U.S. patent number 3,911,178 [Application Number 05/443,319] was granted by the patent office on 1975-10-07 for painting of a molded urethane part.
This patent grant is currently assigned to McCord Corporation. Invention is credited to Floyd E. McDowell, Michael J. Williams.
United States Patent |
3,911,178 |
McDowell , et al. |
October 7, 1975 |
Painting of a molded urethane part
Abstract
Molded urethane automobile parts containing an internal waxy
mold release agent that normally causes "fisheying" in urethane
paints used to topcoat such parts are effectively painted by first
applying a thin clear coat of the thermosetting vehicle of a
urethane-type paint free of pigment, at least partially curing the
clear coating to bind the lubricant or mold release agent, followed
by application of the pigmented final color coat of a urethane
paint and fully curing both coats.
Inventors: |
McDowell; Floyd E. (Exeter,
NH), Williams; Michael J. (Somersworth, NH) |
Assignee: |
McCord Corporation (Detroit,
MI)
|
Family
ID: |
23760325 |
Appl.
No.: |
05/443,319 |
Filed: |
February 19, 1974 |
Current U.S.
Class: |
427/316; 427/307;
427/322; 427/379; 427/393.5; 427/412.1; 428/31; 428/423.3;
428/425.9 |
Current CPC
Class: |
B05D
7/02 (20130101); C08J 7/04 (20130101); B05D
7/546 (20130101); C08J 2375/04 (20130101); Y10T
428/31609 (20150401); Y10T 428/31554 (20150401) |
Current International
Class: |
C08J
7/04 (20060101); C08J 7/00 (20060101); B05D
7/02 (20060101); B05D 3/02 (20060101); B32B
027/40 (); B05D 001/38 () |
Field of
Search: |
;117/72,138.8D,47A,47H
;161/190 ;264/300,DIG.77 ;427/316,307,322,379,385,407 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Husack; Ralph
Attorney, Agent or Firm: McGlynn and Milton
Claims
We claim:
1. In the painting with a paint of a molded urethane part made from
a moldable urethane formulation containing a wax of a type and in
an amount sufficient to serve as a mold release agent, said paint
comprising a urethane lacquer vehicle with a pigment dispersed
therein, the improvement comprising:
A. cleaning a surface of said part to at least in part remove said
wax therefrom:
B. applying a clear continuous barrier coat to said surface of said
vehicle free of pigment as a film having a thickness under 0.5 mil,
dry;
C. at least partially curing said barrier coat by heating to a film
temperature in the range of 180.degree.-260.degree.F, and
D. applying said paint as a film and curing said film by baking at
a film temperature in excess of 225.degree.F.
2. The process of claim 1 wherein said barrier coat and said paint
contain a solvent and are applied to said part after the part has
been heated to a temperature greater than 130.degree.F, and the
part is allowed to air flash after application of the barrier coat,
and after application of said paint prior to baking.
3. The process of claim 1 wherein said wax is selected from the
group consisting of esters and amides of c.sub.12 -C.sub.24 fatty
acids and said film of said paint has a thickness of at least 1
mil, dry.
4. The process of claim 1 wherein said wax is
ethylene-bis-stearamide.
Description
INTRODUCTION
Certain automobile interior and exterior parts are now made from
molded urethanes such as the so-called thermoplastic urethanes and
the self-skinning urethane foams. Such parts after molding are
painted to color match the color of the automobile.
Internal mold release agents are customarily used in the
manufacture of such parts, such as waxes added to the molding
formulations which migrate, bleed or bloom to the surface during
molding and aid in release of the part during demolding. When a
paint comprising a vehicle and a pigment is applied to such a
molded surface the mold release agent can be absorbed by the paint
film and effect the forces that hold the pigment in dispersion in
the paint such that "fisheying" or "crawling" will occur in the
paint film, i.e., the pigment in the paint tends to separate in
areas where the mold release agent or lubricant is present on the
surface of the part such that pigment pockets or voids result.
The mold release agents that are preferred are usually esters or
amides of C.sub.12 -C.sub.24 fatty acids. Once they have migrated
to the surface and served their mold release function, they are
quite difficult to remove. Reasonably cleaning with solvents or
detergents will often not reliably do so.
THIS INVENTION
It has now been found that when such molded parts are to be painted
with a urethane type paint that contains a dispersed pigment, the
deleterious effect of the mold release agent on the surface can be
blocked by first applying a clear coat of only the urethane vehicle
of the paint and at least partially heat curing the clear coat
following which the part can be painted in the normal manner. It
has been found that the lubricant on the surface of the part does
not prevent wetting and uniform film formation by the urethane
vehicle and that once the clear film is at least partially cured
this seems to "lock" the lubricant in and prevent further migration
of any significant amount thereof that would be harmful to the
subsequently applied paint film.
In one situation where Chevrolet "B" and Cadillac bumper end
fillers were being manufactured, rejects because of unsatisfactory
paint film formation were reduced from an average of 10 to 12 per
cent to under 3 per cent by the use of the barrier coat technique
of this invention.
Full curing of the clear barrier coat prior to the application of
the final topcoat does not appear to be required. Heating of the
film to a true film temperature in a range of 180.degree. to
260.degree.F appears to adequately bind the lubricant while leaving
the barrier coat film sufficiently uncured to bind well with the
topcoat when it is applied. The barrier when partially cured in
this manner will not normally pass the xylene rubbing test although
in some cases it may be sufficiently cured to do so. Too hard a
cure of the clear barrier coat may prevent the topcoat from
effectively bonding with it. After the topcoat is applied both
films are fully cured by heating them to a temperature above
225.degree.F.
The clear barrier coat film while continuous need not have a
thickness of greater than 0.5 mil as film thicknesses in the order
of 0.2 to 0.4 mil seems to lock adequately the mold release
lubricant in against migration. Thicker films may contribute to
cold flex cracking. The top pigment-containing paint film can have
the customary thickness, usually about one mil or more.
Generally it is desirable to remove as much as possible of the mold
release agent by solvent degreasing, detergent washing or the like
so as to minimize the chance of strike through.
Because both the barrier coat and the paint contain a solvent, it
is preferred to heat the part to a temperature greater than
130.degree.F prior to their application and to allow the part to
air flash after the application of the barrier coat and after the
application of the paint.
While the paints used in the present inventions are referred to as
urethane paints or urethane lacquers, they are more properly
identified as urethane-polyester-extended melamine lacquers the
vehicles of which are cross-linkable or heatcurable.
DRAWING
Attached to and forming a part hereof is a drawing which
schematically illustrates the significant steps of the process of
this invention and is self-explanatory.
In the drawing the first block, block 10, is labeled "Mold Urethane
Part with Internal Mold Release Agent." Block 11 is labeled "Clean
Surface" and block 12 is labeled "Apply Clear Coat of Urethane
Vehicle." Block 13 is labeled "Partially Cure Clear Coat." Block 14
is labeled "Apply Color Coat of Vehicle Plus Pigment" and block 15
is labeled "Fully Cure Both Films."
EXAMPLE
Test blocks 8 inches .times. 8 inches .times.1/8 inch are prepared
by injection molding of a thermaplastic urethane, Roylar E-2B sold
by Uniroyal Chemical, Naugatuck, Connecticut, 60770, to which 0.3
weight percent of ethylene-bis-stearamide is added as a mold
release agent. Advawax 280 F sold by Cincinnati Milacron Chemicals,
Inc. Reading, Ohio 45215 could as well be used. The surface of the
test blocks are cleaned by washing with a xylene soaked rag.
The clear lacquer used is Durathane 100 applied by an air gun as
supplied by the manufacture, Pittsburgh Plate and Glass Chemical
Company. The color coat used is Durathane 100 dark metallic green
(WV-4517) also applied by air gun as supplied.
The test blocks are preheated to 130.degree.F prior to application
of the first coat and are allowed to air flash for about 5 minutes
after the first coat is applied.
One block is coated with the color coat after the solvent washing
and after the air flash it may be noticed that unacceptable
fisheying has occurred.
The 8 inch .times. 8 inch surface of another preheated block is
first coated with a 0.3 mil film (dry) of the clear Durathane 100,
air flashed and baked 30 minutes at 200.degree.F. After allowing
some cooling but while the part is still warm the surface is
sprayed with a one mil film (dry) of the color coat, air flashed
for a few minutes then baked at 240.degree.F for 30 minutes. Paint
film formation will be noticed to be good and the sample will pass
all of the usual tests such as flex cracking, aging, weathering,
and the like.
* * * * *