U.S. patent number 3,872,629 [Application Number 05/253,570] was granted by the patent office on 1975-03-25 for splicing of coated abrasive materials.
This patent grant is currently assigned to Norton Company. Invention is credited to John F. Malloy.
United States Patent |
3,872,629 |
Malloy |
March 25, 1975 |
Splicing of coated abrasive materials
Abstract
A dried, partially cured, heat-activatable preformed adhesive
film is provided in which the adhesive composition comprises in
admixture a hydroxyl terminated polyurethane-polyester and a
component having available free isocyanate groups. The partially
cured adhesive film can be used in the splicing of coated abrasive
ends together as in the formation of endless belts. Interposed
between two coated abrasive ends to be joined together, the
partially cured adhesive film can be further heated at relatively
low temperatures whereby on being subjected to pressure it will
flow into intimate contact with the surfaces to be joined. Thus,
one is able to form endless belts from a wide variety of coated
abrasive materials.
Inventors: |
Malloy; John F. (Waterford,
NY) |
Assignee: |
Norton Company (Worcester,
MA)
|
Family
ID: |
26710558 |
Appl.
No.: |
05/253,570 |
Filed: |
May 15, 1971 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
34105 |
May 4, 1970 |
|
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Current U.S.
Class: |
51/295; 51/297;
51/298 |
Current CPC
Class: |
C08G
18/10 (20130101); C08G 18/10 (20130101); C08G
18/8029 (20130101); C08G 18/10 (20130101); C08G
18/76 (20130101) |
Current International
Class: |
C08G
18/00 (20060101); C08G 18/10 (20060101); C08g
051/12 (); C08g 041/00 () |
Field of
Search: |
;51/293,295,297,298,299 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Arnold; Donald J.
Attorney, Agent or Firm: Hayes; Oliver W.
Parent Case Text
CROSS REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of application Ser. No.
34,105 filed May 4, 1970, and now abandoned.
Claims
What I claim is:
1. A coated abrasive having its ends joined together by dry,
heat-activatable, preformed adhesive film comprising the reaction
product of a composition comprising in admixture a hydroxyl
terminated polyurethane-polyester having a hydroxyl number of from
about 2 to about 15 and a component having available free
isocyanate groups, the available isocyanate groups in the
composition being present in the amount of from about 0.24 grams to
about 8.5 grams per 100 grams (solid) of said
polyurethane-polyester, said adhesive film being only partially
cured so that it can be subsequently tackified and softened with
application of heat in the range of from 175.degree.F to
350.degree.F for from 5 to 1 second, respectively.
2. The coated abrasive according to claim 1 wherein the isocyanate
component is triphenyl methane triisocyanate.
3. The coated abrasive according to claim 1 wherein the isocyanate
component is diphenylmethane 4,4'-diisocyanate.
4. The coated abrasive according to claim 1 wherein the isocyanate
component is an isocyanate terminated polyurethane reaction product
of trimethylol propane and toluene diisocyanate.
5. The coated abrasive according to claim 1 wherein the thickness
of the film is at least about 1.5 mils.
6. Method of joining abrasive material together comprising the
following procedural steps:
a. providing a dry, heat-activatable, preformed, at least partially
cured adhesive film comprising the reaction product of a hydroxyl
terminated polyurethane-polyester with a component having available
free isocyanate-groups;
b. preparing two free ends of coated abrasive material to be joined
together in overlapped position;
c. positioning the preformed adhesive film on the abrasive side of
one of said ends of said abrasive material;
d. heating said preformed adhesive film at a temperature of from
175.degree. to 350.degree.F for 5 to 1 second respectively, thereby
to soften and tackify the film;
e. overlapping the other free end of said abrasive material with
said one end whereby said softened, tacky, partially cured,
adhesive film is located between the ends to be joined;
f. heating said overlapped ends and adhesive film from 175.degree.F
to 350.degree.F for 30 to 5 seconds, respectively, while subjecting
the same to pressure of from 1500 to 12,000 lbs/in..sup.2, said
heat and pressure being sufficient to cause said adhesive film to
be further softened and flowed into intimate contact with the
surfaces of the ends to be joined; and
g. further curing said adhesive in a moist atmosphere at room
temperature thereby to obtain maximum joint strength.
7. Method according to claim 6 wherein said partial curing of the
adhesive film is obtained by heating the solvent free film for from
15 to 60 minutes at from about 300.degree. F. to about 250.degree.
F.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to a dried, partially cured, adhesive film,
to its method of manufacture, and its use in the joining together
of two adjacent surfaces. In particular, the invention relates to
the splicing of coated abrasive materials and, even more
particularly, to the splicing of coated abrasive materials as in
the formation of endless belts.
2. Description of the Prior Art
One method of manufacturing coated abrasive belts involves
adhesively joining together two overlapped free ends of a strip of
coated abrasive sheet material of a suitable length and width. The
demands on an adhesive used in the formation of an endless belt are
rather severe because a coated abrasive belt during use is
subjected to relatively high tensile and flexural forces. Thus, any
adhesive composition used in the formation of belt joints must be
strong and flexible as well as provide good adhesion (high peel
strength) to prevent delamination of the belt joint upon being
subjected to a severe flexing operation such as when running over a
small diameter contact roll. Moreover, the adhesive must be
resistant to heat, water, lubricants and cutting fluids encountered
in various abrading operations.
Over the years the manufacture of coated abrasive belts has
involved, by and large, the use of liquid adhesive compositions.
These have been, to a large degree, glue or other water-soluble
material. However, where water insolubility and heat resistance has
been found desirable, insoluble resinous types of adhesives have
been used. These adhesive materials include phenol-aldehyde resins,
among others, dissolved in suitable organic solvents.
One disadvantage associated with the use of a liquid adhesive
composition is that its application, in general, requires a "dwell
time" for, among other other things, the removal of solvent. The
operator must, in most instances, apply the adhesive composition,
wait for a certain period of time to pass for the solvent to
evaporate and thereby deposit the adhesive component, and for the
adhesive material to cure to some desired point. Only then are the
ends superposed preparatory to being joined together. Curing of the
adhesive material to some degree before joining is absolutely
necessary in order that an inordinate amount of time is not taken
during the press cycle. Most importantly, the adhesive material
must have sufficient cohesive strength that, on pressing, it will
not be squeezed out thus resulting in an adhesive starved joint
line and therefore a weak joint.
The "open time" or "permissible dwell time", during which the
faying surfaces can be adhesively assembled and a satisfactory bond
achieved, must also be observed by the operator. While it is
possible for the operator to coat other abrasive strips for belt
formation during the dwell time, thus setting up a situation where
belts can be somewhat continuously formed, this manner of operation
has been found somewhat confusing to an operator. Often-times the
adhesively-coated abrasive strips, for one reason or another, are
misplaced, or otherwise improperly kept account of by the operator
thus resulting in some adhesive compositions not receiving the
desirable dwell time and others exceeding it. The result in either
instance is formation of a poor belt joint.
A further disadvantage associated with the use of a liquid adhesive
composition results from the fact that different operators
invariably apply more or less of the adhesive composition than is
required for optimum results. In some instances, moreover, the
adhesive composition, to provide a sufficiently thick adhesive
layer, must be applied in multiple coats because application of a
more viscous composition is not possible.
Because of the nature of a liquid adhesive composition and its
manner of application, the quality of the joint formed often varies
in any particular coated abrasive product and even from
belt-to-belt. This lack of uniformity in the manufacture of endless
coated abrasive belts is naturally accompanied by complaints from
the users of the belts. As a result, over the years, various
adhesive compositions have been developed for use in belt
manufacture and moreover, various means have been devised to
provide better means of quality control. Nevertheless, the problem
of obtaining satisfactory belt joints with uniform characteristics
remains.
It has been suggested heretofore that preformed adhesive films can
be used rather than liquid adhesive compositions. Examplary of the
prior art showing these films are U.S. Pat. Nos. 2,060,906;
2,778,169; 2,794,726; 3,406,053; and 3,449,280. However, of the
preformed adhesive films commercially available or which have been
suggested for use, of which I am aware, none completely satisfy the
requirements for the manufacture of coated abrasive belts or do
they result in a joint with the most desired physical
characteristics.
With some preformed adhesive films suggested heretofore, the films
cohesive or adhesive qualities, inferior heat resistance, etc.,
make it unsuitable for use in a coated abrasive joint wherein it
must withstand the rigorous application to which abrasive materials
are subjected. Other preformed adhesive films of which I am aware
require an excessive curing time or too high a curing temperature
to be used at all in the manufacture of coated abrasive belts. Some
adhesive films, while suitable for the manufacture of endless belts
of certain materials, are unsuitable, because of their curing or
joining temperature, for the manufacture of coated abrasive endless
belts of other materials.
SUMMARY OF THE INVENTION
In accordance with the general aspects of my invention, I have
discovered an adhesive composition which can be provided in film
form and in which form it has a relatively low press joining
temperature thereby making it possible to use the adhesive film in
the bonding of a wide variety of coated abrasive materials.
The adhesive film used in the practice of the invention basically
comprises a dried, partially cured reaction product of a
composition comprising in admixture a hydroxyl terminated
polyurethane polyester and a component having available free
isocyanate groups. The use of such an adhesive film makes it
unnecessary during belt manufacture to allow for a dwell time
during which solvent is evaporated and cure is advanced to a degree
resulting in cohesive strength satisfactory for joining under high
pressure.
A further, and most important, advantage offered with the practice
of my invention is that coated abrasive belts of more uniform
quality and physical characteristics can be manufactured
repetitively than heretofore thus providing increased customer
satisfaction. This results from the fact that not only does an
operator need not be concerned with some minimum or maximum dwell
time but the same amount of adhesive composition is always provided
in the manufacture of belts of any particular coated abrasive
material. Thus, no room is left for varying joint properties due to
application by an operator of more or less adhesive composition
than has been determined previously to be optimally desirable.
Using a dried, partially cured, preformed adhesive film, rather
than a liquid adhesive composition, moreover, results in better
housekeeping, and less waste of adhesive composition. The dried,
adhesive film is further desirable in that in its use no obnoxious
solvent is evaporated in the belt making area thus making special
ventilation unnecessary.
Quite advantageously, and this is of considerable importance, my
invention makes it possible to substantially automate the
manufacture of coated abrasive belts. Thus, increased efficiency in
belt manufacture, as well as more uniform product, is made
possible.
BRIEF DESCRIPTION OF THE DRAWING
The invention will be better understood by referring to the drawing
in which like numerals refer to like parts in the various views and
in which:
FIG. 1 is a partial cross-sectional view showing the formation of a
joint in the manufacture of an endless coated abrasive belt;
and
FIG. 2 is a top view, in part, of a completed endless belt showing
the overlap joint formed therein.
DETAILED DESCRIPTION OF THE INVENTION
Turning now to the drawing, there is disclosed in FIG. 1 thereof,
in accordance with the invention, an endless coated abrasive belt
10. The ends 11 and 12 of coated abrasive strip 13, which are
joined together by a preformed adhesive film 14, hereinafter more
completely described, are shown out of contact with one another for
sake of clarity. However, it will be readily understood that, in a
completed belt, surfaces 15, 16 of belt ends 11, 12 will be closely
adjacent one another and secured together by means of preformed
adhesive film 14. In the finished product it will of course not be
possible to discern that the adhesive, which in the present figure
is shown in greatly exaggerated thickness to better show the
invention, was initially a preformed film.
Abrasive strip material 13, as is usual preparatory to formation of
an abrasive belt, is cut to the desired width and length from a
suitable sheet of coated abrasive material. The ends 11, 12 of the
coated abrasive strip are preferably cut at an angle, e.g., from
30.degree. to 75.degree. with respect to the lengthwise direction,
as more clearly shown in FIG. 2 of the drawing. A preferred angle
is 55.degree.. However, if desired, the ends of the abrasive strip
can be cut normal to the lengthwise direction.
In the practice of my invention, it is preferred, as shown, that
surfaces 15, 16, in accordance with usual techniques, be beveled by
abrading and skiving, respectively. This provides a narrow area
delimited adjacent the free ends of the abrasive strip for
application of the adhesive composition, makes for better adhesion,
and lesser joint thickness. In general, in skiving the upper
portion of end 12 it is preferred to remove all the maker adhesive
19, hereinafter described, from the skived area. A taper of 2-3
mils, as shown, is desired from the trailing edge of the skived
portion to the leading edge thereof. The lower surface of end 11
can be back rubbed, wire brushed, sand blasted, or the like to
provide an area matching with the skived area on end 12.
The coated abrasive sheet material used in the practice of my
invention is of conventional manufacture and forms no part of the
invention per se. In general, the abrasive material comprises a
backing member 17, and abrasive grain 18 secured to the backing
member by means of an adhesive bond or maker 19. Backing member 17
can be of any material conventionally used in the manufacture of
coated abrasive sheet material. This includes paper, cloth,
vulcanized fiber, and the like sized with various materials
depending on the end use of the coated abrasive product. The sizing
and filling materials can be starch, glue, filled or otherwise as
desired, or of a resinous material such as phenol-aldehyde.
The bonding layer or maker coat 19 can be of a resinous material
such as, e.g., phenol-aldehyde, epoxy resin, and the like. However,
quite advantageously, my invention can also be used with a glue
maker adhesive composition. This layer may have a sand size coat
thereover, if desired. Where the sand size coat is of a
heat-hardened resinous material, the maker adhesive coat can be of
either glue or resinous material.
Abrasive grains 18 can be any of those grain materials, natural or
synthetic, used in the manufacture of coated abrasive sheet
material. These include flint, emery, garnet, silicon carbide,
aluminum oxide, and zirconia-alumina grains of any size.
Adhesive film 14 used in the practice of the invention is the
dried, partially cured, reaction product of an adhesive composition
having as its essential component a two-component polyurethane
adhesive composition. Two-component polyurethane adhesive
compositions, as is deemed well known, have as the essential
components thereof an isocyanate and a poly-functional active
hydrogen-containing component. I have discovered that a
particularly suitable adhesive composition is provided for abrasive
belt manufacture wherein the active hydrogen-containing component
is a hydroxyl terminated polyurethane polyester having a hydroxyl
number of from 2 to 15.
Hydroxyl terminated polyurethane polyesters, as is well known, are,
in general, prepared by reacting a molar excess of a hydroxyl
terminated polyester with a suitable polyisocyanate. Many such
polyesters useful for reaction with polyisocyanates are known and
are commercially available. They are, in general, formed by
esterifying and polymerizing a dibasic or polybasic carboxylic
acid, or mixtures of these acids, with a complementary bi- or poly-
functional compound containing more than one alcoholic group, or
mixtures of these compounds. Suitable acids for reaction to form
polyesters, which primarily should be saturated acids, include
succinic, glutaric, adipic, pimelic, maleic, azelaic, sebacic,
diglycolic, and dimer linoleic, and mixtures of these. Examples of
polyhydric alcohols include ethylene glycol; propylene glycol;
butylene glycol; diethylene glycol; 1,5 -pentanediol; and
hexamethylene glycol. Small proportions of a polyhydric alcohol
such as glycerol, castor oil and trimethylol propane may also be
used. The reaction of these materials to form polyesters ordinarily
involves simple heating for a few hours, usually with removal of
water formed during reaction by maintaining a vacuum over the
reaction mixture. The acid and alcohol are combined in proportions
providing a substantial excess of hydroxyl groups over acid groups
and the reaction is carried to a point giving a product having
hydroxy groups, preferably terminal, with a hydroxyl number from
about 30 to about 140, preferably 50-60, an acid number 0-12, and a
molecular weight between about 2000 and 4000.
Reaction of the polyesters with the polyisocyanates involves mixing
one or more polyisocyanates with one or more polyesters and heating
the mixture until the reaction is substantially complete. The
reacted material is then cooled to solidify it and broken up for
convenience in handling. Arylene diisocyanates such as 2,4-toluene
diisocyanate; 1,5-naphthalene diisocyanate, and m-phenylene
diisocyanate are preferred because of toxicity problems with
aliphatic isocyanates but aliphatic isocyanates such as
hexamethylene diisocyanate or pentamethylene diisocyanate may be
used along with or in place of the arylene diisocyanate if proper
safety precautions are taken. The isocyanate and polyester are
combined in relative proportions of about 0.9 to about 1.4 mols of
diisocyanate per mol of polyester.
A polyurethane polyester elastomer, such as is desired in the
practice of my invention, is available commercially in solvent
solution from United Shoe Machinery Corporation. One such solution
is identified as "Bostik 7070" in their bulletin BA20, page 4.
"Bostik 7076" is comparable except that a mixture of
acetone-toluene is used as the solvent rather than ethyl acetate.
The solvent used is, of course, of no consequence and other
solvents or diluents suitable as a vehicle for the polyurethane
elastomer can be used. Merely by way of example, methyl ethyl
ketone may be used, if desired. The polyurethane polyester in
Bostik 7076 is believed to be the reaction product of toluene
diisocyanate with a hydroxyl terminated polyester of adipic acid
and butylene glycol.
The particular isocyanate component utilized in the practice of the
invention is not critical so long as it has available sufficient
free isocyanate groups to react satisfactorily with the reactive
hydrogens and thus cure the adhesive composition to the desired
extent. Any organic diisocyanate or polyisocyanate such as
triisocyanates and tetraisocyanates, or mixture of diisocyanates,
polyisocyanates, or both may be used. Merely by way of example,
toluene diisocyanate, polyphenyl polymethylene polyisocyanates such
as diphenylmethane 4,4-diisocyanate, triphenyl methane
triisocyanate, and the like may be used. Of these materials, the
latter two are the most preferred as will hereinafter be
appreciated. However, regardless of which one is used, the
particular diisocyanate or polyisocyanate used must be either
soluble in the solvent used for the polyurethane polyester or
dissolved in a solvent compatible therewith. An isocyanate material
meeting these requirements and found particularly suitable in the
practice of the invention is a product commercially available under
the trade designation Mondur CB-75 from Mobay Chemical Company.
This product is described in Urethane Coating, Second Edition,
published by Mobay and is the reaction product of trimethylol
propane and toluene diisocyanate.
As the ultimate curing of the adhesive composition used in the
manufacture of the adhesive film depends upon the number of (--NCO)
groups present in the isocyanate component, the amount of
isocyanate component required depends, of course, on the amount of
and particular hydroxyl terminated polyurethane polyester used in
the adhesive composition, as well as upon the particular isocyanate
used. In general, however, a satisfactory bond will be obtained if
the isocyanate component is provided in the adhesive composition in
sufficient quantity to provide from about 0.24 gram (--NCO) to
about 8.5 grams (--NCO) per 100 grams polyurethane polyester
solids, as above described. A preferred range is from about 0.54
gram (--NCO) to about 4.3 grams (--NCO) per 100 grams of the
above-mentioned hydroxyl terminated polyurethane polyester.
The preformed adhesive film is, in general, manufactured according
to usual film casting techniques. An amount of the two-component
polyurethane adhesive composition is cast on a so-called release
liner or carrier to result in the desired film thickness after
solvent evaporation. These materials are well known and several are
available commercially. Such a carrier or release liner may be a
polyethylene coated paper or a paper coated with a silicone resin,
polytetrafluoethylene, or the like.
The adhesive composition is, in the practice of the invention,
applied to the release liner by means of knife-on-roll or reverse
roll coating. However, other means of application are obviously
suitable. Afterwards, the wet, adhesive coated release liner is
heated for a sufficient period of time and at a suitable
temperature for the solvent to evaporate from the adhesive
composition, thus leaving a dried, tack-free adhesive film and one
that is partially cured, yet heat activatable. The film, to provide
adequate bond strength when used in a coated abrasive belt joint,
on drying, should be at least about 1.5 mils thick. Desirably, the
dried, preformed, adhesive film is from about 2.0 to about 5.0 mils
thick. A thinner film results in poor bond strength and a thicker
film makes for too thick a joint thus resulting in bumping and
chattering of the abrasive belt during use.
Heating of the layer of cast adhesive composition is preferably
accomplished in a hot air oven. Various types of these ovens are
available commercially some of which provide for a flow of air
counter-current to the direction of travel of the wet film and such
an oven is preferred. The air temperature and the time allowed for
drying will, of course, depend on the amount of solvent in the
adhesive composition cast. However the time-temperature
relationship should provide for substantially complete solvent
removal as well as for reaction of the components in and some
partial curing of the adhesive film composition. The degree of
partial curing desired may vary, depending somewhat on the specific
application for the particular film adhesive, as well as the
composition thereof. In general, however, the film adhesive should
not be cured to such an extent that, on heating in a press, e.g.,
in the formation of abrasive belts it cannot be heat activated,
i.e., merely be softened and tackified. The extent of partial
curing should, however, provide sufficient cohesive strength in the
adhesive film that it will not unduly flow on application of heat
and pressure. With partial curing such as desired in the practice
of our invention, the preformed adhesive film will, on application
of heat and pressure, flow into intimate contact with the surfaces
to be joined yet not be squeezed out from therebetween. Of
advantage, partial cures have been found satisfactory which result
in an adhesive film which can be heat activated at temperatures,
e.g., less than about 275.degree. F, above which damage could
result to a conventional coated abrasive backing member.
A desirable partial cure may be obtained in general in heating a
film, which initially may be a composition of from about 20 to
about 30 percent solids, these solids comprising from about 63 to
about 98 percent (by weight) hydroxyl terminated polyurethane and
from about 2 to about 37 percent (by weight) isocyanate, after
solvent removal for from about 15 to about 60 minutes at from about
300.degree. F. to about 250.degree. F. The adhesive film should
not, however, be cured to such an extent that it is not desirably
flowable or cannot be activated or tackified with conditions of
pressure and heat found desirable in the manufacture of coated
abrasive belt joints.
Subsequent to formation of the adhesive film, where continuously
manufactured, the adhesive film-carrier combination may then be
wound into rolls. Afterwards, or before if desired, the combination
may be slit into widths of the desired size and would into rolls of
suitable length for use. The adhesive film composition continues
curing (moisture from atmosphere, backing member, etc.) even at
room temperature. However, the rate of curing is relatively slow
and can be retarded even further by storing the adhesive film, as
hereinafter more fully described, at relatively low humidity and
temperature. Provided the adhesive film is stored in a dry
atmosphere at 5.degree. F. or less, it can be used and satisfactory
bonds achieved in belt joints even after a storage of more than 9
months. Once the adhesive film is removed from such a low
temperature and humidity controlled conditions, it must be used,
generally, in from about 8 to about 56 hours depending on
atmosphereic conditions. Thus, the adhesive film has a pot life
outside the controlled environment of about 8 hrs. at 85.degree.
F., 65% relative humidity (R.H.); however, a film of the same
composition has a pot life of about 56 hours at 75.degree. F., 25%
R.H. In order to retard curing of the adhesive film material, thus
in a sense extending the pot life thereof, the rolls of adhesive
film are sealed in plastic bags, e.g., of polyethylene, until ready
for use. The bags containing the rolls of adhesive film are then
maintained under low temperature, e.g., about 0.degree. F. and
humidity conditions - e.g. about 5% relative hmidity (R.H.) as
beforementioned.
Quite advantageously, I have found that providing a desiccant such
as DRIERITE (anhydrous calcium sulfate) in the adhesive film
package results in even better retardation of curing during
storage. This results from the fact that the adhesive film is
moisture curable; thus, removing moisture from the atmosphere in
which the film is stored retards its further curing.
When adhesive film is required for the manufacture of belt joints,
a suitable number of packages thereof is removed from the
controlled environment. Coated abrasive strips of a suitable width
and length are provided and the ends of the strips are prepared for
belt formation according to usual techniques. An appropriate length
of adhesive film-carrier combination is unwound from the roll
thereof, is applied to the skived end of the coated abrasive strip
material which previously has been positioned as usual on the
bottom bar or platen of a platen press and, is then cut off. Quite
obviously, if desired, the length of adhesive film-carrier can be
cut from the roll before application. A press found suitable in the
practice of the invention is one in which both the upper and lower
platens are capable of being heated electrically and is capable of
exerting a pressure of up to 30 tons on an object located
therebetween.
The coated abrasive strip with the adhesive film-release liner
thereon is then subjected to light pressure, e.g., about 200 - 400
lbs./in..sup.2 while being heated by the bottom bar only (e.g.
about 175.degree. - 350.degree. F.) for about 1 - 5 seconds. Thus,
the dried, preformed, partially cured adhesive film is softened and
tackified, i.e., heat activated, in preparation to forming the belt
joint. On release of the pressure and withdrawal of the upper bar,
the release liner is removed. The ends of the coated abrasive strip
are then overlapped as shown in FIG. 1, and these overlapped ends
are then subjected to heat and pressure as above-mentioned. After
the heat-activation operation, the coated abrasive strip with the
overlapped ends is then positioned in a similar press and the
joining of the two ends is completed. In the practice of the
invention, two presses are desirably used. This permits a smoother
operation in that one press can be used for activation of the
adhesive film while the other can be used for joint formation.
However, quite obviously a single press, if desired, can be used to
accomplish both operations.
During the press joining cycle, i.e., the joining of the
superposed, overlapped coated abrasive ends, both bars are heated.
Thus, the adhesive film is subjected to pressure while
simultaneously being heated from both sides. In this way the
adhesive film is caused to flow into intimate contact with the
surfaces to be joined. The joint resulting permits immediate
handling of the belt formed. Joint strength is such that on removal
of the belt from the press it can be further processed, e.g.,
cutting to lesser width, if desired, or packaged, immediately on
cooling. However, if desired, joining can be accomplished at room
temperature but this is generally deemed undesirable and
impractical because the time required for an adequate joint to be
formed which permits immediate handling is excessive.
The pressure used in joining may be varied as desired, e.g., from
about 1,500 lbs./in..sup.2 to about 12,000 lbs./in..sup.2. In
general, the time and temperature required to effect optimum joint
strength whereby to obtain suitable handling strength of the belt
for any particular adhesive composition will, of course, vary with
each particular adhesive composition. Somewhat better joints have
been made by using elevated temperatures within the range from
about 175.degree. F. to about 350.degree. F., a preferred
temperature being about 240.degree. F. to about 335.degree. F., for
from about 5 seconds to about 30 seconds.
Ultimate or maximum joint strength depends somewhat on atmospheric
conditions; however, this is obtained substantially within 24 to 48
hours of belt manufacture at 70.degree. F., 50% R.H. On the other
hand, maximum joint strength is obtained substantially in about 8
to 16 hours, at 85.degree. F., 65% R.H. On curing, the primary
reaction to obtain optimum strength results from reaction of the
excess isocyanate in the adhesive composition with the polyurethane
formed therein between the hydroxyl terminated
polyurethane-polyester and with atmospheric moisture. The joint
strength, on the average, obtained during press joining is at least
about 10% or more of that of the ultimate joint strength.
The following examples, which are given for purposes of
illustration only and are not intended to be limiting of the
inventive concept, will more clearly illustrate the preferred
embodiments of the invention.
EXAMPLE 1
An adhesive composition was prepared by blending together in a 55
gallon drum the components shown below in suitable amounts to
provide the indicated proportions.
______________________________________ Percent By Weight Solids
Based On Components Total Weight Solids
______________________________________ BOSTIK 7076 77.0 (21% solids
in acetone-toluene solvent) MONDUR CB-75 23.0 (75% solids in ethyl
acetate) ______________________________________
Mixing was conducted at room temperature over a period of about 15
minutes. Afterwards the adhesive composition, in which the
components are uniformly dispersed, was deposited according to
usual roll coating techniques onto a silicone release paper. Such a
paper (48 inches wide) is commercially available under the trade
designation Silicone Release Liner No. 662 from Weyerhauser
Company.
The wet coated silicon release paper or carrier was then festooned
and passed through a conventional hot air oven at 17 feet per
minute. Therein the adhesive layer was dried and partially cured by
means of a counter-current flow of air. This was accomplished by
heating the adhesive layer for 15 minutes at 100.degree. F.
followed by 30 minutes at 250.degree. F. An adhesive film having a
thickness of about 3 mils resulted.
The adhesive film was then slit by usual techniques to provide a
film-carrier combination three-eighths inches wide. Afterwards,
this combination was wound into rolls of suitable length (300 feet)
for use in the manufacture of coated abrasive belts. Some of the
rolls were packaged, as before described and stored for subsequent
use.
EXAMPLE 2
A suitable strip of 80X RESINALL METALITE cloth coated abrasive
material (6 inches .times. 60 inches) was prepared for formation of
an endless belt. The abrasive surface of one end of the abrasive
strip was skived by usual techniques thereby removing the abrasive
material and the bonding layer and leaving the upper portion of the
backing material exposed. The skived surface made an angle of about
55.degree. with respect to the lengthwise direction of the strip.
To the skived surface (3/8 .times. 7.5 inches), which was slightly
tapered at an angle of about 5.degree. to the horizontal, was then
applied the film adhesive-carrier combination manufactured in
Example 1. This was accomplished by providing a strip of adhesive
film-carrier matching the skived surface and placing the dried
adhesive film directly against this surface, (the coated abrasive
strip having been positioned previously on the bottom bar of a
conventional platen press.) The release liner was left in position
on the adhesive film.
The upper bar of the press was brought down into contact with the
release liner, thus providing a pressure of about 387 psi on the
adhesive film-carrier and skived belt assembly. The assembly was
maintained under this pressure for a period of about 3 seconds
while being heated solely by the bottom bar having a surface
temperature of about 275.degree. F. This permitted the adhesive
film to soften and to become activated in preparation for the
subsequent bonding step.
Pressure on the assembly was released and the upper bar or platen
was withdrawn from contact with the release liner. The release
liner was then removed from the softened, activated adhesive film
and the matching, slightly tapered, roughened, bottom surface of
the other end of the coated abrasive strip was then positioned in
contact with the upper surface of the adhesive film.
The overlapped coated abrasive strip was then positioned in the
press and pressed while heated only by the lower bar. A pressure of
387 lbs./in..sup.2 was maintained for 3 seconds (bar temperature
275.degree. F.) after which it was released and the upper bar was
slightly withdrawn. The coated abrasive strip was then positioned
in a similar press and the upper bar therein was operated so as to
press against the overlapped portions of the coated abrasive strip
with a pressure of 6500 lbs./in..sup.2. This pressure was
maintained while the joint was heated by both bars for about 20
seconds (bar temperatures 240.degree. F.) after which the pressure
was released and the thus produced abrasive belt was removed from
the press.
On visual examination, the abrasive belt was observed to have a
joint thickness not substantially greater than the thickness of the
coated abrasive material per se. Moreover, this belt joint was
observed to be much neater looking than those generally
manufactured using a liquid adhesive composition there being no
excess adhesive composition on the abrasive or backside of the belt
joint.
The coated abrasive belt thus produced was immediately tested in
accordance with ASTM D903-49. However, a specimen size of 1 .times.
5 inches was used at a separation rate of 5 inches per minute. This
had been conditioned for 24 hours prior to testing at 70.degree.
F., 50% R.H. The joint was found to have an adhesion peel strength
value in excess of 15 pounds/in. of joint width.
On subjecting a belt thus manufactured to severe and continuous
flexing in the immediate area of the belt joint on a multi-head
oscillating flex fatigue tester, the belt joint was found to exceed
4000 flexes before failure occurred. This test is peculiarly
directed at producing delamination failure in the adhesive joint. A
belt joint which will withstand 2,400 flexes without failing has
been considered good in the past.
These tests, it is believed, indicate the excellence of a joint in
coated abrasive material manufactured in accordance with my
invention. With such a belt joint, the life of an abrasive belt is
extended accordingly because more prolonged periods of operation
are attained without joint failure. Thus, more economical use can
be made of belts manufactured in accordance with the invention in
that more of the abrasive surface can be used.
EXAMPLE 3
Using the same adhesive composition as disclosed in Example 1,
sufficient composition was provided on companion release liners to
result, on drying and partial curing at the same conditions
disclosed in Example 1, in adhesive films having a thickness of 1
mil and 3 mil, respectively.
These adhesive films were used in manufacturing endless belts from
120X RESINALL METALITE abrasive cloth. The manner of manufacture of
these belts was that disclosed in Example 2. On evaluation, as
before, for flex fatigue, the belt manufactured using the 1 mil
adhesive film failed after only 770 flexes. However, the belt
manufactured using the 3 mil thick adhesive film exceeded more than
4000 flexes before delaminating.
EXAMPLE 4
The adhesive composition of Example 1 was changed to provide an
increased amount of the isocyanate component therein. Analysis of
the composition showed there to be 8.5 grams (--NCO) per 100 grams
solid polyurethane-polyester component. This adhesive composition
was coated on a release liner as in Example 1 to provide an
adhesive film 3 mils thick.
The thus formed adhesive film was then used in the manufacture of
an endless belt as in Example 2.
On evaluation for flex fatigue, as before, the belt failed after
only 740 flexes. Increasing the isocyanate component in the
adhesive composition makes the joint excessively brittle. Such an
adhesive film is unsatisfactory for use in the manufacture of
abrasive belts.
EXAMPLE 5
The adhesive composition was varied in the amount of isocyanate
component present to determine the effect thereof on joint
characteristics.
__________________________________________________________________________
COMPONENT % BY WEIGHT SOLIDS/TOTAL SOLIDS
__________________________________________________________________________
BOSTIK 7076 99.0 98.0 96.5 92.2 86.0 75.3 63.5 MONDUR CB75 1.0 2.0
3.5 7.8 14.0 24.7 36.5 (-NCO/100 g 0.15 0.24 0.54 1.05 2.15 4.3 7.5
Polyurethane- Polyester Solids) No. Flexes 600 4000 5000+ 5000+
5000+ 4000+ 3200+ To Failure
__________________________________________________________________________
Thus it is seen from the above tabulated data and the results from
Example 4, that belt joints manufactured using a preformed film in
which the adhesive composition contains more than 8.5 grams or less
than 0.24 grams (--NCO) per 100 grams solid polyurethane-polyester
will result in an unsatisfactory coated abrasive belt.
EXAMPLE 6
Endless abrasive belts were manufactured as in Example 2 using the
adhesive film of Example 1 except that belt joining conditions were
varied as indicated below:
a. Joining temperatures 335.degree. F.
A thinner joint resulted, and on evaluating flex characteristics,
the joint was still intact after more than 3000 flexes.
b. Joining temperature 200.degree. F.
The joint, on evaluation, was still intact after more than 3000
flexes.
c. Joining temperature 175.degree. F.
Joint failed after only 1740 flexes.
d. Joining temperature 150.degree. F.
On evaluation for flex characteristics, the joint thus produced
failed in less than 400 flexes.
EXAMPLE 7
Adhesive films manufactured in accordance with Example 1, after
storage in polyethylene bags containing DRIERITE for 9 months at
0.degree. F., 5% R.H., were used in the manufacture of endless
belts as disclosed in Example 2. These belts, on evaluation for
flexural characteristics, were found to exceed 3600 flexes before
delamination.
EXAMPLE 8
The adhesive film composition of Example 1 was partially cured at
various conditions to determine the effect thereof on formation of
belt joints. A film thickness of 3.0 mils was used. Belt joints
were manufactured in accordance with Example 2 except that 120X
RESINALL METALITE abrasive cloth was used. Time and temperature
conditions for partial curing was as indicated below.
______________________________________ PARTIAL CURING TIME, TEMP
FLEXES TO min. .degree.F FAILURE
______________________________________ 5 250 780 15 250 1200 30 250
3000+ 300 250 3000+ 360 250 *
______________________________________ *film had cured to such an
extent it could not be tackified for joining.
Partial curing was subsequent to a 30 minute air dry at 100.degree.
F. for evaporation of solvent.
EXAMPLE 9
An endless abrasive belt was manufactured according to the
procedure disclosed in Example 2 except that 100J RESINIZED
METALITE abrasive cloth was used. This abrasive material is
manufactured using a glue maker coat and a phenolic resin size
coat. On evaluation for flex characteristics, the joint withstood
more than 3000 flexes before failure. Thus, it is seen that by my
invention an adhesive film is provided suitable for use in the
manufacture of belts from coated abrasive material other than that
containing heat resistant resinous maker adhesives.
EXAMPLE 10
An adhesive composition was prepared of the following
formulation:
PERCENT BY WEIGHT SOLIDS BASED ON COMPONENTS TOTAL WEIGHT SOLIDS
______________________________________ BOSTIK 7076 89.5 MONDUR TM*
10.5 ______________________________________ (Mondur TM is available
from Mobay Chemical Company and is their trade designation for
triphenyl methane triisocyanate. The above amount provide 0.84
grams -NCO per 100 grams Bostik 7076 solids.
Two wet films (30 mil) were cast onto release paper as previously
set forth in Example 1. After air drying for 15 minutes, one film
was heated for 10 minutes at 250.degree. F., while the other was
heated for 20 minutes.
Abrasive belt joints were formed with the partially cured adhesive
films (3.0 mil thick) according to the manner set forth in Example
2 except that 120X RESINALL METALITE abrasive cloth was used.
On flex fatigue testing as before, after conditioning for 24 hours
at 70.degree. F., 50% R.H., the joint in which the film had been
partially cured for 10 minutes, failed only after being subjected
to 8460 flexes. Quite unexpectedly, the other joint (20 minutes
partial cure) exceeded 24,000 flexes before failure.
EXAMPLE 11
An adhesive composition was prepared by admixing the components
indicated below:
PERCENT BY WEIGHT SOLIDS BASED ON COMPONENT TOTAL WEIGHT SOLIDS
______________________________________ BOSTIK 7076 98.0 MONDUR MR*
2.0 ______________________________________ *MONDUR MR is
commercially available from Mobay Chemical Company and is their
trade designation for diphenylmethane 4,4-diisocyanate (methylene
bis(4 phenyl isocyanate). The amount -NCO groups made available is
3.0 grams.
A film was cast in the manner disclosed in Example 10 except that
after air drying the film was partially cured by heating for 45
minutes at 250.degree. F.
On evaluating an abrasive belt incorporating this film adhesive,
such as disclosed in the preceding example, failure was found to
occur only after more than 4500 flexes.
EXAMPLE 12
Over a period of several months, the performance of coated abrasive
belts made according to the invention herein, i.e., using a
partially cured, preformed adhesive film, was compared with a
similar number of belts from manufacturing using a similar but
liquid adhesive composition. Although substantially no belts
manufactured according to the invention failed because of premature
joint failure, a very high percentage of belts failed using the
liquid adhesive composition. These failures were determined to have
occurred because of a variety of reasons. These include overcuring
the adhesive composition before assembling the two belt ends
together, application of an insufficient amount of adhesive to the
coated abrasive end, and starvation of the bond line. The latter
defect results because of the adhesive composition squeezing out
from between the superposed ends during pressing.
Although the preformed adhesive films of my invention are
particularly useful in the manufacture of coated abrasive belts,
they obviously are not so limited. They can also be used in the
laminating together of various similar or dissimilar materials,
e.g., metals, such as aluminum and plastic lamina of various types,
e.g., polyester films, as well as wood, cloth, and paper
lamina.
As many different embodiments of my invention will appear to those
skilled in the art of adhesive bonding, it is to be understood that
the specific embodiments of the invention, as presented herein, are
intended by way of illustration only and not limiting on the
invention, but that the limitations thereon are to be determined
only from the appended claims.
* * * * *