U.S. patent number 3,871,982 [Application Number 05/378,079] was granted by the patent office on 1975-03-18 for apparatus for treatment of metal strip with a liquid.
This patent grant is currently assigned to Kalle Aktiengesellschaft. Invention is credited to Walter Idstein.
United States Patent |
3,871,982 |
Idstein |
March 18, 1975 |
Apparatus for treatment of metal strip with a liquid
Abstract
This invention relates to an apparatus for the treatment of
metal strip with a liquid, comprising, at least one tank provided
with an inlet and an outlet for the strip, which inlet and outlet
are below the level of the liquid surface in operation, which tank
comprises at least one treatment chamber through which the strip is
adapted to pass, a reserve chamber, means for transporting liquid
from the reserve chamber to the treatment chamber, and two bell
chamber means, one close to the inlet and the other close to the
outlet, each bell chamber means having an overflow means for liquid
to the reserve chamber and each bell chamber means being so
constructed that, in operation, the space above the liquid surface
is isolated from the ambient atmosphere and is in communication
with pressure-reducing means. The invention also includes a novel
process for the treatment of metal strip.
Inventors: |
Idstein; Walter
(Oestrich/Rhine, DT) |
Assignee: |
Kalle Aktiengesellschaft
(Wiesbaden-Biebrich, DT)
|
Family
ID: |
5850544 |
Appl.
No.: |
05/378,079 |
Filed: |
July 11, 1973 |
Foreign Application Priority Data
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Jul 13, 1972 [DT] |
|
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2234424 |
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Current U.S.
Class: |
204/207; 134/64R;
134/9; 205/139 |
Current CPC
Class: |
C25D
7/0614 (20130101); C25D 11/005 (20130101); C23G
3/021 (20130101); C25D 11/04 (20130101) |
Current International
Class: |
C25D
11/04 (20060101); C25D 7/06 (20060101); C23G
3/02 (20060101); B01k 003/00 (); B08b 003/00 ();
C23b 005/68 () |
Field of
Search: |
;204/206,207,28
;134/9,15,64,122,114 |
Foreign Patent Documents
Primary Examiner: Mack; John H.
Assistant Examiner: Lange; Wayne A.
Attorney, Agent or Firm: Bryan; James E.
Claims
What is claimed is:
1. An apparatus for the treatment of metal strip with a liquid,
comprising, at least one tank provided with an inlet and an outlet
for the strip, which inlet and outlet are below the level of the
liquid surface in operation, which tank comprises
at least one treatment chamber through which the strip is adapted
to pass,
a reserve chamber,
means for transporting liquid from the reserve chamber to the
treatment chamber, and
two bell chamber means, one close to the inlet and the other close
to the outlet, each bell chamber means having an overflow means for
liquid to the reserve chamber and each bell chamber means being so
constructed that, in operation, the space above the liquid surface
is isolated from the ambient atmosphere and is in communication
with pressure-reducing means.
2. An apparatus as claimed in claim 1 including at least one
electrode.
3. An apparatus as claimed in claim 2 wherein the electrode is
arranged above the path of travel of the strip.
4. An apparatus as claimed in claim 3 including means for ensuring
a rapid and uniform flow of liquid between the electrode and the
path of the travel of the strip.
5. An apparatus as claimed in claim 4 wherein the inner wall of at
least one of the bell chamber means is joined to an electrode, and
the only means of communication between the treatment chamber and
the bell chamber means is by gap means between the said electrode
and the path of travel of the strip.
6. An apparatus as claimed in claim 5 wherein the inner wall of
each bell chamber is joined to an electrode.
7. An apparatus as claimed in claim 6 where the treatment chamber
is divided into two compartments by vertical wall means.
8. An apparatus as claimed in claim 1 wherein the reserve chamber
is situated below the treatment chamber.
9. An apparatus as claimed in claim 1 wherein the inlet and outlet
are at substantially the same level.
Description
This invention relates to a process and apparatus for the treatment
of metal strip with a liquid, in particular electrochemical
treatment.
Electrochemical treatment of metals may be carried out in order to
erode the metal and thereby modify the surface, in particular to
roughen it; the treatment also may be carried out in order to
product an oxide layer or electrochemically to remove a metallic
layer. A chemical or physical treatment of the surface with a
liquid is effected, e.g. in the case of etching or pickling and
degreasing.
If the metal being treated is in the form of a continuous element,
e.g. a wire or strip, the treatment is preferably carried out by
continuously conveying the shaped article through the treatment
bath.
It has been proposed, for example in German Offenlegungschift No.
1,621,115, to convey an aluminum strip successively through a
series of various electrochemical treatment baths in which the
strip is first electrolytically roughened and then anodically
oxidized. The strip is conveyed by means of guide rollers.
French Patent No. 1,424,643, discloses a device for the anodic
treatment of aluminum strip in which the strip passes horizontally
through the treatment bath without the use of guide rollers, and is
conveyed through inlet and outlet apertures in each of the side
walls of the bath container, these apertures being fitted with
sealing means to prevent the escape of liquid. The bath liquid is
circulated by means of a pump in such a manner that very turbulent
flow is maintained between the strip and the electrode. This
guarantees a rapid exchange of electrolyte at the surface of the
strip and a rapid dissipation of heat. Under these conditons, it is
possible to operate at high current densities and thus at high
throughput rates of the strip. The apparatus has the advantage that
guide rollers and their supports, which are susceptible to
corrosion, are not required.
A disadvantage of this apparatus resides in the use of rubber
sealing elements which have an abrasive effect at the points where
the strip enters and leaves the bath. This easily can lead to
scratching of the surface of the strip, particularly when it has
been electrochemically treated. Furthermore, the method of
circulating the electrolyte described in this patent does not
guarantee an optimum mixing of the entire bath liquid, nor an
absolutely uniform flow over the entire width of the strip to be
treated. Consequently, flow patterns may appear on the treated
surface. Furthermore, the degassing of the electrolyte, i.e. the
removal of the hydrogen evolved in the case of most electrochemical
processes, is difficult in this apparatus.
In the apparatus according to the German Offenlegungsschrift No.
1,521,068, which describes a device for the electrochemical
treatment of continuous metal strips, no sealing elements are
needed; furthermore a better mixing of the electrolyte in the bath
is ensured. In this case the strip is conveyed horizontally through
an electrolyte trough which at its ends contains weirs over which
the electrolyte flows. The inflow of the electrolyte is through a
slot in the bottom of the trough which extends over the entire
width of the same. The strip is here conveyed closely below the
surface of the liquid (about 3 to 6 mm below). In this apparatus
the main problem is always to keep the strip uniformly covered with
liquid, since the quantity of liquid flowing over the weirs cannot
be directly controlled and the level of the weirs is of necessity
below the path of the strip. Since the quantity of liquid above the
strip can be maintained or supplemented only by the lateral flow of
electrolyte around the strip, the flow of the electrolyte between
the strip and the trough bottom acting as a counterelectrode always
has a longitudinal and a transverse component in a changing
proportion. This may result in flow patterns forming on the treated
surface. It is almost impossible with the supply slot used here,
which is in the bottom of the trough and is made from a relatively
narrow tube by means of extension, to achieve in practice a uniform
distribution of flow rate over the width of the strip.
The present invention provides apparatus for treatment of metal
strip with a liquid, comprising at least one tank provided with an
inlet and an outlet for the strip, which inlet and outlet are at a
level of levels below the level of the liquid surface in operation,
which tank comprises
one or more treatment chambers through which the strip may be
passed,
a reserve chamber,
means for transporting liquid from the reserve chamber to the
treatment chamber(s), and
two bell chambers, one close to the inlet and the other close to
the outlet, each bell chamber having an overflow device for liquid
to the reserve chamber and each chamber being so constructed that,
in operation, the space above the liquid surface is isolated from
the ambient atmosphere and is in communication with
pressure-reducing means.
The reserve chamber is preferably situated below the treatment
chamber(s).
In the apparatus of the invention, neither guide rollers nor
abrasive seals are required and a constant covering of liquid over
the strip in the treatment bath is ensured. When the apparatus is
used for electrochemical treatment, for which purpose it is
primarily intended, a rapid and uniform flow of electrolyte between
the strip and counter-electrode is achieved and, if necessary,
effective degassing of the liquid may be effected.
In accordance with the invention, a process is furthermore proposed
for the treatment of metal strip with a liquid wherein the strip is
conveyed through a liquid contained in a treatment chamber having
an inlet and an outlet for the strip below the surface of the
liquid, wherein flow of the liquid out of the inlet and outlet is
hindered by a reduced pressure above the surface of the liquid.
The inlet and outlet for the metal strip are preferably disposed at
the same level so that the metal strip can be conveyed
substantially horizontally through the liquid. The apertures
preferably are slots in the outer walls of the bell chambers of
such width and length that the strip can be satisfactorily conveyed
through them contact-free. If only one side of the strip is to be
treated, it is advantageously conveyed at the smallest possible
distance from the bottom of the treatment tank. Air is continuously
drawn out of the gas space of the bell chamber. In this manner a
diminished pressure is produced in the gas space of the bell
chamber which hinders flow of the bath liquid out of the inlet and
outlet. As a result of the difference in pressure between the bell
chamber and the main liquid treatment chamber, treatment liquid
flows out of the latter into the bell chamber and out of this
through the overflow into reserve chamber. The liquid in the main
liquid chamber may be supplemented from the reserve container by
return pumps.
The process and apparatus are primarily intended and particularly
suitable for electrochemical treatment, in which an electrolyte is
used as the treatment liquid, and in which there is at least one
electrode, preferably arranged in the electrolyte above the path of
travel of the metal strip. In this case, it is particularly
important to produce in the gap between the electrode and the metal
strip the most rapid and uniform possible flow of electrolyte.
The apparatus according to the invention also may be used for other
continuous treatments of metal strip with liquids, wherein the
strip must be conveyed friction-free through the liquid bath, and a
rapid flow of liquid on the surface of the strip must be
maintained. Treatments of this type are, for example, degreasing,
pickling, descaling, and sealing of, for example, anodized
aluminum.
The apparatus is described below with reference to its primary
intended application, continuous electrochemical treatment.
Advantageously, the apparatus according to the invention is so
constructed that at least one of the bell chambers is joined to or
integral with an electrode on the wall facing the inside of the
treatment tank, and that this liquid content is joined to that of
the remaining tank only by the gap between the electrode and the
transport path of the metal strip. Preferably, both bell chambers
are joined to or integral with an electrode in this manner.
This construction guarantees that the flowing of the electrolyte
liquid from the main liquid chamber into the bell-shaped chamber is
effected exclusively through the space between the electrode and
the path of travel of the strip, and that the liquid flow is
conveyed over the entire width of this space parallel to the path
of travel of the strip and at practically uniform strength.
In the apparatus according to the invention metal strip may undergo
various different electrochemical treatments. A strip, for example,
may be cleaned, descaled, roughened or the like on its surface by
either direct or alternating current treatment. It is furthermore
possible to carry out an anodic oxidation or to galvanize the
strip. The treatment tank may be divided in the middle, in a manner
known per se, by a vertical intermediate wall arranged
perpendicular to the direction of movement of the strip and ending
close above the strip. An electrode is then provided in each
section of the treatment tank, and both electrodes may be joined to
the poles of a current source. Here the current flows from one part
to the other part of the bath substantially through the strip
acting as neutral.
This type of circuit is chiefly used in alternating current
treatment, but also may be used for direct current treatment. In
this case the strip acts in one half of the treatment bath as an
anode, and in the other half as a cathode.
The process and apparatus of the invention make it possible to work
with a very high current density which may be - depending on the
type of treatment - between approximately 2 and 150 A/dm.sup.2. In
the case of electrochemical etching it is preferable to work in the
range of approximately 25 to 120 A/dm.sup.2. Treatment times of
approximetaly 10 seconds to 2 minutes are generally achieved
here.
The rate of flow of the electrolyte liquid in the gap between the
strip and the electrode is adjusted to the value adequate for the
desired current density. Advantageously, as described in French
Patent No. 1,424,643, the rate of flow should be such that with the
given values, Reynolds numbers (Re) above approximately 2500 are
yielded. The regulation of the rate of flow may be effected by
alteration of the capacity of the pump means which pumps the
electrolyte liquid from the reserve chamber back into the treatment
chamber, and if necessary by alteration of the suction capacity in
the bell chamber. Furthermore, the rate of flow may be altered by
changing the width of the gap between the strip and the electrode.
The width of the gap is normally in the order of approxmately 1 to
5 cm, but may be tapered at the junctions to the bell chamber to a
fraction of this value.
The apparatus according to the invention is primarily intended for,
and especially suitable for, essentially one-sided electrochemical
treatment. In principle, a two-sided treatment is possible in which
further electrodes are inserted in the bottom of the treatment tank
and the strip is conveyed through the bath at a correspoding
distance from the bottom of the tank. In the particularly preferred
process, the strip is generally conveyed at so small a distance
from the bottom that it just does not touch it. In this method of
operation, the rear side of the strip is practically unchanged
apart from narrow marginal zones. The strip also, however, may lie
on the bottom of the tank without great disadvantage.
Depending on the suction capacity, greater or smaller quantities of
air may be drawn through the electrolyte liquid into the bell
chambers at the ends of the apparatus. In conjunction with the
diminished pressure prevailing in these chambers, the air bubbling
through produces an effective degassing of the electrolyte liquid,
i.e., a substantial removal of the hydrogen formed when the liquid
passes through the gap between the strip and the electrode. The
degassed electrolyte liquid collects in the reverse container and
is cooled there or in another suitable point in its circuit.
Furthermore, it may be directed through a filter or sieve before
being pumped back into the treatment tank in order to free it from
dispersed impurities. Renewal of the electrolyte liquid may be
effected by portion-by-portion removal of the spent electrolytes
and addition of the corresonding quantity of fresh electrolytes in
the reserve container.
The apparatus according to the invention advantageously may be
composed of several of the above-described basic units comprising a
treatment chamber and two bell chambers. Between these basic units,
washing stations are advantageously arranged for freeing the strip
from the liquid, from a treatment station, still adhering to it.
Also, chemical etching or pickling steps may be arranged before,
after, or between the electrochemical treatment stations. An
example of the combination of several electrochemical treatment
steps in a continuous plant is the electrochemical roughening and
subsequent anodic oxidation of a strip of aluminum. Etching and
galvanizing treatments of aluminum, copper, steel or other metal
strips also may be carried out in several successive stations using
the apparatus according to the invention.
The invention will be further illustrated by way of example only,
with reference to the accompanying drawings, in which:
FIG. 1 is a longitudinal cross-section through a basic unit of
apparatus according to the invention, and
FIGS. 2 and 3 are simplified longitudinal cross-sections through
possible combinations of two basic units according to FIG. 1.
Referring now to FIG. 1, a treatment tank 1 has a non-conductive
base 2 over which the metal strip 3 to be treated is conveyed. At
the ends of the tank 1 there are the bell chambers 4' and 4", which
have their outer walls 5' and 5" the inlet and outlet apertures 6'
and 6" for the strip 3. Inner walls 7' and 7" of the bell chambers
4' and 4" are joined at their lower ends to the electrodes 8' and
8". Gas discharge pipes 9' and 9" lead out of the gas space of the
chambers 4' and 4", which discharge pipes are connected with a
suction pump 10.
In the liquid space of the chambers 4' and 4" there are overflow
pipes 11' and 11" which terminate in a reverse chamber 12 disposed
below the tank 1 and which, viewed in the plane of the drawing,
pass in front of or behind the strip 3.
In the reserve container 12, the electrolyte liquid is maintained
at the desired temperature by heat exchangers 13, by means of which
the heat produced in the electrochemical treatment is normally
drawn off. From the reserve container 12, a conduit 14 leads back
via a pump 15 to the central part of the tank 1. Two discharge
apertures 14' and 14" of the conduit 14 are disposed above the
electrodes 8' and 8" near the walls 7' and 7". By means of this
arrangement, the rough turbulence of the electrolyte liquid pumped
back is calmed before the liquid flows into gap 16' or 16" between
the electrode and the strip.
The reserve containers 12 is provided simultaneously as a safety
tank and a storage tank for the electrolyte liquid cntained in the
tank 1. It contains sealable slots 17' and 17" for the strip 3 at
the corresponding positions in its front and rear walls. When
starting or stopping the treatment plant, or if there is a
breakdown in the suction pump 10 or any other distrubances in
operation, the slots 17' and 17" are closed so that none of the
electrolyte liquid can escape from the container 12 to the
outside.
The electrodes 8' and 8" are connected to the poles of an A.C.
source. In the middle of the tank 1 there is a non-conductive
separating wall 18 which ends closely above the strip 3 and divides
the tank 1 into two essentially symmetrical halves. The flow of
current is therefore from the electrode 8' via the gap 16' to the
strip 3 and from there into the right-hand half via the gap 16" to
the electrode 8". In this arrangement, the flow of current from the
electrode 8' through the electrolytes in the gap between the wall
18 and the strip 3 to the electrode 8" is practically
negligible.
In case small quantities of liquid escape out of the apertures 6'
and 6" on to the strip during operation of the apparatus, in spite
of the diminished pressure in the bell chamber, air nozzles 19' and
19" are provided which remove the liquid from the strip and cause
it to flow back into the reserve container 12.
It is also possible to connect a separate power supply to the strip
itself. In this case, a roller 20 is provided which is in
conductive contact with the metal strip, one pole of the current
source being applied to the roller 20 and the other pole to the
electrodes. It is also possible here to use one electrode only; the
dividing wall 18 is then also dispensable.
FIGS. 2 and 3 illustrate, in simplified form, two possible
arrangements of two devices according to FIG. 1 (basic units) for
carrying out various electrochemical treatment steps on a
strip.
In FIG. 2, the strip 3 runs successively through two basic units A
and B. Before, after and between the basic units A and B there are
normally degreasing, pickling and washing stations which for the
purpose of clarity have been omitted. In the two basic units the
strip is inserted as the neutral between the electrodes 8' and 8",
in which in the basic unit A it is inserted against the first
electrode 8' as an anode and against the electrode 8" as a cathode.
In the basic unit B the series is reversed. An A.C. source may also
be supplied in the basic unit A, and in the basic unit B the strip
3 can be connected to the anode and two electrodes to the cathode
of a D.C. source.
FIG. 3 shows the possibility of a commutation. Two independent D.C.
sources U.sub.1 and U.sub.2 are used. The voltage U.sub.1 may have
its poles reversed by shifting the change-over switch S. In the
solid line representation of the switch S, the strip 3 rests
against the cathode and all electrodes against the anode. If S is
in the position shown by the dotted line, the electrodes 8" are
negative and the electrodes 8' positive while the strip acts as the
neutral.
Obviously many other variations are possible.
It will be obvious to those skilled in the art that many
modifications may be made within the scope of the present invention
without departing from the spirit thereof, and the invention
includes all such modifications.
* * * * *