U.S. patent application number 09/824244 was filed with the patent office on 2001-12-27 for object having a decorative pattern and method of applying the decorative pattern.
Invention is credited to Bethune, Alain, Vayrette, Sophie Helene.
Application Number | 20010054564 09/824244 |
Document ID | / |
Family ID | 8848793 |
Filed Date | 2001-12-27 |
United States Patent
Application |
20010054564 |
Kind Code |
A1 |
Bethune, Alain ; et
al. |
December 27, 2001 |
Object having a decorative pattern and method of applying the
decorative pattern
Abstract
An object formed from a molded support may comprise a material
that may be metallically coated by electrodeposition. At least a
part of the support's surface may be covered with a first metallic
coating formed of at least n superposed layers of metal, where
n.gtoreq.2. The first metallic coating may at least partially
delimit a decorative pattern. A second metallic coating formed of
at most n-1 metal layers may cover the surface of the support in a
region corresponding to the decorative pattern. An outer metallic
layer of the first metallic coating may have at least one of a
color and an appearance that differs from a color and an appearance
of a metallic outer layer of the second metallic coating.
Inventors: |
Bethune, Alain; (Savigny,
FR) ; Vayrette, Sophie Helene; (Courbevoie,
FR) |
Correspondence
Address: |
Thomas L. Irving
FINNEGAN, HENDERSON, FARABOW
GARRETT & DUNNER, L.L.P.
1300 I Street, N.W.
Washington
DC
20005-3315
US
|
Family ID: |
8848793 |
Appl. No.: |
09/824244 |
Filed: |
April 3, 2001 |
Current U.S.
Class: |
206/459.5 ;
215/230 |
Current CPC
Class: |
B65D 51/245 20130101;
B44C 3/005 20130101; B44C 1/228 20130101; B41M 5/24 20130101 |
Class at
Publication: |
206/459.5 ;
215/230 |
International
Class: |
B65D 085/00 |
Foreign Application Data
Date |
Code |
Application Number |
Apr 3, 2000 |
FR |
00 04216 |
Claims
What is claimed is:
1. An object including at least one decorative pattern, the object
comprising: a support formed of molded material; a first metallic
coating covering at least part of a surface of the support, the
first metallic coating being formed of at least n superposed layers
of metal, wherein n.gtoreq.2, the first metallic coating at least
partially delimiting a decorative pattern; and a second metallic
coating covering the surface of the support in a region
corresponding to the decorative pattern, the second metallic
coating being formed of a maximum of n-1 layers of metal; wherein
an outer metallic layer of the first metallic coating has at least
one of a color and an appearance differing from that of an outer
metallic layer of the second metallic coating.
2. An object according to claim 1, wherein the molded material is a
material capable of being metallically coated by at least one of
electrodeposition and galvanoplasty.
3. An object according to claim 2, wherein the molded material is
chosen from zamak, ABS (acrylonitrile butadiene styrene), PP
(polypropylene), POM (polyoxymethylene) and a polyester.
4. An object according to claim 3, wherein the molded material is
filled.
5. An object according to claim 1, wherein the outer metallic layer
of the first metallic coating is formed of a first metal chosen
from chromium, silver, gold and zinc.
6. An object according to claim 5, wherein the outer metallic layer
of the second metallic coating is formed of a second metal,
differing from the first, the second metal being chosen from
chromium, nickel, silver, gold, zinc, copper and an alloy.
7. An object according to claim 6, wherein the second metal is an
alloy comprising bronze.
8. An object according to claim 1, wherein the object is configured
in the form of a container.
9. An object according to claim 1, wherein the object is configured
in the form of an accessory intended to be associated with a
container.
10. An object according to claim 9, wherein the accessory is a
stopper for a container.
11. An object according to claim 1, wherein the object is
configured in the form of a stopper for a container intended for
packaging a cosmetic product, and wherein the object further
comprises a transverse wall and a lateral skirt extending from the
transverse wall, wherein the decorative pattern is formed on at
least one of the transverse wall and the lateral skirt.
12. An object according to claim 11, wherein the skirt is a
cylindrical skirt, and wherein the decorative pattern is formed on
the cylindrical skirt.
13. An object according to claim 1, wherein n=3.
14. A system comprising: the object of claim 8; and a cosmetic
product contained in the object.
15. A system comprising: a container containing a cosmetic product;
and the object of claim 9 on the container.
16. A method of producing at least one decorative pattern on an
object, comprising: providing a support formed of molded material;
depositing at least two superposed layers of metal on at least a
part of a surface of the support, an outer layer of the at least
two layers being formed of a first metal; and eliminating a portion
of at least the outer layer so as to reveal a portion of another
layer formed of a second metal having at least one of a color and
an appearance differing from that of the first metal, wherein the
eliminated portion corresponds to a decorative pattern.
17. A method according to claim 16, wherein the eliminating
includes using a laser beam.
18. A method according to claim 16, wherein the molded material is
a material capable of being metallically coated by at least one of
electrodeposition and galvanoplasty, and wherein the depositing
comprises performing at least one of electrodeposition and
galvanoplasty.
19. A method according to claim 17, further comprising emitting the
laser beam with a YAG type laser.
20. A method according to claim 16, wherein the first and second
metals comprise at least one of a metal and an alloy chosen from
copper, nickel, chromium, silver, gold, zinc and bronze.
21. A method according to claim 16, further comprising molding the
support.
Description
[0001] The present invention relates to an object having a
decorative pattern on at least a portion of its surface, for
example, a stopper with a decorative pattern as commonly used on
containers for perfumes or other cosmetic products. The invention
also relates to a method for producing a decorative pattern on such
an object. The decoration may include a logo, a brand mark, a
design or any other inscription or distinctive sign.
[0002] In the field of cosmetics, particularly for packaging
perfumes or scents, use is made of decorated stoppers, for example
stoppers with a gold or chrome finish on their entire outer surface
or on just part of it, so as to reveal a decoration or a
design.
[0003] One of the techniques used to achieve such a decoration or
design includes metallically coating the plastic part, protecting
those parts that are not to be coated with, for example, a varnish,
and then possibly removing the varnish.
[0004] According to another manufacturing technique, the plastic
part that is to be coated with metal is obtained by molding two
plastics compatible with one another, one of them being capable of
being coated with a metal and the other not. This technique does,
however, have tremendous practical difficulties with its
implementation. Furthermore, it is expensive, particularly as
regards the construction of the molds, and the results obtained are
not entirely satisfactory in that it is difficult to obtain
clear-cut boundaries where the two plastics meet. Furthermore, it
offers little room to maneuver as far as the choice of the
decoration that can be produced is concerned.
[0005] Patent application FR-A-2 751 265 describes a method in
which an object is formed of a metal coatable material, such as an
ABS (acrylonitrile butadiene styrene), a PP (polypropylene), a POM
(polyoxyrn ethylene) or a filled polyester. A sheet of a
non-coatable material such as a PVC (polyvinyl chloride) or PC
(polycarbonate) is overmolded on the part. Next, galvanoplasty is
used to deposit a metallic coating on those areas of the part that
are not covered by the sheet. A method such as this is relatively
complicated and expensive to implement. Furthermore, as with the
technique described earlier, the possibilities with regard to the
decorations that can be achieved are limited.
[0006] Aside from the methods mentioned hereinabove, there are many
other decorating methods that differ according to the material
used. As far as plastics are concerned, mention may be made of
methods involving screen printing, pad printing, ink jet printing,
hot transfer or molding. The decoration can also include a label
stuck onto the object that is to be decorated.
[0007] Laser marking is a particular form of numerically-controlled
marking. Laser marking may be particularly advantageous on account
of its cleanliness, the recyclability of the marked part, the
permanency of the inscription, the flexibility it has to
offer--particularly in the choice of decoration and its
customization, the resolution it can achieve and also because of
how economical it can be to implement. Furthermore, lasers can
allow decoration to be done from a distance, that is to say without
the object to be decorated being brought into physical contact with
a printing member.
[0008] Patent application FR-A-2 778 919 describes a method for
using a laser to mark or etch a part formed of a polymer filled
with inorganic pigments and coated with a layer of chitin or chitin
derivatives. A method such as this has a certain number of
restrictions, particularly in regard to the color and appearance
that can be achieved for the decoration.
[0009] One of the optional subjects of the invention is to produce
an object bearing a permanent decoration, wherein the object may be
simple and economical to produce.
[0010] Another optional subject of the invention is to produce an
object on which a decoration can be fixed, regardless of the
geometry of the object to be decorated.
[0011] Yet another optional subject relates to a method for marking
an object made of thermoplastic, for example, a stopper for a
container, wherein the method may be simple and economical to
implement.
[0012] Still other optional subjects may become apparent from the
following description. It should be understood that certain aspects
of the invention could be practiced without accomplishing one or
more of these optional subjects.
[0013] According to one aspect of the invention, an object formed
from a support obtained by molding a material that can be
metallically coated by electrodeposition may be provided. The
support may be, on at least part of its surface, covered with a
first metallic coating formed of the superposition of n
(n.gtoreq.2) layers of metal and at least partially delimiting a
decorative pattern. The support may be covered on the surface
corresponding to the decorative pattern with a second metallic
coating formed of at most n-1 layers of metal. An outer metallic
layer of the first metallic coating may be of a color and/or
appearance that differs from the color and/or appearance of a
metallic outer layer of the second metallic coating.
[0014] The decorative pattern may include a text, a brand mark, a
logo, a design or any other pattern. The metallic surface of the
decorative pattern, in combination with the metallic surface which
delimits it, may provide aesthetic features. Optionally, many
contrast and color combinations can be obtained simply by altering
the choice and arrangement of the layers of metal of which the
first and second metallic coatings are respectively formed.
[0015] In one embodiment, the support may be metallically coated by
electrodeposition or galvanoplasty when the support is made of
plastic. The support from which the object is formed may be
obtained by molding a material that can be coated by
electrodeposition or galvanoplasty. By way of example, mention may
be made of zamac, ABS (acrylonitrile butadiene styrene), PP
(polypropylene), POM (polyoxymethylene) or a polyester, each of
these being optionally filled.
[0016] The outer layer of the first metallic coating may be formed
of a first metal chosen, for example, from chromium, silver, gold
and zinc. The outer layer of the second metallic coating may be
formed of a second metal, different from the first and chosen, for
example, from chromium, nickel, silver, gold, zinc, copper and an
alloy, such as bronze.
[0017] The object obtained according to the invention may be a
container, for example, chosen from a case, a bottle, a pot, and a
jar. The object also may be an accessory intended to be associated
with such a container, for example, a stopper for the container.
The decorative pattern may be formed on at least one of the
container and the stopper.
[0018] The object may form a stopper for a container intended, for
example, to package a cosmetic product. The stopper may be formed
of a transverse wall and a lateral skirt, for example, a
cylindrical skirt extending from the transverse wall. The
decorative pattern may be formed on the transverse wall and/or on
the lateral skirt.
[0019] According to another aspect of the invention, a method for
producing a decorative pattern on an object formed of a support
obtained by molding a material that can be metallically coated by
electrodeposition or galvanoplasty is provided. The method may
include using electrodeposition or galvanoplasty to deposit on at
least part of the support a coating formed by superposition of at
least two layers of metal, an outer layer of which is formed of a
first metal, and optionally using a laser beam to eliminate at
least a portion of the outer layer of the coating on the surface
corresponding to the decorative pattern so as to reveal, on the
surface, a layer formed of a second metal of a color and/or
appearance that differs from the first metal.
[0020] The laser used may be a laser of YAG type, which can provide
a short wavelength (1.06 .mu.m) that may be readily absorbed by
most non-metallic materials, for example, a thermoplastic which may
be used according to the invention.
[0021] The method according to the invention may have many optional
features. Marking may be quick (e.g., the cycle time, depending on
the decoration and on the object, may be of the order of a few
seconds). The resolution of the produced image may be of good
quality (e.g., of the order of a few lam). Furthermore, it may be
possible to decorate non-planar surfaces or those that would be
difficult to access using conventional screen printing or labeling
techniques. The object to be decorated may be marked from a
distance, without contact with the marking device. Such a technique
of decorating by laser can be implemented in industrial
installations turning out objects using equipment such as
conveyors, robot arms, turntables, or any other means commonly used
in industrial circles.
[0022] When an object is being marked with a laser beam, the object
to be decorated may be stationary, and the laser beam may be moved
around according to the decoration to be produced. Alternatively,
the laser beam may be stationary and the object may be moved around
according to the decorative pattern to be produced.
[0023] By way of non-limiting example, the first and second metals
may be chosen from the following metals or alloys: copper, nickel,
chrome, silver, gold, zinc, and bronze. Other metals may be used,
depending on the colors, appearance or contrast desired.
[0024] According to one aspect of the invention, an object
including at least one decorative pattern is provided. The object
may comprise a support formed of molded material and a first
metallic coating covering at least part of a surface of the
support. The first metallic coating may be formed of at least n
superposed layers of metal, wherein n.gtoreq.2. The first metallic
coating may at least partially delimit a decorative pattern, and a
second metallic coating may cover the surface of the support in a
region corresponding to the decorative pattern. The second metallic
coating may be formed of a maximum of n-1 layers of metal, wherein
an outer metallic layer of the first metallic coating has at least
one of a color and an appearance differing from that of an outer
metallic layer of the second metallic coating.
[0025] According to another aspect of the invention, the object may
be configured in the form of a container.
[0026] According to another aspect of the invention, the object may
be configured in the form of an accessory intended to be associated
with a container.
[0027] According to yet another aspect of the invention, a method
of producing at least one decorative pattern on an object is
provided. The method may include providing a support formed of
molded material and depositing at least two superposed layers of
metal on at least a part of a surface of the support. An outer
layer of the at least two layers may be formed of a first metal.
The method may also include eliminating a portion of at least the
outer layer so as to reveal a portion of another layer formed of a
second metal having at least one of a color and an appearance
differing from that of the first metal, wherein the eliminated
portion corresponds to a decorative pattern.
[0028] According to a further aspect of the invention, the object
may be configured in the form of a stopper for a container intended
for packaging a cosmetic product. The object may further comprise a
transverse wall and a lateral skirt extending from the transverse
wall. The decorative pattern may be formed on at least one of the
transverse wall and the lateral skirt.
[0029] Apart from the provisions set out hereinabove, the invention
may comprise a number of other provisions explained hereinafter
with regard to some non-limiting exemplary embodiments described
with reference to the figures. In the drawings,
[0030] FIG. 1 is a schematic view of the main stages of marking an
object according to one embodiment of the invention;
[0031] FIG. 2A is a cross-sectional view of a galvanized
(metallically coated) object prior to laser marking;
[0032] FIG. 2B is a cross-sectional view of the object of FIG. 2A
after laser marking according to one embodiment of the
invention;
[0033] FIG. 2C is a cross-sectional view of the object of FIG. 2A
after laser marking according to yet another embodiment of the
invention;
[0034] FIG. 3 is an isometric view of an embodiment of an object to
be decorated in accordance with the invention;
[0035] FIG. 4 is an isometric view of an alternative embodiment of
an object to be decorated in accordance with the invention;
[0036] FIG. 5 is an isometric view of another alternative
embodiment of an object to be decorated in accordance with the
invention;
[0037] FIG. 6A is an isometric view of an object decorated
according to an embodiment of an invention; and
[0038] FIG. 6B is a cross-sectional view of the object of FIG. 3A
taken along line 6B-6B.
[0039] As shown in FIG. 1, the object 1 to be decorated may be
configured as a stopper intended for a container such as a bottle,
jar, or case. This stopper 1 may be formed from a support 2,
obtained by molding a galvanizable thermoplastic such as ABS. The
support 2 may comprise a cylindrical lateral skirt 3 of circular
cross-section intended to engage with the neck of the container.
One end of the lateral skirt 3 may extend from a transverse wall 4
of square cross-section, larger than the cross-section of the
cylindrical lateral skirt 3. The lateral skirt 3 may have a
different cross-section, such as a square or oval. The transverse
wall 4 also may have a different cross-section, such as oval or
circular.
[0040] The support 2, once it has been molded, may then be passed
through a series of baths so that its surface is covered, for
example, by galvanoplasty, with a coating having a number of metal
layers.
[0041] Electrodeposition and galvanoplasty are techniques for
metallically coating an object by using the conductivity properties
of the material of which the object is formed. In the case of
galvanoplasty, the thermoplastics used may be made conductive by a
multistage method during which the object to be galvanized is
dipped in a series of baths.
[0042] In a first stage, known as "staining," tiny roughnesses may
be created on the surface of the object so as to generate anchoring
points for the metal deposit. To do that, organic bridges in the
object's structure may be broken down during this stage. In the
case of materials containing butadiene, such as ABS, micro-spheres
of butadiene lying at the surface of the material may be destroyed,
thus giving way to micro-cavities intended to form such anchoring
points.
[0043] In a second stage known as "catalysis," stable colloidal
palladium may be incorporated into the micro-cavities.
[0044] In a third stage known as "acceleration," the protective
colloid may be removed so as to activate the palladium.
[0045] In a fourth stage, the object may be rendered conductive by
an operation known as "chemi-nickel plating."
[0046] Thereafter, electrolysis may be used to deposit one or more
layers of metal onto the layer of nickel. For example, a layer of
copper may be deposited, onto which a layer of nickel, bronze,
chromium or gold may then be deposited. The layer of copper may
have the function of strengthening and improving the rigidity of
the thin nickel deposit.
[0047] As can be seen in the cross-sectional view of the stopper 1,
depicted in FIG. 2A, the galvanized coating may be formed of
superposed layers, e.g., a layer 10 of nickel, a layer 11 of
copper, and a layer 12 of chromium. The thickness of the three
layers of metal Ni/Cu/Cr thus deposited may range from about 10 pm
to about 30 pm.
[0048] After this galvanoplasty stage, the cylindrical lateral
skirt 3 of the stopper 1 may be decorated using a laser 7 of the
Nd: YAG type. To do this, the surface corresponding to the area to
receive the decorative pattern 6 may be swept with a laser beam 5
so as to literally "burn away" at least the outermost layer 12 on
the object in the area to be decorated. Thus, in the example of the
object including a layer 10 of nickel, a layer 11 of copper, and a
layer 12 of chromium, the laser beam may remove at least the layer
12 of chromium on the surface corresponding to the decorative
pattern 6 to be produced, thus revealing the decoration. A
cross-section through the lateral skirt 3 of the stopper, after
marking using the laser beam, is depicted in FIG. 2B. Because the
layer 12 of chromium has been removed from the surface
corresponding to the decorative pattern 6, this surface therefore
has the colors of the layer 11 of copper. Alternatively, it is
possible to eliminate the two outermost layers, shown in FIG. 2C,
thus revealing a nickel-colored decoration.
[0049] As shown in FIGS. 1 and 2A-2C, the decorative pattern 6 may
be produced on the lateral skirt 3 of the object. Alternatively, as
shown in FIGS. 6A and 6B, the decorative pattern 6 may be produced
on the transverse wall 4 of the stopper 1. As shown in
cross-section in FIG. 6B, the surface corresponding to the area to
receive the decorative pattern 6 may be swept with a laser beam 5
so as to literally "burn away" at least the outermost layer 12 on
the object in the area to be decorated. Because the layer 12 of
chromium has been removed from the surface corresponding to the
decorative pattern 6, this surface therefore has the colors of the
layer 11 of copper.
[0050] According to one specific embodiment, the wavelength of the
laser beam 5 may be about 1064 nm and its power may be about 9 W.
The surface to be decorated may be located a distance of about 200
mm away from the laser, and the focal length may be about 160
mm.
[0051] As shown in FIGS. 3-5, the object 1 to be decorated may be a
container or an accessory for use with a container. Referring to
FIG. 3, the object 1 to be decorated may be a stopper 14 configured
to fit on a container 13. As shown in FIG. 4, the object 1 to be
decorated may be both the stopper 14 and the container 13 on which
the stopper 14 is placed, each including a decorative pattern 6,
6', respectively. Further, as illustrated in FIG. 5, the object 1
to be decorated may be the container 13.
[0052] Optionally, the aesthetic appearance of the decorations
obtained by implementing the method according to the present
invention may be entirely compatible with the requirements of the
market for goods known as "luxury goods," such as perfume or other
cosmetic products of the same kind.
[0053] In the foregoing detailed description, reference is made to
some embodiments of the invention. It is obvious that variations
can be made thereto without departing from the spirit of the
invention as claimed hereinafter.
* * * * *