U.S. patent number 3,914,984 [Application Number 05/251,227] was granted by the patent office on 1975-10-28 for system for measuring solids and/or immiscible liquids in liquids.
Invention is credited to Richard A. Wade.
United States Patent |
3,914,984 |
Wade |
October 28, 1975 |
System for measuring solids and/or immiscible liquids in
liquids
Abstract
A system is provided for measuring solids and/or immiscible
liquids in liquids. A series of ultrasonic pulses is transmitted
into a sample chamber and means are provided for receiving the root
signal of each of the ultrasonic pulses and its reflected echo
signals. Each root signal and its measurable reflected echo signals
form a pulse train. Only a selected one of the reflected echo
signals from each pulse train is detected and a signal
corresponding to the selected one signal is displayed.
Inventors: |
Wade; Richard A. (Barrington,
IL) |
Family
ID: |
22951020 |
Appl.
No.: |
05/251,227 |
Filed: |
May 8, 1972 |
Current U.S.
Class: |
73/61.75;
73/599 |
Current CPC
Class: |
G01N
29/032 (20130101) |
Current International
Class: |
G01N
29/032 (20060101); G01N 29/02 (20060101); G01N
015/06 () |
Field of
Search: |
;73/61,61.1,67.5,67.6,67.9,61R,61.1R,67.5R,32A |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Queisser; Richard C.
Assistant Examiner: Kreitman; Stephen A.
Attorney, Agent or Firm: Gerstman; George H.
Claims
What is claimed is:
1. Apparatus for measuring the concentration of suspended solids
and/or immiscible liquids in liquids, which comprises: means for
producing a series of ultrasonic pulses; a transducer for
transmitting said ultrasonic pulses into a sample to be tested;
means spaced from said transducer for receiving the root signal of
each of said ultrasonic pulses and its reflected echo signals with
each root signal and its measurable reflected echo signals forming
a pulse train, said transmitted ultrasonic pulses being spaced
apart a greater length of time than the total time of a said pulse
train; means for detecting only a selected one of said reflected
echo signals from each pulse train; and means for displaying a
signal corresponding to said selected one signal, said producing
means comprises means for producing a series of square pulses; a
one-shot multivibrator triggering on the leading edge of each
square pulse for producing a series of narrower rectangular pulses;
a crystal oscillator for frequency modulating said rectangular
pulses; and means for amplifying said modulated pulses and
transmitting them to said transducer.
2. Apparatus as described in claim 1, said detecting means
comprising a peak detector, means for amplifying and transmitting
the pulse trains received by said receiving means to said peak
detector; means triggered by said square pulse producing means for
preventing other than said selected one echo signal of each train
from being detected by said peak detector; and means for holding
the peak detector output signal, said holding means being coupled
to said displaying means.
3. Apparatus as described in claim 1, wherein the output of said
peak detector is connected to charge a capacitor through a
high-speed diode; and means coupled to the diode and capacitor
junction for modifying the output signal thereat and for
transmitting a signal to said displaying means.
4. Apparatus for measuring solids and/or immiscible liquids in
liquids, which comprises: means for producing a series of
ultrasonic pulses; a transducer for transmitting said ultrasonic
pulses into a sample to be tested; means spaced from said
transducer for receiving the root signal of each of said ultrasonic
pulses and its reflected echo signals with each root signal and its
measurable reflected echo signals forming a pulse train, said
transmitted ultrasonic pulses being spaced apart a greater length
of time than the total time of a said pulse train; means for
detecting only a selected one of said reflected echo signals from
each pulse train; and means for displaying a signal corresponding
to said selected one signal; said detecting means comprising a peak
detector, means for amplifying and transmitting the pulse trains
received by said receiving means to said peak detector; means for
preventing other than said selected one echo signal of each train
from being detected by said peak detector; and means for modifying
and coupling the output of said peak detector to said displaying
means.
5. Apparatus as described in claim 4, wherein the output of said
peak detector is connected to charge a capacitor through a
highspeed diode; and means coupled to the diode and capacitor
junction for modifying the output signal thereat and for
transmitting a signal to said displaying means.
6. Apparatus for measuring the concentration of suspended solids
and/or immiscible liquids in liquids, which comprises: a chamber
for containing a sample to be measured; means for producing a
series of ultrasonic pulses; a transducer for transmitting said
ultrasonic pulses into said chamber; means spaced from said
transducer for receiving the root signal of each of said ultrasonic
pulses and its reflected echo signals with each root signal and its
measurable reflected echo signals forming a pulse train; said
transmitted ultrasonic pulses being spaced apart a greater length
of time than the total time of a said pulse train; means for
detecting only a selected one of said reflected echo signals from
each pulse train; and means for displaying a signal corresponding
to said selected one signal, said transducer and said receiving
means being located to face each other on opposite sides of said
chamber.
Description
BACKGROUND OF THE INVENTION
This invention relates to apparatus for measuring solids and/or
immiscible liquids in liquids.
There are several prior art systems for detecting the percentage of
solids in liquids. In the gravimetric type of prior art system, the
sample of solids and liquid is filtered and the solids remaining on
the filter are weighed. However, the gravimetric type of analysis
is difficult because it generally requires the steps of weighing,
filtering, evaporating, weighing and calculating. Density gauge
types of solids measurement systems have been utilized, but to use
a density system you must have some specific gravity difference
between the solids and the liquid. Another type of system utilizes
timed pulses which are passed through the slurry, and the value of
all of the signals received at a spaced portion of the slurry is
collected and displayed. This system has been found to be
inaccurate in many applications.
I have discovered a system for measuring solids and/or immiscible
liquids in liquids which is simpler and more accurate than prior
art systems and which operates essentially by detecting phase
interfaces. My system is substantially unaffected by side variables
that plague other systems. For example, changes in liquid
composition, provided that the liquid components are miscible, have
a negligible effect. The liquid system may be composed of several
miscible components and the ratio of these components may change
without interfering with the solids measurement. Further, changes
in the temperature of the liquid, except if very substantial, do
not affect the operation of my system. Nor are other factors which
affect the speed of sound through the liquid sample detrimental to
accuracy.
Some of the many uses to which my invention is applicable include
determining the solids concentration of: paper pulp slurries,
crystals in their mother liquor, latex suspensions, precipitates,
suspension polymerization particles, mining fines, fibrous and
particulate foodstuffs, contaminants in cutting and lubricating
fluids, and many types of sols, colloids, emulsions and
suspensions. Since my system detects phase interfaces, measurements
can be made with respect to an immiscible liquid in another liquid,
as well as measurements of solids in liquids.
BRIEF DESCRIPTION OF THE INVENTION
In accordance with the present invention, there is provided
apparatus for measuring solids and/or immiscible liquids in
liquids. Means are provided for producing a series of ultrasonic
pulses. A transducer is provided for transmitting the ultrasonic
pulses into a sample to be tested. In one embodiment of the
invention, the apparatus comprises a chamber for containing a
sample to be tested. However, the sample to be tested could be any
unenclosed body of liquid.
Means are spaced from the transducer for receiving the root signal
of each of the ultrasonic pulses and its reflected echo signals,
with each root signal and its measurable reflected echo signals
forming a pulse train. The transmitted ultrasonic pulses are spaced
apart a greater length of time than the total time of the pulse
train. Means are provided for detecting only a selected one of the
reflected echo signals from each pulse train, and means are
provided for displaying a signal corresponding to the selected one
signal.
In one embodiment of the invention, the detecting means comprises a
peak detector. Means are provided for amplifying and transmitting
the pulse trains received by the receiving means to the peak
detector. Means are provided for preventing other than the selected
one echo signal of each train from being detected by the peak
detector. Means are further provided for modifying and coupling the
output of the peak detector to the displaying means.
A more detailed explanation of the invention is provided in the
following description and claims, and is illustrated in the
accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a block circuit diagram of apparatus in accordance with
the principles of the present invention, for measuring solids
and/or immiscible liquids in liquids; and
FIG. 2 is a voltage versus time chart showing the voltages at
various portions of the circuit of FIG. 1 at selected times.
DETAILED DESCRIPTION OF THE ILLUSTRATIVE EMBODIMENT
The principle of operation of the present invention is to transmit
a series of ultrasonic pulses into a test sample. The root signal
of each of the pulses and its reflected echo signals are received
at another part of the sample. Solid particles in the liquid absorb
and scatter the ultrasonic waves in proportion to their
concentration. As the percentage of solids increases, a smaller
signal is detected by the receiving transducer. As is discussed
below, only a selected one of the reflected echo signals from each
pulse train is detected and displayed.
Referring to FIG. 1, the system includes an astable multivibrator
10 which produces pulses at a predetermined rate. The leading edge
of each of the pulses from astable multivibrator 10 triggers a
one-shot multivibrator 12 which produces a much narrower pulse. The
output of one-shot multivibrator 12 and the output of a high
frequency oscillator 14 is fed to an AND gate 16 to thereby
frequency-modulate the one-shot multivibrator pulse. The
frequency-modulated pulse is amplified by amplifier 18 and fed to a
crystal transducer 20 which is positioned on one side of a sample
chamber. Crystal transducer 20 comprises a piezoelectric transducer
which sends a pulse through the sample chamber to a similar crystal
transducer 22 which faces transducer 20 on the opposite side of the
chamber. The pulses received by transducer 22 are amplified by
amplifier 24 and fed to an input 26a of peak detector 26.
The leading edge of the pulses from astable multivibrator 10 also
trigger a delayed pulse generator 28 which produces pulses at a
predetermined rate. The lagging edges of the pulses produced by
delayed pulse generator 28 trigger a one-shot multivibrator 30
which produces narrower pulses and which pulses are fed to an input
32a of AND gate 32. The output of peak detector 26 is fed to the
other input 32b of AND gate 32 and through high-speed diode 34. The
output of the high-speed diode 34 is fed back to the negative input
26b of peak detector 26. A resistor 35 is connected between
positive input 26a and ground to provide a reference to ground for
detector 26.
The output of peak detector 26 is also fed through high-speed diode
34 to charge capacitor 36. Capacitor 36 holds the peak voltage and
a corresponding signal is displayed on display 40. Display means
40, which could take the form of an analog meter or a digital
readout, is coupled to the capacitor 36 - diode 34 junction through
a voltage follower 42 which provides a high fixed impedance to
isolate the peak detector, a zero adjust 44 and a voltage follower
46 which provides a high fixed impedance to isolate the zero
adjust.
To most clearly understand the operation of the system, reference
is made to the voltage versus time diagrams of FIG. 2, which are
not to scale. As shown in FIG. 2, square pulses 50 produced by
astable multivibrator 10 trigger narrower rectangular pulses 52
produced by one-shot multivibrator 12. Pulses 52 are
frequency-modulated by oscillator 14 and exit AND gate 16 as pulses
54 which are amplified and transmitted through the sample chamber
by transducer 20. Depending upon the type of solids concentration,
the pulses transmitted by transducer 20 will be received by
receiving transducer 22 as a pulse train 56a to 56e, then 57a to
57e, etc., with each pulse train comprising a root signal
designated with the letter a and reflected echo signals designated
with the letters b, c, d, e, etc. The astable multivibrator 10 is
adjusted so that pulses 50 will be spaced in a manner whereby
pulses 54 are spaced apart a greater length of time than the total
decay time of a pulse train. In this manner, root signal 56a and
all of its measurable reflected echo signals will be received by
transducer 22 prior to reception of root signal 57a.
It has been found that the desired accuracy of measurement can be
achieved when only a selected one of the reflected echo signals of
each train is displayed. To this end, the leading edge 50a of pulse
50 triggers delayed pulse generator 28 to produce pulses 60.
Delayed pulse generator 28 is adjusted so that the lagging edges 62
of pulse 60 will trigger one-shot multivibrator 30 just prior to
reception of the selected reflected echo signal. Thus leading edge
64a of pulse 64 produced by one-shot multivibrator 12 will be timed
just prior to reception of the selected reflected echo signal and
lagging edge 64b of pulse 64 will be in time just subsequent to
reception of the selected reflected echo signal. It can be seen
that the second reflected echo signal 56c, 57c, of each train was
selected and leading edge 64a is in time between first reflected
echo signal 56b and second selected reflected echo signal 56c while
lagging edge 64b is in time after selected reflected echo signal
56c and before the third reflected echo signal 56d.
Pulses 64 are fed to input 32a of AND gate 32 while the output of
peak detector 26 is fed to the other input 32b of AND gate 32. The
output of AND gate 32 is fed to the high-speed diode 34. The output
of high-speed diode 34 is fed to the negative input 26b of peak
detector 26, to capacitor 36 and to voltage follower 42.
Peak detector 26 operates in the following manner. As the voltage
into the peak detector is high, the peak detector emits a high
voltage level signal to charge capacitor 36. Such charge continues
until the voltage level at negative input 26b, as determined by the
voltage on capacitor 36, is equal to the voltage at the positive
input 26a of peak detector 26. When the input signal into input 26a
drops below the voltage level at negative input 26b, as determined
by the voltage on capacitor 36, the voltage on capacitor 36 holds
due to diode 34. Thus capacitor 36 holds the peak voltage and
displays it on display means 40. In effect, the peak is detected
only when AND gate 32 receives pulses 64 and the signal level on
positive input 26a of detector 26 is higher than the voltage on
capacitor 36 and negative input terminal 26b of peak detector 26.
This will occur only during transmission of the selected reflected
echo pulse to the positive input terminal 26a of detector 26. The
peak is displayed continuously because the charge on capacitor 36
is held by the diode 34 and the high impedances of the voltage
follower 42 and the peak detector 26.
The length of pulses 50 and 52 are selected in accordance with the
distance between transducers 20 and 22, and the approximate speed
of sound through the liquid (i.e., the time required for a sound
wave to travel through the liquid). In a specific embodiment of the
invention, the transducers 20 and 22 were spaced apart 4 inches.
The spacing must be far enough apart to prevent standing waves from
building up in the sample chamber. Thus the trailing edge of the
pulse has to clear the sending transducer 20 before the leading
edge of the pulse is received by the receiving transducer 22.
Additionally, it is necessary to have enough pulses to identify the
frequency.
In a specific embodiment, pulses 50 were square with the time
between their leading edges 50a being 3.5 milliseconds. It is
preferred that the time between leading edges 50a of pulses 50 be
between 2 and 8 milliseconds. In a specific embodiment, pulses 52
had a width of 70 microseconds and oscillator 14 provided a 2.5
megahertz frequency modulation. Although gated oscillator 14 can
operatively provide a frequency of between 100 kilohertz and 10
megahertz, it is preferred that the frequency be between 1.0
megahertz and 3.5 megahertz. It is further preferred that at least
100 pulses 50 be produced by multivibrator 10 for proper
accuracy.
It is preferable to provide a crystal oscillator 14 so that it can
operate at a very stable frequency. I have found that although
various piezoelectric transducers could be used, transducers 20 and
22 are preferably lead metaniobate or lead zirconate titanate, both
of which have a low Q and do not ring. It is also important that
the peak detector (comparator) 26 be of a high speed, such as 60
megahertz. It is to be understood that the foregoing specific
parameters and the following specific parameters are for
illustrative purposes only, that no limitation is intended, and
that other components may be used in connection with the block
diagram illustrated in FIG. 1:
Circuit Elements Integrated Circuit Model No.
______________________________________ Astable multivibrator 10
Fairchild 710C One-shot multivibrator 12 Fairchild 710C Oscillator
14 Fairchild 710C Amplifiers 18,24 Fairchild 733C Peak detector 26
Fairchild 760C AND gate 32 Fairchild SH3002 Delayed pulse generator
28 Fairchild 9601 One-shot multivibrator 30 Fairchild 9601 Voltage
followers 42, 46 Fairchild 741
______________________________________
A system has been provided for quick, repetitive measurements of
the percentage of solid material in a liquid or the percentage of
an immiscible liquid in a liquid. Although an illustrative
embodiment has been shown and described, it is to be understood
that various modifications and substitutions may be made by those
skilled in the art without departing from the novel spirit and
scope of the present invention .
* * * * *