U.S. patent number RE32,957 [Application Number 06/729,678] was granted by the patent office on 1989-06-20 for absorbent article.
This patent grant is currently assigned to Johnson & Johnson. Invention is credited to Robert T. Elias, deceased, Donald R. Elias, executor.
United States Patent |
RE32,957 |
Elias, deceased , et
al. |
June 20, 1989 |
Absorbent article
Abstract
An absorbent article, such as a disposable diaper, is disclosed
which includes a moisture permeable facing layer, a backing layer,
and an absorbent layer disposed between said facing and backing
layers and including at least one pocket containing a uniform
admixture of discrete superabsorbent particles and discrete
introfying particles.
Inventors: |
Elias, deceased; Robert T.
(late of Downers Grove, IL), Elias, executor; Donald R.
(Westmont, IL) |
Assignee: |
Johnson & Johnson (New
Brunswick, NJ)
|
Family
ID: |
27111925 |
Appl.
No.: |
06/729,678 |
Filed: |
May 2, 1985 |
Related U.S. Patent Documents
|
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
954152 |
Oct 24, 1978 |
|
|
|
Reissue of: |
274931 |
Jun 18, 1981 |
04381783 |
May 3, 1983 |
|
|
Current U.S.
Class: |
604/368; 604/370;
604/375; 604/378 |
Current CPC
Class: |
A61F
13/5323 (20130101); A61F 13/536 (20130101); A61L
15/18 (20130101); A61L 15/60 (20130101); A61F
13/202 (20130101); A61F 13/511 (20130101); A61F
13/539 (20130101); A61F 2013/51042 (20130101); A61F
2013/530481 (20130101); A61F 2013/53051 (20130101); A61F
2013/530671 (20130101); A61F 2013/5395 (20130101) |
Current International
Class: |
A61F
13/15 (20060101); A61L 15/60 (20060101); A61L
15/16 (20060101); A61L 15/18 (20060101); A61F
13/20 (20060101); A61F 013/16 () |
Field of
Search: |
;604/368,370,378
;428/297,306,308 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Yasko; John D.
Assistant Examiner: Rose; Sharon
Parent Case Text
This is a continuation, of application Ser. No. 954,152, filed Oct.
24, 1978 now abandoned.
Claims
I claim:
1. An absorbent article comprising a moisture-permeable first outer
layer, an absorbent layer adjacent said outer layer, said absorbent
layer including at least one discrete pocket therein, at least a
portion of said pocket being moisture permeable, said pocket
containing therewithin a substantially dry uniform admixture of
discrete particulate water-insoluble hydrocolloid material and
discrete water-insoluble introfying paticles, each of said
introfying particles being physically separate from and not
chemically or otherwise bound or joined to any of the hydrocolloid
particles and which introfying particles maintain the particles of
hydrocolloid material in spaced relationship relative to one
another, and introfying particles having sufficient structural
integrity to substantially retain their size and shape when
subjected to compressive forces exerted by said hydrocolloid
particles as they swell and expand when wetted and a second outer
layer at the side of said absorbent layer opposite from said first
outer layer.
2. An absorbent article as set forth in claim 1 wherein said
absorbent layer includes a plurality of discrete pockets each
containing an admixture of hydrocolloid and introfying
particles.
3. An absorbent article as set forth in claim 2 wherein said
absorbent layer includes a cellulosic fibrous batt of loosely
compacted fibers adjacent to said pockets.
4. An absorbent article as set forth in claim 1 wherein said second
outer layer is moisture impermeable.
5. An absorbent article as set forth in claim 1 wherein said
absorbent article is a diaper, said first and second layers being
coterminous and secured to one another, and said absorbent layer
being smaller than said first and second outer layers and disposed
inwardly of the periphery thereof.
6. A disposable diaper comprising a moisture-permeable facing
layer, a moisture-impermeable backing layer, and an absorbent panel
sandwiched between said facing and backing layers, said absorbent
panel being a cellulosic fibrous batt of loosely compacted fibers
and including a plurality of discrete pockets therein, at least a
portion of each of said pockets being moisture permeable, and each
of said pockets containing therewithin a substantially dry uniform
admixture of discrete particles of water-insoluble hydrocolloid
material and discrete water-insoluble introfying particles, each of
said introfying particles being physically separate from and not
chemically or otherwise bound or joined to any of said hydrocolloid
particles, said particles of hydrocolloid material being retained
in spaced relationship relative to one another by said discrete
water-insoluble introfying particles disposed within each pocket,
said introfying particles having sufficient structural integrity to
substantially retain their size and shape when subjected to
compressive forces exerted by said hydrocolloid particles as they
well and expand when wetted.
7. A disposable diaper as set forth in claim 6 wherein said pockets
are spaced from one another.
8. A disposable diaper as set forth in claim 6 wherein said pockets
are interconnected.
9. A disposable diaper as set forth in claim 6 wherein each pocket
includes a moisture permeable membrane surrounding said
hydrocolloid and introfying particles.
10. A disposable diaper as set forth in claim 6 wherein said
absorbent layer includes wicking means on the face thereof adjacent
said moisture impermeable layer.
11. A disposable diaper as set forth in claim 10 wherein said
wicking means is integral with said batt and comprised of a
densified, compacted, porous, absorbent fibrous region having
relatively high cohesive strength, relatively good capillarity,
relatively good shape and volume stability and relatively high
fluid retentivity.
12. A disposable diaper as set forth in claim 6 wherein said
fibrous batt includes a plurality of openings extending between
said facing and backing layers, each opening having a pocket
therein.
13. A disposable diaper as set forth in claim 6 wherein said
pockets are disposed between said facing layer and fibrous
batt.
14. A disposable diaper as set forth in claim 6 wherein said
pockets are disposed between said fibrous batt and backing
layer.
15. An absorbent article comprising a moisture permeable facing
layer, a backing layer, and an absorbent panel sandwiched between
said facing and backing layers, said absorbent panel including at
least one discrete pocket therein, at least a portion of said
pocket being moisture permeable, and said pocket containing
therewithin a plurality of substantially dry discrete particles of
water-insoluble hydrocolloid material, said particles of
hydrocolloid material being retained in spaced relationship
relative to one another by discrete water-insoluble introfying
particles disposed within said pocket, each of said introfying
particles being physically separate from and not chemically or
otherwise bound or joined to any of said hydrocolloid particles,
said hydrocolloid particles and said introfying particles being
present in said pocket in a uniform admixture which has a bulk
volume from about 4 to 60 times as great as the bulk volume of said
hydrocolloid particles therein.
16. An absorbent article comprising a moisture permeable facing
layer, a backing layer, and an absorbent panel sandwiched between
said facing and backing layers, said absorbent panel including at
least one discrete pocket therein, at least a portion of said
pocket being moisture permeable, and said pocket containing
therewithin a plurality of substantially dry discrete particles of
hydrocolloid material, said particles of hydrocolloid material
being retained in spaced relationship relative to one another by
discrete introfying particles disposed within said pocket, each of
said introfying particles being physically separate from and not
chemically or otherwise bound or joined to any of said hydrocolloid
particles, said introfying particles having sufficient structural
integrity to substantially retain their size and shape when
subjected to compressive forces exerted by said hydrocolloid
particles as they swell and expand when wetted, said hydrocolloid
particles and said introfying particles being present in said
pocket in a uniform admixture which has a bulk volume from about 4
to about 60 times as great as the bulk volume of the hydrocolloid
particles therein.
17. An absorbent article as set forth in claims 16 wherein said
hydrocolloid and introfying particles occupy only a portion of
internal volume of said pocket.
18. An absorbent article as set forth in claim 16 wherein at least
a portion of said pocket is defined by an expansible membrane.
19. An absorbent article as set forth in claim 16 wherein said
pocket is formed by a bag formed of a porous, high wet strength,
light-weight filter paper.
20. An absorbent article as set forth in claim 19 wherein said bag
is formed of two sheets of filter paper secured to one another
round their periphery.
21. An absorbent article as set forth in claim 16 wherein said
introfying particles have a bulk density less than about 0.05
gr./ml.
22. An absorbent article as set forth in claim 16 wherein said bulk
volume of said uniform admixture is from about 20 to about 50 times
the bulk volume of the hydrocolloid particles therein. .Iadd.
23. An absorbent panel structure for an absorbent article,
comprising:
an absorbent layer comprising loosely compacted cellulosic fibrous
material; and
pocket means provided within said absorbent layer medially of upper
and lower portions of said loosely compacted cellulosic fibrous
material of said absorbent layer, said pocket means comprising
discrete individual pockets of superabsorbent hydrocolloid
material,
said upper and lower portions of said absorbent layer being
embossed toward each other throughout the thickness of each of said
upper and lower portions, at embossed areas,
said pockets of hydrocolloid material being spaced and physically
separated from each other by said embossed area between adjacent
ones of said pockets. .Iaddend. .Iadd.24. An absorbent panel
structure in accordance with claim 23, including
a densified, paper-like wicking layer comprising cellulosic fibrous
material formed integrally with said absorbent layer at a surface
of one of said upper and lower portions of said absorbent layer.
.Iaddend. .Iadd.25. An absorbent panel structure in accordance with
claim 24, wherein
said densified wicking layer is provided at one of the outer
surfaces of said absorbent layer. .Iaddend. .Iadd.26. An absorbent
panel structure in accordance with claim 25, wherein
said densified wicking layer is provided at the outer surface of
the lower
portion of said absorbent layer. .Iaddend. .Iadd.27. An absorbent
panel structure in accordance with claim 23, including
a plurality of said embossed areas arranged in spaced, parallel
relation to each other. .Iaddend. .Iadd.28. An absorbent panel
structure in accordance with claim 27, including
at least one of said embossed areas extending perpendicularly to
said parallel ones of said embossed area. .Iaddend. .Iadd.29. An
absorbent panel structure in accordance with claim 28,
including
a plurality of said embossed areas extending in spaced apart,
perpendicular relation to said parallel ones of said embossed
areas. .Iaddend. .Iadd.30. An absorbent panel structure in
accordance with claim 23, wherein
said discrete pockets of superabsorbent hydrocolloid material are
each bound by said embossed areas of said upper and lower portions
of said absorbent layer. .Iaddend. .Iadd.31. An absorbent panel
structure in accordance with claim 23, including
a moisture-permeable facing layer, and a moisture-impermeable
backing layer, said absorbent layer and said pocket means being
sandwiched between
said facing layer and said backing layer. .Iaddend. .Iadd.32. An
absorbent panel structure for an absorbent article, comprising:
an absorbent layer comprising absorbent loosely compacted fibrous
material; and
superabsorbent hydrocolloid material positioned within said
absorbent layer medially of upper and lower portions of said
loosely compacted fibrous material of said absorbent layer,
said absorbent panel structure comprising means for retaining said
superabsorbent hydrocolloid material in position medially of said
upper and lower portions of said absorbent layer including embossed
areas at which said upper and lower portions of said absorbent
layer are embossed toward each other throughout the thickness of
each of said upper and lower portions. .Iaddend. .Iadd.33. An
absorbent panel structure in accordance with claim 32,
including
a plurality of said embossed areas arranged in spaced parallel
relation to each other. .Iaddend. .Iadd.34. An absorbent panel
structure in accordance with claim 33, including
at least one of said embossed areas extending transversely of said
spaced parallel ones of said embossed areas. .Iaddend. .Iadd.35. An
absorbent panel structure in accordance with claim 34,
including
a plurality of said embossed areas extending transversely of said
spaced parallel ones of said embossed areas. .Iaddend. .Iadd.36. An
absorbent panel structure in accordance with claim 32,
including
a densified wicking layer comprising fibrous material formed
integrally with said absorbent layer at a surface of one of said
upper and lower
portions of said absorbent layer. .Iaddend. .Iadd.37. An absorbent
panel structure for an absorbent article, comprising:
an absorbent layer comprising loosely compacted cellulosic fibrous
material; and
pocket means provided within said absorbent layer medially of upper
and lower portions of said loosely compacted cellulosic fibrous
material of said absorbent layer, said pocket means comprising
discrete individual pockets of superabsorbent hydrocolloid
material,
said upper and lower portions of said absorbent layer being
embossed toward each other, throughout the thickness of each of
said upper and lower portions, at embossed areas,
said pockets of hydrocolloid material being spaced and physically
separated from each other by said embossed area between adjacent
ones of said pockets,
wherein said pocket means includes fluid permeable membrane means
for containing said individual pockets of hydrocolloid material.
.Iaddend.
.Iadd.38. An absorbent panel structure in accordance with claim 37,
wherein
each said individual pocket comprises an admixture of said
hydrocolloid material and discrete water-insoluble introfying
particles. .Iaddend. .Iadd.39. An absorbent panel structure for an
absorbent article, comprising:
an absorbent layer comprising absorbent loosely compacted fibrous
material; and
superabsorbent hydrocolloid material positioned within said
absorbent layer medially of upper and lower portions of said
loosely compacted fibrous material of said absorbent layer,
said absorbent panel structure comprising means for retaining said
superabsorbent hydrocolloid material in position medially of said
upper and lower portions of said absorbent layer including embossed
areas at which said upper and lower portions of said absorbent
layer are embossed toward each other, throughout the thickness of
each of said upper and lower portions,
wherein said retaining means comprises fluid permeable membrane
means for containing said superabsorbent material in discrete
individual pockets. .Iaddend. .Iadd.40. An absorbent panel
structure in accordance with claim 39, wherein
each said individual pocket comprises an admixture of said
superabsorbent material and discrete water-insoluble introfying
particles. .Iaddend.
Description
BACKGROUND OF THE INVENTION
This invention relates to an improved absorbent article and
particularly to a superabsorbent disposable diaper. More
particularly, this invention provides a superabsorbent batt or
panel component especially desirable for use in a disposable
diaper, but also having use in diverse absorbent articles such as
sanitary napkins, tampons, etc.
The most common absorbent material used in disposable diapers in a
mass of cellulose fibers. Although the cellulose itself will absorb
some liquid, causing the fibers to swell, most of the absorbed
liquid is held in the capilliary spaces among the fibers. The
liquid within the cellulose fibers is difficult to remove, but the
liquid held in between the fibers is removed readily by
squeezing.
Much effort has been expanded to find materials which will be more
cost effective than cellulose fibers with respect to liquid
absorbency and retention. Typical materials and various ways of
incorporating them into absorbent products are disclosed in U.S.
Pat. Nos. 3,344,789, 3,683,917, 3,783,872, 3,814,101, 3,815,601,
3,886,941, 3,890,974, 3,898,143, 3,900,378, 3,901,231, 3,901,236,
3,956,224, 3,957,605, 3,963,805, 4,058,124, 4,090,013, 4,103,062,
and 4,105,033.
Some of the more promising materials are in the form of granules,
beads, fibers, etc. which take liquid into their respective
structures resulting in swelling and becoming like a gel. These
materials are called superabsorbents. superabsorbents have been
placed among fibers to make absorbent pads which combine the
cushioning properties and the integrity of fibrous pads with the
liquid holding capacity of the superabsorbent. However, these
combinations have been disappointing because the liquid holding
capacity has fallen far short of the expected total for fibers and
superabsorbent combined.
Perhaps these failures can be attributed to the fact that a
particle of superabsorbent swells and in so doing pushes the fibers
apart and occupies void space among the fibers. This void space now
occupied by the superabsorbent could previously have been occupied
by liquid.
The present invention provides optimum use of the superabsorbent
effectiveness by confining the superabsorbent in a specially
allocated space so that it does not occupy voids between the
fibers.
SUMMARY OF THE INVENTION
According to the present invention, a disposable diaper or other
catamenial device is provided comprising a moisture permeable
facing layer, a backing layer which may be moisture impermeable,
and a fibrous absorbent panel affixed between said facing and
backing layers, said absorbent panel including one or more discrete
pockets therein, at least a portion of each of said pockets being
moisture permeable, and each of said pockets containing therewithin
a plurality of discrete particles of hydrocolloid material, said
particles of hydrocolloid material being retained in spaced
relationship relative to one another by discrete introfying
particles disposed within each pocket.
Suitable pockets can be individual cells or strips of cells or in
fact multiple cells in both length and width providing a type of
"quilt." Each of the discrete cells contains a mixture of a
superabsorbent and introfying particles.
The particulate absorbent materials contemplated herein contain
water-insoluble but water-swellable polymeric substances having at
least 25 percent of their molecular structure composed of
hydrophilic groups and capable of retaining water in an amount
which is at least 10 times the weight of the absorbent material in
dry form, and preferably about 15 to about 70 times the weight, or
more.
Illustrative particulate absorbent materials that are suitable for
the present purposes are powered graft copolymers of a
water-isoluble polysaccharide such as starch or cellulose having
hydrophilic chains of carboxyl, carboxylate-, and/or
carbamide-bearing moieties.
Water-insoluble starch or a wide variety of cellulosic fibers can
be utilized as starting materials for producing graft copolymers of
this general type. Typical of such cellulosic fibers are: cotton,
cotton linters, wood pulp, bagasse pulp, jute, rayon, and the like.
The polysaccharide chains are then modified by grafting thereon a
hydrophilic chain of the general formula ##STR1## wherein A and B
are selected from the group consisting of --OR.sup.3, --O(alkali
metal), --OHNH.sub.3, --NH.sub.2, wherein R.sup.1, R.sup.2 and
R.sup.3 are selected from the group consisting of hydrogen and
alkyl having 1 to 4 carbon atoms, wherein r is an integer having a
value of 0 to about 5000, s is an integer having a value of 0 to
about 5000, r plus s is at least 500, p is an integer having a
value of zero or 1, and q is an integer having a value of 1 to
4.
Preferred hydrophilic chains are hydrolyzed polyacrylonitrile
chains and copolymers of polyacrylamide and sodium polyacrylate. In
another preferred embodiment both ionizable polymeric moieties and
non-ionizable polymeric moieties can be grafted on the same
polysaccharide backbone.
While the detailed mechanism by which the grafting of the
hydrophilic chain or chains onto a starch or a cellulosic backbone
is not fully known, it is believed that grafting takes place
through a free radical mechanism whereby the free radical is
situated on the backbone which serves as a reducing agent, and the
hydrophilic chain is attached to the starch or cellulosic reducing
agent through a carbon linkage. The produced graft copolymer using
a cellulosic backbone is of the type ##STR2## wherein L represents
the hydrophilic chain of Formula I, above. The graft copolymer
using a starch backbone is substantially similar to that
represented by Formula I except that a starch backbone is present
in lieu of a cellulosic backbone.
Also suitable as absorbents are cross-linked synthetic polymers and
grafts on polysaccharides of synthetic polymers or synthetic
copolymers.
A particulate material that is particularly well suited for the
purposes of the present invention is Permasorb 10, a cross-linked
synthetic polymer commercially available in the form of a powder
from the National Starch and Chemical Corp.
The introfying particulate material is substantially inert mineral
substances of a desirable particle size which enhance the
impregnation of the super-absorbent with the liquid. In effect, the
introfying material is a separator. In other words, it separates
the hydrocolloid particles one from another. The introfying
material is non-reactive, non-swellable, and crush resistant, and
is a particulate material. Examples include particles of volcanic
rock such as perlite, diatomaceous earth such as Celite, inorganic
clay such as kaolin, and the like.
The material used to form the pockets is constructed, at least in
part, of a permeable material. Typical liquid permeable materials
are water-permeable paper, for example, high wet strength paper
used for tea bags, non-woven fabrics, creped tissues, reticulated
foam or screening, and the like. It is advantageous if the material
is heat sealable for ease in formation of the pocket cell. If not,
suitable adhesives or tape or other sealing means may be used. One
suitable water-permeable paper is a product of the Dexter
Corporation, Windsor Locks, Conn., identified as Grade 1234. It is
a high quality, two phase teabag paper made from a blend of manila
hemp and cellulose fibers in one phase and an integral layer of
heat sealable thermoplastic fibers in the other phase.
The disposable diaper of the present invention comprises a moisture
permeable facing layer, a moisture impermeable backing layer, and
an absorbent panel containing the pockets discussed above,
sandwiched between the facing and backing. Each pocket contains a
substantially uniform admixture of hydrocolloid particulate
material and introfying particles.
Several different types of facing materials may be used for the
diaper facing sheet. For example, the facing sheet may be made up
of a mixture of fibers consisting predominantly inexpensive short
cellulosic fibers such as wood pulp fibers or cotton linters, in
amounts of about 75% to about 98%, the balance being textile length
fibers such as rayon as described in U.S. Pat. No. 3,633,348 to
Liloia et al.
Facing sheet materials suitable for use in this invention can have
fabric weight in the range of about 1 to 5 oz./yd..sup.2 and
densities of less than 0.15 g./cc. generally in the range between
0.05 and 0.1 g./cc. The dry strength of the facing sheet for a
fabric having a weight of about 1.5 oz./yd.sup.2 is at least 0.15
lbs./in. of width in the machine direction and at least 0.1
lbs./in. of width in the cross direction. Such fabrics have
unusually good elongation, loft, softness and drape characteristics
in comparison to prior products incorporating any substantial
amount of short fibers.
The facing sheet may also be made of an apertured, non-woven fabric
which is formed, for example, in accordance with the teachings of
commonly assigned U.S. Pat. Nos. 2,862,251; 3,081,514 and
3,081,515. Briefly, such fabrics are foraminous structures wherein
groups or groupings of fibers have been rearranged from a fibrous
nonwoven starting web into positions surrounding less dense fabric
portions by passage of a fluid through the starting material. The
fibers within the groupings are mechanically interlocked, and may
be arranged into various patterns, as is well known by those
skilled in the art. A suitable binder may be utilized to help
retain the fibers in their rearranged locations, as is also well
known by those skilled in the art. The fabric can be made of
naturally occurring fibers, synthetic fibers, or blends thereof.
Typical facing sheets made of a polyester type material can have a
weight of about 0.75 oz./yd..sup.2.
In addition, the facing sheet can be formed of a non-apertured
material, such as a nonwoven isotropic web, or the like. In all of
the aforementioned facing materials, the material should be
relatively hydrophobic so as to retard wicking within the facing
layer.
The highly moisture-absorbent fibrous pad or batt, which usually is
substantially rectangular in shape but smaller than the facing
sheet and the backing sheet, can be formed in accordance with the
teachings of U.S. Pat. No. 3,612,055 to Mesek et al. If desired, a
highly moisture-absorbent layer can be provided substantially
coextensive with backing sheet and facing sheet.
A suitable backing sheet material for the diapers embodying the
present invention can be an opaque polyethylene web about 0.001
inch thick. Another suitable material for this purpose is a
polyethylene terephthalate web having a thickness of about 0.005
inch. Typical disposable diapers which can be fitted with tab-type
adhesive fasteners described hereinabove are shown in U.S. Pat. No.
3,612,055 to Mesek et al. and U.S. Pat. No. 3,683,916 to Mesek et
al.
The absorbent panel is also identified as an absorbent batt.
The body of the batt is substantially more wettable than the facing
layer and tends to draw liquid away from the facing layer. The
individual fibers of the batt are extremely wettable, generally
having liquid-fiber contact angles below about 15.degree. and
approaching zero in the optimum embodiment, as described in detail
in the above-mentioned application. The wickability, or
preferential absorptivity of the body of the batt for water is
limited, however, by its low density which results in a large
effective capillary radius for the capillaries between adjacent
fibers.
The pressure causing a liquid to enter a cylindrical capillary is
expressed by the equation:
wherein
P is a capillary pressure,
.gamma. is the surface tension of the liquid,
.theta. is the liquid-fiber contact angle, and r is the capillary
radius.
With a given liquid, the pressure (capillary force) increases with
the cosine of the liquid-fiber contact angle (reaching a maximum
where the angle is zero), and decreases with narrower capillary
radii so that narrower capillaries will draw liquid from wider
ones.
The relative wickability between the facing layer and the body of
the batt is affected by both the relative densities of the layers
and the relative wettability of the individual fibers in each
layer. The facing layer is sometimes more dense than the body of
the batt, tending to provide greater wickability in the facing
layer, but even then the individual fibers of the batt have
substantially smaller liquid-fiber contact angles than those of the
facing layer, overcoming the density difference and providing a
substantial overall increase in capillary pressure to absorb liquid
into the body of the batt.
A densified fiber layer of the batt is formed on the surface which
contacts the backing. It provides the maximum capillary pressure
because it combines the very low contact angle of the fibers of the
batt with the high density (small capillary radius) of the
densified fibers.
When urine is voided into an area in the facing layer, it partially
wets the facing layer and is absorbed therein, spreading out to a
limited extent to form a roughly circular wetted zone therein. When
the urine passes through the facing layer and comes into contact
with the body of the batt, it is preferentially absorbed into the
body of the batt because of the enhanced wettability thereof. It
spreads within the body of the batt to wet a roughly circular zone
therein that is slightly larger than the wetted zone in the facing
layer.
The urine is transported relatively rapidly in all directions of
the densified layer because the densified layer is continuous over
one face of the absorbent panel.
On occasions when a substantial amount of urine has been voided,
the densified layer becomes saturated and excess urine, aided by
the presence of the impervious sheet and its adherence to the
densified layer in a discontinuous pattern substantially throughout
the interface therebetween, flows into the previously dry portions
of the body of the batt, and finally into the previously dry
portions of the facing layer. It is to be noted, however, that such
flow from a saturated densified layer is from the outermost
portions of the diaper inward so that most of the facing layer
remains dry until all other fibrous portions of the diaper are
saturated.
The densified layer of the batt, for the reasons explained above,
creates a high capillary pressure which tends to move liquid away
rapidly from the area of the original wetting. However, the speed
of liquid migration in terms of volume per unit time is limited in
the densified layer because of the resistance provided by its small
capillaries.
In accordance with the present invention a substantially uniform
admixture of a superabsorbent in particulate form and introfying
particulate material are provided in one or more pockets in the
absorbent panel of a disposable diaper. The admixture is placed in
the pockets in a portion such that when the superabsorbent swells
there is adequate space in the enclosed pocket to retain the
swollen substance. The pockets can be placed in the absorbent panel
between the densified layer and the rest of the panel. They may
also be placed between the densified layer and the liquid
impervious backing layer. In a preferred embodiment, a section of
the absorbent panel is cut out and the pocket or pockets of the
admixture are placed in the cut-out space.
While the size of the introfying particles is not critical to the
present invention, it is preferred that they be no larger than the
hydrocolloid particles. And, for purposes of the present invention,
the introfying particles need not be of uniform size or shape.
However, it is important that the introfying particles be blended
in a uniform admixture with the hydrocolloid particles, and that
the admixture have a bulk volume that is substantially greater than
the bulk volume of the hydrocolloid particles themselves. In this
regard, it is preferred that the admixture have a bulk volume that
is from about 4 to about 60 times as great as the bulk volume of
the hydrocolloid particles therein, with the most preferred
admixture-hydrocolloid range being from about 20 to about 50. Bulk
volume ratios of the type contemplated herein not only provide the
desired spacing for the hydrocolloid particles, but also provide
room for expansion of the hydrocolloid particles when they are
wetted to capacity. Bulk volumes of the particulate materials may
be measured by placing the particulate material in a graduated
cylinder and shaking or vibrating it until constant volume is
obtained.
In a specific example, when Permasorb 10, mentioned above, is the
hydrocolloid and Celite FC (a diatomaceous earth commercially
available from Johns-Manville Corp.) is the introfying particle, an
admixture of equal weights of the two materials produces a total
bulk volume which is about 4.6 times the bulk volume of the
hydrocolloid particles therein, and an increase of the weight
proportion of the Celite FC particles to six times the weight of
the hydrocolloid particles produces a total bulk volume which is
about 23.8 times the bulk volume of the hydrocolloid particles
therein.
With a preferred introfying particle, such as perlite, which has a
bulk density less than about 0.05 g./ml., the increase in bulk
volume is substantially greater. A mixture of 2 parts by weight of
perlite per part of Permasorb 10 produces a bulk volume which is
about 22.8 times the bulk volume of hydrocolloid particles therein;
and a mixture of 5 parts by weight of perlite per part of Permasorb
10 produces a bulk volume which is about 49.1 times as great as the
bulk volume of the hydrocolloid particles therein.
When hydrocolloid particles of the type contemplated herein are
blended with introfying particles of the type set forth above in
bulk volume ratios as described above, the introfying particles
cooperate to maintain the hydrocolloid particles in spaced
relationship thereby preserving the interstitial network between
the hydrocolloid particles and permitting liquid to circulate
through the void areas and contact the exposed surfaces of all of
the hydrocolloid particles. The introfying particles prevent
adjacent hydrocolloid particles from coalescing when they are
wetted and begin to swell, thereby maximizing utilization of the
large absorptive capacity of the hydrocolloid particles. And, since
the admixture is confined with one or more discrete pockets in the
absorbent layer of the absorbent product, the swelling hydrocolloid
particles do not expand in the void areas in the adjacent fibrous
portion of the absorbent layer so that the capillary network of the
fibrous portion is not impaired .
While, as noted above, the inventive concept of the present
application has applicability to a wide variety of absorbent
products, a disposable diaper is illustrated in the accompanying
drawings, in which:
FIG. 1 is a perspective view of a diaper in the configuration
assumed after the diaper is placed on an infant;
FIG. 2 is an enlarged perspective view of the diaper of FIG. 1 laid
out flat, with a portion broken away for clarity of
illustration;
FIG. 3 is a cross-sectional view taken generally along line 3--3 of
FIG. 2;
FIG. 3A is an enlarged cross-sectional view through one of the
discrete pockets of the present invention containing a uniform
admixture of hydrocolloid and introfying particles;
FIGS. 4 and 5 are enlarged plan views showing further embodiments
of the invention; and
FIG. 6 is a cross-sectional view taken generally along line 6--6 of
FIG. 4;
FIG. 7 is an enlarged perspective view of the diaper of a specific
embodiment of the present invention;
FIG. 8 is a cross-sectional view taken generally along Line 7--7 of
FIG. 7;
FIG. 9 is an enlarged perspective view of the diaper of another
specific embodiment;
FIG. 10 is a cross-sectional view taken generally along Line 9--9
of FIG. 9;
FIG. 11 is an enlarged perspective view of the diaper of a still
further specific embodiment;
FIG. 12 is a cross-sectional view taken generally along Line 11--11
of FIG. 11.
DESCRIPTION OF ILLUSTRATED EMBODIMENTS
While this invention is susceptible of embodiment in many different
forms, there is shown in the drawings and will herein be described
in detail preferred embodiments of the invention with the
understanding that the present disclosure is to be considered as an
exemplification of the principles of the invention and is not
intended to limit the invention to the embodiments illustrated. The
scope of the invention will be pointed out in the appended
claims.
The diaper of the present invention is indicated in its entirety at
10 in FIG. 1, and is comprised of a first outer layer 12 which is
moisture permeable and adapted to be positioned adjacent the skin
of an infant, a second outer layer 14 which is moisture impermeable
and adapted to be disposed outwardly and form a moisture barrier
when the diaper is worn, and an absorbent layer or panel 16 which
is disposed between layers 12 and 14 and which is adapted to absorb
and contain liquid passing through facing layer 12 and retained by
backing layer 14. In the illustrated embodiment layers 12, 14 and
16 are rectangular, with layers 12 and 14 being the same size and
coterminous with one another, and with layer 16 being smaller than
layers 12 and 14 and generally centered with respect thereto so
that generally equally sized marginal portions of layers 12 and 14
extend beyond the sides and ends of layer 16, as can be best seen
in FIG. 2.
As noted above, backing layer 14 is preferably formed of a thin
thermoplastic sheet, such as embossed polyethylene, to impart
strength to the diaper as well as providing a moisture barrier.
During manufacturing of the diaper, a plurality of transversely
spaced, longitudinally extending glue lines 18 are deposited on
backing layer 14, and facing layer 12 is secured to backing layer
14 by glue lines that are positioned laterally outwardly of the
side edges of panel 16, and by the ends of glue lines that extend
outwardly beyond the ends of panel 16. Glue lines 18 in the central
portion of the backing layer 14 retain the panel in fixed relation
relative to the facing layer 12 and backing layer 14. As noted
above, absorbent layer 16 is preferably formed from a batt of
loosely compacted cellulosic fibers of papermaking length, and the
surface of layer 16 adjacent backing layer 14 is preferably
moistened and compacted during manufacture to provide a relatively
dense, paper-like wicking layer having enhanced strength for
securement to the backing layer.
The nature of the facing layer 12 is not critical to the present
invention so long as it is moisture permeable, and it may be formed
of generally hydrophobic non-woven fabrics mentioned above, or of a
thermoplastic film having a multiplicity of fine apertures therein.
In the latter case, glue lines 18 may be eliminated in whole or in
part and the facing and backing layers may be heat sealed to one
another. In some instances, as for example when the facing layer is
an apertured non-woven fabric or a thermoplastic film having
relatively large openings therein, in order to prevent fibers from
the absorbent panel for dusting or linting through the facing
layer, a moisture permeable layer, such as a high wet strength
tissue layer, may be interposed between the facing and absorbent
layer.
Tape closures 20 may be provided at one end of the diaper, and
secured to the backing and/or facing layers for securing the diaper
about the torso of an infant in the configuration shown in FIG. 1,
as is well understood in the art.
In order to provide increased absorptive capacity as well as an
increased rate of absorption, absorbent panel 16 has one or more
cells or pockets 22 therein each of which includes a uniform
admixture of discrete hydrocolloid particles 24 and discrete
introfying particles 26. In accordance with the present invention,
the hydrocolloid particles are dry, solid granules when the diaper
is manufactured, having been ground or otherwise formed to maximize
the exposed surface area of the hydrocolloid material. The
hydrocolloid particles need not have the same size or shape, or
chemical composition; since the present invention contemplates that
blends of chemically different hydrocolloid materials may be
utilized. However, as presently understood, it is desired that the
hydrocolloid particles be chemically identical, and generally of
the same size and shape.
The introfying particles 26 are physically separate from and not
chemically or otherwise bound or joined to the hydrocolloid
particles 24. Particles 26 are dry, solid granules that are blended
and distributed in a uniform admixture with particles 24, and are
present in sufficient quantity to segregate and separate the
hydrocolloid particles from one another, even when the hydrocolloid
particles swell and expand upon being wetted. The introfying
particles contemplated by the present invention such as perlite and
Celite mentioned above, have sufficient structural integrity to
substantially retain their size and shape when subjected to
compressive forces exerted by the swelling and expanding
hydrocolloid particles. And, since the bulk volume of the admixture
is substantially greater than the bulk volume of the hydrocolloid
particles, the introfying particles function to preserve the
interstices around the hydrocolloid particles thereby insuring
liquid impinging upon the pockets 22 will have access to all of the
hydrocolloid particles therein.
In the embodiment of FIGS. 1-3 four individually separate and
distinct pocket 22 are provided in panel 16. The number, size,
shape, location and spacing of the pockets 22 is not critical to
the present invention, and a variety of different arrangements will
be hereinafter described. However, each pocket is
moisture-permeable, at least in part, so that liquid can have
access to the contents of the pockets; and each pocket is
constructed and arranged so that the hydrocolloid particles can
expand relatively freely and distend the constraining walls of the
pockets if necessary, without expanding into and thereby
diminishing the absorptive capacity provided by the capillary
network of fibrous panel 16.
With reference to FIGS. 3 and 3A, pockets 22 are illustrated as
being disposed medially between the opposite faces of the panel. In
this arrangement the lowermost portion of the panel, i.e., the
portion below pockets 22 and adjacent backing layer 14 is deposited
first, followed by placement of the pockets 22 and deposition of
the portion of the panel above pockets 22. The present invention
also contemplates that the pockets 22 may be deposited directly on
backing sheet 14 during manufacture, and that the panel 16 may be
air laid thereover. With this technique, it is possible to have one
face of each pocket disposed in direct contact with the backing
sheet and the opposite face either in direct contact with the
facing sheet or separated therefrom by a thin fibrous overlay. In
instances where it is contemplated that the pockets 22 be in direct
contact with both the facing and backing layers, the panel may be
separately formed and cut-out in the areas to receive the pockets
22, which may be inserted in a separate manufacturing step. The
present invention also contemplates that pockets 22 containing
hydrocolloid and introfying particles may be positioned between the
panel 16 and the facing layer 12 and/or between the panel 16 and
the backing layer 14.
In the embodiment of FIGS. 1-3 each pocket 22 is illustrated as
being formed by a pair of sheet-like membranes 28. Membrances 28
are moisture pervious members having a pore size sufficient to
permit entry of liquid, but small enough to prevent the
hydrocolloid particles and introfying particles from escaping.
illustratively the membrances 28 may be formed of the high wet
strength, inherently heat-sealable Dexter tea bag paper mentioned,
and such membranes may be heat sealed to one another around their
perimeter, as is shown at 28a in FIG. 3. The present invention also
contemplates the utilization of bags and pouches which may, for
example, be formed by folding a single moisture permeable membrane
upon itself and sealing facing surfaces together to form a closed
cell or pocket.
While the embodiment of FIGS. 1-3 shows the pockets 22 as being
spaced from one another, the present invention also contemplates
the provision of a plurality of connected, yet independent and
non-communicating pockets. Two of such arrangements are illustrated
in FIGS, 4, 5 and 6, and identical reference characters are
utilized in these views to designate those elements which
correspond to like elements in the embodiment of FIGS. 1-3.
With specific reference to FIGS. 4 and 6, pocket means 30 is
illustrated as being disposed medially of absorbent fibrous panel
16, which is sandwiched between facing layer 12 and backing layer
14. The facing, backing and absorbent layer may be of the type
described above, and it will be noted from FIG. 6 that a wicking
means in the form of densified, cellulosic, paper-like skin 32 is
shown as being formed integrally on the surface of panel 16
adjacent backing layer 14.
Pocket means 30 is defined by a pair of thin flexible membranes 34
and 36 which have their facing surfaces secured to one another in a
plurality of generally equally spaced perpendicularly disposed,
longitudinally and transversely extending seal zones 38. As a
result, pocket means 30 includes a plurality of longitudinally and
transversely adjacent individual pockets 40 which are secured to
one another, but which have their contents retained physically
separate from one another. As is evident from FIGS. 4 and 6, pocket
means 30 defines a quilt like member, and the entire diaper may be
given a quilted appearance by passing it through the nip of
embossing rolls to cause indentations 42 in the facing layer and 44
in the backing layer in alignment with the seal zones 38.
As with the previously described embodiment, membranes 34 and 36
are preferably inherently heat sealable for ease of manufacture. At
least membranes 34 is moisture permeable, so that liquid passing
through facing layer 12 and absorbed in panel 16 will have acess to
the contents of pockets 40. In a simplified arrangement which
eliminates membrane 36, pocket means 30 may be disposed between
panel 16 and backing layer 14, in which case membrane 34 may be
secured directly to backing layer 14, with the individual pockets
being formed therebetween.
Referring now to FIG. 5, a further embodiment of a diaper having a
quilted appearance is illustrated, with individual honeycomb-like
cells 48 being defined between the intersections of sinuous sealing
and embossing zones 46. It is believed that a wide variety of other
interconnected yet non-communicating pocket arrangements will be
readily apparent to those skilled in the art, and the arrangements
of FIGS. 4-6 have been included for purposes of example only.
Referring now to FIGS. 7 and 8, a further embodiment of a diaper 50
is illustrated with individual pockets 62 extending between the
facing 52 and the backing 54. Each pocket includes hydrocolloid
particles and introfying particles as shown in FIG. 3a. Each pocket
62 is formed by a sheet-like membrane 68. The membranes 68 are
moisture pervious. An absorbent fibrous panel 56 surrounds the
pockets 62 between the facing 52 and the backing 54. The absorbent
panel 56 and the facing 52 are adhere to the backing by glue lines
58. Referring now to FIGS. 9 and 10 a further embodiment of a
diaper 70 is illustrated with individual pockets 82 placed between
the facing 72 and an absorbent fibrous panel 76. Each pocket 82
includes hydrocolloid particles and introfine particles as shown in
FIG. 3a. Also each pocket 82 is formed by a sheet-like membrane 88.
The membanes 88 are moisture-pervious. The absorbent panel 76 and
the facing 72 are adhere to the backing 74 by glue lines 78.
Referring now to FIGS. 11 and 12, a further embodiment of a diaper
90 is illustrated with individual pockets 102 placed between an
absorbent fibrous panel 96 and the backing 94. Each pocket 102
includes hydrocolloid particles and introfine particles as shown in
FIG. 3a. Each pocket 102 is formed by a sheet-like membrane 108.
The membranes 108 are moisture-pervious. The absorbent panel 96 and
the facing 92 are adhere to the backing 94 by glue lines 98.
In FIGS. 7, 9, and 11 the diapers are secured by tape tabs 60, 80,
and 100, respectively.
As is set forth above, each of the pockets associated with the
absorbent panels of the various diapers contemplated herein
contains a uniform admixture of discrete hydrocolloid particles and
introfying particles, with the particles of the admixture being
present in a bulk volume range of from about 4 to about 60 times
the bulk volume of the hydrocolloid particles themselves, and with
the particles of the admixture preferably being present in a bulk
volume range of from about 20 to about 50 times the bulk volume of
the hydrocolloid particles themselves. In each of the disclosed
arrangments, the hydrocolloid and introfying particles occupy only
a portion of the internal volume of the individual pockets, so that
the hydrocolloid particles can expand without rupturing the walls
of the individual pockets. The present invention also contemplates
that the walls or membranes of the individual pockets may be
capable of expansion, such as by pleating or creping the materials
from which the pockets are formed.
With pockets of the type described above, when the hydrocolloid
particles are wetted and begin to swell, they expand to
substantially fill the internal volume of the individual pockets,
after which the individual pockets themselves may expand. The
expanding walls will push the adjacent fibers of the batt aside,
but the swelling hydrocolloid particles will remain trapped within
the pockets and will not occupy the capillary voids of the fibrous
panel. As a result the total absorptive capacity of the diaper is
significantly increased. Since the unique pocket arrangement of the
present invention significantly improves the total absorptive
capacity of the diaper, a lesser amount of fibrous material may be
used for a diaper of a given desired absorptive capacity, with the
result that the dry diaper is less bulky and more comfortable to
the infant.
While the present invention has been described in detail with
respect to a diaposable diaper, the present invention should be
considered as being applicable to absorbent articles generally,
unless indicated to the contrary in the appended claims.
* * * * *