U.S. patent number 3,922,398 [Application Number 05/467,978] was granted by the patent office on 1975-11-25 for method for forming fibrous sausage casings.
This patent grant is currently assigned to Tee-Pak, Inc.. Invention is credited to Douglas J. Bridgeford, Frank M. McNeil.
United States Patent |
3,922,398 |
Bridgeford , et al. |
November 25, 1975 |
Method for forming fibrous sausage casings
Abstract
This invention relates to an improvement in a process for
producing fibrous (reinforced) artificial sausage casings. In the
basic process, a porous web is formed into a tube, impregnated with
polymeric dope in an impregnation zone vented for removal of
accumulated fluids, coagulated, regenerated, and then inflated for
drying. The improvement in this basic process resides in the method
for venting fluids from the tubular fibrous casing and comprises
masking a section of the porous web with a masking agent prior to
impregnating said web in said impregnation zone thereby preventing
this section from being impregnated with the polymeric dope and
then removing said mask after the casing has passed through said
impregnating zone. In a preferred embodiment after regeneration and
prior to drying, the masked section is coated with a flexible, air
impermeable film-forming material.
Inventors: |
Bridgeford; Douglas J.
(Champaign, IL), McNeil; Frank M. (Lombard, IL) |
Assignee: |
Tee-Pak, Inc. (Chicago,
IL)
|
Family
ID: |
23857931 |
Appl.
No.: |
05/467,978 |
Filed: |
May 8, 1974 |
Current U.S.
Class: |
427/259;
53/DIG.1; 426/89; 427/434.2; 53/450; 426/105; 427/282; 426/138 |
Current CPC
Class: |
A22C
13/0013 (20130101); Y10S 53/01 (20130101); A22C
2013/0069 (20130101) |
Current International
Class: |
A22C
13/00 (20060101); B44D 001/52 () |
Field of
Search: |
;117/5.5,38,94,122P,113,115 ;426/89,92,105,138,140 ;118/504,505
;53/7,12,13,28,DIG.1 ;427/259,272,282,230,434 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Herbert, Jr.; Thomas J.
Assistant Examiner: Hess; Bruce H.
Attorney, Agent or Firm: Mosely; Neal J. Brewer; Russell
L.
Claims
We claim:
1. In a method for forming a tubular fibrous sausage casing which
includes the steps of extruding a porous web as a tube,
impregnating said porous web with a polymeric dope in an
impregnation zone, coagulating and regenerating the polymer,
venting fluids which accumulate inside said tubular casing during
coagulation and regeneration, and then drying; the improvement for
venting fluids from said tubular casing which comprises:
masking a section of said porous web with a masking agent prior to
the step of impregnating said web with polymeric dope thereby
preventing said section from becoming impregnated; and, then,
removing said masking agent thereby leaving an uncoated section
after said casing has passed through said impregnation zone,
coating said uncoated section of said casing with a flexible,
film-forming, air-impermeable material after said casing has passed
through the regenerating zone and prior to drying.
2. The method of claim 1 wherein said polymeric dope is
viscose.
3. The method of claim 2 wherein said masking agent is removed
prior to the steps of coagulating and regenerating.
4. The method of claim 3 wherein said masking agent is tape.
5. The method of claim 2 wherein said masking agent is selected
from the group consisting of liquid polyhydric alcohols and salt
solutions.
6. The method of claim 5 wherein said masking agent is a polyhydric
alcohol having from 2 - 6 carbon atoms.
7. The method of claim 6 wherein said polyhydric alcohol is
glycerol.
8. The method of claim 5 wherein said film-forming, air impermeable
material is a polymeric film-forming material.
9. The method of claim 8 wherein said polymeric film-forming
materials are thermoplastic polymer granules.
10. The method of claim 9 wherein said film-forming material is
applied by melting a polyolefin or polyamide polymeric film-forming
material, applying this melt to the uncoated section of tubular
casing, and then solidifying said melt.
11. The method of claim 10 wherein said polymeric film-forming
material is granulated nylon.
12. The method of claim 8 wherein said film-forming material is an
emulsion of a lower alkyl ester of acrylic or methacrylic acid.
13. The method of claim 12 wherein said acrylic emulsion is of a
self-crosslinking acrylic ester.
14. The method of claim 8 wherein said polymeric film-forming
material is a solution of a polyamide resin.
15. The method of claim 14 wherein said polyamide resin is a
dimerized vegetable oil fatty acid amide.
16. The method of claim 14 wherein said polyamide resin is a
hydroxylmethylated nylon.
Description
DESCRIPTION OF THE PRIOR ART
In the manufacture of reinforced, regenerated cellulose casings,
paper web of relatively strong natural fibers such as manila hemp
and flax have been coated and impregnated with a polymeric dope,
e.g., viscose. Viscose is the name given to a solution of sodium
cellulose xanthate dissolved in sodium hydroxide. The impregnated
porous web then is passed through a coagulating bath and into a
regeneration bath for regenerating the cellulose. During the
coagulating and regenerating steps of the process, fluids in the
form of liquids and gases accumulate inside the tubular casing.
These fluids must be released periodically in order to maintain the
casing at constant diameter and to permit drying of the casing. The
casing after regeneration then is plasticized and dried. After
drying, the casing is wound onto a reel and is referred to as reel
stock.
In order to effect release of fluids from inside the tubular
fibrous casing, the casings normally are punctured or perforated
before they enter the coagulating tank. Usually perforation is done
intermittently and typically a perforation in the casing is made
every 20 - 40 minutes. These punctures generally are in the form of
long slits, e.g., 2 - 12 inches in length. Thus, as the casing
passes through the coagulating and regenerating baths, the fluids
which have accumulated in the casing are released to the bath
through the perforations.
In order to inflate the casing for drying, it has been customary to
cut out that section of casing containing the puncture by cutting
the casing transverse to the longitudinal axis and then joining the
casing by inserting a hollow rubber coupling into the two ends of
the casing. The ends of the casing are tied about the coupling so
that the casing can be inflated with air for drying. After drying,
the coupling is removed from the casing by cutting and the severed
casing is spliced together. An integral piece is formed by butting
the two ends of the casing together and joining with tape.
It has been recently disclosed that accumulated fluids in fibrous
tubular sausage casings can be removed by introducing a plurality
of small perforations (holes) into the casing and then sealing
these holes by placing a patch of flexible material thereover and
securing with a water activated adhesive. Examples of water
activated adhesives for sealing the patch include alpha-cyanomethyl
acrylate, finely divided carboxymethyl cellulose, sodium alginate,
polyvinyl alcohol and cellulose xanthate.
There are several problems associated with the customary methods of
venting fluids in the manufacture of fibrous sausage casings. One
basic objection with casing having splices therein is that it
resulted in a loss of casing. The spliced section, which included
the two ends joined by tape, is discarded to scrap or sold to
specialty meat processor operations which do not use automatic
stuffing equipment. Another basic objection with spliced fibrous
casing is the poor shirring characteristics of the casing. In
shirring, the tape used for joining the casing often adhered to the
shirring mandrel and caused a shirring "miss." Each "miss" resulted
in downtime and required the shirring operators to remove the bad
section of casing from the mandrel and re-thread the shirring
machine. Another problem of fibrous casing spliced with tape is
that it is difficult to wind long sections on radial winding
apparatus (as shown in U.S. Pat. No. 3,709,703). On winding, the
casings are moistened and, of course, at each juncture the splice
fails because of reduced adhesion of the tape.
SUMMARY OF THE INVENTION
This invention relates to an improvement in a basic process for
forming reinforced regenerated cellulose sausage casings. The basic
process comprises extruding a porous web through an annular die,
impregnating the porous web with a polymeric dope in an
impregnation zone, venting accumulated fluids from inside the
casing, and inflating the casing for drying. The improvement
constituting the basis of the invention resides in the providing of
an improved venting means for removal of accumulated fluids. The
improvement comprises: masking a section of the porous web with a
masking agent prior to the step of impregnating the porous web with
viscose in said impregnation zone and removing the mask after the
masked section of the casing has passed through said impregnating
zone. The masking of the porous web prevents that section from
being impregnated with a polymeric dope and the demasking permits
fluids to vent through the non-impregnated porous web in the
coagulation and regeneration baths.
In a preferred embodiment of the invention, the demasked section of
casing is coated with a flexible film-forming, substantially air
impermeable material after the casing has passed through the
regeneration zone and prior to drying. This subsequent coating of
the masked section with a flexible air impermeable material permits
the casing to be inflated with air for drying.
Advantages of this invention include: a method for removing fluids
which accumulate in the casing during coagulating and regenerating
of the cellulose; a method for removal of fluids which eliminates
conventional perforating and subsequent patching or splicing of the
casing; a method for producing casing which eliminates waste of
casing due to the perforation of the casing; a method for producing
artificial sausage casings which permits shirring of the casing
without substantial danger of rupture or breaking; a method for
producing casing which can be radial wound without failure; and a
method which reduces the manpower needed to produce the casing.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
This process is particularly adapted for the production of
reinforced, regenerated cellulose sausage casings. Reinforced,
regenerated cellulose casings are prepared by impregnating a
tubular porous web, usually manila hemp paper, with polymeric
dopes, e.g., viscose, and then the polymer, i.e., cellulose, is
subsequently regenerated. As stated previously, fluids in the form
of liquids and gases accumulate inside the thus formed tubular
casing and must be removed prior to drying. Liquids generally
accumulate inside the casing because of osmotic pressure generated
in the coagulating baths. Gases accumulate inside the casing in the
regenerating cycle via the reaction between an acid and the
xanthate group.
Any of the polymeric dopes employed in the manufacture of fibrous
or reinforced sausage casings can be used in the process of this
invention. These polymeric dopes are generally solutions or
dispersions of a polymer in alkali, e.g., sodium hydroxide,
although they can be in other solvents. Typical dopes include:
viscose, polyvinyl alcohol, cellulose ethers, e.g., ethyl
cellulose, hydroxyethyl cellulose, and cellulose esters, e.g.,
cellulose proprionate, and cellulose nitrate. Commercial viscose is
the dominant polymeric dope used for making fibrous casings and is
preferred in the practice of this invention.
In practicing this invention, a section of the porous web is masked
with a masking agent for preventing that section of casing from
being impregnated with viscose. This masked section usually is in
the form of a strip, e.g., from about 1 - 2 inches wide and from
about 5 - 30 inches in length. The masking agent, of course, should
be substantially impermeable to polymeric dope penetration. If the
masking agent is not substantially impermeable to dope penetration,
then carryover of the dope into the masked section results and
prevents the venting of fluids which accumulate inside the tubular
casing. Preferably, the masking agent should be one which can be
easily applied to the porous web, be easily removed after the web
has been impregnated without adversely affecting the integrity of
the tubular casing, and sufficiently rigid enough to define a sharp
boundary preventing feathering (non-uniform coating) when the
masked section is subsequently coated with a film-forming
material.
Examples of solid masking agents suitable for masking the porous
web include: tape, fibrous paper, or polymeric films, e.g.,
polyethylene and polypropylene bonded to the porous web with tape,
an adhesive, or viscous liquid, e.g., corn syrup or sugar
solutions. All that is required in these instances is the adhesive
medium provide sufficient strength to hold the masking agent to the
porous web as it passes through the die and that the adhesive
medium be non-detrimental to the coagulating bath. The solid
masking agent can be removed manually from the bath.
Liquid masking agents can also be used for preventing impregnation
of the porous web with the polymeric dope. Preferably the liquid
masking agents should be soluble in the coagulating solution so
that the masking agent can be leached from the web once the web is
through the impregnation zone. Examples of liquid masking agents
include: polyhydric alcohols, e.g., ethylene and propylene glycol,
glycerol, sorbitol, mannitol, polyethylene glycol, etc., hot melt
sugar and salt solutions which crystallize when cooled to
impregnation zone temperatures, e.g., sucrose and corn syrup
solutions (40 -80%) solids, sodium nitrate and sodium acetate. The
salt solutions preferably should have a high solubility at elevated
(80.degree.C.) temperatures and low solubility at low 25.degree.C.
temperatures so that better coverage of the web can be obtained.
These salts also should be non-toxic or detrimental to the
baths.
Liquid masking agents can also be applied to the web and cooled
until solid, e.g., ice. The solid can melt and be leached from the
web. Water works well in these instances.
Masking of a section can also be accomplished by stopping the flow
of viscose for a short period of time to provide a blank or bare
section. Termination of the flow of viscose can be conveniently
done during the formation of the seam or during the processing of
the casing. For example, a spray of viscose may be stopped for
about 1 or 2 seconds leaving a bare section through which
accumulated fluids can be vented. Accordingly, a termination in the
flow of viscose is contemplated as a masking agent.
Sometimes it is desirable to puncture the non-coated section of
casing with a plurality of small needles, e.g., 10 - 50 mils in
diameter to induce venting of gas from inside the casing. It has
been found that it takes about 5 - 6 inches water to force gas
through non-perforated fibrous paper whereas gas readily vents
through perforated casing. These small perforations are sealed by
the flexible film-forming material applied to the casing prior to
drying. On the other hand, larger perforations as noted in U.S.
Pat. No. 3,562,368 must be patched.
In carrying out the process for fibrous casing manufacture, the
masking agent is applied to the porous web either before or after
tube formation. Generally, the masking agent is applied to the
tubular casing. Once the porous web is formed into a tube and a
section of the tube has been masked, it is passed through an
impregnation zone wherein the tube is coated with viscose. The
polymer dope, e.g., viscose, penetrates into the porous web but
fails to penetrate the masked section. After the tubular casing,
including the masked section is passed through the impregnation
zone, the masking agent is removed from the porous web so that the
liquid and gaseous fluids can vent from the casing. Usually removal
of the masking agent is done manually immediately after the
impregnation zone or is effected by the action of coagulation and
regeneration baths. As stated earlier, one of the advantages of
using a water-soluble masking agent is that it is removed by the
coagulating and regenerating baths and, therefore, eliminates the
manpower required to remove the masking agent. This is one of the
disadvantages with using tape as a masking agent even though tape
is very effective for preventing penetration of the polymer dope
into the porous web.
When the coagulating and regenerating cycles have been completed,
and prior to the drying cycle, the uncoated or non-impregnated
section must be coated with a flexible film-forming, air
impermeable material so that the casing can be inflated with air
and dried. In a preferred embodiment, the film-forming, air
impermeable material should be sufficiently strong and flexible to
permit the casing to be passed through the dryer, shirred, and
stuffed with a sausage emulsion by the meat processor without
rupturing or cracking. Further, the film-forming, air impermeable
material should be non-tacky to the touch, substantially
immediately after it is applied to the casing surface. If it is
tacky, other portions of the casing may adhere to the coated
section or the coating section may adhere to the processing
apparatus, e.g., the dryer or to itself. The film-forming, air
impermeable material should cure or set in a period of from about 5
- 60 seconds after it is applied to the casing so that the operator
can attend other lines. Materials having longer residence or cure
times can be employed, as noted in the examples, but they are
usually not preferred for commercial facilities.
Examples of suitable, flexible, film-forming, air impermeable
materials include: gelatin or gelatin crosslinked with a
conventional crosslinking agent such as a dialdehyde, e.g.,
glutaraldehyde or glyoxal, plasticized alginates crosslinked with a
polyvalent metal salt, e.g., calcium chloride; film-forming
polymers, e.g., hot melts preferably having a melting point of
160.degree.C. or less of polyethylene, polypropylene, and nylon
granules, and aqueous dispersions, e.g., solutions or emulsions of
polymeric film-forming materials such as solutions of
hydroxymethylated nylon, low molecular weight polyamide fatty
acids, and lower alkyl esters of acrylic and methacrylic acid
having from 1 - 6 carbon atoms. Other suitable materials include:
alkali cellulose and starch xanthate; cellulose microspheres; and
ground cellulose. Film-forming materials which have commercially
desirable features include: methanol-water solutions of
hydroxymethylated nylon and polyamide fatty acids, e.g., acids of
dimerized vegetable oil acids. These set or gel within a few
seconds and are highly reliable in patching operations.
The film-forming, air impermeable materials can be applied to the
non-impregnated section of tubular casing by conventional means.
For example, liquid solutions of polyhydric alcohols and polymeric
dispersions can be applied by brushing or spraying the dispersions
over the surface of the tubular casing. Hot melt, polymeric
materials can be applied by heating the polymeric material to a
sufficient temperature for converting it to a liquid and then
applying the liquid to the non-impregnated section and then cooling
to permit solidification. Care is taken in the coating of the
previously masked or non-impregnated section to produce a thin film
of materials of uniform thickness. Generally, the film thickness is
from about 1 - 3 mils but the thickness can be regulated as
desired.
The following examples are provided to illustrate preferred
embodiments of the invention and are not intended to restrict the
scope thereof. All percentages are expressed as weight percentages
unless otherwise specified.
EXAMPLE 1
In the manufacture of reinforced, regenerated cellulose sausage
(fibrous) casings, a porous web of manila hemp paper is formed into
a cylindrical tube. A commercially available masking tape sold
under the "Scotch" Trademark by 3M Company of about 1 inch in width
and 12 inches in length is applied to the external wall of the tube
parallel to the longitudinal axis. Sometimes the tape is
desensitized by coating the adhesive surface with cellulose spheres
so that the tape can be removed from the casing without
destruction. The resulting masked casing, then, is passed through a
die and impregnated with viscose. The viscose penetrates the porous
structure of the hemp paper but does not penetrate the section
masked with tape. After the porous web containing the masked
section of paper has passed through the impregnation zone and prior
to immersion of the section in the coagulating tank, the tape is
removed. Removal of the tape is necessary to expose the uncoated or
non-impregnated section of the casing to the coagulating and
regenerating baths for effecting venting of fluids in the form of
liquids and gases from inside the casing. Once the tubular casing
has passed through the coagulating and regenerating baths, the
previously masked but now uncoated or non-impregnated section is
coated with a flexible, air impermeable film-forming material so
that the casing can be inflated with air for drying.
A first coating of an acidified solution of glutaraldehyde in water
having a pH of about 2 is applied over the uncoated section. Then a
4% solution of gelatin (Bloom 275) in water is brushed over the
glutaraldehyde coated area and heated with a hot air (35.degree.C.)
blower. Crosslinking of the gelatin occurs in about 6 seconds
thereby forming a flexible, air impermeable film. The resulting
film has a thickness of about 1 - 2 mils. The casing can be
inflated with air and dried.
After drying, the casing can be wound onto a reel without cracking;
the casing can be shirred or radial wound without the normal
occurrence of breakage normally associated with spliced fibrous
casing; and can be stuffed with a sausage emulsion for the
manaufacture of sausages. Additionally, this method eliminates loss
of casing due to the customary cutting and splicing.
EXAMPLE 2
A fibrous casing is made in accordance with Example 1 except that a
20% solution of hydroxymethylated nylon, sold under the Trademark
of Zytel 61 by DuPont, in methanol and water is brushed over the
non-impregnated section instead of gelatin. The nylon coated
section gels within about 5 seconds due to the presence of water
and glycerin in the casing. The casing is permitted to dry for
about 3 minutes. This casing is non-tacky to the touch, can be
pressurized before passing to the dryer to 8 - 9 psi without danger
of rupture, and processes nicely through the dryer and shirring
operations. If the 20% solution of Zytel 61 in methanol and water
is applied to a non-impregnated section and force dried using a
heat gun (80.degree.C.), pinholes generally result. These pinholes
prevent the casing from being inflated with air. Therefore, it is
preferred to let the casing dry at room temperature for a couple of
minutes. However, because gelation takes place so rapidly, the
operator can leave the casing and attend to other lines.
EXAMPLE 3
A fibrous casing is made in accordance with Example 1 except that a
hot melt is applied to the non-impregnated section of casing
instead of gelatin. A hot melt is made by melting hydroxymethylated
nylon granules and the melt brushed over the surface of the casing.
The hot melt then is cooled to permit film formation. It is noted
that better adhesion results when the nylon melt is applied to
fibrous paper which is dry as opposed to wet fibrous paper. In both
instances, the casing could be inflated with air to pressures of 8
- 9 psi and processed through shirring operation without
substantial danger of rupture.
EXAMPLE 4
A fibrous casing is made in accordance with the method of Example 3
except that a 50% dispersion of polyethylene granules in water is
used in place of the hydroxymethylated nylon granules. The
dispersion when dried results in a strong, flexible, white adherent
coat and is capable of withstanding inflation pressures of 10 psi.
The casing can be wound onto a reel and processed on conventional
shirring machines.
EXAMPLE 5
A fibrous casing is made in accordance with Example 1 except that
an aqueous emulsion of a conventional self-cross-linking acrylic
ester is used as a film-forming material in place of gelatin. The
emulsion is brushed over the non-impregnated section of the casing
and cured. Curing takes place in about 30 seconds when the film of
1 - 3 mils is heated with a hot air (40.degree.C.) blower. It is
noticed that the acrylic latex is somewhat soft and tacky but it is
sufficiently acceptable for permitting the casing to be inflated
and passed through the dryer. The casing can also be wound onto a
reel and shirred without danger of breakage.
EXAMPLE 6
A fibrous casing is made in accordance with Example 1 except that
the masking agent is 40% solution of corn syrup solids in water.
The solution of corn syrup is brushed over a section of about 1 - 2
inches in width and 10 - 12 inches in length. The corn syrup
solution because of its water-solubility is leached from the casing
as it passes through the coagulating and regenerating baths. The
leaching of the corn syrup from the tubular casing in these baths
leaves an uncoated or non-impregnated section through which fluids
inside the casing can be vented.
After the casing is passed through the regenerating bath, the
non-impregnated section or previously masked section is coated with
a condensation polymer made from a dimerized vegetable oil acid and
ethylene diamine. The condensation polymer is sold under the
Trademark Versamid 950 by General Mills Corp. The dimerized
vegetable oil polyamide sets in about 30 seconds and the casing
then can be inflated with air for drying.
The casing processes through the dryer and shirring operation
without problem. The polyamide, film-forming material has excellent
strength and flexibility for preparing reinforced fibrous
casing.
EXAMPLE 7
A fibrous casing is prepared in exactly the same manner as Example
6 except that in place of the dimerized vegetable oil polyamide
film former, the demasked section is first coated with a solution
of 1 1/2% sodium alginate in water and then coated with an 85 : 15
mixture of water and tetrahydrofuran containing 5% sodium alginate.
The sodium alginate is crosslinked by brushing a solution of 10%
calcium chloride in water over the area to form the film-forming,
air impermeable layer. The resultant film is strong, shiny, and
non-tacky. Wet films resist inflation pressures of from 5 - 7 psi
without delamination.
EXAMPLE 8
A fibrous casing is made in accordance with Example 7 except that
in place of the sodium alginate, a 2.5% solution of cellulose
microspheres having a DP of 300 in 85% phosphoric acid-water is
applied to the non-impregnated section. The cellulose coated
section then is immersed in water (26.degree.C.) for about 30 - 60
seconds to precipitate the cellulose.
The resulting film is firm, non-tacky, and resists inflation
pressures of 5 psi. The film processes nicely through the dryer but
it is noted that cracking sometimes occurs in the shirring
operation.
EXAMPLE 9
A fibrous casing is made in accordance with Example 8 except that
pure glycerol is employed as a masking agent in place of the corn
syrup solution. The glycerol is applied by brushing and then
leveled with a 30 mil draw-down bar.
The glycerol dissolves readily in the coagulating solution of
sulfuric acid and sodium sulfate at a rapid rate for producing a
good, well defined window through which fluids and gases can
vent.
* * * * *