U.S. patent application number 10/160827 was filed with the patent office on 2002-10-17 for three-layer-cover golf ball.
Invention is credited to Sullivan, Michael J..
Application Number | 20020151381 10/160827 |
Document ID | / |
Family ID | 25315504 |
Filed Date | 2002-10-17 |
United States Patent
Application |
20020151381 |
Kind Code |
A1 |
Sullivan, Michael J. |
October 17, 2002 |
Three-layer-cover golf ball
Abstract
A golf ball comprising a core and a cover, wherein the cover
comprises an inner cover layer being disposed directly adjacent the
core; an outer cover layer having a thickness less than about 0.050
inches; and an intermediate cover layer is disposed between the
inner and outer cover layers; and wherein the outer cover layer
comprises a composition formed of a reactive liquid material; and
the combination of the inner, outer, and intermediate cover layers
have a thickness of less than about 0.125 inches.
Inventors: |
Sullivan, Michael J.;
(Barrington, RI) |
Correspondence
Address: |
William B. Lacy
Acushnet Company
333 Bridge Street
Fairhaven
MA
02719
US
|
Family ID: |
25315504 |
Appl. No.: |
10/160827 |
Filed: |
May 30, 2002 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
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10160827 |
May 30, 2002 |
|
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09853252 |
Apr 10, 2001 |
|
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Current U.S.
Class: |
473/354 |
Current CPC
Class: |
A63B 37/0031 20130101;
A63B 37/0056 20130101; A63B 37/0024 20130101; A63B 37/0045
20130101; A63B 37/0033 20130101; A63B 37/0052 20130101; A63B
37/0027 20130101; A63B 37/0035 20130101; A63B 37/0021 20130101;
A63B 37/0064 20130101; A63B 37/0083 20130101; A63B 37/0003
20130101; A63B 37/00921 20200801; A63B 37/0076 20130101; A63B
37/0066 20130101; A63B 37/0043 20130101; A63B 37/0037 20130101;
A63B 37/008 20130101; A63B 37/12 20130101 |
Class at
Publication: |
473/354 |
International
Class: |
A63B 037/08 |
Claims
What is claimed is:
1. A golf ball comprising a core and a cover, wherein the cover
comprises: a) an inner cover layer being disposed directly adjacent
the core; b) an outer cover layer having a thickness less than
about 0.050 inches; and c) an intermediate cover layer is disposed
between the inner and outer cover layers; and wherein d) the outer
cover layer comprises a composition formed of a reactive liquid
material; and e) the combination of the inner, outer, and
intermediate cover layers have a thickness of less than about 0.125
inches.
2. The golf ball of claim 1, wherein the outer cover layer has a
thickness less than about 0.035 inches.
3. The golf ball of claim 2, wherein the outer cover layer
thickness is less than about 0.025 inches.
4. The golf ball of claim 1, wherein the thickness of the
combination of the inner, outer, and intermediate cover layers is
less than about 0.105 inches.
5. The golf ball of claim 4, wherein the thickness of the
combination of the inner, outer, and intermediate cover layers is
less than about 0.090 inches.
6. The golf ball of claim 1, wherein the reactive liquid material
comprises a castable liquid reactive thermoset material or a
reaction injection molding material.
7. The golf ball of claim 6, wherein the inner cover layer is
formed of a material comprising polyolefins, polyethylene,
polypropylene, polybutylene, polyethylene acrylic acid copolymers,
polyethylene methacrylic acid copolymers, polyethylene methacrylic
acid terpolymers, polyethylene acrylic acid terpolymers,
polyethylene ethyl acrylate, polyethylene methyl acrylate,
polyethylene vinyl acetate, polyethylene glycidyl alkyl acrylate,
ionomers fully or partially neutralized by a metal ion source or a
salt of an organic acid, or a mixture thereof.
8. The golf ball of claim 7, wherein the inner cover layer has a
material hardness of at least about 55 Shore D.
9. The golf ball of claim 7, wherein the inner cover layer has a
material hardness of at least about 60 Shore D.
10. The golf ball of claim 7, wherein the intermediate cover layer
comprises a thermoplastic material comprising partially or fully
neutralized ionomers, polyolefins, metallocenes, polyesters,
polyamides, thermoplastic elastomers, copolyether-esters,
copolyether-amides, and thermoplastic polyurethanes.
11. The golf ball of claim 10, wherein the intermediate cover layer
has a material hardness of at least 30 Shore D.
12. The golf ball of claim 10, wherein the intermediate cover layer
has a material hardness of at least about 60 Shore D.
13. The golf ball of claim 7, wherein the intermediate cover layer
comprises a composition formed of a reactive liquid material.
14. The golf ball of claim 13, wherein the reactive liquid material
comprises a castable liquid reactive thermoset material or a
reaction injection moldable material.
15. The golf ball of claim 13, wherein the reactive thermoset
material comprises polyurethanes, polyureas, polyurethane ionomers,
epoxies, or a mixture thereof.
16. A golf ball comprising a thermoplastic inner cover layer, an
intermediate cover layer, and outer cover layer comprising a
reactive liquid material.
17. The golf ball of claim 16, wherein the reactive liquid material
comprises polyurethane, polyurea, polyurethane ionomer, epoxy, or a
mixture thereof.
18. The golf ball of claim 16, wherein the inner cover layer is
formed of a material comprising polyolefins, polyethylene,
polypropylene, polybutylene, polyethylene acrylic acid copolymers,
polyethylene methacrylic acid copolymers, polyethylene methacrylic
acid terpolymers, polyethylene acrylic acid terpolymers,
polyethylene ethyl acrylate, polyethylene methyl acrylate,
polyethylene vinyl acetate, polyethylene glycidyl alkyl acrylate,
ionomers fully or partially neutralized by a metal ion source or a
salt of an organic acid, or a mixture thereof.
19. The golf ball of claim 1, wherein the outer cover has a
material hardness of greater than about 55 Shore D.
20. The golf ball of claim 1, wherein the outer cover has a
material hardness of between about 10 and about 40 Shore D.
21. A golf ball comprising a core and a cover, wherein the cover
comprises: a) an inner cover layer being disposed directly adjacent
the core; b) an outer cover layer; and c) an intermediate cover
layer is disposed between the inner and outer cover layers; and
wherein the inner, intermediate, and outer cover layers comprise a
composition formed of a reactive liquid material; and the
combination of the inner, outer, and intermediate cover layers have
a thickness of less than about 0.125 inches.
Description
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] This application is a continuation of U.S. application Ser.
No. 09/853,252, filed Apr. 11, 2001, the disclosure of which is
incorporated herein by reference.
FIELD OF THE INVENTION
[0002] This invention relates generally to golf balls, and more
specifically, to a golf ball having a cover comprising three or
more layers.
BACKGROUND OF THE INVENTION
[0003] The majority of golf balls commercially available today can
be grouped into two general classes: solid and wound. Solid golf
balls include one-piece, two-piece, and multi-layer golf balls.
One-piece golf balls are inexpensive and easy to construct, but
have limited playing characteristics and their use is usually
confined to the driving range. Two-piece balls are generally
constructed with a polybutadiene solid core and a cover and are
typically the most popular with recreational golfers because they
are very durable and provide good distance. These balls are also
relatively inexpensive and easy to manufacture, but are regarded by
top players as having limited playing characteristics. Multi-layer
golf balls are comprised of a solid core and a cover, either of
which may be formed of one or more layers. These balls are regarded
as having an extended range of playing characteristics, but are
more expensive and difficult to manufacture than are one- and
two-piece golf balls.
[0004] Wound golf balls, which typically include a fluid-filled
center surrounded by tensioned elastomeric material and a cover,
are preferred by many players due to their spin and "feel"
characteristics but are more difficult and expensive to manufacture
than are most solid golf balls. Manufacturers are constantly
striving, therefore, to produce a solid ball that retains the
beneficial characteristics of a solid ball while concurrently
exhibiting the beneficial characteristics of a wound ball.
[0005] Golf ball playing characteristics, such as compression,
velocity, "feel," and, therefore, spin, can be adjusted and
optimized by manufacturers to suit players having a wide variety of
playing abilities. For example, manufacturers can alter any or all
of these properties by changing the materials (i.e., polymer
compositions) and/or the physical construction of each or all of
the various golf ball components (i.e., centers, cores,
intermediate layers, and covers). Finding the right combination of
core and layer materials and the ideal ball construction to produce
a golf ball suited for a predetermined set of performance criteria
is a challenging task.
[0006] Efforts to construct a multi-layer golf ball that has the
benefits of both solid and wound balls have been numerous but
manufacturers have generally focused on the use of cover layers
formed of ionomeric compositions. It has been determined, however,
that it is difficult to provide good "feel" characteristics in a
golf ball with the use of non-polyurethane materials, such as
ionomers, which tend to provide a "plastic feel."
[0007] It is desirable, therefore, to construct a golf ball formed
of a thin urethane outer cover layer, at least two inner cover
layers, and at least one core layer, according to the present
invention. In particular, it is desired that this construction
produce a multi-layer golf ball having variable spin rates, based
on predetermined ball construction, while providing the golfer with
good "feel" characteristics generally associated with other
conventional ball constructions.
SUMMARY OF THE INVENTION
[0008] The present invention is also directed to a golf ball
comprising a core and a cover, wherein the cover comprises an inner
cover layer being disposed directly adjacent the core; an outer
cover layer having a thickness less than about 0.050 inches; and an
intermediate cover layer is disposed between the inner and outer
cover layers; and wherein the outer cover layer comprises a
composition formed of a reactive liquid material; and the
combination of the inner, outer, and intermediate cover layers have
a thickness of less than about 0.125 inches.
[0009] The outer cover layer has a thickness less than about 0.035
inches, more preferably less than about 0.025 inches. The thickness
of the combination of the inner, outer, and intermediate cover
layers is less than about 0.105 inches, preferably less than about
0.090 inches. The reactive liquid material is a castable liquid
reactive thermoset material or a reaction injection molding
material.
[0010] The inner cover layer is formed of a material including
polyolefins, polyethylene, polypropylene, polybutylene,
polyethylene acrylic acid copolymers, polyethylene methacrylic acid
copolymers, polyethylene methacrylic acid terpolymers, polyethylene
acrylic acid terpolymers, polyethylene ethyl acrylate, polyethylene
methyl acrylate, polyethylene vinyl acetate, polyethylene glycidyl
alkyl acrylate, ionomers fully or partially neutralized by a metal
ion source or a salt of an organic acid, or a mixture thereof. The
inner cover layer has a material hardness of at least about 55
Shore D, preferably at least about 60 Shore D.
[0011] The intermediate cover layer comprises a thermoplastic
material including partially or fully neutralized ionomers,
polyolefins, metallocenes, polyesters, polyamides, thermoplastic
elastomers, copolyether-esters, copolyether-amides, and
thermoplastic polyurethanes. The intermediate cover layer has a
material hardness of at least about 60 Shore D and includes a
composition formed of a reactive liquid material.
[0012] The reactive liquid material is a castable liquid reactive
thermoset material or a reaction injection moldable material, and
preferably includes polyurethanes, polyureas, polyurethane
ionomers, epoxies, or a mixture thereof.
[0013] The present invention is also directed to a golf ball
comprising a thermoplastic inner cover layer and an intermediate
and outer cover layer comprising a reactive liquid material such as
a polyurethane, polyurea, polyurethane ionomer, epoxy, or a mixture
thereof.
[0014] The inner cover layer may be formed of a material comprising
polyolefins, polyethylene, polypropylene, polybutylene,
polyethylene acrylic acid copolymers, polyethylene methacrylic acid
copolymers, polyethylene methacrylic acid terpolymers, polyethylene
acrylic acid terpolymers, polyethylene ethyl acrylate, polyethylene
methyl acrylate, polyethylene vinyl acetate, polyethylene glycidyl
alkyl acrylate, ionomers fully or partially neutralized by a metal
ion source or a salt of an organic acid, or a mixture thereof. The
outer cover has a material hardness of greater than about 55 Shore
D or, alternatively, between about 10 and about 40 Shore D.
[0015] The present invention is also directed to a golf ball
comprising a core and a cover, wherein the cover comprises an inner
cover layer being disposed directly adjacent the core; an outer
cover layer; and an intermediate cover layer is disposed between
the inner and outer cover layers; and wherein the inner,
intermediate, and outer cover layers comprise a composition formed
of a reactive liquid material; and the combination of the inner,
outer, and intermediate cover layers have a thickness of less than
about 0.125 inches.
BRIEF DESCRIPTION OF THE DRAWINGS
[0016] FIG. 1 is one embodiment of the golf ball of the present
invention having a solid core and an inner, intermediate, and outer
cover layer;
[0017] FIG. 2 is a second embodiment of the golf ball of the
present invention having a core formed of a solid center and an
outer core layer; and an inner, intermediate, and outer cover
layer; and
[0018] FIG. 3 is a third embodiment of the present invention having
a liquid core formed of a liquid center and an outer core layer;
and a cover formed of an inner, intermediate, and outer cover
layer.
DETAILED DESCRIPTION OF THE INVENTION
[0019] Referring to FIG. 1, a golf ball 10 of the present invention
includes a core 12 and a cover comprising an outer cover 14 and at
least two inner cover layers, such as inner cover layer 16 and
intermediate cover layer 18. The golf ball cores of the present
invention may be formed with a variety of constructions. For
example, a golf ball 20 may also comprise a core comprising a
plurality of layers, such as a center 22 and an outer core layer
24, and a cover comprising an outer cover layer 26, an inner cover
layer 28, and an intermediate cover layer 30, as seen in FIG. 2.
Referring to FIG. 3, the golf ball 40 may also comprise a core 44
comprising a solid, liquid, foam, gel, or hollow center 42, and a
cover comprising an outer cover layer 46, an inner cover layer 48,
and an intermediate cover layer 50. Any one of the inner cover
layer 48 or the intermediate cover layer 50 may also comprise a
tensioned elastomeric material. In a preferred embodiment, the core
is a solid core.
[0020] Materials for solid cores include compositions having a base
rubber, a filler, an initiator agent, and a crosslinking agent. The
base rubber typically includes natural or synthetic rubber, such as
polybutadiene rubber. A preferred base rubber is 1,4-polybutadiene
having a cis-structure of at least 40%. Most preferably, however,
the solid core is formed of a resilient rubber-based component
comprising a high-Mooney-viscosity rubber and a crosslinking
agent.
[0021] Another suitable rubber from which to form cores of the
present invention is trans-polybutadiene. This polybutadiene isomer
is formed by converting the cis- isomer of the polybutadiene to the
trans- isomer during a molding cycle. Various combinations of
polymers, cis-to-trans catalysts, fillers, crosslinkers, and a
source of free radicals, may be used. A variety of methods and
materials for performing the cis-to-trans conversion have been
disclosed in U.S. Pat. No. 6,162,135 and U.S. application Ser. No.
09/461,736, filed Dec. 16, 1999; 09/458,676, filed Dec. 10, 1999;
and 09/461,421, filed Dec. 16, 1999, each of which are incorporated
herein, in their entirety, by reference.
[0022] Additionally, without wishing to be bound by any particular
theory, it is believed that a low amount of 1,2-polybutadiene
isomer ("vinyl-polybutadiene") is preferable in the initial
polybutadiene to be converted to the trans- isomer. Typically, the
vinyl polybutadiene isomer content is less than about 7 percent,
more preferably less than about 4 percent, ans most preferably,
less than about 2 percent.
[0023] Fillers added to one or more portions of the golf ball
typically include processing aids or compounds to affect
rheological and mixing properties, the specific gravity (i.e.,
density-modifying fillers), the modulus, the tear strength,
reinforcement, and the like. The fillers are generally inorganic,
and suitable fillers include numerous metals or metal oxides, such
as zinc oxide and tin oxide, as well as barium sulfate, zinc
sulfate, calcium carbonate, barium carbonate, clay, tungsten,
tungsten carbide, an array of silicas, and mixtures thereof.
Fillers may also include various foaming agents or blowing agents,
zinc carbonate, regrind (recycled core material typically ground to
about 30 mesh or less particle size), high-Mooney-viscosity rubber
regrind, and the like. Polymeric, ceramic, metal, and glass
microspheres may be solid or hollow, and filled or unfilled.
Fillers are typically also added to one or more portions of the
golf ball to modify the density thereof to conform to uniform golf
ball standards. Fillers may also be used to modify the weight of
the center or any or all core and cover layers, if present.
[0024] The initiator agent can be any known polymerization
initiator which decomposes during the cure cycle. Suitable
initiators include peroxide compounds such as dicumyl peroxide,
1,1-di(t-butylperoxy) 3,3,5-trimethyl cyclohexane, a-a bis
(t-butylperoxy) diisopropylbenzene, 2,5-dimethyl-2,5
di(t-butylperoxy) hexane or di-t-butyl peroxide and mixtures
thereof.
[0025] Crosslinkers are included to increase the hardness and
resilience of the reaction product. The crosslinking agent includes
a metal salt of an unsaturated fatty acid such as a zinc salt or a
magnesium salt of an unsaturated fatty acid having 3 to 8 carbon
atoms such as acrylic or methacrylic acid. Suitable cross linking
agents include metal salt diacrylates, dimethacrylates and
monomethacrylates wherein the metal is magnesium, calcium, zinc,
aluminum, sodium, lithium or nickel. Preferred acrylates include
zinc acrylate, zinc diacrylate, zinc methacrylate, and zinc
dimethacrylate, and mixtures thereof.
[0026] The crosslinking agent must be present in an amount
sufficient to crosslink a portion of the chains of polymers in the
resilient polymer component. This may be achieved, for example, by
altering the type and amount of crosslinking agent, a method
well-known to those of ordinary skill in the art.
[0027] When the core is formed of a single solid layer comprising a
high-Mooney-viscosity rubber, the crosslinking agent is present in
an amount from about 15 to about 40 parts per hundred, more
preferably from about 30 to about 38 parts per hundred, and most
preferably about 37 parts per hundred.
[0028] In another embodiment of the present invention, the core
comprises a solid center and at least one outer core layer. When
the optional outer core layer is present, the center preferably
comprises a high-Mooney-viscosity rubber and a crosslinking agent
present in an amount from about 10 to about 30 parts per hundred of
the rubber, preferably from about 19 to about 25 parts per hundred
of the rubber, and most preferably from about 20 to 24 parts
crosslinking agent per hundred of rubber.
[0029] The core composition should comprise at least one rubber
material having a resilience index of at least about 40. Preferably
the resilience index is at least about 50. Polymers that produce
resilient golf balls and, therefore, are suitable for the present
invention, include but are not limited to CB23, CB22, BR60, and
1207G.
[0030] Additionally, the unvulcanized rubber, such as
polybutadiene, in golf balls prepared according to the invention
typically has a Mooney viscosity of between about 40 and about 80,
more preferably, between about 45 and about 60, and most
preferably, between about 45 and about 55. Mooney viscosity is
typically measured according to ASTM D-1646.
[0031] The polymers, free-radical initiators, filler, crosslinking
agents, and any other materials used in forming either the golf
ball center or any portion of the core, in accordance with
invention, may be combined to form a mixture by any type of mixing
known to one of ordinary skill in the art. Suitable types of mixing
include single pass and multi-pass mixing, and the like. The
crosslinking agent, and any other optional additives used to modify
the characteristics of the golf ball center or additional layer(s),
may similarly be combined by any type of mixing. A single-pass
mixing process where ingredients are added sequentially is
preferred, as this type of mixing tends to increase efficiency and
reduce costs for the process. The preferred mixing cycle is single
step wherein the polymer, cis-to-trans catalyst, filler, zinc
diacrylate, and peroxide are added sequentially.
[0032] Suitable mixing equipment is well known to those of ordinary
skill in the art, and such equipment may include a Banbury mixer, a
two-roll mill, or a twin screw extruder. Conventional mixing speeds
for combining polymers are typically used, although the speed must
be high enough to impart substantially uniform dispersion of the
constituents. On the other hand, the speed should not be too high,
as high mixing speeds tend to break down the polymers being mixed
and particularly may undesirably decrease the molecular weight of
the resilient polymer component. The speed should thus be low
enough to avoid high shear, which may result in loss of desirably
high molecular weight portions of the polymer component. Also, too
high a mixing speed may undesirably result in creation of enough
heat to initiate the crosslinking before the preforms are shaped
and assembled around a core. The mixing temperature depends upon
the type of polymer components, and more importantly, on the type
of free-radical initiator. Additionally, it is important to
maintain a mixing temperature below the peroxide decomposition
temperature. Suitable mixing speeds and temperatures are well-known
to those of ordinary skill in the art, or may be readily determined
without undue experimentation.
[0033] The mixture can be subjected to compression or injection
molding processes, for example, to obtain solid spheres for the
core or hemispherical shells for forming an intermediate layer,
such as an outer core layer or an inner cover layer. The polymer
mixture is subjected to a molding cycle in which heat and pressure
are applied while the mixture is confined within a mold. The cavity
shape depends on the portion of the golf ball being formed. The
molding cycle may have a single step of molding the mixture at a
single temperature for a fixed time duration. The molding cycle may
also include a two-step process, in which the polymer mixture is
held in the mold at an initial temperature for an initial duration
of time, followed by holding at a second, typically higher
temperature for a second duration of time. In a preferred
embodiment of the current invention, a single-step cure cycle is
employed. Single-step processes are effective and efficient,
reducing the time and cost of a two-step process.
[0034] Further, the core and layers of the present invention may be
reaction injection molded ("RIM"), liquid injection molded ("LIM"),
or injection molded. In the most preferred embodiment, the layers
of the present invention are reaction injection molded. In the RIM
process, at least two or more reactive low viscosity liquid
components are mixed by impingement and injected under high
pressure (1200 psi or higher) into an open or closed mold. The
reaction times for the RIM systems are much faster than the low
pressure mixing and metered machines and, consequently, the raw
materials used for the RIM process are generally much lower in
viscosity to allow intimate mixing. A RIM machine can process fast
reacting materials having viscosities up to about 2,000 cP and a
pot life of less than about 5 seconds. Because low viscosity
materials are used in the RIM process, the components are capable
of being mixed by impingement in less than a second before
injecting the mixed material into the closed mold at about 2,000 to
about 2,500 psi. With a conventional castable urethane process,
materials having viscosities greater than about 3,500 are required
and also require a pot life of greater than about 35 seconds.
[0035] The polybutadiene, cis-to-trans conversion catalyst, if
present, additional polymers, free-radical initiator, filler, and
any other materials used in forming any portion of the golf ball
core, in accordance with the invention, may be combined to form a
golf ball layer by an injection molding process, which is also
well-known to one of ordinary skill in the art. Although the curing
time depends on the various materials selected, those of ordinary
skill in the art will be readily able to adjust the curing time
upward or downward based on the particular materials used and the
discussion herein.
[0036] The cover provides the interface between the ball and a
club. Properties that are desirable for the cover include good
moldability, high abrasion resistance, high tear strength, high
resilience, and good mold release. The cover of the present
invention is a multi-layer cover, preferably comprised of at least
three layers, such as an inner cover layer, an intermediate cover
layer, and an outer cover layer. While the various cover layers of
the present invention may be of any individual thickness, it is
preferred that the combination of cover layer thicknesses be no
greater than about 0.125 inches, more preferably, no greater than
about 0.105 inches, and most preferably, no greater than about 0.09
inches.
[0037] Any one of the at least three cover layers preferably has a
thickness of less than about 0.05 inches, and more preferably,
between about 0.02 inches and about 0.04 inches. Most preferably,
the thickness of any one of the layers is between about 0.03 inches
and about 0.04 inches.
[0038] The inner cover and any intermediate cover layers, can
include any materials known to those of ordinary skill in the art,
including thermoplastic and thermosetting materials, but preferably
include ionic copolymers of ethylene and an unsaturated
monocarboxylic acid, such as SURLYN.RTM., commercially available
from E. I. DuPont de Nemours & Co., of Wilmington, Del., and
IOTEK.RTM. or ESCOR.RTM., commercially available from Exxon. These
are copolymers or terpolymers of ethylene and methacrylic acid or
acrylic acid partially neutralized with salts of zinc, sodium,
lithium, magnesium, potassium, calcium, manganese, nickel or the
like, in which the salts are the reaction product of an olefin
having from 2 to 8 carbon atoms and an unsaturated monocarboxylic
acid having 3 to 8 carbon atoms. The carboxylic acid groups of the
copolymer may be totally or partially neutralized and might include
methacrylic, crotonic, maleic, fumaric or itaconic acid.
[0039] The cover materials of this invention can likewise be used
in conjunction with homopolymeric and copolymer materials such
as:
[0040] (1) Vinyl resins such as those formed by the polymerization
of vinyl chloride, or by the copolymerization of vinyl chloride
with vinyl acetate, acrylic esters or vinylidene chloride.
[0041] (2) Polyolefins such as polyethylene, polypropylene,
polybutylene and copolymers such as ethylene methylacrylate,
ethylene ethylacrylate, ethylene vinyl acetate, ethylene
methacrylic or ethylene acrylic acid or propylene acrylic acid and
copolymers and homopolymers produced using single-site
catalyst.
[0042] (3) Polyurethanes including those prepared from polyols and
diisocyanates or polyisocyanates and those disclosed in U.S. Pat.
No. 5,334,673.
[0043] (4) Polyureas such as those disclosed in U.S. Pat. No.
5,484,870.
[0044] (5) Cationic and anionic polyurethane and polyurea ionomers,
including:
[0045] (a) thermoplastic and thermoset cationic polyurethane and
polyurea ionomers containing cationic moieties such as quatemized
nitrogen groups associated with halide or acetate anion either on
the pendant or polymer backbone of polyurethane or polyurea; or
[0046] (b) thermoplastic and thermoset anionic polyurethane and
polyurea ionomers containing anionic moieties such as carboxylate
or sulfonate or phosphonate neutralized with counter cations either
on the pendant or polymer backbone of polyurethane or polyurea.
[0047] (6) Non-elastic thermoplastics like polyesters and
polyamides such as poly(hexamethylene adipamide) and others
prepared from diamines and dibasic acids, as well as those from
amino acids such as poly(caprolactam). Still further, non-elastic
thermoplastics can include polyethylene terephthalate, polybutylene
terephthalate, polyethylene terephthalate/glycol ("PETG"),
polyphenylene oxide resins, and blends of non-elastic
thermoplastics with SURLYN.RTM., polyethylene, ethylene copolymers,
ethylene-propylene diene terpolymer, etc.
[0048] (7) Acrylic resins and blends of these resins with poly
vinyl chloride, elastomers, etc.
[0049] (8) Thermoplastic rubbers such as olefinic thermoplastic
rubbers including blends of polyolefins with ethylene-propylene
diene terpolymer.
[0050] (9) Thermoplastic elastomers including block copolymers of
styrene and butadiene, or isoprene or ethylene-butylene rubber,
copoly(ether-amides) such as PEBAX.RTM. sold by Elf-Atochem,
copoly(ether-ester) block copolymer elastomers sold under the
trademarks HYTREL.RTM. from DuPont and LOMOD.RTM. from General
Electric Company of Pittsfield, Mass.
[0051] (10) Blends and alloys, including polycarbonate with
acrylonitrile butadiene styrene, polybutylene terephthalate,
polyethylene terephthalate, styrene maleic anhydride, polyethylene,
elastomers, etc. Blends such as polyvinyl chloride with
acrylonitrile butadiene styrene or ethylene vinyl acetate or other
elastomers. Blends of thermoplastic rubbers with polyethylene,
polypropylene, polyacetal, polyamides, polyesters, cellulose
esters, etc.
[0052] (11) Saponified polymers and blends thereof, including:
saponified polymers obtained by reacting copolymers or terpolymers
having a first monomeric component having olefinic monomer from 2
to 8 carbon atoms, a second monomeric component comprising an
unsaturated carboxylic acid based acrylate class ester having from
4 to 22 carbon atoms, and an optional third monomeric component
comprising at least one monomer selected from the group consisting
of carbon monoxide, sulfur dioxide, an anhydride, a glycidyl group
and a vinyl ester with sufficient amount of an inorganic metal
base. These saponified polymers can be blended with ionic and
non-ionic thermoplastic and thermoplastic elastomeric materials to
obtain a desirable property.
[0053] (12) Copolymer and terpolymers containing glycidyl alkyl
acrylate and maleic anhydride groups, including: copolymers and
terpolymers containing glycidyl alkyl acrylate and maleic anhydride
groups with a first monomeric component having olefinic monomer
from 2 to 8 carbon atoms, a second monomeric component comprising
an unsaturated carboxylic acid based acrylate class ester having
from 4 to 22 carbon atoms, and an optional third monomeric
component comprising at least one monomer selected from the group
consisting of carbon monoxide, sulfur dioxide, an anhydride, a
glycidyl group and a vinyl ester. The above polymers can be blended
with ionic and non-ionic thermoplastic and thermoplastic
elastomeric materials to obtain a desirable mechanical
property.
[0054] (13) HiCrystalline acid copolymers and their ionomers,
including: acid copolymers or its ionomer derivatives formed from
an ethylene and carboxylic acid copolymer comprising about 5 to 35
percent by weight acrylic or methacrylic acid, wherein said
copolymer is polymerized at a temperature of about 130.degree. C.
to about 200.degree. C. and a pressure of about 20,000 psi to about
50,000 psi and wherein up to about 70 percent to of the acid groups
were neutralized with a metal ion.
[0055] (14) Oxa acid compounds including those containing oxa
moiety in the backbone having the formula: 1
[0056] where R is an organic moiety comprising moieties having the
formula: 2
[0057] and alkyl, carbocyclic and heterocyclic groups; R' is an
organic moiety comprising alkyl, carbocyclic, carboxylic acid, and
heterocyclic groups; and n is an integer greater than 1. Also, R'
can have the formula: 3
[0058] (15) Fluoropolymers including those having the following
formula: 4
[0059] in which a is a number from 1 to 100, b is a number from 99
to 1, R.sub.1-R.sub.7 are independently selected from the group
consisting of H, F, alkyl and aryl, and R.sub.8 is F or a moiety of
the formula: 5
[0060] in which m is a number from 1 to 18 and Z is selected from
the group consisting of SO.sub.2F, SO.sub.3H, SO.sub.3M.sup.v+,
COF, CO.sub.2H and CO.sub.2M.sup.v+, wherein v is the valence of M
and M is a cation selected from Group I, Ia, IIa, IIb, IIa, IIIb,
1Va, IVb and transition elements. (16) Magnesium ionomers formed
from an olefin and carboxyllic acid copolymer comprising about 5 to
35 weight percent of acrylic or methacrylic acid which are
neutralized up to 60 weight percent by magnesium oxide or magnesium
acetate or magnesium hydroxide.
[0061] Preferably, the inner and/or intermediate cover layer(s) are
comprised of polymers such as ethylene, propylene, butene-1 or
hexane-1 based homopolymers and copolymers including functional
monomers such as acrylic and methacrylic acid and fully or
partially neutralized ionomer resins and their blends, methyl
acrylate, methyl methacrylate homopolymers and copolymers,
imidized, amino group containing polymers, polycarbonate,
reinforced polyamides, polyphenylene oxide, high impact
polystyrene, polyether ketone, polysulfone, poly(phenylene
sulfide), acrylonitrile-butadiene, acrylic-styrene-acrylonitrile,
poly(ethylene terephthalate), poly(butylene terephthalate),
poly(ethylene vinyl alcohol), poly(tetrafluoroethylene) and their
copolymers including functional comonomers and blends thereof.
Still further, the cover 11 is preferably comprised of a polyether
or polyester thermoplastic urethane, a thermoset polyurethane, an
ionomer such as acid-containing ethylene copolymer ionomers,
including E/X/Y copolymers where E is ethylene, X is an acrylate or
methacrylate-based softening comonomer present in 0 to 50 weight
percent and Y is acrylic or methacrylic acid present in 5 to 35
weight percent. The acrylic or methacrylic acid is present in 16 to
35 weight percent, making the ionomer a high modulus ionomer, in 10
to 12 weight percent, making the ionomer a low modulus ionomer or
in 13 to 15 weight percent, making the ionomer a standard ionomer.
Generally, high acid ionomers provide a harder, more resilient
ionomer. Covers made using high acid ionomers usually provide a
high initial velocity and a low spin rate. on the other hand,
covers made with a low modulus ionomer are generally softer and
provide greater spin and control.
[0062] Preferably, the inner cover and intermediate cover layers
include polymers, such as ethylene, propylene, butene-1 or hexane-1
based homopolymers or copolymers including functional monomers,
such as acrylic and methacrylic acid and fully or partially
neutralized ionomer resins and their blends, methyl acrylate,
methyl methacrylate homopolymers and copolymers, imidized, amino
group containing polymers, polycarbonate, reinforced polyamides,
polyphenylene oxide, high impact polystyrene, polyether ketone,
polysulfone, poly(phenylene sulfide), acrylonitrile-butadiene,
acrylic-styrene-acrylonitrile, poly(ethylene terephthalate),
poly(butylene terephthalate), poly(ethelyne vinyl alcohol),
poly(tetrafluoroethylene) and their copolymers including functional
comonomers, and blends thereof.
[0063] Suitable inner and intermediate cover layer compositions
also include a polyether or polyester thermoplastic urethane, a
thermoset polyurethane, a low modulus ionomer, such as
acid-containing ethylene copolymer ionomers, including E/X/Y
terpolymers where E is ethylene, X is an acrylate or
methacrylate-based softening comonomer present in about 0 to 50
weight percent and Y is acrylic or methacrylic acid present in
about 5 to 35 weight percent. More preferably, in a low spin rate
embodiment designed for maximum distance, the acrylic or
methacrylic acid is present in about 16 to 35 weight percent,
making the ionomer a high modulus ionomer. In a higher spin
embodiment, the inner cover layer includes an ionomer where an acid
is present in about 10 to 15 weight percent and includes a
softening comonomer.
[0064] Any cover layer, but preferably the outer cover layer, may
include a polyurethane composition comprising the reaction product
of at least one polyisocyanate, polyol, and at least one curing
agent. Any polyisocyanate available to one of ordinary skill in the
art is suitable for use according to the invention. Exemplary
polyisocyanates include, but are not limited to,
4,4'-diphenylmethane diisocyanate ("MDI"); polymeric MDI;
carbodiimide-modified liquid MDI; 4,4'-dicyclohexylmethane
diisocyanate ("H.sub.12MDI"); p-phenylene diisocyanate ("PPDI");
toluene diisocyanate ("TDI"); 3,3'-dimethyl-4,4'-biphenylene
diisocyanate ("TODI"); isophoronediisocyanate ("IPDI");
hexamethylene diisocyanate ("HDI"); naphthalene diisocyanate
("NDI"); xylene diisocyanate ("XDI"); p-tetramethylxylene
diisocyanate ("p-TMXDI"); m-tetramethylxylene diisocyanate
("m-TMXDI"); ethylene diisocyanate; propylene-1,2-diisocyana- te;
tetramethylene-1,4-diisocyanate; cyclohexyl diisocyanate;
1,6-hexamethylene-diisocyanate ("HDI"); dodecane-1,12-diisocyanate;
cyclobutane-1,3-diisocyanate; cyclohexane-1,3-diisocyanate;
cyclohexane-1,4- diisocyanate; 1-isocyanato-3,3,5-
trimethyl-5-isocyanatomethylcyclohexane; methyl cyclohexylene
diisocyanate; triisocyanate of HDI; triisocyanate of
2,4,4-trimethyl-1,6-hexane diisocyanate ("TMDI"); tetracene
diisocyanate; napthalene diisocyanate; anthracene diisocyanate; and
mixtures thereof.
[0065] Preferably, the polyisocyanate includes MDI, PPDI, TDI, or a
mixture thereof, and more preferably, the polyisocyanate includes
MDI. It should be understood that, as used herein, the term "MDI"
includes 4,4'-diphenylmethane diisocyanate, polymeric MDI,
carbodiimide-modified liquid MDI, and mixtures thereof and,
additionally, that the diisocyanate employed may be "low free
monomer," understood by one of ordinary skill in the art to have
lower levels of "free" monomer isocyanate groups, typically less
than about 0. 1% free monomer groups. Examples of "low free
monomer" diisocyanates include, but are not limited to Low Free
Monomer MDI, Low Free Monomer TDI, and Low Free Monomer PPDI.
[0066] The at least one polyisocyanate should have less than about
14% unreacted NCO groups. Preferably, the at least one
polyisocyanate has no greater than about 7.5% NCO, and more
preferably, less than about 7.0%.
[0067] Any polyol available to one of ordinary skill in the art is
suitable for use according to the invention. Exemplary polyols
include, but are not limited to, polyether polyols,
hydroxy-terminated polybutadiene (including partially/fully
hydrogenated derivatives), polyester polyols, polycaprolactone
polyols, and polycarbonate polyols. In one preferred embodiment,
the polyol includes polyether polyol. Examples include, but are not
limited to, polytetramethylene ether glycol ("PTMEG"), polyethylene
propylene glycol, polyoxypropylene glycol, and mixtures thereof.
The hydrocarbon chain can have saturated or unsaturated bonds and
substituted or unsubstituted aromatic and cyclic groups.
Preferably, the polyol of the present invention includes PTMEG.
[0068] In another embodiment, polyester polyols are included in the
polyurethane material of the invention. Suitable polyester polyols
include, but are not limited to, polyethylene adipate glycol,
polybutylene adipate glycol, polyethylene propylene adipate glycol,
o-phthalate-1,6-hexanediol, and mixtures thereof. The hydrocarbon
chain can have saturated or unsaturated bonds, or substituted or
unsubstituted aromatic and cyclic groups.
[0069] In another embodiment, polycaprolactone polyols are included
in the materials of the invention. Suitable polycaprolactone
polyols include, but are not limited to, 1,6-hexanediol-initiated
polycaprolactone, diethylene glycol initiated polycaprolactone,
trimethylol propane initiated polycaprolactone, neopentyl glycol
initiated polycaprolactone, 1,4-butanediol-initiated
polycaprolactone, and mixtures thereof. The hydrocarbon chain can
have saturated or unsaturated bonds, or substituted or
unsubstituted aromatic and cyclic groups.
[0070] In yet another embodiment, the polycarbonate polyols are
included in the polyurethane material of the invention. Suitable
polycarbonates include, but are not limited to, polyphthalate
carbonate. The hydrocarbon chain can have saturated or unsaturated
bonds, or substituted or unsubstituted aromatic and cyclic groups.
In one embodiment, the molecular weight of the polyol is from about
200 to about 4000.
[0071] Polyamine curatives are also suitable for use in the
polyurethane composition of the invention and have been found to
improve cut, shear, and impact resistance of the resultant balls.
Preferred polyamine curatives include, but are not limited to,
3,5-dimethylthio-2,4-toluenedi- amine and isomers thereof;
3,5-diethyltoluene-2,4-diamine and isomers thereof, such as
3,5-diethyltoluene-2,6-diamine; 4,4'-bis-(sec-butylamino-
)-diphenylmethane; 1 ,4-bis-(sec-butylamino)-benzene,
4,4'-methylene-bis-(2-chloroaniline);
4,4'-methylene-bis-(3-chloro-2,6-di- ethylaniline);
polytetramethyleneoxide-di-p-aminobenzoate; N,N'-dialkyldiamino
diphenyl methane; p,p'-methylene dianiline ("MDA");
m-phenylenediamine ("MPDA"); 4,4'-methylene-bis(2-chloroaniline)
("MOCA"); 4,4'-methylene-bis-(2,6-diethylaniline);
4,4'-diamino-3,3'-diethyl-5,5'-dimethyl diphenylmethane; 2,2',
3,3'-tetrachloro diamino diphenylmethane;
4,4'-methylene-bis-(3-chloro-2,- 6-diethylaniline); trimethylene
glycol di-p-aminobenzoate; and mixtures thereof. Preferably, the
curing agent of the present invention includes
3,5-dimethylthio-2,4-toluenediamine and isomers thereof, such as
ETHACURE 300, commercially available from Albermarle Corporation of
Baton Rouge, LA. Suitable polyamine curatives, which include both
primary and secondary amines, preferably have molecular weights
ranging from about 64 to about 2000.
[0072] At least one of a diol, triol, tetraol, or
hydroxy-terminated curatives may be added to the aforementioned
polyurethane composition. Suitable diol, triol, and tetraol groups
include ethylene glycol; diethylene glycol; polyethylene glycol;
propylene glycol; polypropylene glycol; lower molecular weight
polytetramethylene ether glycol; 1,3-bis(2-hydroxyethoxy) benzene;
1,3-bis-[2-(2-hydroxyethoxy) ethoxy] benzene;
1,3-bis-{2-[2-(2-hydroxyethoxy) ethoxy] ethoxy} benzene;
1,4-butanediol; 1,5-pentanediol; 1,6-hexanediol;
resorcinol-di-(.beta.-hy- droxyethyl) ether;
hydroquinone-di-(.beta.-hydroxyethyl) ether; and mixtures thereof.
Preferred hydroxy-terminated curatives include ethylene glycol;
diethylene glycol; 1,4-butanediol; 1,5-pentanediol; 1,6-hexanediol,
trimethylol propane, and mixtures thereof. Preferably, the
hydroxy-terminated curatives have molecular weights ranging from
about 48 to 2000. It should be understood that molecular weight, as
used herein, is the absolute weight average molecular weight and
would be understood as such by one of ordinary skill in the
art.
[0073] Both the hydroxy-terminated and amine curatives can include
one or more saturated, unsaturated, aromatic, and cyclic groups.
Additionally, the hydroxy-terminated and amine curatives can
include one or more halogen groups. The polyurethane composition
can be formed with a blend or mixture of curing agents. If desired,
however, the polyurethane composition may be formed with a single
curing agent.
[0074] It should also be understood that slow-reacting amine
curatives, such as VERSALINK.RTM. P-250, VERSALINK.RTM. P-650, and
POLAMINE.RTM., and fast-reacting curatives, such as ETHACURE.RTM.
100 and ETHACURE.RTM. 300, may be used individually or as mixtures.
Further, blending of these curatives, and/or varying the mixing
temperature and speed, for example, can adjust the cure rate as
desired. Light stable polyurethanes, such as those disclosed in
U.S. application Ser. No. 09/812,910, filed Mar. 20, 2001, are also
suitable for the layers of the present invention and are
incorporated herein by express reference thereto.
[0075] Any method known to one of ordinary skill in the art may be
used to combine the polyisocyanate, polyol, and curing agent of the
present invention. One commonly employed method, known in the art
as a one-shot method, involves concurrent mixing of the
polyisocyanate, polyol, and curing agent. This method results in a
mixture that is inhomogenous (more random) and affords the
manufacturer less control over the molecular structure of the
resultant composition. A preferred method of mixing is known as a
prepolymer method. In this method, the polyisocyanate and the
polyol are mixed separately prior to addition of the curing agent.
This method affords a more homogeneous mixture resulting in a more
consistent polymer composition.
[0076] An optional filler component may be chosen to impart
additional density to blends of the previously described
components. The selection of such filler(s) is dependent upon the
type of golf ball desired (i.e., one-piece, two-piece
multi-component, or wound). Examples of useful fillers include zinc
oxide, barium sulfate, calcium oxide, calcium carbonate and silica,
as well as the other well known corresponding salts and oxides
thereof. Additives, such as nanoparticles, glass spheres, and
various metals, such as titanium and tungsten, can be added to the
polyurethane compositions of the present invention, in amounts as
needed, for their well-known purposes. Additional components which
can be added to the polyurethane composition include UV stabilizers
and other dyes, as well as optical brighteners and fluorescent
pigments and dyes. Such additional ingredients may be added in any
amounts that will achieve their desired purpose.
[0077] Due to the very thin nature of the cover layers of the
present invention, it has been determined that the use of a
castable, reactive material, which is applied in a fluid form,
makes it possible to obtain very thin outer cover layers on golf
balls. Specifically, it has been determined that castable, reactive
liquids, which react to form a urethane elastomer material, provide
desirable very thin outer cover layers.
[0078] The castable, reactive liquid employed to form the urethane
elastomer material can be applied over the core using a variety of
application techniques such as spraying, dipping, spin coating, or
flow coating methods which are well known in the art. An example of
a suitable coating technique is that which is disclosed in U.S.
Pat. No. 5,733,428, the disclosure of which is hereby incorporated
by reference in its entirety.
[0079] The outer cover is preferably formed around the core and
intermediate cover layers by mixing and introducing the material in
the mold halves. It is important that the viscosity be measured
over time, so that the subsequent steps of filling each mold half,
introducing the core into one half and closing the mold can be
properly timed for accomplishing centering of the core cover halves
fusion and achieving overall uniformity. Suitable viscosity range
of the curing urethane mix for introducing cores into the mold
halves is determined to be approximately between about 2,000 cP and
about 30,000 cP, with the preferred range of about 8,000 cP to
about 15,000 cP.
[0080] To start the outer cover formation, mixing of the prepolymer
and curative is accomplished in a motorized mixer including mixing
head by feeding through lines metered amounts of curative and
prepolymer. Top preheated mold halves are filled and placed in
fixture units using pins moving into holes in each mold. After the
reacting materials have resided in top mold halves for about 40 to
about 80 seconds, a core is lowered at a controlled speed into the
gelling reacting mixture. At a later time, a bottom mold half or a
series of bottom mold halves have similar mixture amounts
introduced into the cavity.
[0081] A ball cup holds the ball core through reduced pressure (or
partial vacuum). Upon location of the coated core in the halves of
the mold after gelling for about 40 to about 80 seconds, the vacuum
is released allowing core to be released. The mold halves, with
core and solidified cover half thereon, are removed from the
centering fixture unit, inverted and mated with other mold halves
which, at an appropriate time earlier, have had a selected quantity
of reacting polyurethane prepolymer and curing agent introduced
therein to commence gelling.
[0082] Similarly, U.S. Pat. Nos. 5,006,297 and 5,334,673 disclose
suitable molding techniques which may be utilized to apply the
castable reactive liquids employed in the present invention.
Further, U.S. Pat. Nos. 6,180,040 and 6,180,722 disclose methods of
preparing dual core golf balls. The disclosures of these patents
are hereby incorporated by reference in their entirety.
[0083] While either of the inner cover layer and the intermediate
cover layer may comprise a polyurethane, as disclosed above, it is
preferred that only one of the two layers comprise polyurethane.
For example, if the inner cover layer comprises a thermoset
polyurethane, the intermediate layer cannot comprise polyurethane,
and vice versa. The outer cover layer, of course, preferably
comprises polyurethane.
[0084] Depending on the desired properties, balls prepared
according to the invention can exhibit substantially the same or
higher resilience, or coefficient of restitution ("COR"), with a
decrease in compression or modulus, compared to balls of
conventional construction. Additionally, balls prepared according
to the invention can also exhibit substantially higher resilience,
or COR, without an increase in compression, compared to balls of
conventional construction.
[0085] The resultant golf balls typically have a coefficient of
restitution of greater than about 0.7, preferably greater than
about 0.75, and more preferably greater than about 0.78. The golf
balls also typically have an ATTI compression of at least about 40,
preferably from about 50 to 120, and more preferably from about 60
to 100. As used herein, the term "ATTI compression" is defined as
the deflection of an object or material relative to the deflection
of a calibrated spring, as measured with an ATTI Compression Gauge,
that is commercially available from Atti Engineering Corp. of Union
City, N.J. ATTI compression is typically used to measure the
compression of a golf ball. When the ATTI Gauge is used to measure
cores having a diameter of less than 1.680 inches, it should be
understood that a metallic or other suitable shim is used to make
the diameter of the measured object 1.680 inches.
[0086] When golf balls are prepared according to the invention,
they typically will have dimple coverage greater than about 60
percent, preferably greater than about 65 percent, and more
preferably greater than about 75 percent. The flexural modulus of
the cover on the golf balls, as measured by ASTM method D6272-98,
Procedure B, is typically greater than about 500 psi, and is
preferably from about 500 psi to 150,000 psi.
[0087] The outer cover can have any material hardness sufficient to
provide predetermined ball performance characteristics. In a low
spin embodiment, the material of the outer cover layer should have
a material hardness greater than about 55 Shore D, preferably
greater than about 60 Shore D, more preferably between about 60 and
about 80 Shore D, and most preferably between about 70 and about 80
Shore D. In a high spin embodiment, the material of the outer cover
layer should have a material hardness less than about 65 Shore D,
preferably less than about 50 Shore D, more preferably between
about 10 and about 40 Shore D, and most preferably between about 30
and about 40 Shore D.
[0088] More importantly, however, is the relationship between the
inner cover layer, the intermediate cover layer, and the outer
cover layer. The inner and intermediate cover layers can have any
material hardness sufficient to produce a predetermined set of golf
ball playing characteristics. The outer cover layer has a first
material hardness, the intermediate cover layer has a second
material hardness, and the inner cover layer has a third material
hardness. There are a number of different embodiments that will
produce a low- or high-spin golf ball when that particular outer
cover layer has been selected.
[0089] In a first embodiment, the third hardness is greater than
the first hardness, which is greater than the second hardness i.e.,
the inner cover layer is the hardest layer, the intermediate layer
is the softest, and the outer cover layer is the between the two.
The inner cover layer hardness is preferably greater than about 60
Shore D and more preferably, greater than about 70 Shore D; the
intermediate layer is preferably less than about 55 Shore D; and
the outer cover layer is preferably greater than about 55 Shore
D.
[0090] In a second embodiment, the second hardness is greater than
the first hardness, which is greater than the third hardness, i.e.,
the intermediate cover layer is the hardest layer, the inner cover
layer is the softest layer, and the outer cover layer is between
the two. The intermediate cover layer hardness is preferably
greater than about 60 Shore D, the inner cover layer hardness is
preferably less than about 55 Shore D, and the outer cover layer is
preferably between about 50 and about 65 Shore D.
[0091] In a third embodiment, the first and second hardness are
identical and greater than the third hardness, i.e., the inner
cover is softer than either the intermediate or cover layers.
Preferably, the outer and intermediate cover layers have an
identical hardness greater than about 60 Shore D and the inner
cover layer hardness is less than about 55 Shore D.
[0092] In a fourth embodiment, the first and second hardness are
identical and less than the third hardness, i.e., the inner cover
layer is the hardest layer and the outer cover and intermediate
cover layers are softer and identical in hardness. Preferably, the
inner cover layer has a hardness greater than about 55 Shore D and
the intermediate and outer cover layers have identical hardness
less than about 60 Shore D.
[0093] In a fifth embodiment, the second and third hardness are
identical and greater than the first hardness, i.e., the
intermediate and inner cover layers are identical and harder than
the outer cover layer. Preferably, the outer cover layer has a
material hardness of less than about 55 Shore D and the
intermediate and inner cover layers have identical hardness values
greater than about 60 Shore D.
[0094] In a sixth embodiment, the second and third hardness are
identical and less than the first, i.e., the intermediate and inner
cover layers are identical and softer than the outer cover layer.
Preferably, the intermediate and inner cover layers have an
identical hardness less than about 55 Shore D and the outer cover
layer has a hardness greater than about 55 Shore D.
[0095] It should be understood, especially to one of ordinary skill
in the art, that there is a fundamental difference between
"material hardness" and "hardness, as measured directly on a golf
ball." Material hardness is defined by the procedure set forth in
ASTM-D2240 and generally involves measuring the hardness of a flat
"slab" or "button" formed of the material of which the hardness is
to be measured. Hardness, when measured directly on a golf ball (or
other spherical surface) is a completely different measurement and,
therefore, results in a different hardness value. This difference
results from a number of factors including, but not limited to,
ball construction (i.e., core type, number of core and/or cover
layers, etc.), ball (or sphere) diameter, and the material
composition of adjacent layers. It should also be understood that
the two measurement techniques are not linearly related and,
therefore, one hardness value cannot easily be correlated to the
other. As used herein, the term "hardness" refers to material
hardness, as defined above.
[0096] The core of the present invention has an ATTI compression of
between about 50 and about 90, more preferably, between about 60
and about 85, and most preferably, between about 70 and about
85.
[0097] The overall outer diameter ("OD") of the core is less than
about 1.590 inches, more preferably between about 1.540 inches and
about 1.570 inches, and most preferably between about 1.525 inches
to about 1.560 inches. The OD of the inner cover layer of the golf
balls of the present invention is preferably between about 1.580
inches and about 1.640 inches, more preferably between about 1.600
inches to about 1.630 inches, and most preferably between about
1.610 inches to about 1.30 inches.
[0098] The present multi-layer golf ball can have an overall
diameter of any size. Although the United States Golf Association
("USGA") specifications limit the minimum size of a competition
golf ball to 1.680 inches. There is no specification as to the
maximum diameter.
[0099] Golf balls of any size, however, can be used for
recreational play. The preferred diameter of the present golf balls
is from about 1.680 inches to about 1.800 inches. The more
preferred diameter is from about 1.680 inches to about 1.760
inches. The most preferred diameter is about 1.680 inches to about
1.740 inches.
[0100] The term "about," as used herein in connection with one or
more numbers or numerical ranges, should be understood to refer to
all such numbers, including all numbers in a range.
[0101] The invention described and claimed herein is not to be
limited in scope by the specific embodiments herein disclosed,
since these embodiments are intended as illustrations of several
aspects of the invention. Any equivalent embodiments are intended
to be within the scope of this invention. Indeed, various
modifications of the invention in addition to those shown and
described herein will become apparent to those skilled in the art
from the foregoing description. Such modifications are also
intended to fall within the scope of the appended claims.
* * * * *