U.S. patent number 3,865,765 [Application Number 05/424,022] was granted by the patent office on 1975-02-11 for resin binder compositions.
This patent grant is currently assigned to Johnson & Johnson. Invention is credited to Bobby R. Bowman, Arthur H. Drelich.
United States Patent |
3,865,765 |
Drelich , et al. |
February 11, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
Resin binder compositions
Abstract
A resin binder composition comprising: (1) a synthetic resin;
(2) a water-soluble, polymeric, carboxylic thickener; and (3) a
metal ammine, complex coordination compound capable of releasing
ions of said metal to control the total migration of the resin
binder during its deposition on a fibrous web.
Inventors: |
Drelich; Arthur H. (Plainfield,
NJ), Bowman; Bobby R. (East Brunswick, NJ) |
Assignee: |
Johnson & Johnson (New
Brunswick, NJ)
|
Family
ID: |
27380586 |
Appl.
No.: |
05/424,022 |
Filed: |
December 12, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
176306 |
Aug 30, 1971 |
3821146 |
Jun 28, 1974 |
|
|
109026 |
Jan 22, 1971 |
3706595 |
Dec 19, 1972 |
|
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Current U.S.
Class: |
524/28 |
Current CPC
Class: |
C08L
33/06 (20130101); D06M 15/263 (20130101); D06M
15/244 (20130101); D06M 15/09 (20130101); C08K
3/10 (20130101); D06M 11/62 (20130101); D06M
15/333 (20130101); C08J 9/28 (20130101); C08L
31/04 (20130101); A61L 15/60 (20130101); D04H
1/66 (20130101); D06P 1/52 (20130101); D06M
15/01 (20130101); C08L 31/04 (20130101); C08L
101/08 (20130101); C08L 27/06 (20130101); C08L
101/08 (20130101); C08L 33/06 (20130101); C08L
101/08 (20130101); C08L 31/04 (20130101); C08L
2666/02 (20130101); C08L 33/06 (20130101); C08L
2666/02 (20130101); C08L 5/04 (20130101); C08J
2201/0547 (20130101); C08L 1/08 (20130101) |
Current International
Class: |
A61L
15/16 (20060101); A61L 15/60 (20060101); D06P
1/44 (20060101); D06M 15/263 (20060101); D06M
15/333 (20060101); D06M 15/244 (20060101); D06P
1/52 (20060101); D06M 11/00 (20060101); C08J
9/00 (20060101); D06M 15/09 (20060101); D04H
1/66 (20060101); C08L 31/00 (20060101); C08K
3/00 (20060101); C08L 33/00 (20060101); C08J
9/28 (20060101); D04H 1/64 (20060101); C08L
31/04 (20060101); C08L 33/06 (20060101); D06M
11/62 (20060101); D06M 15/21 (20060101); D06M
15/01 (20060101); C08L 1/00 (20060101); C08L
1/08 (20060101); C08L 5/00 (20060101); C08L
5/04 (20060101); C08f 045/00 (); C08g 051/00 () |
Field of
Search: |
;260/9,17.4ST |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Phynes; Lucille M.
Parent Case Text
This patent application is a division of co-pending patent
application, Ser. No. 176,306, filed on Aug. 30, 1971, now U.S.
Pat. No. 3,821,146, granted June 28, 1974 which in turn is a
continuation-in-part of copending patent application, Ser. No.
109,026, filed Jan. 22, 1971, now U.S. Pat. No. 3,706,595 which
issued on Dec. 19, 1972.
Claims
What is claimed is:
1. A colloidal synthetic resin binder composition for bonding a
fibrous web of overlapping, intersecting fibers which comprises: a
stable, colloidal aqueous dispersion having an alkaline pH
comprising: (1) from about 0.1% to about 60% by weight on a solids
basis of a colloidal synthetic resin; (2) from about 0.05% by
weight to about 7% by weight, based on the weight of said colloidal
synthetic resin of a sodium salt of an alginate polymer as a
water-soluble, polymeric carboxylic synthetic resin thickener; and
(3) from about 0.01% by weight to about 5% by weight, based on the
weight of said colloidal synthetic resin of a metal ammine complex
coordination compound, having the formula Me (NH.sub.3).sub.x Y
wherein Me is a metal, x is a whole number from 2 to 8, and Y is an
anion, said metal being selected from the group consisting of
chromium, nickel, zinc, and copper.
2. A colloidal synthetic resin composition for application under
controlled migration conditions to porous, absorbent materials
which comprises a stable, colloidal aqueous dispersion having an
alkaline pH comprising: (1) from about 0.1% to about 60% by weight
on a solids basis of a colloidal synthetic resin; (2) from about
0.05% by weight to about 7% by weight, based on the weight of said
colloidal synthetic resin of a sodium salt of an alginate polymer
as a water-soluble, polymeric carboxylic synthetic resin thickener;
and (3) from about 0.01% by weight to about 5% by weight, based on
the weight of said colloidal synthetic resin of a metal ammine
complex coordination compound, having the formula Me
(NH.sub.3).sub.x Y wherein Me is a metal, x is a whole number from
2 to 8, and Y is an anion, said metal being selected from the group
consisting of chromium, nickel, zinc, and copper.
Description
The present invention relates to porous, absorbent fibrous sheet
materials and to their methods of manufacture. More particularly,
the present invention is concerned with the so-called bonded,
"nonwoven" textile fabrics, i.e., fabrics produced from textile
fibers without the use of conventional spinning, weaving, knitting
or felting operations. Although not limited thereto, the invention
is of primary importance in connection with nonwoven fabrics
derived from "oriented" or carded fibrous webs composed of
textile-length fibers, the major proportion of which are oriented
predominantly in one direction.
Typical of such fabrics are the so-called "MASSLINN" nonwoven
fabrics, some of which are described in greater particularity in
U.S. Pat. Nos. 2,705,687 and 2,705,688, issued Apr. 5, 1955, to D.
R. Petterson, et al., and I. S. Ness, et al., respectively.
Another aspect of the present invention is its application to
nonwoven fabrics wherein the textile-length fibers were originally
predominantly oriented in one direction but have been reorganized
and rearranged in predetermined designs and patterns of fabric
openings and fiber bundles. Typical of such latter fabrics are the
so-called "KEYBAK" bundled nonwoven fabrics, some of which are
described in particularity in U.S. Pat. Nos. 2,862,251 and
3,033,721, issued Dec. 2, 1958 and May 8, 1962, respectively, to F.
Kalwaites.
Still another aspect of the present invention is its application to
nonwoven fabrics wherein the textile-length fibers are disposed at
random by air-laying techniques and are not predominantly oriented
in any one direction. Typical nonwoven fabrics made by such
procedures are termed "isotropic" nonwoven fabrics and are
described, for example, in U.S. Pat. Nos. 2,676,363 and 2,676,364,
issued Apr. 27, 1954, to C. H. Plummer, et al.
And, still another aspect of the present invention is its
application to nonwoven fabrics which comprise textile-length
fibers and which are made basically by conventional or modified
aqueous papermaking techniques such as are described in greater
particularity in pending patent application Ser. No. 4,405, filed
Jan. 20, 1970 by P. R. Glor and A. H. Drelich. Such fabrics are
also basically "isotropic" and generally have like properties in
all directions.
The conventional base starting material for the majority of these
nonwoven fabrics is usually a fibrous web comprising any of the
common textile-length fibers, or mixtures thereof, the fibers
varying in average length from approximately one-half inch to about
two and one-half inches. Exemplary of such fibers are the natural
fibers such as cotton and wool and the synthetic or man-made
cellulosic fibers, notably rayon or regenerated cellulose.
Other textile length fibers of a synthetic or man-made origin may
be used in various proportions to replace either partially or
perhaps even entirely the previously-named fibers. Such other
fibers include: polyamide fibers such as nylon 6, nylon 66, nylon
610, etc.; polyester fibers such as "Dacron," "Fortrel" and "Kodel;
" acrylic fibers such as "Acrilan," "Orlon" and "Creslan; "
modacrylic fibers such as "Verel" and "Dynel; " polyolefinic fibers
derived from polyethylene and polypropylene; cellulose ester fibers
such as "Arnel" and "Acele; " polyvinyl alcohol fibers; etc.
These textile length fibers may be replaced either partially or
entirely by fibers having an average length of less than about
one-half inch and down to about one-quarter inch. These fibers, or
mixtures thereof, are customarily processed through any suitable
textile machinery (e.g., a conventional cotton card, a
"Rando-Webber," a papermaking machine, or other fibrous web
producing apparatus) to form a web or sheet of loosely associated
fibers, weighing from about 100 grains to about 2,000 grains per
square yard or even higher.
If desired, even shorter fibers, such as wood pulp fibers or cotton
linters, may be used in varying proportions, even up to 100%, where
such shorter length fibers can be handled and processed by
available apparatus. Such shorter fibers have lengths less than 1/4
inch.
The resulting fibrous web or sheet, regardless of its method of
production, is then subjected to at least one of several types of
bonding operations to anchor the individual fibers together to form
a self-sustaining web. One method is to impregnate the fibrous web
over its entire surface area with various well-known bonding
agents, such as natural or synthetic resins. Such over-all
impregnation produces a nonwoven fabric of good longitudinal and
cross strength, acceptable durability and washability, and
satisfactory abrasion resistance. However, the nonwoven fabric
tends to be somewhat stiff and boardlike, possessing more of the
properties and characteristics of paper or board than those of a
woven or knitted textile fabric. Consequently, although such
over-all impregnated nonwoven fabrics are satisfactory for many
uses, they are still basically unsatisfactory as general purpose
textile fabrics.
Another well-known bonding method is to print the fibrous webs with
intermittent or continuous straight or wavy lines, or areas of
binder extending generally transversely or diagonally across the
web and additionally, if desired, along the fibrous web. The
resulting nonwoven fabric, as exemplified by a product disclosed in
the Goldman U.S. Pat. No. 2,039,312 and sold under the trademark
MASSLINN, is far more satisfactory as a textile fabric than
over-all impregnated webs in that the softness, drape and hand of
the resulting nonwoven fabric more nearly approach those of a woven
or knitted textile fabric.
The printing of the resin binder on these nonwoven webs is usually
in the form of relatively narrow lines, or elongated rectangular,
triangular or square areas, or annular, circular, or elliptical
binder areas which are spaced apart a predetermined distance which,
at its maximum, is preferably slightly less than the average fiber
length of the fibers constituting the web. This is based on the
theory that the individual fibers of the fibrous web should be
bound together in as few places as possible.
The nominal surface coverage of such binder lines or areas will
vary widely depending upon the precise properties and
characteristics of softness, drape, hand and strength which are
desired in the final bonded product. In practice, the nominal
surface coverage can be designed so that it falls within the range
of from about 10% to about 50% of the total surface of the final
product. Within the more commercial aspects of the present
invention, however, nominal surface coverages of from about 12% to
about 40% are preferable.
Such bonding increases the strength of the nonwoven fabric and
retains substantially complete freedom of movement for the
individual fibers whereby the desirable softness, drape and hand
are obtained. This spacing of the binder lines and areas has been
accepted by the industry and it has been deemed necessarily so, if
the stiff and board-like appearance, drape and hand of the over-all
impregnated nonwoven fabrics are to be avoided.
The nonwoven fabrics bonded with such line and area binder patterns
have had the desired softness, drape and hand and have not been
undesirably stiff or board-like. However, such nonwoven fabrics
have also possessed some disadvantages.
For example, the relatively narrow binder lines and realtively
small binder areas of the applicator (usually an engraved print
roll) which are laid down on the fibrous web possess specified
physical dimensions and inter-spatial relationships as they are
initially laid down. Unfortunately, after the binder is laid down
on the wet fibrous web and before it hardens or becomes fixed in
position, it tends to spread, diffuse or migrate whereby its
physical dimensions are increased and its inter-spatial
relationships decreased. And, at the same time, the binder
concentration in the binder area is lowered and rendered less
uniform by the migration of the binder into adjacent fibrous areas.
One of the results of such migration is to make the surface
coverage of the binder areas increase whereby the effect of the
intermittent bonding approaches the effect of the over-all bonding.
As a result, some of the desired softness, drape and hand are lost
and some of the undesired properties of harshness, stiffness and
boardiness are increased.
Various methods have been proposed to prevent or to at least limit
such spreading, diffusing or migration tendencies of such
intermittent binder techniques.
For example, U.S. Pat. No. 3,009,822, issued Nov. 21, 1961 to A. H.
Drelich, et al., discloses the use of a non-migratory regenerated
cellulose viscose binder which is applied in intermittent fashion
to fibrous webs under conditions wherein migration is low and the
concentration of the binder in the binder area is as high as 35% by
weight, based on the weight of the fibers in these binder areas.
Such viscose binder possesses inherently reduced spreading,
diffusing and migrating tendencies, thereby increasing the desired
softness, drape and hand of the resulting nonwoven fabric. This
viscose binder has found acceptance in the industry but the use of
other more versatile binders has always been sought.
Resins, or polymers as they are often referred to herein as
interchangeable terms, are high molecular weight organic compounds
and, as used herein, are of a synthetic or man-made origin. These
synthetic or man-made polymers have a chemical structure which
usually can be represented by a regularly repeating small unit,
referred as a "mer," and are formed usually either by an addition
or a condensation polymerization of one or more monomers. Examples
of addition polymers are the polyvinyl chlorides, the polyvinyl
acetates, the polyacrylic resins, the polyolefins, the synthetic
rubbers, etc. Examples of condensation polymers are the
polyurethanes, the polyamides, the polyesters, etc.
Of all the various techniques employed in carrying out
polymerization reactions, emulsion polymerization is one of the
most commonly used. Emulsion polymerized resins, notably polyvinyl
chlorides, polyvinyl acetates, and polyacrylic resins, are widely
used throughout many industries. Such resins are generally produced
by emulsifying the monomers, stabilizing the monomer emulsion by
the use of various surfactant systems, and then polymerizing the
monomers in the emulsified state to form a stabilized resin
polymer. The resin polymer is usually dispersed in an aqueous
medium as discrete particles of colloidal dimensions (1 to 2
microns diameter or smaller) and is generally termed throughout the
industry as a "resin dispersion," or a "resin emulsion" or
"latex."
Generally, however, the average particle size in the resin
dispersion is in the range of about 0.1 micron (or micrometer)
diameter, with individual particles ranging up to 1 or 2 microns in
diameter and occasionally up to as high as about 3 or 5 microns in
size. The particle sizes of such colloidal resin dispersions vary a
great deal, not only from one resin dispersion to another but even
within one resin dispersion itself.
The amount of resin binder solids in the resin colloidal aqueous
dispersion varies from about 1/10% solids by weight up to about 60%
by weight or even higher solids, generally dependent upon the
nature of the monomers used, the nature of the resulting polymer
resin, the surfactant system employed, and the conditions under
which the polymerization was carried out.
These resin colloidal dispersions, or resin emulsions, or latexes,
may be anionic, non-ionic, or even polyionic and stable dispersions
are available commercially at pH's of from about 2 to about 11.
As will be pointed out in greater detail, such resin dispersions
are used in the present inventive concept at alkaline pH ranges.
Various alkaline reagents, such as ammonia, are therefore added to
bring the pH out of the acid range.
The amount of resin which is applied to the porous or absorbent
material varies within relatively wide limits, depending upon the
resin itself, the nature and character of the porous or absorbent
materials to which the resins are being applied, its intended use,
etc. A general range of from about 4% by weight up to about 50% by
weight, based on the weight of the porous or absorbent material, is
satisfactory under substantially all uses. Within the more
commercial limits, however, a range of from about 10% to about 30%
by weight, based on the weight of the porous or absorbent material,
is preferred.
Such resins have found use in the coating industries for the
coating of woven fabrics, paper and other materials. The resins are
also used as adhesives for laminating materials or for bonding
fibrous webs. These resins have also found wide use as additives in
the manufacture of paper, the printing industry, the decorative
printing of textiles, and in other industries.
In most instances, the resin is colloidally dispersed in water and,
when applied from the aqueous medium to a porous or absorbent sheet
material which contains additional water if carried by the water
until the water is evaporated or otherwise driven off. If it is
desired to place the resin only on the surface of the wet porous or
absorbent sheet material and not to have the resin penetrate into
the porous or absorbent sheet material, such is usually not
possible inasmuch as diffusion takes place between the aqueous
colloidal resin and the water in the porous material. In this way,
the colloidal resin tends to spread into and throughout the porous
material and does not remain merely on its surface.
Or, if it is desired to deposit the resin in a specific
intermittent print pattern, such as is used in bonding nonwoven
fabrics, the aqueous colloid tends to diffuse and to wick along the
individual fibers and to carry the resin with it beyond the
confines of the nominal intermittent print pattern. As a result,
although initially placed on the nonwoven fabric in a specific
intermittent print pattern, the ultimate pattern goes far beyond
that due to the spreading or migration which takes place due to the
diffusion of the water and the resin, until the water is evaporated
or otherwise driven off.
We have discovered new resin binder compositions containing
polymers colloidally dispersed in aqueous media and new methods of
applying such resin binder compositions to porous or absorbent
fibrous materials, whereby the resins are applied in a controlled,
relatively non-migrating manner. If it is desired that the resin be
placed only on the surface of the porous or absorbent material, our
compositions and methods will allow this to be done. Furthermore,
if it is desired that the resin be impregnated throughout the
material, from one surface to the other surface, again, our
composition and method will allow this to be done.
We have now discovered an improved method of controllably
depositing colloidal resin compositions on porous or absorbent
materials whereby spreading, diffusing, and migration of the resin
are controlled and are markedly reduced and wherein the
concentration of the resin in the resin binder area reaches
exceptionally high values in short distances as measured at right
angles to the bond edge. When applied to fibrous webs in the
manufacture of nonwoven fabrics, excellent strength is obtained in
the resulting bonded fabrics along with textile-like softness, hand
and drape.
The improved method involves the use of a resin dispersion which
comprises from about 0.1% to about 60% by weight on a solids basis
of a colloidal synthetic resin, from about 0.05% by weight to about
7% by weight, based on the weight of the colloidal synthetic resin
solids of a water-soluble, polymeric, carboxylic thickener; and
from about 0.01% by weight to about 5% by weight, based on the
weight of the colloidal synthetic resin solids of a metal ammine
complex coordination compound wherein the central metallic atom is
chromium, nickel, zinc, or copper, said colloidal resin dispersion
being stable at alkaline pH's in the presence of an excess of a
complexing substance such as ammonium hydroxide and at certain
concentrations or degrees of dilution but which is unstable at
lesser concentrations or greater degrees of dilution when in the
presence of heavy metal ions such as chromium, nickel, zinc, or
copper.
The synthetic resin may be selected from a relatively large group
of synthetic resins well known in industry for bonding purposes and
may be of a self cross-linking type, externally cross-linking type,
or not cross-linked. Specific examples of such synthetic resins
include: polymers and copolymers of vinyl ethers; vinyl halides
such as plasticized and unplasticized polyvinyl chloride, polyvinyl
chloride-polyvinyl acetate, ethylene-vinyl chloride, etc.; polymers
and copolymers of vinyl esters such as plasticized and
unplasticized polyvinyl acetate, ethylene-vinyl acetate,
acrylic-vinyl acetate, etc.; polymers and copolymers of the
polyacrylic resins such as ethyl acrylate, methyl acrylate, butyl
acrylate, ethylbutyl acrylate, ethyl hexyl acrylate, hydroxyethyl
acrylate, dimethyl amino ethyl acrylate, etc.; polymers and
copolymers of the polymethacrylic resins such as methyl
methacrylate, ethyl methacrylate, isopropyl methacrylate, butyl
methacrylate, etc.; polymers and copolymers of acrylonitrile,
methacrylonitrile, acrylamide, N-isopropyl acrylamide, N-methylol
acrylamide, methacrylamide, etc.; vinylidene polymers and
copolymers, such as polyvinylidene chloride, polyvinylidene
chloride-vinyl chloride, polyvinylidene chloride-ethyl acrylate,
polyvinylidene chloride-vinyl chloride-acrylonitrile, etc.;
polymers and copolymers of polyolefinic resins including
polyethylene, polypropylene, ethylene-vinyl chloride and
ethylene-vinyl acetate which have been listed previously; the
synthetic rubbers such as 1,2-butadiene, 1,3-butadiene,
2-ethyl-1,3-butadiene, high, medium and carboxylated
butadiene-acrylonitrile, butadiene-styrene, chlorinated rubber,
etc., natural latex; the polyurethanes; the polyamides; the
polyesters; the polymers and copolymers of the styrenes including
styrene, 2-methyl styrene, 3-methyl styrene, 4-methyl styrene,
4-ethyl styrene, 4-butyl styrene; natural latex; phenolic
emulsions; etc.
These resins may be used either as homopolymers comprising a single
repeating monomer unit, or they may be used as copolymers
comprising two, three, or more different monomer units which are
arranged in random fashion, or in a definite ordered alternating
fashion, within the polymer chain. Also included within the
inventive concept are the block polymers comprising relatively long
blocks of different monomer units in a polymer chain and graft
polymers comprising chains of one monomer attached to the backbone
of another polymer chain.
As pointed out previously, the compositions and formulations
containing these polymers must be stable at an alkaline pH range of
from about 7 to about 101/2 or even higher which is the range
wherein they are utilized, with preferred pH ranges extending from
about 71/2 to about 10. Such stability is particularly required for
these polymer dispersions, when existing at their normal
concentration levels in the presence of water-soluble polymeric
carboxylic thickeners, and metal ammine complex coordination
compounds, as described herein.
The water soluble polymeric carboxylic thickener may be selected
from a relatively large group of such materials which include, for
example: polyacrylic-acid; polymeric crotonic acid; copolymers of
vinyl acetate and crotonic acid; copolymers of vinyl acetate and
acrylic acid; polyacrylic acid-polyacrylamide copolymers;
polymethacrylic acid; polymethacrylic acid-polyacrylamide
copolymers; carboxymethyl cellulose; carboxyethyl cellulose;
carboxypropyl cellulose; polycarboxymethyl hydroxyethyl cellulose;
alginic acid; polymers of acrylic acid and acrylic acid esters;
polymers of .alpha..beta.-unsaturated carboxylic acids such as
itaconic acid; etc. These water soluble, polymeric, carboxylic
thickeners may be used in their acid forms but normally it is
preferred to use their water soluble neutralized salts, that is,
their sodium, potassium, lithium, ammonium, or like water soluble
salts.
To the emulsion polymerized composition containing the colloidal
resin is added a small amount of from about 0.01% by weight to
about 5% by weight, based on the weight of the synthetic resin
solids, of a metal ammine complex coordination compound wherein the
central metallic atom is chromium, nickel, zinc, or copper.
Examples of metal ammine complex coordination compounds are:
hexammine chromium chloride
[Cr(NH.sub.3).sub.6 ]Cl.sub.3 .H.sub.2 O
pentammine chloro chromium chloride
[Cr(NH.sub.3).sub.5 Cl]Cl.sub.2
hexammine nickel chloride
[Ni(NH.sub.3).sub.6 ]Cl.sub.2
hexammine nickel bromide
[Ni(NH.sub.3).sub.6 ]Br.sub.2
hexammine nickel chlorate
[Ni(NH.sub.3).sub.6 ](ClO.sub.3).sub.2
hexammine nickel iodide
[Ni(NH.sub.3).sub.6 ]I.sub.2
hexammine nickel nitrate
[Ni(NH.sub.3).sub.6 ](NO.sub.3).sub.2
tetrammine zinc carbonate
[Zn(NH.sub.3).sub.4 ]CO.sub.3
tetrammine zinc sulfate
[Zn(NH.sub.3).sub.4 ]SO.sub.4
diammine zinc chloride
[Zn(NH.sub.3).sub.2 ]Cl.sub.2
tetrammine zinc chloride
[Zn(NH.sub.3).sub.4 ]Cl.sub.2
diammine copper acetate
[Cu(NH.sub.3).sub.2 ](C.sub.2 H.sub.3 O.sub.2).sub.2
tetrammine copper sulfate
[Cu(NH.sub.3).sub.4 ]SO.sub.4 .H.sub.2 O
tetrammine copper hydroxide
[Cu(NH.sub.3).sub.4 ](OH).sub.2
The metal ammine complex coordination compound is normally prepared
by chemical reaction between a soluble salt of the metal, such as,
for example, zinc chloride, with an excess of concentrated ammonium
hydroxide, whereby the metal ammine complex coordination compound,
such as, for example, zinc tetrammine chloride, is formed.
The zinc chloride, preferably in an aqueous 70-72% solution, is
slowly dripped into the concentrated ammonium hydroxide (28%
NH.sub.3), with stirring, while the solution is surrounded by
cooling water. The zinc tetrammine chloride forms at once.
The amount of excess ammonium hydroxide should be sufficient to
establish and maintain a pH range of from about 7 to about 10 1/2,
and preferably from about 7 1/2 to about 10, during preparation of
the metal ammine complex coordination compound and during its
formulation into a stable, synthetic resin binder composition.
The amount of excess ammonium hydroxide used in the preparation of
the metal ammine complex coordination compound varies widely and
depends upon many factors such as: the type of resin, thickener,
and surfactant used; the degree of stability desired in the binder
composition; the degree of migrational control required; the degree
of the subsequent water dilution; etc. Under some circumstances,
the excess of ammonia in the metal ammine complex coordination
compound solution may be as low as about 20% on a stoichiometric or
molar basis and may be as high as about 100% excess, or even
higher, as desired or required.
One typical preparation of a metal ammine complex coordination
compound is as follows:
1740 grams of zinc chloride solution (70%) is slowly dripped into
4620 milliliters of concentrated ammonium hydroxide (28% NH.sub.3)
with stirring, while the solution is surrounded by flowing, cooling
water. The zinc tetrammine chloride metal coordination complex
forms at once. The zinc content in the solution is approximately
10%. The reaction is believed to be as follows:
ZnCl.sub.2 + 4NH.sub.4 OH.revreaction.[Zn(NH.sub.3).sub.4 ]
Cl.sub.2 + 4H.sub.2 O
The quantities of zinc chloride and ammonia used herein are 8.94
moles and 68.6 moles, respectively. Inasmuch as four moles of
ammonia are required for each mole of zinc chloride, 35.76 moles of
ammonia are required to react with the 8.94 moles of zinc chloride.
This leaves an excess of 32.84 moles of ammonia in the reaction
solution. As a result, the solution of zinc tetrammine chloride
metal coordination complex is strongly ammoniacal and stable. Its
pH is approximately 10.
A formulated binder composition containing a resin latex, the zinc
tetrammine chloride, a polymeric carboxylic thickener, and the
usual anti-foam agents, pigments, etc., handles normally and easily
until the moment it is applied to the soaked, wet, fibrous web. At
that moment of dilution, the binder thickens suddenly and greatly,
or actually coagulates, thus "freezing" it in place with
substantially no further migration or lateral spreading.
It is believed that, prior to the dilution with water, there is a
stable zinc ammine cation [Zn(NH.sub.3).sub.4 ].sup.+.sup.+ in
solution and that this stable cation has no effect on the other
constituents in the binder composition. However, when dilution
takes place and the water phase is increased, the equilibrium in
the preceding reaction shifts to the left with the formation of the
zinc cation (Zn.sup.+.sup.+), or its hydrated equivalent. It is
believed that this zinc cation reacts with the carboxylic
thickener, causing the formation of an insoluble polymeric gel. In
some way, this insoluble precipitated polymeric gel destabilizes
the latex. And, of course, the reaction is generally similar
between the cation and the surfactant, if it is of the anoinic
type, and/or the resin binder itself, if it contains carboxyl, or
other reaction groups, as described herein.
As defined herein, a metal ammine complex coordination compound is
one of a number of types of metal complex compounds, usually made
by addition of organic or inorganic atoms or groups such as ammonia
(NH.sub.3) to simple inorganic compounds containing the metal atom.
Coordination compounds are therefore essentially compounds to which
atoms or groups are added beyond the number possible of explanation
on the basis of electrovalent linkages, or the usual covalent
linkages, wherein each of the two atoms linked donate one electron
to form the duplet. In the case of the coordination compounds, the
coordinated atoms or groups are linked to the atoms of the
coordination compound, usually by coordinate valences, in which
both the electrons in the bond are furnished by the linked atoms of
the coordinated group.
The colloidal synthetic resin, the water soluble polymeric
carboxylic thickener and the metal ammine complex coordination
compound exist together in a stable emulsion form and normally do
not agglomerate, coagulate or precipitate, as long as the stable
concentration levels of NH.sub.4 OH or degree of dilution are
maintained.
Subsequently, however, when the emulsion is diluted with water to a
sufficiently low concentration of NH.sub.4 OH, the resin
immediately coagulates and agglomerates in place with no further
spreading, diffusion or migration.
It is believed that, when the emulsion is diluted sufficiently, the
metal cation is released from the metal ammine complex coordination
compound and immediately attacks or reacts with the water soluble
polymeric carboxylic thickener causing the resin particles to
agglomerate or coagulate.
It is also believed that the metal ammine complex coordination
compound itself, as exemplified by tetrammine zinc chloride [Zn(NH
.sub.3).sub.4 ]Cl.sub.2, ionizes to the divalent cation
[Zn(NH.sub.3).sub.4 ].sup.+.sup.+ and two anions Cl.sup.-, even in
the presence of high pH, ammoniacal, colloidal latex and water
soluble, polymeric carboxylic thickener. Yet, this complex cation
has no apparent or appreciable effect on the colloidal latex or on
the water soluble, polymeric carboxylic thickener and specifically
does not form an insoluble precipitate with either of them, as
might have been expected.
As stated heretofore, it is further believed that dilution or
otherwise diminishing the ammonium hydroxide content or
concentration of the colloidal dispersion releases the
Zn.sup.+.sup.+ cation and this reacts with and insolubilizes the
polymeric carboxylic thickener. Unexpectedly, however, the
insolubilization of the polymeric carboxylic thickener also causes
the colloidal latex itself to rapidly coagulate, even though the
chemical reaction which takes place does not, insofar as is
presently known, directly involve the latex, or its emulsifying or
stabilizing system, if non-ionic.
Furthermore, methods have been discovered, as described herein to
vary and control this unexpected sequence of chemical and physical
events so as to controllably deposit a colloidal latex on the
surface of, or in, or throughout a porous fibrous substrate. This
method, as stated herein, can be used to very great advantage in
print-bonding nonwoven fabrics or other porous substrates or in
controllably placing and depositing latexes on a porous fibrous
substrate or the like in the textile, paper, leather, and related
industries.
It is also to be appreciated that, when the emulsion is diluted
sufficiently, the metal cation which is released from the metal
ammine complex coordination compound also is capable of attacking
or reacting with any other chemical compounds which are present and
which possess anionic groups, particularly hydroxy, carboxy,
sulfino, sulfo, and like acid groups.
For example, the metal cation which is released immediately attacks
a surfactant system which is anionic and contains surfactants such
as alkyl aromatic sulfonic acids, alkyl sulfonic acids, the
carboxylic acids, and other surfactants such as, for example,
dodecyl benzene sulfonate, octyl benzene sulfonate, hyxyl benzene
sulfonate, octadecyl benzene sulfonate, cetyl sulfonate, hexyl
sulfonate, dodecyl sulfonate, octadecyl sulfonte, and the sodium
and potassium fatty acid soaps containing from 5 to 18 carbon
atoms. Other anionic surfactants include sodium p-1-methyl alkyl
benzene sulfonates in which the alkyl group contains from 10 to 16
carbon atoms, the sodium di-n-alkyl sulfosuccinates in which the
alkyl groups contain from 4 to 12 carbon atoms, the potassium
n-alkyl malonates in which the alkyl group contains from 8 to 18
carbon atoms, the potassium alkyl tricarboxylates in which the
alkyl group contains from 6 to 14 carbon atoms, the alkyl betaines
in which the alkyl group contains from 6 to 14 carbon atoms, the
ether alcohol sulfates, sodium n-alkyl sulfates, containing from 6
to 18 carbon atoms, etc.
The amount of surfactant used may vary from about 0.1% to 5% by
weight of the resin solids dependent on the type resin being
polymerized and the conditions under which it is polymerized.
The specific surfactant which is selected for use in the resin
composition does not relate to the essence of the invention. It is
merely necessary that it possess the necessary properties and
characteristics to carry out its indicated function of stabilizing
the resin composition prior to the time that coagulation and
precipitation of the resin is required. Additionally, in the event
that it is desired that the surfactant assist in or promote the
coagulation and precipitation function, then it must possess the
necessary anionic groups, as described hereinbefore, which are
capable of reaction due to the presence of the metal cations
released from the metal ammine complex coordination compound.
Moreover, the present inventive concept is operative with resins
which have non-ionic or even polyionic emulsifying or stabilizing
systems. The presence of an anionic surfactant system may be
helpful in the controlled coagulation procedures described herein
but it is not necessary or even especially advantageous in many
cases.
The mechanism of instant agglomeration, coagulation and
precipitation of the colloidal resin binder may therefore be
triggered subsequent to dilution by reaction of the metal cation
with either the water soluble, polymeric carboxylic thickener or
the anionic surfactant, or both.
The dilution may be effected in different ways in order to activate
the reaction mechanism. For example, the porous or absorbent
fibrous material may be pre-treated by being pre-wet with a
sufficient quantity of an aqueous medium, preferably water, whereby
the colloidal resin composition immediately becomes sufficiently
diluted. Or, if desired, the colloidal resin composition may be
first printed on the porous or absorbent fibrous material and then
substantially immediately treated with the aqueous medium such as
water to effect the dilution whereupon the colloidal resin
particles substantially immediately agglomerate or coagulate in
place with no further spreading, diffusion or migration.
It is believed that the coagulation and precipitation take place by
dilution alone wherein the NH.sub.3 groups in the metal ammine
complex coordination compound break down and become NH.sub.4 OH in
the excess water being carried by the fibrous web. By this
reaction, the metal cations are released, coagulating and
precipitating the resin. The reaction is believed to be as
follows:
Me(NH.sub.3).sub.x Y+xH.sub.2 O.revreaction.Me(cation)+xNH.sub.4
OH+Y(anion)
wherein Me is a metal such as disclosed herein, x is a whole number
from 2 to 8 (and more commonly 2,4 or 6), and Y is an anion such as
chloride, iodide, bromide, sulfite, sulfate, nitrite, nitrate,
carbonate, acetate, borate, phosphate, citrate, chlorate, oxalate,
etc.
It is to be appreciated that Me and Y normally form compounds, the
formation of which can be explained on the basis of electrovalent
linkages, or the usual covalent linkages, wherein each of the two
atoms linked donate one electron to form the duplet.
It is believed that the addition of the water to the resin
dispersion causes the equilibrium of the reaction mechanism to
shift to the right whereby the metallic cations are released to
bring about the described coagulation and precipitation of the
resin. Lesser amounts of water cause the equilibrium of the
reaction mechanism to move to the left favoring the continued
stability of the metal ammine complex coordination compound and the
resin dispersion.
The amount of the water applied to the fibrous web varies widely,
depending upon many factors, the most important of which is the
nature, concentration, properties and characteristics of the
synthetic resin, the metal ammine complex coordination compound,
and the surfactant system in which they are stabilized. Normally,
the amount of water applied to the fibrous web is in the range of
from about 140% to about 280%, and preferably from about 160% to
about 220%, based on the weight of the fibrous web being treated.
Such amounts are controlled by the use of suitable conventional
vacuum apparatus, nip-rolls, squeeze-rolls, etc.
The amount of water which is applied to the fibrous web prior to
the printing of the resin binder also affects the degree of control
exercised over the coagulation and migration. The greater the
amount of water, the greater is the control and the more rapid is
the coagulation and the less is the migration. On the other hand,
the less the amount of water in the fibrous web, the less is the
control exercised, the less rapid is the coagulation, and the
greater is the migration.
It is also to be realized that the greater the amount of water of
dilution, then the greater is the degree of penetration of the
resin binder into the fibrous web. And, the lesser the amount of
water of dilution, then the lesser is the degree of penetration of
the resin binder into the fibrous web.
The degree of coagulation may be lowered even more and the degree
of migration may be increased by the inclusion in the pre-wetting
water of a small amount of an alkaline or basic material such as
ammonium hydroxide. The pH remains alkaline, just as it does in
other variations of this invention, and the coagulation and
precipitation are purely the result of the dilution.
When printed on a pre-wetted fibrous web during the manufacture of
nonwoven fabrics, the total migration of the resin binder solids
may be reduced to as little as about 50% or less beyond the
originally deposited area. In some instances, the migration is
relatively negligible. Normally, however, the increase in area of
the resin binder solids, even under the most adverse conditions,
does not materially exceed about 200%. Such values are to be
compared to increases in binder migration of at least about 300%
and up to about 800% when emulsion polymerized resins are applied
to fibrous porous absorbent sheet materials, unaided by the
principles disclosed herein.
The concentration of the binder resin solids in the binder area is
correspondingly increased when utilizing the principles of the
present invention and is in the range of from about 50% by weight
to about 120% by weight, and more normally from about 60% to about
80% by weight, based on the weight of the fibers in the binder
area.
The invention will be further illustrated in greater detail by the
following specific examples. It should be understood, however, that
although these examples may describe in particular detail some of
the more specific features of the invention, they are given
primarily for purposes of illustration and the invention in its
broader aspects is not to be construed as limited thereto.
EXAMPLE I
A fibrous card web weighing about 570 grains per square yard and
comprising 100% rayon fibers 11/2 denier and 11/2 inches in length
is intermittently print bonded by the rotogravure process using an
engraved roll having 6 horizontal wavy lines per inch. The width of
each line as measured on the engraved roll is 0.024 inch.
The composition by weight of the resin binder formulation used for
the intermittent print-bonding is:
1. 7 lbs. of a 55% solids latex of Air Reduction Aircoflex 510, a
copolymer of ethylene and vinyl acetate stabilized with a nonionic
surfactant
2. 2 lbs. of water
3. 1 lb. of a 10% solution of a thickening agent, Rohm and Haas
Acrysol 51, a copolymer of acrylic acid and acrylamide. Mol. wt.
375,000 -500,000
4. 50 ml. of a 31% solution of zinc tetrammine chloride metal
coordination complex (sp. gr. 1.13) containing 10% zinc equivalent
or 17.5 grams zinc tetrammine chloride (actual).
Conventional chemical calculations, using the above values, will
establish that there is approximately 0.312 moles of excess ammonia
in the zinc tetrammine chloride solution which is equivalent to
0.069 molar ammonia in the resin binder formulation (approximately
10 lbs. or 4.5 liters) which indicates that there is 0.118% excess
ammonia not tied up in the zinc ammine chloride complex.
The fibrous card web is pretreated or pre-moistened with a large
amount of water to the extent of about 190% moisture based on the
weight of the fibers in the web.
The extra dilution with water is sufficient by itself to upset the
stability of the resin dispersion when applied to the web and it
instantly coagulates and precipitates on the very wet fibrous web.
The printed web is then processed, dried and cured.
The width of the binder line in the finished product is about 0.054
inch which represents a controlled total migration of about 125%.
The surface coverage of the binder is about 32.4%. The percent
binder in the bonded nonwoven fabric is about 17.4%. The
concentration of binder in the binder area is about 54%, based on
the weight of the fibers therein. Such measurements are obtained by
procedures which are described in greater detail in copending
patent application Ser. No. 65,880, filed Aug. 21, 1970.
The resulting nonwoven fabric has excellent strength, excellent
softness, drape and hand, and excellent cross-resilience .
EXAMPLE II
The procedures of Example I are followed substantially as set forth
therein with the exception that 160 grams of American Cyanamid
curing resin CYREZ 933, an aminoform melamine formaldehyde type
external cross-linking agent, is added to the formulation. The
results are good and are generally comparable to those obtained in
Example I, except that this sample has improved wet-abrasion
resistance and very good launder ability. The resulting bonded
nonwoven fabric also finds commercial acceptance.
EXAMPLE III
The procedures of Example II are followed substantially as set
forth therein with the exception that the ethylene-vinyl acetate
copolymer is replaced by 7 pounds of 46% solids latex of Goodrich
2671, a self cross-linking acrylic copolymer containing ethyle
acrylate and acrylonitrile. The results are good and are generally
comparable to those obtained in Example II. The resulting bonded
nonwoven fabric also finds commercial acceptance.
EXAMPLE IV
The procedures of Example II are followed substantially as set
forth therein with the exception that the ethylene-vinyl acetate
copolymer is replaced by 7 pounds of a 55% solids latex of National
Starch Resyn 2345, a copolymer of polyvinyl acetate and an acrylate
containing 10% by weight of di-octyl phthalate plasticizer. The
results are good and are generally comparable to those obtained in
Example II except that this product has good wet-abrasion
resistance and has very good launderability. The resulting bonded
nonwoven fabric also finds commercial acceptance.
EXAMPLE V
The procedures of Example I are followed substantially as set forth
therein with the exception that the ethylene-vinyl acetate
copolymer is replaced by 7 pounds of a 46% solids latex of Goodrich
Geon 576, a plasticized polyvinyl chloride-lower alkyl acrylate
copolymer stabilized with an anionic surfactant. The results are
good and are generally comparable to those obtained in Example I
except that this product has very good heat sealing properties. The
resulting bonded nonwoven fabric also finds commercial
acceptance.
EXAMPLE VI
The procedures of Example I are followed substantially as set forth
therein with the exception that the ethylene-vinyl acetate
copolymer is replaced by 7 pounds of a 50% solids latex of Rohm and
Haas HA-8, a self cross-linking polyethyl acrylate copolymer
stabilized with a non-ionic surfactant. The results are good and
are generally comparable to those obtained in Example I. The
resulting bonded nonwoven fabric also finds commercial acceptance
particularly as a wet wiping cloth.
EXAMPLE VII
The procedures of Example II are followed substantially as set
forth therein with the exception that the thickening agent is 1
pound of a 1% solution of the sodium salt of Hercules
Carboxymethylcellulose 7H3S, having a high degree of polymerization
in excess of about 1000, a high molecular weight in excess of about
200,000, a high viscosity of 900-3,000 centipoises, maximum
viscosity, 1% solution, at 25.degree. C., and a degree of
carboxymethyl substitution in the range of from about 0.65 to about
0.85 D.S. The results are good and are generally comparable to
those obtained in Example II. The resulting bonded nonwoven fabric
also finds commercial acceptance.
EXAMPLE VIII
The procedures of Example II are followed substantially as set
forth therein with the exception that the thickening agent is 1
pound of a 9% solution of the sodium salt of Hercules
Carboxymethylcellulose 7M, having a degree of polymerization in
excess of 500, a medium molecular weight greater than about 70,000,
a medium viscosity 30-100 centipoises, maximum viscosity, 1%
solution, 25.degree.C., and a degree of carboxymethyl substitution
in the range of from about 0.65 to about 0.85 D.S. The results are
good and are generally comparable to those obtained in Example II.
The resulting bonded nonwoven fabric is also commercially
acceptable.
EXAMPLE IX
The procedures of Example II are followed substantially as set
forth therein with the exception that the thickening agent is 1
pound of a 9% solution of the sodium salt of Hercules
Carboxymethylcellulose 12M8, having a medium molecular weight in
excess of about 100,000, a medium viscosity of 400-800 centipoises,
2% solution, 25.degree.C., and a degree of carboxymethyl
substitution in the range of from about 1.2 to about 1.4 D.S. The
results are good and are generally comparable to those obtained in
Example II. The resulting bonded nonwoven fabric finds commercial
acceptance.
EXAMPLE X
The procedures of Example IX are followed substantially as set
forth therein with the exception that 1 pound of a 9% solution of
the sodium salt of Hercules Carboxymethylcellulose 9M8 having a
molelcular weight of about 100,000 is used as the thickening agent.
The results are good and are generally similar to those obtained in
Example IX.
EXAMPLES XI AND XII
The procedures of Example IX are followed substantially as set
forth therein with the exception that the sodium salt of Hercules
Carboxymethylcellulose 7M1 and 7H4 are used. 7M1 has a medium
molecular weight, a medium carboxymethyl substitution of 0.65 -
0.85 D.S., and a low viscosity range in centipoises at 25.degree.
C. of 50 - 100 for a 2% concentration. 7H4 has a high molecular
weight, a medium carboxymethyl substitution of 0.65 - 0.85 D.S.,
and a high viscosity range in centipoises at 25.degree. C. of
2,500-4,500 for a 1% concentration. The results are good and are
generally comparable to those obtained in Example IX. The resulting
bonded nonwoven fabric is acceptable commercially.
EXAMPLE XIII
The procedures of Example II are followed substantially as set
forth therein with the exception that the thickener is the sodium
salt of Hercules Carboxymethylcellulose 7L2, having a low molecular
weight of about 45,000, a degree of polymerization of about 200, a
viscosity range in centipoises at 25.degree. C. of 18 maximum at 2%
concentration. An effect is noted but the results are not
sufficient as to be commercially warranted.
EXAMPLE XIV
The procedures of Example II are followed substantially as set
forth therein with the exception that the thickening agent is 1 1/2
pounds of a 3% solution of the sodium salt of Hercules
Carboxymethylcellulose 4M6, having a medium molecular weight of
about 100,000, a medium viscosity, and a low degree of
carboxymethyl substitution in the range of from about 0.38 to about
0.48 D.S. The results are good and are generally comparable to
those obtained in Example II. The resulting bonded nonwoven fabric
finds commercial acceptance.
EXAMPLE XV
The procedures of Example II are followed substantially as set
forth therein with the exception that the thickening agent is 1
pound of a 10% solution of the sodium salt of Goodyear Carboset 514
polyacrylate copolymer. The results are good and are generally
comparable to those set forth in Example II. The resulting bonded
nonwoven fabric finds commercial acceptance.
EXAMPLE XVI
The procedures of Example II are followed substantially as set
forth therein with the exception that the thickening agent is 1
pound of a 10% solution of a neutralized sodium salt of Rohm and
Haas Acrysol A-5 polyacrylate homopolymer. The results are good and
are generally comparable to those set forth in Example II. The
resulting bonded nonwoven fabric finds commercial acceptance.
EXAMPLE XVII
The procedures of Example II are followed substantially as set
forth therein with the exception that the thickener is 1 pound of a
5% solution of a sodium salt of Kelco Kelgin XL alginate water
soluble, polymeric, carboxylic thickener. The results are good and
are generally comparable to those obtained in Example II. The
resulting bonded nonwoven fabric finds commercial acceptance.
EXAMPLES XVIII AND XIX
The procedures of Example II are followed substantially as set
forth therein with the exception that the 50 milliliters of zinc
tetrammine chloride is: (a) increased to 100 milliliters; and (b)
decreased to 35 milliliters. The results in both cases are good and
are generally comparable to those obtained in Example II. The
resulting bonded nonwoven fabrics are commercially acceptable.
EXAMPLE XX
The procedures of Example II are followed substantially as set
forth therein with the exception that the volume of zinc tetrammine
chloride is increased from 50 milliliters to 100 milliliters and
the amount of Acrysol 51 thickener is increased from 1 lb. to 11/2
lbs. The results are good and are generally comparable to those
obtained in Example II, except that it is noted that practically
all of the resin binder is on one face of the nonwoven fabric
whereby it may be more easily plied to another fabric or to another
material.
EXAMPLES XXI AND XXII
The procedures of Example II are followed substantially as set
forth therein with the exception that the zinc tetrammine chloride
is replaced by an equivalent amount of: (a) zinc tetrammine
sulfate; (b) zinc tetrammine carbonate; and (c) copper diammine
acetate. The results in all three cases are good and are generally
comparable to those obtained in Example II. The resulting bonded
nonwoven fabrics find commercial acceptance.
EXAMPLE XXIII
The procedures of Example II are followed substantially as set
forth therein with the exception that the water soluble polymeric
carboxylated thickener is replaced by succinic acid which is a
dicarboxylic acid. The results are not satisfactory and the use of
succinic acid does not yield commercially acceptable products.
EXAMPLE XXIV
The procedures described in Example I are followed substantially as
set forth therein with the exception that: (1) the carboxylic
thickening agent (Acrysol 51) is omitted; and (2) the synthetic
resin latex (Aircoflex 510) is replaced by a 50% solids synthetic
resin latex of a terpolymer of 46% butadiene, 51% styrene, and 2%
itaconic acid. The zinc tetrammine chloride metal coordination
complex remains the same. The results are inferior to the results
obtained in Example I. The resulting nonwoven fabric has excellent
strength but does not have good softness, drape and hand, or
cross-resilience. At best, it is marginally commercially
acceptable.
EXAMPLE XXV
The procedures described in Example I are followed substantially as
set forth therein with the exception that: (1) the carboxylic
thickening agent (Acrysol 51) is omitted; and (2) the synthetic
resin latex (Aircoflex 510) is replaced by a 50% solids synthetic
resin latex of a terpolymer of 46% butadiene, 51% styrene, and 2%
acrylic acid. The zinc tetrammine chloride metal coordination
complex remains the same. The results are inferior to the results
obtained in Example I. The resulting nonwoven fabric has excellent
strength but does not have good softness, drape and drape, or
cross-resilience. At best, it is marginally commercially
acceptable.
EXAMPLE XXVI
The procedures described in Example I are followed substantially as
set forth therein with the exception that: (1) the carboxylic
thickening agent (Acrysol 51) is omitted; and (2) the synthetic
resin latex (Aircoflex 510) is replaced by a 50% solids synthetic
resin latex of a terpolymer of 46% butadiene, 51% styrene, and a 2%
methacrylic acid. The zinc tetrammine chloride metal coordination
complex remains the same. The results are inferior to the results
obtained in Example I. The resulting nonwoven fabric has excellent
strength but does not have good softness, drape and hand, or
cross-resilience. At best, it is marginally commercially
acceptable.
EXAMPLE XXVII
The procedures described in Example I are followed substantially as
set forth therein with the exception that: (1) the synthetiic resin
latex (Aircoflex 510) is omitted; (2) the added water is increased
from 2 lbs. to 3 lbs.; and (3) 7 lbs. of a 10% solution of the
carboxylic thickening agent (Acrysol 51) is used. The results are
inferior to the results obtained in Example I, particularly insofar
as wet strength is concerned. However, the dry strength, softness,
drape and hand are good. The resulting nonwoven fabric is
commercially acceptable and can be used as a flushable, disposable
facing for a sanitary napkin.
Having now described the invention in specific detail and
exemplified the manner in which it may be carried into practice, it
will be readily apparent to those skilled in the art that
innumerable variations, applications, and extensions of the basic
principles involved may be made without departing from its spirit
and scope.
* * * * *