U.S. patent number 3,842,895 [Application Number 05/216,818] was granted by the patent office on 1974-10-22 for metal alloy casting process to reduce microsegregation and macrosegregation in casting.
This patent grant is currently assigned to Massachusetts Institute of Technology. Invention is credited to Merton C. Flemings, Robert Mehrabian.
United States Patent |
3,842,895 |
Mehrabian , et al. |
October 22, 1974 |
METAL ALLOY CASTING PROCESS TO REDUCE MICROSEGREGATION AND
MACROSEGREGATION IN CASTING
Abstract
Apparatus for reducing segregation in metal alloy castings. The
apparatus is operable to reduce segregate spacing (i.e., dendrite
arm spacing) in short range segregation (microsegregation) and the
overall magnitude of long range segregation (macrosegregation) in
castings by controlling the heat flow process, in an active manner,
during solidification, thereby reducing the time lapse between
initiation and completion of the such solidification. The apparatus
functions to decrease the distance within the material being cast
between the liquidus-isotherm and the solidus-isotherm by
increasing the temperature of the liquid melt around the region of
the liquidus-isotherm.
Inventors: |
Mehrabian; Robert (Cambridge,
MA), Flemings; Merton C. (Lexington, MA) |
Assignee: |
Massachusetts Institute of
Technology (Cambridge, MA)
|
Family
ID: |
22808630 |
Appl.
No.: |
05/216,818 |
Filed: |
January 10, 1972 |
Current U.S.
Class: |
164/466; 164/485;
164/122 |
Current CPC
Class: |
B22D
11/124 (20130101) |
Current International
Class: |
B22D
11/124 (20060101); B22d 011/02 (); B22d
027/02 () |
Field of
Search: |
;164/49,51,52,82,250-252 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
|
|
|
|
|
|
|
705,902 |
|
May 1941 |
|
DD |
|
1,803,473 |
|
May 1970 |
|
DT |
|
1,807,435 |
|
Oct 1970 |
|
DT |
|
409,925 |
|
Mar 1945 |
|
IT |
|
Other References
Caldwell, Experimental Verification of a New Heat Flow Analysis of
Solidification, 1971, pp. i & ii..
|
Primary Examiner: Annear; R. Spencer
Attorney, Agent or Firm: Smith, Jr.; Arthur A. Shaw; Robert
Santa; Martin M.
Claims
What is claimed is:
1. A method of reducing segregation in metal alloy castings in a
continuous-casting process, that comprises, introducing a molten
liquid metal of said alloy into a mold, withdrawing heat from one
region of the liquid metal in the mold to effect solidification
thereof, simultaneously adding heat in a controlled manner to the
liquid metal, and internally controlling flow of said heat through
the liquid metal to retard the velocity of the liquidus isotherm
while maintaining substantially the velocity of the solidus
isotherm, thereby reducing the width of liquid-solid mushy zone
that exists between the liquidus and solidus isotherms and hence
reducing both short range and long range segregation, the liquid
metal being heated by superheating the molten metal prior to
introduction to the mold to provide the necessary added heat and
said flow of the heat being controlled by retarding convection of
the liquid metal within the mold.
2. A method of reducing segregation in metal alloy castings in a
continuous-casting process, that comprises, introducing a molten
liquid metal of said alloy into a mold, withdrawing heat from one
region of the liquid metal in the mold to effect solidification
thereof, simultaneously adding heat in a controlled manner to the
liquid metal, and internally controlling flow of said heat through
the liquid metal to retard the velocity of the liquidus isotherm
while maintaining substantially the velocity of the solidus
isotherm, thereby reducing the width of liquid-solid mushy zone
that exists between the liquidus and solidus isotherms and hence
reducing both short range and long range segregation, a
uni-directional magnet field of substantially constant magnitude
throughout the region occupied by the liquid metal in the mold
being introduced to control the flow of heat by retarding
convection within the liquid metal during the solidification period
and thereby raise the temperature of the melt in the vicinity of
the liquidus isotherm.
3. In a method of casting a body of metal within which a
liquid-solid mushy zone is established during solidification
between solidus and liquidus isotherms defining a solid and a
liquid zone, the steps of: superheating the liquid metal introduced
into the liquid zone; and internally controlling the flow of heat
through said liquid zone to maximize the heating of liquid metal
adjacent to the liquid isotherm causing approach thereof toward the
solidus isotherm, said flow of heat being controlled by
magnetically retarding convection within the liquid zone.
Description
The invention herein was made in the course of a contract under the
sponsorship of the United States Army Materiel Command, Frankford
Arsenal.
The present invention relates to metal casting processes. While the
concepts herein disclosed have use in connection with general
casting techniques, they are of greatest importance and are
described with particular reference to continuous casting
techniques, the latter being the process by which billets or ingots
are formed.
It is known that segregate spacing, that is, dendrite arm spacing,
has influence on the properties of castings and on the properties
of wrought products made from such castings. The subject,
generally, is discussed in a doctoral thesis of A. P. Campagna
entitled "Heat Flow and Solidification of Alloys" and a master's
thesis of T. N. Caldwell entitled "Experimental Verification of a
New Heat Flow Analysis of Solidification", the work which led to
both theses having been done at the Massachusetts Institute of
Technology under the supervision of the inventors Flemings and
Mehrabian herein. A principal object of the present invention is to
teach a way of reducing segregate spacing (i.e., dendrite arm
spacing) in short range segregation (microsegregation) and the
overall magnitude of long range segregation (macrosegregation) in
castings through control of heat flow in the casting during
solidification thereof.
Further objects are discussed in the description to follow and are
particularly pointed out in the appended claims.
By way of summary, the objects of the invention, generally, are
attained in apparatus for reducing segregation in a metal alloy
casting, said apparatus including a mold to receive the molten or
liquid alloy metal of which the casting is made. Cooling means is
provided for withdrawing heat from one region of the liquid metal
in the mold to effect solidification of the liquid metal alloy and
the cooling means acts also to withdraw heat from the casting
thereby formed. Means is provided for adding heat in a controlled
fashion to the liquid melt in the region of the liquidus-isotherm
to retard the velocity of that isotherm while maintaining the
velocity of the solidus-isotherm. In this way the width of the
liquid-solid zone that exists between the liquidus and solidus
isotherms is reduced thereby reducing both short range and long
range segregation.
The invention will now be discussed with reference to the
accompanying drawing, in which:
FIG. 1 is an elevation section view, schematic in form, to
illustrate solidification of a continuous-casting made using prior
art techniques;
FIG. 2 is a view, similar to FIG. 1, showing solidification of a
similar casting but one made using the herein described teachings
and shows a reduction in the physical distance between the
liquidus-isotherm and the solidus-isotherm from the separation
distance in FIG. 1, and FIG. 2 shows schematically, as well,
apparatus operable to effect such reduction;
FIG. 3 is a side elevation view, partially schematic in form and
partially in block diagram form, to show apparatus adapted to
perform the casting techniques disclosed here and is a modification
of the apparatus of FIG. 2;
FIG. 4 shows a modification of the apparatus of FIG. 3;
FIG. 5 shows a further modification of the apparatus of FIG. 3;
and
FIG. 6 shows, in plan view, still another modification of the
apparatus of FIG. 3.
Before going into a detailed discussion of the invention, a brief
overall discussion is given. In general, engineering alloys to
which the invention is directed freeze over a range of temperatures
which differentiates them from pure materials that solidify at a
single temperature designated as their melting point. Therefore,
alloy solidification is characterized by the presence of a
liquid-solid "mushy" region that extends over a range of
temperatures dependent only on the composition of the alloy. The
solidification of an alloy against a cold mold is illustrated in
FIG. 1, where three distinct regions, a solid region 5', a liquid
region 3' and a liquid-solid mushy region 4' of an alloy casting 2'
are shown. The liquid-solid mushy region 4' is delineated by two
isothermal boundaries: the liquidus isotherm labeled 8' (the
solidification front, or start of freezing) and the solidus
isotherm labeled 9' (end of freezing). Solidification of the alloy
takes place due to extraction of heat through the cold mold wall
and both the liquidus and the solidus isotherms move vertically
upward in FIG. 1. Since the process discussed herein is a
continuous one and since, as shown, the casting formed moves
downward as indicated by the arrow labeled A, such "vertical"
movement of the isotherms is relative to, say, the solid region 5';
whereas the isotherms are stationary with relation to the mold, for
example. The distance between the liquidus and the solidus
isotherms is designated as the width of the mushy region, and the
speed with which each isotherm moves is designated as the velocity
of that isotherm. Finally, the local solidification time is the
time that a given location in the casting spends between the
temperatures of the liquidus and solidus isotherms, or the time
that it takes for both these isotherms to sweep across the given
location.
During solidification of such an alloy, the different elements,
that are combined to make up the cast alloy, segregate. As outlined
earlier, the short range distances over which these different
elements segregate are designated as the segregate spacings or
dendrite arm spacings. These segregate spacings, which have a
profound influence on the homogenization and mechanical properties
of the cast alloy, are directly proportional to the `local
solidification time` described in the preceding paragraph.
On the other hand, these elements also segregate over large
distances (macrosegregation), and this type of segregation is
dependent on the size of the liquid-solid mushy zone and the rate
of solidification (i.e., the speed with which liquidus and solidus
isotherms sweep by a given location in the casting).
In conventional methods of continuous casting, a molten metal alloy
is introduced directly to an axially short, water-cooled, chill
mold. The cooling capacity of the chill mold is such that a solid
layer forms in the mold capable of supporting the V-shaped pool of
liquid in the center of the casting. The ingot is further cooled by
the direct application of a coolant as it exits from the bottom of
the mold. The coolant (i.e., water) is applied in such a quantity
that the transversely solidifying ingot becomes completely solid at
a predetermined distance below the bottom of the mold. The
foregoing is shown schematically in FIG. 1 of the drawing where
three regions in the formation of casting 2', i.e., liquid,
liquid-plus-solid, and solid, during solidification of continuously
cast billet are labeled 3', 4' and 5', respectively, as mentioned;
since this is a continuous casting process, the casting 2' moves
downward so that the isotherms appear stationary in space. There is
movement, however, relative to the casting, as before mentioned. In
the next paragraph there is discussed the formation of a casting 2
by employing the teachings of the present invention.
Turning now to FIG. 2, apparatus is shown generally at 100 for
reducing segregation in a metal alloy casting in a continuous
casting process. The apparatus 100 comprises a mold 1 to receive
the molten or liquid metal alloy of which the casting is made;
reference may be made to U.S. Patent No. 3,477,494 (Burkhart et
al.) for details of molds, liquid metal alloy feed devices and
related equipment used to provide a continuously-cast product, the
product there (and here) of most interest being made of aluminum
alloys. The mold 1 usually is a water cooled metal chill mold, as
shown in the patent; there is an annular, square or
otherwise-shaped central opening in the mold to receive the molten
metal and to initiate formation of a casting 2. The cooling
capacity of this chill mold is such that a solid layer 11' forms in
the mold before the casting exits from the bottom of the mold at
12'. A water spray 10 directed upon the casting 2 serves to effect
further withdrawal of heat from the casting to cause complete
solidification of the casting. In the embodiment of FIG. 2, the
liquid metal alloy introduced is superheated and convection in the
liquid melt within the mold, which is labeled 3, is retarded by a
transverse magnetic field of the order of 2,000 gauss provided by
magnetic pole pieces 6 and 7; see U.S. Patent No. 3,464,812
(Flemings et al.). In this way superheat in the liquid metal alloy
3 is preserved and this superheat manifests itself as additional
heat in the vicinity of the liquidus-isotherm labeled 8 to retard
the velocity of that isotherm while maintaining the velocity of the
solidus isotherm labeled 9, thereby reducing the size or width of
the liquid-solid mushy zone 4 (from the width of the zone 4') that
exists between the liquidus and solidus isotherms. In this way
local solidification time, which is used herein to denote the time
difference between initiation and completion of solidification at
any particular location in the casting, is reduced and the cast
structure 2 formed is refined over the structure 2' formed in the
apparatus shown in FIG. 1. It should be noted here that "refined,"
as used in the present specification refers to reduction in
segregate spacing in microsegregation (i.e., dendrite arm spacing),
hence, is closely related to local solidification time; on the
other hand, macrosegregation (long range segregation) is a function
of the width of the liquid-solid zone 4 and the reducing (or
shortening) of that zone reduces or eliminates macrosegregation.
Thus, the effect of reducing the width of the liquid-solid zone
during casting affects both microsegregation and macrosegregation,
but the mechanism in one case differs from that in the other. The
beneficial effect of reducing the width of the mushy zone 4 by the
addition of 150.degree. C superheat to a binary alloy of aluminum
and copper (4.5% aluminum) in the absence of convection in the melt
zone 3, has been investigated and recognized in the thesis of T. W.
Caldwell, aforementioned, the contents of which is incorporated
herein by reference.
The magnetic field provided by the pole pieces 6 and 7 is directed
transversely to the axis of the casting 2 in FIG. 2 and is a d-c or
uni-directional field of substantially constant magnitude. This
magnitude of the field in the liquid melt 3 must be sufficient to
create magnetic forces (i.e., forces between eddy currents, induced
when the liquid metal moves relative to the field, and the magnetic
inducing field) within the melt which are larger than the forces of
convection. As mentioned, a 2,000 gauss field, when casting
aluminum alloys, has been found adequate. It will be appreciated
that the mold 1 is a fairly large piece of equipment in operable
apparatus, and the pole pieces 6 and 7 to provide the field
uniformity and magnitude in the gap occupied by the mold will also
be quite large. The d-c magnetic field can also be provided by a
solenoidal coil 11 wound about the mold 1, as shown in FIG. 3 the
mold being disposed within the central opening of the coil 11. The
electric current in the coil 11 will be quite large; to provide
such current the coil 11 may be water-cooled copper tubing, or
superconducting coils can be used. Electric power to the coil 11 is
provided by an electric power source 14. In FIG. 3 there are also
shown a source of molten metal 13 and a molten-metal feed device
12.
In the embodiment of FIG. 4, heat to the liquid melt 3 in the
vicinity of the liquidus isotherm is provided by a high electrical
resistance heating element 15 in thermal contact with the melt 3
but located at a region removed or remote from the liquidus
isotherm. Means is provided for convecting the liquid melt to
convey the added heat to the liquidus isotherm. The convecting
means in the apparatus of FIG. 4 includes magnetic pole pieces 17,
17', 18, and 18' energized by windings, designated 19, 19', etc. in
the figure, which in turn are connected to an electrical power
source 20. The power source 20 provides a-c electric currents of
about 1 to 60 hertz, depending on the parameters of the system
(including mold size, volume of melt 3, material being cast, etc.);
the magnitude of the a-c field, thus produced, is again the order
of at least 2,000 gauss; but here as well the magnitude will depend
on the parameters. The poles 17-18, 17'-18' act to induce electric
currents in the liquid metal surface and as the electric currents
in the windings 19, 19', etc. alternate (and with appropriate
phasing) the field appears to move, thereby to cause the melt 3 to
oscillate as indicated by the arrows A. It will be appreciated that
additional poles can be employed to control the convection of the
melt and that a polyphase electric system may be used to create a
rotary field.
In the casting system of FIG. 5 heat is added to the melt 3 at the
remote region by two electrodes 21 and 22 disposed above the liquid
metal 3. A source of high-voltage electric energy 23 is connected
across the electrodes 21 and 22 to to provide an arc therebetween,
heat to the melt 3 being transmitted by radiation from the arc and
being convected to the liquidus isotherm by virtue of eddy currents
induced in the melt 3 by the eddy-current fields of coils 24, 24',
25 and 25' which are flat coils and which are energized by an
electric power source 26. The coils 24, 24' etc. are oriented and
wound to induce convection in the desired direction. Again, the
magnitude and frequency of the eddy-current inducing field will
depend upon the material of a melt, mold size etc., but frequencies
of the order of 60 hertz to 1 kilohertz can ordinarily be used.
Field magnitudes of the order of say 1000 to 2000 gauss will
suffice for must uses.
In the casting apparatus of FIG. 6, heat is added at a region of
the melt 3 remote from the liquidus isotherm by passing high
magnitudes of electric current between two electrodes 27 and 28
which are connected to and energized by an electric power source
29. A magnetic field, oriented in the x direction in the figure
between magnetic pole pieces 30 and 31 and thus oriented
orthogonally to the generally z-directed electric current between
the electrodes 27 and 28, serves, through interaction with the
electric current, to convect the added heat to the liquidus
isotherm. The pole pieces 30 and 31 can provide a uni-directional
or d-c magnetic field and the power source 29 can be an a-c or a
d-c source, depending upon what is required in a particular piece
of apparatus, or the field between the poles 30 and 31 can be a-c
(i.e., 60 cycle or some other power frequency) properly phased with
the current between the electrodes 27 and 28. It should be kept in
mind, as well, that the depth of the electric current in the y
direction in the melt 3 can and should be controlled to maximize
heat transfer by convection and to otherwise control the
transfer.
Further modifications of the invention will occur to persons
skilled in the art and all such modifications are deemed to be
within the spirit and scope of the invention as defined in the
appended claims.
* * * * *