte and suitable
for heat-sealing, for example, polyethylene, polypropylene,
polystyrene, polyamide, ionomer and so on, an middle layer of metal
foil that is flexible and strong, for example, aluminum foil,
stainless steel foil and so on and an external layer of insulating
resin that has good electrical insulation, for example, polyamide
system resin, polyester system resin and so on.
[0018] And in this invention inside the above-mentioned envelope
form package, each of cathode electrode sheets of an internal
electrode pair are connected by cathode internal leads and at the
same time each of anode electrode sheets are connected by anode
internal leads. And also each of external leads for cathode and
anode are provided on the position on the outside of the envelope
form package corresponding to the above-mentioned internal cathode
and anode leads and a pair of connecting means that goes
hermetically through the envelope form package connects
electrically between the internal cathode lead and the external
cathode lead and between the internal anode lead and the external
anode lead.
[0019] The size of the above-mentioned internal leads and external
leads is designed to the capacity, volume, weight or application of
a secondary battery in sheet type, though, preferably it should be
in stripe form, for instance, of more than about 0.5 mm, preferably
1 to 5 mm thickness, which is relatively thicker compared to
conventional leads for a secondary battery. And also as far as
material concerns, same as material and shape of leads used for a
conventional secondary battery of this kind, metal such as
aluminum, aluminum alloy, copper, and nickel is preferred to be
used, and preferably the same material as that of the cathode
collector, for example, aluminum or aluminum alloy is preferred to
be used for the internal cathode lead and the external cathode
lead. And as the same material as that of the anode collector, for
example, copper and/or nickel is preferred to be used for the
internal anode lead and the external anode lead.
[0020] As far as material of this connecting means such as a rivet
concerns, it is good enough as far as it connects firmly these
internal leads and external leads and connects electrically them.
For instance, a riveting with solid rivets (hereinafter referred as
`rivets`), full tubular rivets, semi-tubular rivets, split rivets,
compression rivets, blind rivets and so on, a fixing means where
one of an external lead or an internal lead has a stud that is
integral or is fixed to it and at the same time the other lead has
a hole to receive the stud to connect and fix them by clamping the
top of the stud, or a fixing means by a bolt and a nut are samples
of this connecting means.
[0021] Further, regarding material of rivets that comprise this
connecting means, preferably for connecting an internal cathode
lead and an external cathode lead, it is preferred to use aluminum
or aluminum alloy, those are the same material that is used for the
internal lead. And for connecting an internal anode lead and an
external anode lead, it is preferred to use copper and/or nickel,
those are the same material that is used for the internal lead. As
described here, when aluminum or aluminum alloy which is same as
the material used for the cathode collector is used as material of
the internal cathode lead, the external cathode lead and the
connecting means, and copper and/or nickel which is same as the
material used for the anode collector is used as material of the
internal anode lead, the external anode lead and the connecting
means, it can reduce its contact resistance as well as it can
prevent thermal deformation due to their different coefficient of
thermal expansion.
[0022] Moreover, in the present invention, penetrating holes on an
envelope form package, which a connecting means goes through to
connect internal leads and external leads are required to be
hermetically sealed. There is no restriction to how to seal
hermetically these penetrating holes of the envelope form packages,
however, for example, sealing parts may be installed between an
internal lead and the envelope form package and/or between an
external lead and the envelope form package in order to seal the
penetrating holes on the envelope form package, which the
connecting means goes through, or thickness of the internal layer
and/or the external layer around these penetrating holes that this
connecting means goes through may be formed thicker than other
areas beforehand and when the connecting means connect between the
internal leads and the external leads, it may seal the penetrating
holes by the thicker area around the penetrating holes.
[0023] And, in the case of the above-mentioned sealing parts
installation, at least sealing parts installed between the internal
lead and the envelope form package are required to be made of
synthetic resin that is stable with electrolyte and it is preferred
to be made of thermoplastic resin, such as polypropylene,
polyethylene, polyimide, polyamide, polyethylene telephthalate,
polytetrafluoroethylene, or fluorocarbon polymers, same as or
similar to an internal layer of laminated film that comprises the
envelope form package.
[0024] Regarding a lead outlet structure of a secondary battery in
sheet type, position on an envelope form package, where an external
lead is provided, has no restriction, as far as it can be installed
with the corresponding internal lead.
[0025] There is no restriction regarding manufacturing procedure of
a secondary battery that has a lead outlet structure of the present
invention, however, if a flat rectangle sheet type secondary
battery is fabricated with rivets as connecting means, for
instance, the following procedure fabricates it easily.
[0026] (1) First, connect internal cathode and anode leads to the
specified position of an internal electrode pair.
[0027] (2) Next, insert the internal electrode pair into an
envelope form package, whose three sides are heat-sealed.
[0028] (3) Place external leads on the position of the outside of
the envelope form package, corresponding to the internal leads and
align rivet holes of the internal leads, the external leads and
penetrating holes of the envelope form package.
[0029] (4) Insert rivets into the rivet holes and the penetrating
holes and add force on the rivet axis that sticks out through the
rivet holes of the internal leads and the external leads by means
of strikes, hydraulic force or air pressure to clamp the tops of
the rivets that stick out through the rivet holes.
[0030] (5) Seal hermetically by heat-sealing the unsealed side of
the envelope form package.
[0031] (6) Make a relatively small opening, for example, by cutting
one edge of the envelope form package.
[0032] (7) Fill the envelope form package with electrolyte through
the opening and at the same time seal this opening by heat
sealing.
BRIEF DESCRIPTION OF THE DRAWINGS
[0033] FIG. 1 shows a diagonal diagram of a lithium ion secondary
battery in sheet type that has a lead outlet structure related with
an embodiment of the present invention.
[0034] FIG. 2 is a sectional drawing at II-II line in FIG. 1.
[0035] FIG. 3 indicates a sectional drawing at III-III line in FIG.
1.
[0036] FIG. 4 illustrates an internal electrode pair installed
inside an envelope form package in FIG. 1.
[0037] FIG. 5 shows a diagonal diagram of a lithium ion secondary
battery in sheet type that has a conventional lead outlet
structure.
[0038] FIG. 6 indicates a sectional drawing at VI-VI line in FIG.
5.
DESCRIPTION OF SIGNS
[0039] B-lithium ion secondary battery in sheet type, 1-internal
electrode pair, 1a-cathode electrode, 1b-anode electrode,
1c-separator, 2-envelope from package, 4-heat sealed portion, 5a,
5b-internal leads, 6a, 6b-external leads, 7a, 7b-rivet, 8a,
8b-sealing parts, 9-cathode collector, 10-cathode active material,
11-anode collector, 12-anode active material.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
[0040] A preferred embodiment of the present invention is described
below with reference to the drawing which indicates an embodiment
sample and a test sample.
Embodiment Sample
[0041] A lithium ion secondary battery in sheet type, applied the
present invention of a lead outlet structure, is indicated in FIGS.
1 to 3. FIGS. 2 and 3 now show a section of cathode leads and the
cathode leads are mainly explained below, since structure of anode
leads are same as that of the cathode leads.
[0042] The present embodiment of a secondary battery in sheet type
B comprises; an internal electrode pair in sheet type 1 which is
obtained by stacking alternately sheets of cathode electrode 1a and
sheets of anode electrode 1b with separator 1c between them, a
flexible envelope form package 2 that contains inside hermetically
this internal electrode pair 1 and electrolyte (not shown), an
internal cathode lead 5a that connects each of cathode electrode
sheets 1a of the internal electrode pair 1 inside the envelope form
package 2, an internal anode lead (5b, not shown) that connects
each of anode electrode sheets 1b of the internal electrode pair 1
inside the envelope form package 2, an external cathode lead 6a
that are provided on the outside of the above-mentioned envelope 2
form package corresponding to the above-mentioned internal cathode
lead 5a with the above-mentioned envelope form package 2 in
between, an external anode lead 6b that are provided on the outside
of the above-mentioned envelope form package 2, corresponding to
the above-mentioned internal anode lead with the above-mentioned
envelope form package 2 in between, and a pair of two connecting
rivets (total 4 pieces) 7a, 7b, one side of which is connected to
each of the internal leads 5a, 5b inside the above-mentioned
envelope form package and the other side is connected to each of
the external leads 6a, 6b on the outside of the envelope form
package as well so that each of the internal leads 5a, 5b and each
of the external leads 6a, 6b are electrically connected.
[0043] Sealing parts 8a and 8b are in this embodiment installed
between each of the internal leads 5a, 5b and the envelope form
package 2 as well as between each of the external leads 6a, 6b and
the envelope form package 2 in order to seal the rivet holes on the
envelope form package 2, through which the rivets 7a, 7b are
inserted.
[0044] In addition, sign 4 shows the heat sealed portion of the
envelope form package 2.
[0045] The above mentioned electrode pair 1, as indicated in FIG.
4, consists of cathode electrode 1a, which is composed of aluminum
cathode collector 9 coated on both sides with cathode active
material 10, and anode electrode 1b, which is composed of copper
anode collector 11 coated on both sides with anode active material
12. In addition, a cathode internal lead 5a, a cathode external
lead 6a and a rivet 7a that connects them are made of aluminum,
same as the above mentioned cathode collector. An anode internal
lead 5b, an anode external lead 6b and the rivet 7b that connects
them are made of copper, same as the above mentioned anode
collector
[0046] Moreover, in this embodiment, the above mentioned envelope
form package 2 consists of laminated film of three layers, such as
a polyethylene internal layer 2a, an aluminum foil middle layer 2b
and a nylon external layer 2c. A sealing part 8a that is installed
between the above mentioned internal leads 5a, 5b, and the envelope
form package 2 are made of polyethylene, same as the internal layer
2a of the envelope form package 2, and a sealing part 8b that is
installed between the above mentioned internal leads 6a and 6b, and
the envelope form package 2 are made of nylon, same as the external
layer 2c of the envelope form package 2,
[0047] In this embodiment of a lithium ion secondary battery in
sheet type B, after the rivets 7a and 7b clamp each of the internal
leads 5a and 5b and each of the external leads 6a and 6b, the
envelope form package 2 and the sealing parts 8a and 8b between the
internal leads 5a, 5b and the external leads 6a, 6b are pressed,
and then by this mechanism, the holes on the envelope form package
through which the rivets 7a and 7b are inserted are sealed
hermetically and at the same time the rivets 7a and 7b connect
electrically the internal leads 5a, 5b and the external leads 6a,
6b.
Test Sample
[0048] One hundred lithium ion batteries of 4.2V and 10 Ah in sheet
type that is similar form to the embodiment, which comprise an
internal electrode pair of 120 mm.times.300 mm.times.5 mm in size,
internal leads of aluminum or copper of 15 mm.times.100
mm.times.1.5 mm in size, external leads of aluminum or copper of 15
mm.times.100 mm.times.1.5 mm in size, rivets of aluminum or copper
of 4 mm diameter.times.6 mm in size, an envelope form package that
consists of an internal layer of polyethylene of 0.08 mm thickness,
an middle layer of aluminum foil of 0.04 mm thickness and an
external layer of nylon of 0.03 mm thickness, and electrolyte of
mixture of ethylene carbonate (EC) and diethyl carbonate (DEC),
were fabricated, were stored at 80 degree C. for one week, and then
electrolyte leakage occurrences were counted and the voltages were
checked.
[0049] As a result, no electrolyte leakage was found and the
voltages after the storage were among 4.12 to 4.18V.
Comparison Sample
[0050] In addition, one hundred lithium ion batteries of 10 Ah and
4.2V, which have the same composition except that external leads
are extended portions of internal leads through heat sealed portion
of an envelope form package, were fabricated, were stored at 80
degree C. for one week, and then electrolyte leakage occurrences
were counted and the voltages were checked.
[0051] As a result, 45 batteries was found to have electrolyte
leakage and the voltages after the storage were among 0 to
4.0V.
[0052] As the above test sample and comparison sample clearly show,
the lithium ion secondary batteries with conventional structure of
the comparison sample, have large self-discharge, and about half of
the samples have electrolyte leakage. On the contrary, the lithium
ion secondary batteries with a structure of the present invention
have small self discharge such as about 0.05V and none of the
samples has electrolyte leakage.
[0053] When a lead outlet structure of this present invention is
employed, among secondary batteries in sheet type with an envelope
form package as a battery housing, the batteries have light, thin
and flexible characteristics and at the same time secondary
batteries with relatively large capacity can be achieved.
Especially this structure is highly suitable for a lead outlet
structure of a lithium ion secondary battery in sheet type with
relatively large capacity.
* * * * *