U.S. patent application number 09/766507 was filed with the patent office on 2001-12-06 for room temperature curable silicone sealant.
Invention is credited to Atwood, Robert C., Lin, Chiu-Sing, Lucas, Gary M..
Application Number | 20010049427 09/766507 |
Document ID | / |
Family ID | 22645989 |
Filed Date | 2001-12-06 |
United States Patent
Application |
20010049427 |
Kind Code |
A1 |
Atwood, Robert C. ; et
al. |
December 6, 2001 |
Room temperature curable silicone sealant
Abstract
A silicone sealant composition containing: (a) a moisture
curable organopolysiloxane component, comprising a mixture or
reaction product of (i) an organopolysiloxane polymer having
hydrolyzable substituent groups and (ii) a polyfunctional silicon
compound having two or more hydrolyzable substituent groups, (b) a
filler and (c) a hydrocarbon fluid comprising, based on 100 parts
by weight of the hydrocarbon fluid, greater than 40 parts by weight
cyclic paraffinic hydrocarbons and less than 60 parts by weight
noncyclic paraffinic hydrocarbons, exhibits improved tensile,
elongation and adhesive properties.
Inventors: |
Atwood, Robert C.;
(Mechanicville, NY) ; Lin, Chiu-Sing; (Rocky Hill,
CT) ; Lucas, Gary M.; (Glenville, NY) |
Correspondence
Address: |
CANTOR COLBURN, LLP
55 GRIFFIN ROAD SOUTH
BLOOMFIELD
CT
06002
|
Family ID: |
22645989 |
Appl. No.: |
09/766507 |
Filed: |
January 19, 2001 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
60176823 |
Jan 19, 2000 |
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Current U.S.
Class: |
528/10 |
Current CPC
Class: |
Y10T 428/31663 20150401;
C08L 2666/28 20130101; C08L 2666/02 20130101; C08G 77/16 20130101;
C08L 2666/54 20130101; C08L 83/04 20130101; C08L 83/04 20130101;
C08L 83/04 20130101; C09K 3/1018 20130101; Y10S 528/901
20130101 |
Class at
Publication: |
528/10 |
International
Class: |
C08G 077/00 |
Claims
What is claimed is:
1. A curable silicone sealant composition comprising a one-part,
moisture-curable polysiloxane component comprising a mixture or
reaction product of (i) a polysiloxane polymer having hydrolyzable
substituent groups and (ii) a polyfunctional silicon compound
having two or more hydrolyzable substituent groups, a filler, and a
hydrocarbon fluid comprising, based on 100 parts by weight of the
hydrocarbon fluid, greater than 40 parts by weight cyclic
paraffinic hydrocarbons and less than 60 parts by weight noncyclic
paraffinic hydrocarbons.
2. The curable silicone sealant composition of claim 1, comprising,
based on 100 parts by weight of the sealant composition, from 20
pbw to 90 pbw of the moisture-curable organopolysiloxane polymer,
from 1 pbw to 80 pbw of the filler, and from 1 pbw to 50 pbw of the
hydrocarbon fluid.
3. The curable silicone sealant composition of claim 1, comprising,
based on 100 parts by weight of the sealant composition, from 30
pbw to 75 pbw of the moisture-curable organopolysiloxane polymer,
from 2 pbw to 78 pbw of the filler, and from 10 pbw to 40 pbw of
the hydrocarbon fluid.
4. The curable silicone sealant composition of claim 1, comprising,
based on 100 parts by weight of the sealant composition, from 40
pbw to 60 pbw of the moisture-curable organopolysiloxane polymer,
from 3 pbw to 65 pbw of the filler, and from 15 pbw to 35 pbw of
the hydrocarbon fluid.
5. The curable silicone sealant composition of claim 1, wherein the
moisture-curable polysiloxane component comprises a mixture or
reaction product of (i) a polysiloxane polymer having hydrolyzable
substituent groups and (ii) a polyfunctional silicon compound
having two or more hydrolyzable substituent groups.
6. The curable silicone sealant composition of claim 5, wherein the
functional polysiloxane comprises one or more silicone polymers or
copolymers having structural units according to structural formula
(I): R.sub.aSiO.sub.4-a/2 (I) wherein each R is independently
hydroxy, a hydrolyzable organic group, or a monovalent hydrocarbon
radical; 0.ltoreq.a.ltoreq.4; and at least one R group per molecule
is hydroxy or a hydrolyzable organic group.
7. The curable silicone sealant composition of claim 6, wherein the
hydrolyzable organic groups are alkoxy, oximo, amino, aminoxy,
acyloxy, or a combination thereof.
8. The curable silicone sealant composition of claim 5, wherein the
organopolysiloxane polymer comprises a mixture of two or more
linear polymers or copolymers having the structural formula (II):
2wherein each R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6,
R.sup.7, R.sup.8, R.sup.9, and R.sup.10 is independently a
hydrolyzable organic group or a monovalent hydrocarbon radical, at
least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6,
R.sup.7, R.sup.8, R.sup.9 and R.sup.10 per molecule is hydroxy, or
at least two of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5,
R.sup.6, R.sup.7, R.sup.8, R.sup.9 and R.sup.10 per molecule are
hydrolyzable organic groups, and x and y are each numbers selected
to provide a polymer that exhibits a viscosity of from 5,000 to
500,000 centiPoise at 25.degree. C.
9. The curable silicone sealant composition of claim 8, wherein
each R.sup.1, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8
and R.sup.9 is independently (C.sub.1-C.sub.8)alkyl, fluoroalkyl or
phenyl; and each R.sup.2 and R.sup.10 is hydroxyl,
(C.sub.1-C.sub.8)alkyl, fluoroalkyl or phenyl.
10. The curable silicone sealant composition of claim 9, wherein
the polyfunctional organosilicone compound contains at least two
hydrolyzable groups per molecule.
11. The curable silicone sealant composition of claim 5, wherein
the polyfunctional organosilicone compound is
vinyltrimethoxysilane, tetramethoxysilane, methyltriethoxysilane,
tetraethoxysilane, methyltrimethoxysilane,
methylphenyldiethoxysilane, 3,3,3-trifluoropropyltrimethoxysilane,
methyl(tri(methylethylketoximo)sil- ane,
ethyl(tri(N,N-diethylamino)silane, methyltriacetoxysilane,
ethyltriacetoxysilane, methyltri(N-methylacetamido)silane,
n-propylorthosilicate and ethylpolysilicate, or dimers or trimers
thereof.
12. The curable silicone sealant composition of claim 5, wherein
the polyfunctional organosilicon compound has the structural
formula (III): R.sup.11.sub.4Si (III) wherein each R.sup.11 is
independently a hydrolyzable group or a monovalent hydrocarbon
radical, provided that at least one R.sup.11 is H, alkoxy or
alkenyl and that at least two R.sup.11 groups are hydrolyzable
groups.
13. The curable silicone sealant composition of claim 12 wherein at
least three R.sup.11 substituents are each alkoxy, oximo, amino,
aminoxy, or acyloxy.
14. The curable silicone sealant composition of claim 12, wherein
at least three R.sup.11 substituents are (C.sub.1-C.sub.8)alkoxy or
(C.sub.1-C.sub.8)acyloxy, and any remaining R.sup.11 substituent,
is (C.sub.1-C.sub.8)alkyl, (C.sub.2-C.sub.8)alkenyl, aryl, or
fluoroalkyl.
15. The curable silicone sealant composition of claim 12, wherein
the polyfunctional organosilicon compound is vinyltrimethoxysilane,
tetramethoxysilane, methyltriethoxysilane, methyltriacetoxysilane,
ethyltriacetoxysilane, tetraethoxysilane, methyltrimethoxysilane,
di-t-butoxydiacetoxysilane, or a mixture thereof.
16. The curable silicone sealant composition of claim 5, wherein
the moisture curable organopolysiloxane polymer is made by reaction
of 100 parts by weight of the organopolysiloxane polymer with from
about 0.1 to about 15 parts by weight of the polyfunctional
organosilicon compound.
17. The curable silicone sealant composition of claim 5, wherein
the moisture curable organopolysiloxane polymer is made by reaction
of 100 parts by weight of the organopolysiloxane polymer with from
1.0 to about 10 parts by weight of the polyfunctional organosilicon
compound.
18. The curable silicone sealant composition of claim 5, wherein
the moisture curable organopolysiloxane polymer is made by reaction
of 100 parts by weight of the organopolysiloxane polymer with from
about 2 to about 7 parts by weight of the polyfunctional
organosilicon compound.
19. The curable silicone sealant composition of claim 1, further
comprising a condensation cure catalyst.
20. The curable silicone sealant composition of claim 1, wherein
the hydrocarbon fluid comprises at least one cyclic hydrocarbon
containing from 5 to 24 carbon atoms per molecule and, optionally,
at least one non-cyclic paraffinic hydrocarbon containing from 5 to
24 carbon atoms per molecule.
21. The curable silicone sealant composition of claim 20, wherein
the cyclic and non-cyclic hydrocarbons each contain from 8 to 20
carbon atoms per molecule.
22. The curable silicone sealant composition of claim 20, wherein
the cyclic paraffinic hydrocarbon is cyclohexane, cyclooctane,
cyclononane, cyclodecane, or cyclododecane, and the noncyclic
paraffinic hydrocarbon is n-heptane, n-hexane, n-octane,
iso-octane, n-nonane, n-decane, n-undecane, n-dodecane,
iso-dodecane, n-heptadecane, n-octadecane, n-eicosane, or
isoeicosane.
23. The curable silicone sealant composition of claim 20, wherein
the hydrocarbon fluid comprises, based on 100 parts by weight of
the hydrocarbon fluid, from about 42 parts by weight to 100 parts
by weight cyclic paraffinic hydrocarbons and from 0 parts by weight
to about 58 parts by weight noncyclic paraffinic hydrocarbons.
24. The curable silicone sealant composition of claim 20, wherein
the hydrocarbon fluid comprises, based on 100 parts by weight of
the hydrocarbon fluid, from about 45 parts by weight to 75 parts by
weight cyclic paraffinic hydrocarbons and from about 25 parts by
weight to 55 parts by weight noncyclic paraffinic hydrocarbons.
25. The curable silicone sealant composition of claim 20, wherein
the hydrocarbon fluid comprises, based on 100 parts by weight of
the hydrocarbon fluid, from about 50 parts by weight to 70 parts by
weight cyclic paraffinic hydrocarbons and from about 30 parts by
weight to 50 parts by weight noncyclic paraffinic hydrocarbons.
26. The curable silicone sealant composition of claim 20, wherein
the hydrocarbon fluid comprises, based on 100 parts by weight of
the hydrocarbon fluid, from about 55 parts by weight to 65 parts by
weight cyclic paraffinic hydrocarbons and from about 30 parts by
weight to 45 parts by weight noncyclic, paraffinic
hydrocarbons.
27. The curable silicone sealant composition of claim 1, wherein
the filler is a reinforcing filler.
28. The curable silicone sealant composition of claim 27, wherein
the filler is fumed silica, hydrophobicized fumed silica, carbon
black, titanium dioxide, ferric oxide, aluminum oxide, or a mixture
thereof.
29. The curable silicone sealant composition of claim 27, wherein
the filler is fumed silica in amount from 1 parts by weight to 20
parts by weight, based on 100 parts by weight of the total sealant
composition.
30. The curable silicone sealant composition of claim 27, further
comprising a semi-reinforcing or non-reinforcing filler.
31. The curable silicone sealant composition of claim 27, further
comprising calcium carbonate.
32. A method for the manufacture of a one-part, room temperature
curable sealant composition, comprising mixing a one-part,
moisture-curable polysiloxane component comprising a mixture or
reaction product of (i) a polysiloxane polymer having hydrolyzable
substituent groups and (ii) a polyfunctional silicon compound
having two or more hydrolyzable substituent groups, a filler, and a
hydrocarbon fluid comprising, based on 100 parts by weight of the
hydrocarbon fluid, greater than 40 parts by weight cyclic
paraffinic hydrocarbons and less than 60 parts by weight noncyclic
paraffinic hydrocarbons.
33. The method of claim 32, wherein mixing is by continuously
compounding the composition in an extruder.
34. A method for sealing a gap between a first substrate and a
second substrate, wherein the second substrate is spaced apart from
the first substrate to form a gap, comprising applying an amount of
a room temperature curable sealing composition comprising a
one-part, moisture-curable polysiloxane component comprising a
mixture or reaction product of (i) a polysiloxane polymer having
hydrolyzable substituent groups and (ii) a polyfunctional silicon
compound having two or more hydrolyzable substituent groups, a
filler, and a hydrocarbon fluid comprising, based on 100 parts by
weight of the hydrocarbon fluid, greater than 40 parts by weight
cyclic paraffinic hydrocarbons and less than 60 parts by weight
noncyclic paraffinic hydrocarbons in an amount effective to bridge
the gap; and allowing the composition to cure in place to form an
elastomeric seal between the substrates.
35. An assembly comprising a first substrate, a second substrate
spaced apart from the first substrate, and a cured silicone sealant
composition of claim 1.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority to U.S. application Ser.
No. 60/176,823, filed Jan. 19, 2001, which is incorporated by
reference in its entirety.
FIELD OF THE INVENTION
[0002] This invention relates to one part, room temperature
vulcanizable silicone sealants, and in particular to such sealants
having both improved flowability and improved properties upon
cure.
BRIEF DESCRIPTION OF THE RELATED ART
[0003] Silicone compositions that are storable under dry conditions
and which, on exposure to moisture, cure to produce elastomers, are
widely used as sealants and caulks in building and construction
applications. These compositions are often referred to as one part,
room temperature vulcanizable ("RTV") compositions. They typically
contain a moisture-curable polyorganosiloxane polymer, a filler,
and a condensation cure catalyst. When used as sealants, they are
typically packaged in a moisture impervious tube and applied to a
substrate by extrusion from the packaging tube.
[0004] One approach to improving the performance properties of the
elastomer formed from the sealant composition is to increase the
amount of filler contained in the composition. However, increasing
the filler content of the sealant composition also increases the
viscosity of the composition, leading to difficulties in extrusion
from the packaging. There accordingly remains a need in the art for
a sealant composition having a viscosity that is sufficiently low
to enable extrusion of the composition, but which does not at the
same time limit the amount of filler that can be added to the
composition.
SUMMARY OF THE INVENTION
[0005] The present invention relates to a curable silicone sealant
composition comprising
[0006] a one-part, moisture-curable polysiloxane component
comprising a mixture or reaction product of (i) a polysiloxane
polymer having hydrolyzable substituent groups and (ii) a
polyfunctional silicon compound having two or more hydrolyzable
substituent groups,
[0007] a filler, and
[0008] a hydrocarbon fluid comprising, based on 100 parts by weight
of the hydrocarbon fluid, greater than 40 parts by weight cyclic
paraffinic hydrocarbons and less than 60 parts by weight noncyclic
paraffinic hydrocarbons.
[0009] The composition is readily extrudable, and yet upon cure,
exhibits improved tensile, elongation, and adhesive properties.
DETAILED DESCRIPTION OF THE INVENTION
[0010] In a preferred embodiment, the moisture-curable silicone
sealant comprises, based on 100 parts by weight ("pbw") of the
sealant composition, from 20 pbw to 90 pbw, more preferably from 30
pbw to 75 pbw, even more preferably from 40 pbw to 60 pbw, of the
moisture-curable organopolysiloxane polymer, from 1 pbw to 80 pbw,
more preferably from 2 pbw to 78 pbw, even more preferably from 3
pbw to 65 pbw, of the filler, and from 1 pbw to 50 pbw, more
preferably from 10 pbw to 40 pbw, even more preferably from 15 pbw
to 35 pbw, of the hydrocarbon fluid.
[0011] The moisture-curable polysiloxane component comprises a
mixture or reaction product of (i) a polysiloxane polymer having
hydrolyzable substituent groups and (ii) a polyfunctional silicon
compound having two or more hydrolyzable substituent groups.
Suitable functional polysiloxanes comprises one or more silicone
polymers or copolymers having structural units according to
structural formula (I):
R.sub.aSiO.sub.4-a/2 (I)
[0012] wherein each R is independently hydroxy, a hydrolyzable
organic group, or a monovalent hydrocarbon radical,
0.ltoreq.a.ltoreq.4, and at least one R group per molecule is
hydroxy or a hydrolyzable organic group, more preferably a hydroxy
group.
[0013] Suitable hydrolyzable organic groups are those organic
groups, for example, alkoxy, oximo, amino, aminoxy or acyloxy
groups, that are capable of reacting under room temperature
vulcanization conditions in the presence of moisture and a
condensation cure catalyst to thereby allow moisture curing of the
sealant composition.
[0014] Suitable monovalent hydrocarbon radicals include monovalent
acyclic hydrocarbon radicals, monovalent alicyclic hydrocarbon
radicals, and monovalent aromatic hydrocarbon radicals.
[0015] As used herein, the term "monovalent acyclic hydrocarbon
radical" means a monovalent straight or branched chain hydrocarbon
radical, preferably containing from 1 to 20 carbon atoms per
radical, which may be saturated or unsaturated and which may,
optionally, be substituted, for example with one or more halo
groups. Suitable monovalent acyclic hydrocarbon radicals include,
for example, alkyl radicals, for example, methyl, ethyl, sec-butyl,
tert-butyl, octyl, dodecyl, stearyl and eicosyl, haloalkyl, such as
trifluoropropyl, alkenyl radicals, for example, ethenyl and
propenyl, and alkynyl radicals, such as, for example, propynyl and
butynyl.
[0016] As used herein, the term "alicyclic hydrocarbon radical"
means a radical containing one or more saturated hydrocarbon rings,
preferably containing from 6 to 10 carbon atoms per ring, per
radical which may optionally be substituted on one or more of the
rings with one or more alkyl groups, each preferably containing
from 2 to 6 carbon atoms per group and which, in the case of two or
more rings, may be fused rings. Suitable monovalent alicyclic
hydrocarbon radicals include, for example, cyclohexyl and
cyclooctyl.
[0017] As used herein, the term "monocyclic aromatic hydrocarbon
radical" means a hydrocarbon radical containing one aromatic ring
per radical, which may optionally be substituted on the aromatic
ring with one or more alkyl groups, each preferably containing from
2 to 6 carbon atoms per group. Suitable monovalent aromatic
hydrocarbon radicals include, for example, phenyl, tolyl, xylyl,
2,4,6-trimethylphenyl, and naphthyl.
[0018] In one preferred embodiment, the organopolysiloxane polymer
comprises a mixture of two or more linear polymers or copolymers
having the structural formula (II): 1
[0019] wherein each R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5,
R.sup.6, R.sup.7, R.sup.8, R.sup.9, and R.sup.10 is independently a
hydrolyzable organic group or a monovalent hydrocarbon radical, at
least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6,
R.sup.7, R.sup.8, R.sup.9 and R.sup.10 per molecule is hydroxy, or
at least two of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5,
R.sup.6, R.sup.7, R.sup.8, R.sup.9 and R.sup.10 per molecule are
hydrolyzable organic groups, and x and y are each numbers selected
to provide a polymer that exhibits a viscosity of from 5,000 to
500,000 centiPoise ("cp") at 25.degree. C.
[0020] In a preferred embodiment, each R.sup.1, R.sup.3, R.sup.4,
R.sup.5, R.sup.6, R.sup.7, R.sup.8 and R.sup.9 is independently
(C.sub.1-C.sub.8)alkyl, fluoroalkyl or phenyl and each R.sup.2 and
R.sup.10 is hydroxyl, (C.sub.1-C.sub.8)alkyl, fluoroalkyl or
phenyl.
[0021] Suitable polyfunctional organosilicone compounds are those
that contain at least two hydrolyzable groups per molecule.
Suitable polyfunctional organosilicone compounds can be silanes or
partially hydrolyzed products of silanes and include, for example,
vinyltrimethoxysilane, tetramethoxysilane, methyltriethoxysilane,
tetraethoxysilane, methyltrimethoxysilane,
methylphenyldiethoxysilane, 3,3,3-trifluoropropyltrimethoxysilane,
methyl(tri(methylethylketoximo)sil- ane,
ethyl(tri(N,N-diethylamino)silane, methyltriacetoxysilane,
ethyltriacetoxysilane, methyltri(N-methylacetamido)silane,
n-propylorthosilicate and ethylpolysilicate, as well as dimers and
trimers of such compounds.
[0022] In a preferred embodiment, the polyfunctional organosilicone
compound has the structural formula (III):
R.sup.11.sub.4Si (III)
[0023] wherein each R.sup.11 is independently a hydrolyzable group
or a monovalent hydrocarbon radical, provided that at least one
R.sup.11 is H, alkoxy or alkenyl and that at least two R.sup.11
groups are hydrolyzable groups.
[0024] In one preferred embodiment, at least three R.sup.11
substituents are each alkoxy, oximo, amino, aminoxy or acyloxy,
more preferably alkoxy or acyloxy, even more preferably
(C.sub.1-C.sub.8)alkoxy or (C.sub.1-C.sub.8)acyloxy, and the
remaining R.sup.11 substituent, if any, is (C.sub.1-C.sub.8)alkyl,
(C.sub.2-C.sub.8)alkenyl, aryl or fluoroalkyl. Preferred
polyfunctional organosilicone compounds include, for example,
vinyltrimethoxysilane, tetramethoxysilane, methyltriethoxysilane,
methyltriacetoxysilane, ethyltriacetoxysilane, tetraethoxysilane,
methyltrimethoxysilane, di-t-butoxydiacetoxysilane, or mixtures
thereof.
[0025] The relative quantities of each of the silicone-containing
components is readily determined by one of ordinary skill in the
art. In general, the moisture curable organopolysiloxane polymer is
made by reaction of 100 pbw of the organopolysiloxane polymer with
from about 0.1 to about 15 pbw, more preferably from about 1.0 to
about 10 pbw, and most preferably from about 2 to about 7 pbw of
the polyfunctional organosilicone compound.
[0026] It is believed that at least some moisture curable
organopolysiloxane polymer is formed during compounding of the
composition of the present invention by in situ condensation
reaction of the organopolysiloxane polymer with the polyfunctional
organosilicone compound.
[0027] The composition may, optionally, further comprise a
condensation cure catalyst. Suitable condensation cure catalysts
are those that, in the presence of moisture, catalyze the room
temperature crosslinking of the crosslinkable organopolysiloxane
polymer and include, for example, dialkyltincarboxylates, such as,
for example, dibutyl tin dilaurate, dibutyl tin diacetate, and
tin-2-ethylhexanoate, alkyl titanates, such as for example,
tetrabutyl tin titanate, tetra-n-propyl titanate, and organosiloxy
titanium compounds. Various other condensation catalysts are known
in the art.
[0028] Where the polyfunctional organosilicone compound comprises
acyloxy substituent groups, the composition comprises, based on 100
pbw of the composition, from 0 to 1 pbw, more preferably from 0.01
to 0.5 pbw of a dialkyl tin carboxylate condensation cure
catalyst.
[0029] Where the polyfunctional organosilicone compound comprises
hydrolyzable organic groups other than acyloxy groups, the
composition comprises, based on 100 pbw of the composition, from
0.01 to 10 pbw, more preferably from 0.1 to 7 pbw and, even more
preferably, from 1 pbw to 5 pbw of an alkyl titanate or
organosiloxy titanium compound condensation cure catalyst.
[0030] Where the polyfunctional organosilicon compound comprises
hydrolyzable organic groups other than acyloxy groups, the
composition comprises, based on 100 pbw of the composition, from
0.01 to 5 pbw, preferably from 0.05 to 2 pbw, more preferably from
0.1 to 0.3 pbw of a dialkyl tin carboxylate condensation cure
catalyst.
[0031] The hydrocarbon fluid typically comprises one or more cyclic
hydrocarbons containing from 5 to 24 carbon atoms per molecule and,
optionally, one or more non-cyclic paraffinic hydrocarbons
containing from 5 to 24 carbon atoms per molecule. In a preferred
embodiment, the cyclic and non-cyclic hydrocarbons of the
hydrocarbon fluid each contain from 8 to 20, more preferably, from
10 to 15 carbon atoms per molecule. Suitable cyclic paraffinic
hydrocarbons include, for example, cyclohexane, cyclooctane,
cyclononane, cyclodecane, and cyclododecane. Suitable noncyclic
paraffinic hydrocarbons include, for example, n-heptane, n-hexane,
n-octane, iso-octane, n-nonane, n-decane, n-undecane, n-dodecane,
iso-dodecane, n-heptadecane, n-octadecane, n-eicosane, isoeicosane.
In a preferred embodiment, the hydrocarbon fluid comprises less
than about 0.5 percent by weight aromatic hydrocarbons.
[0032] In a preferred embodiment, the hydrocarbon fluid comprises,
based on 100 pbw of the hydrocarbon fluid, from about 42 pbw to 100
pbw, more preferably from about 45 pbw to 75 pbw, still more
preferably from about 50 pbw to 70 pbw, and even more preferably
from about 55 pbw to 65 pbw cyclic paraffinic hydrocarbons and from
0 pbw to about 58 pbw, more preferably from about 25 pbw to 55 pbw,
and still more preferably from about 30 pbw to 50 pbw and even more
preferably from about 30 pbw to 45 pbw noncyclic, that is, linear
or branched, paraffinic hydrocarbons. In a preferred embodiment,
the hydrocarbon fluid comprises less than 15, more preferably less
than 10 pbw normal, that is, linear paraffinic hydrocarbons.
[0033] The filler component is generally a reinforcing filler, a
semi-reinforcing filler, a non-reinforcing filler, or a mixture
thereof. Preferably, the filler is of the reinforcing type, for
example, fumed silica, hydrophobicized fumed silica, carbon black,
titanium dioxide, ferric oxide, aluminum oxide, as well as other
metal oxides. These fillers are commercially available from a
number of sources. Fumed silica is preferred. The curable, silicone
sealant composition may comprise, based on 100 parts by weight of
the sealant composition, from 1 pbw to 20 pbw, more preferably from
5 pbw to 15 pbw, of a reinforcing filler.
[0034] The filler used in the curable sealant composition may,
optionally, further comprise semi-reinforcing or non-reinforcing
fillers. Suitable semi-reinforcing or non-reinforcing fillers
include, for example, quartz, precipitated silica, hydrophobicized
precipitated silica, and calcium carbonate, which are commercially
available from a number of sources. In a preferred embodiment, the
semi-reinforcing or non-reinforcing filler comprises calcium
carbonate. When present, the silicone sealant composition
comprises, based on 100 parts by weight of the sealant composition,
from 0 pbw to 70 pbw, more preferably from 30 pbw to 60 pbw, even
more preferably from 40 pbw to 60 pbw, of a semi-reinforcing
filler, a non-reinforcing filler or a mixture thereof.
[0035] The curable silicone sealant composition may, optionally,
further comprise other known components, for example dyes,
pigments, anti-oxidants, UV stabilizers, adhesion-enhancing agents,
thermal stabilizing agents such as aluminum stearate, biocides,
non-silicone polymers, and thixotropic additives such as
polyethylene glycol or polypropylene glycol.
[0036] The curable sealant composition is made by combining and
mixing the various components of the composition. The mixing may be
conducted as a batch process or as a continuous process and any
convenient mixing apparatus, such as a planetary mixer, may be used
to mix the components. In a preferred embodiment, the composition
is made by continuously compounding the composition in an extruder,
preferably a twin screw extruder.
[0037] In use, the composition is exposed, for example by
extrusion, to ambient moisture, and allowed to cure. Preferably,
the composition is maintained in moisture-impervious packaging up
until the time of use. In a preferred embodiment, the composition
is used to seal a gap between a first substrate and a second
substrate, wherein the second substrate is spaced apart from the
first substrate to form a gap, by applying an amount of the
composition effective to bridge the gap and allowing the
composition to cure in place to form an elastomeric seal between
the substrates.
[0038] A further embodiment is an assembly, comprising a first
substrate, a second substrate spaced apart from the first
substrate, and a cured silicone sealant composition described above
disposed between the first and second substrates and bonded to each
of the substrates.
[0039] The invention is further illustrated by the following
non-limiting example.
EXAMPLE
[0040] The sealant composition of the Example was an acetoxy
sealant comprising 67.2 percent by weight ("wt %") of a
hydroxy-terminated poly(dimethylsiloxane) polymer, 20 wt % of a
hydrocarbon fluid, 9 wt % untreated fumed silica, 3.5 wt % of
catalyst solution and 0.3 wt % other additives. The catalyst
solution silane contained acetoxy-functional silane crosslinking
agents and a condensation cure catalyst. The hydrocarbon fluid
(Conosol.TM. C-200 hydrocarbon fluid) had a nominal composition of
about 60 wt % cycloparaffinic hydrocarbons, from 5 to 6 wt %
n-paraffinic hydrocarbons, with the remainder being iso-paraffinic
hydrocarbons, and exhibited an aromatic content of less than about
0.5 wt %. The sealant composition was tested for physical
properties after curing for 7 days at 75.degree. C. and 50%
relative humidity. The ASTM test methods used and test results are
listed in the Tables below.
1 Property ASTM test # Result Application rate C1183 400
(grams/minute) Tack free time C679 31 (minutes) Boeing flow D2202
0.1 (inches) Shore A hardness C661 23 Tensile strength D412 310
(pounds per square inch) % Elongation D412 517
[0041] Heat aged properties, 24 hr at 100.degree. C.
2 Property ASTM test # Result Shore A C661 23 Tensile strength D412
270 (pounds per square inch) % Elongation D412 516
Peel Adhesion Properties, ASTM C628
[0042]
3 Glass 26 (pounds pull) % Cohesive failure 97
Lap Shear Properties, ASTM E62
[0043]
4 Alclad Aluminum 120 (pounds pull) % Cohesive failure 98
[0044] As may be seen by reference to the above data, the curable
composition has excellent physical properties.
[0045] While preferred embodiments have been shown and described,
various modifications and substitutions may be made thereto without
departing from the spirit and scope of the invention. Accordingly,
it is to be understood that the present invention has been
described by way of illustration and not limitation.
* * * * *