U.S. patent number 3,864,179 [Application Number 05/344,157] was granted by the patent office on 1975-02-04 for production of metal pattern containing fabric.
Invention is credited to Charles Davidoff.
United States Patent |
3,864,179 |
Davidoff |
February 4, 1975 |
Production of metal pattern containing fabric
Abstract
A flexible fibrous sheet material is provided, the component
fiber units of which are electrically non-conductive and
magnetically non-responsive, said material having discrete areas of
electrically conductive or magnetically responsive patterns in
which the fiber units from one surface through to the corresponding
opposite surface of the material are coated with a film of
electrically conductive or magnetically responsive metal. This
material is useful by way of example only, for decorative purposes,
as a flexible electrical circuit, as a magnetically responsive
article such as one track or multi-track recording tape, as part of
a capacitance circuit, as a convenient electrical contacting lead
and circuit connecting part of a human body to a medical instrument
such as an electrocardiac machine, and the like.
Inventors: |
Davidoff; Charles (Manhasset,
NY) |
Family
ID: |
27363368 |
Appl.
No.: |
05/344,157 |
Filed: |
March 23, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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28912 |
Apr 15, 1970 |
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Current U.S.
Class: |
216/108; 427/272;
174/254; 216/100; 361/751; 361/779 |
Current CPC
Class: |
D06Q
1/04 (20130101); D06M 11/83 (20130101); H01H
1/02 (20130101); H05F 1/02 (20130101); Y10T
428/24917 (20150115); Y10T 428/2481 (20150115); Y10T
428/24736 (20150115); Y10S 428/90 (20130101); Y10S
428/901 (20130101) |
Current International
Class: |
D06Q
1/04 (20060101); D06Q 1/00 (20060101); H05F
1/00 (20060101); H01H 1/02 (20060101); H05F
1/02 (20060101); C23f 001/00 () |
Field of
Search: |
;156/3,8,11,13,16
;117/212,8.5,11 ;204/32 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Van Horn; Charles E.
Assistant Examiner: Kalishman; Neal
Attorney, Agent or Firm: Leavitt; Samson B.
Parent Case Text
This is a division of application Ser. No. 28,912, filed Apr. 15,
1970, now abandoned.
Claims
I claim:
1. A method comprising treating a flexible fabric woven with yarns
composed of electrically non-conductive and magnetically
non-responsive continuous filaments individually coated with a
flexible, substantially uniform and continuous about 1 .times.
10.sup..sup.-6 to 40 .times. 10.sup..sup.-6 inch thick film of
electrically conductive or magnetically responsive metal to remove
the metal film coating from all the filaments in only certain
portions of one surface through to the corresponding opposite
surface of the fabric by treating said certain portions with a
solvent for said metal film coating.
2. A method as defined in claim 1 wherein said treatment is applied
to the metal-coated fabric while it is compressed between solid
plates provided with openings corresponding to said certain
portions whereby said solvent is prevented from contacting the
remaining areas or patterns.
3. A method as defined in claim 2 wherein the surfaces of the solid
plates facing and contacting the fabric are resilient.
4. A method as defined in claim 2 wherein said solvent is an
aqueous alkali metal cyanide solution.
5. A method as defined in claim 4 wherein said filaments comprise
nylon, polyethylene terephthalate, polyacrylonitrile, silk or or
glass.
6. A method as defined in claim 5 wherein said metal is silver,
gold or platinum.
7. A method as defined in claim 6 wherein the surface of the solid
plates facing and contacting the fabric are resilient.
8. A method as defined in claim 4 wherein said filaments comprise
nylon.
9. A method as defined in claim 8 wherein said metal is silver.
10. A method as defined in claim 9 wherein the surface of the solid
plates facing and contacting the fabric are resilient.
Description
This invention relates to flexible fibrous sheet material provided
with metallic electrically conductive or magnetically responsive
elements, and to methods for producing same.
Fabrics of the aforementioned type are of course well known. Such
fabrics can for example be prepared and are available which carry
on one or both surfaces uniform or patterned layers of metal or
metal-containing paint, varnish, lacquer or plastic and are
decorative or useful as magnetic or electrical components such as a
printed circuit or the like. Fabrics are also known which contain
in the weave at intervals or in predetermined designs, metallic
filaments or ribbons serving a particularly desired electrical
function. These and similar products have however not been entirely
satisfactory for a number of reasons including reduced flexibility
inherent in their use of solid continuous metal ribbons, filaments
and layers, filament to filament or yarn to yarn adhesion
preventing free independent relative movement thereof, flaking or
separation of metal or metal-containing layers from the surfaces of
the base fabrics, accelerated breakdown of the metal ribbons,
filaments and layers due to their relatively low fatigue strength
under repeated bending and flexing conditions, inadequate recovery
from deformative forces such as rolling, bending, creasing,
squeezing, denting and crumpling, relatively high cost of making
these products involved in special weaving requirements or large
amounts of metal or the like, unduly high gross weight of these
solid metal-containing products, and the like.
It is an object of this invention to provide a flexible fibrous
sheet material provided with metallic electrically conductive or
magnetically responsive elements which is not subject to one or
more of the above disadvantages of defects. Another object of this
invention is the provision of such a material which is
substantially uniformly flexible regardless of the presence and/or
location of the said metallic elements therein. Still another
object is the provision of such a material which has a flexibility,
drape, handle, feel, weight, and/or fatigue resistance
substantially similar to the same material devoid of such metallic
elements. A further object of this invention is the provision of
such a material in which said metallic elements have improved
properties with respect to permanence, resistance to fatigue,
recovery from deformative forces, electrical conductivity, and/or
magnetic response and the like. A still further object of this
invention is the provision of such a material which is relatively
economical and simple to make. Yet a further object is the
provision of methods for preparing such material. Other objects and
advantages will appear as the description proceeds.
The attainment of the above objects is made possible by this
invention which includes the provision of flexible fibrous sheet
material, the component fiber units of which are electrically
non-conductive and magnetically non-responsive, said material
having discrete areas or patterns in which the fiber units from one
surface through to the corresponding opposite surface are coated
with a film of electrically conductive or magnetically responsive
metal. More particularly, the aforedescribed material of my
invention possesses all or substantially all the characteristics
referred to in the preceding paragraph as constituted the objects
of such invention.
The component flexible fiber units of the fibrous sheet material
employed in this invention may comprise, consist of, or be
constituted by any fiber-forming or filament forming substance
which is electrically non-conductive and magnetically
non-responsive. The substance may be natural or synthetic, organic
or inorganic monopolymeric, copolymeric (from two or more
monomers), or mixtures of two or more prepolymerized monomers,
admixed where desired with usual assistants, modifiers, softeners,
plasticizers, colors, stabilizers, fillers, and the like. As
examples of such fibrous substances, there may be mentioned silk,
non-alkaline, boro-silicate and other silica glasses; filaments of
synthetic organic polymers, copolymers and mixed polymers such as
polyvinyl chloride, polyvinylidene chloride, vinyl chloridevinyl
acetate copolymer, polyolefins such as polyethylene and
polypropylene, polyacrylonitrile, modacrylics, acrylic and
methacrylic acids and their methyl, ethyl esters, polyesters such
as polyethylene terephthalate, polyurethanes such as spandex,
linear superpolyamides such as nylon and polypyrrolidone, and
mixtures and copolymers of the foregoing. A number of such fibers,
filaments, and fabrics are commercially available as for example
Vinyon, Saran, Velon, Dynel, Acrilan, Orlon, Dacron, and Terylene
and the like.
The term "fiber unit" is intended to include the individual fibers
and filaments, in addition to yarns, twisted and untwisted bundles
of such fibers and filaments, all of which are used in forming the
flexible fibrous sheet material employed herein. The sheet material
may be fabricated in any desired manner as by weaving, knitting,
and the like, and may of course include mixtures of fibers,
filaments, yarns, and the like of differing polymeric basis as
described above. The component fiber units may likewise comprise
similar mixtures.
The fibers, filaments, component fiber units and sheet material
containing which are employed in this invention are those well
known and commercially available. Their structures, properties,
chemical compositions, and the like are not critical and per se
form no part of this invention. For example, the fibers and
filaments may have any desired size and shape permitting the
flexibility usual in such materials. They may have cross-sectional
shapes which are symmetrical or unsymmetrical, circular,
elliptical, flat, triangular, polygonal, multilobar, and the like,
and range in thickness or diameter from about 0.5 denier or less to
10 denier or more, or from about 1 micron or less to 40 microns or
more. They may be continuous filaments and the twisted or untwisted
yarns or bundles containing them may comprise any number such as
from 2 to 150 filaments or more in a cross-section, and range from
20 denier or less to 200 denier or more. Material fabricated from
yarns and the like may have any desired knitted construction or
weave such as plain, rip stop, twill, leno, and the like, and may
have an open construction or relatively closed, dense construction,
with a weight range for example of from about 0.1 oz. to 1 or more
pounds per square yard, generally about 0.5 to 10 oz. per square
yard, and preferably a relatively light weight close weave of about
1/2 to 3 oz. per square yard.
For most purposes contemplated herein, and for the desired
properties of flexibility, durability, strength, weight, and
metallization, woven fabrics made for continuous filament yarns
having a basis of polyester, polyacrylonitrile, silk, glass, and
optimally nylon, are preferred for use herein. In these fabrics, as
in any of the other above described types of flexible fibrous sheet
material employed herein, the component flexible fiber units are,
as commonly available, substantially entirely unattached to, and
free to move, roll or slide relative to the adjacent fiber units.
Stated otherwise, the component fibers, filaments, yarns and the
like in the material can move independently of each other, since
they are not bonded or attached to each other by any means at their
points of contact or intersection, being only constrained by the
nature of the fiber unit structure or weave.
In accordance with this invention, the above-described flexible
fibrous sheet material, the component fiber units of which are
electrically non-conductive and magnetically non-responsive, is
provided with discrete areas or patterns in which the fiber units
from one surface through to the corresponding opposite surface of
the material are coated with a film of electrically conductive or
magnetically responsive metal. To retain the flexibility, feel,
handle, and fatigue strength, and the like, of the product
substantially uniform in both the coated and uncoated areas, the
thickness of the continuous metal film is relatively small, such as
from about 1 .times. 10.sup..sup.-6 to 40 .times. 10.sup..sup.-6
inches, preferably about 2 .times. 10.sup..sup.-6 to 6 .times.
10.sup..sup.-6 inches. Like the uncoated fiber units, the
metal-coated fiber units are substantially entirely unattached to
each other and are free to move, roll orslide independently of each
other. The metal-containing patterns in the products of this
invention are independent of the construction of the fibrous sheet
material, i.e. whether it is knitted or woven, the direction, size
or shape of the fiber units, etc. Otherwise stated, the lines of
demarcation separating the metal-containing patterns or areas from
the uncoated insulative portions of the material in substantially
all instances cross fiber units whereby one segment or more of the
crossed fiber, filament, yarn, etc. is coated with a film of the
metal and lies within the metal-containing pattern, and the other
segment of the same fiber unit is uncoated and lies outside said
pattern and within the insulative portions.
The metal coating or film may comprise any normally solid
film-forming metal since substantially all such metals have
electroconductive or magnetically responsive properties to some
degree. Thus, the metal may for example be silver, gold, platinum,
palladium, copper, aluminum, nickle, cobalt, iron, titanium,
molybdenum, chromium, tungsten, lead, tin, zinc, cadmium,
manganese, antimony, germanium, indium, rhenium, ruthenium,
rhodium, selenium, rare metals, and the like, and mixtures and
alloys of any two or more thereof. In general, iron, cobalt, and
nickle, and mixtures and alloys thereof, are preferred for magnetic
properties, and gold, platinum, palladium, aluminum, copper, and
especially silver, and mixtures and alloys thereof, are preferred
for electroconductivity.
Several methods may be employed for making the metallized
pattern-containing flexible fibrous sheet material of the present
invention. The preferred method herein comprises removing the metal
film coating from fiber units in only certain portions of one
surface through to the corresponding opposite surface of a flexible
fibrous sheet material, the component fiber units of which are
electrically non-conductive and magnetically non-responsive and are
coated with a continuous film of electrically conductive or
magnetically responsive metal.
The foregoing method involves the use as a starting material of a
flexible fibrous sheet material corresponding overall to the
desired discrete metallized areas or patterns, i.e. in which all
the component electrically non-conductive, magnetically
non-responsive fiber units are coated with a continuous film of
electrically conductive or magnetically responsive metal as
described above. Such starting material, having electrical
resistive values of about 0.01 to 500 ohms per square, and
preferably about 0.5 to 5 ohms per square for optimum
electroconductive purposes, is well known and commercially
available. It may be prepared by methods which are also well known
and disclosed in a number of patents and other publications,
generally involving metallization treatment in known manner of an
electrically non-conductive, magnetically non-responsive flexible
fibrous sheet material to deposit the desired continuous metal film
on the individual fiber units, or similar treatment of the
component fiber units followed by fabricating the resulting
metal-coated fiber units into a flexible fibrous sheet
material.
Illustratively, reference is made to U.S. Pats. Nos. 2,511,472,
2,867,552, 2,896,570, 2,897,091, and 3,043,769 for disclosures of
such metallization treatments of electrically non-conductive,
magnetically non-responsive fibers, filaments, yarns, and fabrics.
The surface metallization treatments disclosed in U.S. Pat. Nos.
2,862,783 and 3,014,818 may also be employed, but only for
metallizing electrically non-conductive, magnetically
non-responsive fiber units, and not the metal-containing fiber
units disclosed in these latter patents. In general, these
metallization treatments involve reduction of one or a mixture of
salts or other reducible compounds of the selected metal ormetals,
as deposited from an aqueous or organic solution thereof, in situ
on the surface of the fiber unit or "gas plating" in which one or a
mixture of heat-decomposable gaseous compounds of the selected
metal or metals is thermally decomposed in situ on the surface of
the fiber unit.
The removal of the metal film from the fiber units in those
portions of the sheet material intended to be insulative, i.e.
those portions other than the discrete areas or patterns in which
the fiber units are metal-coated, is carried out by selectively
treating such portions with a fluid which is a solvent for the
metal. The particular fluid solvent employed in any specific
instance will of course depend mainly on the metal to be removed or
dissolved. Such solvents or metal strippers are generally liquid
and inorganic, optionally with additives which may be organic, and
are well known and commercially available. Routine reference to
standard texts and literature sources will establish those
operative for the specific metal to be removed, as for example the
metal strippers and procedures described in the chapter entitled
"Stripping Metallic Coatings" pages 507 to 517 of "Metal Finishing
Guide Book 1968" published by Metals and Plastics Publications,
Westwood, New Jersey, which disclosure is incorporated herein by
reference thereto. In general, acids are operative as such solvents
but for obvious reasons must be selected according to the metal to
be removed. Thus, dilute nitric acid dissolves silver, copper,
cobalt, iron and nickle; hot or concentrated sulfuric acid
dissolves silver, copper, cobalt, aluminum, and palladium; and aqua
regia dissolves gold and platinum.
The duration and temperature of the metal solvent treatment will of
course depend on the thickness of the metal film on the fiber units
being treated. Generally, temperatures from room temperature to
about 90.degree.C. may be employed, higher temperatures in this
range generally serving to accelerate the solvation process. For
practical purposes, the duration should not exceed about 30 minutes
in any particular instance, but should for most purposes be stopped
when all the metal in the insulative portions has been dissolved.
This is particularly important where the solvent, after removal of
the metal film, will then proceed to attack the freshly exposed
surfaces of the fiber units themselves, unless of course such
attack is unobjectionable or even desired to the point of total
destruction for certain usages.
Since for most purposes solvent attack on the fiber units per se is
to avoided, and such attack on certain fibers by acids is often
difficult to control, it is preferred to employ as the metal
solvent or stripper an alkali metal, e.g. sodium or potassium,
cyanide generally in the form of an aqueous solution ranging in
concentration from about 0.5 to 10% by weight. Certain known
assistants such as hydrogen peroxide, m-nitrobenzoic acid, sodium
m-nitrobenzenesulfonate and the like, may also be added to the
cyanide solution, generally in concentrations of about 0.1 to 10%
by weight. The solvation process may be further expedited with
respect to certain metals such as platinum and palladium by
concurrent mild electrolytic action, as by connecting the portions
of the metal coated fibrous material in contact with the solvent to
a source of low voltage DC current, in a conductive, corrosion
resistant metal tank connected also to the same source of low
voltage DC current. It has been found that the above-described
alkali metal cyanide metal stripping solutions are highly
advantageous in expeditiously removing the metal film without undue
deleterious effect on the fiber units per se under the usual
solvent treatment conditions of temperature and duration.
Following are illustrative examples of some metal solvent or metal
stripping solutions which may be employed in making the products of
this invention as described above:
EXAMPLE A
NaCN or KCN -- 1 oz.
Water to make 1 gal.
Applied at 90.degree.-180.degree.F.
EXAMPLE B
NaCN or KCN -- 50 grams
Water to make 1 liter
Applied at 70.degree.-160.degree.F.
EXAMPLE C
NaCN or KCN -- 1 oz.
H.sub.2 o.sub.2 (30% conc.) -- 0.5% by volume
Water to make 1 gal.
Applied at 70.degree.-160.degree.F.
EXAMPLE D
NaCN or KCN -- 1 oz.
H.sub.2 o.sub.2 (30% conc.) -- 3% by volume
Water to make 1 gal.
Applied at room temperature to 70.degree.-160.degree.F.
EXAMPLE E
NaCN or KCN -- 50 grams
M-nitrobenzoic acid -- 50 grams
Water to make 1 liter
Applied at 50.degree.-70.degree.C.
EXAMPLE F
NaCN or KCN -- 50 grams
Sodium m-nitrobenzene sulfonate -- 50 grams
Water to make 1 liter
Applied at 50.degree.-70.degree.C.
The selective treatment of certain portions of the starting fibrous
sheet material containing metal-coated fiber units with the metal
stripping solvent so as to dissolve the metal only in such portions
may be carried out in a number of ways, and by batch or continuous
manner. For example, this objective may be accomplished by
subjecting such portions to the action of a direct stream, jet or
spray of the metal stripping solvent for a time sufficient to
dissolve out the metal in said portions, preferably followed by a
wash or rinse of such portions or of the entire material with water
to remove all traces of metal compound, dissolved metal and metal
stripping solvent. Complete removal can be established when such
portions are determined by suitable electrical instruments or
meters to be non-conductive.
According to another method, the treatment with the metal stripping
solvent is confined to such certain portions by first providing the
metal-coated fiber units in the remaining areas or patterns of the
fibrous sheet material with a coating resistant to the action of
said metal-stripping solvent, which latter coating is then
preferably removed following said treatment.
The resistant protective coatings must be applied so as to coat the
metal-coated fiber units in the areas or patterns desired to remain
electrically conductive or magnetically responsive from one surface
through to the corresponding opposite surface of the material. The
metal stripping solvent can then be applied to the entire sheet
material, as by dipping or the like, whereby the metal in the
remaining unprotected portions of the material is dissolved and
removed. If the metallized areas or patterns are required to be
exposed, as in uses involving electrical contact with the surfaces
thereof, the resistant protective coating is then removed as by
treatment, by dipping or otherwise, with one or more volatile
solvents.
According to a preferred method for the selective treatment of
certain portions of the starting metallized fibrous material with
the metal stripping solvent so as to dissolve the metal only in
such portions, said treatment is applied to said starting material
while it is compressed between solid plates provided with matching
openings corresponding to such certain portions. The metal
stripping solvent is thereby confined to, and can only contact,
such portions of the material and is prevented by the plates from
contacting the remaining areas or patterns required to remain
metallized. The plates are preferably of rigid material resistant
to the action of the metal stripping solvent such as steel, glass,
plastic or the like, and provided with clamps or other means for
tightly compressing the metallized fibrous material therebetween to
minimize any possibility of seepage of said solvent edgewise into
the portions of the compressed fibrous material adjacent the slots
and outside edges of the plates. As further means for preventing
such seepage, the inner surface of the plates contacting the
compressed fibrous material are preferably resilient, as by being
provided with thin layers of resilient synthetic rubber or closed
foam plastic serving as gaskets. The entire assembly is then
submerged in a bath of the metal stripping solvent, such as in
Examples A-F above, until all the metal coating in the portions of
the fibrous materiall exposed in the slots is dissolved. The
assembly is then removed from the metal stripping bath, thoroughly
washed with water and unclamped or dismantled.
The products of this invention are obviously useful for many
electrical and magnetic purposes. Thus, the areas or patterns
therein containing metal coated fiber units may define at least
part of an electrically conductive circuit, or at least part of a
capacitance circuit, or an antenna or dipole, or magnetically
responsive elements or the like. Their peculiarly advantageous
properties as described above render these products suitable for a
number of novel uses. Thus, where the metallized pattern is in the
form of an antenna of varying geometry such as a dipole or the
like, the product can be invisibly incorporated into the lining of
a curtain for location identification, or into the lining, label or
other part of clothing apparel for discrete shoplifter
identification as at the exits of clothing stores. The metallized
patterns may be a series of separated 1 inch squares whereby the
product can serve as part of a flexible invisible capacitance
circuit. The product with a pattern in the form of a band or series
of bands of electroconductive metal coated fiber units may
constitute a convenient, confortable contact lead connecting part
of a human body to a medical instrument such as an electrocardiac
machine. Or it may serve as an electrical circuit incorporated into
a performer's costume such as a dancer's skirt which could be
electrified for low voltage lighting. Or it may serve as an
electrical connection at the end of a flexible banner such as a
fluttering, waving flag. Patterns in the form of parallel bands of
magnetically responsive metal coating fiber units permit use as a
novel type of multi-track recording tape.
The following examples are only illustrative of preferred
embodiments of my invention and arenot to be regarded as
limitative.
EXAMPLE I
A 3 1/2inch wide by 12 inch long sample of nylon cloth weighing 1
oz. per square yard and composed of 40 denier yarns of continuous
filaments coated with a 2-5 .times. 10.sup..sup.-6 inch thick film
of silver is tightly clamped between two 3 1/2 .times. 12 inch
rigid steel plates each provided with three matching 1/2 inch wide
by 11 1/2inch long slots or openings spaced equally across the
width and length of the plates. The unslotted inside surfaces of
the plates adjacent the compressed cloth are each provided with a 5
mil thick layer of neoprene rubber acting as a gasket preventing
seepage of metal stripping solvent edgewise between the plates into
the areas of compressed cloth adjacent the open slots and outer
edges of the plates.
The entire clamped assembly is then submerged into a KCN metal
stripping bath as in Example A above at about 120.degree. F. for
about 4 minutes with agitation of the bath and/or assembly until
all the silver coating in the portions of the cloth exposed in the
slotted openings is removed by dissolution.
The assembly is then removed from the bath, thoroughly washed with
watter and unclamped or dismantled. The product corresponds to the
starting silvered cloth except for three equally spaced 1/2 inch
wide by 11 1/2inch long desilvered electrically non-conductive
bands corresponding to the slots in the plates. The 1/4 .times.3
1/2 inch strip of silvered cloth between the ends of the
non-conductive bands and the edges at each end of the cloth is cut
away, leaving a pattern of four parallel 1/2 inch wide silvered
electrically conductive bands insulated from each other by the
three desilvered bands. If desired, the plates could be so
constructed as to directly produce the same banded article without
requiring subsequent cutting away of the two ends.
The article as produced above may be employed as part of an
electrical circuit, for example as a human contact lead connected
to an electrocardiac or other medical instrument, or as a feed or
control component of an electronic information storage or retrieval
machine. In the above mentioned use as a human contact lead, the
said article provides the warm, non-metallic feel of a soft,
comfortable bandage as opposed to the cold, relatively rigid metal
cable leads presently used. A similar article containing iron,
nickel and/or cobalt instead of silver is useful as a flexible
magnetic recording tape or other recording component of a magnetic
memory device.
The foregoing description and working example are concerned with a
generally preferred method of producing the metallized
pattern-containing products of this invention involving selective
removal of the metal film coating from certain portions of a
fibrous sheet material in which all the fiber units are coated with
a metal film. The reverse procedure may also be employed for making
the products of my invention, involving direct metallization of
discrete areas or patterns of an unmetallized fibrous sheet
material.
More particularly, such direct metallizing method comprises
coating, with a substantially continuous film of electrically
conductive or magnetically responsive metal, the fiber units from
one surface through to the corresponding opposite surface in
discrete areas or patterns of a flexible fibrous sheet material,
the component fiber units of which are electrically non-conductive
and magnetically non-responsive. This method obviously avoids a
metal stripping step as described above.
Confinement of the direct metallizing treatment to the desired
discrete areas or patterns may preferably be accomplished along the
lines illustrated in Example I above, for example by compressing a
similar but unmetallized sample of nylon cloth between the same
slotted plates, and then subjecting the entire assembly to any
known metallization treatment as described above, such as by
reduction of one or a mixture of salts or other reducible compounds
of the selected metal ormetals on an aqueous or organic solution
thereof, or preferably by "gas plating," i.e. by thermally
decomposing one or a mixture of heat-decomposable gaseous compounds
of the selected metal or metals in situ on the surfaces of the
fiber units in the exposed slotted areas of the assembly.
References in the foregoing descriptions to the metal film coatings
in the discrete areas or patterns of the products of this invention
as continuous or substantially continuous will be understood as
including coatings at least sufficient to provide an uninterrupted
electrically conductive metal path along the length of the fiber
unit. In most instances, the film forms a continuous coating on the
entire surface of the fiber unit except for minute holes, cracks,
etc. inherent in the metallization process. A relatively thin metal
film is necessary to maintain flexibility and avoid the cracking,
breaking and other permanent deformational effects to which thicker
metal films and solid metal filaments (including wires) and layers
are prone.
As illustrative of a further utility of products of the type
produced in Example I above, such products can be adapted for use
as and/or in place of electrically conductive components of
pressure operable switches disclosed and claimed in U.S. Pat. Nos.
3,056,005 and 3,308,253.
This invention has been disclosed with respect to certain preferred
embodiments and it will be understood that various modifications
and variations thereof will become obvious to persons of ordinary
skill in this art which are to be included within the spirit and
purview of this application and the scope of the appended
claims.
* * * * *