U.S. patent number 3,855,012 [Application Number 05/402,127] was granted by the patent office on 1974-12-17 for processing copper base alloys.
This patent grant is currently assigned to Olin Corporation. Invention is credited to Ronald N. Caron, Stanley Shapiro.
United States Patent |
3,855,012 |
Shapiro , et al. |
December 17, 1974 |
PROCESSING COPPER BASE ALLOYS
Abstract
Processing copper alloys to obtain an improved combination of
yield strength and elongation. The process is characterized by cold
rolling with interpass heat treatments to a total reduction of at
least 70%, followed by a final heat treatment under specified
conditions.
Inventors: |
Shapiro; Stanley (New Haven,
CT), Caron; Ronald N. (Branford, CT) |
Assignee: |
Olin Corporation (New Haven,
CT)
|
Family
ID: |
23590643 |
Appl.
No.: |
05/402,127 |
Filed: |
October 1, 1973 |
Current U.S.
Class: |
148/681;
148/684 |
Current CPC
Class: |
C22F
1/08 (20130101) |
Current International
Class: |
C22F
1/08 (20060101); C22f 001/08 () |
Field of
Search: |
;148/11.5R |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Stallard; W.
Attorney, Agent or Firm: Jackson; David A. Bachman; Robert
H.
Claims
What is claimed is:
1. A method for improved yield strength characteristics in copper
or copper base alloys which comprises:
A. providing a copper base alloy selected from the group consisting
of the phosphor bronzes and copper alloys containing from 1-5%
iron, in plate form having a thickness of from 0.300 to 1.800
inches;
B. cold rolling said material in at least three cold rolling cycles
to a total reduction of at least 70% with an intermediate heat
treatment of from 100.degree. to 350.degree.C for from 1 to 4 hours
between each cold rolling cycle, provided that the rolling
reduction in each cold rolling cycle is at least 25% and
C. subjecting said material to a final heat treatment after the
last cold rolling cycle, said final heat treatment being at
100.degree. to 350.degree.C for from 30 minutes to 8 hours.
2. A method according to claim 1 wherein the total reduction in
step (B) is at least 85%.
3. A method according to claim 2 wherein step (B) includes four
cold rolling cycles with three intermediate heat treatment
cycles.
4. A method according to claim 1 wherein the starting material in
step (A) is provided by hot rolling an ingot to plate form having a
thickness of from 0.300 to 1.800 inches.
5. A method according to claim 2 wherein said copper alloy contains
iron in an amount of from 1 to 5%.
6. A method according to claim 1 wherein said starting material is
a copper base alloy ingot which is cold rolled to plate thickness.
Description
BACKGROUND OF THE INVENTION
The process of the present invention is concerned with treating
copper base alloys in order to obtain an improved combination of
yield strength characteristics and elongation.
Since most engineering components, springs in particular, must
operate in the elastic regime, information regarding the onset of
plastic flow in metal systems has long been one of the most
important engineering design criteria. The mechanical property of
great interest in this region is the elastic limit. However, there
are practical difficulties in determining the elastic limit with
information from the engineering tensile test. Since the elastic
limit can be as much as 10-15 ksi greater than the proportional
limit, which is the stress at which the stress-strain curve becomes
nonlinear in the elastic regime, determination of the elastic limit
would require that each tensile specimen be alternatively loaded
and unloaded to increasingly higher loads until that load is
reached which produces a permanent set in the specimen.
However, the 0.01% offset yield strength approximates and is
frequently used in place of the elastic limit in spring design.
Thus, for engineering applications in which little or no plastic
flow can be tolerated an enhanced 0.01% offset yield strength would
lead to improved materials utilization and performance.
Accordingly, it is a principal object of the present invention to
provide a process for obtaining improved yield strength
characteristics in copper base alloys, particularly high 0.01%
offset yield strength.
It is a further object of the present invention to provide a
process as aforesaid which obtains an improved combination of 0.01%
offset yield strength and percent elongation.
A further object of the present invention is to provide a process
as aforesaid which is suitable for manufacturing parts while
allowing retention of the desired high yield strength
properties.
A further object of the present invention is to provide a process
as aforesaid which is simple, inexpensive, easily practiced
commercially and versatile.
Further objects and advantages of the present invention will appear
hereinbelow.
SUMMARY OF THE INVENTION
In accordance with the process of the present invention it has been
found that the foregoing objects and advantages may be readily
obtained. The process of the present invention comprises:
A. providing a copper or copper base alloy material in plate form
having a thickness of from 0.300 inch to 1,800 inch;
B. cold rolling said material in at least three cold rolling cycles
to a total reduction of at least 70% and preferably at least 85%,
with an intermediate heat treatment between each cold rolling cycle
of from 100.degree. to 350.degree.C for from 1 to 4 hours, provided
that the rolling reduction in each cold rolling cycle is at least
25%; and
C. subjecting said material to a final heat treatment after the
last cold rolling cycle, said final heat treatment being at a
temperature of from 100.degree. to 350.degree.C for from 30 minutes
to 8 hours.
The starting plate material may use a variety of materials, such as
hot rolled plate, fully recrystallized plate or continuously cast
plate.
The material produced in accordance with the process of the present
invention may be utilized to manufacture parts. When the part is
manufactured, the yield strength properties fall off due to the
cold work which is given to the part as a result of the forming
operation. Therefore, a further thermal treatment may be performed
on the formed part at a temperature of from 100.degree. to
350.degree.C for from 30 minutes to 8 hours in order to restore the
desirable high 0.01% offset yield strength.
The process of the present invention readily obtains high 0.01%
offset yield strength in copper base alloys in combination with
good elongation. Furthermore, it can be seen that the process is
simple and easy to perform and inexpensive in a commercial
operation.
Further advantages of the instant process will appear
hereinbelow.
DETAILED DESCRIPTION
The process of the present invention, as indicated hereinabove, may
be readily utilized with any copper or copper base alloy material.
Thus, commercial purity or pure copper may be readily employed. A
particularly suitable series of copper alloys for use in the
process of the present invention are the phosphor bronzes, which
are copper base alloys containing from 1 to 10% tin, such as CDA
copper alloy No. 505, 510, 521 and 524. In addition, the iron
containing copper alloys containing from 1 to 5% iron may be
readily utilized, such as CDA copper alloy 194 and 195. In addition
the nickel-silvers are desirably suitable for use in the process of
the present invention. These alloys are copper base alloys
containing from about 10 to 20% nickel and from about 5 to 40%
zinc, such as CDA copper alloy No. 762, 752, and 745. A further
series of copper alloys which may be desirably utilized include the
aluminum-bronzes and brasses containing from 2 to 13% aluminum,
such as CDA copper alloy 638 and 688. Naturally, many other copper
alloys may be desirably utilized in the process of the present
invention. Generally, any copper base alloy may be conveniently
utilized, such as: The CDA 2XX series, brasses containing from
about 5 to 40% zinc; copper alloys containing beryllium; the CDA
4XX series, tin brasses containing tin and zinc; silicon-bronzes;
manganese-zinc containing copper alloys as CDA alloys 669 and 672;
and cupronickels containing from about 5 to 35% nickel as CDA
alloys 706 and 715.
The starting material should be a copper or copper base alloy
material in plate form having a thickness of from 0.300 inch to
1.800 inches. The plate material may be obtained by any desired
method. For example, one may start from a copper base alloy ingot
which is hot or cold rolled to plate thickness. The cold rolled
plate may then be annealed to the fully recrystallized condition.
Alternatively, one may provide a continuously cast copper base
alloy plate as starting material.
The process of the present invention cold rolls the plate material
in at least three cold rolling cycles to a total reduction of at
least 70%, with an intermediate heat treatment of from 100 to
350.degree.C for from 1 to 4 hours between each cold rolling cycle.
The rolling reduction in each cold rolling cycle should be at least
25% and the total reduction in all cold rolling cycles is
preferably greater than 85%. Thus, one may have the following
sequence: cold reduction; heat treatment; cold reduction; heat
treatment; and cold reduction. Alternatively, one may desirably
utilize four cold rolling cycles with three intermediate heat
treatment steps.
Following the final cold reduction step, the material may be
subjected to a final low temperature heat treatment at final gage.
This heat treatment step should be for from 30 minutes to 8 hours
at a temperature of from 100 to 350.degree.C.
In the heat treatment steps generally longer times are used with
lower temperatures.
It is a particular advantage of the process of the present
invention that parts may be readily formed from the thermally
treated strip. We have found that formed parts may lose a portion
of the desirably high yield properties due to the cold work which
they have been subjected to. In order to restore the high yield
properties, the formed parts may be given a further low thermal
temperature treatment of from 30 minutes to 8 hours at temperatures
between 800.degree.C and 350.degree.C.
In the heat treatment steps generally longer times are used with
lower temperatures.
In addition to imparting improved 0.01% offset yield strength, the
process of the present invention also obtains numerous advantages.
The material of the present invention retains the finely structured
cold worked matrix. In addition, the process of the present
invention maintains and strengthens the deformation texture,
resulting in improved texture strengthening of the sheet and formed
part. Still further, the process of the present invention allows
sufficient recovery of ductibility at a marginal strength loss in
order to enhance cold rollability for the additional cold rolling
steps and for subsequent forming of the final material.
The process of the present invention and advantages obtained
thereby may be readily understood from a consideration of the
following illustrative examples.
EXAMPLES
A copper base alloy ingot was provided having the following
composition: tin, 4.4%; phosphorus, 0.07%; balance essentially
copper. The ingot was initially hot rolled and milled to 0.450 inch
gage and was processed to 0.010 inch gage utilizing the processing
schedules A and B set forth below.
Process schedule A involved cold rolling the material 97.8%
directly to 0.010 inch gage. This was done for comparative purposes
and does not represent the process of the present invention.
Process schedule B involved a total reduction of 97.8% to 0.010
inch gage and utilized four cold rolling cycles with three in
process heat treatment steps as follows: cold roll 90.0% to 0.045
inch, heat treat for 2 hours at 250.degree.C, cold roll 40.0% to
0.027 inch, heat treat for 2 hours at 250.degree.C, cold roll 40.8%
to 0.016 inch, heat treat for 2 hours at 250.degree.C and finally
cold roll 37.5% to the final gage of 0.010 inch. Thus, the total
reduction and final gage are the same for process schedules A and
B.
Tensile properties were determined for the longitudinal and
transverse sheet orientations for the material obtained by the two
foregoing processing schedules. The properties for process schedule
A are listed in Table I, while those for process schedule B are
presented in Table II. The properties of the as-cold rolled
condition are identified in the tables by the designation CR.
Properties were also determined on cold rolled material subjected
to a final low temperature heat treatment for a period of 2 hours
at temperatures 200.degree., 250.degree., 275.degree. or
300.degree.C. These heat treated properties are also presented in
Tables I and II.
Comparisons of the tensile properties of the material obtained by
process schedule A with those obtained by process schedule B show
the improvement of the final heat treated 0.01% offset yield
strength obtainable with the process schedule of the present
invention. Furthermore, when compared at equivalent 0.01% offset
yield strengths, the percent elongation values of material
processed according to schedule B are superior to those of scedule
A.
TABLE I ______________________________________ TENSILE PROPERTIES
OF PHOSPHOR BRONZE PROCESSED ACCORDING TO SCHEDULE A Strengths in
ksi 0.01% 0.1% 0.2% Percent Material YS YS YS UTS Elon- gation
______________________________________ Longitudinal CR 97.8% 77 113
121 130 < 0.5 200.degree.C-2 Hours 86 112 -- 126 <0.5
250.degree.C-2 Hours 75 99 100 109 3.4 275.degree.C-2 Hours 74 96
101 103 6.7 300.degree.C-2 Hours 64 85 89 92 15.8 Transverse CR
97.8% -- -- -- -- -- 200.degree.C-2 Hours 96 132 141 151 1.5
250.degree.C-2 Hours 88 118 -- 130 4.8 275.degree.C-2 Hours -- --
-- -- -- 300.degree.C-2 Hours 72 98 -- 104 13.8
______________________________________
TABLE II ______________________________________ TENSILE PROPERTIES
OF PHOSPHOR BRONZE PROCESSED ACCORDING TO SCHEDULE B Strengths in
ksi 0.01% 0.1% 0.2% Percent Material YS YS YS UTS Elon- gation
______________________________________ Longitudinal CR 97.8% 83 116
123 129 < 0.5 200.degree.C-2 Hours 86 115 -- 125 2.5
250.degree.C-2 Hours 85 102 -- 109 5.9 175.degree.C-2 Hours 76 99
103 106 7.9 300.degree.C-2 Hours 64 85 88 90 17.2 Transverse CR
97.8% 90 126 137 150 <0.5 200.degree.C-2 Hours 101 131 138 144
< 0.5 250.degree.C-2 Hours 96 122 128 131 3.5 275.degree.C-2
Hours 96 119 122 124 3.6 300.degree.C-2 Hours 75 97 101 103 13.2
______________________________________
This invention may be embodied in other forms or carried out in
other ways without departing from the spirit or essential
characteristics thereof. The present embodiment is therefore to be
considered as in all respects illustrative and not restrictive, the
scope of the invention being indicated by the appended claims, and
all changes which come within the meaning and range of equivalency
are intended to be embraced therein.
* * * * *