U.S. patent application number 10/324105 was filed with the patent office on 2003-09-11 for magnetic recording medium, a method of manufacturing the same, and a magnetic storage using the magnetic recording medium.
This patent application is currently assigned to Fuji Electric Co., Ltd.. Invention is credited to Iso, Akira, Nakamura, Miyabi, Shimizu, Takahiro, Takizawa, Naoki, Uwazumi, Hiroyuki.
Application Number | 20030170501 10/324105 |
Document ID | / |
Family ID | 27599804 |
Filed Date | 2003-09-11 |
United States Patent
Application |
20030170501 |
Kind Code |
A1 |
Iso, Akira ; et al. |
September 11, 2003 |
Magnetic recording medium, a method of manufacturing the same, and
a magnetic storage using the magnetic recording medium
Abstract
A magnetic recording medium and method of manufacturing thereof
facilitates to prevent a film inflation from occurring in an
environmental condition range between -40.degree. C. and 80.degree.
C. and an 80% relative humidity. The magnetic recording medium
includes a plastic substrate and an undercoating layer on the
plastic substrate. The undercoating layer is provided with a
columnar structure, which prevents water (moisture) between the
plastic substrate and the undercoating layer from aggregating and,
therefore, the film inflation from occurring.
Inventors: |
Iso, Akira; (Nagano, JP)
; Uwazumi, Hiroyuki; (Nagano, JP) ; Shimizu,
Takahiro; (Nagano, JP) ; Takizawa, Naoki;
(Nagano, JP) ; Nakamura, Miyabi; (Ibaragi,
JP) |
Correspondence
Address: |
STAAS & HALSEY LLP
SUITE 700
1201 NEW YORK AVENUE, N.W.
WASHINGTON
DC
20005
US
|
Assignee: |
Fuji Electric Co., Ltd.
Kawasaki
JP
|
Family ID: |
27599804 |
Appl. No.: |
10/324105 |
Filed: |
December 20, 2002 |
Current U.S.
Class: |
428/832.4 ;
427/127; 428/836.3; G9B/5.288; G9B/5.299 |
Current CPC
Class: |
G11B 5/7369 20190501;
G11B 5/8404 20130101; G11B 5/73923 20190501 |
Class at
Publication: |
428/694.0TS ;
428/694.0TP; 428/694.0BP; 427/127 |
International
Class: |
B05D 005/12 |
Foreign Application Data
Date |
Code |
Application Number |
Dec 25, 2001 |
JP |
2001-392508 |
Claims
What is claimed is:
1. A magnetic recording medium, comprising: a nonmagnetic substrate
made of a polymer resin; a magnetic layer above the nonmagnetic
substrate; a protection layer above the magnetic layer; and a
liquid lubricant layer on the protection layer.
2. The magnetic recording medium according to claim 1, further
comprising: a nonmagnetic undercoating layer on the nonmagnetic
substrate.
3. The magnetic recording medium according to claim 2, wherein the
nonmagnetic undercoating layer comprises Ru, Re, Os, or Mo.
4. The magnetic recording medium according to claim 3, wherein the
nonmagnetic undercoating layer comprises an alloy comprising Ru,
Re, Os, or Mo.
5. The magnetic recording medium according to claim 2, wherein the
nonmagnetic undercoating layer comprises an alloy comprising W and
Ti, Zr, or Cr.
6. The magnetic recording medium according to claim 2, wherein the
nonmagnetic undercoating layer comprises an alloy comprising Ni and
P.
7. The magnetic recording medium according to claim 2, further
comprising: an intermediate layer on the nonmagnetic undercoating
layer.
8. The magnetic recording medium according to claim 7, wherein the
intermediate layer comprises Ru, Re, Os, or Mo as a main component
thereof.
9. The magnetic recording medium according to claim 8, wherein the
intermediate layer comprises an alloy comprising Ru, Re, Os, or
Mo.
10. The magnetic recording medium according to claim 7, wherein the
intermediate layer comprises an alloy comprising W and Ti, Zr, or
Cr.
11. The magnetic recording medium according to claim 7, wherein the
intermediate layer comprises an alloy comprising Ni and P.
12. A method of manufacturing a magnetic recording medium
comprising a nonmagnetic substrate made of a polymer resin, a
magnetic layer above the nonmagnetic substrate, a protection layer
above the magnetic layer, and a liquid lubricant layer on the
protection layer, the method comprising: forming an undercoating
layer on the nonmagnetic substrate under a pressure of 5 mTorr or
higher.
13. The method of manufacturing the magnetic recording medium
described in claim 12, the method comprising: forming the
undercoating layer under a pressure of 60 mTorr or higher.
14. The method according to claim 12, wherein the undercoating
layer comprises a CrW alloy.
15. The method according to claim 12, wherein the undercoating
layer comprises an Mo as a main component thereof.
16. The method according to claim 12, wherein the undercoating
layer comprises an NiP alloy.
17. The method according to claim 13, wherein the undercoating
layer comprises a TiW alloy.
18. The method according to claim 13, wherein the undercoating
layer comprises Ru, Re or Os as a main component thereof.
19. A method of manufacturing a magnetic recording medium
comprising a nonmagnetic substrate made of a polymer resin, a
magnetic layer above the nonmagnetic substrate, a protection layer
above the magnetic layer, and a liquid lubricant layer on the
protection layer, the method comprising: forming an intermediate
layer on the nonmagnetic substrate under a pressure of 5 mTorr or
higher.
20. The method of manufacturing the magnetic recording medium
described in claim 19, the method comprising: forming the
intermediate layer under a pressure of 60 mTorr or higher.
21. The method according to claim 19, wherein the intermediate
layer comprises a CrW alloy.
22. The method according to claim 19, wherein the intermediate
layer comprises Mo as a main component thereof.
23. The method according to claim 19, wherein the intermediate
layer comprises an NiP alloy.
24. The method according to claim 20, wherein the intermediate
undercoating layer comprises a TiW alloy.
25. The method according to claim 20, wherein the intermediate
layer comprises Ru, Re or Os as a main component thereof.
26. A magnetic storage, comprising: a magnetic recording medium
mounted thereon, the magnetic recording medium comprising a
nonmagnetic substrate made of a polymer resin, a magnetic layer
above the nonmagnetic substrate, a protection layer above the
magnetic layer, and a liquid lubricant layer on the protection
layer.
27. The magnetic storage according to claim 26, further comprising
a nonmagnetic undercoating layer on the nonmagnetic substrate.
28. The magnetic recording medium according to claim 26, further
comprising: an intermediate layer on the nonmagnetic undercoating
layer.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims the benefit of Japanese Application
No. 2001-392508, filed Dec. 25, 2001, in the Japanese Patent
Office, the disclosure of which is incorporated herein by
reference.
BACKGROUND OF THE INVENTION
[0002] 1. Field of the Invention
[0003] The present invention relates to a magnetic recording medium
mounted on an external storage of a computer such as a magnetic
storage, a method of manufacturing the magnetic recording medium,
and the magnetic storage using the magnetic recording medium.
[0004] 2. Description of the Related Art
[0005] When realizing magnetic recording media exhibiting a high
recording density and compatibility with a low-floating-height
magnetic head, various compositions and structures have been
proposed for a magnetic layer of the magnetic recording media, as
well as various materials for a nonmagnetic undercoating layer and
various materials for a nonmagnetic substrate. Although aluminum
and glass are the main materials for the nonmagnetic substrate at
present, a polymer resin substrate, a so-called plastic substrate,
has been proposed recently for the nonmagnetic substrate.
[0006] To facilitate a lower-height floating of the magnetic head
so that the high recording density realized in the magnetic
recording media may be fully utilized, the magnetic recording media
needs to be used reliably for a long time in various environments.
The magnetic recording media is also applied in digital household
appliances to be used reliably for a long time. The conditions,
under which the magnetic recording media are expected to be useful,
extend from very cold -40.degree. C. to very hot and humid
80.degree. C. and 80% of relative humidity. Some household
appliance makers require that the magnetic recording media work
normally for five years under conditions described above. It is
necessary that the magnetic recording media for the household
appliances be manufactured with low costs. Although the polymer
resin substrate may be used for the substrate of the magnetic
recording media, film inflation (a kind of layer parting) may occur
in the magnetic recording media including the polymer resin
substrate.
[0007] In view of the foregoing, according to an aspect of the
present invention, a magnetic recording medium is provided, which
obviates the problems described above. It is another aspect of the
present invention to provide a method of manufacturing the magnetic
recording medium and the magnetic storage mounting the magnetic
recording medium thereon.
SUMMARY OF THE INVENTION
[0008] Various aspects and advantages of the invention will be set
forth in part in the description that follows and, in part, will be
obvious from the description, or may be learned by practice of the
invention.
[0009] Typically, an undercoating layer is formed on a plastic
substrate or an intermediate layer is formed below a magnetic layer
to improve electromagnetic conversion characteristics of a magnetic
recording medium. Film inflation is prevented from occurring by
controlling a structure of the undercoating layer or the
intermediate layer. To control the layer structure, an appropriate
material of the undercoating layer or the intermediate layer may be
selected to control deposition conditions, especially a pressure,
under which the undercoating layer or the intermediate layer is
formed. Materials, which facilitate providing a columnar structure
in a relatively wide pressure range, include Mo, CrW and NiP. TiW
and Ru, which facilitate obtaining excellent electromagnetic
conversion characteristics, provide the undercoating layer or the
intermediate layer with the columnar structure, when the
undercoating layer or the intermediate layer is formed under a high
pressure.
[0010] The film inflation, which poses problems on the magnetic
recording media including the plastic substrate, is caused by
aggregation of water (moisture). It is possible to prevent water
(moisture) from aggregating and the film inflation from occurring
by controlling the structure of the undercoating layer or the
intermediate layer.
[0011] According to a first aspect of the present invention, there
is provided a magnetic recording medium including: a nonmagnetic
substrate made of a polymer resin; a magnetic layer above the
nonmagnetic substrate; a protection layer above the magnetic layer;
and a liquid lubricant layer on the protection layer.
[0012] The magnetic recording medium further includes a nonmagnetic
undercoating layer on the nonmagnetic substrate.
[0013] Furthermore, the nonmagnetic undercoating layer is a metal
layer including Ru, Re, Os, or Mo, an alloy layer includes Ru, Re,
Os, or Mo, an alloy layer includes W and one or more elements
including Ti, Zr, or Cr, or an alloy layer including Ni and P.
[0014] According to a second aspect of the present invention, there
is provided a method of manufacturing a magnetic recording medium
including forming a TiW alloy undercoating layer under a pressure
of 60 mTorr or higher, forming a CrW alloy undercoating layer under
a pressure of 5 mTorr or higher, forming a metal undercoating layer
including Ru, Re or Os as a main component thereof under the
pressure of 60 mTorr or higher, forming an alloy undercoating layer
including Ru, Re or Os as a main component thereof under the
pressure of 60 mTorr or higher, forming a metal undercoating layer
including Mo as a main component thereof under the pressure of 5
mTorr or higher, forming an alloy undercoating layer containing Mo
as the main component thereof under the pressure of 5 mTorr or
higher, or forming an NiP alloy undercoating layer under the
pressure of 5 mTorr or higher.
[0015] The magnetic recording medium further includes an
intermediate layer on the nonmagnetic undercoating layer.
[0016] The intermediate layer is a metal layer including Ru, Re,
Os, or Mo, an alloy layer including Ru, Re, Os, or Mo, an alloy
layer including W and one or more elements including Ti, Zr, or Cr,
or an alloy layer including Ni and P.
[0017] According to a third aspect of the invention, there is
provided a method of manufacturing a magnetic recording medium
including forming a TiW alloy intermediate layer under a pressure
of 60 mTorr or higher, forming a CrW alloy intermediate layer under
a pressure of 5 mTorr or higher, forming a metal intermediate layer
including Ru, Re or Os as a main component thereof under the
pressure of 60 mTorr or higher, forming an alloy intermediate layer
including Ru, Re or Os as a main component thereof under the
pressure of 60 mTorr or higher, forming a metal intermediate layer
including Mo as a main component thereof under the pressure of 5
mTorr or higher, forming an alloy intermediate layer including Mo
as a main component thereof under the pressure of 5 mTorr or
higher, or forming a NiP alloy intermediate layer under the
pressure of 5 mTorr or higher.
[0018] According to a fourth aspect of the invention, there is
provided a magnetic storage including the above described magnetic
recording medium mounted thereon.
[0019] These together with other aspects and advantages which will
be subsequently apparent, reside in the details of construction and
operation as more fully hereinafter described and claimed,
reference being had to the accompanying drawings forming a part
thereof, wherein like numerals refer to like parts throughout.
BRIEF DESCRIPTION OF THE DRAWINGS
[0020] These and other aspects and advantages of the invention will
become apparent and more readily appreciated from the following
description of the embodiments, taken in conjunction with the
accompanying drawings of which:
[0021] FIG. 1 is a cross sectional view of a magnetic recording
medium, according to a first aspect or a second aspect of the
present invention.
[0022] FIG. 2 is a cross sectional view of the magnetic recording
medium, according to a third aspect of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0023] Reference will now be made in detail to the embodiments of
the present invention, examples of which are illustrated in the
accompanying drawings, wherein like reference numerals refer to
like elements throughout. The embodiments are described below in
order to explain the present invention by referring to the
figures.
[0024] FIG. 1 is a cross sectional view of a magnetic recording
medium, according to a first aspect or a second aspect of the
present invention.
[0025] Referring now to FIG. 1, the magnetic recording medium,
according to the first aspect, includes a laminate formed of a
plastic substrate 1, an undercoating layer 2, a CoCrPt--SiO.sub.2
layer 3, a Ti layer 4, a CN layer 5 and a lubricant layer 6. The
undercoating layer 2 is formed by depositing a TiW layer, a CrW
layer, a Mo layer or a NiP layer under a pressure between 5 mTorr
and 30 mTorr. A thickness of the undercoating layer 2 is fixed at
10 nm. Then, environmental tests are conducted in a constant
temperature oven to investigate whether film inflation occurs in
the magnetic recording medium, according to the first aspect of the
present invention. The magnetic recording medium is stored at first
at a room temperature, then at 80.degree. C. and 80% of relative
humidity for 4 hours, then at -40.degree. C. for 4 hours, and again
at the room temperature. Then, the magnetic recording medium is
observed under an optical microscope to find whether film inflation
occurs. Table 1 lists the results.
1 TABLE 1 Undercoating layers Deposition conditions TiW CrW Mo NiP
5 mTorr x .smallcircle. .smallcircle. .smallcircle. 15 mTorr x
.smallcircle. .smallcircle. .smallcircle. 30 mTorr x .smallcircle.
.smallcircle. .smallcircle. .smallcircle.: Film inflation is not
caused. x: Film inflation is caused.
[0026] Observations in a transmission electron microscope have
revealed that the CrW layer, the Mo layer, and the NiP layer have a
columnar structure or a structure near to the columnar structure.
The TiW layer does not have the columnar structure but has a
uniform structure. In other words, the TiW layer does not have a
distinctive structure. Film inflation is not caused when the CrW
layer, the Mo layer, or the NiP layer is used for the undercoating
layer 2. The film inflation occurs when the TiW layer is used for
the undercoating layer 2.
[0027] Referring again to FIG. 1, the magnetic recording medium,
according to the second aspect of the present invention, includes a
laminate formed of the plastic substrate 1, the undercoating layer
2, the CoCrPt--SiO.sub.2 layer 3, the Ti layer 4, the CN layer 5
and the lubricant layer 6. The undercoating layer 2 is formed by
depositing the TiW layer, or a Ru layer under a pressure between 30
mTorr and 80 mTorr, according to the second aspect of the present
invention. A thickness of the undercoating layer 2 is fixed at 10
nm. Then, environmental tests are conducted in the constant
temperature oven to investigate whether the film inflation occurs
in the magnetic recording medium, according to the second aspect of
the present invention. The magnetic recording medium is stored at
first at the room temperature, then at 80.degree. C. and 80% of
relative humidity for 4 hours, then at -40.degree. C. for 4 hours,
and again at the room temperature. Then, the magnetic recording
medium is observed under an optical microscope to find whether film
inflation occurs. Table 2 lists the results.
2 TABLE 2 Undercoating layers Deposition conditions TiW Ru 30 mTorr
x x 45 mTorr x x 60 mTorr .smallcircle. .smallcircle. 80 mTorr
.smallcircle. .smallcircle. .smallcircle.: Film inflation is not
caused. x: Film inflation is caused.
[0028] Observations in a transmission electron microscope have
revealed that the TiW layer and the Ru layer do not have the
columnar structure when the TiW layer and the Ru layer are formed
under a low pressure but have the columnar structure or a structure
near to the columnar structure when the TiW layer and the Ru layer
are formed under a high pressure. The film inflation occurs in the
TiW layer and the Ru layer formed under a pressure of 60 mTorr or
higher.
[0029] FIG. 2 is a cross sectional view of the magnetic recording
medium according to a third aspect of the present invention.
[0030] Referring to FIG. 2, the magnetic recording medium,
according to the third aspect of the present invention, includes a
laminate formed of a plastic substrate 7, an undercoating layer 8,
an intermediate layer 9, a CoCrPt--SiO.sub.2 layer 10, a Ti layer
11, a CN layer 12 and a lubricant layer 13. The undercoating layer
8 is formed by depositing a TiW layer, or a CrW layer under a
pressure of 30 mTorr. A thickness of the undercoating layer 8 is
fixed at 10 nm. The intermediate layer 9 is formed by depositing
the Ru layer at a pressure between 30 mTorr and 80 mTorr, according
to the third aspect of the present invention. A thickness of the
intermediate layer 9 is fixed at 20 nm. Then, environmental tests
are conducted in the constant temperature oven to investigate
whether the film inflation occurs in the magnetic recording medium,
according to the third aspect of the present invention. The
magnetic recording medium is stored at first at the room
temperature, then at 80.degree. C. and 80% of relative humidity for
4 hours, then at -40.degree. C. for 4 hours, and again at the room
temperature. Then, the magnetic recording medium is observed under
the optical microscope to find whether the film inflation occurs.
Table 3 lists the results.
3TABLE 3 Deposition conditions for the Undercoating layers
intermediate layers CrW TiW 30 m Torr x x 60 m Torr .smallcircle. x
80 m Torr .smallcircle. x .smallcircle.: Film inflation is not
caused. x: Film inflation is caused.
[0031] Observations in the transmission electron microscope have
revealed that the CrW undercoating layer has the columnar
structure. The TiW undercoating layer does not have the columnar
structure but has the uniform structure. In other words, the TiW
undercoating layer does not have the distinctive structure. The Ru
intermediate layer formed under a pressure of 60 mTorr or higher
has the columnar structure. When the undercoating layer and the
intermediate layer have the respective columnar structures, the
film inflation does not occur. When the undercoating layer or the
intermediate layer does not have the columnar structure, film
inflation occurs.
[0032] The magnetic recording medium as previously set forth, may
be mounted in a magnetic storage. U.S. Publication No. US
2002/0141104 A1 titled "Servo Control Method and Servo Control
System for Magnetic Disc Drive" to Sato et al., refers to
incorporating the magnetic recording medium in the magnetic
storage, description of which is incorporated herein by
reference.
[0033] According to an aspect of the present invention, a magnetic
recording medium, which does not cause film inflation in an
environmental condition range between -40.degree. C. and 80.degree.
C. and 80% of relative humidity, is obtained by providing an
undercoating layer on a plastic substrate with a columnar
structure.
[0034] The many features and advantages of the invention are
apparent from the detailed specification and, thus, it is intended
by the appended claims to cover all such features and advantages of
the invention that fall within the true spirit and scope of the
invention. Further, since numerous modifications and changes will
readily occur to those skilled in the art, it is not desired to
limit the invention to the exact construction and operation
illustrated and described, and accordingly all suitable
modifications and equivalents may be resorted to, falling within
the scope of the invention.
* * * * *