U.S. patent number 3,843,885 [Application Number 05/275,400] was granted by the patent office on 1974-10-22 for method for charging electrophotographic material.
This patent grant is currently assigned to Fuji Photo Film Co., Ltd.. Invention is credited to Takao Komaki, Masamichi Sato, Masaaki Takimoto.
United States Patent |
3,843,885 |
Sato , et al. |
October 22, 1974 |
METHOD FOR CHARGING ELECTROPHOTOGRAPHIC MATERIAL
Abstract
An electrophotographic material consisting of a high-insulating
base and a photoconductive insulating layer coated directly
thereon, is exposed uniformly on the side of the surface of the
photoconductive insulating layer, to lights which are absorbable by
the photoconductive insulating layer. Then, corona ions with a
desired polarity produced by a corona discharge unit are sprayed
onto the surface of the photoconductive insulating layer while the
surface of the photoconductive insulating layer is simultaneously
exposed to corona ions with the opposite polarity produced by
another corona discharge unit. Thus, a conductive layer is
temporarily produced on the surface of the photoconductive
insulating layer so that the photoconductive insulating layer is
charged or sensitized.
Inventors: |
Sato; Masamichi (Asaka,
JA), Takimoto; Masaaki (Asaka, JA), Komaki;
Takao (Asaka, JA) |
Assignee: |
Fuji Photo Film Co., Ltd.
(Kanagawa, JA)
|
Family
ID: |
13010024 |
Appl.
No.: |
05/275,400 |
Filed: |
July 26, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Jul 26, 1971 [JA] |
|
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46-55835 |
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Current U.S.
Class: |
250/326;
361/229 |
Current CPC
Class: |
G03G
13/02 (20130101) |
Current International
Class: |
G03G
13/00 (20060101); G03G 13/02 (20060101); G03g
013/02 () |
Field of
Search: |
;250/49.5ZC ;317/262A
;96/1R,1C |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lindquist; William F.
Attorney, Agent or Firm: Sughrue, Rothwell, Mion, Zinn &
Macpeak
Claims
We claim:
1. A method for charging to a first polarity electrophotographic
material consisting of an insulating base and a photoconductive
insulating layer directly coated thereon and including a
semiconductor having majority carriers of said first polarity, said
method comprising:
a. uniformly exposing the surface of said photoconductive layer to
light of a wavelength absorbable by said photoconductive insulating
layer such that said surface becomes conductive; and,
simultaneously while said surface is still conductive:
b. exposing a first area of said surface of said photoconductive
insulating layer to first corona discharge ions of a first
polarity; and
c. exposing a second area of said surface of said photoconductive
insulating layer to second corona discharge ions of the opposite
polarity to said first corona discharge ions, whereby said surface
of said photoconductive insulating layer becomes charged to said
first polarity.
2. The method as defined in claim 1 wherein said photoconductive
layer is made of N-type semiconductor material, and said first
polarity is negative.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to a method and apparatus for charging
electrophotographic material consisting of a high-insulating base
and a photoconductive insulating layer coated thereon.
2. Description of the Prior Art
Electrophotographic material, which consists of a base having
relatively high resistance, e.g., a paper base, and a
photoconductive insulating layer coated thereon, is normally
charged by the double-corona charging method, whereby electrical
charges of one polarity are applied to the surface of the
electrophotographic material while electric charges of the opposite
polarity are applied to the backface of the paper base.
However, this method is not able to provide the charging for
high-insulating electrophotographic material, such as polyethylene
terephthalate, polyethylene, polypropylene, polycarbonate,
polyamide, polyimide, polyvinyl chloride, diacetyl cellulose and
polyacetyl cellulose. The charging of these types of
electrophotographic material which have a high-insulating base, has
been accomplished by providing a conductive layer between the base
and the photoconductive insulating layer.
A method for charging an electrophotographic material having a
high-insulating base and a photoconductive insulating layer coated
directly thereon, without a conductive layer therebetween, is
disclosed in British Pat. No. 971,281 Specification. In the method,
light having a wavelength which penetrates the base and is absorbed
into the photoconductive layer, is irradiated onto the material
from the base-side thereof so as to make the contacting portion, of
the photoconductive insulating layer with the base, temporarily
conductive. Then the charging is provided by corona discharge
during the period when the temporary conductive layer exists. For
applying charges by this method, it is necessary to ground the
conductive layer and therefore a connector is provided in contact
with the surface of the photoconductive insulating layer.
However, the connector which contacts to the surface of
photoconductive insulating layer, tends to produce line-cuts
thereon which produce line-scars in the developed image and
accordingly a significant deterioration of image quality.
Furthermore, since the connector is merely contacted onto the
surface of photoconductive insulating layer, there is a
non-uniformity of charging due to imperfections in the conJact. It
is therefore necessary to more strongly press the connector onto
the surface of photoconductive insulating layer in order to provide
a better contact, so that sharper line-cuts are produced thereon.
In addition, since it is necessary that lights pentrate the base,
it is impossible to use a non-transparent material such as veneer,
plastics, concrete or the like.
SUMMARY OF THE INVENTION
This invention has been made with the intention of overcoming the
above-described disadvantages in the prior electrophotographic
material, and accordingly an object of this invention is to provide
a novel and effective charging method and apparatus for
electrophotographic material consisting of a high-insulating base
and a photoconductive insulating layer coated thereon with no
conductive layer.
Another object of this invention is to provide a method and
apparatus for charging electrophotographic material having a base
of opaque or non-transparent material.
According to this invention, electrophotographic material, which
consists of a high-insulating base and a photoconductive insulating
layer coated directly thereon, is uniformly exposed to light having
a spectrum absorbable in the photoconductive insulating layer on
the side of the surface of the photoconductive insulating layer.
Next, corona ions, with a first polarity are emitted from a corona
discharge unit and are sprayed onto the surface of the
photoconductive insulating layer, while at least a portion of the
photoconductive insulating layer is exposed to corona discharge
ions with the opposite polarity. Thus, a conductive layer is formed
temporarily on the surface of the photoconductive insulating layer,
so that it is possible to charge, or sensitize, the
electrophotographic material.
As described above, this invention provides a novel method and
apparatus to enable the charging of an electrophotographic material
by uniformly exposing the surface of a photoconductive insulating
layer to form a conductive layer on the surface. It is, therefore,
possible that an electrophotographic material consisting of a
high-insulating base and a photoconductive insulating layer coated
thereon is charged without providing any special conductive layer.
Accordingly, it is possible to obtain a good electrophotographic
image with no line-scar because it is not necessary to ground the
material. Further, it is possible to use, as an insulating base,
opaque or non-transparent insulating material such as veneer,
plastics, concrete, wall, floor or the like.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a sectional view of the electrophotographic material used
for this invention.
FIG. 2 is a schematic sectional view for the illustration of the
principle of this invention.
FIG. 3 shows an example of the electrophotographic apparatus
according to this invention, wherein (a) is a schematic sectional
view thereof and (b) is a schematic sectional side view
thereof.
FIG. 4 is a schematic sectional view of another example of the
electrophotographic apparatus according to this invention.
FIG. 5 is a graph of the results of tests carried out in accordance
with Example V set forth below.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
In FIG. 1, there is shown electrophotographic material 10 used for
this invention. Photoconductive insulating layer 11 is made of
vacuumdeposited non-crystalline selenium, the mixture of
photoconductive powder (e.g., zinc oxide, cadmium sulfide) and
insulating resin and a, and a photoconductive organic material or
the like. It is desirable that it exhibits a slow decay after the
exposure light is turned off. When a photoconductive insulating
material is subject to repeat cycles of charging and exposure, an
effect known as fatigue sometimes occurs. The effect is manifested
as an increase in the dark decay rate of the potential, i.e.,
decreased retentivity. High-insulating base 12 is made of
well-drive paper, non-electrosensitive paper, polyethylene
terephthalate, polypropylene, polycarbonate, polyamide, polyimide,
polyvinyl chloride, diacetyl cellulose or polyacetyl cellulose, or
it may be made of other non-transparent insulating material.
The principle of this invention will be made clear in relation to
the case wherein the photoconductive insulating layer is made of
N-type semiconductor, e.g., by kneading together photoconductive
zinc oxide powder and insulating resin, with reference to FIG.
2.
The electrophotographic material 10 is exposed, on the side of the
surface of photoconductive insulating layer 11, to the lights of a
light source (not shown). The light is absorbable into the
photoconductive insulating layer 11 to make it conductive. Main
corona discharge unit 20 and sub-corona discharge unit 21 are
arranged above the electrophotographic material 10 and having
corona wires 22 and 23, respectively. Negative high voltage (e.g.,
- 6 kV) is applied to the corona wire 22 of the main corona
discharge unit 20 to emit negative corona ions onto the
photoconductive insulating layer 11, and positive high voltage
(e.g., + 6 kV) is applied to the corona wire 23 of the sub-corona
unit 21 to emit positive corona ions onto the photoconductive
insulating layer 11.
Fatigue is caused within the photoconductive insulating layer 11 by
uniform exposure, so that there are relatively freely movable
trapped electrons therein. These electrons are repulsed and driven
away by the negative corona ions so that the trap centers are
neutralized. Thus, the area R exposed to the negative corona
discharge recovers from fatigue and is capable of being charged. On
the other hand, the electrons in the area R, driven away by the
negative corona ions, pass through the area outside the area R
which has not recovered from fatigue and permits relatively free
movement of electrons therein. These electrons are attracted by the
positive corona ions emitted from the corona wire 23 for
neutralization. When the trap centers in the area R are
neutralized, the negative corona ions are stored in the surface of
the photoconductive insulating layer within the area R and
therefore positive charges equal to them are produced outside the
area R. The area R is then expanded outwardly as a function of time
so that the negative charging is provided over the large area.
Thus, a conductive layer is formed on the surface of the
photoconductive insulating layer in accordance with the uniform
exposure of the surface to lights and thus the electrophotographic
material is charged. It is, therefore, possible to use
electrophotographic material consisting of an opaque insulating
base, such as veneer, plastics, concrete, wall or floor, and a
photoconductive insulating layer directly coated thereon without
the necessity of any special conductive layer.
FIG. 3 shows an example of electrophotographic apparatus for
practicing the method of this invention, wherein (a) is the
schematic front sectional view thereof and (b) is the schematic
side sectional view thereof. Main corona discharge unit 30 is
composed of corona wire 31, shield case 32 and insulating supporter
33 for corona wire 31. Sub-corona discharge unit 34 is composed of
corona wire 35, shield case 36 and insulating supporter 37 for
corona wire 35. The corona wires 31 and 35 are positioned at right
angles with respect to each other, the corona wire 31 being at a
right angle to the forward direction of the electrophotographic
material 10 and the corona wire 35 is parallel to the forward
direction.
Before the electrophotographic material 10 is exposed to corona
discharge, it is uniformly exposed, on the side of the surface of
the photoconductive insulating layer, to the lights from a light
source 38. The light is absorbed by the photoconductive insulating
layer to make the layer conductive. In order to provide negative
charging, a negative high voltage may be applied to the corona wire
31 of the main corona discharge unit 30 to produce corona
discharge, while a positive high voltage may be applied to the
corona wire 35 of the sub-corona discharge unit 34. To provide
positive charging, the polarity of high voltages applied to the
corona wires may be opposite to the above case.
Though two sub-corona units 34 are used in the above example, it is
possible to use one unit. In addition, if the corona ions emitted
from the corona wire 31 of the main corona discharge unit 30 and
the corona ions emitted from the corona wire 35 of the sub-corona
discharge unit 34 overlap each other, the quantity of charge is
decreased. It is, therefore, desired to provide a partition, and
the shield plate of the one corona discharge unit may also serve as
the partition.
FIG. 4 is a schematic sectional view of another example of the
apparatus according to this invention. Electrophotographic material
10 is uniformly exposed to light from source 42 on the side of the
surface of photoconductive insulating layer. The layer is then
exposed to positive corona ions produced by the sub-corona
discharge unit 41 followed by exposure to negative corona ions
produced by the main discharge unit 40 so as to become negatively
charged. In this apparatus, the corona wire is made longer than the
width of the material to uniformly charge the whole surface.
It may be possible to use, as the corona discharge electrode, a
needle electrode or strip electrode instead of wire electrodes. It
is necessary that the light source emit the lights in a spectrum
which is absorbable by the photoconductive insulating layer. For
example, if the photoconductive insulating layer is made of zinc
oxide, a tungsten light source may be used for pre-exposure. This
photoconductive insulating layer is photosensitive only to
ultraviolet and near ultraviolet lights and extremely absorbative
to the spectral lights, so that only ultraviolet or near
ultraviolet lights are available for exposure. When the
photoconductive insulating layer contains dye-sensitized zinc
oxide, however, its sensitive spectrum is extended up to visible
spectrum from the near ultraviolet spectrum, and the
photoconductive insulating layer exhibits a low absorption
coefficient and high photosensitivity to visible lights.
Accordingly, irradiating visible lights onto the surface thereof,
some of the lights may reach the backface thereof so that the
electrification coefficient of the photoconductive insulating layer
is increased.
Though ultraviolet and near ultraviolet lights are absorbed in the
surface of the photoconductive insulating layer, experiments show
that the after effect on photoconductivity caused by the
ultraviolet lights tends to continue for a relatively long period.
The practice of this invention is achieved with preferred results
with any one of the following combinations: (1) dye-sensitized
layer and ultraviolet lights; (2) dye-sensitized layer and visible
lights; (3) dye-sensitized layer and ultraviolet and visible
lights; and (4) non-sensitized layer and ultraviolet lights.
In addition, if pre-exposure is provided a relatively long time
before corona discharge, it will be necessary to determine the
factor relating to exposure quantity, light quality and time in
accordance with the characteristics of the photoconductive
insulating layer.
In the following, examples of this invention will be described for
the best understanding of this invention.
EXAMPLE I
The electrophotographic material is made by kneading 100 parts
photoconductive zinc oxide power (SaZeX No. 2000, Sakai Chemical
Industry Co. Ltd.), 14 parts insulating resin (Styresol No. 4400,
Japan Reichhold Chemical, Inc.) and 7 parts polyisocyanate compound
(Desmodul L, Bayer A.G.), then painting the mixture onto a film of
polyethylene terephthalate, of 150.mu. thickness, to a thickness of
about 7.mu. and then hardening the material in a constant
temperature bath at 40.degree.C for 17 hours. After putting the
electrophotographic material on a high-insulating plate
(polymethylmethacrylate resin plate of 10 mm thickness) in a dark
place and exposing it uniformly on the side of the surface of the
photoconductive insulating layer, to a tungsten lamp with an
exposure quantity of 200,000 Lux.sup.. sec (10,000 Lux .times. 20
sec), corona discharge units are arranged above the
electrophotographic material as shown in FIG. 3.
In the main corona discharge unit 30, the distance between the
corona wire and the surface to be charged is 15 mm, the space
between the corona wire and the shield case is 15 mm, the diameter
of the wire is 0.05 mm, the length of the wire is 30 mm, the
distance from the lower edge of the shield case to the surface to
be charged is 8 mm, and the material of the wire is tungsten.
In the sub-corona discharge unit 34, the distance between the
corona wire and the surface to be charged is 10 mm, the space
between the corona wire and the shield case is 15 mm, the wire
diameter is 0.05 mm, the wire length is 50 mm, the distance between
the lower edge of the shield case and the surface to be charged is
2 mm, and the wire material is tungsten. Applying -8 kV to the
corona wire of the main corona discharge unit and +9 kV to the
corona wire of the sub-corona discharge unit, the
electrophotographic material is moved in a direction at a right
angle to the corona wire of the main corona discharge unit at the
speed of 50 mm/sec and the discharging is finished within 30 sec
after the above exposure. The electrophotographic material is thus
charged uniformly at the surface to a potential of -140 V except
for both edge portions thereof. Further, the area under the
sub-corona discharge unit is not charged.
EXAMPLE II
The same electrophotographic material as in Example I is put on the
similar insulating plate as in Example I and pre-exposed uniformly
to the lights of 200,000 Lux.sup.. sec (10,000 Lux.sup.. 20 sec).
Then, two needle corona discharge electrodes are arranged above the
material at right angles to the surface to be charged. The distance
between the corona discharge electrodes is 150 mm, the main corona
discharge unit 30 being positioned above the center portion of the
charged surface and the sub-corona discharge unit 34 being
positioned above the edge portion of the charged surface. The
distance between the top of the main discharge unit electrode and
the charged surface is 50 mm, and the distance between the top of
the sub-corona discharge unit electrode and the charged surface is
20 mm. Applying -9 kV to the main corona discharge unit and +5 kV
to the sub-corona discharge unit, the electrophotographic material
is moved below both electrodes at the speed of 30 mm/sec and the
discharging is finished within 30 sec after the previous exposure,
with the result that the center portion of the surface to be
charged is charged to a -130 V surface potential.
EXAMPLE III
The same material as in Example I is made zonal into a roll and
transported at a speed of 30 mm/sec. The light source and corona
discharge units are arranged as shown in FIG. 4. The light source
consists of six tungsten lamps of 200 W arranged in double lines
and provides an exposure quantity of 8000 Lux.sup.. sec during the
material passage. In addition, a shielding plate is provided to
prevent lights of the light source from leaking onto the charged
area. The electrophotographic material passes below the light
source, then below the sub-corona discharge unit 41 and then below
the main corona discharge unit 40. In each corona discharge unit
the corona wire is made of stainless steel with a 5 mm diameter,
the distance between the shield case and the wire is 15 mm, and the
distance between the corona wire and the charged surface is 20 mm.
The distance between the first and the second corona discharge
units is 100 mm. The length of each corona wire is 50 mm longer
than the width of the electrophotographic material. Applying +9.5
kV to the corona wire of the first corona discharge unit 41 and
-8.5 kV to the corona wire of the second corona discharge unit 40,
the electrophotographic material is charged to a surface potential
of -140 V.
EXAMPLE IV
The electrophotographic material is made by painting the same
mixture as in Example I onto a veneer plate of 8 mm thickness and
hardening as in Example I. This material is charged, according to
the process as in Example I, to a surface potential of -120 V.
Next, after contacting a positive transparency onto the material
and then exposing it, image development is made by a cascade
developer containing toners with positive charges to obtain a
positive image.
EXAMPLE V
Using the same electrophotographic material as in Example I and
charging it under the following conditions, measurements of the
relation between exposure quantity and surface potential were made:
The material was placed on the same insulating plate as in Example
I, and two needle electrodes were arranged thereabove with a
distance of 80 mm between electrodes. The distance between the top
of each needle electrode and the photoconductive insulating layer
was 30 mm. The one needle electrode was applied with -5 kV and the
other with a +5 kV, for a duration of 5 sec and 30 sec.
The measured results are shown in FIG. 5.
While the invention has been particularly shown and described with
reference to the preferred embodiments thereof, it will be
understood by those skilled in the art that various changes in form
and details may be made therein without departing from the spirit
and scope of the invention.
* * * * *