U.S. patent application number 10/761671 was filed with the patent office on 2004-08-05 for label and method of making.
Invention is credited to Allen, Loretta E., Bryant, Robert C., Frosig, Peter A., Patton, David L., Simpson, William H..
Application Number | 20040150219 10/761671 |
Document ID | / |
Family ID | 30448027 |
Filed Date | 2004-08-05 |
United States Patent
Application |
20040150219 |
Kind Code |
A1 |
Allen, Loretta E. ; et
al. |
August 5, 2004 |
Label and method of making
Abstract
A method of providing an image on a media having a
image-receiving layer and a protective overlayer, comprising the
steps of providing an image on said image-receiving and providing
machine-readable indicia on said protective overlayer by varying
the temperature of a thermal head used to apply said protective
overlayer.
Inventors: |
Allen, Loretta E.; (Hilton,
NY) ; Bryant, Robert C.; (Honeoye Falls, NY) ;
Simpson, William H.; (Pittsford, NY) ; Patton, David
L.; (Webster, NY) ; Frosig, Peter A.;
(Rochester, NY) |
Correspondence
Address: |
Pamela R. Crocker
Patent Legal Staff
Eastman Kodak Company
343 State Street
Rochester
NY
14650-2201
US
|
Family ID: |
30448027 |
Appl. No.: |
10/761671 |
Filed: |
January 21, 2004 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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10761671 |
Jan 21, 2004 |
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10310519 |
Dec 5, 2002 |
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10310519 |
Dec 5, 2002 |
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10213991 |
Aug 7, 2002 |
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Current U.S.
Class: |
283/107 |
Current CPC
Class: |
B41J 2/325 20130101;
G09F 3/10 20130101; B41M 7/0027 20130101; G09F 3/02 20130101 |
Class at
Publication: |
283/107 |
International
Class: |
B42D 015/00 |
Claims
What is claimed is:
1. A media comprising: a) an image-receiving layer on which an
image may be formed; and b) a protective overlayer provided over
said image-receiving layer, said protective overlayer having
machine-readable indicia formed thereon.
2. A media comprising: a) an image-receiving layer on which an
image may be formed using a thermal head; and b) a protective
overlayer provided over said image-receiving layer, said protective
overlayer having machine-readable indicia formed thereon.
3. The media of claim 2 wherein said indicia being transparent so
as to allow viewing of an image provided on said image-receiving
layer.
4. The media of claim 2 wherein said protective overlayer comprises
an IR absorbing dye.
5. The media of claim 2 further comprising an adhesive layer for
securing to an item.
6. A media comprising: a) a 1.sup.st machine-readable indicia in an
image layer on said media; and b) a 2.sup.nd machine-readable
indicia in a protective overlayer that is identical in content to,
and in register with said 1.sup.st machine-readable indicia in said
image layer.
7. A label comprising: a) a image-receiving layer on which an image
may be formed using a thermal head; and b) a protective overlayer
provided over said image-receiving layer, said protective overlayer
having machine-readable indicia formed thereon.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This is a Divisional of U.S. application Ser. No.
10/310,519, filed Dec. 5, 2002 entitled IMPROVED LABEL AND METHOD
OF MAKING by Loretta E. Allen, Robert C. Bryant, William H.
Simpson, David L. Patton and Peter A. Frosig, which is a
Continuation-in-Part of application Ser. No. 10/213,991 filed Aug.
7, 2002, entitled THERMAL DYE TRANSFERPRINT BEARING PATTERNED
OVERLAYER AND PROCESS FOR MAKING SAME by William H. Simpson, David
Andrew Johnson, Cobb S. Goff and David Edward Coons.
FIELD OF THE INVENTION
[0002] The invention relates to a thermal dye transfer print
comprising a protective overlayer including indicia written in the
protective overlayer.
BACKGROUND OF THE INVENTION
[0003] U.S. Pat. No. 6,092,942 (Koichi et al.) includes a thermal
dye donor element composed of a yellow, magenta and cyan dye patch
plus a protective overlayer which is applied to the receiver layer
containing the printed image by means of a thermal print head. The
protective layer is applied by using an image plane as a mask as
opposed to a uniform application of energy down the page. The
protective layer image is designed to have low and high energy
areas arranged in a pattern to produce corresponding regions of
density in the transferred protective layer. The final pattern in
the transferred protective overlayer represents indicia that can be
interpreted by detecting the variations in the thickness of the
protective layer either mechanically or optically.
[0004] Traditional bar codes formed using a combination of the
cyan, magenta and yellow dyes in a thermal printer produce a
relatively poor machine-readable code because of the lack of carbon
black in these dyes. Carbon black, and similar absorbing materials,
enhance the absorption of the near-infrared and red wavelengths
used by many handheld and point-of-sale scanners to read bar codes.
Typically, for a bar code to be read reliably, it is preferred that
the dyes used in the printing of the bar code symbol absorb light
in the near infrared and red wavelengths.
[0005] Today, more and more information is required on a product
label. More information requires a larger area onto which to print
the information, which translates into bigger labels. Bigger labels
may not be acceptable for many products, particularly small items
such as beauty and pharmaceutical products. Thus, there is a need
to provide Economy of label by providing more information often on
smaller labels that are human and/or machine-readable.
[0006] The present invention provides a thermal dye transfer print
bearing a protective overlayer wherein the overlayer is selectively
applied in such a manner so as to represent indicia. The present
invention also provides a thermal dye transfer print wherein at
least a portion of the indicia provided in the protective overlayer
is identical in content and location to indicia provided in the
image layer so as to enhance the readability of the indicia. The
present invention also provides a thermal dye transfer print
wherein at least a portion of the indicia provided in the
protective overlayer is different to indicia provided in the image
layer. The invention also provides a process for making such prints
as well as a method of reading the indicia.
[0007] The present invention also allows the providing of more
information on a label than traditionally printing human readable
indicia on an image layer. In particular, this is accomplished by
thermally printing machine-readable indicia in a protective
overlayer. The machine-readable indicia located in the protective
overlayer can be located in the same area of the label as
human-readable indicia. For instance, product information,
information that the consumer is interested in, is printed on the
image layer. Bar code information or other product tracking
information, information that the consumer is not interested in, is
printed in the protective overlayer. Therefore, a more
aesthetically pleasing or attractive label can be manufactured
comprising a print with a thermally transferred protective
overlayer containing machine-readable indicia.
[0008] In addition, a method of enhancing the machine readability
of a bar code printed with cyan, magenta and yellow dye is
disclosed.
SUMMARY OF THE INVENTION
[0009] In accordance with one aspect of the present invention there
is provided a method of providing an image on a thermal media
having a image-receiving layer and a protective overlayer,
comprising the steps of:
[0010] a) providing an image on the image-receiving layer using a
thermal head, and;
[0011] b) providing machine-readable indicia on the protective
overlayer by varying the temperature of the thermal head used to
apply the protective overlayer.
[0012] In accordance with another aspect of the present invention
there is provided a method of providing an image on a media having
a image-receiving layer and a protective overlayer, comprising the
steps of:
[0013] a) providing an image on the image-receiving layer;
[0014] b) providing machine-readable indicia on the protective
overlayer by varying the temperature of a thermal head used to
apply the protective overlayer.
[0015] In accordance with yet another aspect of the present
invention there is provided a method of providing an image on a
thermal media having a image-receiving layer and a protective
overlayer, comprising the steps of:
[0016] a) providing an image on the image-receiving layer using a
thermal head, and;
[0017] b) providing indicia on the protective overlayer by varying
the temperature of the thermal head used to apply the protective
overlayer.
[0018] In accordance with still another aspect of the present
invention there is provided a method of providing an image on a
thermal media having a image-receiving layer and an protective
overlayer, comprising the steps of:
[0019] a) providing machine-readable indicia on the protective
overlayer by varying the temperature of the thermal head used to
apply the protective overlayer.
[0020] In accordance with another aspect of the present invention
there is provided a method of providing an image on a thermal media
having an protective overlayer, comprising the steps of:
[0021] a) providing machine-readable indicia on the protective
overlayer by varying the temperature of the thermal head used to
apply the protective overlayer.
[0022] In accordance with yet still another aspect of the present
invention there is provided a method of providing a
machine-readable indicia on a media having a protective overlayer
comprising the steps of:
[0023] a) providing a 1.sup.st machine-readable indicia in an image
layer on the media;
[0024] b) providing a 2.sup.nd machine-readable indicia in a
protective overlayer that is identical in content to, and in
register with the 1.sup.st machine-readable indicia in the image
layer.
[0025] In accordance with still another aspect of the present
invention there is provided a method of providing indicia on a
media having a protective overlayer comprising the steps of:
[0026] a) providing a 1.sup.st machine-readable indicia in an image
layer on the media;
[0027] b) providing a 2.sup.nd machine-readable indicia in a
protective overlayer that is identical in content to, and in
register with the 1.sup.st machine-readable indicia in the image
layer.
[0028] In accordance with yet another aspect of the present
invention there is provided a media comprising:
[0029] a) an image-receiving layer on which an image may be formed,
and;
[0030] b) a protective overlayer provided over the image-receiving
layer, the protective overlayer having machine-readable indicia
formed thereon.
[0031] In accordance with still another aspect of the present
invention there is provided a media comprising:
[0032] a) an image-receiving layer on which an image may be formed
using a thermal head, and
[0033] b) a protective overlayer provided over the image-receiving
layer, the protective overlayer having machine-readable indicia
formed thereon.
[0034] In accordance with another aspect of the present invention
there is provided a media comprising:
[0035] a) a 1.sup.st machine-readable indicia in an image layer on
the media;
[0036] b) a 2.sup.nd machine-readable indicia in a protective
overlayer that is identical in content to, and in register with the
1.sup.st machine-readable indicia in the image layer.
[0037] In accordance with still yet another aspect of the present
invention there is provided a label comprising:
[0038] a) a image-receiving layer on which an image may be formed
using a thermal head, and
[0039] b) a protective overlayer provided over the image-receiving
layer, the protective overlayer having machine-readable indicia
formed thereon.
[0040] In accordance with another aspect of the present invention
there is provided a computer program that when programmed in a
computer causes the computer to provide the steps of:
[0041] a) forming a 1.sup.st machine-readable indicia in an image
layer on a media;
[0042] b) forming a 2.sup.nd machine-readable indicia in a
protective overlayer that is identical in content to, and in
register with the 1.sup.st machine-readable indicia.
[0043] In accordance with yet another aspect of the present
invention there is provided a method of reading a media having
indicia formed in a protective overlayer, the indicia having a
physical topography that represents a machine-readable code
comprising the steps of:
[0044] a) reading the physical topography of the indicia by a
machine so as to obtain information encoded therein, and
[0045] b) interpreting the encoded information so as to obtain the
information.
[0046] These and other aspects, objects, features and advantages of
the present invention will be more clearly understood and
appreciated from a review of the following detailed description of
the preferred embodiments and appended claims and by reference to
the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0047] In the detailed description of the preferred embodiments of
the invention presented below, reference is made to the
accompanying drawings in which:
[0048] FIGS. 1-3 shows various embodiments of a print in the
process of having the protective overlayer applied;
[0049] FIG. 4 is an exploded view of a label showing the image
layer separate from the protective overlayer;
[0050] FIG. 5 is a plan view of a label having machine-readable
indicia imbedded the protective overlayer, and located on a
product;
[0051] FIG. 6A is a graph showing the results of a topographic test
done (Gould Microtopographer stylus instrument);
[0052] FIG. 6B is a single trace of the graph of FIG. 6A;
[0053] FIG. 7A is a graph showing the results of a topographic test
done (Zygo);
[0054] FIG. 7B is an elevation view of the graph of FIG. 7A;
[0055] FIG. 8A represents a method of reading the encoded overcoat
by means of direct illumination;
[0056] FIG. 8B represents a method of reading the overcoat by means
of direct illumination in conjunction with a polarization
analyzer;
[0057] FIG. 9 is an exploded view of a label showing the image
layer and protective layer having the identical image; and
[0058] FIGS. 10-13 shows various embodiments of a print in the
process of having the protective overlayer applied.
DETAILED DESCRIPTION OF THE INVENTION
[0059] The invention is summarized above. It encompasses a thermal
dye transfer print bearing a protective overlayer, wherein the
protective overlayer comprises information-bearing indicia,
especially indicia that is machine-readable, a process for making
the print, and a method of reading the information-bearing
indicia.
[0060] The print of the invention includes overcoat arrangements
wherein the protective overlayer additionally comprises an IR
absorbing dye or where the thickness of the protective overlayer
varies.
[0061] The process for forming the protective overlayer on a
thermal dye transfer print comprises:
[0062] 1) applying to the print a solid sheet comprising a
polymeric binder or layers of polymeric material; and
[0063] 2) applying heat selectively to the surface of the
protective overlayer sheet.
[0064] Suitably, in the process of the invention, the heat is
applied via a thermal print head, especially one where the thermal
print head is variable as to which pixels are energized and/or the
extent to which pixels are energized. Alternatively, the protective
overlayer contains an IR dye and the heat is applied via selective
application of a laser beam.
[0065] Any dye can be used in the dye layer of the dye-donor
element of the invention provided it is transferable to the
image-receiving layer by the action of heat. Especially good
results have been obtained with sublimable dyes. Examples of
sublimable dyes include anthraquinone dyes, e.g., Sumikaron Violet
RS.RTM. (Sumitomo Chemical Co., Ltd.), Dianix Fast Violet 3R
FS.RTM. (Mitsubishi Chemical Industries, Ltd.), and Kayalon Polyol
Brilliant Blue N BGM.RTM. and KST Black 146.RTM. (Nippon Kayaku
Co., Ltd.); azo dyes such as Kayalon Polyol Brilliant Blue BM.RTM.,
Kayalon Polyol Dark Blue 2BM.RTM., and KST Black KR.RTM. (Nippon
Kayaku Co., Ltd.), Sumikaron Diazo Black 5G.RTM. (Sumitomo Chemical
Co., Ltd.), and Miktazol Black 5GH.RTM. (Mitsui Toatsu Chemicals,
Inc.); direct dyes such as Direct Dark Green B.RTM. (Mitsubishi
Chemical Industries, Ltd.) and Direct Brown M.RTM. and Direct Fast
Black D.RTM. (Nippon Kayaku Co. Ltd.); acid dyes such as Kayanol
Milling Cyanine 5R.RTM. (Nippon Kayaku Co. Ltd.); basic dyes such
as Sumiacryl Blue 6G.RTM. (Sumitomo Chemical Co., Ltd.), and Aizen
Malachite Green.RTM. (Hodogaya Chemical Co., Ltd.); or any of the
dyes disclosed in U.S. Pat. No. 4,541,830, the disclosure of which
is hereby incorporated by reference. The above dyes may be employed
singly or in combination to obtain a monochrome. The dyes may be
used at coverage of from about 0.05 to about 1 g/m.sup.2 and are
preferably hydrophobic.
[0066] A dye-barrier layer may be employed in the dye-donor
elements of the invention to improve the density of the transferred
dye. Such dye-barrier layer materials include hydrophilic materials
such as those described and claimed in U.S. Pat. No. 4,716,144.
[0067] The dye layers and protection layer of the dye-donor element
may be coated on the support or printed thereon by a printing
technique such as a gravure process.
[0068] A slipping layer may be used on the backside of the
dye-donor element of the invention to prevent the printing head
from sticking to the dye-donor element. Such a slipping layer would
comprise either a solid or liquid lubricating material or mixtures
thereof, with or without a polymeric binder or a surface-active
agent. Preferred lubricating materials include oils or
semi-crystalline organic solids that melt below 100.degree. C. such
as poly(vinyl stearate), beeswax, perfluorinated alkyl ester
polyethers, poly-caprolactone, silicone oil,
poly(tetrafluoroethylene), carbowax, poly(ethylene glycols), or any
of those materials disclosed in U.S. Pat. Nos. 4,717,711;
4,717,712; 4,737,485; and 4,738,950. Suitable polymeric binders for
the slipping layer include poly(vinyl alcohol-co-butyral),
poly(vinyl alcohol-co-acetal), polystyrene, poly(vinyl acetate),
cellulose acetate butyrate, cellulose acetate propionate, cellulose
acetate or ethyl cellulose.
[0069] The amount of the lubricating material to be used in the
slipping layer depends largely on the type of lubricating material,
but is generally in the range of about 0.001 to about 2 g/m.sup.2.
If a polymeric binder is employed, the lubricating material is
present in the range of 0.05 to 50 weight %, preferably 0.5 to 40
weight %, of the polymeric binder employed.
[0070] Any material can be used as the support for the dye-donor
element of the invention provided it is dimensionally stable and
can withstand the heat of the thermal printing heads. Such
materials include polyesters such as poly(ethylene terephthalate);
polyamides; polycarbonates; glassine paper; condenser paper;
cellulose esters such as cellulose acetate; fluorine polymers such
as poly(vinylidene fluoride) or
poly(tetrafluoroethylene-co-hexafluoropropylene); polyethers such
as polyoxymethylene; polyacetals; polyolefins such as polystyrene,
polyethylene, polypropylene or methylpentene polymers; and
polyimides such as polyimide amides and polyetherimides. The
support generally has a thickness of from about 2 to about 30
.mu.m.
[0071] The image-receiving element that is used with the dye-donor
element of the invention usually comprises a support having thereon
a dye image-receiving layer (from now on to be referred to as an
image-receiving layer). The support may be a transparent film such
as a poly(ether sulfone), a polyimide, a cellulose ester such as
cellulose acetate, a poly(vinyl alcohol-co-acetal) or a
poly(ethylene terephthalate). The support for the image-receiving
element may also be reflective such as baryta-coated paper,
polyethylene-coated paper, white polyester (polyester with white
pigment incorporated therein), an ivory paper, a condenser paper or
a synthetic paper such as DuPont Tyvek.RTM..
[0072] The dye image-receiving layer may comprise, for example, a
polycarbonate, a polyurethane, a polyester, poly(vinyl chloride),
poly(styrene-co-acrylonitrile), polycaprolactone or mixtures
thereof. The dye image-receiving layer may be present in any amount
which is effective for the intended purpose. In general, good
results have been obtained at a concentration of from about 1 to
about 5 g/m.sup.2.
[0073] As noted above, the dye donor elements of the invention are
used to form a dye-transfer image. Such a process comprises
imagewise heating a dye-donor element as described above and
transferring a dye image to an image-receiving element to form the
dye-transfer image. After the dye image is transferred, the
protection layer is then transferred on top of the dye image.
[0074] The dye donor element of the invention may be used in sheet
form or in a continuous roll or ribbon. If a continuous roll or
ribbon is employed, it may have only one dye or may have
alternating areas of other different dyes, such as sublimable cyan
and/or magenta and/or yellow and/or black or other dyes. Such dyes
are disclosed in U.S. Pat. Nos. 4,541,830; 4,698,651; 4,695,287;
4,701,439; 4,757,046; 4,743,582; 4,769,360 and 4,753,922, the
disclosures of which are hereby incorporated by reference. Thus,
one-, two-, three- or four-color elements (or higher numbers also)
are included within the scope of the invention.
[0075] In a preferred embodiment of the invention, the dye-donor
element comprises a poly(ethylene terephthalate) support coated
with sequential repeating areas of yellow, cyan and magenta dye,
and the protection layer noted above, and the above process steps
are sequentially performed for each color to obtain a three-color
dye-transfer image with a protection layer on top. Of course, when
the process is only performed for a single color, then a monochrome
dye transfer image is obtained.
[0076] Thermal printing heads, which can be used to transfer dye
from the dye-donor elements of the invention, are available
commercially. There can be employed, for example, a Fujitsu Thermal
Head FTP-040 MCSOO1, a TDK Thermal Head LV5416 or a Rohm Thermal
Head KE 2008-F3.
[0077] A thermal dye transfer assemblage of the invention
comprises
[0078] (a) a dye-donor element as described above, and
[0079] (b) an image-receiving element as described above,
[0080] the dye-receiving element being in a superposed relationship
with the dye donor element so that the dye layer of the donor
element is in contact with the dye image-receiving layer of the
receiving element.
[0081] The above assemblage comprising these two elements may be
pre-assembled as an integral unit when a monochrome image is to be
obtained. This may be done by temporarily adhering the two elements
together at their margins. After transfer, the image-receiving
element is then peeled apart to reveal the dye-transfer image.
[0082] When a three-color image is to be obtained, the above
assemblage is formed on three occasions during the time when heat
is applied by the thermal printing head. After the first dye is
transferred, the elements are peeled apart. A second dye-donor
element (or another area of the donor element with a different dye
area) is then brought in register with the image-receiving element
and the process is repeated. The third color is obtained in the
same manner. Finally, the protection layer is applied on top.
EXAMPLES
[0083] A. Receiver Element:
[0084] The image-receiving element that is used with the dye-donor
element of the invention usually comprises a support having thereon
a dye-receiving layer. The support may be a transparent film such
as a poly(ether sulfone), a polyimide, a cellulose ester such as
cellulose acetate, a poly(vinyl alcohol-co-acetal) or a
poly(ethylene terephthalate). The support for the dye-receiving
element may also be reflective such as baryta-coated paper,
polyethylene-coated paper, white polyester (polyester with white
pigment incorporated therein), an ivory paper, a condenser paper or
a synthetic paper such as DuPont Tyvek.RTM..
[0085] A dye image-receiving layer such as that found in Kodak
Ektatherm receiver catalog #172-5514.
[0086] The dye image-receiving layer may comprise, for example, a
polycarbonate, a polyurethane, a polyester, poly(vinyl chloride),
poly(styrene-co-acrylonitrile), polycaprolactone or mixtures
thereof. The dye image-receiving layer may be present in any amount
which is effective for the intended purpose. In general, good
results have been obtained at a concentration of from about 1 to
about 5 g/m.sup.2.
[0087] B. Donor Element:
[0088] Protective layer donor elements were prepared by coating on
6 .mu.m PET (poly(ethylene terephthalate)) support:
[0089] On the back side of the element were coated the following
layers in sequence:
[0090] 1) a subbing layer of 0.13 g/m.sup.2 titanium butoxide
(DuPont Tyzor TBT.RTM.) from an 85% n-propyl acetate and 15%
n-butyl alcohol solvent mixture.
[0091] 2) a slipping layer containing an
aminopropyl-dimethyl-terminated polydimethylsiloxane, PS513 (United
Chemical Technologies, Bristol, Pa.) (0.011 g/m.sup.2), a
poly(vinylacetal)(Sekisui KS-1) binder (0.38 g/m.sup.2),
p-toluenesulfonic acid (0.0003 g/m.sup.2), candellila wax (0.022
g/m.sup.2) coated from a solvent mixture of diethylketone, methanol
and distilled water (88.7/9.0/2.3)
[0092] C. Protective Overlayer:
[0093] On the front side of the element was coated a transferable
overlayer of poly(vinyl acetal), KS-1, (Sekisui Co.), at a laydown
of 0.63 g/m.sup.2, colloidal silica, IPA-ST (Nissan Chemical Co.),
at a laydown of 0.462 g/m.sup.2, and divinylbenzene beads, 4 micron
average diameter, (Eastman Kodak Company), at a laydown of 0.011
g/m.sup.2, coated from a 79% 3-pentanone and 21% methanol
mixture.
[0094] D. Test Conditions
[0095] Using Kodak Professional EKTATHERM XLS XTRALIFE Color Ribbon
(Eastman Kodak Co. Catalog No. 807-6135) and a Kodak Model 8300
Thermal Printer a Status A neutral density image with a maximum
density of at least 2.3 was printed on the receiver described
above. The color ribbon-receiver assemblage was positioned on an 18
mm platen roller and a TDK thermal head (No. 3K0345) with a head
load of 6.35 Kg was pressed against the platen roller. The TDK
3K0345 thermal print head has 2560 independently addressable
heaters with a resolution of 300 dots/inch and an average
resistance of 3314 .OMEGA.. The imaging electronics were activated
when an initial print head temperature of 36.4.degree. C. had been
reached. The assemblage was drawn between the printing head and
platen roller at 16.9 mm/sec. Coincidentally, the resistive
elements in the thermal print head were pulsed on for 58 .mu.sec
every 76 .mu.sec. Printing maximum density required 64 pulses "on"
time per printed line of 5.0 msec. The voltage supplied was 13.6
volts resulting in an instantaneous peak power of approximately
58.18.times.10-3 Watt/dot and the maximum total energy required to
print Dmax was 0.216 mJoules/dot. The process is repeated
sequentially, yellow, magenta, cyan to obtain the desired neutral
image.
[0096] Application of the transferable protective overlayer to the
receiver layer was done using a head voltage of 13.6 volts with an
enable width of 72 microseconds. The size of the print is
2400.times.2680 pixels.
[0097] Referring now to FIGS. 1-4, there will be described a method
of making a print in accordance with the present invention. In the
preferred method shown in FIG. 1, thermal print head 10 comprising
resistive elements 12 are used to transfer a protective overlayer
14 from a donor element 16 to a print 18. Print 18 comprises an
image layer 26 on a support media 28. Print 18 of this invention is
not limited to a thermally transferred dye print, and can include
any other method of creating a print, for example, inkjet,
electrophotograhic, lithography, etc. The donor element 16
comprises a slipping layer (not shown) and a subbing layer (not
shown) coated on a backside of a donor support 22. On the front
side of the donor support is coated a donor overlayer 24.
[0098] As shown in FIG. 1, with the image layer 26 of print 18 in
contact with the donor overlayer 24 of donor element 16, the donor
overlayer 24 can be transferred to print 18 by thermal print head
10. As thermal print head 10 moves in direction "A" and resistive
elements 12 are selectively energized to different degrees, the
donor overlayer 24 is caused to separate from the donor support 22
and attach to the image layer 26 of print 18 in different
thickness. The energy required to transfer the donor overlayer 24
in section "1a" is greater than the energy required to transfer the
donor overlayer 24 in section "1b" resulting in the thickness of
the protective overlayer 14 in section "1a" to be greater than the
thickness of the protective overlayer 14 in section "1b". In this
embodiment, protective overlayer 14 is a continuous layer over the
entire surface area of image layer 26, and the thickness of
protective overlayer 14 at any given point is limited to the
thickness defined in either section "1A" or "1B".
[0099] Shown in FIG. 2 is an alternate embodiment of the current
invention. With the image layer 26 of print 18 in contact with the
donor overlayer 24 of donor element 16, the donor overlayer 24 can
be transferred to the print 18 by thermal print head 10. As thermal
print head 10 moves in direction "A" and resistive elements 12 are
selectively energized, the donor overlayer 24 is caused to separate
from the donor support 22 and attach to the image layer 26 of print
18 in the selective areas. The thermal print head 10 is energized
as it moves across section "2a", and de-energized as it moves
across section "2b". In this embodiment, protective overlayer 14 is
not a continuous layer over the entire surface area of image layer
26, and the thickness of protective overlayer 14 at any given point
is limited to the thickness defined in either section "2a" or
"2b".
[0100] Shown in FIG. 3 is another alternate embodiment of the
current invention. With the image layer 26 of print 18 in contact
with the donor overlayer 24 of donor element 16, the donor
overlayer 24 can be transferred to the print 18 by thermal print
head 10. As thermal print head 10 moves in direction "A" and
resistive elements 12 are de-energized or selectively energized to
different degrees, the donor overlayer 24 is caused to separate
from the donor support 22 and attach to the image layer 26 of print
18 in different thickness. The energy required to transfer the
donor overlayer 24 in section "3a" is greater than the energy
required to transfer the donor overlayer 24 in section "3b". In
section "3c", the thermal print head 10 is de-energized. The
resulting in the thickness of the protective overlayer 14 in
section "3a" is greater than the thickness of the protective
overlayer 14 in section "3b", and there is an absence of protective
overlayer in section "3c". In this embodiment, the thickness of
protective overlayer 14 at any given point is limited to the
thickness defined in either section "3a", "3b", or "3c".
[0101] Referring now to FIG. 4, there is shown a product made in
accordance with the preferred method of the current invention. For
the purpose of discussion, the product shown is a label 30. On the
image layer 26 of label 30 is an image 32, and the protective
overlayer 14 of label 30 comprises information-bearing indicia 34.
The information-bearing indicia 34 shown is in the form of a bar
code. The energy required to transfer the protective overlayer 14
in section "4a" is greater than the energy required to transfer the
protective overlayer 14 in section "4b" resulting in the thickness
of the protective overlayer 14 in section "4a" to be greater than
the thickness of the protective overlayer 14 in section "4b". The
resulting thickness differential defines indicia. It should be
noted that the information-bearing indicia is not limited to a bar
code, but can take any form, for example Braille, text, symbols,
etc. As shown in FIG. 4, the location of the information bearing
indicia 34 overlap the image 32 on print 18. Protective overlayer
14 is substantially transparent, and the incorporated
information-bearing indicia 34 in protective overlayer 14 does not
add any human detectable opacity. Therefore, image 32 is viewable
through protective overlayer 14 and information-bearing indicia
34.
[0102] Shown in FIG. 5 is a product 36 onto which label 30 is
applied. Image 32 on label 30 is visible to the viewer and human
readable. The information-bearing indicia 34 is machine-readable,
therefore, substantially invisible to the viewer.
[0103] Next will be described several methods for reading the data
embedded in the protective overlayer 14. The methods described are
forms of surface profilometry. It should be noted that we are not
limited to the methods described herein, and that other methods
reading the data by surface profilometry may be applied.
[0104] FIG. 6A shows a topographic representation of
information-bearing indicia 34 taken along a multiple traces using
a Gould Microtopographer stylus instrument. This technique for
measuring/mapping the physical surface contour is done with a
contact instrument using a diamond stylus with a light load (50
mg). The diamond stylus tip has a 2.5-micron radius with a 90
degree included angle. Multiple traces are required to map the
surface of an area. A single trace as shown in FIG. 6B is limited
to surface contact area of the stylus tip. In this example, it
should be noted that measurements could be read directly from the
graph to determine the physical size relationship of the surface
characteristics. The stylus indexes after each trace, and the
system is calibrated to specimen # 2071 traceable to the National
Institute of Standards and Technology (NIST). In this example, the
information shown in the topographic representation can be
translated into bar code information by converting the peaks to
bars and the valleys to spaces.
[0105] FIGS. 7A and 7B show a topographic representation of
information-bearing indicia 34 mapped using a Zygo NewView 5000.
This technique for measuring/mapping the surface is done using a
non-contact 3D optical profiler, having sub-nanometer z resolution,
and is capable of mapping areas up to 17.5 mm. FIG. 7A is an
oblique view of the total mapped area, while FIG. 7B is an
elevation view showing the surface profile.
[0106] FIG. 8A represents a means for reading the information
contained in the code within the overcoat using direct illumination
40 and an optical detector 42. The preferred illumination source
for this application is a collimated visible laser beam in the
600-700 nm wavelength range, as is commonly found within both
handheld and point-of-sale bar code readers, or alternatively, a
focussed spot of light from a non-coherent light source such as an
incandescent or arc lamp. This type of reader detects the change in
surface characteristics. In this method, an illuminating beam 44 is
placed at a preferred incident angle 46 while the optical detector
42 is held at a suitable detection angle 48 such as to maximize the
response of the detector to the modulation of a reflected light 50
beam as the target area is scanned. The preferred incident and
detection angles will depend upon the actual materials used and
degree of scattering from the encoded areas. Scanning is
accomplished either by relative motion of the reader and code
symbol or by opto-mechanical deflection of the incident beam
typically using a oscillating or rotating mirror as is common
practice in bar code readers.
[0107] FIG. 8B represents a means for reading the information
contained in the code within the overcoat using direct illumination
40 and optical detection 42 with addition of a pre-polarizer 52
and, subsequently, a polarization analyzer 54. The preferred
illumination source for this application is a collimated visible
laser beam in the 600-700 nm wavelength range, as is commonly found
within both handheld and point-of-sale bar code readers.
Alternatively, a focussed spot of light from an non-coherent light
source, such as, an incandescent or arc lamp, the output of which
has been polarized by a polarizing element may be used (not
shown).
[0108] In this method, the polarized illuminating beam 44 is placed
at a preferred incident angle 46 while the detector 42 is held at a
suitable detection angle 48 such as to maximize the response of the
detector to the modulation of the reflected light beam as the
target area is scanned. The polarization analyzer 54 is used as an
analyzer to enable the discrimination between light whose
polarization has been altered by the encodement from light whose
polarization has not been effected. The preferred incident,
detection, and polarization angles will depend upon the actual
materials used and degree of de-polarization of the incident light
in the encoded areas. Scanning is accomplished either by relative
motion of the reader and code symbol or by opto-mechanical
deflection of the incident beam typically using a galvanometer or
rotating mirror as is common practice in bar code readers.
[0109] Common to both FIGS. 8A and 8B, as print 18 moves in the
direction of arrow 56, illuminating beam 44 illuminates
information-bearing indicia 34 along a single trace in a linear
fashion. In order to illuminate a larger area of the
information-bearing indicia 34, multiple traces need to be taken in
a step-wise function.
[0110] In the embodiment where the indicia 34 is a machine-readable
code XX printed in a bar code format. One example of the bar code
XX is the Universal Product Code (UPC). Other examples of standard
ID or linear bar codes are "2 of 5" and "3 of 9". The previously
mentioned bar codes are understood by those skilled in the art.
These bar codes are read by scanning in a direction that is
perpendicular to the bars and spaces via a bar code reader, such
as, those commonly used in grocery store checkouts. However, it is
to be understood that any suitable machine-readable code may be
used that is currently available or may become available, for
example, but not by way of limitation, a bar code.
[0111] In another embodiment where the indicia 34 is a readable
pattern such as Braille. The incident-beam laser scans the
topographic representation of information-bearing indicia, and via
reflected or absorbed light records the topographic map in memory.
The topographic map is then compared by running through a pattern
recognition algorithm and matched known patterns for Braille
letters. The pattern, for example, but not by way of limitation,
Braille.
[0112] In yet another embodiment where the indicia 34 represents a
binomial code, the incident-beam laser scans the code and it is
decoded via a binomial code look up table.
[0113] Referring now to FIG. 9, there is shown an alternate product
made in accordance with the preferred method of the current
invention. For the purpose of discussion, the product shown is a
label 30. FIG. 9 is an exploded view of a print having identical
indicia printed on the image layer 26 and in a protective overlayer
14. As shown in FIG. 9, the represented indicia is a 1-Dimensional
(1-D) bar code. It should be noted that the indicia is not limited
to a bar code, but can take any form, for example, Braille, text,
symbols, 2-Dimensional code, etc. Image 32 and protective overlayer
14 of label 30 comprise information-bearing indicia 34. As shown in
FIG. 9, the information bearing indicia 34 and image 32 comprise
the same information, and the location of the information bearing
indicia 34 exactly overlap the image 32 on print 18.
[0114] The reflective characteristics of the protective overlayer
14 are altered in the area of the information-bearing indicia 34.
In addition, the reflective characteristics of the protective
overlayer 14 are altered in the area that is in register with image
32. By default, the reflective characteristics of image 32 are such
that light is absorbed in printed areas and reflected in
non-printed area. By changing the reflective characteristics of the
protective overlayer 14 in register with the reflective
characteristics of image 32, the readability of the indicia on
label 30 is enhanced when read with an incident-beam laser
scanner.
[0115] FIGS. 10-13 show various arrangements of indicia encoded
into the protective overlayer 14. Specifically, FIG. 10 shows a
minimum thickness of the protective overlayer applied over the
entire surface of print 18, and a second greater thickness of the
protective overlayer applied to the surface of print 18 where image
32 is located. The difference between the minimum and second
greater thickness is such that a detectable difference can be
discerned. FIG. 11 shows a maximum thickness of the protective
overlayer applied to the surface of print 18 where image 32 is
located, and an absence of the protective overlayer where there is
an absence of an image. FIG. 12 shows a minimum thickness of the
protective overlayer applied over the entire surface of print 18,
and a maximum thickness of the protective overlayer applied to the
surface of print 18 where there is an absence of an image. FIG. 13
shows a maximum thickness of the protective overlayer applied to
the surface of print 18 where there is an absence of an image, and
a maximum thickness of the protective overlayer applied to the
surface of print 18 where image 32 is located.
[0116] A test was done to determine the readability of a bar code
made in accordance with the present invention as shown in FIG. 9.
Two sample bar codes were prepared. Sample "A" is a process black
bar code printed using cyan, magenta, and yellow dyes on a white
receiver. Sample "B" is a process black bar code printed using
cyan, magenta, and yellow dyes on a white receiver plus image-wise
application of the protective overlayer. Image-wise in this context
meaning that the protective overlayer is applied only in the black
areas of the bar code. Both samples were read using a 660-nm
wavelength bar code reader. On a scale of 0-4.0, with 4.0 being the
highest rating, sample "A" scored a rating of 3.5, and sample "B"
scored a rating of 3.8. A 10% rating increase was realized when the
protective overlayer was applied in an image-wise fashion.
[0117] In addition, it was noted that there is a difference in the
readability of thermally printed bar codes depending on the
orientation of the bar code to the direction of print. The
difference was more notable when a protective overlayer was
applied. Two sample bar codes were prepared. Sample "AA" is a
process black bar code printed using cyan, magenta, and yellow dyes
on a white receiver, an image-wise application of the protective
overlayer, and where the orientation of the bars is 90.degree. to
the direction of print. Sample "BB" is a process black bar code
printed using cyan, magenta, and yellow dyes on a white receiver,
an image-wise application of the protective overlayer, and where
the orientation of the bars is 0.degree. to the direction of print.
Both samples were read using a 660-nm wavelength bar code reader.
On a scale of 0-4.0, with 4.0 being the highest rating, sample "AA"
scored a rating of 3.0 and sample "BB" scored a rating of 3.8. A
25% rating increase was realized when the orientation of the bar
code was 0.degree. to the direction of print.
[0118] The entire contents of the patents and other publications
referred to in this specification are incorporated herein by
reference.
[0119] It should be noted that the image-bearing print portion of
this invention is not limited to a thermally transferred dye print
and can include any other method of creating a print, for example,
inkjet, electrophotograhic, lithography, etc.
[0120] The invention has been described in detail with particular
reference to certain preferred embodiments thereof, but it will be
understood that variations and modifications can be effected within
the scope of the invention.
Parts List
[0121] 10 print head
[0122] 12 resistive elements
[0123] 14 protective overlayer
[0124] 16 donor element
[0125] 18 print
[0126] 22 donor support
[0127] 24 donor overlayer
[0128] 26 image layer
[0129] 28 support media
[0130] 30 label
[0131] 32 image
[0132] 34 indicia
[0133] 36 product
[0134] 42 optical detection
[0135] 44 illuminating beam
[0136] 46 incident angle
[0137] 48 detection angle
[0138] 50 reflective light
[0139] 52 pre-polarizer
[0140] 54 polarization analyzer
[0141] 56 arrow
* * * * *