U.S. patent number 3,918,867 [Application Number 05/357,894] was granted by the patent office on 1975-11-11 for device for extruding permanent magnet bodies.
This patent grant is currently assigned to U.S. Philips Corporation. Invention is credited to Lutz Beyer.
United States Patent |
3,918,867 |
Beyer |
November 11, 1975 |
Device for extruding permanent magnet bodies
Abstract
A device for increasing the anisotropy of extruded bodies
consisting of permanent magnetic material in which powdered
material is mixed with a binder and extruded, in the presence of an
orienting magnetic field, through a nozzle provided with partitions
extending in the direction of extrusion so that the material is
divided into several strips which are united again in the outlet of
the nozzle to form a single unitary body.
Inventors: |
Beyer; Lutz (Pinneberg,
DT) |
Assignee: |
U.S. Philips Corporation (New
York, NY)
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Family
ID: |
27182014 |
Appl.
No.: |
05/357,894 |
Filed: |
May 7, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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243842 |
Apr 13, 1972 |
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51505 |
Jul 1, 1970 |
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Foreign Application Priority Data
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Jun 28, 1969 [DT] |
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1932970 |
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Current U.S.
Class: |
425/174; 264/108;
425/461; 264/DIG.58; 425/DIG.33 |
Current CPC
Class: |
B29C
48/09 (20190201); B29C 48/022 (20190201); B22F
3/20 (20130101); H01F 1/113 (20130101); B29C
48/70 (20190201); H01F 41/0273 (20130101); Y10S
425/033 (20130101); B29K 2503/06 (20130101); B29C
48/03 (20190201); Y10S 264/58 (20130101) |
Current International
Class: |
B29C
47/00 (20060101); B29C 47/12 (20060101); B29C
47/58 (20060101); B29C 47/70 (20060101); H01F
41/02 (20060101); H01F 1/032 (20060101); H01F
1/113 (20060101); B22F 3/20 (20060101); B29B
003/04 () |
Field of
Search: |
;264/40,108,113,DIG.58
;425/174,174.8,174.8E,461,DIG.33 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Annear; R. Spencer
Attorney, Agent or Firm: Trifari; Frank R. Steinhauser; Carl
P.
Parent Case Text
This application is a division of application Ser. No. 243,842,
filed Apr. 13, 1972, now abandoned which was a continuation of
application Ser. No. 51,505, filed July 1, 1970 now abandoned.
Claims
What is claimed is:
1. A device for extruding permanent magnetic bodies consisting of
magnetic particles mixed with a binder comprising a nozzle having a
tubular member and a plurality of thin juxtaposed partitions each
provided with a knife-edge extending longitudinally within said
tubular member in the direction of extrusion, the length of each of
the partitions decreasing radially from the center of the tubular
member towards the wall, and means surrounding said tubular member
for producing an orienting magnetic field within said tubular
member.
2. A device as claimed in claim 1 in which the free cross-section
of the tubular member is constant and the partitions extend
parallel to one another.
3. A device as claimed in claim 1 in which the free cross-section
of the nozzle decreases in the direction of the outlet and the
distance between adjacent partitions decreases in the direction of
extrustion.
Description
The invention relates to a method of increasing the anisotropy of
extruded bodies consisting of a permanent magnetic material, in
which the powdered material mixed with a binder is extruded, under
the influence of a magnetic orienting field, by the nozzle of an
extruder and emerges from the outlet of the nozzle as an elongated
body.
As a permanent magnetic material is to be considered for said
purpose in particular a hexaferrite material of the formula BaO.
6Fe.sub.2 O.sub.3, in which the barium may be replaced in whole or
in part by strontium, calcium or lead. The powder particles of
these materials are plate-shaped. The largest dimension is
approximately 5 .mu.m. The thickness lies in the order of magnitude
of 0.5 .mu.m. The easy axis of magnetization of the said particles
is at right angles to the plane of the particles, and lies in the
direction of the thickness of the plates. Other permanent magnetic
materials, for example, alloys or mixtures, for example, consisting
of manganese- bitmuth, are also suitable for said method.
Two groups of anisotropic magnets which can be manufactured by
extrusion are to be distinguished:
1. SINTERED MAGNETS:
The extruded body, after compression, is sintered which is
associated with shrinkage and variation in shape. For maintaining
small tolerances it is required to grind the sintered magnets
afterwards.
2. PLASTOMAGNETS:
The powdered magnetic material is mixed with a synthetic resin or
rubber which hardens after shaping. Usually, plastomagnets, after
their design, in this case after the extrusion, are therefore ready
and further machining is not necessary, The drawback of
plastomagnets as compared with sintered magnets, however, is a
lower density and an associated lower magnetic flux density.
In order to obtain the magnetic anisotropy the same methods are to
be considered both for the sintered magnets and for the
plastomagnets. It is known, for example, from German Auslegeschrift
No. 1,286,230, to manufacture bodies consisting of barium ferrite
powder by means of an extruder, in which the nozzle of the extruder
is surrounded by a device for producing an orienting magnetic
field. As a result of the size of the outlet of the nozzle, the
powder particles are not noteworthily oriented mechanically. The
extruded bodies are then sintered and have the following properties
in the easy axis of magnetisation:
B.sub.r = = 2800 gauss.
B.sup.h c = = 22000 oersted.
(BH).sub.max = 1.7.10.sup.6 gauss-oersted.
On the other hand it is known to orient plate-shaped anisotropic
magnetic powder particles by shear stresses which are produced by
the method of designing. British Pat. specification No. 860,220
describes a method in which a plastoferrite material is rolled
between two rollers to a foil having a thickness of approximately
0.75 mm. On the basis of the strong shear stresses prevailing in a
narrow rolling slit, said foils have a pronounced easy axis of
magnetization since the plate-shaped magnetic particles have been
oriented mechanically during rolling. In practice, such thin foils
are hardly used. Therefore, several such foils would have to be
rolled one on the other for manufacturing anisotropic permanenet
magnets of the desirable thicknesses, which is cumbersome and
expensive.
It is the object of the present invention to provide a method of
increasing the anisotropy of extruded bodies having substantially
any thickness, in which the magnetic powder particles are oriented
not only by an external magnetic field but also by shear stresses
produced in the nozzle.
In the above-mentioned method according to the invention this is
achieved in that the material to be extruded is conducted in the
nozzle along partitions provided in the direction of extrusion and
is divided into several strips which are united again to form a
compact elongated body in the outlet of the nozzle.
The elongated body is divided into a number of thin strips by the
partitions, in which strips, due to the presence of the slit-shaped
space between two partitions, shear stresses are produced which
result in a high degree of orientation of the permanent magnetic
particles at the surface of the strips, so that the particles are
oriented mechanically and hence anisotropy occurs. For stimulating
the mechanical orientation, a d.c. magnetic field of from 3 to 10
kilo-oersted is applied throughout the length of the nozzle of the
extruder. As a result of this, first of all a de-orientation of the
particles is avoided when the material leaves the ends of the
partitions, at the transition of two strips to one single elongated
body. After passing the partitions, the anisotropic strips are
again united to form one single elongated body in the outlet of the
nozzle, which body emerges as such from the nozzle.
The invention will be described with reference to the accompanying
drawing, in which
FIG. 1 is a longitudinal cross-sectional view on an enlarged scale
of a nozzle of a device for carrying out the method according to
the invention,
FIG. 2 is the cross-sectional view of a device shown in FIG. 1.
As a preferred embodiment of manufacturing extruded bodies, the
manufacture will now be described of a ferrite material of the
formula BaO.6Fe.sub.2 O.sub.3 having a hexagonal crystal lattice
structure.
The starting materials, for example, barium carbonate and iron
oxide and, if desirable, other additions, are mixed in a
corresponding ratio and sintered at temperatures between
approximately 1000.degree. and 1300.degree.C. The sintered product
is then ground to powder having a particle size of approximately 5
to 10 .mu.m and mixed with a binder. The resulting plastic mass is
then extruded in a device according to the invention to form a body
having the desirable diameter.
An extruder for carrying out the method according to the invention
comprises a nozzle 1 consisting of a non-magnetic material, for
example, brass. The rectangular nozzle channel is denoted by 2 and
its cross-section decreases towards the end of the nozzle, at which
end the channel changes into an outlet 3 having a constant
cross-section. In the channel 2 of the nozzle, a number of
partitions 4 are provided which extend in the direction of
extrusion and at least mainly parallel to the upper and lower walls
of the channel as well as relative to each other. The partitions 4
are mortised in the side-walls 5 of the nozzle 1. They may consist
of a magnetic or a non-magnetic material, for example, bronze or
brass, and have a thickness of approximately 0.8 mm in the centre.
At the beginning and if desirable at the end, the partitions are
shaped in the form of knife-edges. Viewed in the direction of
extrusion, the length of the partitions 4 decreases from the centre
of the nozzle radially towards the outside. The mutual distance
between the partitions 4 decreases in the direction of the outlet
of the nozzle 3; on the side of the extruder it is approximately 2
mm and decreases in the direction towards the outlet 3 of the
nozzle to approximately 1 mm.
In this manner the partitions 4 divide the nozzle channel 2 into
slit-shaped spaces 10 through which the above-described material 6,
i.e. a ferrite material of the formula BaO.6 Fe.sub.2 O.sub.3 is
forced so that an approximately parabolic velocity distribution
over the height of the strips formed by the partitions 4 is
obtained. The formation of a parabolic velocity distribution over
the height of the slit is characteristic in itself of a laminar
flow in a space having a slit-shaped cross-section. However, in the
case of plastic masses this law experiences a variation which is
caused by the dependence, difficult to understand, of the
properties of the substance on the condition of movement prevailing
at any instant, or on the influencing shear stresses; such masses
are denoted by "structure viscous." In these masses the influence
of the properties of the substance on the local flow rates is
complicated. With an increasing deviation from the Newton fluid
laws, a stronger smoothing of the original parabolic velocity
distribution across the slit-shaped space between two partitions 4
is formed, that is to say, the central zone, in which the effective
shear stress is small or equal to zero, increases with increasing
deviation of the mass from Newton fluid laws.
Therefore, a strip extruded, for example, from the above-mentioned
ferrite mass has at its surface a high degree of orientation of the
magnetic particles, the central layers on the contrary being highly
unoriented. From this it follows that the thickness of the
elongated body and the height of the spaces 10 formed between two
partitions 4, respectively, is decisive of an anisotropy averaged
over the thickness of the body. On the basis of the steeper
velocity profile in an elongated plane space 10, a thin strip has a
higher degree of orientation than rather thick strips. In FIG. 1,
the decrease of veloctiy of the elongated bodies of material
dependent upon the slit height is denoted by arrows.
The material to be extruded is first divided by the partitions 4
into several, in the present case six, strips which, as a result of
their small thickness, show a steep velocity profile so that a
strong mechanical orienting effect is exerted on the powder
particles. The plate-shaped anisotropic powder particles orient
themselves with their longitudinal plane parallel to the partitions
4.
FIG. 1 shows how the velocity profiles of the strips in the
individual spaces 10 between the partitions 4, successively pass
into a common profile, that is to say into one single elongated
body in the outlet 3 of the nozzle. This single elongated body then
emerges from the outlet 3.
In order to stimulate the mechanical orientation, a d,c. magnetic
field of from 3 to 10 kOe is applied throughout the length of the
nozzle 1. FIG. 2 shows the device for producing said magnetic
field. This device comprises two coils 7, soft-magnetic poleshoes
8, and a soft-magnetic frame 9 for closing the magnetic circuit.
The magnetic field produced passes at right angles through the
partitions 4. Since the anisotropic magnetic plates extend
substantially in parallel relative to the partitions 4, the
magnetic field hence also extends at right angles to the plane
through the plate, so in the easy axis of magnetisation
thereof.
Instead of an electromagnetic device for producing an orienting
magnetic field, permanent magnetic devices may also be used.
In accordance with the type of added binder, the body extruded in
this manner can be used as a plastomagnet or be subjected to a
subsequent sintering treatment at temperatures between
approximately 1200.degree. and 1300.degree.C. The finished bodies
are magnetized. Anisotropic sintered magnets consisting of BaO.6
Fe.sub.2 O.sub.3 manufactured by a method according to the
invention had the following properties in the easy axis of
magnetisation.
B.sub.r = 3400 gauss.
B.sup.h c = 2400 oersted.
(BH).sub.max = 2.6.10.sup.6 gauss-oersted.
* * * * *