U.S. patent application number 09/902803 was filed with the patent office on 2002-04-18 for avermectin pesticide with an organosilicone surfactant.
Invention is credited to Omilinsky, Barry.
Application Number | 20020045661 09/902803 |
Document ID | / |
Family ID | 22812293 |
Filed Date | 2002-04-18 |
United States Patent
Application |
20020045661 |
Kind Code |
A1 |
Omilinsky, Barry |
April 18, 2002 |
Avermectin pesticide with an organosilicone surfactant
Abstract
A pesticide composition is provided which is made from a
pesticide compound, such as those from the avermectin family, and
an organosilicone surfactant, such as polysiloxane, as the solvent
for the pesticide. The use of the organosilicone surfactant as a
solvent in conjunction with the avermectin pesticide in accordance
with the present invention is advantageous in that it allows for
control of pests such as nematodes and mites in substantially
greater amounts for a longer period of time than has been
accomplishing using prior art formulations including those which
use similar concentrations of the active ingredient or those which
use the pesticide in combination with an agricultural spray oil. In
addition, a method is provided wherein pests can be reduced or
eliminated from crops by application of an effective amount of the
avermectin and organosilicone surfactant pesticide formulation of
the present invention.
Inventors: |
Omilinsky, Barry;
(Princeton, NJ) |
Correspondence
Address: |
LARSON & TAYLOR, PLC
1199 NORTH FAIRFAX STREET
SUITE 900
ALEXANDRIA
VA
22314
US
|
Family ID: |
22812293 |
Appl. No.: |
09/902803 |
Filed: |
July 12, 2001 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
60217736 |
Jul 12, 2000 |
|
|
|
Current U.S.
Class: |
514/560 |
Current CPC
Class: |
A01N 43/90 20130101;
A01N 43/90 20130101; A01N 25/30 20130101; A01N 55/00 20130101; A01N
25/02 20130101; A01N 2300/00 20130101; A01N 25/30 20130101; A01N
43/90 20130101; A01N 25/02 20130101; A01N 43/90 20130101 |
Class at
Publication: |
514/560 |
International
Class: |
A01N 037/00 |
Claims
What is claimed is:
1. A composition for use as a pesticide, said composition
comprising an avermectin compound in the range of about 0.001 to
25% by weight and an organosilicone surfactant in the range of
about 75 to 99.999% by weight.
2. The composition according to claim 1, wherein the avermectin
compound comprises about 1-5% by weight.
3. The composition according to claim 1, wherein the organosilicone
composition comprises about 95-99% by weight.
4. The composition according to claim 1, wherein the avermectin
compound comprises an avermectin selected from the group consisting
of avermectin A1a, A1b, A2a, A2b, B1a, B1b, B2a, and B2b.
5. The composition according to claim 1, wherein the avermectin
compound comprises abamectin.
6. The composition according to claim 1, wherein the organosilicone
compound comprises a polysiloxane.
7. The composition according to claim 6, wherein said polysiloxane
is trisiloxane-8-ethoxylate.
8. The composition, according to claim 6, wherein the concentration
of said polysiloxane is approximately 90-110 grams.
9. The composition according to claim 1, wherein the composition is
diluted with a suitable amount of an aqueous diluent.
10. The composition according to claim 1, wherein the composition
is diluted with water.
11. The composition, according to claim 1, wherein the
concentration of said avermectin is approximately 1-5 grams.
12. A composition for use as a pesticide, said composition
comprising an avermectin compound and a trisiloxane-8-ethoxylate,
wherein said avermectin is in the range of approximately 1-5% by
weight and said trisiloxane-8-ethoxylate is in the range of
approximately 95-99% by weight.
13. The composition, according to claim 12, wherein the avermectin
is in the range of about 1-5 grams and said
trisiloxane-8-ethoxylate is present in an amount in the range of
about 90-110 grams.
14. A composition for use as a pesticide, said composition
comprising an avermectin compound and an organosilicone surfactant
wherein the ratio of the avermectin compound to the organosilicone
compound ranges from about 1:100,000 to about 1:3 by weight.
15. A composition according to claim 14 wherein the ratio of the
avermectin compound to the organosilicone compound ranges from
about 1:100 to about 1:15 by weight.
16. A method of treating plants or crops so as to prevent or reduce
infestation by pests comprising applying an effective amount of the
composition of claim 1 to said plants or crops.
17. A method of treating plants or crops so as to prevent or reduce
infestation by pests comprising applying an effective amount of the
composition of claim 14 to said plants or crops.
Description
FIELD OF THE INVENTION
[0001] This invention relates in general to the use of pesticides,
such as those from the avermectin family, and an organosilicone
surfactant as a solvent for the pesticide.
BACKGROUND OF THE INVENTION
[0002] Standard pesticide formulations such as those disclosed in
U.S. Pat. Nos. 5,558,806 and 5,104,647, issued to Policello et al.,
incorporated herein by reference, utilize active ingredients such
as abamectin solubilized in a formulation with a 1:1 ratio of an
organosilicone surfactant such as polysiloxane with another
ingredient such as Tergitol.RTM. "TMN-6" (trimethylnononal
ethoxylate). However, when the active ingredient such as abamectin
has been solubilized in the polysiloxane:TMN6 blend, the spreading
of the material is detrimental to the efficacy of the
pesticide.
[0003] Other pesticide formulations, such as those disclosed in
U.S. Pat. No. 4,560,677 issued to Dybas, incorporated herein by
reference, include an avermectin pesticide in combination with an
agricultural spray oil which is added in the interest of extending
the time period over which the pesticide will be effective.
However, while some extension of the period of effectiveness is
added by the use of the agricultural spray oil, the added time
period is only achieved by virtue of the addition of the expensive
spray oil, and thus the combination of avermectin with spray oils
does not constitute an efficient or cost effective manner of
achieving adequate coverage of pesticides for an extended period of
time.
[0004] There is thus a distinct need in the field of pesticides to
develop new formulations with solvents that result in a more
efficient and efficacious pesticide, and which can be utilized in a
more productive manner so as to reduce or eliminate the possibility
of deleterious attack on plant crops by pests such as nematodes or
mites. In addition, there is a distinct need in the field of
pesticides to develop new formulations which can provide an
effective and inexpensive pesticide for elongated periods of time
without the need for the additional expense and complication of
adding an agricultural spray oil.
SUMMARY OF THE INVENTION
[0005] Accordingly, it is thus an object of the present invention
to provide a novel pesticide composition including an active
ingredient such as those compounds of the avermectin family and an
organosilicone surfactant as the solvent for the pesticide.
[0006] It is further an object of the present invention to provide
a novel pesticide which utilizes an organosilicone surfactant as a
solvent so as to provide superior mite control when compared to
standard formulations at the same concentration of the active
ingredient.
[0007] It is still further an object of the present invention to
provide a novel pesticide composition which can be used to control
mites in citrus and other crops, and which can also be utilized to
control a wide variety of insects using a pesticide concentration
that is less than those concentrations used in previous pesticide
formulations.
[0008] It is even further an object of the present invention to
provide a novel pesticide composition which can be used to provide
extended and inexpensive crop treatment without the need for the
expensive and complex addition of an agricultural spray oil.
[0009] These and other objects are achieved by virtue of the
present invention which comprises a novel pesticide formulation
comprising a pesticide, such as those of the avermectin family, and
an organosilicone surfactant, such as polysiloxane, as the solvent
for the pesticide. In addition, a method is provided wherein pests
can be reduced or eliminated from crops by virtue of the use of the
pesticide formulation of the present invention. The use of the
organosilicone surfactant as a solvent in conjunction with the
avermectin pesticide in accordance with the present invention has
resulted in control of pests such as mites in substantially greater
amounts for a longer period of time than has been accomplishing
using prior art formulations including those which use similar
concentrations of the active ingredient or those which use the
pesticide in combination with an agricultural spray oil.
[0010] These and other features of the present invention as set
forth in, or will become obvious from, the detailed description of
the preferred embodiments provided hereinbelow.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0011] In accordance with the present invention, an improved
pesticide is provided which involves the use of a variety of
pesticides, such as those of the avermectin family, with an
organosilicone surfactant, such as polysiloxane, as a solvent for
the pesticide. In the preferred embodiment of the present
invention, the pesticide that is used is one from the avermectin
family of pesticides whose structures are closely related complex
16-membered lactones which exhibit synergistic effects when
dissolved in the organosilicone material. These avermectin
pesticides include compounds such as these have been disclosed in
U.S. Pat. No. 4,560,677, incorporated herein by reference. The
avermectin pesticide useful in the present invention thus may be
any avermectin pesticide well known in the art, such as the
avermectin compounds disclosed in U.S. Pat. No. 4,560,677 (issued
to Dybas), or others well known in the art. One such particularly
preferred pesticide is known as abamectin (or avermectin B-1) which
can be utilized in accordance with the invention. Other avermectins
useful in accordance with the invention are those classified as
avermectin A1a, A1b, A2a, A2b, B1a, B1b, B2a, and B2b, having the
formulas as described in U.S. Pat. No. 4,560,677.
[0012] However, although the present invention is known to be
particularly useful with pesticides of the avermectin family, such
as abamectin, the present invention will be useful with any
pesticide that is compatible for use with an organosilicone
surfactant. As will be recognized by one of ordinary skill in this
art, a variety of pesticides may be employed in accordance with the
present invention to accomplish crop protection against a variety
of insect and other pests, and thus the particular pesticide to be
used with the organosilicone surfactant of the invention will be
dependent upon the type of crop involved and the particular pest
for which is sought to be protected against. The present invention
is designed to control a wide variety of pests that usually damage
plants or crops, including nematodes, spider mites, other mites,
and other common pests typically faced by plant species. The plants
that can be protected using the present invention include numerous
plants subject to pests including food crops and ornamental plants
as well.
[0013] In the preferred embodiment, the pesticide composition in
accordance with the present invention is prepared by placing an
amount of the active ingredient, such as a pesticide of the
avermectin family, in the range of approximately 0.001 to 25% by
weight, the solubility limit of the active ingredient, with a
preferred range of about 1-5%, into an organosilicone surfactant
such as polysiloxane which will comprise approximately 75 to
99.999% by weight of the composition. As recited above, it is
intended to indicate that these preferred weight percent amounts in
the composition are those amounts which will be present in the
resulting composition prior to any dilution. In this preferred
embodiment, the avermectin family compound and the organosilicone
surfactant are mixed in these weight percentages, and the resulting
composition or concentrate may be utilized in this form, as would
be the case for use by individuals in plants or gardens found in or
around the home. However, when used in more industrial
applications, such as for fields or crops, or for use with plants
or foliage in a larger scale, this concentrated form of the
composition of the invention may be diluted as necessary with an
aqueous fluid, e.g., water, to any desired amount. Depending on the
size of the actual application, ranging from relatively small areas
to large fields of crops or other plants, the diluent, such as
water, may be added in amounts ranging from a few liters to
hundreds or thousands of gallons of aqueous liquid.
[0014] In any event, the avermectin:organosilicone ratio in the
final preferred composition will thus range from about 0.001:100
(1:100,000) to about 25:75 (1:3) by weight. In the particularly
preferred embodiment, the avermectin:organosilicone ratio will
range from about 1:100 to about 5:75 (1:15) by weight.
[0015] In a particularly preferred embodiment utilizing an
avermectin compound as an active ingredient, approximately 1-5
grams of avermectin is mixed into about 90-110 grams of
polysiloxane. If the active material is less than 100% in purity,
it is preferred that the material be corrected and the polysiloxane
level be concomitantly reduced. In the preferred process of
preparing the pesticide composition of the invention, this mixture
is blended until the avermectin is dissolved in the polysiloxane.
The polysiloxane preferably may also be warmed (e.g., to about
40.degree. C. or other suitable temperature depending on the
precise ingredients used) in order to facilitate and expedite the
dissolution process. Finally, as set forth above, the formulation
may be diluted with an appropriate amount of a suitable aqueous
liquid such as water.
[0016] One particularly preferred polysiloxane which may be used in
the invention is the polysiloxane known as
trisiloxane-8-ethoxylate, but any polysiloxane that may be useable
on plants and crops is suitable for use in the present invention.
One preferred polysiloxane formulation utilized as the
organosilicone surfactant of the invention is known as Silwet-77,
and this formulation includes polyalkyleneoxide-modified
heptamethyltrisiloxane at a level of about 84%, and
allyloxypolyethyleneglycol methyl ether at a level of 16%. In
preparing the composition of the present invention, as indicated
above, an amount of the avermectin compound in the range of about
0.001% to about 25% by weight of the composition, and preferably
about 1 to 5% of the overall composition, should be utilized to
prepare the desired pesticide formulation. However, as set forth
above, with regard to the use of the active avermectin ingredient,
e.g., abamectin, if this active ingredient is utilized in a
percentage of less than 100%, the material is preferably corrected
and the polysiloxane is concomitantly reduced.
[0017] Once prepared in the manner stated above, or in any other
conventional manner that would be employed to prepare a pesticide
composition from ingredients as recited above, the avermectin
pesticide compositions may be applied to crops in any suitable
manner based on the size and nature of the plants or crops to be
treated. The application of the pesticides of the present invention
may be conducted in any of a number of suitable ways well known in
this field. Such application procedures include spraying, pouring,
hosing, or other conventional methods for applying a pesticide
utilizing conventional equipment such as a spray hose, hand mister,
crop duster, etc. In the preferred method, individual plants or
crops are sprayed until dripping with the pesticide formulation of
the present invention, and this can be done as many times as
necessary for the particular plant or crop, e.g., daily, weekly,
etc. depending on the plant or crop and the likelihood of pest
infestation.
[0018] It is thus contemplated that the amount applied to the
plants or crops will be that amount effective to reduce or
eliminate damage to the plant or crop by pests such as mites. This
effective amount will differ depending on the specific plant or
crop being treated, as well as with the varying environmental
conditions, e.g., temperature, water level, moisture levels, etc.,
that such plants or crops will be subject to. In addition, in
circumstances where pest infestation is more likely, applications
of the present pesticide may be increased as needed.
[0019] As utilized in the manner set forth above, the pesticide
formulation of the present invention can thus be utilized
advantageously to control a wide variety of insects using a
pesticide concentration that is less than those concentrations used
in previous pesticide formulations.
[0020] It is thus submitted that the foregoing embodiments are only
illustrative of the claimed invention, and alternative embodiments
well known or obvious to one skilled in the art not specifically
set forth above also fall within the scope of the claims.
[0021] In addition, the following examples are presented as
illustrative of the claimed invention, and are not deemed to be
limiting of the scope of the invention, as defined by the claims
appended hereto, in any manner.
EXAMPLES
Example 1
[0022] A composition is prepare by weighing an equivalent of
approximately 2 grams of the active ingredient avermectin into
about 98 grams of a polysiloxane. The polysiloxane material is
described in the literature as trisiloxane-8-ethoxylkate. The
material data sheet (trade name Silwet L-77) describes CAS#
27306-78-1, polyalkyleneoxide modified heptamethyltrisiloxane at a
level of 84%. Another component believed to be a by-product of the
ethoxylation reaction is described as CAS# 272-80-8,
allyloxypolyethyleneglycol methyl ether at a level of 16%. The
molecular formula is (C.sub.2H.sub.40).sub.n
C.sub.11H.sub.30O.sub.3Si.su- b.3. Where n=8, the molecular weight
is 646. Accordingly, a range of 2 to 20 moles of ethylene oxide (or
C.sub.2H.sub.40) will provide a molecular range of 382 to 1174.
With regard to the use of the active ingredient, e.g., avermectin,
if the active material is utilized in a percentage of less than
100%, the material is preferably corrected and the polysiloxane is
concomitantly reduced. In any event, the polysiloxane is preferably
warmed to approximately 40.degree. C. to speed dissolution. The
composition in accordance with the present invention was thus
applied in tests assessing the effectiveness of the pesticide in
protection against pests such as nematodes and spider mites and was
thus shown to be more effective against such pests than prior art
formulations.
Example 2
[0023] Tests were conducted to compare the effectiveness of the
present invention, a pesticide formulation in accordance with the
invention designated as "OTX 951" which uses polysiloxane alone as
the solvent was compared with the formulation disclosed in U.S.
Pat. No. 5,558,806 which consists of a blend of polysiloxane and
the "TMN6" additive (Tergitol.RTM. as described above) in a 1:1
blend. The data accumulated with regard to the effectiveness of
both of these formulations is summarized below in Table 1:
1TABLE 1 % Mortality Two Spotted Spider Mite 2 oz/100 gallons
Treatment Initial 7 Days 14 Days 21 Days Water 10 5 0 0 Agri-Mek
100 85 35 45 OTX 951 100 80 95 65 OTX 956 100 80 50 35 OTX 957 100
80 45 45
[0024] As shown in Table 1 above, these data clearly show that when
the abamectin is solubilized in the polysiloxane:TMN6 blend, the
spreading of the material is detrimental to the efficacy of the
pesticide as reflected in the superior results achieved by the
polysiloxane formulation of the present invention. Utilizing the
polysiloxane alone in accordance with the present invention is
clearly more efficacious, and the experimental results achieved as
reflected in Table 1 above show and improvement (in terms of
mortality of spider mites) by greater than twice that achieved by
the prior art formulation after 14 days.
Example 3
[0025] The tests as described in Example 1 were expanded upon, and
the following results with regard to testing of the compositions of
the present invention were obtained as follows:
Overview
[0026] An assessment was made with regard to residual activity of
Avermectin formulations against Two-spotted spider mites (TSSM) on
ornamental plants.
Methods
[0027] Plants--Vinca (Vinca major) for this test was grown in a
greenhouse environment to a height of ca 7 inches. Plants were
fertilized (Peters 20-20-20, 1 teaspoon/gallon) once a week to
promote healthy plant growth.
[0028] Treatments and Assessments--Plants were sprayed to drip
using a hand mister and allowed to dry overnight (See treatment
list below). Leaf discs, 20 mm in diameter, were cut from the vinca
plants and placed on moistened cotton in small dishes. Five adult,
female two-spotted spider mites (TSSM) were added to each leaf
disc. These were four replicates for each treatment. Leaf discs
were assessed at 48 hours to determine percent mortality and number
of eggs per disc. Plants were returned to the greenhouse where they
were bottomed watered for the remainder of the test period. Samples
were taken from the plants at 0, 7, 14, 21, 28 and 35 days after
treatment (DAT).
[0029] Statistical Results--All data were analyzed via ANOVA (SAS
program) and means test was LSD (0.05% level). LSD analysis data
are reported as transformed means.
[0030] Treatment List and Rates
[0031] 1. Water
[0032] 2. Agri-Mek 0.15 lb EC 2 oz./100 gal.
[0033] 3. OTX 951 18 g/L 2 oz./100 gal.
[0034] 4. OTX 956 18 g/L 2 oz./100 gal.
[0035] 5. OTX 957 18 g/L 2 oz./100 gal.
[0036] Experimental Results--Table 2 below shows a summary of the
mortality and egg laying assessments of TSSM on vinca over a 35-day
period, including some of the results included and discussed in
Example 1, above. Means separation test analysis is shown in Table
3. Equal TSSM mortality counts were recorded on Agri-Mek and OTX
951 plants at 0 and 7 DAT. However, at 14 DAT and beyond, OTX 951
plants resulted in significantly improved control of TSSM. This
trend continued until the end of the test (35 DAT). OTX 956 showed
some improved activity over Agri-Mek up to 21 DAT and OTS 957 was
ca equal to Agri-Mek throughout the test.
[0037] These tests thus support the conclusion that the OTX-951
formulation of the present invention offers a significant TSSM
efficacy advantage over that of the Agri-Mek standard.
Example 4
[0038] Additional tests were conducted which assessed the pesticide
composition of the present invention (referred to in the Tables
below as OTX 951) on citrus fruits (e.g., oranges) as compared with
formulations such as those described in U.S. Pat. No. 4,560,677
which include an agricultural spray oil in addition to the
pesticide. As reflected in Tables 4-7 below, the tests showed that
the use of the OTX-951 formulation of the present invention could
be used effectively and for longer times than similar formulations
which were used in conjunction with an expensive agricultural spray
oil. Moreover, the pesticide compositions of the present invention
were shown to be effective when used in lesser amounts than the
standard treatment formulations
[0039] Accordingly, the additional tests confirmed the improved
efficacy of the OTX-951 formulation of the present invention over
prior art formulations, such as those that required the use of an
agricultural spray oil, as evidenced in the results shown in Tables
4-7. Once again, these tests evidenced the efficacy and significant
advantages of the improvements provided by the present invention in
terms of efficient and inexpensive use of agricultural pesticides
for prolonged periods of time which are superior over prior art
methods.
2 TABLE 2 48 hours 48 hours Trt # Alive % Mort # Eggs/Disc Mites
Added Time: 28 days Water 5.0 0.0 29.0 Agri-Mek 2.5 50.0 5.5 2
oz/100 gal OTX 951 1 5 70 0 8 8 2 oz/100 gal OTX 956 3 5 30 0 20 0
2 oz/100 gal OTX 957 2.5 50.0 11 0 2 oz/100 gal Mites Added Time 35
days Water 5.0 0.0 46.0 Agri-Mek 3.0 40.0 14.8 2 oz/100 gal OTX 951
2 0 60 0 14 5 2 oz/100 gal OTX 956 3 3 35 0 13 8 2 oz/100 gal OTX
957 3 0 40 0 16.0 2 oz/100 gal
[0040]
3TABLE 3 Statistical Analysis of TSSM Mortality Data t Grouping
Mean N trt LSD - Mortality Time 0 A 1.57080 4 5 A 1.57080 4 2 A
1.57080 4 3 A 1.57080 4 4 B 0.24826 4 1 LSD - Mortality Time 7 days
A 1.2843 4 2 A 1.2339 4 3 A 1.1687 4 5 A 1.1687 4 4 B 0.1399 4 1
LSD - Mortality Time 14 days A 1.4552 4 3 B 0.7865 4 4 B 0.7312 4 5
B 0.5147 4 2 C 0.0316 4 1 LSD - Mortality Time 21 days A 1.0077 4 3
B A 0.7362 4 2 B A 0.7312 4 5 B 0.6257 4 4 C 0.0316 4 1 LSD -
Mortality Time 28 days A 1.0630 4 3 B A 0.7914 4 2 B A 0.7914 4 5 B
C 0.4594 4 4 C 0.0316 4 1 LSD - Mortality Time 35 days A 0.8995 4 3
B A 0.6279 4 5 B A 0.6229 4 2 B A 0.5726 4 4 B 0.0316 4 1
[0041]
4TABLE 4 No. Mites/Lensfield/fruit Rate Treatment (lbs ai/A) Pre 7
DAT 21 DAT 35 DAT 49 DAT 77 DAT OTX 951 0.00625 0.72 0.66 0.26 0.03
0.16 0.95 Agrimek 0.00625 0.72 0.97 0.78 2.36 8.28 6.3 Agrimek +
Oil 0.00625 + 7.5 gal 2.6 0.36 0.75 2.08 6.33 6.3 Micromite + Oil
0.3 + 7.5 gal 0.55 0.52 0.61 0.45 0 65 0.77 Check 0.46 1.08 0.98
2.24 7 85 26.6
[0042]
5TABLE 5 No. Mites/Lensfield/fruit Treatment Rate/A Pre 7 DAT 28
DAT 56 DAT 70 DAT OTX 951 5.0 oz 4.6 0 0 0.01 0 Alert + 9.5 oz 6.00
0.00 0.00 0.00 0.00 Oil Agrimek + 10 oz + 5.5 0 0.06 0 0 Oil 8 gal
Micromite + 1.25 lbs + 5.8 0.02 0.07 0 0 Oil 8 gal Check 4.9 260
3.4 1 93 0 23
[0043]
6TABLE 6 No. Mites/Lensfield/fruit Rate Pre Treatment (lbs ai/A) #
21 DAT 35 DAT 56 DAT 70 DAT 84 DAT OTX 951 5 oz 2.01 0.04 0.05 0.09
0.18 0.24 OTX 952 5 oz 1.41 0.24 0.04 2.9 3 65 0.21 Agrimek + Oil
10 oz + 8 gal 1.94 0 0.08 0.96 0 88 0 18 Nexter 75 W + Oil 6.6 oz +
8 gal 1.45 0.07 0.92 4.4 4 23 2.03 Check 1.88 0.81 1.65 3.96 4 98
1.04
[0044]
7TABLE 7 No. Mites-Lensfield/fruit Rate Pre Treatment (lbs ai/A) #
7 DAT 14 DAT 28 DAT 42 DAT 56 DAT 77 DAT OTX 951 5 oz 9.1 0.00 0.00
0.00 0.01 0.00 0.02 Agrimek + Oil 10 oz + 8 gal 15.83 0.00 0.00
0.00 0.00 0 00 0.00 Polyram 80 DF 5 lbs. 10.93 0.00 0.00 0.00 0.02
0.03 0.00 Check 14.88 6.77 4.98 1.11 3.66 3 88 14.88
* * * * *