U.S. patent number 3,827,850 [Application Number 05/386,202] was granted by the patent office on 1974-08-06 for photoflash lamp coating.
This patent grant is currently assigned to GTE Sylvania Incorporated. Invention is credited to John W. Shaffer, John J. Vetere.
United States Patent |
3,827,850 |
Shaffer , et al. |
August 6, 1974 |
PHOTOFLASH LAMP COATING
Abstract
A photoflash lamp having a protective coating over its glass
envelope comprising a vacuum-formed thermoplastic sleeve with
longitudinally extending ribs disposed between the plastic sleeve
and glass envelope for reducing stress levels in the formed sleeve
and for providing thermally insulating air gaps between the sleeve
and envelope.
Inventors: |
Shaffer; John W. (Williamsport,
PA), Vetere; John J. (Williamsport, PA) |
Assignee: |
GTE Sylvania Incorporated
(Danvers, MA)
|
Family
ID: |
23524595 |
Appl.
No.: |
05/386,202 |
Filed: |
August 6, 1973 |
Current U.S.
Class: |
431/360;
174/50.51 |
Current CPC
Class: |
G03B
15/04 (20130101); F21K 5/02 (20130101) |
Current International
Class: |
F21K
5/08 (20060101); F21K 5/00 (20060101); G03B
15/04 (20060101); G03B 15/03 (20060101); F21k
005/02 () |
Field of
Search: |
;431/93-95 |
Foreign Patent Documents
Primary Examiner: Dority, Jr.; Carroll B.
Attorney, Agent or Firm: Coleman; Edward J.
Claims
What we claim is:
1. A photoflash lamp comprising an hermetically sealed glass
envelope, a combustion-supporting gas in said envelope, a quantity
of combustible material located in said envelope, ignition means
attached to said envelope and disposed in operative relationship to
said combustible material, a vacuum-formed thermoplastic coating on
the exterior surface of said glass envelope, and rib means disposed
between said thermoplastic coating and said glass envelope.
2. A lamp according to claim 1 wherein said rib means comprises a
plurality of longitudinally extending ribs.
3. A lamp according to claim 2 wherein said ribs are equally spaced
about said envelope whereby the extent of coating wall supported
between adjacent ribs provides flexure for relieving stresses in
said thermoplastic coating.
4. A lamp according to claim 2 wherein said ribs provide thermally
insulating air gaps between said envelope and said coating.
5. A lamp according to claim 1 wherein the composition of said
coating comprises a light-transmitting thermoplastic selected from
the group consisting of acrylic, acrylonitrile-butadiene-styrene,
cellulose acetate, ionomers, methylpentene polymer, nylon,
polycarbonate, polystyrene, polysulfone, and alloys thereof.
6. A lamp according to claim 1 wherein said coating comprises a
preformed sleeve of thermoplastic material having a plurality of
longitudinally extending ribs molded on its inner surface to
provide said rib means, said interiorly ribbed sleeve having been
vacuum-formed onto said glass envelope.
7. A lamp according to claim 6 wherein said envelope and said
sleeve are substantially tubular in shape, said molded ribs are
equally spaced about the inner surface of said tubular sleeve, the
radially inward extension of each of said ribs from said sleeve is
selected such that if a straight chord were drawn between adjacent
ribs on the inside diameter of said tubular sleeve it would lie
substantially tangent to the outer wall of said glass envelope
midway between the adjacent ribs, and the number of said ribs is
selected to provide a desired amount of stress relief in said
vacuum-formed thermoplastic coating.
8. A lamp according to claim 7 wherein the thermoplastic material
of said coating comprises a polycarbonate resin.
9. A lamp according to claim 1 wherein said combustion-supporting
gas in said envelope is at a pressure exceeding one atmosphere, and
said combustible material in said envelope is filamentary.
Description
BACKGROUND OF THE INVENTION
This invention relates to photoflash lamps and, more particularly,
to an improved protective coating for flashlamps.
A typical photoflash lamp comprises an hermetically sealed glass
envelope, a quantity of combustible material located in the
envelope, such as shredded zirconium or hafnium foil, and a
combustion supporting gas, such as oxygen, at a pressure well above
one atmosphere. The lamp also includes an electrically or
percussively activated primer for igniting the combustible to flash
the lamp. During lamp flashing, the glass envelope is subject to
severe thermal shock due to hot globules of metal oxide impinging
on the walls of the lamp. As a result, cracks and crazes occur in
the glass and, at higher internal pressures, containment becomes
impossible. In order to reinforce the glass envelope and improve
its containment capability, it has been common practice to apply a
protective lacquer coating on the lamp envelope by means of a dip
process. To build up the desired coating thickness, the glass
envelope is generally dipped a number of times into a lacquer
solution containing a solvent and a selected resin, typically
cellulose acetate. After each dip, the lamp is dried to evaporate
the solvent and leave the desired coating of cellulose acetate, or
whatever other plastic resin is employed.
In the continuing effort to improve light output, higher
performance flashlamps have been developed which contain higher
combustible fill weights per unit of internal envelope volume,
along with higher fill gas pressures. In addition, the combustible
material may be one of the hotter burning types, such as hafnium.
Such lamps, upon flashing, appear to subject the glass envelopes to
more intense thermal shock effects, and thus require stronger
containment vessels. One approach to this problem has been to
employ a hard glass envelope, such as the borosilicate glass
envelope described in U.S. Pat. No. 3,506,385, along with a
protective dip coating. Although providing some degree of
improvement in the containment capability of lamp envelopes, the
use of dip coatings and hard glass present significant
disadvantages in the areas of manufacturing cost and safety.
To overcome these disadvantages, a more economical and
significantly improved containment vessel for flashlamps is
described in a copending application Ser. No. 268,576, filed July
3, 1973 and assigned to the assignee of the present application.
According to this previously filed application, a thermoplastic
coating, such as polycarbonate, is vacuum formed onto the exterior
surface of the glass envelope. The method of applying the coating
comprises: placing the glass envelope within a preformed sleeve of
the thermoplastic material; drawing a vacuum in the space between
the thermoplastic sleeve and the glass envelope; and,
simultaneously heating the assembly incrementally along its length,
whereby the temperature and vacuum cause the thermoplastic to be
incrementally formed onto the glass envelope with the interface
substantially free of voids, inclusions and the like. This method
provides an optically clear protective coating by means of a
significantly faster, safer and more economical manufacturing
process, which may be easily integrated on automated production
machinery. The process permits use of the stronger, more
temperature resistant thermoplastics, and the resulting coating
maintains the glass substrate under a compressive load, thereby
making the glass envelope itself more resistant to thermal shock.
As a result, this coating reduces the cost of materials by
permitting the use of soft glass to meet high containment
requirements.
In general, thermoplastic materials have a coefficient of thermal
expansion several times greater than the coefficient of thermal
expansion of the glass envelope. Hence, as the thermoplastic
coating cools from the softening temperature subsequent to vacuum
forming, it will exert a compressive load on the envelope to
thereby in effect strengthen the glass. For example, the
thermoplastic coating may exert a compressive load of from 1,000 to
about 4,000 pounds per square inch on the glass envelope. Although
the glass becomes stronger with a higher compressive load, an
increase in the compressive loading on the glass results in a
corresponding increase in the tensile loading on the coating.
Typically, these tension stresses in the coating may be
approximately 2,000 to 3,000 pounds per square inch. In itself,
this loading appears acceptable if uniform throughout the coating.
In actual practice, however, higher localized stresses appear to
develop, probably due to irregularities in the glass, friction
between the plastic and glass, and irregularities on the inner
surface of the plastic.
In order to relieve these local points of high stress and provide a
more uniform compressive loading on the glass envelope, a copending
application Ser. No. 287,724, filed Sept. 11, 1972 now U.S. Pat.
No. 3,770,366 and assigned to the assignee of the present
application, describes the use of a thin layer of silicone mold
release between the glass and thermoplastic material. The mold
release agent appears to lubricate the glass-plastic interface and
permit the adjacent surfaces to slide over one another, thereby
tending to equalize the stresses.
It is also desirable, however, to predictably control the overall
compressive loading on the glass and the corresponding tensile
loading in the coating, i.e., the average level of the stresses
remaining after the thermoplastic has been vacuum-formed onto the
glass envelope of the lamp and cooled. A plasticizer may be added
to the composition of the thermoplastic to accomplish this purpose;
however, in certain of the thermoplastics particularly suitable for
this application, it has been found difficult to control the
behavior of the plasticizer so as to avoid producing adverse
effects. An improved method for controlling the average stress
level is described in a copending application Ser. No. 289,446,
filed Sept. 15, 1972 and assigned to the present assignee, wherein
a secondary stress relief operation is added to the coating
process. After the thermoplastic coating has cooled and contracted
from the vacuum-forming process, a narrow band of the coating is
heated longitudinally and/or circumferentially. This heated band of
coating yields to relieve the stresses generated by contraction of
the remainder of the coating which remains cool. Upon subsequent
cooling of the heated band, it contracts and again generates
tensile stresses in the coating. In this instance, however, the
developed stresses are lower than those produced from cooling of
the entire coating. As a result, the average tensile stresses in
the coating are relieved to some degree. In many applications,
however, additional stress relief is required to assure that the
structural integrity of the coating is maintained over long term
aging.
SUMMARY OF THE INVENTION
Accordingly, it is an object of the present invention to provide a
photoflash lamp having a stronger reinforcing coating with enhanced
aging characteristics.
It is a particular object of the invention to provide a vacuum
formed thermoplastic coating for a flashlamp which includes a means
for significantly self-relieving the stresses in the coating
resulting from the vacuum forming process.
Another object of the invention is to provide an improved
containment vessel for a flashlamp.
These and other objects and features are attained, in accordance
with the invention, by disposing one or more longitudinally
extending ribs between the vacuum-formed thermoplastic coating and
the glass envelope. For example, the ribs may be molded on the
inner surface of the plastic sleeve which is formed onto the
envelope. Preferably, only the ribs contact the glass, and upon
cooling, contraction of the plastic sleeve is accommodated by
flexure of the sleeve wall between adjacent ribs, thereby
self-relieving stresses in the coating. In addition, the ribs cause
small air gaps to be formed between portions of the coating and the
glass surface of the flashlamp envelope which tend to insulate the
plastic coating and keep it somewhat cooler, and thus stronger,
during flashing.
BRIEF DESCRIPTION OF THE DRAWINGS
This invention will be more fully described hereinafter in
conjunction with the accompanying drawings, in which:
FIG. 1 is an enlarged sectional elevation of an electrically
ignitable photoflash lamp having a protective coating in accordance
with the invention;
FIG. 2 is an enlarged sectional elevation of a percussive-type
photoflash lamp having a protective coating in accordance with the
invention;
FIG. 3 is a cross-section of the coated envelope wall of the lamp
of FIG. 1 or FIG. 2 showing the ribs disposed between the coating
and envelope in accordance with the invention;
FIG. 4 is an enlarged sectional elevation of a preformed sleeve of
thermoplastic having internal ribs according to the invention and
adapted for assembly and vacuum forming onto the glass envelope of
a percussive-type photoflash lamp, the section of FIG. 4 being
taken on line 4--4 of FIG. 5;
FIG. 5 is an end view of the preformed sleeve of FIG. 4; and
FIG. 6 is an enlarged elevation, partly in section, showing a
percussive flashlamp assembled in the thermoplastic sleeve of FIGS.
4 and 5 prior to vacuum forming.
DESCRIPTION OF PREFERRED EMBODIMENT
The teachings of the present invention are applicable to either
percussive or electrically ignited photoflash lamps of a wide
variety of sizes and shapes. Accordingly, FIGS. 1 and 2
respectively illustrate electrically ignited and percussive-type
photoflash lamps embodying the principles of the invention.
Referring to FIG. 1, the electrically ignitable lamp comprises an
hermetically sealed lamp envelope 2 of glass tubing having a press
4 defining one end thereof and an exhaust tip 6 defining the other
end thereof. Supported by the press 4 is an ignition means
comprising a pair of lead-in wires 8 and 10 extending through and
sealed into the press. A filament 12 spans the inner ends of the
lead-in wires, and beads of primer 14 and 16 are located on the
inner ends of the lead-in wires 8 and 10 respectively at their
junction with the filament. Typically, the lamp envelope 2 has an
internal diameter of less than 1/2 inch, and an internal volume of
less than 1 cc., although the present invention is equally suitable
for application to larger lamp sizes. A combustion-supporting gas,
such as oxygen, and a filamentary combustible material 18, such as
shredded zirconium or hafnium foil, are disposed within the lamp
envelope. Typically, the combustion-supporting gas fill is at a
pressure exceeding one atmosphere, with the more recent
subminiature lamp types having oxygen fill pressures of up to
several atmospheres. As will be detailed hereinafter, the exterior
surface of glass envelope 2 is covered by a vacuum-formed
thermoplastic coating 20, with a plurality of longitudinally
extending ribs 21 disposed between the thermoplastic coating and
the glass envelope in accordance with the invention.
The percussive-photoflash lamp illustrated in FIG. 2 comprises a
length of glass tubing defining an hermetically sealed lamp
envelope 22 constricted at one end to define an exhaust tip 24 and
shaped to define a seal 26 about a primer 28 at the other end
thereof. The primer 28 comprises a metal tube 30, a wire anvil 32,
and a charge of fulminating material 34. A combustible 36, such as
filamentary zirconium or hafnium, and a combustion supporting gas,
such as oxygen, are disposed within the lamp envelope, with the
fill gas being at a pressure of greater than one atmosphere. As
will be detailed hereinafter, the exterior surface of glass
envelope 22 is covered by a vacuum-formed thermoplastic coating 46,
with a plurality of longitudinally extending ribs 48 disposed
between the thermoplastic coating and the glass envelope in
accordance with the invention.
The wire anvil 32 is centered within the tube 30 and is held in
place by a circumferential indenture 38 of the tube 30 which loops
over the head 40, or other suitable protuberances, at the lower
extremity of the wire anvil. Additional means, such as lobes 42 on
wire anvil 32 for example, may also be used stabilizing the wire
anvil, supporting it substantially coaxial within the primer tube
30 and insuring clearance between the fulminating material 34 and
the inside wall of tube 30. A refractory bead 44 is fused to the
wire anvil 32 just above the inner mouth of the primer tube 30 to
eliminate burn through and function as a deflector to deflect and
control the ejection of hot particles of fulminating material from
the primer. The lamp of FIG. 2 is also typically a subminature type
having envelope dimensions similar to those described with respect
to FIG. 1.
Although the lamp of FIG. 1 is electrically ignited, usually from a
battery source, and the lamp of FIG. 2 is percussion-ignitable, the
lamps are similar in that in each the ignition means is attached to
one end of the lamp envelope and disposed in operative relationship
with respect to the filamentary combustible material. More
specifically the igniter filament 12 of the flash lamp in FIG. 1 is
incandesced electrically by current passing through the metal
filament support leads 8 and 10, whereupon the incandesced filament
12 ignites the beads of primer 14 and 16 which in turn ignite the
combustible 18 disposed within the lamp envelope. Operation of the
percussive-type lamp of FIG. 2 is initiated by an impact onto tube
30 to cause deflagration of the fulminating material 34 up through
the tube 30 to ignite the combustible 36 disposed within the lamp
envelope.
As shown in FIG. 3, the plurality of ribs 48 or 21 are equally
spaced about the glass envelope 22 or 2, and adjacent ribs support
an extent 50 of coating wall therebetween which provides flexure
for relieving stresses in the coating. This configuration also has
the advantageous byproduct of providing small air gaps 52 between
the coating and glass surface which tend to thermally insulate the
coating and keep it somewhat cooler (and thereby stronger) during
flashing than is the case when the coating is in full thermal
contact with the glass surface.
One method of providing such a rib-supported lamp coating is
illustrated by FIGS. 4-6. Referring first to FIGS. 4 and 5, the
thermoplastic material to be coated on the exterior surface of the
lamp envelope is initially provided as a preformed sleeve 54 having
the shape of a test tube. To facilitate the one or more metallic
members depending from the lamp envelope (i.e. leads 8 and 10, or
primer tube 30) one or more holes are provided at the bottom of the
test tube shaped sleeve. For purposes of example, the method of
FIGS. 4-6 will be described with reference to vacuum forming the
thermoplastic coating 46 on the percussive lamp of FIG. 2, although
it will be understood that a similar method may be employed with
the electrically ignited lamp of FIG. 1. Accordingly, sleeve 54 is
provided with a single coaxially disposed hole 56 to facilitate
passage of the coaxially projecting primer tube 30. The several
longitudinally extending ribs 48 are molded or otherwise formed on
the inner surface of sleeve 54 and equally spaced thereabout as
shown. Sleeve 54 may be formed by a molding process, and to
minimize possible checks and crazes in the plastic upon being
vacuum formed to the glass envelope, the preformed sleeve 48
generally should be prebaked at about 125.degree.C for at least 15
minutes to drive away residual moisture prior to assembly with the
glass envelope. In most cases, however, such prebaking is not
required for thermoplastic sleeves containing a plasticizer.
In the next step, shown in FIG. 6, the glass envelope 22 of the
percussive lamp is placed within the preformed thermoplastic sleeve
54, with the primer tube 30 projecting through hole 56. It will be
noted that both the sleeve 54 and the lamp envelope 22 have
generally tubular sidewalls. To facilitate the vacuum forming
process, the fit should be as close as possible.
The next step is heating and vacuum forming. The envelope and
sleeve assembly 22, 54 is held during the evacuating and heating
processes by means of a chuck gripping the primer tube 30. Another
chuck, having an evacuating tube, grips the open end of the
thermoplastic sleeve 54. One or more localized sources of heat
encircle the envelope and sleeve assembly for uniformly applying
heat about the tubular sleeve in a substantially localized
elevational plane. In operation, the process comprises drawing a
vacuum in the space between the sleeve 54, and envelope 22, while
simultaneously heating the envelope and sleeve assembly
incrementally along its length. More specifically, the vacuum is
drawn at the open end of sleeve 54, while at the same time, the
heaters are controlled to heat the sleeve to approximately the
softening temperature of the thermoplastic material. A relative
incremental axial movement is effected between the envelope-sleeve
assembly and the heaters, so that incremental heating in a
localized elevational plane starts at the end of the sleeve 54
through which the primer tube 30 projects, and then proceeds toward
the open end of the sleeve from which the vacuum is being drawn. By
proper adjustment of vacuum and forming temperature, the sleeve
conformity to the glass is controlled so that only the sleeve ribs
48 contact the glass. At the conclusion of the incremental heating
process, the sleeve 54 is constricted and tipped off at 58 (FIG.
2), thereby completing the encapsulation of glass envelope 22 in
the thermoplastic coating 46.
Upon cooling, the contraction of the coating 46 is accommodated by
flexure of the coating wall 50 between adjacent ribs 48. FIG. 3
illustrates the final, non-cylindrical form of the coating 46. This
accommodation of shrinkage may be viewed in terms of the length
difference between a segment of the circumference of a circle and
its corresponding chord. Accordingly, the ribbed coating is
self-relieving to provide the desired low stress levels without the
secondary operations of applying a lubricant to the glass surface
or additional stripe heating and cooling steps. In addition, as
previously discussed, the physical properties of the thermoformed
coating are further enhanced by the small thermally insulating air
gaps 52 provided by the rib structure.
Polycarbonate resin has been found to be particularly suitable for
the ribbed coating, however, the composition of sleeve 54, and thus
coating 46, may be of any vacuum formable light-transmitting
thermoplastic material having a reasonably high impact strength and
softening temperature. Suitable materials include acrylic,
acrylonitrile-butadiene-styrene, cellulose acetate, ionomers,
methylpentene polymer, nylon, polycarbonate, polystyrene,
polysulfone, or alloys thereof. In the case of some of the harder
materials, it may also be desirable to add a small amount (1-20%)
of a compatible plasticizer to the composition. Further, commercial
blue dyes can be used in the sleeve, or coating, for color
corrections desirable with various photographic color film.
The principles of this invention could be used in combination with
interfacial lubrication or localized heating to provide stress
relief if so desired. The number of ribs is optimally from six to
12, however, even a single rib would provide some flexural relief
or stress. Above 30 ribs, the difference between the sum of chords
and the circumference of the circumscribed circle is insufficient
to accommodate the shrinkage of most thermoplastics over a glass
object. Resultant stress level may thereby be controlled by
selection of the number of internal ribs in the sleeve. Rib height,
or radially inward extension from the sleeve inner diameter, is
chosen such that formation of a straight chord would result in
tangency or near tangency with the outer wall of the glass envelope
midway between the ribs.
An alternative to the use of internal ribs in a cylindrical sleeve
would be external ribs on the glass envelope. A second alternative
would be insertion of a grid of wire or transparent material
between the glass envelope and plastic sleeve to function in like
manner to the ribs. A third alternative would be to mold the sleeve
in the form of an undulating or corrugated wall rather than as an
essentially cylindrical wall with thickened sections or ribs as
described herein.
Although the invention has been described with respect to specific
embodiments, it will be appreciated that modifications and changes
may be made by those skilled in the art without departing from the
true spirit and scope of the invention.
* * * * *