U.S. patent number 3,871,952 [Application Number 05/348,596] was granted by the patent office on 1975-03-18 for manufacture of non-woven fibrous material from a foamed furnish.
This patent grant is currently assigned to Wiggins Teape Research & Development Limited. Invention is credited to Neil George Douglas Robertson.
United States Patent |
3,871,952 |
Robertson |
March 18, 1975 |
Manufacture of non-woven fibrous material from a foamed furnish
Abstract
Non-woven fibrous material is manufactured from a foamed fibre
dispersion fed to a foraminous support and the invention resides in
forming the foamed fibre dispersion by applying a vacuum to the
underside of the support to recover a major part of the liquid from
the dispersion on the support, delivering the recovered liquid to a
mixer and mixing the recovered liquid in the mixer with fibres, a
air, and a surface active agent to obtain a mixture thereof which
is fed to a foaming device in which the foamed fibre dispersion is
formed for feeding to the support.
Inventors: |
Robertson; Neil George Douglas
(Marlow, EN) |
Assignee: |
Wiggins Teape Research &
Development Limited (London, EN)
|
Family
ID: |
26251228 |
Appl.
No.: |
05/348,596 |
Filed: |
April 6, 1973 |
Foreign Application Priority Data
|
|
|
|
|
Apr 7, 1972 [GB] |
|
|
16210/72 |
Mar 30, 1973 [GB] |
|
|
15344/73 |
|
Current U.S.
Class: |
162/101; 162/190;
162/202; 162/264; 162/289 |
Current CPC
Class: |
D21F
11/002 (20130101) |
Current International
Class: |
D21F
11/00 (20060101); D21d 003/00 () |
Field of
Search: |
;162/101,202,289,336,343
;261/DIG.26 ;252/359E ;425/4 ;239/343 ;138/145,146 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Bashore; S. Leon
Assistant Examiner: Chin; Peter
Attorney, Agent or Firm: Burns, Doane, Swecker &
Mathis
Claims
I claim:
1. A process for manufacturing a non-woven fibrous material from a
foamed fiber dispersion fed to a foraminous support from a foaming
device wherein the amount of surface active agent required is
reduced, the process comprising:
establishing an air/water/fibers/surface active agent mixture
provided by a mixer;
delivering said mixture to a closed foaming device and effecting
foaming thereof by the creation of turbulence without the use of
moving mechanical means to establish said foamed fiber
dispersion;
feeding said foamed fiber dispersion to said foraminous
support;
recovering, by vacuum draining through vacuum box means, a major
part of the liquid, generally in a foamed condition, from said
foamed fiber dispersion on said foraminous support;
recirculating said liquid so recovered generally in a foamed
condition directly from said vacuum box means to said mixer;
introducing into said mixer, together with said recirculated
liquid, fibers, water and metered quantities of air and make-up
surface active agent;
directing the contents of said mixer to said foaming device;
and
repeating said feeding, recovering, recirculating, introducing and
directing steps.
2. The method according to claim 1 including the step of dispersing
clumps of fibers following introduction of metered quantities of
air and surface active agent and prior to passage to the mixer.
3. A closed circuit system for manufacturing non-woven fibrous
material from a foamed fiber dispersion wherein the amount of
surface active agent required is reduced, the system
comprising:
a mixer for establishing an air/water/fibers/surface active agent
mixture;
a closed foaming device, downstream of said mixer, for effecting
foaming of said mixture by the creation of turbulence without the
use of moving mechanical means;
pipe means for deliverying said mixture from said mixer to said
closed foaming device;
feeding means for feeding said foamed fiber dispersion effected by
said closed foaming device to a foraminous support on which said
non-woven fibrous material is formed;
vacuum drain means, including vacuum box means, for recovering a
major part of the liquid, generally in a foamed condition, from
said foamed fiber dispersion on said foraminous support;
a pulper connected by pulp delivery pipe means to said mixer;
pump means operable to recycle said liquid so recovered generally
in a foamed condition directly from said vacuum box means through
said pulp delivery pipe means to said mixer; and metering means
operable to introduce into said pulp delivery pipe means upstream
of said mixer metered quantities of air and make-up surface active
agent.
4. The system according to claim 3 including a deflaker in said
pulp delivery pipe means, downstream of said metering means and
upstream of said mixer, for effecting dispersion of fiber clumps
passing through said pulp delivery pipe means.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to the manufacture of non-woven fibrous
material, for example paper.
2. Description of the Prior Art
It is known to manufacture paper and other nonwoven fibrous
material by depositing a suspension of fibres in a liquid, usually
water, onto a foraminous support, called the wire, of a
paper-making machine, which allows the liquid to drain through
while retaining most of the fibres in the form of a web in which
the fibres lie intermeshed, all substantially in the plane of the
web. Due to the random nature of the process of deposition, and
also because of the natural tendency of most fibres to form flocs,
or clumps, the web is usually not uniform but contains areas which
are particularly thin or light, or which are particularly thick or
heavy. The degree of uniformity, or the lack of uniformity, of the
web, may be controlled to some extent by the exercise of the
machine operator's skill and by the design of the machine. In
particular, the formation of acceptably uniform webs from fibres
which have an excessive tendency to flocculate, or clump together,
such as long synthetic fibres, or long, lightly beaten cotton or
wood fibres, or other long natural fibres from animal, vegetable or
mineral sources, requires that the fibres be dispersed in very
large volumes of liquid. The subsequent drainage of such large
volumes of liquid cannot be accomplished on conventional
paper-making machines but requires costly modifications
thereto.
A less common known method of manufacturing fibrous material is
that in which fibres are first dispersed in a liquid medium of high
viscosity, such as an aqueous solution of sugar, or of natural
gums, the dispersion then being drained through the wire of a
paper-making machine thereby to form a fibrous web on the wire.
This method has the advantage that when the dispersing action
ceases, the fibres very quickly cease their motion in the liquid
medium, and become immobile before they can become flocculated and
clumped together to any appreciable extent. Thus, the fibres in
such a liquid medium remain well dispersed until the liquid medium
is drained from the dispersion and the web formed. However, due to
the always high viscosity of the liquid medium initial dispersion
of fibres therein is difficult, and its drainage through the
forming web and through the supporting wire is slow and difficult,
so that this known method is not well suited to the large-scale
continuous manufacture of fibrous material.
It has also been proposed to add a surface active agent to the
water conventionally used in the water-laying of fibrous webs on a
paper-making machine, and by agitation produce a foamed fibre
dispersion having an air content of at least 65% by volume to
assist in the formation of a uniform fibrous web and, more
especially, a uniform fibrous web comprising fibres longer than
those conventionally employed in the water-laying manufacture of
fibrous webs on a paper-making machine, i.e. fibres having a length
in excess of about 3 mm.
Known methods of forming such a foamed fibre dispersion involve
subjecting water containing surface active agent to a vigorous
shearing action, for example by the use of apparatus comprising a
casing for containing the water, and an impeller mounted within the
casing for rotation relative thereto such that the water is
subjected to a vigorous shearing action between blades of the
impeller and an inner surface of the casing. With the use of such
apparatus fibres can be added either to the water prior to foaming
thereof or to foam already formed in the apparatus.
Known foamed fibre dispersion forming apparatus as described above,
while being effective to form dispersions having required
properties, has the disadvantage that it comprises relatively
moving parts, i.e. the impeller and the casing, and thus requires
an input of power to provide the necessary movement. Further, the
relative movement of the parts results in wear in the
apparatus.
SUMMARY
It has now been discovered, firstly that fibrous material having a
higher degree of uniformity of fibre dispersion throughout the
material than can be produced at the same weight consistency using
only water as the dispersion medium, can be manufactured using a
foamed liquid medium having an air content above a lower limit less
than 65%; secondly that there is an air content level for the
foamed liquid medium above which although the dispersion of fibres
in the foamed liquid medium is more uniform than can be obtained at
the same weight consistency using only water as the dispersion
medium, nevertheless the fibres in the foamed liquid medium have a
tendency to agglomerate; and thirdly that the size distribution of
the bubbles in the foamed liquid medium is of considerable
importance.
It has also been discovered that not all foamed liquid media
comprising air bubbles dispersed in a liquid containing a surface
active agent are useful for dispersing fibres, and in fact that
certain foamed liquid media can be used to produce agglomeration of
fibres (and particles) rather than dispersion thereof, albeit that
the overall fibre dispersion may be better than could be obtained
at the same weight consistency using water only as the dispersion
medium.
It has been further discovered that an important parameter in
relation to the dispersion/agglomeration properties of a foamed
liquid medium of the kind under consideration is the volume
percentage of air therein, and that the possible volume percentage
of air range (i.e. 0% to about 99.9%) can be divided into three
sub-ranges two of which, namely up to about 55% and over about 75%,
can be used to effect agglomeration of fibres and/or particles, and
the other, namely from about 55% to about 75%, can be used to
effect substantially uniform dispersion of generally discrete
fibres.
The volume percentage of air required to effect the most uniform
dispersion of any particular fibres and/or particles is generally
dependent upon the shape, size, physical properties and
concentration of the fibres and/or particles. The relationship
between the size of the fibres and/or particles and the arithmetic
mean diameter of the air bubbles is also relevant in determining
the most uniform dispersion of any particular fibres and/or
particles.
It has been ascertained that at all volume percentages of air,
fibres normally occupy only the liquid between the air bubbles;
that is that fibres do not penetrate the air bubbles. Thus, factors
determining whether a particular foamed liquid medium will effect
dispersion or agglomeration of fibres apart from the volume
percentage or air therein are the number, shape and size of the air
bubbles in the medium.
When the foamed liquid medium contains a volume percentage of air
of between about 55 and 75%, the fibres are dispersed
substantially, uniformly throughout the foamed liquid medium.
When the volume percentage of air in a foamed liquid medium is less
than about 55%, the air is contained in a relatively few relatively
wide diameter range bubbles which divide the medium into pockets of
liquid in which the fibres collect, and as the viscosity of the
liquid (normally water) is relatively low, the fibres are free to
move and thus agglomerate within the liquid pockets.
When the volume percentage of air in a foamed liquid medium is
greater than about 75% and the bubbles have a substantially uniform
size distribution, the packing density of the bubbles is so high
that the bubbles are deformed from their normally spherical shape
into polyhedrally shaped bubbles. In a medium containing such
bubbles, surface tension effects result in forces in the planes of
the inter-bubble lamellae, the forces being directed towards the
line of intersection of the lamellae and into the points of
intersection of the lines of intersection of the lamellae. These
forces move fibres into the lines of intersection of the lamellae
and the fibres become aligned in bundles in these lines.
However, although when using a foamed liquid medium having a volume
percentage of air above 75% therein there is some degree of fibre
agglomeration, nevertheless the overall fibre dispersion in a web
produced using such a foam can be better than can be obtained at
the same fibre weight consistency using only water as the
dispersion medium.
Work has shown that as the volume percentage of air in a foamed
liquid medium increases, firstly the number of bubbles per unit
volume of the medium increase; secondly the arithmetic mean
diameter of the bubbles decreases; and thirdly the range of bubble
diameters decreases. The inherent desirable viscosity properties of
the foamed liquid medium produced in accordance with the present
invention derive from not only the number of bubbles therein per
unit volume, but also from the substantially uniform size of the
bubbles.
The effect on the viscosity of the medium of the bubble size
distribution is thought to result from the fact that the volume
percentage of air required for close packing of the bubbles is less
if the bubbles have a substantially uniform size distribution.
The chemical nature of the surface active agent used is not
critical provided that it is able to produce a foamed liquid medium
having the specified properties. The surface active agent may be
anionic, cationic, or nonionic, and it has been found that
proprietary surface active agents such as that sold under the name
"ACE" liquid, this being an anionic substance, by Industrial Soaps
Ltd., that sold as "TEXOFOR (Registered Trade Mark) FN 15," a
non-ionic substance by Glover Chemicals Ltd., and that sold as
"AMINE Fb19," a cationic substance, by Float-Ore Ltd. are all
suitable. Other surface active agents that have been used are
oxtylphenoxypolyethoxy ethanol, and commercial grade dodecyl
benzene sulfonate.
The arithmetic mean diameter of the bubbles in a foamed liquid
medium can be determined by plunging a microscope slide cooled to
about - 70.degree.C into the medium, and then removing the slide
with a sample of the medium frozen thereto and placing the slide
into a freezing stage of a microscope. Photomicrographs at say 100
.times. magnification can then be taken and the arithmetic mean
diameter of the visible bubbles then determined therefrom. This
method has the advantage that a sample of the medium is taken from
within the medium mass, and it is no only the outer layer of
bubbles that is examined.
It is a main object of the present invention to provide such a
method of and apparatus for manufacturing non-woven fibrous
material from a foamed fibre dispersion, which method and apparatus
permits liquid, generally in a foamed condition, recovered by
vacuum boxes to be recirculated to a mixer in which a
gas/water/fibre/surface active agent dispersion is formed
preparatory to being converted into a foamed fibre dispersion,
having required properties, thereby reducing wastage of surface
active agent, reducing operating and maintenance costs, and
substantially reducing the need for effluent treatment.
According to one aspect of the invention there is provided a method
of manufacturing non-woven fibrous material, for example paper, by
feeding to a foraminous support from a foaming device a foamed
fibre dispersion formed by the foaming device, said method
including the steps of forming the foamed fibrous dispersion which
is fed to the support by recovering a major part of the foamed
water from foamed fibre dispersion on the support by connecting the
input side of a vacuum-creating device to the underside of the
support and the output side to a mixer, introducing fibres into the
mixer, together with recovered foamed water, a air and surface
active agent, and following mixing thereof in the mixer feeding the
air/water/fibre/surface active agent mixture to the foaming
device.
According to another aspect of the invention there is provided in a
machine for manufacturing non-woven fibrous material, which machine
includes a foraminous support on which the material is formed,
apparatus comprising a closed foaming device arranged to form a
foamed fibre dispersion and to feed the dispersion for deposition
on the support; a mixer; vacuum-creating means to drain liquid from
foamed water from foamed fibre dispersion on the support, the
negative pressure side of the vacuum-creating means being connected
to the underside of the support and the positive pressure side
being connected to the mixer; means operable to deliver to the
mixer foamed water drained from foamed fibre dispersion on the
support; and means connecting the mixer with the foaming device to
deliver thereto a water/fibre/air/surface active agent mixture
formed in the mixer.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 illustrates diagrammatically apparatus for carrying into
effect the method according to the invention,
FIG. 2 illustrates diagrammatically, in plan, one form of apparatus
for forming a foamed fibre dispersion, and
FIG. 3 is a section diagrammatically illustrating a part of the
apparatus of FIG. 2.
DESCRIPTION OF PREFERRED EMBODIMENT
Referring to the drawings, the reference 1 indicates a foraminous
support, being the wire of a Fourdrinier paper-making machine, on
which there is deposited from a head box 2 a foamed fibre
dispersion, not shown, from which a non-woven fibrous material is
formed by draining water, generally in a foamed condition, from the
dispersion through the foraminous support 1. Draining is effected,
in known manner by vacuum-creating means 3 and 4 the negative
pressure sides of which are connected to the underside of the
support 1. As can be seen from FIG. 1, the vacuum-creating means 3
and 4 are spaced apart along the support and between the means 3
and 4 the support 1 passes over what are known as table rolls 5.
Some drainage, about 20%, takes place as the dispersion passes over
the rolls 5 and the water so drained falls into a wire pit 6 from
which it overflows over a weir 7 into a hog pit 8 in which it is
slushed by an agitator 9 and from which it is pumped by a pump 10
into a broke tank 11. The vacuum-creating means are associated
respectively with what are usually termed wet vacuum boxes 12 and
dry vacuum boxes 13.
The positive pressure sides of the vacuum-creating means are
respectively connected by pipes 14 and 15 with a pipe 16 in which
drained foamed water containing surface active agent meets and
becomes infused with a mixture of air/water/fibres/surface active
agent fed to the pipe 16 by a pump 17 at a pressure of about 25 to
30 pounds per square inch. The pipe 16 is connected with an in-line
mixer 18, of any suitable kind which effects a coarse mixing of the
mixture to provide a fairly homogeneous mixture which passes from
the mixer through an inlet pipe 19 to an in-line foaming device 20
in which a foamed fibre dispersion, having desired properties as
referred to above, is formed for delivery through an outlet pipe 21
to the head box 2. The foaming device may be of any suitable closed
kind, but is preferably of the kind described below with reference
to FIG. 2 because this does not utilise any mechanical moving
parts, it is not open to atmosphere, and it is possible to admit
metered quantities of air and surface active agent to a water/fibre
dispersion as the latter approaches the mixer.
As is usual in the manufacture of non-woven fibrous material, the
fibre is first beaten with water in a conventional beater 22, such
as a Hollander beater, to form stock having a consistency of about
4% by weight based on bone dry fibre. The stock is pumped by a pump
23 to chests 24 where it is held to provide bulk storage for the
apparatus, the fibre being kept substantially uniformly in
suspension by conventional agitators 25. From the chests 24 the
stock is pumped along a line 26 by a pump 27 to a refiner 28 from
which the stock passes to a thickener 29. The thickener serves to
de-water the stock so that it leaves the thickener at a consistency
which is usually between 20% and 30% by weight based on bone dry
fibre, but should be sufficiently high to minimise the input of
fresh water into the apparatus while achieving the required dryness
for the web that is removed from the foraminous support 1 prior to
drying. Water extracted from the stock in the thickener 29 is
removed through a drain pipe 30 and may either go to drain or be
re-directed for reuse in the beater 22. The thickened stock is
delivered to a pulper 31 in which it is mixed by conventional
agitating means 32 with water which is stored in a tank 33 which
receives drained foamed water from pipe 14 through a valve 34, and
with broke pumped to tank 33 from the broke tank 11 by a pump 35,
passing if desired through a broke deflaker 36.
Surface active agent may, if desired, be added to the water in tank
33 but it is preferred to admit both air and surface active agent
to the water/fibre dispersion as it flows through a pipe 37 to the
pipe 16. The pump 17 is included in pipe 37 and the air and surface
active agent are delivered into pipe 37, preferably on the output
side of pump 17, through metering devices 38, 39 respectively. A
deflaker 40 which serves to disperse clumps of fibres is also
included in pipe 37.
The preferred kind of foaming device 20 mentioned above comprises a
plurality of foam-forming pipes 41, which may consist of flexible
tubes, each of which has at least one internal region of
constricted cross-section formed by a tubular insert 42 which may
be circular or of other desired cross-section. An inlet manifold,
formed by a housing 43, and an outlet manifold, formed by a housing
44, are connected one to the other by the foam-forming pipes 41.
The inlet manifold is connected to the inlet pipe 19 by a flange 45
and the outlet manifold is connected to the outlet pipe 21 by a
flange 46. Each foam-forming pipe 41 extends laterally from a
housing and is coiled, as at 47, between the ends thereof connected
respectively to the inlet and the outlet housing. In a preferred
embodiment the housings 43, 44 are circular and the foam-forming
pipes extend radially therefrom.
Each end of each of the foam-forming pipes is connected to a
housing 43, 44 through a manually operable valve 48 connected to a
stub pipe 49 extending laterally from the housing. The tubular
inserts 42 are connected to the valves 48 and the foam-forming
pipes 41 are fitted over the inserts 42 as illustrated in FIG.
3.
One end 50 of the inlet housing 43 is open to communicate with the
inlet pipe 19 and the end of the housing opposite said open end is
closed by a plug 51, FIG. 3, having a conical configuration 52
extending into the housing to prevent the formation of air pockets
in the inlet housing 43.
There may be forty-eight foam-forming pipes 41 arranged in four
ranks or banks each of twelve pipes and the housings 43, 44 are
preferably independently supported so that little or no vibration
is transmitted between the inlet and outlet manifolds. Generally
before using the foam-forming apparatus to make any particular kind
of product the number of foam-forming pipes to be used is selected
by manipulation of the valves 48. If desired, the number of
foam-forming pipes 41 in use can be changed during operation of the
apparatus by manipulation of the valves 48.
When the foam-forming apparatus is in operation a mixture of air,
water and fibre, and surface active agent fed to the manifold 41 is
substantially equally divided into each foam-forming pipe and the
tubular inserts 42 set up turbulence in the mixture which effects
foaming and dispersion of the fibres, to provide a foamed fibre
dispersion having desired properties as referred to above.
From the foregoing description it will be understood that recovered
drained liquid is continuously recycled through a loop formed by
the pipes 14, 15, 16 mixer 18, pipe 19, and foaming device 20, thus
reducing the quantity of "make-up" surface active agent required,
and that by using the described preferred form of foaming device it
is possible, by metering air and surface active agent into the
approach flow system, to provide control over the air content and
thus the viscosity of the foam.
* * * * *