U.S. patent number RE42,427 [Application Number 11/728,981] was granted by the patent office on 2011-06-07 for thermal transfer recording web roll.
This patent grant is currently assigned to Dai Nippon Printing Co., Ltd.. Invention is credited to Junichi Hiroi, Hiroaki Inoue, Tatsuya Kita, Hisaki Ota, Hitoshi Saito, Hiroshi Sugita, Shinichiro Takeda, Noboru Yamakawa.
United States Patent |
RE42,427 |
Yamakawa , et al. |
June 7, 2011 |
Thermal transfer recording web roll
Abstract
A coreless thermal transfer recording web roll 10 is formed by
rolling a thermal transfer recording web 10a in a roll. An inner
end part 11 of the thermal transfer recording web 10a of the
thermal transfer recording web roll 10 has a tab 11a formed at a
substantially middle of the inner end part 11, and sticking parts
11b formed on the opposite sides of the tab 11a, respectively.
Pseudoadhesive double-coated tapes 14 are attached to the sticking
parts 11b, respectively. The pseudoadhesive double-coated tapes
become tack-free after the sticking parts 11b have been separated
from the innermost layer of the thermal transfer recording web 10a
of the thermal transfer recording web roll 10.
Inventors: |
Yamakawa; Noboru (Tokyo-to,
JP), Saito; Hitoshi (Tokyo-to, JP), Ota;
Hisaki (Tokyo-to, JP), Inoue; Hiroaki (Tokyo-to,
JP), Hiroi; Junichi (Tokyo-to, JP), Kita;
Tatsuya (Tokyo-to, JP), Takeda; Shinichiro
(Tokyo-to, JP), Sugita; Hiroshi (Tokyo-to,
JP) |
Assignee: |
Dai Nippon Printing Co., Ltd.
(Shinjuku-Ku, JP)
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Family
ID: |
29717546 |
Appl.
No.: |
11/728,981 |
Filed: |
March 27, 2007 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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Reissue of: |
10464861 |
Jun 19, 2003 |
6894711 |
May 17, 2005 |
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Foreign Application Priority Data
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Jun 21, 2002 [JP] |
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2002-181961 |
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Current U.S.
Class: |
347/221 |
Current CPC
Class: |
B41J
33/02 (20130101); B41J 33/04 (20130101) |
Current International
Class: |
B41J
15/02 (20060101); B65H 75/28 (20060101); B65H
75/30 (20060101) |
Field of
Search: |
;347/221 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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0 405 363 |
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Jan 1991 |
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EP |
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405363 |
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Jan 1991 |
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EP |
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2001-139192 |
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May 2001 |
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JP |
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2001-139192 |
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May 2001 |
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JP |
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2001-261203 |
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Sep 2001 |
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JP |
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2001-261203 |
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Sep 2001 |
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JP |
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Other References
Computer-generated translation of JP 2001-261203, published on Sep.
26, 2001. cited by examiner .
Computer-generated translation of JP 2001-139192, published on May
22, 2001. cited by examiner .
Machine-generated translation of JP 2001-139192, published on May
22, 2001. cited by examiner.
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Primary Examiner: Tran; Huan H
Attorney, Agent or Firm: Burr & Brown
Claims
What is claimed is:
1. A thermal transfer recording web roll for use on a printer,
formed by winding a thermal transfer recording web having a base
web, and a recording layer formed on one of the surfaces of the
base web; wherein the thermal transfer recording web is wound in a
substantially cylindrical shape, a sticking part sticking to an
innermost layer of the thermal transfer recording web is formed in
an inner end part of the thermal transfer recording web, and the
outer surface of the inner end part of the thermal transfer
recording web is held by the inner surface of the innermost layer
of the thermal transfer recording web through the sticking part,
wherein the inner end part of the thermal transfer recording web is
provided with a tab for winding.
2. The thermal transfer recording web roll for a printer according
to claim 1, wherein the sticking part becomes tack-free after the
outer surface of the inner end part of the thermal transfer
recording web is separated from the inner surface, of the innermost
layer of the thermal transfer recording web.
3. The thermal transfer recording web roll for a printer according
to claim 1, wherein the sticking part has a pseudoadhesive property
that enables the sticking part to be separated from the innermost
layer of the thermal transfer recording web by a peeling force not
higher than a peeling force corresponding to a take-up torque
exerted by the printer.
4. The thermal transfer recording web roll for use on a printer
according to claim 3, wherein the sticking part includes a
pseudoadhesive .[.a.]. double-coated tape.
5. The thermal transfer recording web roll for use on a printer
according to claim 1, wherein the inner end part of the thermal
transfer recording web has the tab formed in a middle part thereof
with respect to the width, and a pair of sticking parts
respectively on the .[.Opposite.]. .Iadd.opposite .Iaddend.sides of
the tab.
6. The thermal transfer recording web roll for use on a printer
according to claim 5, wherein the tab and the sticking parts.[.,.].
are demarcated by slits, respectively.
7. The thermal transfer recording web roll for use on a printer
according to claim 1, wherein the tab projects in a winding
direction of the thermal transfer recording web relative to the
sticking part.
8. The thermal transfer recording web roll for use on a printer
according to claim 7, wherein the tab has a rectangular projection
projecting from a middle part of the inner end of the thermal
transfer recording web.
9. The thermal transfer recording web roll for use on a printer
according to claim 7, wherein the tab has a triangular projection
projecting from a middle part of the inner end of the thermal
transfer recording web.
10. The thermal transfer recording web roll for use on a printer
according to claim 1, wherein an adhesive layer is formed on the
other surface of the base web, and a release tape is applied to the
adhesive layer.
11. The thermal transfer recording web roll for use on a printer
according to claim 1, wherein a noncontact IC tag is attached to a
part of the thermal transfer recording web near the inner end part
of the thermal transfer recording web.
12. The thermal transfer recording web roll for use on a printer
according to claim 1, wherein adhesive strength of the sticking
part between the innermost layer of the thermal transfer recording
web and the inner end part of the thermal transfer recording web is
higher than a peeling force corresponding to a take-up torque
exerted by the printer.
.Iadd.13. A thermal transfer recording web roll for use on a
printer, formed by winding a thermal transfer recording web having
a base web, and a recording layer formed on one of the surfaces of
the base web; wherein the thermal transfer recording web is wound
in a substantially cylindrical shape, a sticking part sticking to
an innermost layer of the thermal transfer recording web is formed
in an inner end part of the thermal transfer recording web, the
outer surface of the inner end part of the thermal transfer
recording web is held by the inner surface of the innermost layer
of the thermal transfer recording web through the sticking part,
and an end indicating hole or an end indicating mark is formed at
an upstream part of the sticking portion of the innermost layer for
indicating the inner end part of the thermal transfer recording
web..Iaddend.
.Iadd.14. The thermal transfer recording web roll for use on a
printer according to claim 13, wherein the sticking part becomes
tack-free after the outer surface of the inner end part of the
thermal transfer recording web is separated from the inner surface
of the innermost layer of the thermal transfer recording
web..Iaddend.
.Iadd.15. The thermal transfer recording web roll for use on a
printer according to claim 13, wherein the sticking part has a
pseudoadhesive property that enables the sticking part to be
separated from the innermost layer of the thermal transfer
recording web by a peeling force not higher than a peeling force
corresponding to take-up torque exerted by the
printer..Iaddend.
.Iadd.16. The thermal transfer recording web roll for use on a
printer according to claim 15, wherein the sticking part includes
pseudoadhesive double-coated tape..Iaddend.
.Iadd.17. The thermal transfer recording web roll for use on a
printer according to claim 13, wherein the inner end part of the
thermal transfer recording web is provided with a tab for
winding..Iaddend.
.Iadd.18. The thermal transfer recording web roll for use on a
printer according to claim 17, wherein the inner end part of the
thermal transfer recording web has the tab formed in a middle part
thereof with respect to the width, and further comprising a pair of
sticking parts respectively on the opposite sides of the
tab..Iaddend.
.Iadd.19. The thermal transfer recording web roll for use on a
printer according to claim 18, wherein the tab and the sticking
parts are demarcated by slits, respectively..Iaddend.
.Iadd.20. The thermal transfer recording web roll for use on a
printer according to claim 17, wherein the tab projects in a
winding direction of the thermal transfer recording web relative to
the sticking part..Iaddend.
.Iadd.21. The thermal transfer recording web roll for use on a
printer according to claim 20, wherein the tab has a rectangular
projection projecting from a middle part of the inner end of the
thermal transfer recording web..Iaddend.
.Iadd.22. The thermal transfer recording web roll for use on a
printer according to claim 20, wherein the tab has a triangular
projection projecting from a middle part of the inner end of the
thermal transfer recording web..Iaddend.
.Iadd.23. The thermal transfer recording web roll for use on a
printer according to claim 13, wherein an adhesive layer is formed
on the other surface of the base web, and a release tape is applied
to the adhesive layer..Iaddend.
.Iadd.24. The thermal transfer recording web roll for use on a
printer according to claim 13, wherein a noncontact IC tag is
attached to a part of the thermal transfer recording web near the
inner end part of the thermal transfer recording web..Iaddend.
.Iadd.25. The thermal transfer recording web roll for use on a
printer according to claim 13, wherein adhesive strength of the
sticking part between the innermost layer of the thermal transfer
recording web and the inner end part of the thermal transfer
recording web is higher than a peeling force corresponding to a
take-up torque exerted by the printer..Iaddend.
Description
TECHNICAL FIELD
The present invention relates to a thermal transfer recording web
roll to be used on a thermal transfer printer.
BACKGROUND ART
There are a variety of thermal transfer methods using thermal
transfer sheets made by forming color transfer layers on base
sheets. The color transfer layers of the thermal transfer sheets
are heated from behind the thermal transfer sheets with a thermal
head or the like in patterns for yellow, magenta and cyan images of
characters, figures or patterns, respectively, and the patterned
yellow, magenta and cyan layers are transferred to the surface of a
transfer recording medium. Thermal transfer methods are classified
roughly by the type of the color transfer layers into those of the
sublimation transfer system and those of the melt transfer system.
The thermal transfer method of the sublimation transfer system uses
thermal transfer sheets made by forming color transfer layers each
of a binder containing a dye that sublimates or shifts when heated
on base sheets, heats the thermal transfer sheets from behind to
make the dyes contained in the color transfer layers transfer from
the thermal transfer sheets to a recording medium. The surface of
the recording medium is coated with a recording layer that can
easily be dyed.
The thermal transfer method of the melt transfer system uses
thermal transfer sheets made by forming color transfer layers that
soften, melt and become transferable when heated on base sheets,
heats the thermal transfer sheets from behind to transfer the color
transfer layers to the surface of a recording medium. Both the
thermal transfer methods of the sublimation transfer system and
those of the melt transfer system are capable of forming
monochromatic images and multicolor images. In forming a multicolor
image, the thermal transfer method uses three or four color thermal
transfer sheets for, for example, yellow, magenta and cyan images
or, when necessary, yellow, magenta, cyan and black images, and
thermally transfers the color images of those colors to a recording
medium to form color images.
The thermal transfer method holds a plurality of thermal transfer
recording sheets in a stack and feeds the thermal transfer
recording sheets to a printer or uses a thermal transfer recording
web roll and feeds the thermal transfer recording web to a
printer.
Recently, the thermal transfer method is used for the thermal
transfer recording of a large amount of prints, and thermal
transfer recording web rolls are used. The thermal transfer
recording web roll, in general, is formed by winding a thermal
transfer recording web around a feed core (bobbin). The leading
edge of the recording web wound around the feed core is attached
adhesively to a take-up core and is taken upon the take-up core
after the completion of thermal transfer recording or the recording
web is cut in a sheet after the completion of thermal transfer
recording and the printed recording sheet is delivered.
The aforesaid conventional thermal transfer recording web roll has
the following problems.
(1) The conventional thermal transfer recording web roll needs a
feed core formed in a high dimensional accuracy to roll the thermal
transfer recording web uniformly around the feed core without
creasing the thermal transfer recording web. Thus, the feed core is
inevitably costly.
A feed core of a reduced cost may be a paper tube formed mainly of
paper pulp instead of a plastic material. The paper tube is brought
into contact with a driving member of a printer to rotate the
thermal transfer recording web roll on the printer. Paper powder is
produced due to the abrasion of the paper tube by the driving
member in rotating the thermal transfer recording web roll, the
paper powder scatters in the printer and, consequently, pinholes
are formed in prints formed by thermal transfer printing
deteriorating image quality.
(2) The core is mere waste after the thermal transfer recording web
held thereon has been used up. Since the cylindrical core is bulky
for its weight, the core cannot efficiently be carried for waste
disposal. The core is not recycled and thrown away, which is
against demand for waste reduction to avoid environmental
problems.
(3) It takes time and requires troublesome work to store cores, to
set a core on a take-up machine for taking up a thermal transfer
recording web and to wind a thermal transfer recording web around
the core.
(4) An end part of a thermal transfer recording web cannot
correctly attached to a desired part of a core in attaching the end
part to the core with an adhesive tape, an adhesive double-coated
tape or a paste. The thermal transfer recording web meanders while
the same is being wound round the core and, consequently, the width
of a thermal transfer recording web roll formed on the core is
somewhat greater than that of the thermal transfer recording web.
Since the thermal transfer recording web is wound under a specified
tension and a specified pressure around a hard, cylindrical core,
the position of the thermal transfer recording web roll formed on
the core cannot be adjusted relative to the core. Therefore, the
core must have a length greater than the width of the thermal
transfer sheet taking into consideration the attachment of the end
part of the thermal transfer recording web to an incorrect part of
the core, and the formation of a thermal transfer recording web
roll having a width greater than the width of the thermal transfer
recording web. Thus, the thermal transfer recording web roll formed
by winding a thermal transfer recording web around a core is
inevitably large.
Sometimes, the thermal transfer recording web roll is deformed when
shocks act on the thermal transfer recording web roll when the
thermal transfer recording web roll is dropped or handled
improperly in carrying the thermal transfer recording web roll or
loading the thermal transfer recording web roll into a printer. It
is difficult to straighten the deformed, hard thermal transfer
recording web roll.
The incorrect winding of the thermal transfer recording web around
the core and the deformation of the thermal transfer recording web
roll while the thermal transfer recording web roll is handled
affect adversely to the accuracy of print position on the thermal
transfer recording web.
(5) Flaws corresponding to steps including an end part of the
thermal transfer recording web attached to the core and an end
detection hole formed in the thermal transfer recording web are
formed in the thermal transfer recording web roll due to pressure
and tension that act on the thermal transfer recording web, and the
flaws become apparent in different densities of prints. FIG. 10 is
a view of assistance in explaining the formation of flaws in a
thermal transfer recording web 10a. In FIG. 10 flaws 3 due to an
end indicating hole 2 and an end part of the thermal transfer
recording web attached to a core 1. Sometimes, the hardness of the
thermal transfer recording web roll is reduced by adjusting winding
tension and winding pressure to prevent the foregoing problem due
to the adverse effect of the end part of the thermal transfer
recording web attached to the core and the end detecting hole on
prints, which, however, could not achieve a desired effect.
DISCLOSURE OF THE INVENTION
It is an object of the present invention to provide a thermal
transfer recording web roll to be used on a thermal transfer
printer, capable of being produced at a low cost without requiring
much time and labor and of producing prints having a high print
quality by thermal transfer printing.
According to the present invention, a thermal transfer recording
web roll for use on a printer, formed by winding a thermal transfer
recording web having a base web, and a recording layer formed on
one of the surfaces of the base web; wherein the thermal transfer
recording web is wound in a substantially cylindrical shape, a
sticking part sticking to an innermost layer of the thermal
transfer recording web is formed in an inner end part of the
thermal transfer recording web, and the outer surface of the inner
end part of the thermal transfer recording web is held by the inner
surface of the innermost layer of the thermal transfer recording
web through the sticking part.
The thermal transfer recording web roll according to the present
invention for use on a printer, the sticking part may become
tack-free after the outer surface of the inner end part of the
thermal transfer recording web is separated from the inner surface
of the innermost layer of the thermal transfer recording web.
The thermal transfer recording web roll according to the present
invention for use on a printer, the sticking parts may have a
pseudoadhesive property that enables the sticking parts to be
separated from the innermost layer of the thermal transfer
recording web by a peeling force not higher than a peeling force
corresponding to a take-up torque exerted by the printer.
The thermal transfer recording web roll according to the present
invention for use on a printer, the sticking part may include
pseudoadhesive a double-coated tape.
The thermal transfer recording web roll according to the present
invention for use on a printer, the inner end part of the thermal
transfer recording web may be provided with a tab for winding.
The thermal transfer recording web roll according to the present
invention for use on a printer, the inner end part of the thermal
transfer recording web may have the tab formed in a middle part
thereof with respect to the width, and a pair of sticking parts
respectively on the opposite sides of the tab.
The thermal transfer recording web roll according to the present
invention, the tab and the sticking parts may be demarcated by
slits, respectively.
The thermal transfer recording web roll according to the present
invention, the tab may project in a winding direction of the
thermal transfer recording web relative to the sticking parts.
The thermal transfer recording web roll according to the present
invention, the tab may have a rectangular projection projecting
from a middle part of the inner end of the thermal transfer
recording web.
The thermal transfer recording web roll according to the present
invention, the tab may have a triangular projection projecting from
a middle part of the inner end of the thermal transfer recording
web.
The thermal transfer recording web roll according to the present
invention, an adhesive layer may be formed on the other surface of
the base web, and a release tape is applied to the adhesive
layer.
The thermal transfer recording web roll according to the present
invention, a noncontact IC tag may be attached to a part of the
thermal transfer recording web near the inner end part of the
thermal transfer recording web.
The thermal transfer recording web roll according to the present
invention, adhesive strength of the sticking part between the
innermost layer of the thermal transfer recording web and the inner
end part of the thermal transfer recording web is higher than a
peeling force corresponding to a take-up torque exerted by the
printer.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a perspective view of a thermal transfer recording web
roll in a first embodiment according to the present invention in an
unused state;
FIG. 2 is a plan view of an inner end part of a thermal transfer
recording web unwound from the thermal transfer recording web roll
shown in FIG. 1;
FIG. 3 is a perspective view of an innermost layer of a thermal
transfer recording web;
FIG. 4 is a view of assistance in explaining an effect of
preventing the deformation of a thermal transfer recording web
roll;
FIG. 5 is a view of assistance in explaining an effect of
preventing the deformation of a thermal transfer recording web
roll;
FIG. 6 is a view of assistance in explaining the effect of a
sticking part;
FIG. 7 is a view of assistance in explaining the relation between
an end detecting method of detecting an end part to be carried out
by a printer, and an inner end part attaching method;
FIG. 8 is an end view of a thermal transfer recording web roll in a
second embodiment according to the present invention;
FIG. 9 is a view of thermal transfer recording webs in
modifications; and
FIG. 10 is a view showing flaws formed in an inner end part of a
thermal transfer recording web forming a conventional thermal
transfer recording web roll.
BEST MODE FOR CARRYING OUT THE INVENTION
Preferred embodiments of the present invention will be described
with reference to the accompanying drawings.
First Embodiment
FIG. 1(A) shows an unused thermal transfer recording web roll in a
first embodiment according to the present invention, and FIG. 1(B)
is a sectional view of a thermal transfer recording web 10a.
A thermal transfer recording web roll 10 in the first embodiment is
formed by rolling the thermal transfer recording web 10a, and has
an inner end part 11, an outer end part 12 and a fastening tape
13.
As shown in FIG. 1(B), the thermal transfer recording web 10a has a
base web 30, an intermediate layer 31 formed on one of the surfaces
of the base web 30, and a recording layer 32 formed on a surface of
the intermediate layer 31.
Base Web
Preferably, the base web 30 has a mechanical strength sufficient
for preventing troubles in handling because the base web 30 holds
the recording layer 32 thereon and is heated in transferring an
image thereto by thermal transfer. There are not any particular
restrictions on the material forming the base web 30. The base web
30 may be formed of cellulose paper, such as condenser paper,
glassine paper, parchment paper, paper having a high degree of
sizing, synthetic paper (polyolefin paper and polystyrene paper),
wood-free paper, art paper, cast coated paper, wallpaper, lining
paper, paper impregnated with a synthetic resin of an emulsion,
paper impregnated with synthetic rubber latex, cardboard, may be
formed of a film of one of polyester resins, polyacrylate resins,
polycarbonate resins, polyurethane resins, polyimide resins,
polyether imide resins, cellulose derivatives, polyethylene resins,
ethylene-vinyl acetate copolymers, polypropylene resins,
polystyrene resins, acrylic resins, polyvinyl chloride resins,
polyvinylidene chloride resins, polyvinyl alcohol resins, polyvinyl
butyral resins, nylons, polyether ether ketone resins, polysulfone
resins, polyether sulfone resins, tetrafluoroethylene
perfluoroalkylvinyl ether resins, polyvinyl fluoride resins,
tetrafluoroethylene ethylene resins, tetrafluoroethylene
hexafluoropropylene resins, polychlorotrifluoroethylene resins, and
polyvinylidene fluoride resins. The base web 30 may be a white,
opaque film of a material prepared by mixing one of the foregoing
synthetic resins and a white pigment or filler or may be a foam
web.
The base web 30 may be a laminate formed by laminating webs of the
foregoing materials. A typical laminate may be a synthetic paper
sheet formed by laminating a cellulose paper sheet and a synthetic
paper sheet, or a synthetic paper sheet formed by laminating a
cellulose paper sheet and a plastic film. The thickness of the base
web 30 is optional. Usually, the thickness of the base web 30 is in
the range of about 10 to about 300 .mu.m. If the adhesion between
the base web 30 and the intermediate layer 31 is insufficient, it
is preferable to coat the surface of the base web 30 with a primer
to finish the surface of the base web 30 by a corona discharge
treatment.
Intermediate Layer
The intermediate layer 31 is formed on the base web 30 mainly for
coloring the recording surface and opacification to conceal the
base web 30. A material forming the intermediate layer 31 contains
two or more kinds of dyes, a white pigment, necessary additives and
a resin as a binder. Resins suitable for forming the intermediate
layer 31 are, for example, thermoplastic resins, such as
polyurethane resins, acrylic resins, polyester resins and
polycarbonate resins, and thermosetting resins, such as resins
obtained through the partial crosslinking of the aforesaid resins,
crosslinked polyurethane resins, epoxy resins, melamine resins and
urea resins.
The white pigment may be an inorganic pigment, such as titanium
oxide, zinc oxide, barium sulfate or alumina white, an extender
pigment, such as kaolin clay, silica, magnesium carbonate or
calcium carbonate, or a mixture of some of those pigments.
The intermediate layer 31 is formed by an intermediate layer
forming method including the steps of preparing a coating liquid by
dissolving or dispersing the aforesaid resin, at least two kinds of
dyes, a white pigment and, when necessary, additives in a suitable
organic solvent, such as ethyl acetate, methyl ethyl ketone,
toluene, xylene or cyclohexanone, coating at least one of the
surfaces of the base web 30 with a coating layer of the coating
liquid by a coating means, such as a gravure coating process, a
screen printing process or a reverse-roll coating process using a
gravure plate, drying the coating layer and, when necessary,
subjecting the coating layer to a crosslinking process. The
intermediate layer 31 thus formed has a solid basis weight in the
range of about 0.5 to 10 g/m.sup.2, more preferably, in the range
of 1 to 6 g/m.sup.2. An excessively thin intermediate layer is
unable to exhibit a desired effect. The effect of an intermediate
layer does not enhance beyond a certain level even if the thickness
thereof is increased excessively, and an excessively thick
intermediate layer reduces print sensitivity.
Recording Layer
The recording layer 32 formed on the intermediate layer 31 formed
on the base web 30 receives when heated a dye transferred from a
thermal transfer sheet and records an image formed thereon.
Materials suitable for forming the recording layer 32 are
polyolefin resins, such as polypropylene resins, halogenated
polymers, such as polyvinyl chloride resins and polyvinylidene
chloride resins, vinyl resins, such as polyvinyl acetate resins,
ethylene-vinyl acetate copolymers, vinyl chloride-acetate
copolymers and polyacrylate resins, acetal resins, such as
polyvinyl formal resins, polyvinyl butyral resins and polyvinyl
acetal resins, saturated and unsaturated polyester resins,
polycarbonate resins, cellulose resins, such as cellulose acetate
resins, styrene resins, such as polystyrene resins, acryl-styrene
copolymers and acrylonitril-styrene copolymers, urea resins,
melamine resins, and polyamide resins, such as benzoguanamine
resins. The recording layer 32 may be formed of a compatible blend
of some of the foregoing resins.
When the binder contained in the intermediate layer 31 is a resin
having active hydrogen in hydroxyl groups or carboxyl groups,
addition of a curing agent that react with active hydrogen in the
recording layer 32 enhances the adhesion between the intermediate
layer 31 and the recording layer 32. Preferable curing agents for
such a purpose are isocyanate compounds, amino compounds, and
organometallic compounds. Catalysts respectively suitable for use
in combination with those curing agents may be used to increase the
reaction rates of the curing agent. It is preferable that the least
necessary amount of curing agent is added to the material forming
the recording layer 32 in order to adhere to the intermediate layer
31.
In some cases, the resin contained in the recording layer 32 fuses
with a dye binder holding a dye during the thermal transfer image
recording. Therefore, it is preferable that the recording layer 32
contains a lubricant, such as a phosphate, a surface-active agent,
a fluorine compound, a fluorine resin, a silicon compound, a
silicone oil or a silicone resin, to provide the recording layer 32
with a satisfactory release characteristic. It is particularly
preferable to add a modified silicone oil to and to cure the
recording layer 32. Although the lubricant content is dependent on
the type of the lubricant, it is preferable that the lubricant
content is the least possible value that is sufficient for the
lubricant to satisfactorily exercise its effect in the range of 1
to 20 parts by weight on the solid bases. When a modified silicone
oil having reactive groups capable of reacting with the curing
agent is added to the recording layer 32, it is preferable that the
ratio of the equivalent weight of the reactive groups of the
modified silicone oil to that of the reactive groups of the curing
agent is in the range of 1:1 to 1:10. A releasing layer, i.e., a
layer of the aforesaid lubricant or a layer of a mixture of the
binder and the aforesaid lubricant, may be formed on the recording
layer instead of adding the lubricant to the recording layer.
The recording layer 32 is formed by applying a coating liquid
prepared by dissolving or dispersing a mixture of a resin and
necessary additives in an organic solvent to the intermediate layer
31 by a coating process, such as a gravure printing process, a
screen printing process or a reverse-roll coating process using a
gravure plate, in a coating layer and drying the coating layer.
Although the recording layer may have any thickness, the thickness
of the recording layer, in general, is in the range of 1 to 50
.mu.m.
Slip Layer
A slip layer 33 may be formed on the back surface of the base web
30 of the thermal transfer recording web 10a to improve the
facility of mechanical carrying of the thermal transfer recording
web 10a and to prevent the curling of the thermal transfer
recording web 10a. It is preferable to add a proper amount of an
organic or inorganic filler to the binder or to use a resin having
a high lubricity, such as a polyolefin resin or a cellulose resin,
as the binder. The slip layer 33 may be formed of a mixture
prepared by adding as additives, an organic filler, such as an
acrylic filler, a nylon filler, a Teflon.RTM. filler or a
polyethylene wax, and an inorganic filler, such as silicon dioxide
or a metal oxide, to a resin, such as an acrylic resin, a cellulose
resin, a polycarbonate resin, a polyvinyl acetal resin, a polyvinyl
alcohol resin, a polyamide resin, a polystyrene resin, a polyester
resin or a halogenated polymer. An acrylic resin is preferable and
an acrylpolyol is most preferable. It is preferable to use a resin
obtained by curing an acrylpolyol with a curing agent.
The slip layer 33 is formed by applying a coating liquid prepared
by thoroughly kneading a mixture prepared by mixing the aforesaid
resin, a filler, a solvent and a diluent to the back surface of the
base web 30 by a coating process, such as a gravure printing
process, a screen printing process or a reverse-roll coating
process using a gravure plate, in a coating layer and drying the
coating layer. Although the slip layer 33 may have any thickness,
the thickness of the slip layer 33, in general, is in the range of
1 to 10 .mu.m
Adhesive Layer
An adhesive layer 34 of an adhesive resin, such as an acrylate
resin, a polyurethane resin or a polyester resin, may be formed on
the surface and/or the back surface of the base web 30. The
adhesive layer 34 is formed by applying a coating liquid containing
the aforesaid resin to the surface and/or the back surface of the
base web 30 by a coating process, such as a gravure printing
process, a screen printing process or a reverse-roll coating
process using a gravure plate, in a coating layer and drying the
coating layer. The surface and/or the back surface of the base web
30 may be processed by a corona discharge process instead of
coating the surface and/or the back surface of the base web 30 with
the coating layer to enhance adhesion between the base web 30 and
the layer formed on the former.
Antistatic Layer
An antistatic layer 35 may be formed on at least one of the
outermost surfaces of the thermal transfer recording web 10a. The
antistatic layer 35 is formed by spreading a coating liquid
prepared by dissolving or dispersing a fatty ester, a sulfate, a
phosphate, an amide, a quaternary ammonium salt, betaine, an amino
acid or an ethylene oxide addition product in a solvent. The
antistatic layer 35 may be formed by spreading a conductive resin
produced by introducing a group having an antistatic effect, such
as a quaternary ammonium salt, a phosphate, an ethosulfate, a vinyl
pyrrolidone or sulfonic acid, into an acrylic resin, a vinyl resin
or a cellulose resin or an antistatic resin produced through the
copolymerization of such an antistatic group and such a resin.
Preferably, the basis weight of the antistatic layer 35 is in the
range of 0.001 to 0.1 g/m.sup.2. The antistatic layer 35 may be
formed by a spraying process or a transfer process instead of a
coating process. The thermal transfer recording web 10a provided
with the antistatic layer 35 has an excellent antistatic property
and is capable of preventing double-sheet feeding.
The inner end part 11 of the rolled thermal transfer recording web
10a has a tab 11a and sticking parts 11b.
FIG. 2 shows the inner end part 11 of the thermal transfer
recording web 10a unwound from the thermal transfer recording web
roll 10.
A winding machine used in a manufacturing process catches the
thermal transfer recording web 10a by the tab 11a in winding the
thermal transfer recording web 10a in the thermal transfer
recording web roll 10. The inner end part 11 is cut into three
parts by slits 11c. The tab 11a is the middle one of those three
parts.
The two parts on the opposite sides, with respect to the width, of
the tab 11a are the sticking parts 11b. Pseudoadhesive
double-coated tapes 14 are attached to the back surfaces (outer
surfaces) of the sticking parts 11b. The pseudoadhesive
double-coated tapes 14 stick to the innermost layer, i.e., the
first layer, of the thermal transfer recording web roll 10 formed
by rolling the thermal transfer recording web 10a. The sticking
parts 11b provided with the pseudoadhesive double-coated tapes 14
loose their sticking property after the sticking parts 11b have
been separated from the inner surface of the innermost layer of the
thermal transfer recording web 10a.
The outer end part 12 is fastened temporarily to the thermal
transfer recording web 10a with a fastening tape 13 to prevent the
thermal transfer recording web roll 10 from coming loose.
FIG. 3 shows the innermost layer formed by rolling the thermal
transfer recording web 10a.
The sticking parts 11b of the inner end part 11 of the thermal
transfer recording web 10a stick. Thus, the inner end part 11 is
held in place on the innermost layer as shown in FIG. 3 without
using any core.
Since the winding machine grips the tab 11a in winding the thermal
transfer recording web 10a, the tab ha is curved permanently
radially inward as shown in FIGS. 1 and 3. If the inner end part 11
is entirely a sticking part, the inner end part 11 extends radially
inward and interferes with a mounting shaft 5a included in a
printer 5 in loading the thermal transfer recording web roll 10
into the printer 5, which makes a loading operation difficult and
cause faulty loading.
In this embodiment, the tab 11a is at the middle, with respect to
the width, of the inner end part 11 of the thermal transfer
recording web 10a, and the sticking parts 11b extend in a circular
shape conforming to the innermost layer. Therefore, the tab 11a
will not obstruct the insertion of the mounting shaft 5a of the
printer 5 into the thermal transfer recording web roll 10. Thus,
the thermal transfer recording web roll 10 can easily and correctly
loaded into the printer 5.
FIGS. 4 and 5 are views of assistance in explaining an effect of
preventing the deformation of the thermal transfer recording web
roll 10.
A thermal transfer recording web roll provided with a core 1 is
formed by winding a thermal transfer recording web around the hard
cylindrical core 1 under a specified tension and a specified
pressure around a hard, cylindrical core 1, and therefore the
position of the thermal transfer recording web roll formed on the
core cannot be adjusted relative to the core 1. Although the
thermal transfer recording web roll 10 in the first embodiment is
easily deformable because the thermal transfer recording web roll
10 in the first embodiment, which is a coreless thermal transfer
recording web roll, is formed by winding the thermal transfer
recording web 10a under low pressure and low tension, the shape of
the thermal transfer recording web roll 10 can easily be corrected,
there is no problem in the position of the thermal transfer
recording web roll 10 relative to a core, and hence the thermal
transfer recording web roll 10 is easy to use and handle.
FIG. 6 is a view of assistance in explaining the effect of the
sticking parts 11b of the thermal transfer recording web 10a.
If the inner end part 11 of the thermal transfer recording web roll
10 is not provided any parts corresponding to the sticking parts
11b and the thermal transfer recording web roll 10 is used on the
printer 5, the thermal transfer recording web 10 loosens and the
diameter of the thermal transfer recording web roll 10 increases at
a stage immediately before the thermal transfer recording web 10 is
used up. Consequently, the thermal transfer recording web 10a comes
into contact with the inner surfaces of walls of the printer 5 in
the vicinity of the thermal transfer recording web roll 10, the
thermal transfer recording web 10a is rubbed with the walls and
scraps and fragments of the thermal transfer recording web 10a
adhere to the inner surfaces of the walls of the printer 5. Dyes
cannot be printed on thus flawed or scratched parts of the thermal
transfer recording web 10a and on parts of the recording layer 32
covered with the scraps and fragments of the thermal transfer
recording web 10a scattered in the printer 5, and the printing
ribbon cannot normally be separated form those parts of the thermal
transfer recording web 10a.
If the inner end part 11 of the thermal transfer recording web roll
10 is not provided any parts corresponding to the sticking parts
11b, the thermal transfer recording web 10a needs to be wound in
several turns to hold the thermal transfer recording web roll 10 in
its shape. When flanges 5b included in the printer 5 are pressed
against the opposite ends of the thermal transfer recording web
roll 10 to hold the thermal transfer recording web roll 10 in
place, the thermal transfer recording web roll 10 cannot be held
when the thermal transfer recording web 10a is wound in one
layer.
Since the inner end part 11 of the thermal transfer recording web
roll 10 in this embodiment is provided with the sticking parts 11b,
the flanges 5b of the printer 5 are able to hold the thermal
transfer recording web roll 10 between the flanges 5b even if the
thermal transfer recording web roll 10 has only one layer.
Although the pseudoadhesive double-coated tapes 14 are attached to
the sticking parts 11b in this embodiment, an optimum method of
attaching the sticking parts 11b to the inner surface of the
innermost layer must selectively be determined taking into
consideration an end detecting method by which the printer detects
the end of the thermal transfer recording web 10a of the thermal
transfer recording web roll 10.
FIG. 7 is a view of assistance in explaining the relation between
an end detecting method of detecting an end part to be carried out
by the printer, and an attaching method of attaching the inner end
part of the thermal transfer recording web 10a to the innermost
layer of the thermal transfer recording web roll 10.
When the printer 5 is provided with a sensor that detects light
passed through an end indicating hole 2 formed in the thermal
transfer recording web 10a or light reflected from an end
indicating mark 2a marked on the thermal transfer recording web 10a
of the thermal transfer recording web roll 10, a thermal transfer
recording web feed mechanism included in the printer 5 stops when
the sensor detects the light passed through the end indicating hole
2 or the light reflected from the end indicating mark 2a.
Therefore, the sticking parts 11b may be of any shape provided that
the sticking parts 11b are attached to the innermost layer (FIGS.
7(A) and 7(B)).
When the thermal transfer recording web 10a of the thermal transfer
recording web roll 10 is provided with neither any hole
corresponding to the end indicating hole 2 nor any mark
corresponding to the end indicating mark 2a, and the printer 5
detects a change in the torque acting on the thermal transfer
recording web feed mechanism, the shape of the sticking parts 11b
must selectively be determined so that the printer 5 is able to
detect the change in the torque (FIGS. 7(C) and 7(D)).
When the approach of the end is indicated by the duration of a
maximum take-up torque for a predetermined time, the sticking parts
11b may be attached to the innermost layer with adhesive means
capable of sticking to the innermost layer, such as adhesive
double-coated tapes 14a, adhesive tapes or an adhesive (FIG. 7(E)).
The adhesive strength bonding the sticking parts 11b to the
innermost layer must withstand the peeling effect of a take-up
torque applied to the thermal transfer recording web roll 10 by the
printer 5.
When the approach of the end is indicated by the reduction of the
take-up torque to naught, the printer stops upon the separation of
the sticking parts 11b from the innermost layer. Therefore, the
sticking surfaces of the sticking parts 11b must become tack-free
(nonadhesive) after the sticking parts 11b have been separated from
the innermost layer. The bond strength between the sticking parts
11b and the innermost layer should not be excessively high, and the
sticking parts 11b must be separated from the innermost layer when
a torque not higher than the take-up torque and not lower than a
predetermined level acts on the thermal transfer recording web roll
10. Therefore, it is preferable to use the pseudoadhesive
double-coated tapes 14 (FIG. 7(F)).
The thermal transfer recording web 10a of the thermal transfer
recording web roll 10 in this embodiment is provided with the end
indicating hole 2 as shown in FIG. 3 and is intended to be used on
a printer 5 that detects the end indicating hole. However, since
the sticking parts 11b are attached to the innermost layer with the
pseudoadhesive double-coated tapes 14, the thermal transfer
recording web roll 10 can be used on a printer 5 that detects
neither an end indicating hole nor an end indicating mark and
decides that the thermal transfer recording web 10a is
substantially used up when the take-up torque decreases to a
naught.
The pseudoadhesive double-coated tape 14 will be explained.
The pseudoadhesive double-coated tape 14 has either of the
following two forms.
(1) Release tape/Adhesive layer/Nonwoven or paper tape/Resin
layer/Plastic base/Adhesive layer/Release tape
(2) Release tape/Adhesive layer/Plastic base/Resin layer/Plastic
base/Adhesive layer/Release tape
In forming the pseudoadhesive double-coated tape of the form (1), a
molten resin is extruded through a T-die or the like on a nonwoven
tape (or a plastic base) to form a resin layer, and the nonwoven
tape (or the plastic base) is laminated to a plastic base (or a
nonwoven tape), an adhesive layer is formed on the surface of the
nonwoven tape (or the plastic base), an adhesive layer is formed on
the surface of the plastic base (or the nonwoven tape), and then
release tapes are applied to the adhesive layers.
Suitable resins for forming the resin layer include polypropylene
resin, such as Novatec-P available from Mitsubishi Kagaku,
polyolefin resins, such as TPX (polymethylpentene) available from
Mitsui Kagaku, polyamide resins, ionomers and nylons.
Since the thermal transfer recording web roll 10 in the first
embodiment is a coreless roll, the thermal transfer recording web
can be rolled without using any core and much time and labor at a
low cost, and pictures of satisfactory picture quality can be
printed by thermal transfer printing on the thermal transfer
recording web.
Second Embodiment
FIG. 8 shows a thermal transfer recording web roll 10 in a second
embodiment according to the present invention.
The thermal transfer recording web roll 10 in the second embodiment
is the same in construction as the thermal transfer recording web
roll 10 in the first embodiment, except that the former is provided
with a radio frequency identification tag 20 near an inner end part
11 of the thermal transfer recording web 10a.
The radio frequency identification tag 20 is an on contact IC tag
(RFID) attached to a part near the inner end part 11 of the inner
surfaces of the thermal transfer recording web roll 10. Information
about the type, size and such of the thermal transfer recording web
roll 10 is recorded on the noncontact IC tag. When the thermal
transfer recording web roll 10 is loaded into a printer 5, a
read-write head R/W reads the information held by the noncontact IC
tag.
Since the radio frequency identification tag 20 is attached to the
thermal transfer recording web roll 10, the coreless thermal
transfer recording web roll 10 is able to hold necessary
information and the printer is able to use the information.
Modifications
The present invention is not limited in its practical application
to the foregoing embodiments, various modifications of the
foregoing embodiments may be made and various changes are possible
in the foregoing embodiments without departing from the scope of
the present invention.
For example, although the tab 11a and the sticking parts 11b are
arranged along the width of the thermal transfer recording web 10a
in the foregoing embodiments, the tab 11a may be formed in a middle
part with respect to the width of the thermal transfer recording
web 10a so as to protrude in the winding direction, and a sticking
part 11b may be formed in the inner end part as shown in FIGS. 9(A)
and 9(B). In FIGS. 9(A) and 9(B), the sticking part 11b and a
pseudoadhesive double-coated tape 14 are indicated by broken
lines.
An adhesive layer 37 may be formed on a surface of the base web 30,
opposite to the recording layer 31 of the thermal transfer
recording web 10a of the thermal transfer recording web roll 10 in
the first embodiment, and a release tape 38 may be applied to the
adhesive layer 37 to use the thermal transfer recording web 10a as
a photograph sealing web.
As apparent form the foregoing description, the present invention
has the following effects.
(1) The thermal transfer recording web roll 10 can be produced at a
low cost because the thermal transfer recording web roll 10 is
formed by rolling the thermal transfer recording web 10a in a
substantially cylindrical shape without using any core.
Since the thermal transfer recording web roll 10 is not provided
with any core, the thermal transfer recording web roll 10 does not
produce unnecessary waste.
The deformation of the thermal transfer recording web roll 10 can
easily be corrected and handling of the thermal transfer recording
web roll 10 is facilitated.
Any flaws corresponding to steps including an end detection hole
formed in the thermal transfer recording web are not formed in the
thermal transfer recording web and pictures can be formed in
satisfactory picture quality on the thermal transfer recording
web.
(2) Since the thermal transfer recording web 10a is provided with
the sticking parts 11b at parts of the inner end part 11 that is in
contact with the inner surface of the innermost layer of the
thermal transfer recording web 10a, the thermal transfer recording
web roll 10 will not loosen immediately before the thermal transfer
recording web 10a of the thermal transfer recording web roll 10 is
used up and thereby troubles that may result from the loosening of
the thermal transfer recording web roll 10 can be avoided.
(3) Since the sticking surfaces of the sticking parts 11b become
tack-free after the sticking parts 11b have been separated from the
innermost layer, the thermal transfer recording web roll 10 can be
used on a printer that detects the end of the thermal transfer
recording web 10a by any detecting method.
(4) The pseudoadhesive sticking parts become tack-free surely and
simply after the same have been separated from the innermost
layer.
(5) since the tab 11a is at the middle of the inner end part 11 of
the thermal transfer recording web 10a, the tab 11a will not
obstruct the loading operation for loading the thermal transfer web
roll 10 into the printer 5 and the thermal transfer recording web
roll 10 can easily and correctly loaded into the printer 5.
(6) Since the inner end part 11 of the thermal transfer recording
web 10a is provided with the slits 11c demarcating the tab 11a and
the adjacent sticking parts 11b, any scraps and fragments are not
produced in manufacturing the thermal transfer recording web roll
10.
(7) When the tab 11a projects in the winding direction, the thermal
transfer recording web 10a can easily be attached to the winding
machine.
(8) When the adhesive layer 37 is formed on the surface, opposite
the surface on which the recording layer 32 is formed, of the base
web 30, and the release tape 38 is attached to the adhesive layer
37, a coreless thermal transfer recording web roll for use on a
photograph sealing printing machine can be formed, and even an
unskilled operator is able to handle the coreless thermal transfer
recording web roll easily.
(9) When the thermal transfer recording web roll 10 is provided
with the noncontact IC tag 20 in a part of the thermal transfer
recording web 10a near the inner end part 11, the coreless thermal
transfer recording web roll 10 is able to hold various pieces of
information.
* * * * *