U.S. patent number 3,895,250 [Application Number 05/341,244] was granted by the patent office on 1975-07-15 for electronic high vacuum tube and method of providing a coating therefor.
This patent grant is currently assigned to Siemens Aktiengesellschaft. Invention is credited to Hermann Christgau, Karl Franz, Jurgen Niepel.
United States Patent |
3,895,250 |
Christgau , et al. |
July 15, 1975 |
Electronic high vacuum tube and method of providing a coating
therefor
Abstract
An electronic high vacuum tube has a high vacuum container
containing two conducting parts of different electrical potentials
which produce between these parts high electrical field strength.
The invention is particularly characterized in that at least the
part which lies upon the high potential has upon its outer surface
an electrically insulating layer which binds alkali metals. This
coating is produced by immersing the part to be coated into a bath
consisting of a solution of partially condensed polyimides followed
by special treatment.
Inventors: |
Christgau; Hermann (Erlangen,
DT), Franz; Karl (Erlangen, DT), Niepel;
Jurgen (Erlangen, DT) |
Assignee: |
Siemens Aktiengesellschaft
(Munich, DT)
|
Family
ID: |
5839523 |
Appl.
No.: |
05/341,244 |
Filed: |
March 14, 1973 |
Foreign Application Priority Data
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Mar 20, 1972 [DT] |
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2213493 |
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Current U.S.
Class: |
313/358; 313/529;
313/106; 313/355 |
Current CPC
Class: |
H01J
31/501 (20130101) |
Current International
Class: |
H01J
31/50 (20060101); H01J 31/08 (20060101); H01j
031/50 () |
Field of
Search: |
;313/94,107,178,355,80,106,439 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Wibert; Ronald L.
Assistant Examiner: Rosenberger; Richard A.
Attorney, Agent or Firm: Scher; V. Alexander
Claims
What is claimed is:
1. An electronic high vacuum tube, comprising a high vacuum
container, two conducting members located within said container,
means connected with said members and providing them with different
electrical potentials which produce high electrical field strength
between said members, and an electrically insulating coating
carried by at least the member having a higher potential, said
coating binding alkali metals and consisting of a compound selected
from the group consisting of polytetrafluorethylene, polysulfon,
polyarylsulfon and silicon resin.
2. A tube in accordance with claim 1, wherein said coating has a
thickness ranging between 0.5 .mu. to 10 .mu..
3. A tube in accordance with claim 1, wherein said coating has a
thickness amounting to 5 .mu..
Description
This invention relates to an electronic high vacuum tube, the high
vacuum case of which contains two conducting parts of different
electrical potentials, which produce between them a high electrical
field strength. The invention also relates to a method of making a
coating upon one of the parts.
Tubes of this type are, for example, electronically optical image
amplifiers wherein electrodes subjected to high voltage produce an
image of released electrons upon a sheet-like photocathode.
However, they can be also used in other high vacuum tubes to
eliminate undesired effects, since no secondary electrons are
released.
The quality of electronic image amplifiers, particularly X-ray
image amplifiers is determined primarily by the amplifying factor
and the properties with which the images are transmitted. A measure
for these properties is the visually measured analysis and the
modulation transmission function which provides contrast
transmission depending upon the size of details. Since electronic
optical image transforming tubes and image amplifiers carry
voltages of 15 to 35 kv for electronic optical magnification,
disturbing field emissions can take place. In order to avoid them
as much as possible, the surfaces of the voltage carrying parts,
such as grids, actuating electrodes etc., are made very flat. For
example, the surfaces are smoothed to such an extent that all
unevenesses amounting to more than 1 .mu. m disappear. Despite this
smoothing electronic emissions or spontaneous flashovers take
place. The undesired effects consist primarily in that the
flashovers or other discharges are followed by appearance of light
which acts upon the emission layer of the photocathode and releases
electrons. These electrons produce intensive light appearances upon
the viewing screen and disturb considerably the image reproducing
properties of the tube.
An object of the present invention is to eliminate to the greatest
extent the release of electrons by electrodes which are subject to
voltage and by current carrying parts.
Other objects will become apparent in the course of the following
specification.
In the accomplishment of the objectives of the present invention it
was found desirable to provide the outer surface of at least that
part which is subject to the higher potential with an electrically
insulating layer which binds the alkali metals.
A simple reason for the detrimental effects can lie in the
manufacture of the photocathode. In the known process antimony and
caesium, or several alkali metals are steamed on in the tube upon a
carrier. Alkali metals particularly caesium are unavoidably spread
over surfaces of other parts of the tube. On surfaces covered with
alkali metals, the work function of electrons is diminished to the
work function of electrons on surfaces of alkali metals. The
coating of the present invention acts against the diminution.
In an electronic image amplifier the greatest voltage difference is
located as a rule between the third electrode and the following
anode. According to an embodiment of the present invention the
layer of an organic substance applied upon this electrode prevents
discharges in that the outer surface is smoothed, thereby
diminishing in the known manner the outflow of electrons. On the
other hand the alkali metals used in the manufacture of
photocathodes are bound by the organic substances, thereby
preventing the outgoing of the electrons at the outer surface.
As useful vacuum fixed substances were found to be organic
substances, such as thin layers of polyimide. They consist of
condensation products of organic acids, for example, pyromelilotic
acid or maleic acid with amines, for example, 1, 4 -diaminobinzol.
These layers bind alkalimetal gases and consequently those of
caesium, which appear during the making of the photocathode by a
mechanism wherein side bindings are acceptable or in the form of
fixed solutions. In addition to the diminution of surface rawness,
high fluorated hydrocarbons, such as, for example,
polytetrafluorethylene, polysulfon, particularly polyarylsulfon,
and also silicon resin, also cause the binding of alkali metals.
This has the property of binding alkali metal gases, for example,
by a substitution, whereby the freed hydrogen is removed during the
evacuation of the tube.
The invention will appear more clearly from the following detailed
description when taken in conjunction with the accompanying drawing
the sole FIGURE of which shows by way of example only, a section
through an X-ray image amplifier constructed in accordance with the
present invention .
The drawing shows an amplifier having electrodes 1, 2 and 3 located
between the cathode 4 and the anode 5 behind the inlet window 6 of
a high vacuum tube 7 consisting of glass.
The photocathode consists of a carrier 8, a luminous layer 9 and
the actual photocathode layer 10. On the other side of the
electrode structure the anode 5 is closed by the luminous layer 11
located in front of the end window 12 of the tube. The cathode is
connected by a line 13 to the ground potential of current supplying
means (not shown). The connection 14 of the electrode 1 is
subjected to 80 v., the connection 15 of the electrode 2 to a
potential of 300 v., the connection 16 of the electrode 3 to a
potential of 3.5 kv., and the connection 17 of the anode to a
potential of 25 kv. The coating of the present invention is applied
to the electrode 3 and is indicated as 18. It consists of polyimide
and is applied by a process described hereinbelow.
If an X-ray quantum passes in the known manner through the ray
inlet window and the carrier 10 and strikes the luminous layer 9,
it produces there a luminous action which releases electrons in the
photocathode layer 10. These electrons are actuated by the
potentials located at the electrodes 1, 2 and 3 and the anode 5 and
are directed to the luminous layer 11. They receive the greatest
acceleration in the range of electrode 3 and can produce there at
the outer surfaces electrons which do not come from the
photocathode and which cause appearances releasing additional
electrons at the photocathode. These would produce on the screen 11
representations which are not released by the X-rays. This is
prevented by the coating 18 which covers the outer surface of the
electrode 3. The coating has a thickness of 5 .mu. m and it
prevents the release of an uncontrollable amount of electrons.
The method of making the polyimide layer is as follows:
The inner ring is inserted with its bent edge extending downwardly
into a bath containing a solution of partly condensed polyimide
dissolved in a diluter, as, for example, dimetylformamide. It was
found advantageous to use twice as much of the diluter as of the
partial condensate, since then the solution at room temperature has
useable own viscosity. The amount of liquid in the bath can be used
to determine the duration of the application of coating upon the
electrode 3. After immersion the ring is removed from the bath, is
mounted upon a holding device to remove the excessive drops and is
dried while being rotated by an infrared radiator. After the resin
during drying has reached a viscosity wherein the layer does not
run any more, the lacquer film is heated in a warming cabinet in
air for 1 hour at 100.degree.c and thereupon for 2 hours at
300.degree.c.
A study of experiments as the result of which the present invention
was produced, showed that the thickness of layers should be in
general between 0.1.mu. and 950 .mu.. In case of thinner layers
there is the danger that holes or the like could be still present
in the layer. Thicker layers could have a negative effect upon the
photocathode. Specifically layers out of materials with a strong
binding effect upon alkalimetals can bind a great deal of metal in
case of a large amount of material due to the final steam pressure
of the alkalimetal and thus cause a reduction of alkalimetal in the
photocathode. A particularly suitable range for conditions in image
transformers lies between 0.5 .mu. and 10 .mu. , particularly at 5
.mu. , since on the one hand the creation of interfering caesium
layers is effectively avoided and on the other hand no disturbance
of the photocathode takes place as yet. The application of layers
of polyimide and silicon resin can take place in known manner by
brushing, immersing, spraying, splashing etc. In case of electrodes
used in image amplifiers the immersing process is advantageous
since a well reproduceable layer thickness is produced with small
technical exertion. This is particularly the case when excessive
amount of coating is cast off from the parts being coated by
rotation. After the application the resins can be condensed and
then degassed by heating in air and in high vacuum.
Polytetrafluorethylene is advantageously applied by sintering
whirling resin powder or by spraying a suspension followed by
sintering. Silicon resin is particularly well deposited by
electrophosetic deposit upon the electrons.
* * * * *