U.S. patent number 3,868,970 [Application Number 05/366,728] was granted by the patent office on 1975-03-04 for multipositional selector valve.
This patent grant is currently assigned to Phillips Petroleum Company. Invention is credited to Buell O. Ayers, Lewis B. Roof.
United States Patent |
3,868,970 |
Ayers , et al. |
March 4, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
MULTIPOSITIONAL SELECTOR VALVE
Abstract
A valve adapted with a flow distributor enabling selection of
one of a plurality of flow paths therethrough. The valve is adapted
with means for attaching a plurality of chromatographic columns
thereto such that flow can be directed into any of the columns,
individually.
Inventors: |
Ayers; Buell O. (Bartlesville,
OK), Roof; Lewis B. (Bartlesville, OK) |
Assignee: |
Phillips Petroleum Company
(Bartlesville, OK)
|
Family
ID: |
23444242 |
Appl.
No.: |
05/366,728 |
Filed: |
June 4, 1973 |
Current U.S.
Class: |
137/625.46 |
Current CPC
Class: |
F16K
11/074 (20130101); Y10T 137/86863 (20150401) |
Current International
Class: |
F16K
11/06 (20060101); F16K 11/074 (20060101); F16k
003/08 (); F16k 011/02 () |
Field of
Search: |
;137/625.11,625.46 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Klinksiek; Henry T.
Claims
What is claimed is:
1. An apparatus comprising:
a. an inlet;
b. a movably-positionable distributor comprising a first circular
grooved channel in a rotatable plate, said first circular grooved
channel in direct contact with a channel from said inlet, said
first circular grooved channel having a second channel extending
therefrom whereby by rotation of said plate registry can be
maintained with any one of a plurality of openings located at the
same direction in the same direction away from this first circular
grooved channel;
c. a first plurality of openings, each of said openings connected
to a conduit leading from said distributor; and
d. a first plurality of conduits each connected to one of said
openings.
2. The apparatus of claim 1 in which said plurality of conduits are
individually adapted for the insertion thereinto of a
chromatographic column.
3. The apparatus of claim 1 in which said distributor is
positionable by motor means.
4. The apparatus of claim 3 in which said motor means is controlled
by selector switches.
5. The apparatus of claim 1 in which said apparatus comprises a
mounting plate and a column plate.
6. The apparatus of claim 5 in which said inlet is positioned in
said mounting plate and said first plurality of conduits open from
said column plate.
7. The apparatus of claim 6 in which a second plurality of conduits
provide open communication through said mounting plate and opens
from said mounting plate.
8. The apparatus of claim 7 comprising:
a. an outlet;
b. said movably-positionable distributor comprising a second
circular grooved channel in said rotatable plate, said second
circular grooved channel in direct contact with a channel to an
outlet, said second circular grooved channel having a second
channel extending therefrom whereby by rotation of said plate
registry can be maintained with any one of a second plurality of
openings located at the same distance in the same direction away
from the second circular grooved channel; and
c. a second plurality of openings, each of said openings connected
to one of said second plurality of conduits.
9. The apparatus of claim 8 in which chromatographic columns are
positionable between said plurality of conduits opening from said
valve and said second plurality of conduits opening from said
mounting plate.
10. The apparatus of claim 1 in which said apparatus is adapted
with storage conduits.
Description
This invention relates to a multipositional selector valve.
In one of its more specific aspects, this invention relates to a
valve positionable in relation to a plurality of chromatographic
analyzers for the purpose of directing a sample into a plurality of
analyzing columns or into a plurality of retention or storage
columns.
The use of chromatographic analysis as an analytical procedure is
well known. Such as U.S. Pat. Nos. 2,972,246 to Reinecke et al. and
3,376,894 to Broerman describe the underlying principles of the
procedures involved.
Frequently, in conducting such analyses, it is desirable to direct
a plurality of portions of a sample into a plurality of analyzing
columns or it may be desirable to direct a plurality of eluted
portions of a sample being analyzed into a plurality of cumulating
columns from which the portions can be subsequently recovered for
further detailed analysis. The valve of the present invention
provides a means for collecting such a plurality of samples.
According to the apparatus of this invention there is provided a
valve comprising an inlet, a distributor, a conduit in open
communication between said inlet and said distributor and a
plurality of conduits in open communication between the distributor
and a plurality of outlets opening from the valve.
The valve of the present invention is an improvement over multiport
valves of the prior art because it embodies a first upper portion
of comparatively small diameter to provide for the routing of the
sample into any of a plurality of flow paths with a minimum
opportunity of sample loss and it employs a second lower portion of
a comparatively larger diameter to provide a sufficient area for
the attachment of a plurality of columns to the plurality of
conduits leading from the valve into the columns.
The apparatus of this invention will be more easily understood if
explained in conjunction with the attached drawings in which
FIG. 1 is a view of the valve in elevation;
FIGS. 2 through 9 are views of several of the individual elements
comprising the valve; and,
FIG. 10 is a schematic diagram illustrating one flow pattern
through the valve.
The apparatus of this invention will be described in terms of a
preferred embodiment adapted for positioning in conjunction with a
plurality of chromatographic columns, for example, six in number.
Each element shown in the FIGURES will be described with reference
to a vertical axis through a plan view of the element.
As shown in FIG. 1, the valve 1 is comprised of column plate 2,
column gasket 3, mounting plate 4, stator gasket 5, stator 6, rotor
7 and rotor cap 8. These elements can be indexed relative to each
other to form one or more flow paths through the valve. The valve
also is adapted with rotor shaft 9, spring 10, spring plate 11, and
microselector switches 12 and motor 13. The column plate, column
gasket, mounting plate, stator gasket and stator are indexed in
predetermined positions and maintained in fixed positions by means
of suitable bolting. The rotor and rotor cap are positioned as a
movable entity in relation to the aforementioned elements and held
in leak-proof arrangement relative thereto by means of the spring
and spring plate.
The sample takes the flow path shown schematically in FIG. 10.
The sample is introduced into an inlet in mounting plate and flows
through the mounting plate into the column gasket which acts to
channel the sample into the proper conduit.
The sample flows up through the mounting plate, stator and into a
channel of the rotor. The rotor is positioned in a selected
relationship to the stator so as to direct the sample through a
preselected path down through the valve and from the column
plate.
Affixed to the column plate and projecting downwardly is U-shaped
column 100. The sample flows from the valve down one leg of the
column, up the other leg of the column, and back up into the valve.
The sample is directed into the rotor which preselects the outward
path therefrom.
The sample then flows downwardly from the rotor, across the column
gasket and up through the mounting plate and from the valve.
The apparatus will be described in detail with the elements being
discussed in flow sequence. Each element is described in relation
to a center line B'-B and point B' thereon with all positions being
given therefrom in a clockwise direction. Unless otherwise stated,
all holes in all members are to be considered as penetrating the
depth of the member concerned.
Referring now to FIG. 2, there is shown a plan view of mounting
plate 4. This plate can be fabricated of steel, can be about 6
inches in diameter and about five-eighths inch in thickness. It
will be adapted with a plurality of bolts holes arranged as
convenient.
On a circle 3 inches in diameter, as related to the center of the
plate, at 45.degree. and 75.degree., respectively, from reference
point B' there are positioned outlet hole 21 and inlet hole 20
penetrating the plate.
On a 1 3/8 inch diameter hole circle, there is positioned one hole
22a at a location 75.degree. clockwise from reference point B'.
On a 1 1/8 inch diameter hole circle, there are positioned six
holes 23a, 23b, 23c, 23d, 23e, and 23f, these holes being
positioned equally arcuately spaced and straddling the center line
B.
On a 7/8 inch diameter hole circle, there are positioned six holes
24a, 24b, 24c, 24d, 24e and 24f, these being positioned equally
arcuately spaced, two holes being intersected by center line
B'-B.
On a 5/8 inch diameter hole circle, there is positioned one hole
25a at a location 45.degree. clockwise from reference point B'.
The mounting plate is also adapted with center hole 29 which can be
0.257 inch in diameter and penetrates the plate.
Referring now to FIG. 3, there is shown column gasket 3. This
gasket will be 6 inches in diameter and can be composed of
one-eighth inch thick Teflon. This gasket will be penetrated by a
center hole 39 which is five-sixteenths inch in diameter. It will
be adapted with bolt holes in matching arrangement to those of the
mounting plate. The after-described slots all are one thirty-second
inch in width and penetrate the gasket.
Inlet slot 30 is positioned on a radius 75.degree. clockwise from
reference point on a B'. It extends from a point 1 3/8 inch
diameter circle centered on the gasket to a point on a 3 inch
diameter circle centered on the gasket.
Outlet slot 31 is positioned on a radius 45.degree. clockwise from
reference point B'. It extends from a point five-sixteenths inch
from the center of the gasket to a point 1 1/2 inches from the
center of the gasket.
The gasket will contain six slots 32a, 32b, 32c, 32d, 32e and 32f
equally arcuately spaced and extending outwardly from loci 1 1/8
inches from the center of the gasket to loci on a 5 inch diameter
circle centered on the gasket. Slot 32a will be positioned on a
radii 30.degree. clockwise from reference point B'.
The gasket will contain six slots 33a, 33b, 33c, 33d, 33e and 33f
equally arcuately spaced and extending outwardly from loci on a 7/8
inch diameter circle centered on the gasket to loci on a 5 inch
diameter circle centered on the gasket. Slot 33a will be positioned
on the center line B'-B.
Referring now to FIG. 4, there is shown column plate 2. This plate
can be formed of steel and will be 6 inches in diameter and
five-eighths inch thick. It will be drilled and tapped for any
suitable number of bolt holes by means of which the plate is
adapted for holding the previously-described elements in matching
relationship. It is also adapted with twelve holes, penetrating the
plate, spaced equidistantly on a 5 inch diameter circle, one of
these holes being positioned on plate center line B'-B. These holes
are tapped in their lower portions to permit the attachment of
threaded connections at the inlet to and the outlet from the
column, a column thus assuming a U-shape when both of the column
ends are fitted to the column plate.
The column plate is also adapted with center hole having a diameter
of 0.257 inch and penetrated the plate to a depth of one-fourth
inch at which point the hole is enlarged to 5/8 inch diameter.
Referring now to FIG. 5, there is shown stator gasket 5 which can
be made of one-eighth inch thick Teflon and which can be 1 5/8 inch
in diameter. It is penetrated by a center hole 59 having a 5/16
inch diameter.
The stator gasket is penetrated by fourteen holes having a diameter
of one thirty-second inch.
The stator is adapted with first hole 57a penetrating the stator
and positioned 45.degree. clockwise from center line B'-B on a 5/8
inch diameter circle. The stator is adapted with a second hole 58a
penetrating the stator and positioned 75.degree. clockwise from
center line B'-B on a 1 3/8 inch diameter circle.
Six of these holes, 51a, 51b, 51c, 51d, 51e and 51f, are positioned
on a 1 1/8 diameter circle, the holes being equally arcuately
spaced apart, and straddling center line B'-B.
A second series of six holes, 52a, 52b, 52c, 52d, 52e and 52f, are
positioned on a 7/8 inch diameter circle, being equidistantly
spaced apart, hole 52a being positioned on center line B'-B.
The stator gasket is adapted with six slots one thirty-second inch
in width, each penetrating the gasket. These slots, 53a, 53b, 53c,
53d, 53e and 53f, each have a first terminus positioned on a 1 1/8
inch diameter circle and extend inwardly in a clockwise direction
in a straight line such that the second terminus of each is
positioned on a 7/8 inch diameter circle. Each slot extends from a
first radius to a second radius positioned 30.degree. therefrom,
the slots being so positioned on alternate 30.degree. segments of a
circle, slot 53a having a first terminus positioned on center line
B'-B on the 1 1/8 inch diameter circle and extending inwardly to
the 7/8 inch diameter circle to a point 30.degree. in a clockwise
direction from center line B'-B.
Referring now to FIG. 6 there is shown stator 6. This element can
be fabricated of steel and have a diameter of 1 5/8 inch O.D. and a
thickness of one-half inch. It has a 5/16 inch diameter center
hole.
The stator is adapted with first hole 61a penetrating the stator
and positioned 45.degree. clockwise from center line B'-B on a
5/8inch diameter circle. The stator is adapted with a second hole
62a penetrating the stator and positioned 75.degree. clockwise from
center line B'-B on a 1 3/8 inch diameter circle. The stator is
adapted with a first series of twelve holes 63a, 63b, 63c, etc.,
each penetrating the plate, all positioned on a 7/8 inch diameter
circle, equally arcuately spaced 30.degree. apart, hole 63a being
positioned on the center line B'-B.
The stator is adapted with a second series of 12 holes 64a, 64b,
64c, etc., each penetrating the plate, all positioned on a 1 1/8
inch diameter circle, equally arcuately spaced 30.degree. apart,
hole 64a being positioned on the center line B'-B.
Referring now to FIG. 7 there is shown rotor 7, shown in a view of
its underside. This element can be fabricated of steel and have a
diameter of 1 5/8 inch and a thickness of one-fourth inch. It has a
center hole 79a having a 3/8 inch diameter.
The motor is adapted with a first groove or channel 71a which lies
on a 5/8 inch diameter circle. This groove is one thirty-second
inch wide and one thirty-second inch deep and encircles the center
hole. At a locus 240.degree. clockwise from reference point B',
this groove extends outwardly from the center hole a distance of
one-fourth inch.
The rotor is adapted with a second groove or channel 73a which lies
on a 13/8 inch diameter circle. This groove is one thirty-second
inch wide and one thirty-second inch deep and encircles the center
hole. At a locus 270.degree. clockwise from reference point B',
this groove extends inwardly towards the center hole a distance of
one-fourth inch and terminates at terminus 74a.
The grooved surface of the rotor and the adjacent stator face will
preferably be lapped to facilitate rotation of the rotor relative
to the stator positioned therebeneath.
Referring now to FIG. 8 there is shown rotor cap 8 in a view of its
underside. This element can be fabricated of steel and have a
diameter of 1 5/8 inch and a thickness of one-fourth inch. The
rotor cap has a center hole 89a having a 0.257 inch diameter with
two seven sixty-fourths inch wide slots extending outwardly about
one-fourth inch from the center of the circle and also has a
circular section nineteen thirty-seconds inch in diameter extending
one-sixteenth inch above its upper surface.
Referring now to FIG. 9, there is shown rotor shaft 9. It will be a
circular, stainless steel member having a length of about 4 3/4
inch and a diameter of one-fourth inch. It will be penetrated by a
first 3/32 inch aperture 9a at five-eighths inch from its first end
and a second aperture 9b 2 1/8 from its first end. Its second end
9c will be threaded for a distance of one-half inch from its
end.
This rotor shaft extends down through the previously-described
elements, extending through the column plate into a nut positioned
therebeneath in aperture 49 of the column plate. A pin is
positioned through aperture 9b of rotor shaft 9 to lock into slot
89a of the rotor cap and to effect rotation of the rotor cap
operating as a movable entity relative to the elements
therebeneath.
The spring and spring plate are positioned in bearing relation to
the rotor cap and maintained in position by a pin positioned
through aperture 9a.
The rotor shaft is coupled to a motor shaft affixed to a motor. The
rotation of the motor is controlled by suitable microselector
switches and cam arrangement which form no part of the
invention.
Rotation is effected through the motor to turn the rotor shaft
which turns the rotor cap and rotor to any preselected position
such that material flowing upwardly through the valve can be caused
to flow in a preselected path down through the valve and into a
preselected column affixed to the column plate.
It will also be seen that not only can a plurality of samples be
introduced into a plurality of columns but a plurality of samples
can be stored in the stator-stator gasket section of the apparatus
upon suitable indexing, these samples being recovered from various
cuts separated in any of the plurality of chromatographic columns
or being introduced into the selector valve and stored therein for
subsequent usage.
Simultaneously therewith, there can be contained within the valve,
between the rotor and the mounting plate, in any selected channel
68, as shown in FIG. 10, another sample which, after entrapment
therein, can be introduced into any of the plurality of columns
affixed to the base of the column plate.
It will be appreciated that the various parts described can be
adapted with one or more apertures to facilitate assembly and
subsequent indexing of the various parts in sequential flow
arrangement, any flow arrangement being selectable upon integration
of the movements of the various parts as effected by the turning of
the motor shaft in relation to the cams and micro-selector
switches.
For example, in one embodiment of the invention the valve described
has been used as a 12 port-12 position rotary switching valve, the
valve being constructed to switch any or none of six
chromatographic columns into a system. Six of the valve positions
are available to switch the column into the system with the six
alternate valve positions being employable to bypass all columns.
In this operation the valve can collect, store and introduce
samples into the columns and can similarly collect, store and
reintroduce component cuts from original samples.
It will be evident from the foregoing that various modifications
can be made to the method of this invention. Such are considered,
however, to be within the scope of the invention.
* * * * *