U.S. patent application number 10/272616 was filed with the patent office on 2003-08-21 for detergent compositions.
Invention is credited to Allan, William D., Dole, Victoria F., Hill, Jonathan R., Lukenbach, Elvin R., Mc Culloch, Laura, Nystrand, Glenn A., Taylor, Charles J..
Application Number | 20030158065 10/272616 |
Document ID | / |
Family ID | 27268656 |
Filed Date | 2003-08-21 |
United States Patent
Application |
20030158065 |
Kind Code |
A1 |
Lukenbach, Elvin R. ; et
al. |
August 21, 2003 |
Detergent compositions
Abstract
A conditioning shampoo composition comprised of a mixture of
anionic and amphoteric surfactants and optional conditioners which
imparts cleansing, wet detangling, dry detangling and manageability
to hair and which is relatively non-irritating and thus suitable
for use by young children and adults having sensitive skin and
eyes.
Inventors: |
Lukenbach, Elvin R.;
(Flemington, NJ) ; Dole, Victoria F.; (Whitehouse
Station, NJ) ; Nystrand, Glenn A.; (Lebanon, NJ)
; Mc Culloch, Laura; (Basking Ridge, NJ) ; Allan,
William D.; (Worthing, GB) ; Hill, Jonathan R.;
(Nottingham, GB) ; Taylor, Charles J.; (Hampshire,
GB) |
Correspondence
Address: |
AUDLEY A. CIAMPORCERO JR.
JOHNSON & JOHNSON
ONE JOHNSON & JOHNSON PLAZA
NEW BRUNSWICK
NJ
08933-7003
US
|
Family ID: |
27268656 |
Appl. No.: |
10/272616 |
Filed: |
October 16, 2002 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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10272616 |
Oct 16, 2002 |
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09487109 |
Jan 19, 2000 |
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6489286 |
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09487109 |
Jan 19, 2000 |
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08789593 |
Jan 24, 1997 |
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6090773 |
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60010784 |
Jan 29, 1996 |
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Current U.S.
Class: |
510/267 ;
510/425; 510/428; 510/473; 510/476 |
Current CPC
Class: |
A61K 8/8152 20130101;
A61K 8/8158 20130101; A61K 8/731 20130101; A61K 8/463 20130101;
A61Q 5/12 20130101; A61K 2800/5426 20130101; A61K 8/86 20130101;
A61K 8/737 20130101; A61K 8/44 20130101; A61Q 19/005 20130101; A61Q
5/02 20130101; A61K 2800/596 20130101 |
Class at
Publication: |
510/267 ;
510/425; 510/428; 510/473; 510/476 |
International
Class: |
C11D 017/08; C11D
017/00 |
Foreign Application Data
Date |
Code |
Application Number |
Jan 3, 1997 |
GB |
9700059.0 |
Claims
We claim:
1. A detergent composition comprising: a surfactant portion
comprising: 1. a nonionic surfactant; 2. an amphoteric surfactant;
and 3. an anionic surfactant; and a conditioner portion comprising
at least two cationic conditioning polymers selected from: 1. a
cationic cellulose derivative; 2. a cationic guar derivative; and
3. a homopolymer or copolymer of a cationic monomer selected from:
a. a monomer having the formula 28 wherein R is H or CH.sub.3, Y is
O or NH, R.sub.1 is an alkylene group having from about 2 to about
6-carbon atoms, R.sub.2, R.sub.3 and R.sub.4 are each independently
an alkyl group or hydroxyalkyl group having from about 1 to about
22 carbon atoms, and X is a monovalent anion selected from halide
and alkyl sulfate having from about 1 to about 4 carbon atoms, or
b. diallyidimethylammonium chloride.
2. The detergent composition of claim 1 wherein the surfactant
portion is present in an amount, based upon the total weight of the
detergent composition, of from about 5 percent to about 20
percent.
3. The detergent composition of claim 1 wherein the conditioner
portion is present in an amount, based upon the total weight of the
detergent composition, from about 0.01 percent to about 1.0
percent.
4. The detergent composition of claim 1 wherein the conditioner
portion is present in an amount, based upon the total weight of the
detergent composition, from about 0.01 percent to about 0.5
percent.
5. The detergent composition of claim 1 wherein the conditioner
portion is present in an amount, based upon the total weight of the
detergent composition, from about 0.01 percent to about 0.3
percent.
6. The detergent composition of claim 1 wherein the cationic
cellulose derivative is polyquaternium-10 and is present in an
amount, based upon the total weight of the detergent composition,
of from about 0.01 percent to about 0.5 percent.
7. The detergent composition of claim 1 wherein the cationic guar
derivative is guar hydroxypropyltrimonium chloride and is present
in an amount, based upon the total weight of the detergent
composition, of from about 0.01 percent to about 0.5 percent.
8. The detergent composition of claim 1 wherein at least one of the
cationic conditioning polymers is a homopolymer or copolymer of a
monomer having the formula 29and is present in an amount, based
upon the total weight of the detergent composition, of from about
0.01 percent to about 0.5 percent.
9. The detergent composition of claim 1 wherein at least one of the
cationic conditioning polymers is an acrylamidopropyltrimonium
chloride/acrylamide copolymer and is present in an amount, based
upon the total weight of the detergent composition, of from about
0.01 percent to about 0.5 percent.
10. The detergent composition of claim 1 wherein at least one of
the cationic conditioning polymers is selected from
polyquaternium-6 or polyquaternium-7 and is present in an amount,
based upon the total weight of the detergent composition, of from
about 0.01 percent to about 0.5 percent.
11. The detergent composition of claim 1 wherein the nonionic
surfactant comprises: a) a polyoxyethylene derivative of a polyol
ester 1. derived from a fatty acid containing from about 8 to about
22 carbon atoms and a polyol selected from sorbitol, sorbitan,
glucose, 1-methyl glucoside, polyglucose having an average of about
1 to about 3 glucose residues, glycerine, pentaerythritol and
mixtures thereof, 2. containing an average of from about 10 to
about 120 oxyethylene units, and 3. having an average of from about
1 to about 3 fatty acid residues per molecule of the
polyoxyethylene derivative of polyol ester, b) an alkyl glucoside
having an alkyl group containing from about 6 to about 22 carbon
atoms and having from about 1 to about 6 glucose residues per
molecule of alkyl glucoside, or c) mixtures thereof, wherein the
nonionic surfactant is present in an amount, based upon the total
weight of the detergent composition, of from about 0.1 percent to
about 10 percent.
12. The detergent composition of claim 1 wherein the amphoteric
surfactant comprises: a. an amphocarboxylate compound of the
formula: A-CONH(CH.sub.2).sub.xN.sup.+R.sub.5R.sub.6R.sub.7 wherein
A is an alkyl or alkenyl group having from about 7 to about 21
carbon atoms; x is an integer of from about 2 to about 6; R.sub.5
is hydrogen or a carboxyalkyl group containing from about 2 to
about 3 carbon atoms; R.sub.6 is a hydroxyalkyl group containing
from about 2 to about 3 carbon atoms or is a group of the formula:
R.sub.8--O--(CH.sub.2).sub.nCO.sub.2.sup.- wherein R.sub.8 is an
alkylene group having from about 2 to about 3 carbon atoms and n is
1 or 2; and R.sub.7 is a carboxyalkyl group containing from about 2
to about 3 carbon atoms; b. an alkyl betaine of the formula:
B-N.sup.+R.sub.9R.sub.10(CH.sub.2).sub.pCO.sub.2.sup.- wherein B is
an alkyl or alkenyl group having from about 8 to about 22 carbon
atoms; R.sub.9 and R.sub.10 are each independently an alkyl group
or a hydroxyalkyl group having from about 1 to about 4 carbon
atoms; and p is 1 or 2; c. an amidoalkyl betaine of the formula:
D-CO--NH(CH.sub.2).sub.q--N.sup.+R.sub.11R.sub.12(CH.sub.2).sub.mCO.sub.2-
.sup.- wherein D is an alkyl or alkenyl group having from about 7
to about 21 carbon atoms; R.sub.11 and R.sub.12 are each
independently an alkyl or a hydroxyalkyl group having from about 1
to about 4 carbon atoms; q is an integer from about 2 to about 6;
and m is 1 or 2; d. an amidoalkyl sultaine of the formula: 30
wherein E is an alkyl group or alkenyl group having from about 7 to
about 21 carbon atoms; R.sub.14 and R.sub.15 is are each
independently an alkyl group or a hydroxyalkyl group having from
about 1 to about 4 carbon atoms; r is an integer from about 2 to
about 6; and R.sub.13 is an alkylene or hydroxyalkylene group
having from about 2 to about 3 carbon atoms; e. an amphophosphate
compound of formula: 31 wherein G is an alkyl group or alkenyl
group having about 7 to about 21 carbon atoms; s is an integer from
about 2 to about 6; R.sub.16 is hydrogen or a carboxyalkyl group
containing from about 2 to about 3 carbon atoms; R.sub.17 is a
hydroxyalkyl group containing from about 2 to about 3 carbon atoms
or is a group of the formula:
R.sub.19--O--(CH.sub.2).sub.t--CO.sub.2.sup.- wherein R.sub.19 is
an alkylene group having from about 2 to about 3 carbon atoms and t
is 1 or 2; and R.sub.18 is an alkylene or hydroxyalkylene group
having from about 2 to about 3 carbon atoms; f. a phosphobetaine
compound of formula 32 wherein E, r, R.sub.1, R.sub.2, R.sub.3, are
as defined above; g. a pyrophosphobetaine compound of formula 33
wherein E, r, R.sub.1, R.sub.2, R.sub.3, are as defined above; h. a
carboxyalkyl alkylpolyamine of formula: 34 wherein I is an alkyl or
alkenyl group containing from about 8 to about 22 carbon atoms;
R.sub.22 is a carboxyalkyl group having from about 2 to about 3
carbon atoms; R.sub.21 is an alkylene group having from about 2 to
about 3 carbon atoms and u is an integer from about 1 to about 4;
or i.) mixtures thereof, wherein the amphoteric surfactant is
present in an amount, based upon the total weight of the detergent
composition, of from about 0.5 percent to about 10 percent.
13. The detergent composition of claim 12 wherein R.sub.5 is
hydrogen.
14. The detergent composition of claim 12 wherein the amphoteric
surfactant comprises, based upon the total weight of the detergent
composition, from about 0.5 percent to about 9.5 percent of an
alkyl betaine, amidoalkyl betaine, or mixtures thereof, the alkyl
group having from about 8 to about 22 carbon atoms; and about 0.5
percent to about 9.5 percent of an amphocarboxylate.
15. The detergent composition of claim 1 wherein the anionic
surfactant comprises: an alkyl sulfate of the formula
R'--CH.sub.2OSO.sub.3X'; an alkyl ether sulfate of the formula
R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3X'- ; an alkyl monoglyceryl
ether sulfate of the formula 35an alkyl monoglyceride sulfate of
the formula 36an alkyl monoglyceride sulfonate of the formula 37an
alkyl sulfonate of the formula R'--SO.sub.3X'; an alkylaryl
sulfonate of the formula 38an alkyl sulfosuccinate of the formula:
39an alkyl ether sulfosuccinate of the formula: 40an alkyl
sulfosuccinamate of the formula: 41an alkyl amidosulfosuccinate of
the formula 42an alkyl carboxylate of the formula:
R'--(OCH.sub.2CH.sub.2).s- ub.w--OCH.sub.2CO.sub.2X'; an alkyl
amidoethercarboxylate of the formula: 43an alkyl succinate of the
formula: 44a fatty acyl sarcosinate of the formula: 45a fatty acyl
amino acid of the formula: 46a fatty acyl taurate of the formula:
47a fatty alkyl sulfoacetate of the formula: 48an alkyl phosphate
of the formula: 49or mixtures thereof wherein R' is an alkyl group
having from about 7 to about 22 carbon atoms, R'.sub.1 is an alkyl
group having from about 1 to about 18 carbon atoms, R'.sub.2 is a
substituent of a natural or synthetic .alpha.-amino acid, X' is
selected from the group consisting of alkali metal ions, alkaline
earth metal ions, ammonium ions, and ammonium ions substituted with
from about 1 to about 3 substituents, each of the substituents may
be the same or different and are selected from alkyl groups having
from 1 to 4 carbon atoms and hydroxyalkyl groups having from about
2 to about 4 carbon atoms and v is an integer from 1 to 6; w is an
integer from 0 to 20; wherein the anionic surfactant is present in
an amount, based upon the total weight of the shampoo composition
of from about 1 percent to about 10 percent.
16. The detergent composition of claim 1 further comprising a
pearlescent or opacifying agent selected from: a) mono or diesters
of 1) a fatty acid having from about 16 to about 22 carbon atoms
and 2) ethylene glycol or propylene glycol: b) mono or diesters of
1) a fatty acid having from about 16 to about 22 carbon atoms and
2) a polyalkylene glycol of the formula HO-(JO).sub.a--H wherein J
is an alkylene group having from about 2 to about 3 carbon atoms;
and a is 2 or 3: c) fatty alcohols containing from about 16 to
about 22 carbon atoms: d) fatty esters of the formula KCOOCH.sub.2L
wherein K and L independently are alkyl or alkenyl groups having
from about 15 to about 21 carbon atoms; e) inorganic solids
insoluble in the detergent composition, and f) mixtures thereof,
wherein the pearlescent or opacifying agent is present in an
amount, based upon the total weight of the detergent composition,
of from about 0.25 percent to about 2.5 percent.
17. The detergent composition of claim 16 wherein the inorganic
solid is comprised of mica, titanium dioxide, and mixtures
thereof.
18. The detergent composition of claim 1 further comprising a
humectant selected from: a) water soluble liquid polyols selected
from glycerine, propylene glycol, hexylene glycol, butylene glycol,
dipropylene glycol, and mixtures thereof; b) polyalkylene glycol of
the formula HO--(R"O).sub.b--H wherein R" is an alkylene group
having from about 2 to about 3 carbon atoms and b is an integer of
from about 2 to about 10; c) polyethylene glycol ether of methyl
glucose of formula
CH.sub.3--C.sub.6H.sub.10O.sub.5--(OCH.sub.2CH.sub.2).sub.c--OH
wherein c is an integer from about 5 to about 25; d) urea; or e)
mixtures thereof, wherein the humectant is present in an amount,
based upon the total weight of the detergent composition of from
about 0.5 percent to about 5 percent.
19. The detergent composition of claim 1 further comprising a
thickener comprised of: a.) mono or diesters of 1) polyethylene
glycol of formula HO--(CH.sub.2CH.sub.2O).sub.zH wherein z is an
integer from about 3 to about 200; and 2) fatty acids containing
from about 16 to about 22 carbon atoms; b.) fatty acid esters of
ethoxylated polyols; c.) ethoxylated derivatives of mono and
diesters of fatty acids and glycerine; d.) hydroxyalkyl cellulose;
e.) alkyl cellulose; f.) hydroxyalkyl alkyl cellulose; and g)
mixtures thereof; wherein the thickener is present in an amount
sufficient to provide the detergent composition with a Brookfield
viscosity between about 500 centipoise to about 10,000
centipoise.
20. The detergent composition of claim 1 further comprising a
volatile silicone-based conditioner selected from
polydimethylsiloxane, polydimethylcyclosiloxane,
hexamethyldisiloxane, and mixtures thereof, wherein the
silicone-based conditioner is present in an amount, based upon the
total weight of the detergent composition, of from about 0.25
percent to about 2.5 percent and has an atmospheric pressure
boiling point less than about 220.degree. C.
21. The detergent composition of claim 1 further comprising one or
more additives comprising colorants, fragrances, preservatives, pH
adjusting agents, and mixtures thereof.
22. The detergent composition of claim 1 wherein the detergent
composition has a pH in the range of about 5 to about 7.5.
23. The detergent composition of claim 11 wherein the pearlescent
or opacifying agent is added to the detergent composition as a
preformed, stabilized aqueous dispersion.
24. The detergent composition of claim 1 wherein the conditioner
portion comprises a mixture of Polyquaternium-10 and guar
hydroxypropyltrimonium chloride.
25. The detergent composition of claim 1 wherein the conditioner
portion comprises a. Polyquaternium-10 or guar
hydroxypropyltrimonium chloride, and b. a homopolymer or copolymer
of a cationic monomer having the formula 50wherein R is H or
CH.sub.3, Y is O or NH, R.sub.1 is an alkylene group having from
about 2 to about 3 carbon atoms, R.sub.2, R.sub.3 and R.sub.4 are
each independently an alkyl group having from about 1 to about 4
carbon atoms, and X is a monovalent anion selected from halide and
alkyl sulfate.
26. The detergent composition of claim 1 wherein the conditioner
portion comprises a mixture of guar hydroxypropyltrimonium chloride
and a homopolymer or copolymer of diallyldimethylammonium
chloride.
27. A conditioning detergent composition comprising, based upon the
total weight of the detergent composition: a. from about 1 percent
to about 10 percent of nonionic surfactants comprising: 1) a
polyoxyethylene derivative of a polyol ester a. derived from a
fatty acid containing from about 8 to about 22 carbon atoms and a
polyol selected from sorbitol, sorbitan, glucose, 1-methyl
glucoside, polyglucose having an average of about 1 to about 3
glucose residues, glycerine, pentaerythritol and mixtures thereof,
b. containing an average of from about 10 to about 120 oxyethylene
units, and c. having an average of from about 1 to about 3 fatty
acid residues per molecule of the polyoxyethylene derivative of
polyol ester, 2) an alkyl glucoside having an alkyl group
containing from about 6 to about 22 carbon atoms and having from
about 1 to about 6 glucose residues per molecule of alkyl
glucoside, or 3) mixtures thereof, and b. from about 0.5 percent to
about 10 percent of one or more amphocarboxylate amphoteric
surfactants of the formula:
A-CONH(CH.sub.2).sub.xN.sup.+R.sub.5R.sub.6R--wherein A is an alkyl
or alkenyl group having from about 7 to about 21 carbon atoms; x is
an integer of from about 2 to about 6; R.sub.5 is hydrogen or a
carboxyalkyl group containing from about 2 to about 3 carbon atoms;
R.sub.6 is a hydroxyalkyl group containing from about 2 to about 3
carbon atoms or a group of the formula:
R.sub.8--O--(CH.sub.2).sub.nCO.sub.2.sup.- wherein R.sub.8 is an
alkylene group having from about 2 to about 3 carbon atoms and n is
1 or 2; and R.sub.7 is a carboxyalkyl group containing from about 2
to about 3 carbon atoms, c. from about 0.5 percent to about 10
percent of one or more betaine amphoteric surfactants selected
from; 1) an alkyl betaine of the formula:
B-N.sup.+R.sub.9R.sub.10(CH.sub.2).sub.p- CO.sub.2.sup.- wherein B
is an alkyl or alkenyl group having from about 8 to about 22 carbon
atoms; R.sub.9 and R.sub.10 are each independently an alkyl group
or a hydroxyalkyl group having from about 1 to about 4 carbon
atoms; and p is 1 or 2; or 2) an amidoalkyl betaine of the formula:
D-CO--NH(CH.sub.2).sub.q--N.sup.+R.sub.11R.sub.12(CH.sub.2).sub.mCO.sub.2-
.sup.- wherein D is an alkyl or alkenyl group having from about 7
to about 21 carbon atoms; R.sub.11 and R.sub.12 are each
independently an alkyl group or a hydroxyalkyl group having from
about 1 to about 4 carbon atoms; q is an integer from about 2 to
about 6; and m is 1 or 2; d. from about 1 percent to about 10
percent of one or more anionic alkyl ether sulfate surfactants of
the formula R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3X'- , wherein R' is
an alkyl or alkenyl group having from about 7 to about 22 carbon
atoms. X' is selected from the group consisting of alkali metal
ions, alkaline earth metal ions, ammonium ions, ammonium ions
substituted with from 1 to 3 substituents, each of the substituents
may be the same or different and are selected from alkyl groups
having from about 1 to about 4 carbon atoms and hydroxyalkyl groups
having from about 2 to about 4 carbon atoms, and v is an integer
from 1 to 6; e. from about 0.01 percent to about 0.5 percent of
Polyquaternium-10; and f. from about 0.01 percent to about 0.5
percent of guar hydroxypropyltrimonium chloride; wherein the
surfactants in a through d are present in an amount, based upon the
total weight of the detergent composition, from about 5 percent to
about 20 percent.
28. The detergent composition of claim 27 further comprising from
about 0.25 percent to about 2.5 percent, based upon the total
weight of the detergent composition, of a pearlescent or opacifying
agent comprising a diester of a. a fatty acid having from about 16
to about 22 carbon atoms; and b. ethylene glycol or propylene
glycol.
29. The detergent composition of claim 27 further comprising from
about 0.5 percent to about 5 percent, based upon the total weight
of the detergent composition, of a humectant comprising
glycerine.
30. The detergent composition of claim 27 further comprising a
thickener comprising a diester of a. polyethylene glycol of formula
HO--(CH.sub.2CH.sub.2O).sub.z--H wherein z is an integer from 3 to
200; and b. a fatty acid containing from about 16 to about 22
carbon atoms, wherein the thickener is present in an amount
sufficient to provide the detergent composition with a Brookfield
viscosity between about 500 centipoise to about 10,000
centipoise.
31. The detergent composition of claim 27 further comprising, based
upon the total weight of the detergent composition, of from about
0.25 percent to about 2.5 percent of a silicone-based conditioner
comprised of polydimethylsiloxane, polydimethylcyclosiloxane,
hexamethyldisiloxane, and mixtures thereof.
32. The detergent composition of claim 27 further comprising
additives comprised of colorants, fragrances, preservatives, pH
adjusting agents, and mixtures thereof.
33. The detergent composition of claim 27 wherein the detergent
composition has a pH of from about 5 to about 7.5.
34. The detergent composition of claim 28 wherein the pearlescent
or opacifying agent is added to the detergent composition as a
preformed, stabilized aqueous dispersion.
35. The detergent composition of claim 31 wherein the
silicone-based conditioner comprises a volatile silicone compound
having an atmospheric pressure boiling point of less than about
220.degree. C.
36. A detergent composition comprising: a surfactant portion
comprising: 1. a nonionic surfactant; 2. an amphoteric surfactant;
and 3. an anionic surfactant; and a conditioner portion comprising
at least two cationic conditioning polymers.
37. A conditioning detergent composition comprising, based upon the
total weight of the detergent composition: a. from about 2 percent
to about 10 percent of a polyoxyethylene derivative of polyol ester
nonionic surfactant derived from 1) a polyol comprised of sorbitol,
sorbitan, and mixtures thereof, and 2) lauric acid, containing an
average of from about 20 to about 80 oxyethylene units per molecule
of a polyoxyethylene derivative of polyol ester, and having an
average of from about 1 to about 2 lauric acid residues per
molecule of a polyoxyethylene derivative of polyol ester, and
mixtures thereof; b. from about 0.5 percent to about 5 percent of
an amphocarboxylate amphoteric surfactant of the formula
A-CONH(CH.sub.2).sub.xN.sup.+R.sub.5R.sub.6R.sub.7 wherein A is an
alkyl group having about 11 carbon atoms, x is 2, R.sub.1 is
hydrogen, R.sub.5 is a group of the formula
R.sub.8--O--(CH.sub.2).sub.nCO.sub.2.sup.- wherein R.sub.8 is a 2
carbon alkylene group; and n is 1; and R.sub.7 is a carboxymethyl
group, and mixtures thereof; c. from about 0.5 percent to about 8
percent of a betaine surfactant selected from: 1) an alkyl betaine
of the formula B-N.sup.+R.sub.9R.sub.10CH.sub.2CO.sub.2.sup.-
wherein B is a lauryl group having 12 carbon atoms, and R.sub.1 and
R.sub.2 are each methyl groups, 2) an amidoalkyl betaine of the
formula
D-CO--NH(CH.sub.2).sub.q--N.sup.+R.sub.11R.sub.12CH.sub.2CO.sub.2.sup.-
wherein DCO represents a fatty acid derived from coconut oil, q is
3 and R.sub.11 and R.sub.12 are each methyl groups, and 3) mixtures
thereof; d. from about 2 percent to about 8 percent of an alkyl
ether sulfate anionic surfactant of the formula
R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3X', wherein R' is an alkyl
group having from about 12 to about 13 carbon atoms, X' is a sodium
ion; and v is an integer from 1 to 4, and mixtures thereof: e. from
about 0.01 percent to about 0.3 percent of Polyquaternium-10; f.
from about 0.01 percent to about 0.3 percent of guar
hydroxypropyltrimonium chloride: wherein the surfactants a through
d are present in an amount, based upon the total weight of the
detergent composition, of from about 5 percent to about 20
percent.
38. The detergent composition of claim 37 further comprising, based
upon the total weight of the detergent composition, from about 0.5
percent to about 2 percent of pearlescent or opacifying agent
comprising ethylene glycol distearate.
39. The detergent composition of claim 37 further comprising, based
upon the total weight of the detergent composition, from about 0.25
percent to about 1.5 percent of a volatile silicone-based
conditioner comprising polydimethylcyclosiloxane, wherein the
silicone-based conditioner has an atmospheric pressure boiling
point of less than about 220.degree. C.
40. The detergent composition of claim 37 further comprising one or
more additives comprised of colorants, fragrances, preservatives,
pH adjusting agents, and mixtures thereof.
41. The detergent composition of claim 37 wherein the detergent
composition has a pH of from about 5 to about 7.5.
42. The detergent composition of claim 37 further comprising a.
from about 0.5 percent to about 3 percent of a humectant comprising
glycerine, and/or b. a thickener comprising a stearate diester of
polyethylene glycol of the formula HO--(CH.sub.2CH.sub.2O).sub.z--H
wherein z is about 150 wherein the thickener is present in an
amount sufficient to provide the detergent composition with a
Brookfield viscosity between about 500 centipoise to about 10,000
centipoise.
43. The detergent composition of claim 38 wherein the pearlescent
or opacifying agent is added to the detergent composition as a
preformed, stabilized aqueous dispersion.
44. The detergent composition of claim 37 wherein said detergent
composition contains, based upon the total weight of the detergent
composition, A. from about 4 percent to about 5 percent of the
nonionic surfactant, B. from about 0.5 percent to about 1.5 percent
of the amphocarboxylate amphoteric surfactant, C. from about 3
percent to about 5 percent of the cocamidopropyl betaine of the
formula
D-CO--NH(CH.sub.2).sub.q--N.sup.+R.sub.11R.sub.12CH.sub.2CO.sub.2.sup.-
wherein DCO represents the fatty acid derived from coconut oil, q
is 3 and R.sub.11 and R.sub.12 are each methyl groups, D. from
about 2.5 percent to about 3.5 percent of a sodium trideceth
sulfate anionic surfactant having the formula
R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3X' wherein R' is an alkyl group
having 13 carbon atoms, X' is sodium ion and v is an integer from 1
to 4, E. from about 0.01 percent to about 0.3 percent of
Polyquaternium-10, and F. from about 0.01 percent ot about 0.3
percent of guar hydroxypropyltrimonium chloride, and wherein the
detergent composition has a pH of from about 5 to about 7.5.
45. The detergent composition of claim 44 further comprising
ethyleneglycol distearate in an amount, based upon the total weight
of the detergent composition, of from about 0.5 percent to about
1.5 percent.
46. The detergent composition of claim 45 further comprising in an
amount, based upon the total weight of the detergent composition,
from about 0.5 percent to about 1 percent of a volatile
silicone-based conditioner having a boiling point less that about
220.degree. C.
47. The detergent composition of claim 37 comprised of, based upon
the total weight of the detergent composition: A. from about 4
percent to about 8 percent of the nonionic surfactant. B. from
about 1.5 percent to about 3 percent of the amphocarboxylate
amphoteric surfactant, C. from about 0.25 percent to about 2.5
percent of lauryl betaine of the formula
B-N.sup.+R.sub.9R.sub.10CH.sub.2CO.sub.2.sup.- wherein B is a
lauryl group and R.sub.9 and R.sub.10 are each methyl groups, D.
from about 2 percent to about 4 percent of a sodium laureth sulfate
anionic surfactant having the formula
R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3X' wherein R' is a lauryl
group, X' is sodium ion and v is an integer from 1 to 4, E. from
about 0.01 percent to about 0.3 percent of polyquaternium-10, F.
from about 0.01 percent to about 0.3 percent of a guar
hydroxypropyltrimonium chloride, wherein the detergent composition
has a pH of from about 5 to about 7.5.
48. The detergent composition of claim 47 comprising ethylene
glycol distearate in an amount, based upon the weight of the
detergent composition, of from about 0.5 percent to about 1.5
percent.
49. The detergent composition of claim 48 further comprising a
volatile silicone-based conditioner having a boiling point less
that about 220.degree. C. in an amount, based upon the total weight
of the detergent composition, of from about 0.5 percent to about
1.0 percent.
50. A conditioning detergent composition comprising, based upon the
total weight of the detergent composition: A. from about 5 percent
to about 20 percent of a surfactant portion comprising, based upon
the total weight of the detergent composition, of 1. about 2.0
percent to about 8 percent of a nonionic surfactant comprising a
polyoxyethylene derivative of polyol ester, an alkyl glucoside
wherein the alkyl group contains from about 8 to about 14 carbon
atoms, or mixtures thereof; 2. about 1 to about 6 percent, of an
amidoalkyl sultaine amphoteric surfactant; and 3. from about 1
percent to about 6 percent of an alkyl ether sulfate anionic
surfactant; and B. from about 0.01 percent to about 1.0 percent of
a conditioner portion comprising at least two cationic conditioning
polymers selected from: 1. a cationic cellulose derivative; 2. a
cationic guar derivative; and 3. a homopolymer or copolymer of a
cationic monomer selected from: a. a monomer having the formula 51
wherein R is H or CH.sub.3, Y is O or NH, R.sub.1 is an alkylene
group having from about 2 to about 3 carbon atoms, R.sub.2, R.sub.3
and R.sub.4 are each independently an alkyl group having from about
1 to about 4 carbon atoms, and X is a monovalent anion selected
from halide and alkyl sulfate, or b. diallyldimethylammonium
chloride.
51. The detergent composition of claim 50 wherein the conditioner
portion is present in an amount of from about 0.01 percent to about
0.3 percent, based upon the total weight of the composition.
52. The detergent composition of-claim 50 wherein the nonionic
surfactant is a mixture of decyl glucoside and polyoxyethylene
sorbitan monolaurate; the amphoteric surfactant is cocamidopropyl
hydroxysultaine; and the anionic surfactant is sodium laureth
sulfate.
53. The detergent composition of claim 50 which further comprises a
thickener in an amount sufficient to provide the detergent
composition with a Brookfield viscosity between about 500
centipoise and about 10,000 centipoise, said detergent composition
having a pH between about 5 and about 7.5.
54. A conditioning detergent composition comprising, based upon the
total weight of the detergent composition: A. from about 5 percent
to about 20 percent a surfactant portion comprising, based upon the
total weight of the detergent composition, from: 1. about 0.1
percent to about 8 percent of a nonionic surfactant comprised of a.
a polyoxyethylene derivative of polyol ester; b. an alkyl
glucoside, the alkyl group having from about 8 to about 14 carbon
atoms; or c. mixtures thereof; 2. about 2 percent to about 6
percent of a carboxyalkyl alkyl polyamine amphoteric surfactant of
the formula: 52 wherein I is an alkyl or alkenyl group containing
from about 8 to about 22 carbon atoms; R.sub.22 is a carboxyalkyl
group having from about 2 to about 3 carbon atoms: R.sub.21 is an
alkylene group having from about 2 to about 3 carbon atoms and u is
an integer from about 1 to about 4; 3. from about 2 percent to
about 8 percent of an anionic surfactant selected from an alkyl
ether sulfosuccinate, alkyl ether sulfate, or mixtures thereof, the
alkyl group having from about 8 to about 14 carbon atoms; and B.
about 0.01 percent to about 1.0 percent of a conditioner portion
comprising at least two cationic conditioning polymers selected
from: 1. a cationic cellulose derivative; 2. a cationic guar
derivative; 3. a homopolymer or copolymer of a cationic monomer
selected from: a. a monomer having the formula 53 wherein R is H or
CH.sub.3, Y is O or NH, R.sub.1 is an alkylene group having from
about 2 to about 6 carbon atoms, R.sub.2, R.sub.3 and R.sub.4 are
each independently an alkyl group or a hydroxyalkyl group having
from about 1 to about 22 carbon atoms, and X is a monovalent anion
selected from halide and alkyl sulfate having from about 1 to about
4 carbon atoms, or b. diallyidimethylammonium chloride.
55. The detergent composition of claim 54 wherein the conditioner
portion is present in an amount, based upon the total weight of the
composition, of from about 0.01 percent to about 0.3 percent.
56. The detergent composition of claim 54 wherein the nonionic
surfactant is polyoxyethylene sorbitan monolaurate; the amphoteric
surfactant is sodium carboxymethyl coco polypropylamine; and the
anionic surfactant is disodium laureth sulfosuccinate.
57. The detergent composition of claim 54 which further comprises;
A. a thickener in an amount sufficient to provide the detergent
composition with a Brookfield viscosity between about 500
centipoise and about 10,000 centipoise; and/or B. from about 0.5 to
about 2.5 percent by weight, based upon the total weight of the
detergent composition, of lauryl betaine; said detergent
composition having a pH between about 5 and about 7.5.
58. A detergent composition comprising: a. an carboxyalkyl
alkylpolyamine amphoteric surfactant of the formula: 54 wherein I
is an alkyl or alkenyl group containing from about 8 to about 22
carbon atoms; R.sub.22 is a carboxyalkyl group having from about 2
to about 3 carbon atoms: u is an integer from 1 to 4; R.sub.21 is
an alkylene group having from about 2 to about 3 carbon atoms and
b. an anionic surfactant, except those anionic surfactants of the
group consisting of 1) an alkyl sulfate of the formula
R'--CH.sub.2OSO.sub.3X'; and 2) an alkylaryl sulfonate of the
formula 55 wherein R' is an alkyl group having from about 7 to
about 14 carbon atoms, R'.sub.1 is an alkyl group having from about
1 to about 12 carbon atoms, X' is selected from the group
consisting of alkali metal ions, alkaline earth metal ions and
ammonium ions, and ammonium ions substituted with from about 1 to
about 3 substituents; each of the substituents may be the same or
different and are selected from the group consisting of alkyl
groups having 1 to 4 carbon atoms and hydroxyalkyl groups having
from about 2 to about 4 carbon atoms; and c.) optionally a
non-ionic surfactant, with the proviso that if the non-ionic
surfactant is omitted and the anionic surfactant is an alkyl ether
sulfate of the formula R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3', then
v is greater than or equal to 3.
59. The detergent composition of claim 58 wherein said amphoteric
surfactant is sodium carboxymethyl coco polypropylamine or mixtures
thereof.
60. The detergent composition of claim 58 wherein the anionic
surfactant is an alkyl ether sulfosuccinate of the formula:
56wherein R' is an alkyl group having from about 7 to about 22
carbon atoms, X' is selected from the group consisting of alkali
metal ions, alkaline earth metal ions, ammonium ions, and ammonium
ions substituted with from about 1 to about 3 substituents, each of
the substituents may be the same or different and are selected from
alkyl groups having from 1 to 4 carbon atoms and hydroxyalkyl
groups having from about 2 to about 4 carbon atoms and v is an
integer from 1 to 6 or mixtures thereof.
61. The detergent composition of claim 58 wherein the surfactants a
through c are present in an amount, based upon the total weight of
the detergent composition, of from about 4 percent to about 20
percent.
62. The detergent composition of claim 58 wherein the weight ratio
of said amphoteric surfactant to said anionic surfactant ranges
from about 1:3 to about 3:1.
63. The detergent composition of claim 58 further comprising at
least one conditioner selected from: 1. a cationic cellulose
derivative; 2. a cationic guar derivative; and 3. a homopolymer or
copolymer of a cationic monomer selected from: a. a monomer having
the formula 57 wherein R is H or CH.sub.3, Y is O or NH, R.sub.1 is
an alkylene group having from about 2 to about 6 carbon atoms,
R.sub.2, R.sub.3 and R.sub.4 are each independently an alkyl group
or hydroxyalkyl group having from about 1 to about 22 carbon atoms,
and X is a monovalent anion selected from halide and alkyl sulfate
having from about 1 to about 4 carbon atoms, or b.
diallyldimethylammonium chloride.
64. The detergent composition of claim 63 wherein each conditioner
is present in an amount based upon the total weight of the
composition, of from about 0.01 percent to about 0.5 percent.
65. The detergent composition comprising: a. an carboxyalkyl
alkylpolyamine amphoteric surfactant of the formula: 58 wherein I
is an alkyl or alkenyl group containing from about 8 to about 22
carbon atoms; R.sub.22 is a carboxyalkyl group having from about 2
to about 3 carbon atoms; u is an integer from 1 to 4; R.sub.21 is
an alkylene group having from about 2 to about 3 carbon atoms and
b. an anionic surfactant, c.) optionally a non-ionic surfactant,
and d.) at least two conditioners selected from; 1. a cationic
cellulose derivative; 2. a cationic guar derivative; and 3. a
homopolymer or copolymer of a cationic monomer selected from: a. a
monomer having the formula 59 wherein R is H or CH.sub.3, Y is O or
NH, R.sub.1 is an alkylene group having from about 2 to about 6
carbon atoms, R.sub.2, R.sub.3 and R.sub.4 are each independently
an alkyl group or alkyl modified with a hydroxy group having from
about 1 to about 22 carbon atoms, and X is a monovalent anion
selected from halide and alkyl sulfate having from about 1 to about
4 carbon atoms, or b. diallyldimethylammonium chloride
66. The detergent composition of claim 65 wherein each of said
conditioners are present in an amount, based upon the total weight
of the composition, of from about 0.01 percent to about 0.5
percent
67. A detergent composition comprising a. an amidoalkyl sultaine
amphoteric surfactant of the formula: 60 wherein E is an alkyl
group or alkenyl group having from about 7 to about 21 carbon
atoms; R.sub.14 and R.sub.15 are each independently an alkyl group
or a hydroxyalkyl group having from about 1 to about 4 carbon
atoms; r is an integer from about 2 to about 6; and R.sub.13 is an
alkylene or hydroxyalkylene group having from about 2 to about 3
carbon atoms; b. an anionic surfactant, except those anionic
surfactants of the group consisting of 1. an alkyl sulfate of the
formula R'--CH.sub.2OSO.sub.3X'; 2. an alkyl ether sulfate of the
formula R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3X'; and 3. an alkylaryl
sulfonate of the formula 61 wherein R' is an alkyl group having
from about 7 to about 14 carbon atoms, R'.sub.1 is an alkyl group
having from about 1 to about 12 carbon atoms, X' is selected from
the group consisting of alkali metal ions, alkaline earth metal
ions and ammonium ions, and ammonium ions substituted with from
about 1 to about 3 substituents; each of the substituents may be
the same or different and are selected from the group consisting of
alkyl groups having 1 to 4 carbon atoms and hydroxyalkyl groups
having from about 2 to about 4 carbon atoms; and v is an integer
from 1 to 5; and c. optionally a non-ionic surfactant.
68. The detergent composition of claim 67 wherein said amphoteric
surfactant is cocoamidopropyl hydroxysultaine or mixtures
thereof.
69. The detergent composition of claim 67 wherein the anionic
surfactant is an alkyl ether sulfosuccinate of the formula:
62wherein R' is an alkyl group having from about 7 to about 22
carbon atoms, X' is selected from the group consisting of alkali
metal ions, alkaline earth metal ions, ammonium ions, and ammonium
ions substituted with from about 1 to about 3 substituents, each of
the substituents may be the same or different and are selected from
alkyl groups having from 1 to 4 carbon atoms and hydroxyalkyl
groups having from about 2 to about 4 carbon atoms and v is an
integer from 1 to 6 or mixtures thereof.
70. The detergent composition of claim 67 wherein the surfactants a
through c are present in an amount, based upon the total weight of
the detergent composition, of from about 4 percent to about 20
percent.
71. The detergent composition of claim 67 wherein said amphoteric
surfactant and said anionic surfactant are present in a weight
ratio of from about 3:1 to about 1:3.
72. The detergent composition of claim 67 further comprising at
least one conditioner selected from: 1. a cationic cellulose
derivative; 2. a cationic guar derivative; and 3. a homopolymer or
copolymer of a cationic monomer selected from; a. a monomer having
the formula 63 wherein R is H or CH.sub.3, Y is O or NH, R.sub.1 is
an alkylene group having from about 2 to about 6 carbon atoms,
R.sub.2, R.sub.3 and R.sub.4 are each independently an alkyl group
or hydroxyalkyl group having from about 1 to about 22-carbon atoms,
and X is a monovalent anion selected from halide and alkyl sulfate
having from about 1 to about 4 carbon atoms, or b.
diallyldimethylammonium chloride.
73. The detergent composition of claim 72 wherein each conditioner
is present in an amount, based, upon the total weight of the
composition, of from about 0.01 percent to about 0.5 percent.
74. A detergent composition comprising a. an amidoalkyl sultaine
amphoteric surfactant of the formula: 64 wherein E is an alkyl
group or alkenyl group having from about 7 to about 21 carbon
atoms; R.sub.14 and R.sub.15 are each independently an alkyl group
or a hydroxyalkyl group having from about 1 to about 4 carbon
atoms; r is an integer from about 2 to about 6; and R.sub.13 is an
alkylene or hydroxyalkylene group having from about 2 to about 3
carbon atoms; b. an anionic surfactant, c. optionally a non-ionic
surfactant, and d. at least two conditioners selected from; 1. a
cationic cellulose derivative; 2. a cationic guar derivative; and
3. a homopolymer or copolymer of a cationic monomer selected from;
a. a monomer having the formula 65 wherein R is H or CH.sub.3, Y is
O or NH, R.sub.1 is an alkylene group having from about 2 to about
6 carbon atoms, R.sub.2, R.sub.3 and R.sub.4 are each independently
an alkyl group or hydroxyalkyl group having from about 1 to about
22 carbon atoms, and X is a monovalent anion selected from halide
and alkyl sulfate having from about 1 to about 4 carbon atoms, or
b. diallyidimethylammonium chloride.
75. The detergent composition of claim 74 wherein each of said
conditioners are present in an amount, based upon the total weight
of the composition, of from about 0.01 percent to about 0.5
percent.
Description
CROSS-REFERENCE TO RELATED APPLICATION
[0001] This Application claims the benefit of U.S. Provisional
Application No. 60/010,784 filed on Jan. 29, 1996, which is
incorporated by reference in its entirety.
BACKGROUND OF THE INVENTION
[0002] 1. Field of the Invention
[0003] This invention relates to conditioning detergent
compositions suitable for use in personal cleansing application
which not only impart cleansing, wet detangling, dry detangling and
manageability properties to hair, but also which are relatively
non-irritating and thus suitable for use by young children and
adults having sensitive skin and eyes.
[0004] 2. Description of the Prior Art
[0005] In the past, it has been considered desirable to cleanse
hair and then to condition it after cleansing. For many years, it
was necessary to perform these acts in two separate steps. However,
with the advent of so-called "two-in-one" conditioning shampoos, it
became possible to condition and cleanse simultaneously.
Unfortunately, many of these two-in-one conditioning shampoos and
body cleansers have proven to be relatively irritating to the eyes
and skin and uncomfortable for use with children or sensitive
adults. Therefore, it is an object of this invention to create a
conditioning shampoo which has good cleansing ability, excellent
conditioning properties and has a low degree of ocular and skin
irritation.
SUMMARY OF THE INVENTION
[0006] In accordance with this invention, there is provided a
detergent composition comprising:
[0007] a surfactant portion comprising:
[0008] 1. a nonionic surfactant;
[0009] 2. an amphoteric surfactant; and
[0010] 3. an anionic surfactant; and
[0011] a conditioner portion comprising at least two cationic
conditioning polymers selected from:
[0012] 1. a cationic cellulose derivative;
[0013] 2. a cationic guar derivative; and
[0014] 3. a homopolymer or copolymer of a cationic monomer selected
from:
[0015] a. a monomer having the formula 1
[0016] wherein
[0017] R is H or CH.sub.3,
[0018] Y is O or NH,
[0019] R.sub.1 is an alkylene group having from about 2 to about 6
carbon atoms,
[0020] R.sub.2, R.sub.3 and R.sub.4 are each independently an alkyl
group or hydroxyalkyl group having from about 1 to about 22 carbon
atoms, and
[0021] X is a monovalent anion selected from halide and alkyl
sulfate having from about 1 to about 4 carbon atoms, or
[0022] b. diallyidimethylammonium chloride.
[0023] In accordance with another embodiment of this invention,
there is provided a detergent composition comprising, based upon
the total weight of the composition:
[0024] a. a carboxyalkyl alkylpolyamine amphoteric surfactant of
the formula: 2
[0025] wherein
[0026] I is an alkyl or alkenyl group containing from about 8 to
about 22 carbon atoms;
[0027] R.sub.22 is a carboxyalkyl group having from about 2 to
about 3 carbon atoms;
[0028] R.sub.21 is an alkylene group having from about 2 to about 3
carbon atoms
[0029] u is an integer of 1 to 4; and
[0030] b. an anionic surfactant, except those anionic surfactants
of the group consisting of
[0031] 1) an alkyl sulfate of the formula
R'--CH.sub.2OSO.sub.3X'; and
[0032] 2) an alkylaryl sulfonate of the formula 3
[0033] wherein
[0034] R' is an alkyl group having from about 7 to about 14 carbon
atoms,
[0035] R'.sub.1 is an alkyl group having from about 1 to about 12
carbon atoms,
[0036] X' is selected from the group consisting of alkali metal
ions, alkaline earth metal ions ammonium ions, and ammonium ions
substituted with from about 1 to about 3 substituents; each of the
substituents may be the same or different and are selected from the
group consisting of alkyl groups having 1 to 4 carbon atoms and
hydroxyalkyl groups having from about 2 to about 4 carbon atoms;
and
[0037] c.) optionally a non-ionic surfactant,
[0038] with the proviso that if the non-ionic surfactant is omitted
and the anionic surfactant is an alkyl ether sulfate of the
formula
R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3X',
[0039] then v is greater than or equal to 3.
[0040] In accordance with yet another embodiment of this invention,
there is provided a detergent composition comprising
[0041] a. an amidoalkyl sultaine amphoteric surfactant of the
formula: 4
[0042] wherein
[0043] E is an alkyl group or alkenyl group having from about 7 to
about 21 carbon atoms;
[0044] R.sub.14 and R.sub.15 are each independently an alkyl group
or a hydroxyalkyl group having from about 1 to about 4 carbon
atoms;
[0045] r is an integer from about 2 to about 6; and
[0046] R.sub.13 is an alkylene or hydroxyalkylene group having from
about 2 to about 3 carbon atoms;
[0047] b. an anionic surfactant, except those anionic surfactants
of the group consisting of
[0048] 1. an alkyl sulfate of the formula
R'--CH.sub.2OSO.sub.3X';
[0049] 2. an alkyl ether sulfate of the formula
R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3X'; and
[0050] 3. an alkylaryl sulfonate of the formula 5
[0051] wherein
[0052] R' is an alkyl group having from about 7 to about 14 carbon
atoms,
[0053] R'.sub.1 is an alkyl group having from about 1 to about 12
carbon atoms,
[0054] X' is selected from the group consisting of alkali metal
ions, alkaline earth metal ions, and ammonium ions, and ammonium
ions substituted with from about 1 to about 3 substituents; each of
the substituents may be the same or different and are selected from
the group consisting of alkyl groups having 1 to 4 carbon atoms and
hydroxyalkyl groups having from about 2 to about 4 carbon atoms;
and
[0055] v is an integer from 1 to 5; and
[0056] c. optionally a non-ionic surfactant.
[0057] The composition of this invention, when used in a shampoo or
body cleanser, possesses one or more of the following properties:
cleansing, wet detangling, dry detangling, manageability, and low
degree of ocular irritation.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
[0058] In one embodiment of the present invention, the shampoo
composition may suitably comprise, consist of or consist
essentially of an anionic surfactant, an amphoteric surfactant, a
non-ionic surfactant, and at least two cationic conditioning
polymers. The composition is preferably comprised of, based upon
the total weight of the shampoo composition, from about 5 percent
to about 20 percent, and more preferably from about 5 percent to
about 14 percent of a surfactant portion and, based upon the total
weight of the composition, from about 0.01 percent to about 3.0
percent, preferably from about 0.01 percent to about 2.0 percent,
more preferably from about 0.01 percent to about 1.0 percent, even
more preferably from about 0.01 percent to about 0.5 percent, and
most preferably from about 0.01 percent to about 0.3 percent, of a
conditioner portion.
[0059] In this embodiment, the surfactant portion of the present
invention contains nonionic, amphoteric and anionic surfactants.
Preferably the weight ratio between the amphoteric surfactant and
the anionic surfactant may range from about 3:1 to about 1:3, and
preferably from about 2:1 to about 1:2. The weight ratio of the
amphoteric/anionic surfactant combination:non-ionic surfactant may
vary widely, and preferably is about 2:1 to about 1:2. The nonionic
surfactant is present in an amount, based upon the total weight of
the shampoo composition, of from about 0.1 percent to about 10
percent, preferably from about 1 percent to about 10 percent, and
more preferably from about 4 percent to about 8 percent. The
amphoteric surfactant is present in an amount, based upon the total
weight of the shampoo composition, of from about 0.5 percent to
about 10 percent, preferably from about 1 percent to about 8
percent, and more preferably from about 2 percent to about 6
percent. The anionic surfactant is present in the shampoo
composition in an amount from about 1.0 percent to about 10
percent, preferably from about 1 percent to, about 8 percent, and
more preferably from about 1 percent to about 6 percent, based on
the overall weight of the shampoo composition.
[0060] One class of nonionic surfactants useful in the present
invention are polyoxyethylene derivatives of polyol esters, wherein
the polyoxyethylene derivative of polyol ester (1) is derived from
(a) a fatty acid containing from about 8 to about 22, and
preferably from about 10 to about 14 carbon atoms, and (b) a polyol
selected from sorbitol, sorbitan, glucose, .alpha.-methyl
glucoside, polyglucose having an average of about 1 to about 3
glucose residues per molecule, glycerine, pentaerythritol and
mixtures thereof, (2) contains an average of from about 10 to about
120, and preferably about 20 to about 80 oxyethylene units; and (3)
has an average of about 1 to about 3 fatty acid residues per mole
of polyoxyethylene derivative of polyol ester.
[0061] Examples of preferred polyoxyethylene derivatives of polyol
esters include, but are not limited to PEG-80 sorbitan laurate and
Polysorbate 20. PEG-80 sorbitan laurate, which is a sorbitan
monoester of lauric acid ethoxylated with an average of about 80
moles of ethylene oxide, is available commercially from ICI
Surfactants of Wilmington, Del. under the tradename, "Atlas
G-4280." Polysorbate 20, which is the laurate monoester of a
mixture of sorbitol and sorbitol anhydrides condensed with
approximately 20 moles of ethylene oxide, is available commercially
from ICI Surfactants of Wilmington, Del. under the tradename "Tween
20."
[0062] Another class of suitable nonionic surfactants includes long
chain alkyl glucosides or polyglucosides, which are the
condensation products of (a) a long chain alcohol containing from
about 6 to about 22, and preferably from about 8 to about 14 carbon
atoms, with (b) glucose or a glucose-containing polymer. The alkyl
gluocosides have about 1 to about 6 glucose residues per molecule
of alkyl glucoside. A preferred glucoside is decyl glucoside, which
is the condensation product of decyl alcohol with a glucose polymer
and is available commercially from Henkel Corporation of Hoboken,
N.J. under the tradename, "Plantaren 2000."
[0063] The compositions of the present invention also contain an
amphoteric surfactant. As used herein, the term "amphoteric" shall
mean: 1) molecules that contain both acidic and basic sites such
as, for example, an amino acid containing both amino (basic) and
acid (e.g., carboxylic acid, acidic) functional groups; or 2)
zwitterionic molecules which possess both positive and negative
charges within the same molecule. The charges of the latter may be
either dependent on or independent of the pH of the composition.
Examples of zwitterionic materials include, but are not limited to,
alkyl betaines and amidoalkyl betaines. The amphoteric surfactants
are disclosed herein without a counter ion. One skilled in the art
would readily recognize that under the pH conditions of the
compositions of the present invention, the amphoteric surfactants
are either electrically neutral by virtue of having balancing
positive and negative charges, or they have counter ions such as
alkali metal, alkaline earth, or ammonium counter ions.
[0064] Commercially available amphoteric surfactants are suitable
for use in the present invention and include, but are not limited
to amphocarboxylates, alkyl betaines, amidoalkyl betaines,
amidoalkyl sultaines, amphophosphates, phosphobetaines,
pyrophosphobetaines, carboxyalkyl alkyl polyamines and mixtures
thereof.
[0065] Examples of suitable amphocarboxylate compounds include
those of the formula:
A-CONH(CH.sub.2).sub.xN.sup.+R.sub.5R.sub.6R.sub.7
[0066] wherein
[0067] A is an alkyl or alkenyl group having from about 7 to about
21, and preferably from about to about 16 carbon atoms;
[0068] x is an integer of from about 2 to about 6;
[0069] R.sub.5 is hydrogen or a carboxyalkyl group containing from
about 2 to about 3 carbon atoms, and preferably is hydrogen;
[0070] R.sub.6 is a hydroxyalkyl group containing from about 2 to
about 3 carbon atoms or is a group of the formula:
R.sub.8--O--(CH.sub.2).sub.nCO.sub.2.sup.-
[0071] wherein
[0072] R.sub.8 is an alkylene group having from about 2 to about 3
carbon atoms and n is 1 or 2; and
[0073] R.sub.7 is a carboxyalkyl group containing from about 2 to
about 3 carbon atoms;
[0074] Preferably, the amphocarboxylate compound is an imidazoline
surfactant, and more preferably a disodium lauroamphodiacetate,
which is commercially available from Mona Chemical Company of
Paterson, N.J. under the tradename, "Monateric 949J." When an
amphocarboxylate is used in the shampoo composition, it should be
present in an amount of about 0.5 percent to about 10 percent, and
preferably from about 0.5 percent to about 6 percent, based on the
overall weight of the composition.
[0075] Examples of suitable alkyl betaines include those compounds
of the formula:
B-N.sup.+R.sub.9R.sub.10(CH.sub.2).sub.pCO.sub.2.sup.-
[0076] wherein
[0077] B is an alkyl or alkenyl group having from about 8 to about
22, and preferably from about 8 to about 16 carbon atoms,
[0078] R.sub.9 and R.sub.10 are each independently an alkyl or
hydroxyalkyl group having from about 1 to about 4 carbon atoms;
and
[0079] p is 1 or 2.
[0080] A preferred betaine for use in the present invention is
lauryl betaine, available commercially from Albright & Wilson,
Ltd. of West Midlands, United Kingdom as "Empigen BB/J." If
present, the alkyl betaine should be used in an amount, based on
the overall weight of the composition, of from about 0.25 percent
to about 10 percent, preferably from about 0.25 percent to about 8
percent, and more preferably, from about 0.25 percent to about 5
percent.
[0081] Examples of suitable amidoalkyl betaines include those
compounds of the formula:
D-CO--NH(CH.sub.2).sub.q--N.sup.+R.sub.11R.sub.12(CH.sub.2).sub.mCO.sub.2.-
sup.-
[0082] wherein
[0083] D is an alkyl or alkenyl group having from about 7 to about
21, and preferably from about 7 to about 15 carbon atoms;
[0084] R.sub.11 and R.sub.12 are each independently an alkyl or
hydroxyalkyl group having from about 1 to about 4 carbon atoms;
[0085] q is an integer from about 2 to about 6: and m is 1 or
2.
[0086] A preferred amidoalkyl betaine is cocamidopropyl betaine,
available commercially from Goldschmidt Chemical Corporation of
Hopewell, Va. under the tradename, "Tegobetaine L7." When present
in the shampoo compositions of this invention, the amidoalkyl
betaine should be used in an amount of from about 0.25 percent to
about 10 percent, preferably from about 0.25 percent to about 8
percent, and more preferably from about 0.25 percent to about 5
percent, based on the overall weight of the composition.
[0087] Examples of suitable amidoalkyl sultaines include those
compounds of the formula 6
[0088] wherein
[0089] E is an alkyl or alkenyl group having from about 7 to about
21, and preferably from about 7 to about 15 carbon atoms;
[0090] R.sub.14 and R.sub.15 are each independently an alkyl, or
hydroxyalkyl group having from about 1 to about 4 carbon atoms;
[0091] r is an integer from about 2 to about 6; and
[0092] R.sub.13 is an alkylene or hydroxyalkylene group having from
about 2 to about 3 carbon atoms;
[0093] Preferably the amidoalkyl sultaine is cocamidopropyl
hydroxysultaine, available commercially from Rhone-Poulenc Inc. of
Cranbury, N.J. under the tradename, "Mirataine CBS." When present
in the shampoo compositions of this invention, it should be used in
an amount of from about 0.5 percent to about 10 percent, preferably
from about 1.0 percent to about 6 percent, and more preferably from
about 1.5 percent to about 5 percent, based on the overall weight
of the composition.
[0094] Examples of suitable amphophosphate compounds include those
of the formula: 7
[0095] wherein
[0096] G is an alkyl or alkenyl group having about 7 to about 21,
and preferably from about 7 to about 15 carbon atoms;
[0097] s is an integer from about 2 to about 6;
[0098] R.sub.16 is hydrogen or a carboxyalkyl group containing from
about 2 to about 3 carbon atoms;
[0099] R.sub.17 is a hydroxyalkyl group containing from about 2 to
about 3 carbon atoms or a group of the formula:
R.sub.19--O--(CH.sub.2).sub.t--CO.sub.2.sup.-
[0100] wherein
[0101] R.sub.19 is an alkylene or hydroxyalkylene group having from
about 2 to about 3 carbon atoms and
[0102] t is 1 or 2; and
[0103] R.sub.18 is an alkylene or hydroxyalkylene group having from
about 2 to about 3 carbon atoms.
[0104] Preferably the amphophosphate compounds are sodium
lauroampho PG-acetate phosphate, available commercially from Mona
Industries of Paterson, N.J. under the tradename. "Monateric 1023,"
and those disclosed in U.S. Pat. No. 4,380,637, which is
incorporated herein by reference, with sodium lauroampho PG-acetate
phosphate being most preferred.
[0105] Examples of suitable phosphobetaines include those compounds
of the formula: 8
[0106] wherein E, r, R.sub.1, R.sub.2 and R.sub.3, are as defined
above. Preferably the phosphobetaine compounds are those disclosed
in U.S. Pat. Nos. 4,215,064, 4,617,414, and 4,233,192, which are
all incorporated herein by reference.
[0107] Examples of suitable pyrophosphobetaines include those
compounds of the formula: 9
[0108] wherein E, r, R.sub.1, R.sub.2 and R.sub.3, are as defined
above. Preferably the pyrophosphobetaine compounds are those
disclosed in U.S. Pat. Nos. 4,382,036, 4,372,869, and 4,617,414,
which are all incorporated herein by reference.
[0109] Examples of suitable carboxyalkyl alkylpolyamines include
those of the formula: 10
[0110] wherein
[0111] I is an alkyl or alkenyl group containing from about 8 to
about 22, and preferably from about 8 to about 16 carbon atoms;
[0112] R.sub.22 is a carboxyalkyl group having from about 2 to
about 3 carbon atoms;
[0113] R.sub.2, is an alkylene group having from about 2 to about 3
carbon atoms and
[0114] u is an integer from about 1 to about 4.
[0115] Preferably the carboxyalkyl alkyl polyamine is sodium
carboxymethyl coco polypropylamine, available commercially from
Akzo Nobel Surface Chemistry under the tradename, "Ampholak 7CX/C."
When present in the shampoo compositions of this invention, it
should be used in an amount of from about 0.5 percent to about 10
percent, preferably from about 1.0 percent to about 8 percent, and
more preferably from about 2.0 percent to about 6.0 percent, based
on the overall weight of the composition.
[0116] In a preferred embodiment, the amphoteric surfactant portion
of the compositions is comprised of a mixture of amphoteric
surfactants, such as amphocarboxylate and alkyl betaine, or
amphocarboxylate and amidoalkyl betaine. In this embodiment, the
amphocarboxylate is present in the shampoo composition in an
amount, based upon the total weight of the shampoo composition, of
from about 0.5 percent to about 9.5 percent and the alkyl betaine
or amidoalkyl betaine is present in an amount, based upon the total
weight of the shampoo composition, of from about 9.5 percent to
about 0.5 percent.
[0117] The compositions of this embodiment also contain at least
one anionic surfactant. Preferably, the anionic surfactant is
selected from the following classes of surfactants:
[0118] an alkyl sulfate of the formula
R'--CH.sub.2OSO.sub.3X';
[0119] an alkyl ether sulfate of the formula
R'(OCH.sub.2CH.sub.2).sub.vOSO.sub.3X';
[0120] an alkyl monoglyceryl ether sulfate of the formula 11
[0121] an alkyl monoglyceride sulfate of the formula 12
[0122] an alkyl monoglyceride sulfonate of the formula 13
[0123] an alkyl sulfonate of the formula
R'--SO.sub.3X';
[0124] an alkylaryl sulfonate of the formula 14
[0125] an alkyl sulfosuccinate of the formula: 15
[0126] an alkyl ether sulfosuccinate of the formula: 16
[0127] an alkyl sulfosuccinamate of the formula: 17
[0128] an alkyl amidosulfosuccinate of the formula 18
[0129] an alkyl carboxylate of the formula:
R'--(OCH.sub.2CH.sub.2).sub.w--OCH.sub.2CO.sub.2X'.
[0130] an alkyl amidoethercarboxylate of the formula: 19
[0131] an alkyl succinate of the formula: 20
[0132] a fatty acyl sarcosinate of the formula: 21
[0133] a fatty acyl amino acid of the formula: 22
[0134] a fatty acyl taurate of the formula: 23
[0135] a fatty alkyl sulfoacetate of the formula: 24
[0136] an alkyl phosphate of the formula: 25
[0137] wherein
[0138] R' is an alkyl group having from about 7 to about 22, and
preferably from about 7 to about 16 carbon atoms,
[0139] R'.sub.1 is an alkyl group having from about 1 to about 18,
and preferably from about 8 to about 14 carbon atoms,
[0140] R'.sub.2 is a substituent of a natural or synthetic I-amino
acid,
[0141] X' is selected from the group consisting of alkali metal
ions, alkaline earth metal ions, ammonium ions, and ammonium ions
substituted with from about 1 to about 3 substituents, each of the
substituents may be the same or different and are selected from the
group consisting of alkyl groups having from 1 to 4 carbon atoms
and hydroxyalkyl groups having from about 2 to about 4 carbon atoms
and
[0142] v is an integer from 1 to 6;
[0143] w is an integer from 0 to 20;
[0144] and mixtures thereof. Preferably the anionic surfactant is
comprised of sodium trideceth sulfate, sodium laureth sulfate,
disodium laureth sulfosuccinate, or mixtures thereof. Sodium
trideceth sulfate is the sodium salt of sulfated ethoxylated
tridecyl alcohol that conforms generally to the following formula,
C.sub.13H.sub.27(OCH.sub.2CH.sub.2).s- ub.nOSO.sub.3Na, where n has
a value between 1 and 4, and is commercially available from Stepan
Company of Northfield, Ill. under the tradename, "Cedapal TD-403M."
Sodium laureth sulfate is available from from Albright &
Wilson, Ltd. West Midlands, United Kingdom under the tradename,
"Empicol 0251/70-J." Disodium laureth sulfosuccinate is available
commercially from Albright & Wilson, Ltd. of West Midlands,
United Kingdom under the tradename, "Empicol SDD."
[0145] In this embodiment, the shampoo composition of the present
invention also contains a conditioner portion which is comprised of
at least two cationic conditioning polymers. Preferred cationic
conditioning polymers are selected from the following:
[0146] 1. a cationic cellulose derivative;
[0147] 2. a cationic guar derivative; and
[0148] 3. a homopolymer or copolymer of a cationic monomer selected
from:
[0149] a. a monomer having formula I, 26
[0150] wherein
[0151] R is H or CH.sub.3,
[0152] Y is O or NH,
[0153] R.sub.1 is an alkylene group having from about 2 to about 6,
and preferably from about 2 to about 3 carbon atoms.
[0154] R.sub.2, R.sub.3 and R.sub.4 are each independently an alkyl
group having from about 1 to about 22, and preferably from about 1
to about 4 carbon atoms, and
[0155] X is a monovalent anion selected from halide and alkyl
sulfate, or
[0156] b. diallyidimethylammonium chloride.
[0157] The amount of each conditioner component may range, based
upon the total weight of the composition, from about 0.01 percent
to about 1.0 percent, preferably from about 0.01 percent to about
0.5 percent, and more preferably from about 0.01 to about 0.2
percent.
[0158] Preferably, the cationic cellulose derivative is a polymeric
quaternary ammonium salt derived from the reaction of hydroxyethyl
cellulose with a trimethylammonium substituted epoxide. The
material known as Polyquaternium-10, commercially available from
Amerchol Corporation of Edison, N.J. as "Polymer JR400," is
especially useful in this regard.
[0159] The cationic guar derivative is preferably a guar
hydroxypropyltrimonium chloride, available commercially from
Rhone-Poulenc Inc., of Cranbury, N.J. under the tradename, "Jaguar
C-17."
[0160] Another preferred cationic polymer includes those compounds
derived from acrylamidopropyl trimonium chloride which has the
formula: 27
[0161] and more preferably is the copolymer of this monomer with
acrylamide, the latter of which is available commercially from
Allied Colloids, of Suffolk, Va. under the tradename, "Salcare
SC60."
[0162] Other preferred cationic conditioning polymers are those
derived from the monomer diallyldimethylammonium chloride. The
homopolymer of this monomer is Polyquaternium-6, which is available
commercially form Allied Colloids of Suffolk, Va. under the
tradename, "Salcare SC30." The copolymer of diallyldimethylammonium
chloride with acrylamide is known as Polyquaternium-7, and is also
available from Allied Colloids under the tradename "Salcare
SC10."
[0163] In a preferred embodiment, the conditioner portion is a
combination of cationic cellulose derivative with a cationic guar
derivative. In this embodiment, the cationic cellulose derivative
is present in the composition in an amount, based on the overall
weight of the shampoo composition, of from about 0.01 percent to
about 2 percent, preferably from about 0.05 percent to about 1.0
percent, and more preferably from about 0.05 percent to about 0.3
percent, and the cationic guar derivative is present in an amount,
based on the overall weight of the shampoo composition, of from
about 0.01 percent to about 1.0 percent, preferably from about 0.05
percent to about 1.0 percent, and more preferably from about 0.05
percent to about 0.3 percent.
[0164] In another preferred embodiment, the conditioner portion is
comprised of cationic cellulose derivative or cationic guar
derivative and a homopolymer or copolymer of the cationic monomer
having formula 1. In this embodiment, the cationic cellulose
derivative or cationic guar derivative is present in an amount,
based on the overall weight of the composition, of from about 0.01
percent to about 0.5 percent, and preferably from about 0.01
percent to about 0.2 percent, and the homopolymer or copolymer of
the above monomer is present in an amount, based on the overall
weight of the composition, of from about 0.01 percent to about 0.5
percent, preferably from about 0.01 percent to about 0.2
percent.
[0165] In another preferred embodiment, the conditioner portion is
comprised of cationic guar derivative and a homopolymer or
copolymer of diallyidimethylammonium chloride. In this embodiment,
the cationic guar derivative is present in an amount, based on the
overall weight of the shampoo composition, of from about 0.01
percent to about 0.5 percent, preferably from about 0.01 percent to
about 0.2 percent, and the homopolymer or copolymer of
diallyidimethylammonium chloride is present in an amount, based on
the overall weight of the shampoo composition, of from about 0.01
percent to about 0.5 percent, preferably from about 0.01 percent to
about 0.2 percent.
[0166] In accordance with another embodiment of this invention,
there is provided a composition suitably comprised of, consisting
of, or consisting essentially of an amphoteric surfactant and an
anionic surfactant, with the total amount of surfactants ranging,
based upon the total weight of the composition, from about 4
percent to about 20 percent, preferably from about 4 percent to
about 15 percent, and more preferably from about 4 percent to about
10 percent. Examples of suitable amphoteric surfactants include
those described above and preferably include the above-described
carboxyalkyl alkylpolyamines, the amidoalkyl sultaines, and
mixtures thereof. Examples of suitable anionic surfactants include
those described above and preferably include those anionic
surfactants except the anionic surfactant compounds of the group
consisting of: 1) the above-described alkyl sulfates or alkylaryl
sulfonates when the amphoteric surfactant is the above described
carboxyalkyl alkylpolyamine; and 2) the alkyl sulfates, alkyl ether
sulfates, and alkylaryl sulfonates when the amphoteric surfactant
is the above-described amidoalkyl sultaine.
[0167] In this embodiment, the amount of each of the amphoteric
surfactant and anionic surfactant used in the composition may
range, based upon the total weight of the composition, from about 2
percent to about 10 percent, and preferably from about 2 percent to
about 6 percent, respectively. The weight ratio of amphoteric
surfactant:anionic surfactant may range from about 3:1 to about
1:3, preferably from about 2:1 to about 1:2, and most preferably
from about 1.5:1 to about 1:1.5. Optionally, the composition of
this embodiment may contain one or more of the above-mentioned
non-ionic surfactants and/or one or more of the above-mentioned
cationic conditioners. Preferably, the non-ionic surfactant, it
used, is a polyoxyethylene derivative of a polyol ester, more
preferably Polysorbate 20, and the preferred cationic conditioner
is Polyquarternium 10, guar hydroxypropyltriammonium chloride,
acrylamidopropyl trimonium chloride/acrylamide copolymer, and
mixtures thereof. The amount of nonionic surfactant used in the
composition may range, based upon the total weight of the
composition, of from about 0 to about 5 percent, and preferably
from about 0.5 percent to about 1 percent. When the nonionic
surfactant is used, the weight ratio of amphoteric/anionic
surfactant:nonionic surfactant is from about 40:1 to about 2:1 and
preferably from about 20:1 to about 10:1. The amount of each
cationic conditioner used in the composition may range, based upon
the total weight of the composition, from about 0 to about 0.5
percent, and preferably from greater than about 0 percent to about
0.3 percent, and more preferably from greater than about 0 percent
to about 0.2 percent.
[0168] The composition of the present invention may also include
one or more optional ingredients nonexclusively including a
pearlescent or opacifying agent, a thickening agent, secondary
conditioners, humectants, chelating agents, and additives which
enhance their appearance, feel and fragrance, such as colorants,
fragrances, preservatives, pH adjusting agents, and the like. The
pH of the shampoo compositions of this invention is preferably
maintained in the range of from about 5 to about 7.5, and more
preferably from about 5.5 to about 7.0.
[0169] Commercially available pearlescent or opacifying agents
which are capable of suspending water insoluble additives such as
silicones and/or which tend to indicate to consumers that the
resultant product is a conditioning shampoo are suitable for use in
this invention. The pearlescent or opacifying agent is present in
an amount, based upon the total weight of the composition, of from
about 0 percent to about 3 percent, preferably from about 0.25
percent to about 2.5 percent, and more preferably, from about 0.5
percent to about 1.5 percent. Examples of suitable pearlescent or
opacifying agents include, but are not limited to mono or diesters
of (a) fatty acids having from about 16 to about 22 carbon atoms
and (b) either ethylene or propylene glycol; mono or diesters of
(a) fatty acids having from about 16 to about 22 carbon atoms (b) a
polyalkylene glycol of the formula
HO-(JO).sub.a--H
[0170] wherein
[0171] J is an alkylene group having from about 2 to about 3 carbon
atoms;
[0172] and a is 2 or 3;
[0173] fatty alcohols containing from about 16 to about 22 carbon
atoms; fatty esters of the formula
KCOOCH.sub.2L
[0174] wherein K and L independently contain from about 15 to about
21 carbon atoms;
[0175] inorganic solids insoluble in the shampoo composition, and
mixtures thereof.
[0176] In a preferred embodiment, the pearlescent or opacifying
agent is introduced to the shampoo composition as a pre-formed,
stabilized aqueous dispersion, such as that commercially available
from Henkel Corporation of Hoboken, N.J. under the tradename,
"Euperlan PK-3000." This material is a combination of glycol
distearate (the diester of ethylene glycol and stearic acid).
Laureth-4 (CH.sub.3(CH.sub.2).sub.10CH.sub.2(OCH.sub.2CH.s-
ub.2).sub.4OH) and cocamidopropyl betaine and preferably is in a
weight percent ratio of from about 25 to about 30:about 3 to about
15:about 20 to about 25, respectively.
[0177] Commercially available thickening agents which are capable
of imparting the appropriate viscosity to the conditioning shampoo
compositions are suitable for use in this invention. If used, the
thickener should be present in the shampoo compositions in an
amount sufficient to raise the Brookfield viscosity of the
composition to a value of between about 500 to about 10,000
centipoise. Examples of suitable thickening agents nonexclusively
include: mono or diesters of 1) polyethylene glycol of formula
HO--(CH.sub.2CH.sub.2O).sub.2H
[0178] wherein z is an integer from about 3 to about 200;
[0179] and 2) fatty acids containing from about 16 to about 22
carbon atoms; fatty acid esters of ethoxylated polyols; ethoxylated
derivatives of mono and diesters of fatty acids and glycerine;
hydroxyalkyl cellulose; alkyl cellulose; hydroxyalkyl alkyl
cellulose; and mixtures thereof. Preferred thickeners include
polyethylene glycol ester, and more preferably PEG-150 distearate
which is available from the Stepan Company of Northfield, Ill. or
from Comiel, S.p.A. of Bologna, Italy under the tradename. "PEG
6000 DS".
[0180] Commercially available secondary conditioners such as
volatile silicones which imparts additional attributes such as
gloss to the hair are suitable for use in this invention.
Preferably, the volatile silicone conditioning agent has an
atmospheric pressure boiling point less than about 220 C. The
volatile silicone conditioner is present in an amount of from about
0 percent to about 3 percent, preferably from about 0.25 percent to
about 2.5 percent, and more preferably from about 0.5 percent to
about 1.0 percent, based on the overall weight of the composition.
Examples of suitable volatile silicones nonexclusively include
polydimethylsiloxane, polydimethylcyclosiloxane,
hexamethyldisiloxane, cyclomethicone fluids such as
polydimethylcyclosiloxane available commercially from Dow Corning
Corporation of Midland, Mich. under the tradename, "DC-345" and
mixtures thereof, and preferably include cyclomethicone fluids.
[0181] Commercially available humectants which are capable of
providing moisturization and conditioning properties to the shampoo
composition are suitable for use in the present invention. The
humectant is present in an amount of from about 0 percent to about
10 percent, preferably from about 0.5 percent to about 5 percent,
and more preferably from about 0.5 percent to about 3 percent,
based on the overall weight of the composition. Examples of
suitable humectants nonexclusively include: 1) water soluble liquid
polyols selected from the group comprising glycerine, propylene
glycol, hexylene glycol, butylene glycol, dipropylene glycol, and
mixtures thereof; 2) polyalkylene glycol of the formula
HO--(R"O).sub.b--H
[0182] wherein R" is an alkylene group having from about 2 to about
3 carbon atoms and b is an integer of from about 2 to about 10;
[0183] 3) polyethylene glycol ether of methyl glucose of
formula
CH.sub.3--C.sub.6H.sub.10O.sub.5--(OCH.sub.2CH.sub.2).sub.c--OH
[0184] wherein c is an integer from about 5 to about 25;
[0185] 4) urea; and 5) mixtures thereof, with glycerine being the
preferred humectant.
[0186] Examples of suitable chelating agents include those which
are capable of protecting and preserving the compositions of this
invention. Preferably, the chelating agent is EDTA, and more
preferably is tetrasodium EDTA available commercially from Dow
Chemical Company of Midland, Mich. under the tradename, "Versene
100XL" and is present in an amount, based upon the total weight of
the composition, from about 0 to about 0.5 percent, and preferably
from about 0.05 percent to about 0.25 percent. Suitable
preservatives include Quaternium-15, available commercially as
"Dowicil 200" from the Dow Chemical Corporation of Midland, Mich.
and are present in the composition in an amount, based upon the
total weight of the composition, from about 0 to about 0.2 percent,
and preferably from about 0.05 percent to about 0.10 percent.
[0187] The above described composition may be prepared by combining
the desired components in a suitable container and mixing them
under ambient conditions in any conventional mixing means well
known in the art, such as a mechanically stirred propeller, paddle,
and the like. Although the order of mixing is not critical, it is
preferable to pre-blend certain components, such as the fragrance
and the nonionic surfactant before adding such components into the
main mixture.
[0188] When a cationic guar conditioner is used, it is also
preferable to preblend the cationic guar conditioner with glycerin
under ambient conditions, then allow the guar conditioner to be
"wet-out" by the glycerin. Although the time to "wet-out" may vary,
typically this time period may range from about 5 minutes to about
30 minutes. Preferably, the, guar conditioner:glycerin weight ratio
is from about 1:100 to about 1:1, and more preferably from about
1:50 to about 1:5, and most preferably from about 1:15 to about
1:7. The resulting suspension is mixed with water under ambient
conditions at a suspension:water weight ratio of from about 1:5 to
about 1:20. The resulting water-suspension mixture is then
acidified with an amount of acid, preferably citric acid, effective
to reduce the pH of the overall composition to a value of about
4.
[0189] When using a thickener component, it is also preferable to
preblend the desired thickener with from about 5 percent to about
20 percent, based upon the total weight of the composition, of
water and preferably at a temperature of from about 60.degree. C.
to about 80.degree. C. When processing with a thickener, it is also
preferable to reduce the temperature of the overall composition to
less than about 45.degree. C. before any preformed pearlizer is
added thereto.
[0190] The detergent composition of the present invention is
preferably used in personal cleansing applications nonexclusively
including shampoos, gels such as shower gels, baths such as baby
baths, and the like.
[0191] The invention illustratively disclosed herein suitably may
be practiced in the absence of, any component, ingredient, or step
which is not specifically disclosed herein. Several examples are
set forth below to further illustrate the nature of the invention
and the manner of carrying it out. However, the invention should
not be considered as being limited to the details thereof.
EXAMPLES
[0192] All amounts of materials are given in parts by weight based
on 100 parts of the overall formulation, unless stated otherwise.
The following test procedures were used in the following
Examples:
[0193] 1. Hair Conditioning Properties: Conditioning properties of
shampoos are determined by measuring the average energy and force
required to comb hair in the wet and dry state after the hair has
been washed with a particular shampoo formulation in accordance
with the method set forth as follows:
[0194] a) Preparation of Hair samples: Human hair tresses are
prepared by weighing out about 10-12 grams of virgin brown hair,
and binding the cuticle end with a cable tie and hot melt glue. The
cuticle end of the bundle is positioned in a binder clip. The hair
is fanned out evenly over the width of the binder clip. Hot melt
glue is applied along the edge of the binder clip, joining the clip
and the hair. Glue is applied to the inside of the clip for further
strength. A rubber band is applied to the outside of the clip, to
keep the jaws of the dip from separating. The glue is allowed to
dry thoroughly. The tress is washed to remove contaminants such as
dust or shampoo residue by immersing the tress in methanol for ten
seconds and removing the tress and allowing it to air dry. Loose
hair is removed. Tangles are removed by combing the tresses with a
standard comb or brush. Static charge buildup is removed using a
static reducing gun.
[0195] The number of trials required for the test is equal to the
number of formulations (and suitable controls) under test. The
formulations are randomized such that each product is applied to
each tress at some point in time. Two shampooings each using about
1 cc of shampoo composition are required. The tress is thoroughly
wet under running, 100 F tap water. About 1 cc of a given shampoo
composition is applied evenly from top to bottom of the tress.
Using the fingers of both hands, the shampoo is rubbed into the
hair for approximately 30 seconds to produce lather. The tress is
then rinsed thoroughly under running, 100 F water. The tress is
then again washed and rinsed using a second 1 cc sample of product.
The tress is then allowed to drip dry for 5 minutes.
[0196] The tresses are then suspended from a sturdy ring stand such
that they hang freely and have several inches of clearance between
the bottom of the tress and the top of the bench.
[0197] b) Wet Detangling Energy: A Combing Force Device (CFD),
which is a hand held, electromechanical instrument which measures
the amount of force or energy required to pass a comb through the
hair, is held horizontally in the one hand and tangles are removed
from the tresses by starting at the lower portion of the tress and
moving the CFD downward. Each successive stroke is started at a
point which is higher than the previous stroke. This measurement
continues until the CFD passes freely through the entire length of
the tress. Once all tangles have been removed, three top-to-bottom
strokes complete the detangling measurement. The cumulative energy
to detangle the hair tresses is reported as wet detangling energy,
in units of gram-seconds (g/sec).
[0198] c) Wet Comb Force: After the detangling energy measurement
is completed on all tresses, the tresses are measured for wet comb
force. A sensor attached to a curling iron measures the twisting,
or torsional force of the curling iron as the instrument is moved
though the hair. The instrument is passed through the detangled
tresses about 25 times. Comb force, expressed in grams, is the
median force required to pass the comb through the detangled
tress.
[0199] d) Dry Detangling Enemy: After the tresses are blow-dried
until they are no longer damp, the detangling procedure set forth
in b is repeated using the dry tresses.
[0200] e) Dry Comb Force: After the tresses are blow-dried until
they are no longer damp and dry detangling energy is determined,
the combing procedure set forth in c) is repeated using the dry
tresses.
[0201] 2.) Ocular Irritation Properties: Irritation to the eyes
expected for a given formulation is measured in accordance with the
Invittox Protocol Number 86, the "Trans-epithelial Permeability
(TEP) Assay" as set forth in Invittox Protocol Number 86 (May
1994), in general, the ocular irritation potential of a product can
be evaluated by determining its effect on the permeability of a
cell layer, as assessed by the leakage of fluorescein through the
layer. Monolayers of Madin-Darby canine kidney (MDCK) cells are
grown to confluence on microporous inserts in a 24-well plate
containing medium or assay buffer in the lower wells. The
irritation potential of a product is evaluated by measuring the
damage to the permeability barrier in the cell monolayer following
a 15 minute exposure to dilutions of the product. Barrier damage is
assessed by the amount of sodium fluorescein that has leaked
through to the lower well after 30 minutes, as determined
spectrophotometrically. The fluorescein leakage is plotted against
the concentration of test material to determine the EC.sub.50 (the
concentration of test material that causes 50% of maximum dye
leakage, i.e. 50% damage to the permeability barrier).
[0202] Exposure of a layer of MDCK cells grown on a microporous
membrane to a test sample is a model for the first event that
occurs when an irritant comes in contact with the eye. In vivo, the
outermost layers of the corneal epithelium form a selectively
permeable barrier due to the presence of tight junctions between
cells. On exposure to an irritant, the tight junctions separate,
thereby removing the permeability barrier. Fluid is imbibed to the
underlying layers of epithellum and to the stroma, causing the
collagen lamellae to separate, resulting in opacity. The TEP assay
measures the effect of an irritant on the breakdown of tight
junctions between cells in a layer of MDCK cells grown on a
microporous insert. Damage is evaluated spectrophotometrically, by
measuring the amount of marker dye (sodium fluorescein) that leaks
through the cell layer and microporous membrane to the lower well.
Generally, a passing score is reflected in an EC.sub.50 of 2.2% or
higher.
Example 1
Compounding if Shampoo Composition
[0203] The following pre-blends were prepared:
[0204] Preblend A: 1.5 parts of PEG 6000 DS were mixed with 20
parts deionized water, at 65.degree. C. in mixing vessel until a
homogeneous mixture was obtained.
[0205] Preblend B: 1.00 part glycerine was added to a mixing
vessel. 0.1 pan Jaguar C17 was added slowly with agitation and the
agitation was continued for 15 minutes. 10.0 parts water were
added, 20% citric acid solution was added to adjust the pH of the
blend to 4.0, and agitation was continued for an additional 15
minutes.
[0206] Preblend C: 1.0, part Atlas G-4280 was mixed with 0.25 parts
fragrance.
[0207] Preblend D: 0.05 parts Dowicil 200 were blended with 0.15
parts water and the mixture was stirred until solution was
obtained.
[0208] After charging 25.75 parts water to a mixing vessel, 0.19
parts of Polymer JR-400 was added thereto with maintained agitation
until a clear solution was obtained. 12.16 parts Tegobetaine L7,
9.50 parts Cedepal TD-403M, 2.85 Monateric 949J and 5.5 parts Atlas
G-4280 were added sequentially to the solution with agitation.
After Preblend A, which was maintained at a temperature of
65.degree. C. was added with agitation to the solution, Preblend C
was then added thereto with agitation. An additional 1.14 parts of
Tegobetaine L7 was then added thereto. 0.18 part Versene 100 XL,
3.21 parts of dye solution, preblend D. 4.00 parts Euperlan PK 3000
and 0.75 parts DC 345 were then added sequentially with agitation
thereto. Citric add solution was added in an amount to adjust the
pH of the solution to 15.0. Preblend B was then added with
agitation. The pH was then checked and adjusted to 6.0 with
additional citric add solution. The amounts of the ingredients used
to make the composition of Example 1 are shown in Table 1
below.
[0209] The resulting composition was tested for detangling energy
and comb force, and the results are provided in Table 2 below.
Ocular irritation of the resulting composition was also measured,
and the data are presented in Table 3.
1 TABLE 1 Comparative INCI Name of Active Example Example
Ingredient Ingredient 1 2 1 2 Atlas G-4280 PEG-80 Sorbitan Laurate
6.50 6.50 6.50 6.50 Monateric 949J Lauroamphoglycinate 2.85 2.85
2.85 2.85 Tegobetaine L7 Cocamidopropyl Betaine 13.30 13.30 13.30
13.30 Cedepal TD-403M Sodium Trideceth Sulfate 9.50 9.50 9.50 9.50
Polymer JR 400 Polyquatemium-10 0.19 0.19 0.19 -- Jaguar C17 Guar
0.10 0.10 -- 0.10 Hydroxypropyltrimonium Chloride PEG 6000 DS
PEG-150 Distearate 1.50 1.50 1.50 1.50 Fragrance 0.25 0.25 0.25
0.25 Versene 100XL Tetrasodium EDTA 0.18 0.18 0.18 0.18 Color
(0.10% aq. sol'n) 3.21 3.21 3.21 3.21 Dowicll 200 Quatemium-15 0.05
0.05 0.05 0.05 Euperian PK 3000 Glycol Distearate, 4.00 4.00 4.00
4.00 Laureth-4 and Cocamidopropyl Betaine DC 345 Fluid
Cyclomethicone 0.75 -- -- -- Citric Acid (20% Sol'n) pH to Citric
Acid 0.85 0.85 0.85 0.85 5.9-6.2 Glycerin Glycerin 1.00 1.00 1.00
1.00 Deionized Water Deionized Water Q.S. to Q.S. to Q.S. to Q.S to
100 100 100 100
Example 2
Compounding of Shampoo Composition without Cyclomethicone
[0210] The procedure of Example 1 was repeated using the
ingredients as set forth in Table 1. The resulting composition was
tested for detangling energy and comb force, and the results are
provided in Table 2 below.
Comparative Example 1
Compounding of Shampoo Composition without Guar Cationic
Conditioner or Cyclomethicone.
[0211] The procedure of Example 1 was repeated using the
ingredients as set forth in Table 1. The resulting composition was
tested for detangling energy and comb force, and the results are
provided in Table 2 below.
Comparative Example 2
Compounding of Shampoo Composition without Polyquaternium-10 or
Cyclomethicone
[0212] The procedure of Example 1 was repeated using the
ingredients as set forth in Table 1. The resulting composition was
tested for detangling energy and, comb force, and the results are
provided in Table 2 below:
2TABLE 2 Detangling Energy and Comb Force Measurements Comparative
Comparative Property Example 1 Example 2 Example 1 Example 2 Wet
Detangling 2218 .+-. 457 2214 .+-. 683 3458 .+-. 1264 3006 .+-. 630
Energy (gram-seconds) WetCombForce 200 .+-. 25 192 .+-. 51 259 .+-.
77 191 .+-. 58 (grams) Dry Detangling 2505 .+-. 1174 3162 .+-. 1386
4025 .+-. 940 2891 .+-. 909 Energy (gram-seconds) Dry Comb 169 .+-.
70 164 .+-. 79 161 .+-. 59 146 .+-. 66 Force (grams)
[0213] As indicated by the data in Table 2, the formulations of
Examples 1 and 2, which contain both Polyquaternium-10 and Guar
hydroxypropyltrimonlum chloride, exhibit significantly improved wet
detangling force tower detangling energy) than either of
Comparative examples 1 or 2, each of which contains only one of the
conditioners.
[0214] In accordance with prior experience, Polyquaternium-10, when
used as the sole conditioner in a shampoo formulation, was known to
have imparted dry hair managability benefits to the compositions
Similarly, cationic guar compounds have been known, to impart wet
detangling benefits. Due to the cationic nature of both of these
compounds, it was thought that these compounds, when used mixed
together, would have competed for the anionic sites on the hair and
would thus not have resulted in a shampoo composition exhibiting
both improved wet and dry detangling benefits. However, we have
unexpectedly found that the combination of cationic cellulose
derivatives and cationic guar derivatives in the compositions of
this invention impacts superior wet and dry detangling properties
to the compositions. More specifically, the wet and dry detangling
energy is much lower when using the combination of conditioners of
this invention, i.e., cationic guar derivatives and
Polyquaternium-10, than if either of the conditioners are used
alone.
[0215] Example 1 differs from Example 2 in the presence of volatile
silicone in formulation. As seen from the data in Table 2, the
presence of volatile silicone in Example 1 results in a further
reduction in dry detangling energy. Thus, it can be seen that the
combination of cationic polymer conditioners and volatile silicone
of the compositions of this invention afford both excellent wet
detangling and dry detangling benefits.
3TABLE 3 TEP Ocular Irritation Results Formulation Mean EC.sub.50
Rating Formula of Example 1 3.94 .+-. 1.20 pass Johnson's Baby
shampoo 3.34 .+-. 0.64 pass Pert Plus for Kids Light 0.74 .+-. 0.23
fail Conditioning Pert Plus for Kids Normal 0.81 .+-. 0.28 fail
Conditioning
[0216] As indicated above, formulations which exhibit a mean
EC.sub.50 value of 2.2 or higher are deemed to pass the ocular
irritation test while those exhibiting an EC.sub.50 value below 2.2
are deemed to fail the test. As shown in Table 3, the formulation
of Example 1 exhibits a passing value, which is on par with
Johnson's Baby Shampoo, a commercial shampoo known for its ocular
mildness. In contrast, other commercial shampoos, i.e., the Pert
Plus products marketed by the Proctor & Gamble Company, fail
the test
[0217] Thus, it can be seen from the above Examples that the
compositions of the present invention possess superior wet and dry
detangling capabilities while retaining low ocular irritation
values.
Examples 3-15
Preparation of Cleansing Compositions
[0218] The following preferred formulations, as shown in Tables
4-7, were made in accordance with the procedure described in
Examples 1 and 2.
4TABLE 4 INCI Name of Active Example Ingredient Ingredient 3 4 5
Atlas G-4280 PEG-80 Sorbitan Laurate 6.50 6.50 6.50 Monateric 949J
Lauroamphoglycinate 2.85 2.85 2.85 Tegobetaine L7 Cocamidopropyl
Betaine 13.30 13.30 13.30 Cedepal TD-403M Sodium Trideceth Sulfate
9.50 9.50 9.50 Polymer JR 400 Polyquaternium-10 0.14 -- 0.10 Jaguar
C17 Guar 0.10 0.10 -- Hydroxypropyltrimonium Chloride Salcare SC60
Acrylamidopropyltrimonium -- 0.10 0.10 Chloride acrylamide
copolymer PEG 6000 DS PEG-150 Distearate 1.50 1.50 1.50 Fragrance
0.25 0.25 0.25 Versene 100XL Tetrasodium EDTA 0.18 0.18 0.18 Color
(0.10% aq. sol'n) 3.21 3.21 3.21 Dowicil 200 Quaternium-15 0.05
0.05 0.05 Euperian PK 3000 Glycol Distearate, Laureth-4 4.00 4.00
4.00 and Cocamidopropyl Betaine DC 345 Fluid Cyclomethicone 0.75 --
-- Citric Acid (20% Sol'n) pH to Citric Acid 0.85 0.85 0.85 5.9-6.2
Glycerin Glycerin 1.00 1.00 1.00 Deionized Water Deionized Water
Q.S. to Q.S. to Q.S. to 100 100 100
[0219]
5 TABLE 5 Example Ingredient INCI Name of Active Ingredient 6 7 8 9
Tween 20 Polysorbate 20 6.30 6.30 6.30 5.30 Monateric 949-J
Disodium Lauroamphodiacetate 8.29 8.29 8.29 8.29 Empigen BB/J
Lauryl Betaine 2.00 2.00 2.00 2.00 Empicol 0251/70-J Sodium Laureth
Sulfate 4.26 4.26 4.26 4.26 Polymer JR 400 Polyquatemium-10 0.19 --
0.10 0.19 Jaguar C17 Guar hydroxypropyl Trimonium 0.10 0.10 -- 0.10
Chloride Salcare SC60 Acrylamidopropyltrimonium Chloride -- 0.12
0.10 -- acrylamide copolymer PEG 6000 DS PEG-150 Distearate 1.90
1.90 1.90 1.90 Fragrance 0.15 0.15 0.15 0.15 Nervanaid B30
Tetrasodium EDTA 0.20 0.20 0.20 0.20 Color 1 (0.2% solution) 1.25
1.25 1.25 1.25 Color 2 (0.1% solution) 0.30 0.30 0.30 0.30 Genapol
437-X* Ethylene glycol distearate, -- -- -- 2.5 cocamidopropyl
betaine and cocamide monoethanolamid/diethanolamid- e Citric Acid
(20% Sol'n) Citric Acid 1.25 1.25 1.25 1.25 Dowicil 200
Quatemium-15 0.05 0.05 0.05 0.05 Benzyl Alcohol Benzyl Alcohol 0.10
0.10 0.10 0.10 Glycerin Glycerin 1.00 1.00 1.00 1.00 Deionized
Water Deionized Water QS to QS to QS to QS to 100 100 100 100
*Genapol 437-X is a commericial product containing about 20%
ethylene glycol distearate, about 6% cocamidopropyl betaine and
about 5% cocamide monoethanolamide/diethanolamide available from
Hoechst AG, Frankfurt, Germany.
[0220]
6 TABLE 6 Example Ingredient INCI Name of Active Ingredient 10 11
12 Tween 20 Polysorbate 20 0.50 0.50 0.50 Empigen BB/J Lauryl
Betaine 4.20 4.20 4.20 Ampholak 7CX/C Sodium Carboxymethyl 13.34
13.34 13.34 Cocopolypropylamine Empicol SDD Disodium Laureth
Sulfosuccinate 13.79 13.79 13.79 Polymer JR 400 Polyquatemium-10
0.19 -- 0.05 Jaguar C17 Guar hydroxypropyl Trimonium 0.10 0.10 --
Chloride Salcare SC60 Acrylamidopropyltrimonium -- 0.12 0.05
Chloride/ acrylamide copolymer PEG 6000 DS (Comiel PEG-150
Distearate 1.95 1.95 1.95 S.p.A.) Fragrance 0.14 0.14 0.14 Versene
100XL Tetrasodium EDTA 0.20 0.20 0.20 Color (0.2% solution) 0.23
0.23 0.23 Citric Acid (20% Sol'n) Citric Acid 1.77 1.77 1.77
Dowicil 200 Quaternium-15 0.05 0.05 0.05 Glycerin Glycerin 1.00
1.00 1.00 Deionized Water Deionized Water QS to QS to QS to 100 100
100
[0221]
7 TABLE 7 Example Ingredient INCI Name of Active Ingredient 13 14
15 Plantaren 2000N Decyl Glucoside 3.60 3.60 3.60 Atlas G-4280
PEG-80 Sorbitan Laurate 3.60 3.60 3.60 Mirataine CBS Cocamldopropyl
Hydroxysultaine 6.50 6.50 6.50 Monateric 1023 Sodium Lauroampho
PG-Acetate 1.45 1.45 1.45 Phosphate Cedepal SN-303 Sodium Laureth
Sulfate 3.60 3.60 3.60 Polymer JR 400 Polyquatemium-10 0.19 -- 0.10
Jaguar C17 Guar hydroxypropyl Trimonium 0.10 0.10 -- Chloride
Salcare SC60 Acrylamidopropyltrimonium Chloride -- 0.12 0.10
acrylamide copolymer Aculyn 22 Acrylates/Steareth-20 Methacryiate
1.10 1.10 1.10 Copolymer PEG 6000 DS PEG-150 Distearate 0.72 0.72
0.72 Fragrance Versene 100XL Tetrasodiurn EDTA 0.05 0.05 0.05 Color
1 (0.2% solution) Color 2 (0.1% solution) Citric Acid (20% Sol'n)
Citric Acid 0.46 0.46 0.46 Sodium Hydroxide (20% Sodium Hydroxide
0.32 0.32 0.32 Sol'n) Dowicil 200 Quaternium-15 0.05 0.05 0.05
Glycerin Glycerin 1.00 1.00 1.00 Deionized Water Deionized Water QS
to QS to QS to 100 100 100
[0222] Selected compositions from Tables 4-7 were evaluated for
hair and skin cleansing on human subjects, where the compositions
were evaluated for their cleansing, conditioning and irritancy
properties. Selected compositions were also evaluated by manual
washing and combing of tresses. The compositions were found to be
satisfactory conditioning personal cleansing compositions.
Examples 16-54
Preparation of Cleansing Compositions
[0223] Additional compositions are prepared in accordance with the
procedure set forth in Examples 1 and 2 using the components as set
forth in Tables 8-13 below.
8 TABLE 8 Example Ingredient INCI Name of Active Ingredient 16 17
18 19 20 21 22 Ampholak 7CX/C Sodium Carboxymethyl 6.67 13.34 33.35
6.67 20.25 13.34 13.34 Cocopolypropylamine Empicol SDD Disodium
Laureth Sulfosuccinate 6.9 13.79 34.5 20.25 6.67 13.79 13.79
Polymer JR 400 Polyquaternium-10 -- -- -- -- -- 1.0 -- Jaguar C17
Guar hydroxypropyl Trimonium -- -- -- -- -- -- 0.01 Chloride
Salcare SC60 Acrylamidopropyltrimonium Chloride -- -- -- -- -- --
-- acrylamide copolymer PEG 6000 DS (Comiel PEG-150 Distearate * *
* * * * * S.p.A.)* Fragrance 0.14 0.14 0.14 0.14 0.14 0.14 0.14
Versene 100XL Tetrasodium EDTA 0.20 0.20 0.20 0.20 0.20 0.20 0.20
Color (0.2% solution) 0.23 0.23 0.23 0.23 0.23 0.23 0.23 Citric
Acid (20% Sol'n) Citric Acid 1.00 1.77 3.50 1.00 1.77 3.50 3.50
Dowicil 200 Quatemium-15 0.05 0.05 0.05 0.05 0.05 0.05 0.05
Glycerin Glycerin 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Deionized
Water Deionized Water QS to QS to QS to QS to QS to QS to QS to 100
100 100 100 100 100 100 *PEG 6000 DS added in quantity sufficient
to adjust viscosity to between 500 and 10,000 centipoise
[0224]
9 TABLE 9 Example Ingredient INCI Name of Active Ingredient 23 24
25 26 27 28 29 Ampholak 7CX/C Sodium Carboxymethyl 13.34 13.34
13.34 13.34 13.34 13.34 13.34 Cocopolypropylamine Empicol SDD
Disodium Laureth Sulfosuccinate 13.79 13.79 13.79 13.79 13.79 13.79
13.79 Tween 20 Polysorbate 20 -- -- -- -- 2.0 2.0 2.0 Polymer JR
400 Polyquaternium-10 0.005 0.005 0.7 -- 0.05 0.1 0.08 Jaguar C17
Guar hydroxypropyl Trimonium 0.005 -- 0.3 0.5 0.15 -- -- Chloride
Salcare SC60 Acrylamidopropyltrimonium Chloride -- 0.005 -- 0.5 --
0.4 0.04 acrylamide copolymer PEG 6000 DS (Comiel PEG-150
Distearate * * * * * * * S.p.A.)* Fragrance 0.14 0.14 0.14 0.14
0.14 0.14 0.14 Versene 100XL Tetrasodium EDTA 0.20 0.20 0.20 0.20
0.20 0.20 0.20 Color (0.2% solution) 0.23 0.23 0.23 0.23 0.23 0.23
0.23 Citric Acid (20% Sol'n) Citric Acid 1.00 1.77 3.50 1.00 1.77
3.50 3.50 Dowicil 200 Quaternium-15 0.05 0.05 0.05 0.05 0.05 0.05
0.05 Glycerin Glycerin 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Deionized
Water Deionized Water QS to QS to QS to QS to QS to QS to QS to 100
100 100 100 100 100 100 *PEG 6000 DS added in quantity sufficient
to adjust viscosity to between 500 and 10,000 centipoise
[0225]
10 TABLE 10 Example Ingredient INCI Name of Active Ingredient 30 31
32 33 34 35 36 Mirataine CBS Cocamidopropyl Hydroxysultaine 6.67
13.34 33.35 6.67 20.25 13.34 13.34 Empicol SDD Disodium Laureth
Sulfosuccinate 6.9 13.79 34.5 20.25 6.67 13.79 13.79 Polymer JR 400
Polyquaternium-10 -- -- -- -- -- 1.0 -- Jaguar C17 Guar
hydroxypropyl Trimonium -- -- -- -- -- -- 0.01 Chloride Salcare
SC60 Acrylamidopropyltrimonium Chloride -- -- -- -- -- -- --
acrylamide copolymer PEG 6000 DS* PEG-150 Distearate * * * * * * *
Fragrance 0.14 0.14 0.14 0.14 0.14 0.14 0.14 Versene 100XL
Tetrasodium EDTA 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Color (0.2%
solution) 0.23 0.23 0.23 0.23 0.23 0.23 0.23 Citric Acid (20%
Sol'n) Citric Acid 1.00 1.77 3.50 1.00 1.77 3.50 3.50 Dowicil 200
Quaternium-15 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Glycerin Glycerin
1.00 1.00 1.00 1.00 1.00 1.00 1.00 Deionized Water Deionized Water
QS to QS to QS to QS to QS to QS to QS to 100 100 100 100 100 100
100 *PEG 6000 DS added in quantity sufficient to adjust viscosity
to between 500 and 10,000 centipoise
[0226]
11 TABLE 11 Example Ingredient INCI Name of Active Ingredient 37 38
39 40 41 42 43 Ampholak 7CX/C Sodium Carboxymethyl 13.34 13.34
13.34 13.34 13.34 13.34 13.34 Cocopolypropylamine Empicol SDD
Disodium Laureth Sulfosuccinate 13.79 13.79 13.79 13.79 13.79 13.79
13.79 Tween 20 Polysorbate 20 -- -- -- -- 2.0 2.0 2.0 Polymer JR
400 Polyquaternium-10 0.005 0.005 0.7 -- 0.05 0.1 0.08 Jaguar C17
Guar hydroxypropyl Trimonium 0.005 -- 0.3 0.5 0.15 -- -- Chloride
Salcare SC60 Acrylamidopropyltrimonium Chloride -- 0.005 -- 0.5 --
0.4 0.04 acrylamide copolymer PEG 6000 DS (Comiel PEG-150
Distearate * * * * * * * S.P.A.)* Fragrance 0.14 0.14 0.14 0.14
0.14 0.14 0.14 Versene 100XL Tetrasodium EDTA 0.20 0.20 0.20 0.20
0.20 0.20 0.20 Color (0.2% solution) 0.23 0.23 0.23 0.23 0.23 0.23
0.23 Citric Acid (20% Sol'n) Citric Acid 1.00 1.77 3.50 1.00 1.77
3.50 3.50 Dowicil 200 Quaternium-15 0.05 0.05 0.05 0.05 0.05 0.05
0.05 Glycerin Glycerin 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Deionized
Water Deionized Water QS to QS to QS to QS to QS to QS to QS to 100
100 100 100 100 100 100 *PEG 6000 DS added in quantity sufficient
to adjust viscosity to between 500 and 10,000 centipoise
[0227]
12TABLE 12 INCI Name of Active Example Ingredient Ingredient 44 45
46 47 48 49 50 Atlas G-4280 PEG-80 Sorbitan Laurate 2.62 10.5 6.50
13.9 0.14 6.50 6.50 Monateric 949J Lauroamphoglycinate 1.15 4.6
2.85 2.85 2.85 0.3 5.7 Tegobetaine L7 Cocamidopropyl Betaine 5.37
21.5 13.30 13.30 13.30 1.4 26.60 Cedepal TD-403M Sodium Trideceth
Sulfate 3.84 15.35 9.50 9.50 9.50 9.50 9.50 Polymer JR 400
Polyquaternium-10 0.005 0.5 0.25 0.25 0.01 0.1 Jaguar C17 Guar
0.005 -- -- 0.5 0.01 0.1 0.10 Hydroxypropyltrimonium Chloride
Salcare SC60 Acrylamidopropyltrimonium -- 0.5 0.25 -- 0.01 0.10
Chloride acrylamide copolymer PEG 6000 DS* PEG-150 Distearate * * *
* * * * Fragrance 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Versene 100XL
Tetrasodium EDTA 0.18 0.18 0.18 0.18 0.18 0.18 0.18 Color (0.10%
aq. sol'n) 3.21 3.21 3.21 3.21 3.21 3.21 3.21 Dowicil 200
Quaternium-15 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Euperlan PK 3000
Glycol Distearate, Laureth-4 4.00 4.00 4.00 4.00 4.00 4.00 4.00 and
Cocamidopropyl Betaine DC 345 Fluid Cyclomethicone 0.75 0.75 0.75
0.75 0.75 0.75 0.75 Citric Acid (20% Sol'n) pH to Citric Acid 0.85
0.85 0.85 0.85 0.85 0.85 0.85 5.9-6.2 Glycerin Glycerin 1.00 1.00
1.00 1 00 1.00 1.00 1.00 Deionized Water Deionized Water Q.S to Q.S
to Q.S to Q.S to Q.S to Q.S to Q.S to 100 100 100 100 100 100 100
*PEG 6000 DS added in quantity sufficient to adjust viscosity to
between 500 and 10,000 centipoise
[0228]
13TABLE 13 INCI Name of Active Example Ingredient Ingredient 51 52
53 54 Atlas G-4280 PEG-80 Sorbitan Laurate 6.50 6.50 6.50 6.50
Monateric 949J Lauroamphoglycinate 2.85 2.85 2.85 2.85 Tegobetaine
L7 Cocamidopropyl Betaine 13.30 13.30 13.30 13.30 Cedepal TD-403M
Sodium Trideceth Sulfate 3.33 33.3 9.50 9.50 Polymer JR 400
Polyquaternium-10 0.10 0.10 0.10 Jaguar Cl7 Guar -- -- -- 0.10
Hydroxypropyltrimonium Chloride Salcare SC60
Acrylamidopropyltrimonium 0.10 0.10 -- -- Chloride acrylamide
copolymer Salcare SC30 Polyquaternium-6 -- -- 0.10 Salcare SC10
Polyquaternium-7 -- -- 0.10 PEG 6000 DS* PEG-150 Distearate * * * *
Fragrance 0.25 0.25 0.25 0.25 Versene 100XL Tetrasodium EDTA 0.18
0.18 0.18 0.18 Color (0.10% aq. sol'n) 3.21 3.21 3.21 3.21 Dowicil
200 Quaternium-15 0.05 0.05 0.05 0.05 Euperlan PK 3000 Glycol
Distearate, Laureth-4 4.00 4.00 4.00 4.00 and Cocamidopropyl
Betaine DC 345 Fluid Cyclomethicone 0.75 0.75 0.75 0.75 Citric Acid
(20% Sol'n) pH to Citric Acid 0.85 0.85 0.85 0.85 5.9-6.2 Glycerin
Glycerin 1.00 1.00 1.00 1.00 Deionized Water Deionized Water Q.S.
to Q.S. to Q.S. to Q.S. to 100 100 100 100 *PEG 6000 DS added in
quantity sufficient to adjust viscosity to between 500 and 10,000
centipoise
Example 55
In vitro Tests
[0229] Samples of shampoo compositions shown in Table 14 were
evaluated in in vitro tests. In general, members of a test panel
were given a blind sample of each respective formulation in Table
14, as well as a blind sample of commercially available Pert Plus
for Kids; conditioning shampoo ("Pert Plus"). The members were
asked to independently use the samples, in approximately
equivalents amounts, to shampoo and condition their hair for a
given period of time.
[0230] The results of the in vitro tests revealed that formulations
of Examples 1 and 5 were rated as partly to Pert Plus with respect
to ease of conditioning of hair in the dry and wet states. However,
the formulation of Example 1 was preferred relative to Pert Plus
for the attribute of speed of detangling. By contrast; the
formulation of Comparative Example 3, containing only a single
cationic polymeric conditioner, was less preferred than Pert Plus
with respect to these attributes. These results further illustrated
that the formulations of the present invention containing at least
two conditioning polymers demonstrated performance superior to
shampoos containing only a single conditioning polymer.
14 TABLE 14 Comparative INCI Name of Active Example Example
Ingredient Ingredient 1 5 3 Atlas G-4280 PEG-80 Sorbitan Laurate
6.50 6.50 6.50 Monateric 949J Lauroamphoglycinate 2.85 2.85 2.85
Tegobetaine L7 Cocamidopropyl Betaine 13.30 13.30 13.30 Cedepal
TD-403M Sodium Trideceth Sulfate 9.50 9.50 9.50 Polymer JR 400
Polyquaternium-10 0.19 0.10 -- JaguarC17 Guar 0.10 -- --
Hydroxypropyltrimonium Chloride Salcare SC60
Acrylamidopropyltrimonium -- 0.10 0.12 chloride acrylamide
copolymer PEG 6000 DS PEG-150 Distearate 1.50 1.50 0.50 Fragrance
0.25 0.25 0.25 Versene 100XL Tetrasodium EDTA 0.18 0.18 0.18 Color
(0.10% aq. sol'n) 3.21 3.21 3.21 Dowicil 200 Quaternium-15 0.05
0.05 0.05 Euperian PK 3000 Glycol Distearate, Laureth-4 4.00 4.00
4.00 and Cocamidopropyl Betaine DC 345 Fluid Cyclomethicone 0.75 --
-- Citric Acid (20% Sol'n) pH to Citric Acid 0.85 0.85 0.85 5.9-6.2
Glycerin Glycerin 1.00 1.00 1.00 Deionized Water Deionized Water
Q.S. to Q.S. to Q.S. to 100 100 100
* * * * *