U.S. patent application number 10/794100 was filed with the patent office on 2004-09-02 for packaging material, method of making it, and package and therefrom.
This patent application is currently assigned to Sonoco Development, Inc.. Invention is credited to Huffer, Scott W., Schuetz, Jeffrey M..
Application Number | 20040170773 10/794100 |
Document ID | / |
Family ID | 25112991 |
Filed Date | 2004-09-02 |
United States Patent
Application |
20040170773 |
Kind Code |
A1 |
Huffer, Scott W. ; et
al. |
September 2, 2004 |
Packaging material, method of making it, and package and
therefrom
Abstract
A packaging material, a method of making such a material, and a
package made from such material, are disclosed. A substrate
comprises at least one sheet of plastic material. An energy-curable
coating is applied to one side of the substrate, which will be the
outside of the eventual package. The energy-curable coating is
cured by exposing it to an electron beam or other appropriate
energy. A cold-seal cohesive coating is applied to the other side
of the substrate. The package is formed by pressing together
portions of the inside surface of at least one sheet of the
material having the cold-seal cohesive coating on them to form a
seal. Preferably, the cold-seal cohesive coating is applied only to
those portions of the material that are to form seams in the
eventual package.
Inventors: |
Huffer, Scott W.;
(Hartsville, SC) ; Schuetz, Jeffrey M.; (Florence,
SC) |
Correspondence
Address: |
Thomas J. Durling, Esq.
Drinker Biddle & Reath LLP
One Logan Square
18th and Cherry Sts.
Philadelphia
PA
19103-6996
US
|
Assignee: |
Sonoco Development, Inc.
|
Family ID: |
25112991 |
Appl. No.: |
10/794100 |
Filed: |
March 4, 2004 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
10794100 |
Mar 4, 2004 |
|
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|
09778334 |
Feb 7, 2001 |
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Current U.S.
Class: |
427/551 ;
427/407.1; 427/595 |
Current CPC
Class: |
Y10T 428/1334 20150115;
Y10T 428/14 20150115; Y10T 428/2809 20150115; Y10T 428/31841
20150401; Y10T 428/1379 20150115; Y10T 428/31837 20150401; Y10T
428/1386 20150115; B32B 27/32 20130101; Y10T 428/31511 20150401;
Y10T 428/287 20150115; Y10T 428/1383 20150115; Y10T 428/31917
20150401; B65D 65/14 20130101; Y10T 428/31826 20150401; Y10T
428/2883 20150115; Y10T 428/24777 20150115; Y10T 428/24802
20150115 |
Class at
Publication: |
427/551 ;
427/595; 427/407.1 |
International
Class: |
B05D 001/36; B05D
007/00 |
Claims
What is claimed is:
1. A packaging material comprising: a substrate comprising at least
one sheet of plastic material; a cold-seal cohesive coating on an
inner side of the substrate; and an energy-cured coating on an
outer side of the substrate.
2. A packaging material according to claim 1, wherein the substrate
comprises a laminate of at least two sheets of plastic
material.
3. A according to claim 2, wherein an outer sheet of the laminate
is clear, and further comprising printing on a surface between the
outer sheet and an adjacent sheet.
4. A packaging material according to claim 1, further comprising
printing on an outer surface of the substrate covered by the
energy-cured coating.
5. A packaging material according to claim 1, wherein the cold-seal
cohesive coating comprises natural rubber latex, styrene butadiene,
isoprene or synthetic rubber.
6. A packaging material according to claim 1, wherein the cold-seal
cohesive coating comprises a minor proportion of acrylate or ethyl
vinyl acetate.
7. A packaging material according to claim 1, wherein the cold-seal
cohesive coating is applied only over selected portions of the
inner surface of the substrate.
8. A packaging material according to claim 1, wherein the energy
cured coating is an electron-beam cured coating.
9. A packaging material according to claim 1, wherein the energy
cured coating is a cross-linked epoxy acrylate coating.
10. A package comprising: at least one sheet of packaging material
comprising: a substrate comprising at least one sheet of plastic
material; a cold-seal cohesive coating on an inner side of the
substrate; and an energy-cured coating on an outer side of the
substrate; wherein said package has at least one seam formed by
portions of said cold-seal cohesive coating cohering together.
11. A package according to claim 10, wherein the substrate
comprises a laminate of at least two sheets of plastic
material.
12. A package according to claim 11, wherein an outer sheet of the
laminate is clear, and further comprising printing on a surface
between the outer sheet and an adjacent sheet.
13. A package according to claim 10, further comprising printing on
an outer surface of the substrate covered by the energy-cured
coating.
14. A package according to claim 10, wherein the cold-seal cohesive
coating comprises natural rubber latex, styrene butadiene, isoprene
or synthetic rubber.
15. A package according to claim 14, wherein the cold-seal cohesive
coating comprises a minor proportion of acrylate or ethyl vinyl
acetate.
16. A package according to claim 10, wherein the cold-seal cohesive
coating is applied only over selected portions of the inner surface
of the substrate.
17. A package according to claim 17, wherein said cold-seal
cohesive coating is applied to said substrate only at said at least
one seam.
18. A package according to claim 10, wherein the energy cured
coating is an electron-beam cured coating.
19. A package according to claim 10, wherein the energy cured
coating is a cross-linked epoxy acrylate coating.
20. A method of making a packaging material, comprising the steps
of: providing a substrate comprising at least one sheet of plastic
material; applying an energy-curable coating to one side of the
substrate; curing the energy-curable coating by exposing it to a
suitable energy; and applying a cold-seal cohesive coating to the
other side of the substrate.
21. A method according to claim 20, further comprising the step of
printing in ink on said at least one sheet of plastic material
before applying said energy-curable coating.
22. A method according to claim 21, which comprises applying the
energy-curable coating over the ink printing.
23. A method according to claim 21, comprising the steps of:
printing in ink on a sheet of plastic; and laminating the printed
sheet of plastic and another sheet of plastic together with the
printing between them to form said substrate; wherein one of said
sheets of plastic forming said substrate is clear; and applying
said energy-curable coating to the exposed side of said clear sheet
of plastic.
24. A method according to claim 20, wherein said step of curing
comprises exposing said energy-curable coating to an electron beam.
Description
FIELD OF THE INVENTION
[0001] The invention relates to a cold-sealable packaging material,
especially to one suitable for packaging candy bars and other
confectionery.
BACKGROUND OF THE INVENTION
[0002] Cold-sealable materials are known for packaging products
that would be adversely affected by exposure to heat, such as might
occur during heat-sealing of a package, after the product has been
produced. Candy bars with an external chocolate coating are an
example of such a product.
[0003] Previously used cold-seal packaging materials typically use
one of two structures. One structure comprises a layer of white
oriented polypropylene (OPP) material, with ink printing on the
outside, covered by a layer of lacquer, and a rubber latex cold
seal coating on the inside. Another structure comprises a laminate
of a white OPP ply and a clear OPP ply, bonded together by an
adhesive, with a rubber latex cold seal coating on the exposed,
inside, face of the white OPP ply. The clear OPP ply is reverse
printed. Both of these structures present a number of problems.
With the laminated structure, when the material is stored in rolls,
the cold seal coating lies against the clear OPP outer ply, and it
is difficult to prevent the cold seal coating from offsetting onto
the outer ply when the material is unrolled. Special measures can
be taken when applying the coating to ensure that the coating bonds
securely to the white OPP ply, so that it will remain attached to
that ply and not offset onto the outer ply. However, such measures
increase the cost and complication of manufacture. The lacquer in
the single-ply structure can be formulated to act as a release
layer, but previously used lacquers often contain mobile additives.
Such additives may poison the cold seal coating while the packaging
material is stored in rolls and the cold seal coating is in contact
with the lacquer, or may migrate through the packaging and
contaminate the contents in use. Such lacquers are also not very
stable, and have a limited life, because of the loss of volatile or
migratory components.
SUMMARY OF THE INVENTION
[0004] The present invention relates to a packaging material that
avoids, or at least reduces, some of the problems of the previously
proposed materials.
[0005] In one aspect, the invention provides a packaging material,
and a method of making such a material. A substrate comprises at
least one sheet of plastic material. An energy-curable coating is
applied to one side of the substrate, which will be the outside of
the eventual package. The energy-curable coating is cured by
exposing it to a suitable energy. A cold-seal cohesive coating is
applied to the other side of the substrate.
[0006] The substrate may be printed with ink and the ink covered
and protected by the energy-cured coating. This structure replaces
a laminated structure that incorporates a clear outer ply which is
printed on the inside of that ply or the facing surface of the next
ply.
[0007] In another aspect of the invention, a package is formed from
the packaging material. Portions of the inside surface of at least
one sheet of the material having the cold-seal cohesive coating on
them are pressed together to form a seal.
[0008] Preferably, the cold-seal cohesive coating is applied only
to those portions of the material that are to form seams in the
eventual package.
[0009] Preferably, the energy-curable coating is a coating that is
cross-linked when irradiated with an electron beam.
[0010] The foregoing and other features and advantages of the
present invention will become more apparent in light of the
following detailed description of the preferred embodiments
thereof, as illustrated in the accompanying figures.
BRIEF DESCRIPTION OF THE DRAWINGS
[0011] FIG. 1 is an oblique view of a package according to the
present invention.
[0012] FIG. 2 is a cross-section through one embodiment of
packaging material according to the invention.
[0013] FIG. 3 is a cross-section through another embodiment of
packaging material according to the invention.
DETAILED DESCRIPTIONS OF THE DRAWINGS
[0014] Referring to the drawings, and initially to FIG. 1, one form
of package according to the present invention is shown and
indicated generally by the reference numeral 10. The package 10
comprises a sheet 12 of packaging material, enclosing contents 14,
which may be a candy bar. As shown in FIG. 1, the sheet 12 is
wrapped round the contents 14, and its side edges are turned up to
form flanges 16, which are joined and sealed together with their
inside surfaces face-to-face by a cold seal 18, to form a generally
tubular shape. The ends of the tube are flattened, and joined and
sealed together by cold seals 20. A storage space, containing the
contents 14, is thus defined by the area within the sheet 12 and
within the seals 18 and 20. The storage space is sealed off from
the surrounding environment.
[0015] If the contents 14 are a solid object such a s a candy bar,
the package may be formed round the contents, substantially in the
order in which it has been described. If the contents 14 are loose
objects such as small pieces of candy, then the package may be
formed into a bag, by sealing the longitudinal seal 18 and one end
seal 20, filled, and then closed by sealing the other end seal 20.
In either case, the material for the sheet 12 may be provided in
the form of a long strip, with the flanges 16 formed by the side
edges of the sheet, and may be cut into lengths immediately before,
or after, the end seals 20 are formed. Machines for forming and
sealing such packages are available commercially, and the process
will not be further described here.
[0016] The sheet 12 of the package 10 can be manufactured from a
structure as shown in FIG. 2 based on a single ply of plastic
material, or from a laminate structure as shown in FIG. 3.
[0017] Referring now to FIG. 2, the first form of packaging
material has a substrate consisting of a single ply 34 of white
oriented polypropylene (OPP) material. Ink printing 36 is applied
to the outer surface of the OPP ply 34. As shown in FIG. 2, the ink
is applied in discrete areas, allowing the white color of the OPP
ply 34 to be seen as a background, but it may instead be applied in
a continuous layer. The ink may be a conventional ink suitable for
printing on OPP and may be applied by printing processes known for
the purpose.
[0018] The outside of the OPP ply 34 is covered, over the printing
36, with a layer of electron-beam curable (EB) coating 38, which
will be described in more detail below. The coating 38 is cured
immediately after being applied. It forms a protective layer,
preventing the printing from becoming smudged or abraded in
handling, and also serves as a release layer for the cold seal
coating to be discussed below.
[0019] A cold seal coating 40 is applied to the inside surface of
the white OPP ply 34. The cold seal coating 40 may be a continuous
layer, but preferably, as shown in FIG. 2, it is pattern-applied at
only those places where a seal is to be formed. That entails
maintaining register between the back side with the cold seal
coating and the front side with the printing. Preferably, the cold
seal coating machine is a flexographic or rotogravure printing
machine forming part of the same production line as, and is
mechanically synchronized with, the printing press for the ink
printing 36. Flexographic and rotogravure printing machines are
well known in the art and, in the interests of conciseness, will
not be described here. The package forming and cutting machine can
then be kept in register with the cold seal pattern in exactly the
same way as it is kept in register with the ink printing on the
other side of the material. Instead, the ink printing 36 may be
applied first, and the cold seal coating machine and the package
forming and cutting machine may separately be kept in register with
the printing. Methods of, and apparatus for, keeping subsequent
machines in register with a printed pattern are well known in the
art and, in the interests of conciseness, will not be described
here. Pattern-applying the cold seal has the advantages that far
less cold seal coating is used, and that the cold seal coating does
not contact the contents of the package 10, or does so only along
very narrow areas at the seams. Pattern-applying the cold seal 40
will be necessary for some uses, especially food uses, where more
than minimal contact between the contents 14 of the package 10 and
the cold seal coating 40 will not be acceptable.
[0020] Referring now to FIG. 3, the second form of packaging
material has a substrate comprising a laminate of an inner ply 42
of white OPP material and an outer ply 44 of clear OPP material,
laminated together by a layer 46 of a suitable adhesive. The ink
printing 36 is applied to the inner surface of the outer OPP ply
44. As with the first form of material shown in FIG. 2, the ink is
applied in discrete areas, allowing the white color of the inner
OPP ply 42 to be seen as a background, but it may instead be
applied in a continuous layer. Instead, the ink printing 36 may be
applied to the outer surface of the inner OPP ply 42, provided that
the adhesive 46 is sufficiently clear that it will not obscure the
printing.
[0021] The outside of the outer OPP ply 44 is covered with a layer
of EB coating 38. In this structure it is not needed to protect the
ink 36, but it forms a protective layer for the outer surface of
the OPP laminate, and serves as a release layer for the cold seal
coating to be discussed below.
[0022] The adhesive 46 is a solvent based adhesive based on two
aliphatic component materials that have the chemical composition of
a polyol and an isocyanate. Both of these components can be based
on chemicals that are low enough in molecular weight to be applied
to the films without needing solvents for dilution and application.
The chemical constituents are still found to be 21 C.F.R. .sctn.
177.1390 and .sctn. 175.105 approved where needed within the
package, and so may be used in food packaging.
[0023] The cold-seal coating 40 used in either form of the
packaging material shown in FIGS. 2 and 3 may be based on rubber
latex, but is preferably based on uncured isoprene or styrene
butadiene rubber. These synthetic rubbers are more stable than
natural rubber, allowing a material with a longer life, are more
consistent, and do not present the risk of allergic reactions, and
even anaphylactic shock, experienced by some people with natural
latex products. The coating 40 is preferably a cohesive material. A
cohesive material is defined as a material that adheres strongly to
another surface of the same material and only weakly to other
surfaces, and that when peeled apart fails primarily by separating
at the interface between the two cohesive coatings, rather than by
either coating detaching from its substrate. In order to ensure
adhesion of the coating 40 to its substrate, approximately 20% of
acrylate or ethylene vinyl acetate monomers may be added to the
coating material, to act as a surfactant and adhesive. For
application, the coating 40 is formed into an emulsion with water,
at a consistency that can be applied with a conventional
rotogravure printing press. The coating is applied at a thickness
of 5 to 7 microns (about 0.2 to 0.3 mils).
[0024] In either of the packaging materials 30 or 32, the electron
beam curable coating 38 may comprise a number of species of
suitable compounds. The materials best suited for the coating 40
are a combination of oligomers and monomers. The preferred oligomer
is an epoxy acrylate. The preferred monomer is acrylate. The
monomers act as diluents, used to reduce the viscosity of the
coating for purposes of application. The concentration of monomer
may be adjusted to provide a wide range of viscosity, such that
many coating systems may be employed to apply the EB coating.
[0025] The electron beam curable coating 40 is cured using a
suitable electron beam source. Suitable electron beam sources may
be obtained commercially from Energy Science, Inc. of Wilmington,
Mass. The electron energy output should be within the range of 110
kV to 135 kV at a dosage of 2.5 to 5.0 megarads. Preferably, the
energy is within the range of 125 kV to 135 kV at a dosage of 3.0
to 4.0 megarads.
[0026] When exposed to an electron beam from a suitable source,
acrylate monomer reacts into the epoxy acrylate chain to form
cross-links. The cross-linking requires no initiator compounds.
Therefore no residual volatile organic compounds are present in the
finished product. Curing is substantially instantaneous and
provides a cure percentage at or near one hundred percent.
[0027] Various desirable additives, the exact nature of which will
depend on the specifications of the packaging material 30 or 32,
may also be added. Often, defoamers and slip agents are desirable.
Additives may also be provided to improve qualities such as the
coefficient of friction, gloss, and processing qualities. The
additives included in the EB coating 40 tend to become "reacted-in"
during polymerization of the coating. For example, slip agents
provided to improve the coefficient of friction are fixed in the
cross-linking process, and are therefore not so susceptible to the
problems associated with migration. It is thus possible to use a
wider range of additives, and thus to achieve unexpectedly greater
control of the properties of the external surface of the packaging,
than was possible with previously used lacquer coatings.
[0028] Although the invention has been described and illustrated
with respect to the exemplary embodiments thereof, it should be
understood by those skilled in the art that the foregoing and
various other changes, omissions, and additions may be made therein
and thereto, without parting from the spirit and scope of the
present invention.
* * * * *