U.S. patent number 3,900,690 [Application Number 05/469,292] was granted by the patent office on 1975-08-19 for process for the production of dimensionally stable, planar materials coated on one side.
This patent grant is currently assigned to Glasurit Werke M. Winkelmann GmbH. Invention is credited to Gunther Schwarz.
United States Patent |
3,900,690 |
Schwarz |
August 19, 1975 |
Process for the production of dimensionally stable, planar
materials coated on one side
Abstract
A method of producing dimensionally stable, coated cellulose
containing base materials wherein one side of the material is
coated in a conventional manner with the customary inorganic or
organic coating agents, such as sodium silicate or synthetic resins
optionally containing coloring agents, pigments and/or hard
powdered materials, such as emery, quartz sand, pulverized glass,
silicon carbide, pumice, aluminum oxides, kieselguhr or films, and
the other side of the material is impregnated with a solution of a
silicone fluid in one or more organic solvents and the solvents are
optionally evaporated.
Inventors: |
Schwarz; Gunther (Hiltrup,
DT) |
Assignee: |
Glasurit Werke M. Winkelmann
GmbH (N/A)
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Family
ID: |
27183530 |
Appl.
No.: |
05/469,292 |
Filed: |
May 13, 1974 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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264588 |
Jun 20, 1972 |
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Foreign Application Priority Data
Current U.S.
Class: |
428/447; 427/211;
428/453; 428/537.5; 451/526; 451/531; 427/387; 428/537.1 |
Current CPC
Class: |
B32B
27/00 (20130101); D21H 17/59 (20130101); Y10T
428/31993 (20150401); Y10T 428/31663 (20150401); Y10T
428/31989 (20150401) |
Current International
Class: |
B32B
27/00 (20060101); D21H 17/00 (20060101); B05D
5/00 (20060101); D21H 17/59 (20060101); B05C
009/04 (); B44D 001/02 () |
Field of
Search: |
;117/68,68.5,155R,155L,161L,161LN,161ZA ;51/394,399 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lusignan; Michael R.
Attorney, Agent or Firm: Wells; Gilbert L.
Parent Case Text
CROSS REFERENCES TO RELATED APPLICATIONS
The present application is a Continuation of application Ser. No.
264,588, filed June 20, 1972, and now abandoned. Applicant claims
priority under 35 U.S.C. 119 for Application P 21 32 925.9, filed
July 2, 1971 in the Patent Office of the Federal Republic of
Germany. A copy of the priority document is in the file of
application Ser. No. 264,588.
Claims
I claim:
1. A method for producing a dimensionally stable porous cellulosic
substrate by impregnating the uncoated side opposite to that
bearing a moistureproof impermeable surface coating with silicone
fluids, and drying said coating, the improvement comprising
applying to said uncoated side of said substrate a solution
containing 90 - 97 percent by weight of a solvent selected from the
group consisting of organic hydrophilic solvents or solvents
containing not less than 10 percent of said hydrophilic solvents
and 3 - 10 percent by weight silicone fluid having a viscosity of
0.65 - 1,000,000 centistokes and a molecular weight between about
600 - 400,000.
2. The method of claim 1, wherein said impermeable surface coating
is selected from the group consisting of sodium silicate and
synthetic resins.
3. The method of claim 1, wherein said impermeable surface coating
is a pressed film.
4. The method of claim 1, wherein said base sheet material is
exposed to moisture prior to the application of said silicone
fluid.
5. The product obtained by the method of claim 1.
Description
BACKGROUND OF THE INVENTION
This invention relates to a process for the production of
dimensionally stable planar materials of a cellulose-containing
substance, which are coated on one side and which tend to warp,
buckle, or bulge due to characteristic physical properties of the
cellulose-containing substance and the coating applied to one
side.
Cellulose-containing materials, insofar as they are coated on one
side, are not dimensionally stable, i.e., these materials warp
torsionally or are distorted tensionally, planar materials bulge or
are bent to a greater or lesser extent depending on the thickness
of the sheet. Thus, for example, paper webs, cardboards, hardboard
sheets of wood pulp or some other cellulose-containing material, or
vulcanized fiberboard sheets which are unilaterally coated have the
disadvantageous property of warping to differently strong degrees,
depending on the amount of atmospheric humidity. This troublesome,
undesirable phenomenon makes it difficult in most cases to use,
manipulate, and completely exploit, for example, abrasive belts,
emery paper, or abrasive papers, as well as self-adhesive films or
self-adhesive wallpapers. Hardboards made from wood pulp or
cellulose compounds are used in furniture manufacture, for house
trailers, and for the interior outfitting of automobile bodies.
They furthermore serve as building components in prefabricated
house construction. With the use of hardboards coated on one side,
the distortion behavior can cause warping by tensional forces, and
for example, can render furniture or house trailers manufactured
therefrom unattractive after a short period of time. Also,
fastening operations as employed in building construction, for
example gluing, affixing, or nailing, can be carried out when the
hardboard sheets coated on one side are deformed, only at increased
expense and by special procedures, without being able to ensure
durability. The only possible countermeasure against warping has
heretofore been to coat these sheets or papers symmetrically on
both sides in the same manner. However, this can almost never be
accomplished in practice.
SUMMARY OF THE INVENTION
It is an object of the present invention to avoid these
disadvantageous properties of the coated materials made of
cellulose-containing substances so that they no longer occur, and
the materials remain dimensionally stable.
This problem has been solved, surprisingly, by a process for the
production of dimensionally stable, coated, planar materials of
cellulose-containing substances which is characterized in that one
side of the material is conventionally coated with the customary
inorganic or organic coating agents, such as, for example, sodium
silicate or synthetic resins which can contain coloring substances,
pigments and/or hard powdered materials of various degrees of
fineness, such as emery, quartz sand, pulverized glass, silicon
carbide, pumice, aluminum oxides, kieselguhr, or film coated,
whereas the other side of the material is treated with a solution
of a silicone fluid in one or more organic solvents so that the
silicone fluid penetrates into the pores of the material and the
solvent is optionally evaporated.
Solvents which are hydrophilic are preferred. They are used by
themselves or in a mixture with other organic solvents.
The process is carried out so that 1-30 g./m.sup.2 of a 0.1-50
percent by weight, preferably 3-10 percent by weight, silicone
solution is applied.
The application of the silicone solution takes place directly prior
to or after the application of the principal coating on the other
side and the curing thereof, prior to or after the rewetting of the
material.
By the terms "dimensionally stable" according to the present
invention means that the materials of cellulose-containing
substances do not warp torsionally or become distorted by tensile
effects; that they do not bulge, bend, or become distorted by
bending effects, or are deformed in any other manner, as soon as
they carry a coating on one side.
The after-treatment of the uncoated side of the materials according
to the present invention, which is simple to execute, surprisingly
yielded a complete, lasting elimination of the deformational
phenomena normally present. Actually, an increase in warping or
bulging was, on the contrary, to be expected, since silicone
fluids, being lubricating and smoothing substances, can affect the
internal, characteristic properties of the porous,
cellulose-containing material along the lines of a plasticizer, and
thus increase the difference in the physical behavior of the
coating with respect to the material substrate, which difference is
responsible for warping.
Materials coated on one side, such as abrasive belts, emery papers,
and abrasive paper, as well as hardboard sheets, retained their
shape when treated according to the process of the present
invention and could be used and processed substantially more
readily and trouble-free. Also storage tests under various
conditions and over rather long periods of time showed the coated
materials to be permanently dimensionally stable, without any
warping and changes otherwise occurring in untreated materials
coated on one side. It has furthermore been found that, for
example, the surface becomes essentially smoother and more
supple.
This unexpectedly advantageous effect is attained by the
application of silicone fluids in the form of a solution thereof in
organic solvents to the uncated side of the materials of
cellulose-containing substances.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Suitable silicone fluids are methyl siloxanes, methylpolysiloxanes,
methylphenyl-siloxanes, and methylphenylpolysiloxanes, wherein
organosubstituents of the same type or of different types are
present, such as, for example, products with ethyl and methyl
hydrogen groups, as well as such organofunctional groups as, for
example, .beta.-cyanoethyl, .gamma.-cyanopropyl,
.gamma.-trifluoropropyl, .delta.-aminobutyl, and tetrachlorophenyl
groups. Silicone fluids are obtained according to conventional
methods by the hydrolysis of chlorosilanes and subsequent
condensation and/or polymerization to cyclic or linear
polysiloxanes. Silicone fluids are clear, colorless, neutral, and
almost odorless fluids exhibiting viscosities of between 0.65 and
1,000,000 centistokes and a molecular weight of between 600 and
400,000. In technical literature, these compounds have been
described in detail. Thus, reference is had to the book
"Einfuehrung in die Chemie der Silikone" [Introduction to Silicone
Chemistryl] by Eugene G. Rochow, publishers Chemie G.m.b.H.,
Weinheim/Bergstrasse, 1952; and "Ullmanns Encyklopaedie der
technischen Chemie" [Ullmann's Encyclopedia of Technical
Chemistry], vol. 15, 1964, pp. 778-782.
Silicone fluids are also disclosed in the Kirk-Othmer "Encyclopedia
of Chemical Technology", 2nd Edition, Vol. 18, (1969) pages
237-241. The preparation of dimethyl silicone fluids is disclosed
at page 237, methyl phenyl silicone fluids are disclosed at p. 241
along with chlorinated phenyl groups attached to silicone, methyl
trifluoropropyl silicone fluid and methyl alkyl silicone fluids and
Table 7 on page 238 discloses the properties of Silicone Fluids.
U.S. Pat. Nos. 3,179,619 and 3,050,492 cited in Kirk-Othmer
disclose homopolymers and copolymers with dimethyl silicone.
The disclosures of these literature and patent references to
silicone fluids are incorporated herein.
The silicone fluids are soluble in many organic solvents, such as
aliphatic hydrocarbons, aromatic hydrocarbons, esters, furthermore
dimethyl sulfoxide, and dimethylformamide. Preferably suitable are
hydrophilic solvents, such as alcohols, especially ethyl, propyl,
butyl, isopropyl, isobutyl alcohol, furthermore glycols, glycol
esters, glycol ethers, and glycerin. Examples in this connection
are methyl, ethyl, butyl, isobutyl, propyl, and amyl glycol; methyl
glycol esters, ethyl glycol esters, butyl glycol esters, methyl
glycol acetate, ethyl glycol acetate, ethylene glycol, propylene
glycol, butyl diglycol, and other polyglycols. The solvents can be
used individually or in mixtures with one another.
The application of the silicone fluid solution to the uncoated side
of the materials is effected by means of the usual methods, such
as, for example, brushing, casting, spraying, or rolling. It is
particularly advantageous to use those silicone fluid solutions
which contain between about 0.1 and 50 percent by weight,
preferably, however, between about 3 and 10 percent by weight of
silicone fluid and 90-97 percent by weight solvent.
The process of this invention is applicable to all materials made
of cellulose-containing substances which are coated on one side.
Materials made from cellulose-containing substances are intended to
mean all materials which contain cellulose-containing matter on the
outer surface of the material. The materials can have any desired
shape, but are preferably planar materials, such as, for example,
sheets, panels, films which can be linear or curved. Among the
suitable materials are cardboard, papers, films of cellulose
material, hardboards, composite sheets, plywood panels, and
vulcanized fiber.
The materials are coated on one side; in other words, they are
covered with a hardened layer which provides an airtight seal
against the surrounding atmosphere for the material of
cellulose-containing matter. Thereby, the cellulose-containing
substance can breathe, and the moisture exchange at varying
atmospheric humidities can take place, only toward the uncoated
side.
The materials of cellulose-containing matter can be coated on one
side with any desired layer which ensures an airtight seal for this
side from the surrounding atmosphere. These layers can be of an
inorganic or organic character. Thus, suitable substances are, for
example, synthetic resins, such as urea-formaldehyde resins,
melamine-formaldehyde resins, or phenol-formaldehyde resins, alkyd
resins, polyester resins, polyamide resins, epoxy compounds,
polyurethanes, polysulfides, polybutadiene, chlorinated rubber,
polyethylene, polypropylene, and many others.
It is furthermore possible to embed into the synthetic resins
coloring agents, hard powders of various degrees of fineness, and
pigments, such as, for example, emery, quartz sand, powdered glass,
carbides, silicon carbide, pumice, aluminum oxides, kieselguhr,
polishing agents, etc.
The coating can furthermore consist of an inorganic material, e.g.
sodium silicate.
The production of such coatings does not pertain to the subject
matter of the present application. They can be applied in a
conventional manner by rolling, spraying, calendering the coating
agents from solutions in organic solvents or from aqueous
dispersions. It is also possible to press films against the
substrate. Thereafter, the coating can be dried and cured in the
usual manner. The curing process is omitted in the manufacture of
self-adhesive films. After the coated side has been cured by baking
at elevated temperatures in the usual manner, the material of
cellulose-containing matter contains only minor amounts of
moisture. In order to restore the equilibrium with respect to the
atmospheric humidity, a rewetting is generally carried out after
the curing procedure, by spraying the uncoated side with water.
According to the process of the present invention, the silicone
fluid solution is applied prior to or after the curing process and
prior to or after the rewetting step.
The materials coated on one side and obtained according to the
process of the present invention are required for a great variety
of fields of application. Thus, it is, above all, possible to
produce abrasive papers and abrasive belts in a dimensionally
stable form. Also hardboards and plywood panels can find a
broadened application in the furniture, house trailer, and building
industries. Also vulcanized fiberboards remain dimensionally
stable. Further fields of use are the treatment of self-adhesive
films, self-adhesive wallpapers, as well as postage stamps.
The following examples are to explain the process of this invention
without limiting same. All percentage data relate to percent by
weight and all parts are parts by weight.
EXAMPLE 1
An abrasive belt, coated on one side with a phenolic resin and the
usual abrasive agents, is treated on the uncoated side with a
solution of 5 parts by weight of phenyl methyl siloxane (having the
trade name silicone oil PL from Bayer AG, Leverkusen, Germany) in
butyl glycol. With the aid of a roll, between 10 and 15 g./m.sup.2
(grams per square meter) is rolled onto the substrate. After the
solvent has been evaporated and the belt has dried, a supple,
smooth, distortion-free abrasive belt is obtained which permanently
retains its shape.
EXAMPLE 2
A hardboard panel, covered on one side with a varnish coat of an
acid-curing varnish with a layer thickness of 50-100 micron, is
treated on the backside by rolling thereonto a solution of 6 parts
of a methylpolysiloxane (having the tradename silicone oil M from
Bayer AG, Leverkusen, Germany) in a mixture of butyl glycol and
glycerin (80:20). In this way, 15-17 g./m.sup.2 is applied. A
hardboard panel is thus obtained which retains its smooth form and
does not warp even at extreme atmospheric humidity values.
EXAMPLE 3
A paper web coated with a phenolic resin wherein emery is embedded
and exhibiting a thickness of 1.2 mm. is sprayed on the uncoated
side with a solution of 5 parts by weight of silicone oil M (as
described in example 2) in a mixture of 60 parts of toluene, 15
parts of monoglycol butyl ether, and 15 parts of isobutanol, so
that about 15-17 g./m.sup.2 is thus applied. After drying for 10
hours at 60.degree.C in a drying chamber, the dimensional stability
was retained without change after a storage period of 6 weeks at a
relative atmospheric humidity of 80 percent, whereas an identical
sample treated only with the solvent mixture without the silicone
fluid in the same manner exhibited strong warpage after a short
storage period of 20 hours.
EXAMPLE 4
A solution of 5 parts by weight of silicone oil PL (as described in
example 1) in a mixture of 90 percent of mineral spirit and 10
percent of butanol is rolled onto the backside of a hardboard panel
provided with an epoxy coating, immediately after baking the epoxy
coating. After drying in air, the uncoated backside is sprayed with
water. About 14 g./m.sup.2 of the silicone fluid solution is
applied. The thus-treated hardboard panel retains it smooth,
dimensionally stable shape and shows no tendency toward
bulging.
EXAMPLE 5
Papers coated on one side, e.g. postage stamps or wallpapers
wherein the coating consists of a glue film are treated, on the
uncoated side
a. prior to the glue application,
b. simultaneously with the glue application, or
c. after the glue application
with an 8 percent solution of a methylpolysiloxane (having the
tradename silicone oil M from Bayer AG, Leverkusen, Germany) in
butyl diglycol by spreading. The amount of silicone oil solution
applied depends on the weight of the paper and on the compression
of the paper and amounts, on the average, to between 5 and 30
g./m.sup.2. After drying, gummed papers (postage stamps or
wallpapers) are obtained which neither bulge nor warp.
EXAMPLE 6
A self-adhesive surfacing or decorative sheet wherein the substrate
consists of papers impregnated with ureaformaldehyde or
melamine-formaldehyde or phenol-formaldehyde resins and the
self-adhesive coating consits of melamine resin or urea resin, is
treated with the silicone fluid solution as indicated in Example 1.
After drying, the self-adhesive foils do not warp and retain their
smooth shape on a permanent basis.
EXAMPLE 7
For comparison purposes, an abrasive belt coated, as described in
Example 1, on one side with a phenolic resin and the usual abrasive
agents, is treated on the uncoated side by rolling with a mixture
of butyl glycol and glycerin (80:20). As in Example 1, 10-15
g./m.sup.2 is applied by rolling. The abrasive belt obtained after
evaporation of the solvent retains its smooth shape only
temporarily and is warped again after a short period of time.
* * * * *