U.S. patent number RE40,534 [Application Number 11/203,649] was granted by the patent office on 2008-10-07 for clear conditioning detersive compositions containing polysiloxanes with at least one cyclic side chain.
This patent grant is currently assigned to Chemsil Silicones, Inc.. Invention is credited to James Jeffries Harrison, Nohemi Harrison, James Parr, Zimming Sun.
United States Patent |
RE40,534 |
Harrison , et al. |
October 7, 2008 |
Clear conditioning detersive compositions containing polysiloxanes
with at least one cyclic side chain
Abstract
This invention relates to a clear shampoo comprising a
polysiloxane component and methods for making the same. In one
embodiment, the polysiloxane component comprises a side chain
component having a hindered amine group.
Inventors: |
Harrison; James Jeffries (West
Hills, CA), Sun; Zimming (Fountain Valley, CA), Parr;
James (San Juan Capistrano, CA), Harrison; Nohemi (West
Hills, CA) |
Assignee: |
Chemsil Silicones, Inc.
(Chatsworth, CA)
|
Family
ID: |
46280207 |
Appl.
No.: |
11/203,649 |
Filed: |
August 12, 2005 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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10056964 |
Nov 7, 2001 |
6642194 |
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Reissue of: |
10022042 |
Dec 17, 2001 |
06605577 |
Aug 12, 2003 |
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Current U.S.
Class: |
510/122; 510/276;
510/308; 510/515; 510/466; 510/287; 510/119 |
Current CPC
Class: |
A61K
8/898 (20130101); A61Q 5/12 (20130101); A61Q
5/02 (20130101) |
Current International
Class: |
C11D
9/36 (20060101) |
Field of
Search: |
;510/119,276,287,308,466,515 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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0407042 |
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Jan 1991 |
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EP |
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6-321742 |
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Nov 1994 |
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JP |
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WO 96/32092 |
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Oct 1996 |
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WO |
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Primary Examiner: Boyer; Charles I
Attorney, Agent or Firm: Stout, Uxa, Buyan & Mullins,
LLP Uxa; Frank J. Fisher; Carlos A.
Parent Case Text
This application is a continuation-in-part of U.S. patent
application Ser. No. 10/056,964, filed Nov. 7, 2001 .Iadd.now U.S.
Pat. No. 6,642,194.Iaddend., the disclosure of which is
incorporated in its entirety herein by reference.
Claims
What is claimed is:
1. A hair shampoo composition comprising an effective amount of a
detersive component, an effective amount of an emulsifier component
and a polysiloxane component in an amount effective as a hair
conditioner, the hair shampoo composition being clear, the
polysiloxane component comprises at least one side chain component
A having the general formula: ##STR00011## R.sub.1 is an H, OH or a
C1-C5 hydrocarbon; X is a C1-C10 hydrocarbon, a heteroatom or
##STR00012## Z is a heteroatom and d is 0 to about 6, the
polysiloxane component has a viscosity of about 1 centistoke to
about 1,000,000 centistoke.
2. The composition of claim 1 comprising about 5% to about 60% of
the detersive component, about 0.01% to about 10% of the emulsifier
component, and about 0.01% to about 10% of the polysiloxane
component.
3. The composition of claim 1 wherein the detersive component
comprises a surfactant selected from the group consisting of an
anionic surfactant, an amphoteric surfactant and a mixture
thereof.
4. The composition of claim 1 wherein the emulsifier component
comprises a non-ionic emulsifier.
5. A clear hair shampoo composition comprising: (a) about 0.01% to
about 10% of an emulsifier component; and (b) about 0.01% to about
10% of a polysiloxane component, the polysiloxane component
comprises a side chain component A having the general formula;
##STR00013## R.sub.1 is an H or a C1-C5 hydrocarbon; X is a C1-C10
hydrocarbon, a heteroatom or ##STR00014## Z is a heteroatom and d
is 0 to about 6, the polysiloxane component has a viscosity of
about 1 centistoke to about 1,000,000 centistoke and is effective
as a hair conditioner in a hair shampoo, wherein the composition is
formulated as a clear hair shampoo composition.
6. The composition of claim 5 wherein the polysiloxane component
has a viscosity of about 1,000 centistoke to about 500,000
centistoke.
7. The composition of claim 5 wherein the polysiloxane component
has a viscosity of about 1,000 centistoke to about 10,000
centistoke.
8. The composition of claim 5 wherein the polysiloxane component
has a viscosity of about 1,000 centistoke to about 5,000
centistoke.
9. The composition of claim 5 wherein the polysiloxane component
has a viscosity of about 2,000 centistoke to about 4,000
centistoke.
10. The composition of claim 5 wherein the emulsifier component
comprises: about 0.01% to about 5% of an anionic or an amphoteric
surfactant; and about 0.01% to about 5% of a non-ionic
emulsifier.
11. The composition of claim 5 in the side chain component A has
the general formula: ##STR00015## wherein R1, R2, R3, R4, R5, R6,
R7, R8 and R9 are independently an H, a C1-C10 hydrocarbon, an
ester, carboxyl or a halogen; X is a C1-C10 hydrocarbon, a
heteroatom or ##STR00016## Z is a heteroatom and d is 0 to about
6.
12. The composition of claim 5 wherein the side chain component A
has the general formula: ##STR00017##
13. The composition of claim 5 further comprising a detersive
component.
14. The composition of claim 5 further comprising about 5% to about
60% of a detersive component.
15. The composition of claim 5 further comprising a shampoo
additive component.
16. A method of making a clear hair shampoo composition comprising:
combining (1) a microemulsion comprising an effective amount of an
emulsifier component, a polysiloxane component in an amount
effective as a hair conditioner in a hair shampoo and water and (2)
an effective amount of a detersive component at conditions
effective to form a clear hair shampoo composition, wherein the
polysiloxane component comprises at least one side chain component
A having the general formula: ##STR00018## R.sub.1 is an H, OH or a
C1-C5 hydrocarbon; X is a C1-C10 hydrocarbon, a heteroatom or
##STR00019## Z is a heteroatom and d is 0 to about 6, the
polysiloxane component has a viscosity of about 1 centistoke to
about 1,000,000 centistoke.
17. The method of claim 16 wherein the side chain component A has
the general formula: ##STR00020## wherein R.sub.1, R.sub.2,
R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9
are independently an H, a C1-C10 hydrocarbon, an ester, carboxyl or
a halogen; X is a C1-C10 hydrocarbon, a heteroatom or ##STR00021##
Z is a heteroatom and d is 0 to about 6.
18. The method of claim 16 wherein the side chain component A has
the general formula: ##STR00022##
19. The method of claim 16 wherein the polysiloxane component has a
viscosity of about 1 centistoke to about 1,000,000 centistoke.
.Iadd.20. A method of cleansing or conditioning hair comprising
applying to said hair a composition comprising an effective amount
of an emulsifier component and a polysiloxane component in an
amount effective as a hair conditioner, the polysiloxane component
comprises at least one side chain component A having the general
formula: ##STR00023## R.sub.1 is an H, OH or a C.sub.1-C.sub.5
hydrocarbon; X is a C.sub.1-C.sub.10 hydrocarbon, a heteroatom or
##STR00024## Z is a heteroatom and d is 0 to about 6, the
polysiloxane component has a viscosity of about 1 centistoke to
about 1,000,000 centistoke..Iaddend.
.Iadd.21. The method of claim 20 wherein the composition comprises
an effective amount of a surfactant component..Iaddend.
.Iadd.22. The method of claim 21 wherein the surfactant component
is selected from the group consisting of anionic surfactants,
amphoteric surfactants and mixtures thereof..Iaddend.
.Iadd.23. The method of claim 21 wherein the composition comprises
about 5% to about 60% by weight of the surfactant
component..Iaddend.
.Iadd.24. The method of claim 20 wherein the composition comprises
an effective amount of a color component..Iaddend.
.Iadd.25. The method of claim 20 wherein the composition is
clear..Iaddend.
.Iadd.26. The method of claim 20 wherein the composition is
formulated as a hair shampoo composition..Iaddend.
.Iadd.27. The method of claim 20 wherein the composiion has
enhanced skin affinity as compared to a similar composition lacking
said polysiloxane..Iaddend.
.Iadd.28. The method of claim 21 wherein the composition is
formulated as a composition effective for cleaning
skin..Iaddend.
.Iadd.29. The method of claim 20 wherein the composition contains a
non-ionic emulsifier..Iaddend.
.Iadd.30. The method of claim 20 wherein the side chain component A
included in the composition has the general formula: ##STR00025##
wherein R1, R2, R3, R4, R5, R6, R7, R8 and R9 are independently an
H, a C.sub.1-C.sub.10 hydrocarbon, an ester, carboxyl or a halogen;
X is a C.sub.1-C.sub.10 hydrocarbon, a heteroatom or ##STR00026## Z
is a heteroatom and d is 0 to about 6..Iaddend.
.Iadd.31. The method of claim 20 wherein the side chain component A
included in the composition has the general formula: ##STR00027##
.Iaddend.
.Iadd.32. The method of claim 20 wherein the composition comprises
about 0.01% to about 10% by weight of the emulsifier
component..Iaddend.
.Iadd.33. The method of claim 20 wherein the composition comprises
about 0.01% to about 10% by weight of the polysiloxane
component..Iaddend.
.Iadd.34. The method of claim 20 wherein the polysiloxane component
of the composition has a viscosity of about 1 centistokes to about
1,000,000 centistokes..Iaddend.
.Iadd.35. The method of claim 20 wherein the polysiloxane component
of the composition has a viscosity of about 1,000 centistoke to
about 500,555 centistoke..Iaddend.
.Iadd.36. The method of claim 20 wherein the polysiloxane component
of the composition has a viscosity of about 1,000 centistoke to
about 10,000 centistoke..Iaddend.
.Iadd.37. The method of claim 20 wherein the polysiloxane component
of the composition has a viscosity of about 1,000 centistoke to
about 5,000 centistokes..Iaddend.
.Iadd.38. The method of claim 20 wherein the polysiloxane component
of the composition has a viscosity of about 2,000 centistoke to
about 4,000 centistoke..Iaddend.
Description
BACKGROUND OF THE INVENTION
The concept of cleansing and conditioning detersive products has
drawn great attention since its launch in the early 1980's. From a
technical point, cleansing and conditioning are contradictions,
since conditioning has to deposit some ingredients on an object and
cleansing has to remove the deposited ingredients from the object.
To combine cleansing and conditioning in detersive products means
when the product removes the dirt from the object, the product also
simultaneously deposits some conditioning ingredients on the
object. The conditioning effects depend on the equilibrium between
the removed dirt, conditioning ingredient and deposit conditioning
ingredients. For hair products, conditioning involves depositing
certain agents onto the hair to give it the protection, softness,
shine and detangling effects. Less deposition means less
conditioning and more deposition means more conditioning or over
conditioning.
To achieve proper conditioning formulations, chemists are faced
with the challenge of choosing the appropriate conditioning
ingredients, the proper ratio of conditioning ingredients to
surfactants and methods of incorporating conditioning ingredients
into the detersive system to form stable products.
A conditioning ingredient should have the basic characteristic of
being water-insoluble, easy to be spread and have some affinities
with the application objects. Polysiloxane, such as dimethicone,
and derivatives are water-insoluble and are widely used
conditioning ingredients. Furthermore, polysiloxanes usually give
good hair protection, softening, shine and detangling effects.
The various technical methods for incorporating polysiloxanes, such
as dimethicone, into the detersive products have been patented. The
focus is on the particle size distribution of dimethicone
surfactant emulsion and stability of the shampoo. Smaller particle
size means more stability and more deposition to the targeted
object.
Although some success has been achieved in being able to
incorporate polysiloxanes, such as dimethicones, into detersive
compositions, other challenges still remain. It remains a challenge
to be able to formulate a stable conditioning/detersive
composition, especially when a polysiloxane (e.g. dimethicone) is
employed. Considering the regular viscosity of the detersive
composition and the relatively lightweight of the conditioning
ingredients, it is very difficult to achieve a long-term stability
of the products. For example, the products tend to separate with
the conditioning ingredients settling on top of the water-detergent
solution. Furthermore, it remains a challenge to be able to
formulate a clear stable conditioning/detersive composition,
especially when the conditioning ingredient is a polysiloxane.
There continues to be a need to have a more stable formulation
having a conditioner and a detersive composition. In particular,
there is a need to have a clear detersive formulation which
comprises a polysiloxane.
SUMMARY OF THE INVENTION
The present invention meets this need and provides for a stable,
clear detersive composition having a polysiloxane component. In one
embodiment, the present invention provides for a clear detersive
composition comprising a conditioner. A clear
conditioning/detersive composition includes, for example, a
conditioning shampoo which is substantially clear.
The term "clear" as used herein means a substantial amount of light
may pass through. Alternatively, the term "clear" means transparent
or translucent, as opposed to opaque.
In accordance with the invention, a composition comprising an
emulsifier component and a polysiloxane component is provided. The
polysiloxane component comprises at least one side chain component
A having the general formula: ##STR00001## R1 is an H, OH, or a
C1-C5 hydrocarbon; X is a C1-C10 hydrocarbon, a heteroatom or
##STR00002## Z is a heteroatom and d is 0 to about 6.
Further in accordance with the present invention, the composition
further comprises a detersive component. For example, the
composition comprises about 5% to about 60% of the detersive
component, about 0.01% to about 10% of the emulsifier component,
and about 0.01% to about 10% of the polysiloxane component.
Still further in accordance with the present invention, a method of
making a clear shampoo is provided. The method comprises the steps
of forming a micro-emulsion of a polysiloxane component, and
combining the micro-emulsion with a detersive component. The
micro-emulsion is formed by combining a non-ionic emulsifier with a
polysiloxane component.
Any feature or combination of features described herein are
included within the scope of the present invention provided that
the features included in any such combination are not mutually
inconsistent as will be apparent from the context, this
specification, and the knowledge of one of ordinary skill in the
art.
Additional advantages and aspects of the present invention are
apparent in the following detailed description and claims.
DETAILED DESCRIPTION OF THE INVENTION
The present invention is, in part, based upon the surprising
discovery that a polysiloxane component may be combined with a
detersive component to form a clear composition, preferably a clear
shampoo. In a broad embodiment, the composition comprises an
emulsifier component and a polysiloxane component.
Without wishing to limit the invention to any theory or mechanism
of operation, it is believed that a clear composition, for example,
a clear shampoo composition, may be produced by combining a
detersive component with performed micro emulsion comprising a
polysiloxane component. The micro emulsions may or may not remain
intact after it is combined with a detersive component.
In one embodiment, a composition of the present invention remains
stable (for example remain clear) for about 360 days after
manufacturing.
In one embodiment, the micro emulsions are formed by mixing the
emulsifier components with the polysiloxane components, preferably
in the presence of water. For example, micro emulsion are formed by
homogenizing emulsifier components with polysiloxane components in
a tank at about 40 to about 70 degrees C. In one embodiment, a
homogenizer employed is model number ME 100 LC by Charles Ross and
Son, Hauppauga, N.Y. In one embodiment, the ratio (by weight) of
the emulsifier component to the polysiloxane component in a micro
emulsion is about 1:1, 1:2, 1:3, or 1:4.
In one embodiment, emulsifier components include a non-ionic
emulsifier. In another embodiment, the emulsifier components
include a non-ionic emulsifier and at least one of an anionic
emulsifier and an amphoteric emulsifier. The anionic amphoteric
emulsifiers are selected from the anionic and amphoteric
surfactants, respectively.
Non-limiting examples of non-ionic surfactants include:
Capryleth-n, where n=4, 5; Deceth-n, where n=3, 4, 5, 6, 8, 9, 10;
Undeceth-n, where n=3, 5, 7, 8, 9, 11; Coceth-n, where n=3, 5, 7,
8, 10; C9-11 Pareth-n, where n=5, 6, 8; C9-15 Pareth-8; C11-15
Pareth-n, where n=3, 5, 9, 12, 15, 20, 30, 40; C11-21-Pareth-n,
where n=3, 10; C12-1-n, where n=3, 5, 7, 9, 12; C12-14 Pareth-n,
where n=5, 7, 9, 12; C12-15 Pareth-n, where n=2, 3, 4, 5, 7, 9, 10,
11, 12; C12-16 Pareth-n, where n=5, 7, 9; C14-15 Pareth-n, where
n=4, 7, 8, 11, 12, 13; C20-22 Pareth-30; C20-40 Pareth-n, where
n=3, 10, 24, 40; C22-24 Pareth-33; C30-50 Pareth-n, where n=3, 10,
40; C40-60 Pareth-n, where n=3, 10; C12-14 Sec-Pareth-5; C12-14
Sec-Pareth-n, where n=8, 9, 15, 20, 30, 40, 50; C11-15
Sec-Pareth-12; Dihydrocholeth-n, n=15, 20, 30; Glycereth-n, where
n=7, 12, 20, 26, 31; Hydrogenated Talloweth-n, where n=12, 25;
Isoceteth-n, where n=10, 15, 20, 30; Isodeceth-n, where n=4, 5, 6;
Isolaureth-n, where n=3, 6, 10; Isosteareth-n, where n=2, 3, 10,
12, 20, 22, 25, 50; Laneth-n, where n=5, 10, 15, 16, 20, 25, 40,
50, 60, 75; Laureth-n, where n=1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11,
12, 13, 14, 15, 16, 20, 21, 23, 25, 30, 40, 50; Myreth-n, where
n=2, 3, 4, 5, 10; Octyldodeceth-n, where n=5, 10, 16, 20, 25, 30;
Oleth-n, where n=2, 4, 5, 6, 7, 8, 9, 10, 11, 12, 15, 16, 20, 23,
24, 25, 30, 35, 40, 44, 50, 106; PPG-2-Ceteareth-9;
PPG-4-Ceteareth-12; PPG-10-Ceteareth-20; PPG-1-Ceteth-n, where n=1,
5, 10, 20; PPG-2-Ceteth-n, where n=1, 5, 10, 20; PPG-2-Ceteth-n,
where n=5, 10, 20; PPG-4-Ceteth-n, where n=1, 5, 10, 20;
PPG-5-Ceteth-20; PPG-8-Ceteth-n, where n=1, 2, 5, 10; PPG-n Cetyl
Ether, where n=10, 20, 28, 30, 50; PPG-2 C12-15 Pareth-6; PPG-4
C13-15 Pareth-15; PPG-5 C9-15 Pareth-6; PPG-6 C9-11 Pareth-n, where
n=5, 12, 11; PPG-3 C12-14 Sec-Pareth-7; PPG-4 C12-14 Sec-Pareth-5;
PPG-5 C12-14 Sec-Pareth-7; PPG-5 C12-14 Sec-Pareth-9;
PPG-1-Deceth-6; PPG-2-Deceth-10; PPG-4-Deceth-n, where n=4, 6;
PPG-6-Deceth-n, where n=4, 9; PPG-8 Deceth-6; PPG-14 Deceth-6;
PPG-6-Decyltetradeceth-n, where n=12, 20, 30; PPG-13
Decyltetradeceth-24; PPG-20-Decyltetradeceth-10;
PPG-9-Ethylhexeth-5; PPG-20-Glycereth-30; PPG-24-Glycereth-24;
PPG-66-Glycereth-12; PPG-2-Isodeceth-n, where n=4, 6, 9, 12;
PPG-3-Isodeceth-n, where n=1, 9; PPG-3-Isosteareth-9;
PPG-12-Laneth-50; PPG-3-Laureth-9; PPG-4 Laureth-n, where n=2, 5,
7; PPG-6-Laureth-3; PPG-25-Laureth-25; PPG-9-Steareth-3;
PPG-23-Steareth-34; PPG-30 Steareth-4; PPG-34-Steareth-3; PPG-1
Trideceth-6; PPG-4 Trideceth-6; PPG-6 Trideceth-8; Sorbeth-n, where
n=6, 20, 30, 40; Tocophereth-n, where n=5, 10, 12, 18, 50;
Trideceth-n, where n=2, 3, 5, 6, 7, 8, 9, 10, 11, 12, 15, 18, 20,
21, 50; Ceteth-n, where n=1, 2, 3, 4, 5, 6, 7, 10, 12, 14, 15, 16,
17, 18, 20, 23, 24, 25, 30, 40, 45; Ceteareth-n, where n=3, 4, 5,
6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 20, 22, 23, 24, 25,
27, 28, 29, 30, 33, 34, 40, 50, 55, 60, 80, 100; Cetoleth-n, where
n=6, 10, 11, 15, 20, 22, 24, 25, 30; Choleth-n, where n=5, 10, 15,
20, 24, 30; Steareth-n, where n=2, 3, 4, 5, 6, 7, 8, 10, 11, 13,
14, 15, 16, 20, 21, 25, 27, 30, 40, 50, 80, 100; and Beheneth-n,
where n=5, 10, 20, 25, 30.
Non-limiting examples of anionic surfactants which may be employed
as emulsifiers include: Alkyl ether sulfates, Alkyl sulfates,
.alpha.-Olefin sulfonates, sulfocuccinates, Alkyl isethionates,
Acyl amides, Acyl peptides, Alkyl ether carboxylates, Alkyl
phosphates, Acylamphoglycinates, Acylamphopropionates and Amine
oxides, Ammonium C12-15 Alkyl Sulfate, Ammonium Capryleth Sulfate,
Ammonium Coco-Sulfate, Ammonium C12-15 Pareth Sulfate, Ammonium
Laureth-n Sulfate, where n=3, 5, 7, 9, 12; Ammonium Lauryl Sulfate,
Ammonium Myreth Sulfate, Ammonium Myristyl Sulfate, Ammonium
Nonoxynol-4 Sulfate, Ammonium Nonoxynol-30 Sulfate, DEA-C12-13
Alkyl Sulfate, DEA-C12-15 Alkyl Sulfate, DEA-Cetyl Sulfate,
DEA-C12-13 Pareth-3 Sulfate, DEA-Laureth Sulfate, DEA-Lauryl
Sulfate, DEA-Myreth Sulfate, DEA-Myristyl Sulfate, Magnesium
Coco-Sulfate, Magnesium Laureth-n Sulfate, where n=2, 5, 8, 16;
Magnesium Lauryl Sulfate, Magnesium Myreth Sulfate, Magnesium Oleth
Sulfate, Magnesium PEG-3 Cocamide Sulfate, Magnesium Sulfate,
Magnesium/TEA-Coco-Sulfate, MEA-Laureth Sulfate, MEA-Lauryl
Sulfate, MIPA C12-15 Pareth Sulfate, MIPA-Laureth Sulfate,
MIPA-Lauryl Sulfate, Mixed Isopropanolamines Lauryl Sulfate,
Potassium Glycol Sulfate, Potassium Lauryl Sulfate, Potassium
Persulfate, Potassium Sulfate, Protamine Sulfate, Sodium C8-10
Alkyl Sulfate, Sodium C12-13 Alkyl Sulfate, Sodium C12-15 Alkyl
Sulfate, Sodium C12-18 Alkyl Sulfate, Sodium C16-20 Alkyl Sulfate,
Sodium Cellulose Sulfate, Sodium Cetearyl Sulfate, Sodium Cetyl
Sulfate, Sodium Cholesteryl Sulfate, Sodium Chondroitin Sulfate,
Sodium Coceth Sulfate, Sodium Coceth-30 Sulfate, Sodium
Coco/Babassu Sulfate, Sodium Coco/Hydrogenated Tallow Sulfate,
Sodium Cocomonoglyceride Sulfate, Sodium Coco-Sulfate, Sodium C9-15
Pareth-3 Sulfate, Sodium C10-15 Pareth Sulfate, Sodium C12-13
Pareth Sulfate, Sodium C12-15 Pareth Sulfate, Sodium C13-15
Pareth-3 Sulfate, Sodium C12-14 Sec-Pareth Sulfate, Sodium
Cyclodextrin Sulfate, Sodium Deceth Sulfate, Sodium Decyl Sulfate,
Sodium Dermatan Sulfate, Sodium Dextran Sulfate, Sodium
Dicocoylethylene-diamine PEG-15 Sulfate, Sodium Ethylhexyl Sulfate,
Sodium Laneth Sulfate, Sodium Laureth Sulfate, where n=2, 2, 5, 7,
8, 12, 40; Sodium Lauryl Sulfate, Sodium/MEA-PEG-3 Cocamide
Sulfate, Sodium Myreth Sulfate, Sodium Myristyl Sulfate, Sodium
Nonoxynol-1 Sulfate, Sodium Nonoxynol-3 Sulfate, Sodium Nonoxynol-4
Sulfate, Sodium Nonoxynol-6 Sulfate, Sodium Nonoxynol-8 Sulfate,
Sodium Nonoxynol-10 Sulfate, Sodium Nonoxynol-25 Sulfate, Sodium
Octoxynol-2 Sulfate, Sodium Octoxynol-6 Sulfate, Sodium Octoxynol-9
Sulfate, Sodium Oleth Sulfate, Sodium Oleyl Sulfate, Sodium
Stearoyl Chondroitin Sulfate, Sodium Stearyl Sulfate, Sodium
Sucrose Octasulfate, Sodium Tallow Sulfate, Sodium Trideceth
Sulfate, Sodium Tridecyl Sulfate, TEA-C10-15 Alkyl Sulfate,
TEA-C12-13 Alkyl Sulfate, TEA-C12-14 Alkyl Sulfate, TEA-C12-15
Alkyl Sulfate, TEA-Coco-Sulfate, TEA-C12-13 Pareth-3 Sulfate,
TEA-Laneth-5 Sulfate, TEA-Laureth Sulfate, TEA-Lauryl Sulfate,
TEA-Oleyl Sulfate, TEA-PEG-3 Cocamide Sulfate, TIPA-Laureth
Sulfate, TIPA-Lauryl Sulfate, Ammonium C9-10 Perfluorosulfonate,
Ammonium Cumenesulfonate, Ammonium Dodecylbenzenesulfonate,
Ammonium Xylenesulfonate, Calcium Dodecylbenzenesulfonate, Calcium
Lignosulfonate, Calcium Pantetheine Sulfonate, Cocamidopropyl
Dimethylammonium C8-16 Isoalkylsuccinyl Lactoglobulin Sulfonate,
DEA-Dodecylbenzenesulfonate, DEA-Methyl Myristate Sulfonate,
Disodium Bisethylphenyl Triaminotriazine Stilbenedisulfonate,
Disodium Cetyl Phenyl Ether Disulfonate, Disodium
Cocoamphocarboxyethylhydroxypropylsulfonate, Disodium Decyl Phenyl
Ether Disulfonate, Disodium Distyrylbiphenyl Disulfonate, Disodium
Lauriminobishydroxypropylsulfonate, Disodium Lauryl Phenyl Ether
Disulfonate, Disodium Methylene Dinaphthalenesulfonate,
Isopropylamine Dodecylbenzenesulfonate, Magnesium Lauryl
Hydroxypropyl Sulfonate, MIPA-Dodecylbenzenesulfonate, Potassium
Cumenesulfonate, Potassium Dodecylbenzenesulfonate, Potassium
Lauryl Hydroxypropyl Sulfonate, Potassium Phenylbenzimidazole
Sulfonate, Potassium Toluenesulfonate, Potassium Xylene Sulfonate,
Sodium Benzotriazolyl Butylphenol Sulfonate, Sodium C13-17 Alkane
Sulfonate, Sodium C14-18 Alkane Sulfonate, Sodium C9-22 Alkyl Sec
Sulfonate, Sodium C14-17 Alkyl Sec Sulfonate, Sodium
Caproamphohydroxypropylsulfonate, Sodium
Capryloamphohydroxy-propylsulfonate, Sodium Caprylyl Sulfonate,
Sodium C8-16 Isoalkylsuccinyl Lactoglobulin Sulfonate, Sodium
Cocoamphohydroxypropylsulfonate, Sodium Cocoglyceryl Ether
Sulfonate, Sodium Cocomonoglyceride Sulfonate, Sodium C12-14 Olefin
Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin
Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium C14-15 Pareth-PG
Sulfonate, Sodium C12-15 Pareth-3 Sulfonate, Sodium C12-15 Pareth-7
Sulfonate, Sodium C12-15 Pareth-15 Sulfonate, Sodium
Cumenesulfonate, Sodium Decylbenzenesulfonate, Sodium
Dodecylbenzenesulfonate, Sodium Guaiazulene Sulfonate, Sodium
Hexyldiphenyl Ether Sulfonate, Sodium Hydroxymethane Sulfonate,
Sodium Lauroamphohydroxypropylsulfonate, Sodium Lignosulfonate,
Sodium Methylnaphthalenesulfonate, Sodium Naphthalenesulfonate,
Sodium Naphthol Sulfonate, Sodium m-Nitrobenzenesulfonate, Sodium
Octoxynol-2 Ethane Sulfonate, Sodium
Oleoamphohydroxypropylsulfonate, Sodium Palm Glyceride Sulfonate,
Sodium Pantetheine Sulfonate, Sodium Phenolsulfonate, Sodium
Phenylbenzimidazole Sulfonate, Sodium
Polydimethylglycinophenolsulfonate, Sodium
Polynaphthalenesulfonate, Sodium Polystyrene Sulfonate, Sodium
Shale Oil Sulfonate, Sodium Stearoamphohydroxypropylsulfonate,
Sodium Stearoxy PG-Hydroxyethylcellulose Sulfonate, Sodium
Toluenesulfonate, Sodium Tridecylbenzenesulfonate, Sodium
Xylenesulfonate, TEA-Dodecylbenzenesulfonate,
TEA-Phenylbenzimidazole Sulfonate, TEA-Tridecylbenzenesulfonate,
Ammonium Lauryl Sulfosuccinate, Cholesteryl C16-18 Alkenyl
Succinate, Decyl Succinate, Diammonium Lauramido-MEA
Sulfosuccinate, Diammonium Lauryl Sulfosuccinate, Diammonium
Oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate,
Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate,
Diethoxyethyl Succinate, Diethylhexyl Sodium Sulfosuccinate,
Diethylhexyl Succinate, Diethyl Succinate, Diglycol Guanidine
Succinate, Diheptyl Sodium Sulfosuccinate, Disodium Cetearyl
Sulfosuccinate, Disodium Cocamido MEA-Sulfosuccinate, Disodium
Cocamido MIPA-Sulfosuccinate, Disodium Cocamido PEG-3
Sulfosuccinate, Disodium Coco-Glucoside Sulfosuccinate, Disodium
Cocoyl Butyl Gluceth-10 Sulfosuccinate, Disodium C12-15 Pareth
Sulfosuccinate, Disodium C12-14 Sec-Pareth Sulfosuccinate, Disodium
C12-14 Sec-Pareth-5 Sulfosuccinate, Disodium C12-14 Sec-Pareth-7
Sulfosuccinate, Disodium C12-14 Sec-Pareth-9 Sulfosuccinate,
Disodium C12-14 Sec-Pareth-12 Sulfosuccinate, Disodium Cystinyl
Disuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6
Sulfosuccinate, Disodium Dimethicone Copolyol Sulfosuccinate,
Disodium Hydrogenated Cottonseed Glyceride Sulfosuccinate, Disodium
Isodecyl Sulfosuccinate, Disodium Isostearamido MEA-Sulfosuccinate,
Disodium Isostearamido MIPA-Sulfosuccinate, Disodium Isostearyl
Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium
Lauramido MEA-Sulfosuccinate, Disodium Lauramido PEG-2
Sulfosuccinate, Disodium Lauramido PEG-5 Sulfosuccinate, Disodium
Laureth Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium
Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate,
Disodium Lauryl Sulfosuccinate, Disodium Myristamido
MEA-Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium
Oleamido MEA-Sulfosuccinate, Disodium Oleamido MIPA-Sulfosuccinate,
Disodium Oleamido PEG-2 Sulfosuccinate, Disodium Oleth-3
Sulfosuccinate, Disodium Oleyl Sulfosuccinate, Disodium Palmitamido
PEG-2 Sulfosuccinate, Disodium Palmitoleamido PEG-2 Sulfosuccinate,
Disodium PEG-4 Cocamido MIPA-Sulfosuccinate, Disodium PEG-5
Laurylcitrate Sulfosuccinate Disodium PEG-8 Palm Glycerides
Sulfosuccinate Disodium PEG-8 Ricinosuccinate, Disodium
Ricinoleamido MEA-Sulfosuccinate, Disodium Sitostereth-14
Sulfosuccinate, Disodium Stearamido MEA-Sulfosuccinate, Disodium
Stearyl Sulfosuccinate, Disodium Succinate, Disodium Tallamido
MEA-Sulfosuccinate, Disodium Tallowamido MEA-Sulfosuccinate,
Disodium Tetrapropenyl Succinate, Disodium Tridecylsulfosuccinate,
Disodium Undecylenamido MEA-Sulfosuccinate, Disodium Undecylenamido
PEG-2 Sulfosuccinate, Disodium Wheat Germamido MEA-Sulfosuccinate,
Disodium Wheat Germamido PEG-2 Sulfosuccinate, Di-TEA-Oleamido
PEG-2 Sulfosuccinate, Glyceryl Stearate Succinate, Hydroxypropyl
Methylcellulose Acetate/Succinate, Isostearyl Diglyceryl Succinate,
Methoxy-PEG-7 Rutinyl Succinate, PEG-20 Hexadecenylsuccinate,
PEG-50 Hydrogenated Castor Oil Succinate, PEG-3 PPG-20 Succinate,
Potassium Dextrin Octenylsuccinate, Potassium PEG-50 Hydrogenated
Castor Oil Succinate, Sodium Bisglycol Ricinosulfosuccinate, Sodium
Dextrin Octenylsuccinate, Sodium/MEA Laureth-2 Sulfosuccinate,
Sodium PEG-50 Hydrogenated Castor Oil Succinate, Sodium Starch
Octenylsuccinate, TEA-Dextrin Octenylsuccinate, TEA-PEG-50
Hydrogenated Castor Oil Succinate.
Ammonium Laureth-6 Carboxylate, Ammonium Laureth-8 Carboxylate,
Cetyl C12-15-Pareth-9 Carboxylate, Cetyl PPG-2 Isodeceth-7
Carboxylate, Isopropyl C12-15-Pareth-9 Carboxylate, Isopropyl
PPG-2-Isodeceth-7 Carboxylate, Magnesium Laureth-11 Carboxylate,
MEA-Laureth-6 Carboxylate, MEA PPG-6 Laureth-7 Carboxylate,
MEA-PPG-8-Steareth-7 Carboxylate, Potassium Laureth-3 Carboxylate,
Potassium Laureth-4 Carboxylate, Potassium Laureth-5 Carboxylate,
Potassium Laureth-6 Carboxylate, Potassium Laureth-10 Carboxylate,
Potassium Trideceth-n, where n=3, 3, 7, 15, 19, Sodium Capryleth-2
Carboxylate, Sodium Capryleth-9 Carboxylate, Sodium Ceteth-13
Carboxylate, Sodium C9-11 Pareth-6 Carboxylate, Sodium C11-15
Pareth-7 Carboxylate, Sodium C12-13 Pareth-n Carboxylate, where
n=6, 8, 12, Sodium C12-15 Pareth-n Carboxylate, where n=6, 7, 8,
Sodium C14-15 Pareth-8 Carboxylate, Sodium C12-14 Sec-Pareth-8
Carboxylate, Sodium Isostearth-6 Carboxylate, Sodium Isostearth-11
Carboxylate, Sodium Laureth-3 Carboxylate, Sodium Laureth-n
Carboxylate, where n=4, 5, 6, 8, 11, 12, 13, 14, 17, Sodium Lauryl
Glycol Carboxylate, Sodium PEG-6 Cocamide Carboxylate, Sodium PEG-8
Cocamide Carboxylate, Sodium PEG-3 Lauramide Carboxylate, Sodium
PEG-4 Lauramide Carboxylate, Sodium PEG-7 Olive Oil Carboxylate,
Sodium PEG-8 Palm Glycerides Carboxylate, Sodium Trideceth-3
Carboxylate, where n=3, 4, 6, 7, 8, 12, 15, 19, Sodium Undeceth-5
Carboxylate.
Ammonium Cocoyl Sarcosinate, Ammonium Lauroyl Sarcosinate,
Isopropyl Lauroyl Sarcosinate, Potassium Cocoyl Sarcosinate,
Potassium Lauroyl Sarcosinate, Sodium Cocoyl Sarcosinate, Sodium
Lauroyl Sarcosinate, Sodium Myristoyl Sarcosinate, Sodium Palmitoyl
Sarcosinate, TEA-Cocoyl Sarcosinate, TEA-Lauroyl Sarcosinate,
TEA-Oleoyl Sarcosinate, TEA-Palm Kernel Sarcosinate, Palmitoyl
Oligopeptide, Pantothenic Acid Polypeptide, Ammonium Cocoyl
Isethionate, Dibromopropamidine Diisethionate, Hexamidine
Diisethionate, Sodium Cocoyl Isethionate, Sodium Isethionate,
Sodium Lauroyl Isethionate, Sodium Myristoyl Isethionate, Sodium
Oleoyl Isethionate.
Aluminum Dicetyl Phosphate, Benzalkonium Cetyl Phosphate, C8-10
Alkyl Ethyl Phosphate, C9-15 Alkyl Phosphate, Ceteareth-2
Phosphate, Ceteareth-4 Phosphate, Ceteareth-5 Phosphate,
Ceteareth-10 Phosphate, Ceteth-8 Phosphate, Ceteth-10 Phosphate,
Cetyl Phosphate, Cocamidopropyl PG-Dimonium Chloride Phosphate,
Cocoyl Hydroxyethylimidazolinium PG-Chloride Phosphate, C6-10
Pareth-4 Phosphate, C12-13 Pareth-10 Phosphate, C12-15 Pareth-n
Phosphate, where n=2, 3, 6, 8, 9, 10; C12-16 Pareth-6 Phosphate,
DEA-Ceteareth-2 Phosphate, DEA-Cetyl Phosphate, DEA-C8-18
Perfluoroalkylethyl Phosphate, DEA-Oleth-3 Phosphate, DEA Oleth-n
Phosphate, where n=5, 10, 20; DEA-Polyperfluoroethoxymethoxy PEG-2
Phosphate, Deceth-9 Phosphate, Deceth-4 Phosphate, Deceth-6
Phosphate, Diceteareth-10 Phosphate, Dicetyl Phosphate, Di-C12-15
Pareth-n Phosphate, where n=2, 4, 6, 8, 10; Dilaureth-4 Phosphate,
Dilaureth-10 Phosphate, Dimyristyl Phosphate, Dioleth-8 Phosphate,
Disodium Lauryl Phosphate, Disodium Oleyl Phosphate, Glycereth-26
Phosphate, Hydrogenated Vegetable Glycerides Phosphate,
Hydroxyethyl Cetyldimonium Phosphate, Isosteareth-2 Phosphate,
Laneth-4 Phosphate, Laureth-n Phosphate, where n=1, 2, 3, 4, 7, 8;
Lauryl Phosphate, Linoleamidopropyl PG-Dimonium Chloride Phosphate,
Manganese Glycerophosphate, MEA-Dicetearyl Phosphate,
Myristamidopropyl Dimethylamine Dimethicone Copolyol Phosphate,
Myristamidopropyl Dimethylamine Phosphate, Nonoxynol-3 Phosphate,
Nonoxynol-4 Phosphate, Nonoxynol-6 Phosphate, Nonoxynol-9
Phosphate, Nonoxynol-10 Phosphate, Nonyl Nonoxynol-n Phosphate,
where n=7, 8, 9, 10, 11, 15, 24, Oleth-n Phosphate, where n=2, 3,
4, 5, 10, 20, Oleyl Ethyl Phosphate, Oleyl Phosphate, Palmeth-2
Phosphate, PEG-15 Cocamine Oleate/Phosphate, PEG-26-PPG-30
Phosphate, PEG-45 Stearate Phosphate, Potassium C9-15 Alkyl
Phosphate, Potassium C12-13 Alkyl Phosphate, Potassium Cetyl
Phosphate, Potassium Deceth-4 Phosphate, Potassium Dihydroxyethyl
Cocamine Oxide Phosphate, Potassium Dimethicone Copolyol Panthenyl
Phosphate, Potassium Dimethicone Copolyol Phosphate, Potassium
Glycerophosphate, Potassium Isostearth-2 Phosphate, Potassium
Lauryl Phosphate, Potassium Monofluorophosphate, Potassium
Trideceth-6 Phosphate, PPG-21 Butyl Ether Phosphate, PPG-25 Butyl
Ether Phosphate, PPG-35 Butyl Ether Phosphate, PPG-5-Ceteth-10
Phosphate, PPG-10 Cetyl Ether Phosphate, Sodium Coco PG-Dimonium
Chloride Phosphate, Sodium C13-15 Pareth-8 Butyl Phosphate, Sodium
C13-15 Pareth-8 Phosphate, Sodium Diceteareth-10 Phosphate, Sodium
Dihydroxycetyl Phosphate, Sodium Dilaureth-10 Phosphate, Sodium
Dioleth-8 Phosphate, Sodium Emuamidopropyl PG-Dimonium Chloride
Phosphate, Sodium Glyceryl Oleate Phosphate, Sodium Laureth-4
Phosphate, Sodium Lauroampho PG-Acetate Phosphate, Sodium Lauryl
Phosphate, Sodium Milkamidopropyl PG-Dimonium Chloride Phosphate,
Sodium Monofluorophosphate, Sodium Oleamidopropyl PG-Dimonium
Chloride Phosphate, Sodium Oleth-7 Phosphate, Sodium Oleth-8
Phosphate, Sodium Olivamidopropyl PG-Dimonium Chloride Phosphate,
Sodium Steareth-4 Phosphate, Sodium Sunfloweramidopropyl
PG-Dimonium Chloride Phosphate, Sodium Zinc Cetyl Phosphate,
Stearamidoethyl Diethylamine Phosphate, Stearamidoethyl
Ethanolamine Phosphate, Stearamidopropyl PG-Dimonium Chloride
Phosphate, Steardimonium Hydroxypropyl PEG-7 Dimethicone Phosphate,
Steareth-2 Phosphate, Steareth-3 Phosphate, Stearyl PG-Dimonium
Chloride Phosphate, Stearyl Phosphate, TEA-C12-13 Alkyl Phosphate,
TEA-Dimethicone Copolyol Phosphate, TEA-Polyphosphatel
Triceteareth-4 Phosphate, Triceteth-5 Phosphate, Tricetyl
Phosphate, Tri-C12-15 Pareth-n Phosphate, where n=2, 6, 8, 10,
Tricresyl Phosphate, Trideceth-n Phosphate, where n=3, 6, 10,
Trilaureth-4 Phosphate, Trilauryl Phosphate, Trioleth-8 Phosphate,
Trioleyl Phosphate, Trisodium Lauroampho PG-Acetate Chloride
Phosphate, Tristearyl Phosphate.
Non-limiting examples of amphoteric surfactants which may be
employed as emulsifiers include: Almondamido-propyl Betaine,
Apricotamidopropyl Betaine, Avocadamidopropyl Betaine,
Babassuamidopropyl Betaine, Behenamidopropyl Betaine, Behenyl
Betaine, Canolamidopropyl Betaine, Capryl/Capramidopropyl Betaine,
Cetyl Betaine, Cocamidoethyl Betaine, Cocamidopropyl Betaine,
Coco-Betaine, Coco/Oleamidopropyl Betaine, Decyl Betaine,
Hydrogenated Tallow Betaine, Isostearamidopropyl Betainem
Lauramidopropyl Betaine, Lauryl Betaine, Milkamidopropyl Betaine,
Minkamidopropyl Betaine, Myristamidopropyl Betaine, Myristyl
Betainem Oleamidopropyl Betaine, Oleyl Betaine, Olivamidopropyl
Betaine, Palmamidopropyl Betaine, Palmitamidopropyl Betaine, Palm
Kernelamidopropyl Betaine, Polytetrafluoroethylene Acetoxypropyl
Betaine, Ricinoleamidopropyl Betaine, Sesamidopropyl Betaine,
Soyamidopropyl Betaine, Stearamidopropyl Betaine, Stearyl Betaine,
Tallowamidopropyl Betaine, Tallow Betaine, Tallow Dihydroxyethyl
Betaine, Undecylenamidopropyl Betaine, Wheat Germamidopropyl
Betaine, Almondamidopropylamine Oxide, Babassuamidopropylamine
Oxide, Behenamine Oxide, Cocamidopropylamine Oxide, Cocamine Oxide,
Decylamine Oxide, Decyltetradecylamine Oxide, Diaminopyrimidine
Oxide, Dihydroxyethyl C8-10 Alkoxypropylamine Oxide, Dihydroxyethyl
C9-11 Alkoxypropylamine Oxide, Dihydroxyethyl C12-15
Alkoxypropylamine Oxide, Dihydroxyethyl Cocamine Oxide,
Dihydroxyethyl Lauramine Oxide, Dihydroxyethyl Stearamine Oxide,
Dihydroxyethyl Tallowamine Oxide, Hydrogenated Palm Kernel Amine
Oxide, Hydrogenated Tallowamine Oxide, Hydroxyethyl Hydroxypropyl
C12-15 Alkoxypropylamine Oxide, Isostearamidopropylamine Oxide,
Isostearamidopropyl Morpholine Oxide, Lauramidopropylamine Oxide,
Lauramine Oxide, Laurtrimonium Trichlorophenoxide, Milkamidopropyl
Amine Oxide, Minkamidopropylamine Oxide, Myristamidopropylamine
Oxide, Myristamine Oxide, Myristyl/Cetyl Amine Oxide,
Oleamidopropylamine Oxide, Oleamine Oxide, Olivamidopropylamine
Oxide, Palmitamidopropylamine Oxide, PPalmitamine Oxide, PEG-3
Lauramine Oxide, Sesamidopropylamine Oxide, Soyamidopropylamine
Oxide, Stearamidopropylamine Oxide, Stearamine Oxide,
Tallowamidopropylamine Oxide, Tallowamine Oxide, Wheat
Germamidopropylamine Oxide.
In one embodiment, the composition comprises about 0.01% to about
10% of an emulsifier component, preferably about 0.01% to about 8%,
more preferably 0.1% to about 5%, even more preferably 0.1% to
about 5%. Preferably, the emulsifier components form micro
emulsions with the polysiloxane components.
In one embodiment, the composition comprises about 0.01% to about
10% of a non-ionic emulsifier, preferably about 0.01% to about 8%,
more preferably 0.1% to about 5%, even more preferably 0.1% to
about 5%. Preferably, the emulsifier components form micro
emulsions with the polysiloxane components.
In one embodiment, the composition comprises about 0.01% to about
5% of a non-ionic emulsifier and at least one of about 0.01% to
about 5% of an anionic emulsifier/surfactant and an amphoteric
emulsifier/surfactant.
In one embodiment, the composition comprises about 0.01% to about
10% of a polysiloxane component. Preferably, the composition
comprises about 0.05% to about 6%, more preferably 0.1% to about 5%
of the polysiloxane component.
The popularity of polysiloxane, or dimethicone and dimethicone
derivatives, in shampoo compositions originate from their chemical
and physical properties. There is a weak inter-molecular
interaction between polysiloxane molecules and continuing rotation
around Si--C and Si--O bonds of the polysiloxane molecules because
of the longer Si--C and Si--O than C--C and C--O in regular organic
compound. Thus, there is much more space around the silicon atoms
and therefore render the polysiloxane excellent spreadbility.
Polysiloxane and derivatives also have high refractive index.
Furthermore, polysiloxane and derivatives can deliver a smooth
feel, detangling and sheen effect to hair.
In one embodiment, the polysiloxane component has the general
formula: ##STR00003## wherein a, b and c are independently 0 to
about 1000, preferably 0 to about 500, more preferably 0 to about
100. "s.c.c." as used herein means side chain component. A side
chain component is any atom, molecule, polymer or chemical entity
which may be covalently attached to the Si of the polysiloxane
component. For example, one side chain component may be a
hydrocarbon, for example a C1-C10 hydrocarbon or a hydroxide, and
another side chain component on the same polysiloxane component may
be a hydroxide.
In a preferred embodiment, the polysiloxane component has the
general formula: ##STR00004## wherein a, b and c are independently
0 to about 50.
In a preferred embodiment, the polysiloxane component comprises
about 2 to about 1000 Si, preferably about 4 to about 500 Si, more
preferably about 10 to about 300 Si.
In one embodiment, the polysiloxane component comprises at least
one side chain component A having the general formula: ##STR00005##
R1 is an H or a C1-C5 hydrocarbon, and X is a C1-C10 hydrocarbon, a
heteroatom or ##STR00006## wherein Z is a heteroatom and d is 0 to
about 6. Non-limiting examples of heteroatoms useful in this
invention includes N, O, S and P. In a preferred embodiment, Z is O
(oxygen) and d is about 3.
In one embodiment, the cyclic moiety of the side chain component is
saturated. In another embodiment, the cyclic moiety is substituted.
For example, the a side chain component A of the polysiloxane
component may include the general formula: ##STR00007## wherein R1,
R2, R3, R4, R5, R6, R7, R8 and R9 are independently an H, a C1-C10
hydrocarbon, an ester, carboxyl or a halogen, and X is a C1-C10
hydrocarbon, a heteroatom or ##STR00008## wherein Z is a heteroatom
and d is 0 to about 6. Preferably, X is a C1-C5 hydrocarbon or a
heteroatom. In one embodiment, X is a heteroatom selected from the
group consisting of N, O, Si, P, and S. In a preferred embodiment,
R1, R4, R5, R6 and R7 are H's and R2, R3, R8 and R9 are C1 alkyls.
Also, in a preferred embodiment, the cyclic moiety is a 5 or 6
member ring.
For example, a side chain component A of a preferred polysiloxane
component of this invention has the general formula:
##STR00009##
Side chain component A employed in accordance with this invention
preferably has a "hindered amine", or a secondary restricted
monoamine function group. Preferably, the molecules can be
partially protonated at normal shampoo pH range (pH 4-7). The
hindered amine functional group is believed to render several
beneficial effects. For example, it is believed that the hindered
amine polysiloxane (or dimethicone) has more hair or skin affinity
and give more conditioning effects. Furthermore, a shampoo
comprising a polysiloxane component with a hindered amine
functional group is more stable gives more hair softness,
smoothness and shine than a shampoo which does not have a hindered
amine group.
In one embodiment, the ratio of the Si to the side chain component
A in a polysiloxane component is 1:1, preferably 1:0.1, more
preferably 1:0.01, even more preferably 1:0.001.
In one embodiment, every other Si of the polysiloxane component has
a side chain component A. In another embodiment, every third Si has
the side chain component A. In yet another embodiment, every forth,
fifth or sixth Si has a side chain component A.
In one embodiment, a polysiloxane component comprises a set of
adjacent Si's of the polysiloxane component having side chain
component A followed by a set of adjacent Si's having side chain
components which are not side chain component A. See, for example,
the molecule M below: ##STR00010## wherein m and n are
independently 0 to about 200. See also the molecules identified at
www.nicnas.gov.au/publications/ CAR/new/NA/NAFULLR/NA08
00FR/NA819FR.pdf as of Nov. 30, 2001, the disclosure of which is
incorporated in its entirety herein by reference. In a preferred
embodiment, the polysiloxane component comprises propoxytetramethyl
piperidinyl dimethicone. Preferably, the propoxytetramethyl
piperidinyl dimethicone has a molecular weight of about 10,000 to
about 100,000.
In one embodiment, the polysiloxane component has a viscosity in
the range of about 1 cps (centistoke) to about 1,000,000 cps
(centistoke). Preferably, the polysiloxane component has a
viscosity in the range of about 100 cps to about 500,000 cps. More
preferably, the polysiloxane component has a viscosity in the range
of about 1,000 cps to about 100,000 cps. For example, the
polysiloxane component may have a viscosity of about 3,000 cps to
about 4,000 cps, preferably about 3,500 cps.
In one embodiment, the polysiloxane component has a viscosity in
the range of less than about 1,000,000 cps (centistoke).
Preferably, the polysiloxane component has a viscosity of less than
about 500,000 cps. More preferably, the polysiloxane component has
a viscosity of less than about 100,000 cps. Even more preferably,
the polysiloxane component has a viscosity of less than about
10,000 cps.
In one embodiment, the polysiloxane component has a viscosity in
the range of more than about 1 cps (centistoke). Preferably, the
polysiloxane component has a viscosity of more than about 1,000
cps. More preferably, the polysiloxane component has a viscosity of
more than about 3,000 cps. Even more preferably, the poly siloxane
component has a viscosity of more than about 10,000 cps.
The amine contents of the polysiloxane components vary with
viscosity. The particular value of amine content corresponding to a
certain range of viscosity may be determined readily by one of
ordinary skill in the art. The amine content of the polysiloxane
component may be about 200 to about 40,000 (ppm, N) at about room
temperature.
In one embodiment, the polysiloxane component comprises the
molecule M and has a viscosity of about 500 to about 6,000 cps at
room temperature. In a preferred embodiment, the polysiloxane
component comprises the molecule M and has a viscosity of about
1,000 to about 5,000 cps at room temperature. In a more preferred
embodiment, the polysiloxane component comprises the molecule M and
has a viscosity of about 2,000 to about 4,000 cps at room
temperature. In an even more preferred embodiment, the polysiloxane
component comprises the molecule M and has a viscosity of about
3,000 to about 4,000 cps, for example about 3,500 cps at room
temperature.
In one embodiment, the polysiloxane component is water insoluble.
In one embodiment, the polysiloxane component is a colorless,
viscous liquid. In one embodiment, the shelf life of the
polysiloxane is up to 12 months from date of manufacture.
In one embodiment, the composition comprises about 0.01% to about
10% of an emulsifier component and about 0.01% to about 10% of a
polysiloxane component. In one embodiment, the emulsifier component
is a mixture of non-ionic emulsifier and an anionic emulsifier
(and/or amphoteric emulsifier). For example, the emulsifier
component may comprise more than about 90%, more than about 80%,
more than about 50%, more than about 30% or more than about 10% of
non-ionic emulsifier.
Preferably, the emulsifier component and the polysiloxane component
form a micro-emulsion. For example, an emulsifier component
comprising an anionic emulsifier (e.g. Capryeth-3) and a non-ionic
emulsifier (e.g. Undeceth-5) is added to propoxytetramethyl
piperidinyl dimethicone and water to form a micro-emulsion of
propoxytetramethyl piperidinyl dimethicone.
The mixture containing the micro-emulsion may be designated as
"phase A". Phase A may be added to a detersive component,
designated as "phase B", to form a clear composition. A detersive
component comprises a chemical or formulation which is effective
for cleaning, preferably cleaning hair. For example, the detersive
component may comprise one or more of the anionic surfactants or
amphoteric surfactants identified herein. In one embodiment, a
detersive component may also include emulsifier components, for
example the non-ionic emulsifiers above.
In one embodiment, the composition comprises about 5% to about 60%
of the detersive component, preferably about 10% to about 50%, more
preferably about 20% to about 40%, even more preferably about 20%
to about 30%.
A detersive component may further comprise a shampoo additive
component. Shampoo additive components include any chemical or
formulation that adds to the beneficial qualities of a shampoo.
Shampoo additive components include, without limitation,
ingredients for boosting foam, protecting the integrity of
composition, increasing viscosity, covering the odor of raw
material and increasing the attraction of the shampoo. Non-limiting
examples of shampoo additive components include alkylamide MEA or
alkylamide DEA. Sodium Chloride, preservatives, fragrance and
colors.
In one embodiment, the composition comprises about 5% to about 60%
(by weight) of the detersive component, 0.01% to about 10% (by
weight) of the emulsifier component and about 0.01% to about 10%
(by weight) of the polysiloxane component. Preferably, the
polysiloxane component comprises a propoxytetramethyl piperidinyl
dimethicone.
In one embodiment, the ratio (by weight) of phase a:phase B is
about 0.1:99.9, 1:99, 2:98.
We hereby incorporate the disclosures of U.S. Pat. Nos. 5,540,952,
5,277,968 and 6,040,288 in their entirety by reference.
The invention is further illustrated by the following exemplar
formulations, which are intended as illustrations only. The thermal
and physical stabilities have been tested at both ambient and
elevated (40.degree. C.) temperatures. Examples 1-7 are the clear
detersive formulations. Examples 1-7 use the pre-emulsified
microemulsion in the formula; therefore, it is easy to make stable
and clear Propoxytetramethyl Piperidinyl Dimethicone detersive
emulsion. The composition is obtained by preparing phase A at
60-70.degree. C. and incorporating silicone phase A into phase B at
about 40-50.degree. C. for clear detersive composition. The
examples 8-11 are the opaque formulations and were made by directly
dispersing the hindered amine silicone into surfactant system. The
fragrance, preservatives and color are added and then mixing at
40-50.degree. C. afterwards. The pH for inventive detersive
composition should be within 4-7 pH ranges. "q.s." means quantum
sufficit, or as much as suffices.
Each of the percentages of the ingredients identified in the
Examples below may be individually varied to be higher or lower by
about 5% to about 40%, preferably about 5% to about 20%, more
preferably about 5% to about 10%, and would still be considered to
be within the scope of this invention.
In each of the Examples below, the viscosity of the identified
polysiloxane component may be about 1 cps to about 1,000,000 cps
(centistoke). For example, the propoxytetramethyl piperidinyl
dimethicone (Molecule M) of Example 1 may be about 2,000 cps; the
propoxytetramethyl piperidinyl dimethicone (Molecule M) of Example
2 may be about 3,000 cps; the propoxytetramethyl piperidinyl
dimethicone (Molecule M) of Example 3 may be about 3,500 cps; the
propoxytetramethyl piperidinyl dimethicone (Molecule M) of Example
4 may be about 4,000 cps; the propoxytetramethyl piperidinyl
dimethicone (Molecule M) of Example 5 may be about 100,000 cps; the
propoxytetramethyl piperidinyl dimethicone (Molecule M) of Example
6 may be about 200,000 cps; the propoxytetramethyl piperidinyl
dimethicone (Molecule M) of Example 7 may be about 400,000 cps.
EXAMPLE 1
TABLE-US-00001 Phase A Capryleth-3 1.12% Undeceth-5 1.68%
Propoxytetramethyl Piperidinyl Dimethicone 6.40% Water 16.2% Phase
B TEA-C12-13 Pareth-3 Sulfate 16.52% Sodium
Cocoamphohydroxypropylsulfonate 19.72% Cocamidopropyl Betaine 5.62%
Lauramide MEA 4.36% Disodium EDTA 0.05% Fragrance q.s.
Preservatives q.s. Sodium Chloride 1.70% Color q.s. Water to
100%
EXAMPLE 2
TABLE-US-00002 Phase A C9-11 Pareth-3 0.70% C14-15 Pareth-7 0.89%
Propoxytetramethyl Piperidinyl Dimethicone 4.30% Water 8.78% Phase
B Sodium C9-15 Pareth-3 Sulfate 12.58% Sodium Oleth Sulfate 18.72%
Coco-Betaine, Coco/Oleamidopropyl Betaine 4.84% Linoleamide MEA
4.15% Sodium Chloride 1.70% Fragrance q.s. Preservatives q.s. Color
q.s. Water to 100%
EXAMPLE 3
TABLE-US-00003 Phase A Glycereth-4 0.56% Isosteareth-6 0.85%
Propoxytetramethyl Piperidinyl Dimethicone 2.88% Water 8.05% Phase
B Sodium Cocoamphohydroxypropylsulfonate 17.58% Ammonium
Dodecylbenzenesulfonate 18.72% Myristyl Betaine Oleamidopropyl
Betaine 6.8% Myristamide MEA 4.53% Disodium EDTA 0.05% Fragrance
q.s. Preservatives q.s. Sodium Chloride 1.70% Color q.s. Water to
100%
EXAMPLE 4
TABLE-US-00004 Phase A Oleth-3 0.48% PPG-2-Ceteth-5 0.70%
Propoxytetramethyl Piperidinyl Dimethicone 3.50% Water 7.01% Phase
B Sodium C12-15 Alkyl Sulfate 15.58% Potassium Laureth-5
Carboxylate 18.72% Behenamide MEA 4.26% Soyamidopropyl Betaine 5.9%
Disodium EDTA 0.05% Fragrance q.s. Preservatives q.s. Sodium
Chloride 1.70% Color q.s. Water to 100%
EXAMPLE 5
TABLE-US-00005 Phase A Ceteth-3 0.24% Ceteareth-6 0.30%
Propoxytetramethyl Piperidinyl Dimethicone 1.50% Water 3.0% Phase B
Sodium C12-15 Alkyl Sulfate 13.58% Sodium C12-15 Pareth Sulfate
18.72% Tallowamidopropylamine Oxide 4.3% Cocamide MEA 3.56%
Disodium EDTA 0.05% Fragrance q.s. Preservatives q.s. Sodium
Chloride 1.70% Color q.s. Water to 100%
EXAMPLE 6
TABLE-US-00006 Phase A Deceth-3 0.28% Trideceth-3 0.42%
Propoxytetramethyl Piperidinyl Dimethicone 1.40% Water 4.20% Phase
B Sodium C9-15 Pareth-3 Sulfate 12.58% Sodium C12-13 Alkyl Sulfate
18.72% Cocamide MEA 3.37% Apricotamidopropyl Betaine 4.4% Disodium
EDTA 0.05% Fragrance q.s. Preservatives q.s. Sodium Chloride 1.70%
Color q.s. Water to 100%
EXAMPLE 7
TABLE-US-00007 Phase A Undeceth-3 0.06% C14-15 Pareth-7 0.075%
Propoxytetramethyl Piperidinyl Dimethicone 0.40% Water 0.75% Phase
B Sodium Oleth Sulfate 12.58% Sodium Myristyl Sulfate 18.72%
Ricinoleamidopropyl Betaine 3.95% Cocamide MEA 3.84% Disodium EDTA
0.05% Fragrance q.s. Sodium Chloride 1.70% Preservatives q.s. Color
q.s. Water to 100%
EXAMPLE 8
TABLE-US-00008 Sodium Trideceth Sulfate 16.53% TEA-C12-13 Pareth-3
Sulfate 18.72% Lauramidopropylamine Oxide 3.58% Cocamide MEA 3.84%
Disodium EDTA 0.05% Glycereth-4 0.36% Oleth-9 0.45%
Propoxytetramethyl Piperidinyl Dimethicone 2.25% Fragrance q.s.
Preservatives q.s. Sodium Chloride 1.70% Color q.s. Water to
100%
EXAMPLE 9
TABLE-US-00009 Ammonium Dodecylbenzenesulfonate 12.58% Potassium
Dodecylbenzenesulfonate 18.72% Isosteareth-4 0.74% Trideceth 7
1.26% Propoxytetramethyl Piperidinyl Dimethicone 4.20%
Cocoamidopropylamine Oxide 4.56% Cocamide MEA 3.84% Disodium EDTA
0.05% Fragrance q.s. Preservatives q.s. Sodium Chloride 1.70% Color
q.s. Water to 100%
EXAMPLE 10
TABLE-US-00010 Sodium Cocoamphohydroxypropylsulfonate 19.21%
Ammonium Lauryl Sulfosuccinate, 18.72% Cocamide MEA 3.84%
Myristamide MEA 2.89% Trideceth 4 1.40% C14-15 Pareth-6 2.10%
Propoxytetramethyl Piperidinyl Dimethicone 7.10% Disodium EDTA
0.05% Fragrance q.s. Preservatives q.s. Sodium Chloride 1.70% Color
q.s. Water to 100%
EXAMPLE 11
TABLE-US-00011 Potassium Laureth-5 Carboxylate, 22.58% Disodium
Lauramido MEA-Sulfosuccinate 18.02% Myristamide MEA 3.47% Cocamide
MEA 3.84% Trideceth 3 1.20% Trideceth 6 1.50% Propoxytetramethyl
Piperidinyl Dimethicone 8.00% Disodium EDTA 0.05% Fragrance q.s.
Preservatives q.s. Sodium Chloride 1.70% Color q.s. Water to
100%
While this invention has been described with respect to various
specific examples and embodiments, it is to be understood that the
invention is not limited thereto and that it can be variously
practiced with the scope of the following claims.
* * * * *
References