U.S. patent number 5,609,210 [Application Number 08/468,678] was granted by the patent office on 1997-03-11 for apparatus and method for suppressing a fire.
This patent grant is currently assigned to Olin Corporation. Invention is credited to Lyle D. Galbraith, Gary F. Holland, Robert M. Mitchell, Donald R. Poole.
United States Patent |
5,609,210 |
Galbraith , et al. |
March 11, 1997 |
Apparatus and method for suppressing a fire
Abstract
There is provided an apparatus for suppressing a fire. The
apparatus includes a gas generator charged with a combustive
propellant. Upon ignition, the combustive propellant generates a
copious volume of gas. The gas is directed by a first conduit to a
chamber containing a packed powder that is effective to suppress a
fire. A second conduit directs the gas driven packed powder to the
fire. In one embodiment, the fire suppressing packed powder is
magnesium carbonate.
Inventors: |
Galbraith; Lyle D. (Redmond,
WA), Holland; Gary F. (Snohomish, WA), Poole; Donald
R. (Woodinville, WA), Mitchell; Robert M. (Issaquah,
WA) |
Assignee: |
Olin Corporation (Redmond,
WA)
|
Family
ID: |
26767097 |
Appl.
No.: |
08/468,678 |
Filed: |
June 6, 1995 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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248932 |
May 26, 1994 |
5423384 |
Jun 13, 1995 |
|
|
82137 |
Jun 24, 1993 |
5449041 |
Sep 12, 1995 |
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Current U.S.
Class: |
169/26; 169/61;
169/62; 169/77; 169/84 |
Current CPC
Class: |
A62C
35/023 (20130101); A62C 99/0018 (20130101); C06D
5/06 (20130101) |
Current International
Class: |
A62C
35/00 (20060101); A62C 35/02 (20060101); A62C
39/00 (20060101); C06D 5/00 (20060101); C06D
5/06 (20060101); A62C 035/00 () |
Field of
Search: |
;169/5,6,7,9,11,12,26,27,28,30,35,60,61,62,71,72,77,78,84,85
;149/19.6,35,36,61,77 ;252/2,4,5 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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776622 |
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Jan 1981 |
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SU |
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1034752 |
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Aug 1983 |
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SU |
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1082443 |
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Mar 1984 |
|
SU |
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1217430 |
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Mar 1986 |
|
SU |
|
1475685 |
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Apr 1989 |
|
SU |
|
Other References
The Journal of Fire & Flammability, vol. 12 (Jul. 1981)
.COPYRGT.1981 Technomic Publishing Co., Inc. "HF and HBr Production
From Full Scale CF3Br(Halon 1301) Fire Suppression Tests" by
Sheinson et al, appearing at pp. 229-235. .
The Journal of Fire & Flammability, vol. 13 (Oct. 1982)
.COPYRGT.1982 Technomic Publishing., Inc. "Fire Control in Aircraft
1 Comparative Testing of Some Dry Powder Chemical Fire
Extinguishants and a New Effective System" by Ling et al, appearing
at pp. 215-236. .
The New Encyclopedia Britannica (vol. 19) 15th Edition
.COPYRGT.1986. "Fire Prevention and Control" appearing at pp.
186-188. .
Scientific American (Jun. 1993) vol. 268; No. 6. "Extinguished-- A
Champion Firefighter Goes Down for the Count" by W. W. Gibbs,
appearing at p. 136..
|
Primary Examiner: Pike; Andrew C.
Attorney, Agent or Firm: Rosenblatt; Gregory S. Garabedian;
Todd E.
Parent Case Text
CROSS REFERENCE TO RELATED APPLICATION
This patent application is a division of U.S. patent application
Ser. No. 08/248,932 filed May 26, 1994 which matured into U.S. Pat.
No. 5,423,384 to D. Galbraith et al. issued Jun. 13, 1995 that was
a continuation-in-part of U.S. patent application Ser. No.
08/082,137 filed Jun. 24, 1993 which matured into U.S. Pat. No.
5,449,041 issued to Lyle D. Galbraith on Sep. 12, 1995.
Claims
We claim:
1. An apparatus for suppressing a fire, said apparatus
comprising:
a) a gas generator having a combustive propellant effective to
produce a gas yield in excess of 1.5 moles per 100 grams of
propellant;
b) a packed powder contained within a chamber and selected from the
group consisting of magnesium hydroxide, calcium hydroxide,
strontium hydroxide, barium hydroxide, aluminum hydroxide,
magnesium carbonate, potassium sulfate, and mixtures thereof;
c) a first conduit providing a passageway between said gas
generator and said chamber; and
d) a second conduit providing a passageway between said chamber and
said fire.
2. The apparatus of claim 1 wherein said gas generator contains a
mixture of a nitrogen rich fuel and an oxidizer in a fuel to
oxidizer ratio, by weight, of from about 1:1 to about 1:2.
3. The apparatus of claim 2 wherein said fuel is 5-aminotetrazole
and said oxidizer is selected from the group consisting of
strontium nitrate, potassium chlorate, and mixtures thereof.
4. The apparatus of claim 3 wherein said packed powder is magnesium
carbonate.
5. The apparatus of claim 1, wherein the packed powder has a
particle size from 5 to 100 microns.
6. The apparatus of claim 5, wherein particle size is from about 10
to 50 microns.
Description
BACKGROUND OF THE INVENTION
This invention relates to an apparatus and a method for suppressing
a fire. More particularly, a gas generator produces an elevated
temperature first gas which interacts with a vaporizable liquid to
generate a second gas having flame suppressing capabilities.
Fire involves a chemical reaction between oxygen and a fuel which
is raised to its ignition temperature by heat. Fire suppression
systems operate by any one or a combination of the following: (i)
removing oxygen, (ii) reducing the system temperature, (iii)
separating the fuel from oxygen, and (iv) interrupting the chemical
reactions of combustion. Typical fire suppression agents include
water, carbon dioxide, dry chemicals, and the group of halocarbons
collectively known as Halons.
The vaporization of water to steam removes heat from the fire.
Water is an electrical conductor and its use around electrical
devices is hazardous. However, in non-electrical situations, when
provided as a fine mist over a large area, water is an effective,
environmentally friendly, fire suppression agent.
Carbon dioxide (CO.sub.2) gas suppresses a fire by a combination of
the displacement of oxygen and absorption of heat. Carbon dioxide
gas does not conduct electricity and may safely be used around
electrical devices. The carbon dioxide can be stored as compressed
gas, but requires high pressure cylinders for room temperature
storage. The cylinders are heavy and the volume of compressed gas
limited. Larger quantities of carbon dioxide are stored more
economically as a liquid which vaporizes when exposed to room
temperature and atmospheric pressure.
When exposed to room temperature and atmospheric pressure, the
expansion characteristics of liquid CO.sub.2 are such that
approximately one third of the vessel charge freezes during the
blow down process. Only about two thirds of the CO.sub.2 is
exhausted in a reasonable time. The remainder forms a dry ice mass
which remains in the storage vessel. While the dry ice eventually
sublimes and exits the vessel, the sublimation period is measured
in hours and is of little use in fire suppression.
The problem with liquid carbon dioxide based fire suppression
systems is worse when low temperature operation is required. At
-65.degree. F., the vapor pressure of carbon dioxide is about 0.48
MPa (70 psig) (compared to 4.8 MPa (700 psig) at 70.degree. F.)
which is totally inadequate for rapid expulsion. The vessel
freeze-up problem is worse. About 50% of the liquid carbon dioxide
solidifies when exposed to -65.degree. F. and atmospheric
pressure.
Improved carbon dioxide suppression systems add pressurized
nitrogen to facilitate the rapid expulsion of carbon dioxide gas at
room temperature. The pressurized nitrogen does not resolve the
freezing problem at low temperatures and at upper service extremes,
about 160.degree. F., the storage pressure is extremely high,
dictating the use of thick, heavy, walled storage vessels.
Chemical systems extinguish a fire by separating the fuel from
oxygen. Typical dry chemical systems include sodium bicarbonate,
potassium bicarbonate, ammonium phosphate, and potassium chloride.
Granular graphite with organic phosphate added to improve
effectiveness, known as G-1 powder, is widely used on metal fires.
Other suitable dry compounds include sodium chloride with
tri-calcium phosphate added to improve flow and metal stearates for
water repellency, dry sand, talc, asbestos powder, powdered
limestone, graphite powder, and sodium carbonate. Dry chemical
systems are delivered to a fire combined with a pressurized inert
gas or manually such as with a shovel. The distribution system is
inefficient for large fires and a significant amount of time is
required to deliver an effective quantity of the dry powder to
suppress a large fire.
The most efficient fire suppression agents are Halons. Halons are a
class of brominated fluorocarbons and are derived from saturated
hydrocarbons, such as methane or ethane, with their hydrogen atoms
replaced with atoms of the halogen elements bromine, chlorine,
and/or fluorine. This substitution changes the molecule from a
flammable substance to a fire extinguishing agent. Fluorine
increases inertness and stability, while bromine increases fire
extinguishing effectiveness. The most widely used Halon is Halon
1301, CF.sub.3 Br, trifluorobromomethane. Halon 1301 extinguishes a
fire in concentrations far below the concentrations required for
carbon dioxide or nitrogen gas. Typically, a Halon 1301
concentration above about 3.3% by volume will extinguish a
fire.
Halon fire suppression occurs through a combination of effects,
including decreasing the available oxygen, isolation of fuel from
atmospheric oxygen, cooling, and chemical interruption of the
combustion reactions. The superior fire suppression efficiency of
Halon 1301 is due to its ability to terminate the runaway reaction
associated with combustion. The termination step is catalytic for
Halon 1301 due to the stability of bromine radicals
(Br.circle-solid.) formed when Halon 1301 is disposed on a
combustion source.
When unreacted Halon 1301 migrates into the stratosphere, sunlight
breaks down the Halon 1301 forming bromine radicals.
Br.circle-solid. then reacts to consume ozone in an irreversible
manner.
In view of the current recognition that ozone depletion is a
serious environmental problem, a move is on to identify: (i) fire
suppression agents having a less severe environmental impact than
Halon and (ii) devices to deliver these more environmentally
friendly agents.
SUMMARY OF THE INVENTION
Accordingly, it is an object of the invention to provide a fire
suppression apparatus for effectively delivering a fire suppressant
which is less environmentally hazardous than Halon. It is a feature
of the invention that the apparatus effectively delivers both
liquid and solid fire suppressants. It is an advantage of the
invention that the apparatus does not require significantly more
space than Halon fire suppression apparatus. A further advantage of
the invention is that both high and low vapor pressure liquids are
effectively stored, vaporized, and delivered in gaseous form.
In accordance with the invention, there is provided an apparatus
for suppressing a fire. The apparatus contains a gas generator and
a vaporizable liquid contained within a chamber. A passageway is
provided between the chamber and a fire. When activated, the
apparatus suppresses a fire by generating an elevated temperature
first gas. A first liquid is substantially vaporized by interaction
with the first gas generating a second gas having flame suppressing
capabilities; the second gas is then directed at the fire.
In another embodiment of the invention, the first gas is an
effective flame suppressant such as CO.sub.2, N.sub.2, or water
vapor. The first gas may be used directly as a flame suppressant or
combined with the second gas for flame suppression.
The above stated objects, features, and advantages will become more
apparent from the specification and drawings which follow.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 illustrates in cross-sectional representation an apparatus
for vaporizing a liquid to a flame suppressing gas in accordance
with a first embodiment of the invention.
FIG. 2 illustrates in cross-sectional representation an apparatus
for vaporizing a liquid to a flame suppressing gas in accordance
with a second embodiment of the invention.
FIG. 3 illustrates in cross-sectional representation an apparatus
for delivering a dry chemical flame suppressant to a fire.
FIG. 4 illustrates in cross-sectional representation a carbon
dioxide producing gas generator.
FIG. 5 graphically illustrates increasing the magnesium carbonate
content in the gas generator reduces the formation of corrosive
effluent.
FIG. 6 graphically illustrates the relationship between pressure
and density for ice and water.
FIG. 7 illustrates in cross sectional representation a water based
fire suppression system in accordance with the invention.
DETAILED DESCRIPTION OF THE DRAWINGS
FIG. 1 shows in cross-sectional representation a fire suppression
apparatus 10 in accordance with a first embodiment of the
invention. A gas generator 12 containing a suitable solid
propellant 14 delivers an elevated temperature first gas 16 to a
vaporizable liquid 18 contained in a chamber 20. A first conduit 22
provides a passageway between the gas generator 12 and the chamber
20. The first gas 16 interacts with the vaporizable liquid 18
converting the liquid to a second gas 24. By proper selection of
the vaporizable liquid 18, the second gas has flame suppressing
capabilities. A second conduit 26 directs the second gas 24 to a
fire. An optional aspirator 28 uniformly distributes the second gas
24 over a wide area.
The fire suppression apparatus 10 is permanently mounted in a
ceiling or wall of a building, aircraft, or other suitable
structure or vehicle. A sensor 30 detects the presence of a fire.
Typically, the sensor 30 detects a rise in temperature or a change
in the ionization potential of air due to the presence of smoke. On
detecting a fire, the sensor 30 transmits an activating signal to a
triggering mechanism 32. The activating signal may be a radio
pulse, electric pulse transmitted by wires 34, or other suitable
means.
The triggering mechanism 32 is any device capable of igniting the
solid propellant 14. One triggering mechanism is an electric squib.
The electric squib has two leads interconnected by a bridge wire,
typically 0.076 mm-0.10 mm (3-4 mil) diameter nichrome. When a
current passes through the leads, the bridge wire becomes red hot,
igniting an adjacent squib mixture, typically, zirconium and
potassium perchlorate. The ignited squib mixture then ignites an
adjacent black powder charge, creating a fireball and pressure
shock wave which ignites the solid propellant 14 housed within the
gas generator 12.
The gas generator 12 contains a solid propellant 14 which on
ignition generates a large volume of a high temperature gas
containing fire suppressing fluids such as carbon dioxide,
nitrogen, and water vapor. Depending on the selection of the
vaporizable liquid and the type of fire anticipated as requiring
suppression, the gas is generated for a period of time ranging from
a few milliseconds to several seconds. One particularly suitable
gas generator is the type used in automotive air bags. This type of
gas generator is described in U.S. Pat. No. 3,904,221 to Shiki et
al., which is incorporated by reference in its entirety herein. A
housing 36 supports the solid propellant 14 and directs an
explosive shock wave in the direction of the vaporizable liquid 18.
Typical materials for the housing 36 include aluminum alloys and
stainless steel.
The preferred solid propellant 14 is a combustible mixture which
generates a copious amount of high temperature gas. The chemical
reactions converting the propellant to the first gas generally do
not occur efficiently at temperatures below about 1093.degree. C.
(2000.degree. F.). The gas yield in moles per 100 grams of
propellant should be in excess of about 1.5 moles and preferably in
excess of about 2.0 moles. The propellants are generally a mixture
of a nitrogen rich fuel and an oxidizing agent in the proper
stoichiometric ratio to minimize the formation of hydrogen and
oxygen. The preferred fuels are guanidine compounds, azide
compounds and azole compounds.
Two preferred solid propellants are "RRC-3110" and "FS-01" (both
available from Olin Aerospace Company of Redmond, Washington). The
compositions (in weight percent) of these propellants are:
______________________________________ RRC-3110
______________________________________ 5-Aminotetrazole 28.62%
Strontium nitrate 57.38% Clay 8.00% Potassium 5-Aminotetrazole
6.00% ______________________________________
When ignited, RRC-3110 generates H.sub.2 O, N.sub.2, and CO.sub.2
as well as SrO, SrCO.sub.3, and K.sub.2 CO.sub.3 particulate.
______________________________________ FS-01
______________________________________ 5-Aminotetrazole 29.20%
Strontium nitrate 50.80% Magnesium carbonate 20.00%
______________________________________
When ignited, FS-01 generates H.sub.2 O, N.sub.2, and CO.sub.2 as
well as SrO, SrCO.sub.3, and MgO particulate.
Another useful propellant composition is:
______________________________________ Guanidine nitrate 49.50%
Strontium nitrate 48.50% Carbon 2.00%
______________________________________
When ignited, this composition releases a mixture of H.sub.2 O,
N.sub.2, and CO.sub.2 gases along with SrO and SrCO.sub.3
particulate solids.
Propellants which generate KCl salt are also suitable. KCl is
effective in suppressing fires, but the corrosive nature of the
salt limits the application of these propellants. Two such
propellants are:
______________________________________ 5-Aminotetrazole 30.90%
Potassium perchlorate 44.10% Magnesium carbonate 25.00%
______________________________________
When ignited, this propellant generates H.sub.2 O, N.sub.2, and
CO.sub.2 gas as well as KCl and MgO particulate.
______________________________________ Potassium chlorate 61.0%
Carbon 9.0% Magnesium carbonate 30.0%
______________________________________
When ignited, this propellant generates CO.sub.2 as the only gas
and KCl and MgO particulate.
Another suitable propellant generates nitrogen gas and solid slag
which remains in the housing 36; only the gas is delivered to the
vaporizable liquid eliminating contamination of the area by the
solid particulate.
______________________________________ Sodium azide 59.1% Iron
oxide 39.4% Potassium nitrate 1.0% Carbon 0.5%
______________________________________
When ignited, this propellant generates N.sub.2 gas and slag which
is not discharged from the housing.
The propellants useful in the apparatus of the invention are not
limited to the five specified above. Any solid propellant capable
of generating similar gaseous products at high velocity and high
temperature is suitable.
The most preferred propellants contain magnesium carbonate as a
suppressing agent. The magnesium-carbonate may be combined with a
fuel, as in the FS-01 propellant, combined with other suppressing
agents, or utilized as a single component fire suppressing
propellant. The magnesium carbonate endothermically decomposes to
carbon dioxide (a good oxygen displacer) and magnesium oxide (a
good heat sink and coolant).
Suitable propellants contain from that amount effective to
extinguish a fire up to about 95% by weight magnesium carbonate and
the balance being the mixture of a fuel and an oxidizer.
Preferably, the propellant contains from about 20% to about 70% by
weight magnesium carbonate and most preferably from about 30% to
about 60% by weight magnesium carbonate.
When the magnesium carbonate content is low, propellants containing
strontium nitrate yield effluent rich in strontium oxide. On
exposure to atmospheric moisture, this yields extremely basic
solutions that are corrosive to aluminum and other materials
utilized in aircraft manufacture. With reference to FIG. 5, the
inventors have determined a minimum magnesium carbonate content of
about 35% is desired to minimize the corrosion potential.
Propellant additives such as magnesium carbonate act as endothermic
heat sinks and carbon dioxide generators. These effects decrease
the corrosivity of propellant effluent by minimizing the amount of
strontium oxide generated. FIG. 5 graphically illustrates the
composition of the gaseous effluent generated by igniting the FS-01
fuel with varying amounts of magnesium carbonate present. The
strontium oxide content is identified by reference line 80.
Approximately 35 weight percent magnesium carbonate is required to
achieve an essentially strontium oxide free effluent.
Strontium carbonate (reference line 82) and magnesium oxide
(reference line 84) form compounds with a pH near 7 when exposed to
atmospheric moisture and generally do not cause significant
corrosion.
A preferred propellant contains a nitrogen rich fuel, an oxidizer,
and magnesium carbonate. Suitable propellants include modifications
of FS-01 containing 5-aminotetrazole and an oxidizer, such as
strontium nitrate, potassium perchlorate, or mixtures thereof. The
fuel to oxidizer ratio, by weight, is from about 1:1 to about 1:2.
Combined with the fuel and oxidizer is from about 20% to about 70%
by weight magnesium carbonate (measured as a percentage of the
propellant/magnesium carbonate/additives compacted mixture). The
propellant may also contain additives such as clay (to improve
molding characteristics) or graphite (to improve flow
characteristics).
The propellant is a mixture of compacted powders. If all powder
components are approximately the same size, the burn rate is
unacceptably low. Preferably, the propellant is a mixture of
relatively large magnesium carbonate particles having an average
particle diameter of from about 150 microns to about 200 microns
and relatively small fuel and oxidizer particles having an average
particle diameter of from about 50 microns to about 75 microns. The
larger magnesium carbonate particles form discrete coolant sites
and do not reduce the propellant burn rate as drastically as when
all components are approximately the same size.
The solid propellant may be required to generate the gas over a
time ranging from about 30 milliseconds to several seconds.
Typically, a short "burn time" is required in an explosive
environment while a longer burn time is required in a burning
environment. If a short burn time is desired, the propellant is in
the form of tablets, typically on the order of 1 centimeter in
diameter by about one-half centimeter thick. Increasing the pellet
size increases the burn time. For a burn time of several seconds,
the gas generator contains a single propellant slug compression
molded into the housing.
Referring back to FIG. 1, to prevent the housing 36 from melting
during ignition of the solid propellant 14, a cooling material 38
may be disposed between the housing 36 and solid propellant 14. One
cooling material is granular magnesium carbonate which generates
carbon dioxide when heated above 150.degree. C. (300.degree. F.).
One mole of MgCO.sub.3 will produce one mole of CO.sub.2 plus one
mole of MgO, which remains in the housing 36 in the form of a slag.
Small amounts of MgO dust may be exhausted during ignition of the
solid propellant.
To prevent contamination of the chamber 20 by the solid propellant
14 prior to ignition, a first rupture diaphragm 40 isolates the
vaporizable liquid 18. The isolation diaphragm 40 is ruptured by
the pressure of the shock wave. No active device such as a disk
rupturing detonator is required. To prevent the generation of
mechanical debris, the isolation diaphragm 40 may have score lines
and hinge areas to open in a petal like fashion.
The first conduit 22 forms a passageway to communicate the first
gas 16 to the vaporizable liquid 18. The first gas 16 is
superheated and traveling at high velocity. Interaction of the
first gas and the vaporizable liquid 18 vaporizes the liquid,
generating a second gas 24. The second gas 24 ruptures the second
isolation diaphragm 42 and is expelled as a fire suppressing gas,
preferably through aspirator 28.
The selection of the vaporizable liquid 18 is based on a desire
that the second gas 24 be less reactive with atmospheric ozone than
Halon. The vaporizable liquid 18 contains no bromine, and
preferably also no chlorine. Preferred groups of vaporizable
liquids 18 include fluorocarbons, molecules containing only a
carbon-fluorine bond, and hydrogenated fluorocarbons, molecules
containing both carbon-hydrogen and carbon-fluorine bonds. Table 1
identifies preferred fluorocarbons and hydrogenated fluorocarbons
and their vaporization temperatures. For comparison, the data for
Halon 1301 is also provided.
TABLE 1 ______________________________________ Vaporization
Vaporization Pressure Temperature Room System Formula (.degree.C.)
Temperature (psi) ______________________________________ HFC-32
CH.sub.2 F.sub.2 -52 120 HFC-227 CF.sub.3 CHFCH.sub.3 -15 59
HCFC-22 CHClF.sub.2 -41 139 HCFC-134A CF.sub.3 CH.sub.2 F -27 83
FC-116 CF.sub.3 CF.sub.3 -78 465 HCFC-124 CHClFCF.sub.3 -12 61
HFC-125 CF.sub.3 CF.sub.2 H -48 195 FC-31-10 C.sub.4 F.sub.10 -2 --
FC-C318 (CF.sub.2).sub.4 -4 -- HF-23 CF.sub.3 H -82 700 HCFC-123
CF.sub.3 CCl.sub.2 H -28 13 FC-218 CF.sub.3 CF.sub.2 CF.sub.3 -36
120 FC-614 C.sub.6 F.sub.14 +56 -- HALON 1301 CF.sub.3 Br -58 220
______________________________________
The most preferred fluorocarbons and hydrogenated fluorocarbons are
those with the higher boiling points and lower vapor pressures. The
higher boiling point reduces the pressure required to store the
vaporizable liquid 18 as a liquid. The lower vapor pressures
increase the rate of conversion of the vaporizable liquid to fire
suppressing gas on ignition. Particularly suitable are HFC-227,
FC-31-10, FC-C318 and FC-218.
Unsaturated or alkene halocarbons have a low vapor pressure and a
relatively high boiling point. These unsaturated molecules contain
a carbon-carbon double bond, together with a carbon-fluorine bond,
and in some cases, a carbon-hydrogen bond. The unsaturation causes
these compounds to be considerably more photosensitive than a
saturated species, leading to significant photochemical degradation
in the lower atmosphere. The low altitude photodegradation may
lessen the contribution of these compounds to stratospheric ozone
depletion. Through the use of an unsaturated halocarbon in the fire
suppression apparatus of the invention, it is possible that bromine
containing compounds may be tolerated.
Representative haloalkenes have a boiling point of from about
35.degree. C. to about 100.degree. C. and include
3-bromo-3,3-difluoro-propene, 3-bromo-1,1,3,3,tetrafluoropropene,
1-bromo-3,3,3-trifluoro-1-propene,
4-bromo-3,3,4,4,tetrafluoro-1-butene, and
4-bromo-3,4,4-trifluoro-3-(trifluormethyl)-1-butene, as well as
homologues, analogs, and related compounds.
One disadvantage with the fluorocarbons and hydrogenated
fluorocarbons, whether saturated or unsaturated, is the generation
of small amounts of hydrogen fluoride when the vapor contacts a
fire. Hydrogen fluoride is corrosive to equipment and hazardous to
personnel.
The significant heat and pressure conducted by the first gas 16
permits the use of liquid carbon dioxide or water as the
vaporizable liquid 18. The expansion problem identified above for
nonenergetically discharged liquid carbon dioxide is eliminated by
the superheating effect of the first gas 16. Water is converted to
a fine mist of steam on interaction with the first gas and is
highly effective for flame suppression.
As water is such an effective fire suppression media when delivered
in the form of fine droplets, a mist, or as a superheated steam to
a fire, it is one of the most favored fluids for use in this gas
generation concept. However, because water freezes at a temperature
of 0.degree. C. (32.degree. F.), a means must be incorporated to
either suppress the freezing point or the design of the gas
generator must be such that it can operate effectively with the
water frozen solid.
Most military and commercial applications require that fire
suppression equipment operate effectively over a temperature range
of -54.degree. C. to +71.degree. C. (+65.degree. F. to +160.degree.
F.). Many additives such as ammonia, alcohol, glycols, and salts
are capable of suppressing the water freezing point to below
-54.degree. C. (-65.degree. F.), but a considerable portion of the
mixture becomes the additive. Most additives are flammable or
corrosive, degrading the effectiveness and desirable features of a
water system when freezing point depressants are present in the
water.
To maintain the desirable features of water as the agent for the
gas generator driven system, the system can be designed to operate
effectively over the desired -54.degree. C. to +71.degree. C.
(-65.degree. F. to +160.degree. F.) temperature range even if the
water has frozen solid.
FIG. 6 graphically illustrates the relationship between density and
temperature for water and ice at atmospheric pressure, moderate
increased pressure, and moderate vacuums. At slightly over
0.degree. C. (+32.degree. F.), the density of liquid water is 1.0
g/cm.sup.3 (62.40 lbm/ft.sup.3). If the temperature of the water is
reduced just below 0.degree. C. (32.degree. F.), the water will
freeze to ice and expand considerably in volume. The density of ice
at 0.degree. C. (+32.degree. F.) is 0.92 g/cm.sup.3 (357.50
lbm/ft.sup.3).
Below 0.degree. C., the density of ice increases as the temperature
is decreased as illustrated by reference line 86. Above 0.degree.
C., the density of water decreases as the temperature is increased
as illustrated by reference line 88.
FIG. 7 shows in cross-sectional representation a water based fire
suppression system 90 that accommodates the expansion of ice due to
freezing of the water. The fire suppression system 90 includes a
solid propellant gas generator 12 described above and previously
illustrated in FIG. 1. The gas generator 12 communicates with a
tank 92 by a passageway formed by a first conduit 93. The tank 92
contains a mixture of water 94 and ice 96. The tank 92 has a volume
larger than the volume of ice that would be contained if all the
water 94 was frozen.
The gas generator 12 provides sufficient thermal energy to heat the
ice 96 to the freezing point and melt the ice by directing a hot
gas 98 produced by the gas generator 12 in the direction of the ice
96. Nozzle 100 may be provided to direct the flow of the hot gas 98
to impinge the mixture of ice and water inducing turbulence to
assure good mixing and vaporization of the water.
Heating of the ice 96 and water 94 is further enhanced by the use
of a propellant which exhausts a significant percent of solids into
the tank 92 along with the hot gases 98. Preferably, at least about
20% by weight, and most preferably, at least about 40% by weight of
the effluent is solid particles.
The tank 92 is designed to facilitate unrestricted expansion of ice
96. There are no pockets or cavities to interfere with the ice
growth. Mechanical parts of the gas generator are not in the path
of ice growth to minimize breaking of the mechanical parts.
The temperature of the generated gases is preferably in excess of
about 925.degree. C. (1700.degree. F.) an typically exceeds
1093.degree. C. (2000.degree. F.). The gas generator is preferably
selected so that the exhaust contains at least 20% and preferably
in excess of about 40% by weight hot solid particulate (i.e. MgO,
etc.). This exhaust stream provides a very effective means for
rapidly melting the ice.
Another feature of the water-based fire suppression system 90 is
that the ullage space 102 above the water 94 and ice 96 is
sufficiently large to assure that the resulting pressure of the hot
gases 98 exhausting into the tank 92 do not produce a pressure
sufficient to rupture the outlet burst disc 104, typically about
13.8 MPa (2000 psig). The system is designed to require additional
hot gases 98 from the gas generator 92 to be added to superheat the
vaporized water before the outlet disc 104 is ruptured and flow
commences.
Once the outlet disc 104 has been ruptured, the continuing flow of
gases 98 from the gas generator 12 creates significant turbulence
and mixing of the water 94 within the tank 92 vaporizing the water
to produce steam 106. Depending upon the particular fire
suppressing application, it may be desirable to design the unit to
produce low quality steam at low temperatures or superheated steam
at higher temperatures. Any temperature and steam quality can be
produced by the proper proportioning of the water and solid
propellant used in the system. The steam 106 is directed at the
fire through a second passageway formed by a second conduit
107.
It is sometimes desirable to incorporate an additive 108 to the
water 94 to reduce the heat of fusion of the ice 96. Effective
chemical additives include polyvinyl alcohol and water soluble
polymers such as methyl cellulose, added to the water in
concentrations of less than about 15% by volume. The additives 108
also tend to form a viscous gel when properly added to the water.
This higher viscosity working fluid is much less prone to leaking
from the tank 92 than water.
In a second embodiment of the invention, the fire suppression
apparatus 50 is as illustrated in cross-sectional representation in
FIG. 2. The elements of the second fire suppression apparatus 50
are substantially the same as those illustrated in FIG. 1 and like
elements are identified by like Figure numerals. Typically the
solid propellant 14 generates solid particulate along with the
first gas. Particulate may be also be generated by other components
of the fire suppression apparatus such as the magnesium carbonate
cooling layer 38. If the environment in which the flame suppression
apparatus 50 is located would be detrimentally effected by the
presence of solid particulate, a bladder 52 may be disposed between
the gas generator 12 and the chamber 20. The energetic first gas 16
forcedly deforms the flexible bladder 52, generating a shock wave
vaporizing the vaporizable liquid 18 and generating the second gas
24. The bladder 52 may be any suitable material such as a high
temperature elastomer.
This second embodiment does not superheat the vaporizable liquid 18
as effectively as the first embodiment. The transfer of heat
through the elastomeric material 52 is limited. Accordingly, lower
boiling point vaporizable liquids such as HFC-32, FC-116, and HF-23
are preferred.
In a third embodiment of the invention, a solid flame suppressant
may be utilized as illustrated by the flame suppression apparatus
60 of FIG. 3. The flame suppression apparatus 60 illustrated in
cross-sectional representation is similar to the earlier
embodiments and like elements are identified by like reference
numerals, while elements performing a similar function are
identified by primed reference numerals. The chamber 20' is packed
with small diameter, on the order of from about 5 to about 100
micron, and preferably from about 10 to about 50 micron, particles
62 of any effective flame suppressing material. Suitable materials
include potassium bicarbonate, sodium bicarbonate, ammonium
phosphate, potassium chloride, granular graphite, sodium chloride,
magnesium hydroxide, calcium hydroxide, strontium hydroxide, barium
hydroxide, aluminum hydroxide, magnesium carbonate, potassium
sulfate, sand, talc, powdered limestone, graphite powder, sodium
carbonate, strontium carbonate, calcium carbonate, and magnesium
carbonate. These and other suitable materials may be mixed with
boron oxide as disclosed in U.S. Pat. No. 4,915,853 to
Yamaguchi.
In the preceding embodiments of the invention, the flame
suppression apparatus has been described in terms of a superheated
gas interacting with a vaporizable liquid. The superheated gas is
predominantly nitrogen, carbon dioxide, and water vapor, all
effective fire suppressants. In certain applications, it is
preferred to omit the vaporizable liquid and discharge the flame
suppressing gases generated by the solid propellant directly onto
the fire. A carbon dioxide producing gas generator 70 is
illustrated in cross-sectional representation in FIG. 4.
The carbon dioxide producing gas generator 70 is similar to the gas
generators described above. An electric squib 32 activates an
energetic mixture of a solid propellant 14. On ignition, the solid
propellant 14 ignites a magnesium carbonate containing propellant
72 generating MgO, CO.sub.2, N.sub.2, and water vapor. A perforated
screen 74 separates the propellants from the housing 12. A
magnesium carbonate cooling bed 76 is disposed between the housing
12 and propellants, and on heating generates additional CO.sub.2.
The propellant 72 may contain other fire suppressing agents, in
addition to magnesium carbonate, either alone or in combination.
Suitable fire suppressing agents include magnesium hydroxide,
calcium hydroxide, strontium hydroxide, barium hydroxide, and
aluminum hydroxide.
The following examples illustrate the effectiveness of the flame
suppressing apparatus of the invention.
EXAMPLES
Example 1
The gas generator 70 is an efficient apparatus for delivering a low
molecular weight inerting agent, such as CO.sub.2, N.sub.2, or
water vapor, to a fire. The weight of the apparatus and propellant
compares favorably to the weight of a halon based fire suppression
system.
Gas Generator Characteristics
Length--42.24 centimeters (16.63 inches)
Diameter--13.97 centimeters (5.50 inches)
Displaced external volume--0.0065 meter.sup.3 (395 inch.sup.3)
FS-01 propellant load--2.01 kilograms (4.437 pounds), generates
1.41 kilograms (3.10 pounds) of CO.sub.2, N.sub.2, and water
vapor
MgCO.sub.3 coolant load--6.00 kilograms (13.21 pounds), generates
3.13 kilograms (6.894 pounds) of CO.sub.2)
Total inerting gas produced--4.54 kilograms (10.00 pounds)
Estimated mass of total system--11.8 kilograms (26.10 pounds)
Gas Generator Materials
Housing 12--Aluminum alloy 6061-T6
Solid propellant 14--BKNO.sub.3
FS-01 propellant 72--in pellet form, size of pellets based on
desired burn time, about 1 centimeter diameter by 0.5 centimeter
thick tablets provide a 30 millisecond burn,
MgCO.sub.3 coolant bed 76--granular
Perforated retaining screen 74 has 1.27 millimeter (0.050 inch)
perforations.
This system will produce about 4.54 kilograms (10 pounds) of
CO.sub.2, N.sub.2, and water vapor, leave a mass of about 11.8
kilograms (26.10 pounds) and occupy 0.0065 meter.sup.3 (395
inch.sup.3) of space. By comparison, a Halon 1301 system containing
4.54 kilograms (10 pounds) of fire suppressant has a mass of about
8.6 kilograms (19 pounds) and occupies 0.0065 meter.sup.3 (365
inch.sup.3) of space. While the system of the invention is only
sightly larger and more massive than the Halon system, other Halon
replacement systems are predicted to increase the mass by a factor
of 2 or 3.
Example 2
The corrosive action of saturated solutions of the effluent
components on materials commonly utilized in aircraft was
evaluated. An aqueous solution saturated with the effluent was
prepared and the pH measured. Various materials were then exposed
to a 50% relative humidity atmosphere of each saturated solution.
After a 30 day exposure, the coupons were analyzed for corrosion
pits. Table 2 illustrates the benefit of removing strontium oxide
from the effluent.
The patents cited in this application are intended to be
incorporated by reference.
It is apparent that there has been provided in accordance with this
invention an apparatus and method for suppressing a fire which
fully satisfies the objects, means, and advantages set forth
hereinbefore. While the invention has been described in combination
with specific embodiments thereof, it is evident that many
alternatives, modifications, and variations will be apparent to
those skilled in the art in light of the foregoing description.
Accordingly, it is intended to embrace all such alternatives,
modifications, and variations as fall within the spirit and broad
scope of the claims.
TABLE 2
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FS-01 FS-01 40% 20% Composition MgO SrCO.sub.3 MgCO.sub.3
MgCO.sub.3 3110 SrO KOH
__________________________________________________________________________
pH 8.5 9.0 9.0 11.0 11.5 13.5 13.5 (measured) Sat. Aq. Soln. A06061
Mg 0.8-1.2 not not 0 uniform uniform uniform uniform chromated Si
0.4-0.8 analyzed analyzed pitting pitting pitting pitting surface
Cu 0.15-0.40 Cr 0.04-0.34 Al Balance A07075 Zn 5.1-6.1 0 0 0 0 0 3
3 anodized Mg 2.1-2.9 surface Cu 1.2-2.0 Cr 0.18-0.35 Al Balance
A07050 Zn 2.7-3.3 0 0 0 2 5 uniform 0 anodized Mg 1.4-1.8 pitting
surface Mn 0.4-0.6 Cr 0.2-0.4 Al Balance Ti-6Al-4V Al 6 0 0 0 0 0 0
0 bare V 4 surface Ti Balance A07075 0 0 0 not not 10 50 bare
analyzed analyzed surface A07050 0 0 0 not not 24 94 bare analyzed
analyzed surface Graphite/ 0 0 0 0 0 0 0 Epoxy Kevlar Poly (p- 0 0
0 0 0 0 0 phenylene- diamine-co- terephthalic) acid
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