U.S. patent number 3,910,806 [Application Number 05/429,604] was granted by the patent office on 1975-10-07 for method for metalizing a cathode ray tube screen.
This patent grant is currently assigned to Zenith Radio Corporation. Invention is credited to James W. Schwartz.
United States Patent |
3,910,806 |
Schwartz |
October 7, 1975 |
Method for metalizing a cathode ray tube screen
Abstract
This disclosure depicts methods and structures for applying a
very thin layer of electrically conductive, light-reflective metal
such as aluminum to the phosphor screen of a cathode ray tube. More
particularly, there is disclosed the application of such a metal
layer by the transfer of a metal layer formed on a substrate
directly to a phosphor layer on the inner surface of a cathode ray
tube faceplate. The metal layer is adhered to the phosphor layer by
an adhering step which may involve the use of a pressure-sensitive
adhesive. In one embodiment disclosed, the substrate is then
stripped off; alternatively, the substrate may be removed by
dissolution or volatilization. Remaining volatile substances are
driven off in a baking operation. Other associated and alternative
operations are depicted.
Inventors: |
Schwartz; James W. (Glenview,
IL) |
Assignee: |
Zenith Radio Corporation
(Chicago, IL)
|
Family
ID: |
23703949 |
Appl.
No.: |
05/429,604 |
Filed: |
January 2, 1974 |
Current U.S.
Class: |
156/233; 156/237;
430/23; 427/68; 430/139 |
Current CPC
Class: |
H01J
29/28 (20130101) |
Current International
Class: |
H01J
29/18 (20060101); H01J 29/28 (20060101); B44C
001/10 (); G03C 005/00 () |
Field of
Search: |
;156/230,233.7,241
;117/33.5CM,33.5C,33.5CP ;96/36.1 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Drummond; Douglas J.
Attorney, Agent or Firm: Coult; John H.
Claims
I claim:
1. A method for making a luminescent screen on the concave surface
of a curved faceplate for a color cathode ray tube, comprising (not
necessarily in the following order):
depositing on the inner surface of the cathode ray tube faceplate a
phosphor screen comprising interleaved patterns of red-emissive,
blue-emissive and green-emissive phosphor materials held in a
photosensitized volatilizable binder;
providing a web comprising a flexible and deformable sheet
substrate, a release agent deposited on the substrate and an
ultra-thin layer of electrically conductive, light-reflective metal
deposited on the release agent;
applying to the layer of a metal a pressure-sensitive adhesive
which volatizes at a temperature not exceeding the volatization
temperature of said binder;
using a press having a contour related to that of the concave
surface of the faceplate, pressing the web against the inner
surface of the faceplate by successive contact of adjacent web
areas so as to adhere the light-reflective layer to the phosphor
screen without forming air bubbles under the web;
stripping off the substrate; and
baking the faceplate at a temperature effective to volatilize said
binder and said adhesive to thereby leave a patterned phosphor
screen covered with said ultra-thin layer of metal.
2. The method defined by claim 1 wherein said substrate comprises a
thermoplastic material and wherein said step of pressing the web
includes heating the press and the web during the pressing
operation to cause the web to assume the exact contour of the
platen.
Description
Background of the Invention
This invention relates in general to the fabrication of phosphor
screens for cathode ray tubes, and more particularly to improved
methods and structures for applying a metal layer on the phosphor
screen of a television cathode ray tube of a type having an
envelope which includes a separate faceplate section. The metal
layer, typically aluminum has the following primary functions.
First, it serves as the high voltage accelerating anode for the
cathode ray tube and acts as an electrically conductive layer for
preventing the build-up of charge on the screen. Second, it
reflects to the viewer light emitted rearwardly by the phosphor
screen. Third, it acts as a physical barrier preventing negative
ions from striking the phosphor screen.
It is standard practice in the fabrication of cathode ray tube
screens to deposit a phosphor layer containing the phosphor
material and a binder on the inner surface of the faceplate.
Subsequently, a thin layer of aluminum is evaporated on the
phosphor layer. Before the metal layer is deposited on the phosphor
layer, an intermediate smoothing film is applied in order to
improve the surface characteristics of the deposited aluminum
layer.
The deposition of the thin metal layer, due to the nature of the
vacuum deposition process, involves mounting the faceplate on a
vacuum chamber, pumping the chamber down to a vacuum, heating a
boat of aluminum and timing the evaporation to insure deposition of
a metal layer having the appropriate thickness (typically 1500 A).
The metal layer is desirably thick enough to reflect light emitted
by the phosphor screen and yet thin enough to be transparent to the
electron beam. The described evaporation process, particularly when
set up on a high volume assembly line, is undesirably expensive.
U.S. Pat.
Prior Art
This invention is directed to an improved cathode ray tube screen
metalization process involving the transfer of a metal layer to the
screen. It has been suggested in U.S. Pat. Nos. 2,734,013;
3,389,030; and 3,649,269 that a phosphor layer may be formed on the
faceplate of a cathode ray tube by a transfer process. These
patents discuss transfer processes in which a self-supporting web
or decal containing a phosphor material and a binder is formed on a
base and then subsequently transferred to a flat plate or cathode
ray tube faceplate. Metalization of the transferred screen is
achieved by conventional evaporation techniques after formation of
the screen. U.S. Pat. No. 2,734,013 suggests as an alternative,
without elaboration, that the ". . . light-reflecting layer may be
applied . . . during fabrication of the decalcomania . . . "
None of these teachings are useful in solving the problem to which
the present invention is addressed for at least the following
reasons. The present invention involves the metalization of color
phosphor screens, the phosphor patterns on which are, in the most
common application, formed by photochemical processes which employ
each tube's shadow mask as the mask for the phosphor pattern. A
phosphor screen with a pre-formed phosphor pattern is thus not
useful. Further, none of these patents deal with the metalization
of pre-formed phosphor screens.
The brief suggestion in the U.S. Pat. No. 2,734,013 that the
light-reflective layer may be transferred along with the phosphor
layer is neither substantiated nor useful in the context of the
present invention. The U.S. Pat. No. 2,734,013 suggests the
feasibility of transferring a metal layer to a cathode ray tube
faceplate, which layer is supported on a laminate comprising a
layer of phosphor in a binder and a second film layer serving as a
smooth base for the metal layer. The present invention is addressed
to the much more difficult and dissimilar problem of transferring a
very thin and fragile, unsupported layer of metal, typically only
1500 A thick, to a preformed patterned phosphor screen without
tearing of the layer and with satisfactory uniformity and
yield.
Metalization by direct transfer techniques has been known to be
successfully tried only on small articles, as disclosed, e.g., in
the article "Application of the Transfer Tape Technique in Electron
Tubes," ADVANCES IN ELECTRON TUBE TECHNIQUES, Proceedings of the
6th National Conference, Sept. 1962.
Other Prior Art
U.S. Pat. No. 2,858,233
Objects of the Invention
It is a general object of this invention to provide improved
methods and structures for metalizing the phosphor screen of a
cathode ray tube.
It is a less general object to provide methods for metalizing
cathode ray tube screens which are vastly more simple and
economical than the prior art vacuum metalization methods.
It is yet another object to provide such metalization methods and
structures which yield a metal layer having greater reflectivity
than prior art methods and structures, and thus to provide
metalization methods and structures which result in a greater
luminous output from the processed cathode ray tube.
Brief Description of the Drawings
The features of the invention which are believed to be novel are
set forth with particularity in the appended claims. The invention,
together with further objects and advantages thereof, may best be
understood by reference to the following description taken in
conjunction with the accompanying drawings and in which:
FIGS. 1-8 show, in highly schematic fashion, a method and structure
for metalizing a cathode ray tube screen in accordance with this
invention; and
FIGS. 9-15 depict an alternative method for implementing the
principles of this invention.
Description of the Preferred Embodiments
This invention has general applicability to the metalization of
phosphor screens of cathode ray tubes of the types having envelopes
including a discrete faceplate or front panel. In accordance with
this invention, the phosphor screen of a cathode ray tube is
metalized by a transfer process which involves forming a layer of
metal to be applied to the screen on a substrate and subsequently
transferring the metal layer to the phosphor screen. In a preferred
method of practicing the invention, shown diagrammatically in FIGS.
1-8, the substrate is adapted to be stripped from the transferred
metal layer.
Before engaging a discussion of the preferred screen metalization
process, there will first be described a preferred method for
forming a metalized web from which the metal layer is transferred.
FIG. 1 illustrates a substrate 10. For reasons which will become
clear as this description proceeds, the substrate 10 is preferably
composed of a flexible and deformable material which may, for
reasons stated below, be a thermoplastic material, such as a
polyester, having a thickness approximately 0.0005 inch, however,
it is contemplated that substrates composed of other materials such
as polypropylene and shrinkable polyester may be used.
A release agent 12 is preferably employed to release from the
substrate 10 layers subsequently deposited thereon. The release
agent must be compatible with the operation and manufacture of the
involved cathode ray tube and must provide a smooth base for
successively deposited layers; it may be removable, as by
dissolution or volatilization.
By way of example, it has been found that 4 .times. 10.sup..sup.-7
inch layer of evaporated sodium chloride works very satisfactorily.
It is contemplated that other materials such as potassium chloride,
or other salts may also be employed. Sodium chloride has been used
previously as a release agent in an experimental image tube
manufacturing process wherein a layer thereof was deposited upon a
flat glass substrate, followed by evaporation of a layer of
aluminum. The substrate was immersed in a solvent which dissolved
the sodium chloride, permitting the aluminum layer to float free in
the solvent. The aluminum layer was lifted from the solvent and
deposited upon the faceplate of a prescreened image tube.
FIG. 2 shows the FIG. 1 substrate 10 and release agent 12, upon
which is deposited a thin layer 14 of electrically conductive,
light-reflective material such as aluminum. In successful
reductions to practice of the present invention, a layer of
aluminum approximately 1500 A thick was evaporated on the substrate
10 and release agent 12 in a conventional vacuum deposition
chamber.
To cause the metal layer 14 to adhere to a phosphor layer on the
inner surface of a cathode ray tube faceplate (to be described in
detail below), a thin layer of adhesive 16 is deposited upon the
metal layer 14 and cured. In accordance with this embodiment of the
invention, the adhesive is preferably a pressure-sensitive adhesive
such as K-396N or 86-2003, manufactured by National Starch &
Chemical Corporation, which is capable of being converted to
gaseous form if heated to temperatures above about 400.degree.C. By
way of example, a 100-400 A layer of such adhesive may be employed
as the adhesive 16.
The adhesive 16 preferably has a high flash point in the interest
of safety; it also must be compatible with cathode ray tube
manufacture and operation. It is desirably used in the smallest
amount as possible which will cause satisfactory adhesion of the
metal layer since it will ultimately have to be baked out through
the transferred metal layer. In the preferred method of application
the adhesive is sprayed upon the metal layer 14 so as to form a
discontinuous layer comprising discrete adhesive drops spaced on
the surface of the metal layer 14. It is contemplated that other
adhesives than those described and other application methods may be
employed to carry out the teachings of this invention.
FIG. 4 depicts a cathode ray tube faceplate 18 having disposed on
an inner surface 20 thereof a phosphor layer 22 comprising a
phosphor material held in a photosensitized binder. The phosphor
layer 22 may be deposited by conventional slurry techniques and
comprises, in a color cathode ray tube, e.g.,
successively-deposited layers of red-emissive, blue-emissive and
green-emissive phosphor materials carried typically in a
photosensitized binder of PVA (polyvinyl alcohol).
FIG. 5 illustrates a step wherein the web 24, comprising substrate
10, release agent 12, metal layer 14 and adhesive 16, is applied to
the phosphor layer 22. In the schematic FIG. 5 illustration, the
application is accomplished by first draping the web 24 over a
press 26. In the FIG. 5 illustration, the press 26 is shown as
comprising a base 28 having an upper surface 30 having generally
the contour of the inner surface 20 of the faceplate 18. Disposed
on the base 28 is a resilient cushion 32 which is somewhat thicker
in the center than on the edges in order that the press will have a
yieldable upper surface and in order that the press will cause the
web 24 to engage the phosphor layer 22 initially in the center of
the faceplate and thereafter to cause the web to be pressed against
the phosphor layer 22 progressively outwardly from the faceplate
center. By this technique, formation of bubbles under the web is
precluded. A similar pressing technique is disclosed in the
referent U.S. Pat. No. 3,389,030 in the manufacture of black and
white cathode ray tubes. Other press structures and application
techniques may be employed. It may be desirable, in order to effect
a more rapid or more conforming application of the web 24 to the
phosphor layer 22, to apply heat and/or air pressure to the web 24
as it is applied to the press or to the phosphor layer 22.
After the web 24 is adhered to the phosphor layer 22, the press 26
is removed, leaving on the faceplate a decal having the shape of
the cathode ray tube screen. The invention is preferably employed
for metalizing a phosphor screen of the "black surround" type
described and claimed in U.S. Pat. No. 3,146,368 -- Fiore et al. A
phosphor screen formed according to this patent has black material
separating phosphor elements which emit different colored light.
The black material typically extends beyond the
electron-illuminated field and onto the sides of the faceplate. The
decal preferably overlaps the black material in a screen of this
type, precluding any need to form the decal to the exact shape of
the electron-illuminated field. The decal may be formed by
pre-cutting an outline of the decal configuration with perforations
before transferring the decal, or, alternatively, the decal may be
trimmed in situ. The shape of the metal layer deposited on the
substrate can be determined, if desired, by evaporating the metal
layer onto the substrate through a mask having an opening
corresponding in configuration to the screen configuration.
Alternatively, a pre-cut decal, rather than a continuous web,
having the configuration of the screen may be employed.
In order to minimize breaking of the metal layer during the web
draping operation, it may be desirable to pre-form or partially
pre-form the substrate to the contour of the press or the faceplate
before deposition of the metal layer thereon. So that the substrate
may nevertheless be handled in roll form, pre-contoured decals may
be formed at intervals on a substrate roll, the decals
corresponding generally in size and configuration to the screen and
having concentric circular or rectangular flutes or corrugations
defining a flat bellows which is expansible out of the plane of the
web without stretching thereof. When the decals are drawn over the
press, the bellows will open and permit the decal to assume the
shape of the press without excessive stretching thereof.
As shown in FIG. 6, the substrate 10 is then stripped away, leaving
on the inner surface of the faceplate 18 the phosphor layer 22, the
adhesive 16, the metal layer 14 and the release agent 12. It should
be understood that FIG. 6 is schematic -- in practice, the
substrate would come away from the faceplate with the press.
If the release agent is sodium chloride, for example, or some other
composition which is capable of being dissolved, the release agent
may be removed by a suitable solvent. See FIG. 7. If sodium
chloride is used, the solvent may be water. The solvent, of course,
will vary with the release agent used. Alternatively, if the
release agent is sodium chloride, it may be desirable for reasons
of economy to eliminate the release agent removal operation
altogether. Tests have shown that the presence of sodium chloride
in the tube does not result, upon electron bombardment, in
poisoning of the electron guns.
FIG. 8 illustrates a baking operation for driving off the
photosensitized binder from the phosphor layer, the adhesive layer
16 and, where the release agent may be of a nature as to be readily
volatilized, the release agent. It is conventional in the
manufacture of cathode ray tubes to include a "bake-out" operation,
typically carried out at 400.degree.C or above during which the
photosensitized binder and the afore-described smoothing layer or
"film" deposited to form a base for the evaporated aluminum layer,
are driven off. Thus, since a bake-out operation is required as a
necessary step in the conventional manufacture of a cathode ray
tube, the removal of the adhesive 16 can be achieved without the
necessity of adding any special tube processing operations. Thus,
by the use of the above-described metal transfer web, and by the
above-described method, the phosphor screen of a cathode ray tube
may be rapidly and economically metalized.
It has been found in a number of screens built and tested, that
because the metal layer 14 is deposited upon a smooth surface,
i.e., the prepared upper surface of the substrate 10, rather than
on a relatively rough surface as in the case of conventional
metalization of phosphor screens, the resulting metal layer is
smoother than the metal layers deposited by conventional
evaporation techniques. Tests have shown that in some cases, gains
in brightness of the end product cathode ray tubes have been
achieved.
FIGS. 9-15 portray in highly schematic form a second embodiment of
the invention wherein the substrate comprising the base for a
transfer web or decal is not strippable, but rather is adapted to
be removed by dissolution or volatilization.
As above, before engaging a discussion of the FIGS. 9-15 screen
metalization process, there will first be described a preferred
method for forming the metalized decal or web from which the metal
layer is transferred. FIG. 9 illustrates a substrate 42. For
reasons which will become clear as this description proceeds, the
substrate 42 is preferably composed of a flexible plastic material
which may, for reasons stated below, be dissolved or volatilized. A
suitable substrate material is an acrylic film having a thickness
approximately 0.0005 to 0.0010 inch, however, it is contemplated
that a substrate composed of other materials such as
nitro-cellulose may be used.
FIG. 10 shows the FIG. 9 substrate 42, upon which is deposited a
thin layer 44 of electrically conductive, light-reflective material
such as aluminum. To cause the metal layer 44 to adhere to a
phosphor layer on the inner surface of a cathode ray tube faceplate
(to be described in detail below), a layer 46 of adhesive is
deposited upon the metal layer 44 (see FIG. 10) or on the inner
surface 48 of the faceplate 50. In accordance with this embodiment
of the invention, the adhesive preferably takes the form of a thin
film of ethyl silicate.
FIG. 11 depicts a cathode ray tube faceplate 50 having a novel
flangeless configuration, on an inner surface 48 of which is
disposed a phosphor layer 52 comprising a phosphor material held in
a binder. The phosphor layer 52 may be as layer 22 described
above.
FIG. 12 illustrates a step wherein a decal 54, comprising substrate
42, metal layer 44 and adhesive layer 46, is applied to the
phosphor layer 52. As discussed above, the decal 54 is preferably
formed to the shape and curvature of the inner surface 48 of the
faceplate 50 to minimize wrinkling of the decal 54 upon transfer
thereto and to minimize stretching of the metal layer 44.
In the schematic FIG. 12 illustration, the application is
accomplished by first draping the decal 54 over a press 56 and
securing it thereto. A tension band 57 is shown to schematically
illustrate means for securing the decal 54. The press 56 and the
decal application operation represented by FIG. 12 may be as
described above with respect to FIG. 5.
After the decal 54 is adhered to the phosphor layer 52, the press
56 is removed, leaving on the faceplate 50 a decal 54 having the
shape of the cathode ray tube screen.
The substrate 42 is then removed, preferably in this method
embodiment by dissolution, as shown schematically in FIG. 14,
leaving on the inner surface 48 of the faceplate 50 the phosphor
layer 52, the adhesive layer 46 and the metal layer 44. If the
substrate 42 comprises an acrylic, the solvent is preferably
toluene. If the substrate 42 comprises nitro-cellulose, the solvent
is preferably acetone and amyl acetate.
If the substrate 42 is of a composition such as acrylic which is
readily volatilized rather than dissolved, the dissolution step
shown in FIG. 14 would, of course, be eliminated. Rather, the
faceplate would be baked, as shown schematically in FIG. 15 to
volatilize and drive off the substrate.
The baking operation, represented in FIG. 15 by an oven 58, may be
the conventional "bake-out" operation during which the phosphor
binder and the afore-described smoothing layer or "film" deposited
to form a base for the evaporated aluminum layer, are driven off.
Thus, since a bake-out operation is required as a necessary step in
the conventional manufacture of a cathode ray tube, the removal of
the substrate 12 and the adhesive layer 16 can be achieved without
the necessity of adding any special tube processing operations.
The invention is not limited to the particular details of
construction of the embodiments depicted and other modifications
and applications are contemplated. Certain changes may be made in
the above-described methods and apparatus without departing from
the true spirit and scope of the invention herein involved. For
example, to minimize the possibility of blistering of the metal
layer during the bake-out operation, the metal layer deposited upon
the substrate may be caused to have tiny perforations which will
serve ultimately as out-gassing openings for the materials
volatilized under the metal layer. In the FIGS. 1-8 embodiment,
rather than using a release agent, as described, satisfactory
results may be obtainable by the use of a non-stick substrate, the
surface of which inherently has low adherance to the metal layer.
Alternatively, other forces than adhesion, e.g., electrostatic, may
be employed to hold the metal layer upon the strippable substrate
until the transfer of the metal layer is accomplished. Whereas in
the above-described methods the binder in the phosphor layer to
which the metal layer is transferred is described as a
photosensitized binder, the invention is equally applicable to
transferring a metal layer onto phosphor layers having
non-sensitized organic binders or phosphor layers of other
compositions. It is intended, therefore, that the subject matter of
the above depiction shall be interpreted as illustrative and not in
a limiting sense.
* * * * *