U.S. patent application number 09/349806 was filed with the patent office on 2002-08-22 for methods for achieving improved color in microencapsulated electrophoretic devices.
Invention is credited to DRZAIC, PAUL, JACOBSON, JOSEPH M., MORRISON, IAN D., WILCOX, RUSSELL J..
Application Number | 20020113770 09/349806 |
Document ID | / |
Family ID | 22231169 |
Filed Date | 2002-08-22 |
United States Patent
Application |
20020113770 |
Kind Code |
A1 |
JACOBSON, JOSEPH M. ; et
al. |
August 22, 2002 |
METHODS FOR ACHIEVING IMPROVED COLOR IN MICROENCAPSULATED
ELECTROPHORETIC DEVICES
Abstract
A method for manufacturing a full color, reflective display
includes the steps of depositing a first plurality of
electrophoretic display elements in substantial registration with a
first electrode and a second plurality of electrophoretic display
elements in substantial registration with a second electrode. The
electrophoretic display elements include a capsule containing a
species of particles dispersed in a suspending fluid. The selective
deposition of the display elements can be achieved by ink-jet
printing methods, screen printing methods or other printing
methods. In some embodiments the electrodes are printed onto the
substrate before selective deposition of the display elements,
while in other embodiments the substrate is provided having the
electrodes already disposed on it. In still other embodiments, the
sequence of printing of electrodes and electrophoretic display
elements can be varied.
Inventors: |
JACOBSON, JOSEPH M.; (NEWTON
CENTRE, MA) ; MORRISON, IAN D.; (ACTON, MA) ;
WILCOX, RUSSELL J.; (NATICK, MA) ; DRZAIC, PAUL;
(LEXINGTON, MA) |
Correspondence
Address: |
TESTA, HURWITZ & THIBEAULT, LLP
HIGH STREET TOWER
125 HIGH STREET
BOSTON
MA
02110
US
|
Family ID: |
22231169 |
Appl. No.: |
09/349806 |
Filed: |
July 8, 1999 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
60092050 |
Jul 8, 1998 |
|
|
|
Current U.S.
Class: |
345/107 ; 427/58;
427/74; 427/77 |
Current CPC
Class: |
G02F 2202/28 20130101;
G09F 9/372 20130101; H01L 51/0077 20130101; G02F 1/16757 20190101;
G02B 26/026 20130101; G02F 1/1334 20130101; G09F 9/302 20130101;
H01L 27/28 20130101; B41J 2/2117 20130101; H01L 51/005 20130101;
B41J 3/4076 20130101; B41J 3/4073 20130101; G02F 1/167 20130101;
H01L 51/0512 20130101; G02F 1/133305 20130101; B05D 5/06
20130101 |
Class at
Publication: |
345/107 ; 427/58;
427/74; 427/77 |
International
Class: |
B05D 005/12; G09G
003/34 |
Claims
What is claimed is:
1. A method of manufacturing a color electrophoretic display
comprising the steps of: (a) providing a substrate having at least
two electrodes disposed thereon; (b) selectively depositing a first
plurality of electrophoretic display elements in substantial
registration with a first electrode, each of said first plurality
of display elements comprising a capsule containing a plurality of
a first species of particles, said first species of particles
responsive to a first applied electric field and having a first
optical property; and (c) selectively depositing a second plurality
of electrophoretic display elements in substantial registration
with a second electrode, each of said second plurality of display
elements comprising a capsule containing a plurality of a second
species of particles, said second species of particles responsive
to a second applied electric field and having a second optical
property.
2. The method of claim 1, wherein step (a) comprises the step of:
providing a substrate having at least two electrodes disposed
thereon, at least one of said at least two electrodes having a
pre-determined pattern.
3. The method of claim 1, wherein step (a) comprises the steps of:
(a-a) providing a substrate; and (a-b) depositing at least two
electrodes on said substrate.
4. The method of claim 3,wherein step (a-b) comprises depositing at
least two electrodes on said substrate, at least one of said at
least two electrodes having a predetermined pattern.
5. The method of claim 1, wherein step (b) comprises selectively
depositing by ink-jet printing a first plurality of electrophoretic
display elements in substantial registration with the at least one
electrode, each of said first plurality of display elements
comprising a capsule containing a plurality of a first species of
particles, said first species of particles responsive to a first
applied electric field and having a first optical property.
6. The method of claim 1, wherein step (b) comprises selectively
depositing by screen printing a first plurality of electrophoretic
display elements in substantial registration with the at least one
electrode, each of said first plurality of display elements
comprising a capsule containing a plurality of a first species of
particles, said first species of particles responsive to a first
applied electric field and having a first optical property.
7. The method of claim 1, wherein step (b) comprises selectively
depositing by gravure printing a first plurality of electrophoretic
display elements in substantial registration with the at least one
electrode, each of said first plurality of display elements
comprising a capsule containing a plurality of a first species of
particles, said first species of particles responsive to a first
applied electric field and having a first optical property.
8. The method of claim 1, wherein step (b) comprises: (b-a)
providing a carrier bearing a first plurality of electrophoretic
display elements, each of said first plurality of display elements
comprising a capsule containing a plurality of a first species of
particles, said first species of particles responsive to a first
applied electric field and having a first optical property; (b-b)
disposing said carrier adjacent said substrate; and (b-c) applying
an electrical signal to said at least one electrode to transfer at
least some of said first plurality of electrophoretic display
elements from said carrier to said substrate in substantial
registration with said at least one electrode.
9. The method of claim 8, wherein step (b-a) comprises providing a
carrier bearing a first plurality of electrophoretic display
elements, each of said first plurality of display elements
comprising a capsule containing a plurality of a first species of
particles and a dyed fluid, said first species of particles
responsive to a first applied electric field and having a first
optical property.
10. The method of claim 8, wherein said first plurality of
electrophoretic display elements is held upon said carrier by an
applied electric field.
11. The method of claim 8, wherein said first plurality of
electrophoretic display elements is held upon said carrier by
electrostatic forces.
12. The method of claim 8, wherein said first plurality of
electrophoretic display elements is held upon said carrier by
chemical bonding forces.
13. The method of claim 8, wherein said first plurality of
electrophoretic display elements is held upon said carrier by
surface tension.
14. The method of claim 8, wherein step (b-a) comprises providing a
carrier having a substantially flat surface, and bearing a first
plurality of electrophoretic display elements, each of said first
plurality of display elements comprising a capsule containing a
plurality of a first species of particles, said first species of
particles responsive to a first applied electric field and having a
first optical property.
15. The method of claim 8, wherein step (b-a) comprises providing a
carrier having a substantially cylindrical surface, and bearing a
first plurality of display electrophoretic elements, each of said
first plurality of display elements comprising a capsule containing
a plurality of a first species of particles, said first species of
particles responsive to a first applied electric field and having a
first optical property.
16. The method of claim 4, wherein step (b-a) comprises providing a
carrier that is a fluid, bearing a first plurality of
electrophoretic display elements, each of said first plurality of
display elements comprising a capsule containing a plurality of a
first species of particles, said first species of particles
responsive to a first applied electric field and having a first
optical property.
17. An electrophoretic display manufactured according to the
process of claim 1.
18. A method of manufacturing an electrophoretic display comprising
the steps of: (a) providing a substrate; (b) selectively depositing
in a pre-determined pattern upon said substrate a first plurality
of electrophoretic display elements, each of said first plurality
of display elements comprising a capsule containing a plurality of
a first species of particles, said first species of particles
responsive to a first applied electric field and having a first
optical property; (c) selectively depositing at least one electrode
upon said first plurality of electrophoretic display elements; (d)
selectively depositing in a pre-determined pattern upon said
substrate a second plurality of electrophoretic display elements,
each of said second plurality of display elements comprising a
capsule containing a plurality of a second species of particles,
said second species of particles responsive to a second applied
electric field and having a second optical property; and (e)
selectively depositing at least one electrode upon said second
plurality of electrophoretic display elements.
19. The method of claim 18, wherein step (b) comprises selectively
depositing in a pre-determined pattern upon said substrate a first
plurality of electrophoretic display elements, each of said first
plurality of display elements comprising a capsule containing a
plurality of a first species of particles and a dyed fluid, said
first species of particles responsive to a first applied electric
field and having a first optical property.
20. The method of claim 18, wherein step (c) comprises selectively
depositing at least one electrode upon, and in substantial
registration with, said first plurality of electrophoretic display
elements.
21. A method of manufacturing an electrophoretic display comprising
the steps of: (a) providing a substrate; (b) selectively depositing
upon said substrate at least two electrodes; (c) selectively
depositing a first plurality of electrophoretic display elements in
substantial registration with a first electrode, each of said first
plurality of display elements comprising a capsule containing a
plurality of a first species of particles, said first species of
particles responsive to a first applied electric field and having a
first optical property; and (d) selectively depositing a second
plurality of electrophoretic display elements in substantial
registration with a second electrode, each of said second plurality
of display elements comprising a capsule containing a plurality of
a second species of particles, said second species of particles
responsive to a second applied electric field and having a second
optical property.
22. The method of claim 21, wherein step (b) comprises selectively
depositing in a pre-determined pattern upon id substrate at least
two electrodes.
23. The method of claim 22, wherein step (c) comprises selectively
depositing upon, and in substantial registration with, a first
electrode a first plurality of electrophoretic display elements,
each of said first plurality of display elements comprising a
capsule containing a plurality of a first species of particles,
said first species of particles responsive to a first applied
electric field and having a first optical property.
24. A method of manufacturing an electrophoretic display comprising
the steps of: (a) providing a first substrate; (b) selectively
depositing in a pre-determined pattern upon said first substrate a
first plurality of electrophoretic display elements, each of said
first plurality of display elements comprising a capsule containing
a plurality of a first species of particles, said first species of
particles responsive to a first applied electric field and having a
first optical property; (c) providing a second substrate; (d)
depositing at least one electrode upon said second substrate; and
(e) disposing said first substrate adjacent said second substrate
with said first plurality of electrophoretic display elements
adjacent said at least one electrode.
25. The method of claim 24, wherein step (d) comprises depositing
at least one electrode upon said second substrate in a pattern
substantially calculated to match said pre-determined pattern.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority to U.S. Ser. No. 60/092,050
filed Jul. 8, 1998, the contents of which is incorporated herein by
reference.
FIELD OF THE INVENTION
[0002] The present invention relates to electronic displays and, in
particular, to full color electrophoretic displays and methods of
manufacturing full-color microencapsulated electrophoretic
displays.
BACKGROUND OF THE INVENTION
[0003] Electrophoretic display media are generally characterized by
the movement of particles through an applied electric field. These
displays are highly reflective, can be made bistable, can be scaled
to large areas, and consume very little power. These properties
allow encapsulated electrophoretic display media to be used in many
applications for which traditional electronic displays are not
suitable. While bichromatic electrophoretic displays have been
demonstrated in a limited range of colors (e.g. black/white or
yellow/red), to date there has not been successful
commercialization of a full-color electrophoretic display. One
reason for this failure of commercialization is the lack of a
method of manufacture that is efficient and inexpensive.
[0004] One traditional technique for achieving a bright, full-color
display which is known in the art of emissive displays is to create
display elements that are red, green and blue. In this system, each
element has two states: on, or the emission of color; and off.
Since light blends from these elements, the overall display can
take on a variety of colors and color combinations. In an emissive
display, the visual result is the summation of the wavelengths
emitted by the display elements at selected intensities, white is
seen when red, green and blue are all active in balanced
proportion. The brightness of the white image is controlled by the
intensities of emission of light by the individual display
elements. Black is seen when none are active or, equivalently, when
all are emitting at zero intensity. As an additional example, a red
visual display appears when the red display element is active while
the green and blue are inactive, and thus only red light is
emitted.
[0005] This method can be applied to bichromatic reflective
displays, typically using the cyan-magenta-yellow subtractive color
system. In this system, the reflective display elements absorb
characteristic portions of the optical spectrum, rather than
generating characteristic portions of the spectrum as do the
elements in an emissive display. White reflects everything, or
equivalently absorbs nothing. A colored reflective material
reflects light corresponding in wavelength to the color seen, and
absorbs the remainder of the wavelengths in the visible spectrum.
To achieve a black display, all three display elements are turned
on, and they absorb complementary portions of the spectrum.
[0006] However, such techniques require that the colored display
elements be deposited onto a substrate in substantially equal
proportions aligned with the proper addressing electrodes. Failure
to achieve either substantially equal proportions of colored
display elements or failure to achieve registration of the display
elements with the addressing electrodes results in a color display
that is unsatisfactory.
SUMMARY OF THE INVENTION
[0007] This invention teaches practical ways to efficiently and
cheaply manufacture full-color, encapsulated electrophoretic
displays. In one embodiment the display media can be printed and,
therefore the display itself can be made inexpensively.
[0008] An encapsulated electrophoretic display can be constructed
so that the optical state of the display is stable for some length
of time. When the display has two states which are stable in this
manner, the display is said to be bistable. If more than two states
of the display are stable, then the display can be said to be
multistable. For the purpose of this invention, the terms bistable
and multistable, or generally, stable, will be used to indicate a
display in which any optical state remains fixed once the
addressing voltage is removed. The definition of a stable state
depends on the application for the display. A slowly-decaying
optical state can be effectively stable if the optical state is
substantially unchanged over the required viewing time. For
example, in a display which is updated every few minutes, a display
image which is stable for hours or days is effectively bistable or
multistable, as the case may be, for that application. In this
invention, the terms bistable and multistable also indicate a
display with an optical state sufficiently long-lived as to be
effectively stable for the application in mind. Alternatively, it
is possible to construct encapsulated electrophoretic displays in
which the image decays quickly once the addressing voltage to the
display is removed (i.e., the display is not bistable or
multistable). As will be described, in some applications it is
advantageous to use an encapsulated electrophoretic display which
is not bistable or multistable. Whether or not an encapsulated
electrophoretic display is stable, and its degree of stability, can
be controlled through appropriate chemical modification of the
electrophoretic particles, the suspending fluid, the capsule,
binder materials, or addressing methods.
[0009] An encapsulated electrophoretic display may take many forms.
The display may comprise capsules dispersed in a binder. The
capsules may be of any size or shape. The capsules may, for
example, be spherical and may have diameters in the millimeter
range or the micron range, but is preferably from ten to a few
hundred microns. The capsules may be formed by an encapsulation
technique, as described below. Particles may be encapsulated in the
capsules. The particles may be two or more different types of
particles. The particles may be colored, luminescent,
light-absorbing or transparent, for example. The particles may
include neat pigments, dyed (laked) pigments or pigment/polymer
composites, for example. The display may further comprise a
suspending fluid in which the particles are dispersed.
[0010] The successful construction of an encapsulated
electrophoretic display requires the proper interaction of several
different types of materials and processes, such as a polymeric
binder and, optionally, a capsule membrane. These materials must be
chemically compatible with the electrophoretic particles and fluid,
as well as with each other. The capsule materials may engage in
useful surface interactions with the electrophoretic particles, or
may act as a chemical or physical boundary between the fluid and
the binder. Various materials and combinations of materials useful
in constructing encapsulated electrophoretic displays are described
in co-pending application Ser. No. 09/140,861, the contents of
which are incorporated by reference herein.
[0011] In some cases, the encapsulation step of the process is not
necessary, and the electrophoretic fluid may be directly dispersed
or emulsified into the binder (or a precursor to the binder
materials) and an effective "polymer-dispersed electrophoretic
display" constructed. In such displays, voids created in the binder
may be referred to as capsules or microcapsules even though no
capsule membrane is present. The binder dispersed electrophoretic
display may be of the emulsion or phase separation type.
[0012] Throughout the Specification, reference will be made to
printing or printed. As used throughout the specification, printing
is intended to include all forms of printing and coating,
including: premetered coatings such as patch die coating, slot or
extrusion coating, slide or cascade coating, and curtain coating;
roll coating such as knife over roll coating, forward and reverse
roll coating; gravure coating; dip coating; spray coating; meniscus
coating; spin coating; brush coating; air knife coating; silk
screen printing processes; electrostatic printing processes;
thermal printing processes; lithographic printing processes;
ink-jet printing processes and other similar techniques. A "printed
element" refers to an element formed using any one of the above
techniques.
[0013] As noted above, electrophoretic display elements can be
encapsulated. Throughout the Specification, reference will be made
to "capsules," "elements," and "display elements." A capsule or
display element may itself comprise one or more capsules or other
structures.
[0014] In one aspect the present invention relates to a method for
manufacturing a color electrophoretic display. A substrate is
provided having at least two electrodes. A first plurality of
electrophoretic display elements are disposed on the substrate in
substantial registration with one of the electrodes. The first
plurality of electrophoretic display elements includes capsules
containing a first species of particles suspended in a dispersing
fluid and having a first optical property. A second plurality of
electrophoretic display elements is disposed on the substrate in
substantial registration with the other electrode. The second
plurality of electrophoretic display elements includes capsules
containing a second species of particles suspended in a dispersing
fluid and having a second optical property.
[0015] In another aspect the present invention relates to a method
for manufacturing a color electrophoretic display. A substrate is
provided. A first plurality of electrophoretic display elements are
disposed on the substrate. The first plurality of electrophoretic
display elements includes capsules containing a first species of
particles suspended in a dispersing fluid and having a first
optical property. At least one electrode is deposited on the first
plurality of electrophoretic display elements.
[0016] In still another aspect the present invention relates to a
method for manufacturing a color electrophoretic display. A
substrate is provided and at least two electrodes are deposited on
the substrate. A first plurality of electrophoretic display
elements are disposed on the substrate in substantial registration
with one of the electrodes. The first plurality of electrophoretic
display elements includes capsules containing a first species of
particles suspended in a dispersing fluid and having a first
optical property. A second plurality of electrophoretic display
elements is disposed on the substrate in substantial registration
with the other electrode. The second plurality of electrophoretic
display elements includes capsules containing a second species of
particles suspended in a dispersing fluid and having a second
optical property.
[0017] In yet another aspect the present invention relates to a
method for manufacturing a color electrophoretic display. A
substrate is provided and a first plurality of electrophoretic
display elements are disposed on the substrate. The first plurality
of electrophoretic display elements includes capsules containing a
first species of particles suspended in a dispersing fluid and
having a first optical property. A second substrate is provided and
at least one electrode is deposited on the second substrate. The
first and second substrate are disposed adjacent each other so that
the display elements are adjacent the electrode.
BRIEF DESCRIPTION OF THE DRAWINGS
[0018] The invention is pointed out with particularity in the
appended claims. The advantages of the invention described above,
together with further advantages, may be better understood by
referring to the following description taken in conjunction with
the accompanying drawings. In the drawings, like reference
characters generally refer to the same parts throughout the
different views. Also, the drawings are not necessarily to scale,
emphasis instead generally being placed upon illustrating the
principles of the invention.
[0019] FIG. 1A is a diagrammatic side view of an embodiment of a
rear-addressing electrode structure for a particle-based display in
which a smaller electrode has been placed at a voltage relative to
the large electrode causing the particles to migrate to the smaller
electrode.
[0020] FIG. 1B is a diagrammatic side view of an embodiment of a
rear-addressing electrode structure for a particle-based display in
which the larger electrode has been placed at a voltage relative to
the smaller electrode causing the particles to migrate to the
larger electrode.
[0021] FIG. 1C is a diagrammatic top-down view of one embodiment of
a rear-addressing electrode structure.
[0022] FIG. 1D is a diagrammatic side view of one embodiment of a
display having three display elements, each display element being
produced by a printing process.
[0023] FIG. 1E is a diagrammatic plan view of one embodiment of a
display having three display elements, each display element being
produced by a printing process.
[0024] FIG. 2 is a cross-sectional view of a rear electrode
addressing structure that is formed by printing.
[0025] FIG. 3A is a schematic flow diagram of selected steps in a
method of manufacturing a display that employs a process in which
electrodes are first printed on a substrate, followed by the
printing of display elements upon the electrodes.
[0026] FIG. 3B is a schematic flow diagram of selected steps in a
method of manufacturing a display that employs a process in which
display elements are first printed on a substrate, followed by the
printing of electrodes upon the display elements.
[0027] FIG. 3C is a schematic flow diagram of selected steps in a
method of manufacturing a display that employs a process in which
electrodes are printed on a first substrate, display elements are
printed on a second substrate, and the two structures are combined
to form a display.
[0028] FIG. 3D is a diagrammatic side view of an embodiment of an
addressing structure having transparent electrodes, in which an
alternating-current electric field has been applied to the capsule
causing the particles to disperse into the capsule.
[0029] FIG. 3E is a diagrammatic side view of an embodiment of an
addressing structure for a display element having three
sub-pixels.
[0030] FIG. 3F is a diagrammatic side view of an embodiment of a
dual particle curtain mode addressing structure addressing a
display element to appear white.
[0031] FIG. 3G is a diagrammatic side view of an embodiment of a
dual particle curtain mode addressing structure addressing a
display element to appear red.
[0032] FIG. 3H is a diagrammatic side view of an embodiment of a
dual particle curtain mode addressing structure addressing a
display element to absorb red light.
[0033] FIG. 3I is a diagrammatic side view of an embodiment of a
dual particle curtain mode addressing structure for a display
element having three sub-pixels, in which the display is addressed
to appear red.
[0034] FIG. 3J is a diagrammatic side view of another embodiment of
a dual particle curtain mode addressing structure for a display
element.
[0035] FIG. 3K is a diagrammatic plan view of an embodiment of an
interdigitated electrode structure.
[0036] FIG. 3L is a diagrammatic side view of another embodiment of
a dual particle curtain mode display structure having a dyed fluid
and two species of particles, addressed to absorb red.
[0037] FIG. 3M is a diagrammatic side view of another embodiment of
a dual particle curtain mode display structure having clear fluid
and three species of particles, addressed to absorb red.
[0038] FIG. 4A depicts an embodiment of a manufacturing process
that employs a drum for printing electrodes or display
elements.
[0039] FIG. 4B depicts an embodiment of a manufacturing process
that employs an inkjet for printing electrodes or display
elements.
[0040] FIG. 4C depicts an embodiment of a manufacturing process
that employs a flat platen for printing electrodes or display
elements.
[0041] FIG. 5 is a flowchart showing the steps to be taken to
fabricate a display using a method of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
[0042] Electronic ink is an optoelectronically active material that
comprises at least two phases: an electrophoretic contrast media
phase and a coating/binding phase. The electrophoretic phase
comprises, in some embodiments, a single species of electrophoretic
particles dispersed in a clear or dyed medium, or more than one
species of electrophoretic particles having distinct physical and
electrical characteristics dispersed in a clear or dyed medium. In
some embodiments the electrophoretic phase is encapsulated, that
is, there is a capsule wall phase between the two phases. The
coating/binding phase includes, in one embodiment, a polymer matrix
that surrounds the electrophoretic phase. In this embodiment, the
polymer in the polymeric binder is capable of being dried,
crosslinked, or otherwise cured as in traditional inks, and
therefore a printing process can be used to deposit the electronic
ink onto a substrate.
[0043] In one embodiment, the ink may comprise display elements
capable of displaying different colors. In one particular
embodiment, some display elements contain red particles, some
display elements contain green particles, and some display elements
contain blue particles, respectively. In another particular
embodiment, some display elements contain cyan particles, some
display elements contain magenta particles, and some display
elements contain yellow particles, respectively. By addressing each
display element to display some fraction of its colored particles,
a display can be caused to give an appearance corresponding to a
selected color at a selected brightness level.
[0044] Electronic ink is capable of being printed by several
different processes, depending on the mechanical properties of the
specific ink employed. For example, the fragility or viscosity of a
particular ink may result in a different process selection. A very
viscous ink would not be well-suited to deposition by an inkjet
printing process, while a fragile ink might not be used in a knife
over roll coating process.
[0045] The optical quality of an electronic ink is quite distinct
from other electronic display materials. The most notable
difference is that the electronic ink provides a high degree of
both reflectance and contrast because it is pigment based (as are
ordinary printing inks). The light scattered from the electronic
ink comes from a very thin layer of pigment close to the viewing
surface. In this respect it resembles an ordinary, printed image.
Also, electronic ink is easily viewed from a wide range of viewing
angles in the same manner as a printed page, and such ink
approximates a Lambertian contrast curve more closely than any
other electronic display material. Since electronic ink can be
printed, it can be included on the same surface with any other
printed material, including traditional inks. Electronic ink can be
made optically stable in all display configurations, that is, the
ink can be set to a persistent optical state. Fabrication of a
display by printing an electronic ink is particularly useful in low
power applications because of this stability.
[0046] Electronic ink displays are novel in that they can be
addressed by DC voltages and draw very little current. Therefore,
elements forming electronic inks may be made of non-traditional
materials and electronic inks may be manufactured by and used in
non-traditional methods. As such, the conductive leads and
electrodes used to deliver the voltage to electronic ink displays
can be of relatively high resistivity. The ability to use resistive
conductors substantially widens the number and type of materials
that can be used as conductors in electronic ink displays. In
particular, the use of costly vacuum-sputtered indium tin oxide
(ITO) conductors, a standard material in liquid crystal devices, is
not required. Aside from cost savings, the replacement of ITO with
other materials can provide benefits in appearance, processing
capabilities (printed conductors), flexibility, and durability.
Additionally, the printed electrodes are in contact only with a
solid binder, not with a fluid layer (like liquid crystals). This
means that some conductive materials, which would otherwise
dissolve or be degraded by contact with liquid crystals, can be
used in an electronic ink application. These include opaque
metallic inks for the rear electrode (e.g., silver and graphite
inks), as well as conductive transparent inks for either substrate.
These conductive coatings include semiconducting colloids, examples
of which are indium tin oxide and antimony-doped tin oxide. Organic
conductors (polymeric conductors and molecular organic conductors)
also may be used. Polymers include, but are not limited to,
polyaniline and derivatives, polythiophene and derivatives,
poly3,4-ethylenedioxythiophene (PEDOT) and derivatives, polypyrrole
and derivatives, and polyphenylenevinylene (PPV) and derivatives.
Organic molecular conductors include, but are not limited to,
derivatives of naphthalene, phthalocyanine, and pentacene. Polymer
layers can be made thinner and more transparent than with
traditional displays because conductivity requirements are not as
stringent.
[0047] As an example, there is a class of materials called
electroconductive powders which are also useful as coatable
transparent conductors in electronic ink displays. One example is
Zelec ECP electroconductive powders from DuPont Chemical Co. of
Wilmington, Del.
[0048] It is possible to produce a wide gamut of colors from the
superposition of suitable proportions of three properly chosen
colors. In one embodiment, the colors red, green, and blue can be
combined in various proportions to produce an image that is
perceived as a selected color. Emissive or transmissive displays
operate according to additive rules, where the perceived color is
created by summing the emission wavelengths of a plurality of
emitting or transmitting objects. For an emissive or transmissive
display that includes three display elements, one of which can
produce red light, one green light, and one blue light,
respectively, one can generate a wide gamut of colors, as well as
white and black. At one extreme, the combination of all three at
full intensity is perceived as white, and at the other, the
combination of all three at zero intensity is perceived as black.
Specific combinations of controlled proportions of these three
colors can be used to represent other colors.
[0049] In a reflective display, the light that a viewer perceives
is the portion of the spectrum that is not absorbed when the light
to be reflected falls on the reflector surface. One may thus
consider a reflecting system as a subtractive system, that is, that
each reflective surface "subtracts" from the light that portion
which the reflector absorbs. The color of a reflector represents
the wavelengths of light the reflector absorbs. A yellow reflector
absorbs substantially blue light. A magenta reflector absorbs
substantially green light. A cyan reflector absorbs substantially
red light. Thus, in an alternative embodiment employing reflectors,
nearly the same results as an emissive system can be obtained by
use of the three colors cyan, yellow, and magenta as the primary
colors, from which all other colors, including black but not white,
can be derived. To obtain white from such a display, one must
further introduce a third state per display element, namely
white.
[0050] While the methods described discuss particles, any
combination of dyes, liquids droplets and transparent regions that
respond to electrophoretic effects could also be used. Particles of
various optical effects may be combined in any suitable proportion.
For example, certain colors may be over- or under-populated in the
electrophoretic display, for example, by printing more display
elements of one color than of another color, to account for the
sensitivities of the human eye and to thereby achieve a more
pleasing or uniform effect. Similarly, the sizes of the display
elements may also be disproportionate to achieve various optical
effects.
[0051] Although these examples describe microencapsulated
electrophoretic displays, the invention can be utilized across
other reflective displays including liquid crystal,
polymer-dispersed liquid crystal, rotating ball, suspended particle
and any other reflective display capable of being printed. In
short, many schemes are possible by which display elements in a
direct color reflective display can be printed. Such printing
schemes will vary by the nature of the display and any suitable
means may be used.
[0052] Referring now to FIGS. 1A and 1B, an addressing scheme for
controlling particle-based displays is shown in which electrodes
are disposed on only one side of a display, allowing the display to
be rear-addressed. Utilizing only one side of the display for
electrodes simplifies fabrication of displays. For example, if the
electrodes are disposed on only the rear side of a display, both of
the electrodes can be fabricated using opaque materials, which may
be colored, because the electrodes do not need to be
transparent.
[0053] FIG. 1A depicts a single capsule 20 of an encapsulated
display media. In brief overview, the embodiment depicted in FIG.
1A includes a capsule 20 containing at least one particle 50
dispersed in a suspending fluid 25. The capsule 20 is addressed by
a first electrode 30 and a second electrode 40. The first electrode
30 is smaller than the second electrode 40. The first electrode 30
and the second electrode 40 may be set to voltage potentials which
affect the position of the particles 50 in the capsule 20.
[0054] The particles 50 represent 0.1% to 20% of the volume
enclosed by the capsule 20. In some embodiments the particles 50
represent 2.5% to 17.5% of the volume enclosed by capsule 20. In
preferred embodiments, the particles 50 represent 5% to 15% of the
volume enclosed by the capsule 20. In more preferred embodiments
the particles 50 represent 9% to 11% of the volume defined by the
capsule 20. In general, the volume percentage of the capsule 20
that the particles 50 represent should be selected so that the
particles 50 expose most of the second, larger electrode 40 when
positioned over the first, smaller electrode 30. As described in
detail below, the particles 50 may be colored any one of a number
of colors. The particles 50 may be either positively charged or
negatively charged.
[0055] The particles 50 are dispersed in a dispersing fluid 25. The
dispersing fluid 25 should have a low dielectric constant. The
fluid 25 may be clear, or substantially clear, so that the fluid 25
does not inhibit viewing the particles 50 and the electrodes 30, 40
from position 10. In other embodiments, the fluid 25 is dyed. In
some embodiments the dispersing fluid 25 has a specific gravity
substantially matched to the density of the particles 50. These
embodiments can provide a bistable display media, because the
particles 50 do not tend to move absent an electric field applied
via the electrodes 30, 40.
[0056] The electrodes 30, 40 should be sized and positioned
appropriately so that together they address the entire capsule 20.
There may be exactly one pair of electrodes 30, 40 per capsule 20,
multiple pairs of electrodes 30, 40 per capsule 20, or a single
pair of electrodes 30, 40 may span multiple capsules 20. In the
embodiment shown in FIGS. 1A and 1B, the capsule 20 has a
flattened, rectangular shape. In these embodiments, the electrodes
30, 40 should address most, or all, of the flattened surface area
adjacent the electrodes 30, 40. The smaller electrode 30 is at most
one-half the size of the larger electrode 40. In preferred
embodiments the smaller electrode is one-quarter the size of the
larger electrode 40; in more preferred embodiments the smaller
electrode 30 is one-eighth the size of the larger electrode 40. In
even more preferred embodiments, the smaller electrode 30 is
one-sixteenth the size of the larger electrode 40. It should be
noted that reference to "smaller" in connection with the electrode
30 means that the electrode 30 addresses a smaller amount of the
surface area of the capsule 20, not necessarily that the electrode
30 is physically smaller than the larger electrode 40. For example,
multiple capsules 20 may be positioned such that less of each
capsule 20 is addressed by the "smaller" electrode 30, even though
both electrodes 30, 40 are equal in size. It should also be noted
that, as shown in FIG. 1C, electrode 30 may address only a small
corner of a rectangular capsule 20 (shown in phantom view in FIG.
1C), requiring the larger electrode 40 to surround the smaller
electrode 30 on two sides in order to properly address the capsule
20. Further, electrodes may be of any shape, such as concentric
rings or rectangles. Selection of the percentage volume of the
particles 50 and the electrodes 30, 40 in this manner allow the
encapsulated display media to be addressed as described below.
[0057] Electrodes generally may be fabricated from any material
capable of conducting electricity so that electrode 30, 40 may
apply an electric field to the capsule 20. In the embodiments to be
discussed here, conductive material may be printed by using
conductive ink. Conductive inks are well known and may be prepared
by including in the ink fluid a conductive material such as
powdered metal or powdered graphite. As noted above, the
rear-addressed embodiments depicted in FIGS. 1A and 1B allow the
electrodes 30, 40 to be fabricated from opaque materials such as
solder paste, copper, copper-clad polyimide, graphite inks, silver
inks and other metal-containing conductive inks. Alternatively,
electrodes may be fabricated using transparent materials such as
indium tin oxide and conductive polymers such as polyaniline or
polythiopenes. Electrodes 30, 40 may be provided with contrasting
optical properties. In some embodiments, one of the electrodes has
an optical property complementary to optical properties of the
particles 50. Alternatively, since the electrodes need not be
transparent, an electrode can be constructed so as to display a
selected color. Since electric current is not always required to be
conducted from an electrode to a display element, but is only
required to flow within the electrode to set up an electric field,
one is in general able to overcoat the electrode with a colored ink
so as to impart a desired color to an electrode, without
detrimental effect on the operation of an electrode.
[0058] The operation of the electrophoretic display element will be
presented with regard to an embodiment that displays two states,
for example, black and white. In this embodiment, the capsule 20
contains positively charged black particles 50, and a substantially
clear suspending fluid 25. The first, smaller electrode 30 is
colored black, and is smaller than the second electrode 40, which
is colored white or is highly reflective. When the smaller, black
electrode 30 is placed at a negative voltage potential relative to
larger, white electrode 40, the positively-charged particles 50
migrate to the smaller, black electrode 30. The effect to a viewer
of the capsule 20 located at position 10 is a mixture of the
larger, white electrode 40 and the smaller, black electrode 30,
creating an effect which is largely white. Referring to FIG. 1B,
when the smaller, black electrode 30 is placed at a positive
voltage potential relative to the larger, white electrode 40,
particles 50 migrate to the larger, white electrode 40 and the
viewer is presented a mixture of the black particles 50 covering
the larger, white electrode 40 and the smaller, black electrode 30,
creating an effect which is largely black. In this manner the
capsule 20 may be addressed to display either a white visual state
or a black visual state.
[0059] Other two-color schemes are easily provided by varying the
color of the smaller electrode 30 and the particles 50 or by
varying the color of the larger electrode 40. For example, varying
the color of the larger electrode 40 allows fabrication of a
rear-addressed, two-color display having black as one of the
colors. Alternatively, varying the color of the smaller electrode
30 and the particles 50 allow a rear-addressed two-color system to
be fabricated using white as one of the colors. Further, it is
contemplated that the particles 50 and the smaller electrode 30 can
be different colors. In these embodiments, a two-color display may
be fabricated having a second color that is different from the
color of the smaller electrode 30 and the particles 50. For
example, a rear-addressed, orange-white display may be fabricated
by providing blue particles 50, a red, smaller electrode 30, and a
white (or highly reflective) larger electrode 40. In general, the
optical properties of the electrodes 30, 40 and the particles 50
can be independently selected to provide desired display
characteristics. In some embodiments the optical properties of the
dispersing fluid 25 may also be varied, e.g. the fluid 25 may be
dyed.
[0060] In another embodiment, this technique may be used to provide
a full color display. Referring now to FIGS. 1D and 1E, an
embodiment is depicted that comprises three display elements. It
should be understood that although FIGS. 1D and 1E depict
rectangular elements having equally-sized display elements, an
element may have any shape and a display may be comprised of
display elements that are unequal in size or shape, or
alternatively the display may be comprised of display elements that
are unequal in number by color or optical property. The display
elements may each be formed as a single large capsule, or each may
be distributed across any number of small capsules or cells. For
the purposes of illustration, the simpler case of a single large
capsule for each display element is shown. In both cases we refer
to the regions 20, 20', 20", as capsules. Thus, a first capsule 20
contains positively charged black particles 50 and a substantially
clear suspending fluid 25. A first, smaller electrode 30 is colored
black, and is smaller than the second electrode 40, which is
colored red. When the smaller, black electrode 30 is placed at a
negative voltage potential relative to larger, red electrode 40,
the positively-charged particles 50 migrate to the smaller, black
electrode 30. The effect to a viewer of the capsule 20 located at
position 10 is a mixture of the larger, red electrode 40 and the
smaller, black electrode 30, creating an effect which is largely
red. When the smaller, black electrode 30 is placed at a positive
voltage potential relative to the larger, red electrode 40,
particles 50 migrate to the larger, red electrode 40 and the viewer
is presented a mixture of the black particles 50 covering the
larger, red electrode 40 and the smaller, black electrode 30,
creating an effect which is largely black. In this manner the first
capsule 20 may be addressed to display either a red visual state or
a black visual state. One can equally have a second capsule 20'
wherein the larger electrode 40' is green, and a third capsule 20"
wherein the larger electrode 40" is blue. A second capsule 20'
contains positively charged black particles 50' and a substantially
clear suspending fluid 25'. A first, smaller electrode 30' is
colored black, and is smaller than the second electrode 40', which
is colored green. When the smaller, black electrode 30' is placed
at a negative voltage potential relative to larger, green electrode
40', the positively-charged particles 50' migrate to the smaller,
black electrode 30'. The effect to a viewer of the capsule 20'
located at position 10' is a mixture of the larger, green electrode
40' and the smaller, black electrode 30', creating an effect which
is largely green. When the smaller, black electrode 30' is placed
at a positive voltage potential relative to the larger, green
electrode 40', particles 50' migrate to the larger, green electrode
40' and the viewer is presented a mixture of the black particles
50' covering the larger, green electrode 40' and the smaller, black
electrode 30', creating an effect which is largely black.
Similarly, a third capsule 20" contains positively charged black
particles 50" and a substantially clear suspending fluid 25". A
first, smaller electrode 30" is colored black, and is smaller than
the second electrode 40", which is colored blue. When the smaller,
black electrode 30" is placed at a negative voltage potential
relative to larger, blue electrode 40", the positively-charged
particles 50" migrate to the smaller, black electrode 30". The
effect to a viewer of the capsule 20" located at position 10" is a
mixture of the larger, blue electrode 40" and the smaller, black
electrode 30", creating an effect which is largely blue. When the
smaller, black electrode 30" is placed at a positive voltage
potential relative to the larger, blue electrode 40", particles 50"
migrate to the larger, blue electrode 40" and the viewer is
presented a mixture of the black particles 50" covering the larger,
blue electrode 40" and the smaller, black electrode 30", creating
an effect which is largely black. Further, the relative intensities
of these colors can be controlled by the actual voltage potentials
applied to the electrodes. By choosing appropriate combinations of
the three colors, one may create a visual display which appears as
the effective combination of the selected colors as an additive
process. As an alternative embodiment, the first, second and third
capsules can have larger electrodes 40, 40', 40" which are
respectively colored cyan, yellow, and magenta. Operation of the
alternative cyan, yellow, and magenta embodiment is analogous to
that of the red, green, and blue embodiment, with the feature that
the color to be displayed is selected by a subtractive process.
[0061] In other embodiments the larger electrode 40 may be
transparent or reflective instead of white. In these embodiments,
when the particles 50 are moved to the smaller electrode 30, light
reflects off the reflective surface of the larger electrode 40 and
the capsule 20 appears light in color, e.g. white. When the
particles 50 are moved to the larger electrode 40, the reflecting
surface is obscured and the capsule 20 appears dark because light
is absorbed by the particles 50 before reaching the reflecting
surface. In other embodiments, proper switching of the particles
may be accomplished with a combination of alternating-current (AC)
and direct-current (DC) electric fields.
[0062] In still other embodiments, the rear-addressed display
previously discussed can be configured to transition between
largely transmissive and largely opaque modes of operation
(referred to hereafter as "shutter mode"). Referring back to FIGS.
1A and 1B, in these embodiments the capsule 20 contains at least
one positively-charged particle 50 dispersed in a substantially
clear dispersing fluid 25. The larger electrode 40 is transparent
and the smaller electrode 30 is opaque. When the smaller, opaque
electrode 30 is placed at a negative voltage potential relative to
the larger, transmissive electrode 40, the particles 50 migrate to
the smaller, opaque electrode 30. The effect to a viewer of the
capsule 20 located at position 10 is a mixture of the larger,
transparent electrode 40 and the smaller, opaque electrode 30,
creating an effect which is largely transparent. Referring to FIG.
1B, when the smaller, opaque electrode 30 is placed at a positive
voltage potential relative to the larger, transparent electrode 40,
particles 50 migrate to the second electrode 40 and the viewer is
presented a mixture of the opaque particles 50 covering the larger,
transparent electrode 40 and the smaller, opaque electrode 30,
creating an effect which is largely opaque. In this manner, a
display formed using the capsules depicted in FIGS. 1A and 1B may
be switched between transmissive and opaque modes. In some
embodiments the electrodes may be disposed on the viewing side of
the capsule 20. Such a display can be used to construct a window
that can be rendered opaque or a wide range of colors by using a
tinted electrode. Although FIGS. 1A-1D depict a pair of electrodes
associated with each capsule 20, it should be understood that each
pair of electrodes may be associated with more than one capsule
20.
[0063] A similar technique may be used in connection with the
embodiment of FIGS. 3A, 3B, 3C, and 3D. Referring to FIG. 3A, a
capsule 20 contains at least one dark or black particle 50
dispersed in a substantially clear dispersing fluid 25. A smaller,
opaque electrode 30 and a larger, transparent electrode 40 apply
both direct-current (DC) electric fields and alternating-current
(AC) fields to the capsule 20. A DC field can be applied to the
capsule 20 to cause the particles 50 to migrate towards the smaller
electrode 30. For example, if the particles 50 are positively
charged, the smaller electrode is placed a voltage that is more
negative than the larger electrode 40. Although FIGS. 3A-3D depict
only one capsule per electrode pair, multiple capsules may be
addressed using the same electrode pair.
[0064] The smaller electrode 30 is at most one-half the size of the
larger electrode 40. In preferred embodiments the smaller electrode
is one-quarter the size of the larger electrode 40; in more
preferred embodiments the smaller electrode 30 is one-eighth the
size of the larger electrode 40. In even more preferred
embodiments, the smaller electrode 30 is one-sixteenth the size of
the larger electrode 40.
[0065] Causing the particles 50 to migrate to the smaller electrode
30, as depicted in FIG. 3A, allows incident light to pass through
the larger, transparent electrode 40 and be reflected by a
reflecting surface 60. In shutter mode, the reflecting surface 60
is replaced by a translucent layer, a transparent layer, or a layer
is not provided at all, and incident light is allowed to pass
through the capsule 20, i.e. the capsule 20 is transmissive. If the
translucent layer or the transparent layer comprises a color, such
as a color filter, the light that is transmitted will be those
wavelengths that the filter passes, and the reflected light will
consist of those wavelengths that the filter reflects, while the
wavelengths that the filter absorbs will be lost. The visual
appearance of a shutter mode display may thus depend on whether the
display is in a transmissive or reflective condition, on the
characteristics of the filter, and on the position of the
viewer.
[0066] Referring now to FIG. 3B, the particles 50 are dispersed
throughout the capsule 20 by applying an AC field to the capsule 20
via the electrodes 30, 40. The particles 50, dispersed into the
capsule 20 by the AC field, block incident light from passing
through the capsule 20, causing it to appear dark at the viewpoint
10. The embodiment depicted in FIGS. 3A-3B may be used in shutter
mode by not providing the reflecting surface 60 and instead
providing a translucent layer, a transparent layer, a color filter
layer, or no layer at all. In shutter mode, application of an AC
electric field causes the capsule 20 to appear opaque. The
transparency of a shutter mode display formed by the apparatus
depicted in FIGS. 3A-3D may be controlled by the number of capsules
addressed using DC fields and AC fields. For example, a display in
which every other capsule 20 is addressed using an AC field would
appear about half as transmissive as when the particles are all
addressed by the AC field.
[0067] FIGS. 3C and 3D depict an embodiment of the electrode
structure described above in which electrodes 30, 40 are on "top"
of the capsule 20, that is, the electrodes 30, 40 are between the
viewpoint 10 and the capsule 20. In these embodiments, both
electrodes 30, 40 should be transparent. Transparent conducting
layers can be fabricated using conductive polymers, such as
polyaniline, polythiophenes, indium tin oxide, or polymers
containing conducting particles less than 100 nanometers in
diameter such as copper iodide, ionic polymers, or slat-doped
polymers. These materials may be made soluble so that electrodes
can be fabricated using coating techniques such as spin coating,
spray coating, meniscus coating, printing techniques, forward and
reverse roll coating and the like. In these embodiments, light
passes through the electrodes 30, 40 and is either absorbed by the
particles 50, reflected by reflecting layer 60 (when provided),
transmitted throughout the capsule 20 (when reflecting layer 60 is
not provided), or partially transmitted and/or reflected if a color
filter is present in place of retroreflecting layer 60.
[0068] Referring to FIG. 3E, three display element capsules 22, 22'
and 22" each contain at least one white particle 50 dispersed in a
substantially clear dispersing fluid 25. In one embodiment, each
display element capsule 22, 22' and 22" has a transparent electrode
42, 42', and 42" disposed above it and a colored filter 60, 60' and
60" disposed below it. A common reflective surface 70 may be shared
behind the color filter layer. In an alternative embodiment, the
display includes an emissive light source 70 Smaller, opaque
electrodes 30, 30' and 30" and larger, transparent electrodes 40,
40' and 40" may apply direct-current (DC) electric fields and
alternating-current (AC) fields to the capsules 20, 20' and 20". A
DC field can be applied to the capsules 20, 20' and 20" to cause
the particles 50, 50' 50" to migrate towards the smaller electrodes
30, 30' and 30". For example, if the particles 50, 50' and 50" are
positively charged, the smaller electrodes 30, 30' and 30" are
placed a voltage that is more negative than the larger electrodes
40, 40' and 40".
[0069] The smaller electrode 30 is at most one-half the size of the
larger electrode 40. In preferred embodiments the smaller electrode
30 is one-quarter the size of the larger electrode 40; in more
preferred embodiments the smaller electrode 30 is one-eighth the
size of the larger electrode 40. In even more preferred
embodiments, the smaller electrode 30 is one-sixteenth the size of
the larger electrode 40.
[0070] Causing the particles 50 to migrate to the smaller electrode
30, as depicted in the first two capsules of FIG. 3E, allows
incident light to pass through the larger, transparent electrode
40, through filter 60, reflect off substrate 70 and pass back
through the device. If the first, second and third filters 60, 60'
and 60" are colored cyan, magenta, and yellow respectively, and the
particles 50 are white, this system can display full color in a
standard two-color fashion.
[0071] The filter layer 60 may be a translucent layer, a
transparent layer, a color filter layer, or a layer is not provided
at all, and further substrate 70 may be reflective, emissive,
translucent or not provided at all. If the layer 60 comprises a
color, such as a color filter, the light which is transmitted will
be those wavelengths that the filter passes, and the reflected
light will consist of those wavelengths that the filter reflects,
while the wavelengths that the filter absorbs will be lost. The
visual appearance of a the display element in 3E may thus depend on
whether the display is in a transmissive or reflective condition,
on the characteristics of the filter, and on the position of the
viewer. In an alternative embodiment layer 60 may be provided on
top of the capsule adjacent to electrode 42.
[0072] Referring now to FIGS. 3F-3K, one embodiment of a tri-color
element is described. Clear electrode 42 allows light to pass into
capsule 22 and to strike either white particles W, red particles R,
or a colored substrate 60. The substrate 60 can be a combination of
color filter and non-colored substrate or it can be provided as a
unitary colored substrate. Capsule 22 also includes a suspending
fluid that can be dye-colored (possibly eliminating the need for a
separate color filter 60) or substantially clear. Electrodes 45 and
35 are transparent and may be equally sized or sized in any
suitable manner taking into account the relative particles sizes
and mobilities of particles W and R. A gap exists between 45 and
35. Assume that particles W are negatively charged and particles R
are positively charged. In FIG. 3F, top electrode 42 is set at a
positive voltage potential relative to bottom electrodes 35 and 45,
moving particles W to the top and particles R to the bottom and
thus white is displayed. In FIG. 3G by reversing the polarity of
the electrodes, red is displayed. In both FIGS. 3F and 3G the
particles obscure substrate 60. In FIG. 3H electrode 45 is at a
negative voltage potential relative to electrode 35, while
electrode 42 is at a voltage potential between the potentials of 45
and 35, such as zero. Alternatively, electrode 42 switches between
the potentials of 45 and 35 so that over time the effective voltage
of 42 is again between the potentials of 45 and 35. In this state,
the particles R move toward electrode 45 and the particles W move
toward electrode 35 and both particles R and W move away from the
gap in the center of the capsule 22. This reveals substrate 60,
permitting a third color such as cyan to be imaged. In alternate
embodiments the color combinations can differ. The specific colors
of the filters and particles need not differ. This system, called
"dual particle curtain mode," can image three arbitrary colors. In
a preferred embodiment the colors are as described wherein one
color is white and the other two colors are complements. In this
manner, referring again to FIG. 3H, if a small portion of red is
visible it absorbs part of the light reflected from the cyan
substrate and the net result is black, which may be offset by a
small portion of visible white. Thus, the element in FIG. 3H may
appear to be cyan even if some red and white is visible. As
mentioned above, the edges of the element may be masked to hide
particles R and W when in the mode shown in FIG. 3H.
[0073] Referring now to FIG. 3I, a full-color element is shown
comprising three display elements, each operating in the manner
taught by FIGS. 3F-3H wherein the colored particles are positively
charged, and the white particles are negatively charged. The system
may still function with top electrode 42 extended as a common top
electrode as shown in FIG. 3I. For example, to achieve the state
shown, electrodes 42, 45, 35, 45', 35', 45", 35" may be set to
voltage potentials -30V, 60V, 60V, -60V, +60V, -60V, +60V
respectively.
[0074] Referring now to FIGS. 3J-3K, an electrode scheme is shown
whereby a cluster of microcapsules may be addressed for an entire
display element in a manner similar to those described above. Clear
electrode 42 allows light to pass into microcapsules 27 and to
strike either white particles W, red particles R, or colored
substrate 60. As above, colored substrate 60 may be a combination
of color filter and non-colored substrate 60 or colored substrate
60 may be provided as a unitary colored substrate. Capsules 27
include a suspending fluid that may be dye-colored (possibly
eliminating the need for a separate color filter 60) or
substantially clear. Electrodes 45 and 35 are transparent and may
be equally sized or sized in any suitable manner taking into
account the relative particle sizes and mobilities of particles W
and R. A gap exists between 45 and 35. Assume that particles W are
negatively charged and particles R are positively charged. The
system operates in the manner described in FIGS. 3F-3K, although
for any given microcapsule 27 there may be multiple gaps. FIG. 3K
illustrates an embodiment of a suitable electrode pattern in which
45 and 35 are interdigitated.
[0075] Referring now to 3L-3M, an alternate embodiment is shown.
Again clear electrode 42 allows light to pass into capsule 22 and
to strike white particles W or red particles R. In the embodiment
shown in FIG. 3L, capsule 22 includes a suspending fluid 62 that is
dyed cyan. When electrodes 45 and 35 are set at appropriate
voltages particles, R and W move down to electrodes 45 and 35
respectively, where they are obscured by light-absorbing suspending
fluid 62. Alternatively, as shown in FIG. 3M, suspending fluid 62
is substantially clear and a third species of cyan particles C is
included in capsules 22. The cyan particles have a relatively
neutral charge. When electrodes 45 and 35 are set at appropriate
voltages particles R and W move down to electrodes 45 and 35
respectively, revealing the cyan particles.
[0076] The addressing structure depicted in FIGS. 3A-3M may be used
with electrophoretic display media and encapsulated electrophoretic
display media. FIGS. 3A-3M depict embodiments in which electrode
30, 40 are statically attached to the display media. In certain
embodiments, the particles 50 exhibit bistability, that is, they
are substantially motionless in the absence of a electric
field.
[0077] While various of the substrates described above are
reflective, an analogous technique may be employed wherein the
substrates emit light, with the particles again acting in a
"shutter mode" to reveal or obscure light. A preferred substrate
for this use is an electroluminiscent (EL) backlight. Such a
backlight can be reflective when inactive, often with a
whitish-green color, yet emit lights in various wavelengths when
active. By using whitish EL substrates in place of static white
reflective substrates, it is possible to construct a full-color
reflective display that can also switch its mode of operation to
display a range of colors in an emissive state, permitting
operation in low ambient light conditions.
[0078] FIGS. 4A and 4B depict an embodiment of a rear-addressing
electrode structure that creates a reflective color display in a
manner similar to halftoning or pointillism. The capsule 20
contains white particles 55 dispersed in a clear suspending fluid
25. Electrodes 42, 44, 46, 48 are colored cyan, magenta, yellow,
and white respectively. Referring to FIG. 4A, when the colored
electrodes 42, 44, 46 are placed at a positive potential relative
to the white electrode 48, negatively-charged particles 55 migrate
to these three electrodes, causing the capsule 20 to present to the
viewpoint 10 a mix of the white particles 55 and the white
electrode 48, creating an effect which is largely white. Referring
to FIG. 4B, when electrodes 42, 44, 46 are placed at a negative
potential relative to electrode 48, particles 55 migrate to the
white electrode 48, and the eye 10 sees a mix of the white
particles 55, the cyan electrode 42, the magenta electrode 44, and
the yellow electrode 46, creating an effect which is largely black
or gray. By addressing the electrodes, any color can be produced
that is possible with a subtractive color process. For example, to
cause the capsule 20 to display a red color to the viewpoint 10,
the yellow electrode 46 and the magenta electrode 42 are set to a
voltage potential that is more positive than the voltage potential
applied by the cyan electrode 42 and the white electrode 48.
Further, the relative intensities of these colors can be controlled
by the actual voltage potentials applied to the electrodes. Again,
AC current may be used appropriately to randomize the position of
the particles as a step in this process.
[0079] The technique used in FIGS. 4A and 4B could be used in a
similar manner with fewer electrodes and controlling fewer colors.
For example, if electrode 42 were not present, the element could
still display three colors. If electrodes 44 and 46 were colored
red and cyan respectively, the capsule could display red, cyan and
white. This construction could be used then employed as a display
element, to be matched with similar display elements displaying
other trios of colors thus achieving a full-color display as
described above.
[0080] The addressing structures described in FIGS. 1-4B typically
comprise a top electrode controlled by display driver circuitry. It
may be seen that if the top electrode is absent, the display may be
imaged by an externally applied voltage source, such as a passing
stylus or electrostatic print head. The means that techniques
applied above to generate a full-color electrophoretic display
could also be applied for a full-color electrophoretic media.
[0081] As will be evident from the above discussion, color
electrophoretic displays require careful registration of display
elements to the electrodes used to address those display elements.
Referring now to FIG. 5, steps that may be taken to efficiently and
cheaply manufacture a display while avoiding the registration
problems of prior art display are shown.
[0082] A substrate is provided that has at least two electrodes
(step 502). The number of electrodes provided will vary depending
on the number of regions to be individually addressed. For example,
in a traditional RGB display, three electrodes or sets of
electrodes may be provided in order to address red capsules, green
capsules, and blue capsules. The electrodes may have a
predetermined pattern of interest. For example, a display may
include both electronic ink and traditional, printed inks. In such
a display, the electrodes may be patterned to address only those
portions of the display meant to bear electronic ink.
[0083] In some embodiments, the substrate is provided and the
electrodes are printed on the substrate using any one of a number
of printing techniques. Referring now to FIG. 6, the structure of a
printed electrode is shown. A conductive material 162 can be
printed onto an insulative substrate 160. In some embodiments, such
as the one shown in FIG. 6, the substrate 160 defines one or more
vias 164 that allow the printed conductive material 162 to be
driven by addressing logic 166. The addressing logic 166 may also
be printed.
[0084] Referring back to FIG. 5, a first plurality of
electrophoretic display elements is selectively printed on the
substrate in substantial registration with at least one of the
electrodes disposed on the substrate (step 504). The
electrophoretic display elements generally are capsules containing
one or more species of particles in a dispersing fluid as described
above in connection with FIGS. 1-4B. The display elements, which
may form the contrast phase of an electronic ink, may be printed
onto the substrate using any of the printing techniques described
above. In certain embodiments, the printing technique itself
provides the accuracy necessary to register the display elements to
the appropriate electrode. For example, an ink-jet printing process
could be used to print red capsules in substantial registration
with a "red" electrode, green capsules in substantial registration
with a "green" electrode, and blue capsules in substantial
registration with a "blue" electrode. The capsules can be printed
sequentially or an ink-jet head may be used that allows red, green,
and blue capsules to be simultaneously printed in a selective
fashion.
[0085] In some embodiments, the display elements may be coated onto
the substrate using an intermediate having a substantially
cylindrical surface or a substantially flat surface, such as a
lithographic belt. In specific embodiments, the intermediate is a
roller, belt, blotter, brush, or sponge. The display elements may
be held to the intermediate by electrostatic forces, surface
tension, chemical bonding forces, or an applied electric field.
[0086] The properties of the binder phase. An be adjusted to match
the desired printing process. For example, an ink to be used in
inkjet printing may be adjusted to have a low viscosity. An ink
suitable for lithographic printing may be adjusted to have a
suitable contact angle. The display elements can be dispersed in a
suitable carrier fluid such as water or an organic solvent that is
dried after coating. The carrier fluid can also contain agents to
modify surface tension, contact angle, viscosity, or electrical
conductivity. The binder phase may contain monomers, oligomers,
polymers, or polymerization inhibitors. These components can be
used to form physically robust display element layers.
[0087] In one embodiment the display elements could be dispersed in
a low viscosity water solution containing a polymer. This solution
could be inkjet printed in registration with the appropriate
electrode pattern. In another embodiment the display element can be
dispersed in an ultraviolet-curable resin used in lithographic
printing processes, deposited on the appropriate electrodes by a
lithographic process, and cured to form the display element layer.
In all cases, the display elements are printed in substantial
registration with the appropriate electrodes.
[0088] In other embodiments, the electronic ink is coated onto the
substrate using an appropriate coating method such as
knife-over-roll coating, silk-screen printing processes, brushing
or other non-patterned coating techniques. In these embodiments, an
electric signal is applied to the electrode to which the display
elements should be registered. Application of an electric signal
attracts the display elements proximate the electrode. For certain
embodiments employing a carrier, the applied signal overcomes the
forces holding the display elements to the carrier and transfers
the elements to the substrate adjacent the electrode. The display
elements can be dispersed in a low viscosity liquid, such as low
molecular weight hydrocarbons like methylethylketone or
cyclohexane, or alcohols such as ethanol or propanol. The display
elements are then treated to produce a controlled surface charge
by, for example, adjusting the pH of the dispersing liquid or
adding surface active agents such as soaps, detergents, or other
dispersants. Because the charge of the display elements is
controlled, an electric charge can be use to transfer the display
elements to the appropriate electrode.
[0089] Other display elements may then be removed from the
substrate, e.g. by washing the substrate, to leave only the display
elements that are proximate to the electrode. A second plurality of
electrophoretic display elements are selectively deposited on the
substrate in substantial registration with another electrode (step
506) using techniques similar to those just described. The
technique used to selectively deposit the first plurality of
display elements need not be the same technique as that used to
selectively deposit the second plurality of display elements.
[0090] This technique for printing displays can be used to build
the rear electrode structure on a display or to construct two
separate layers that are laminated together to form the display.
For example an electronically active ink may be printed on an
indium tin oxide electrode. Separately, a rear electrode structure
as described above can be printed on a suitable substrate, such as
plastic, polymer films, or glass. The electrode structure and the
display element can be laminated to form a display.
[0091] While the examples described here are listed using
encapsulated electrophoretic displays, there are other
particle-based display media which should also work as well,
including encapsulated suspended particles and rotating ball
displays.
[0092] While the invention has been particularly shown and
described with reference to specific preferred embodiments, it
should be understood by those skilled in the art that various
changes in form and detail may be made therein without departing
from the spirit and scope of the invention as defined by the
appended claims.
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