U.S. patent number 3,822,916 [Application Number 05/307,144] was granted by the patent office on 1974-07-09 for in-situ extraction of mineral values from ore deposits.
This patent grant is currently assigned to Akzona Incorporated. Invention is credited to Charles H. Jacoby.
United States Patent |
3,822,916 |
Jacoby |
July 9, 1974 |
IN-SITU EXTRACTION OF MINERAL VALUES FROM ORE DEPOSITS
Abstract
There is disclosed a method for the in-situ extraction of
metal/mineral values from metalliferous and/or nonmetallic ores
occurring in substantially impermeable ore deposits of the laminar
gneiss or schist or conglomerate types, or the like. The invention
is particularly adaptable for example to the mining of copper and
nickle and manganese carbonate or sulphide type ores. In accordance
with this invention, the geologic formation containing the ore is
first penetrated by two or more, suitably spaced-apart openings,
such for example bore holes extending from the earth's surface to
the bottom level of the deposit. There is then established a
liquid-permeable "base" fractured zone interconnecting the lower
ends of the bore holes within the ore body by means of a
hydraulic-fracturing technique such as described in my U.S. Pat.
No. 3,064,957; the base fracture being propped open by means of any
suitable agent such as described for example in U.S. Pat. No.
2,645,291. An explosive material of liquid or slurry form is then
flowed into the cavitated U-tube system comprising the bore holes
and the "base" fractured zone, thereby replacing the hydraulic
fracturing fluid by an explosive material of fluidized powder or
liquid or slurry form. This operation is conducted under only
substantially the earth's-surface-ambient atmospheric pressure
conditions, thereby eliminating serious prior art hazards. The
explosive is then detonated so as to fracture the overlying ore
body according to the petro-fabrics of the ore deposit and/or the
stress patterns of the mineral constituents thereof. The ore body
is thereby rendered permeable, and a suitable solvent/reactive
material (such as sulphuric acid in the case of the metal
carbonates) for recovery of the desired value-containing salt
solution is then caused to percolate through the permeabilized ore
deposit. The invention also contemplates a specific geometry for
the solvent/reactive flow pattern through the ore body, featuring a
vertical migration and "floating" of the solvent/reactant on top of
the more metal concentrated fraction of the product flow stream;
thereby maintaining an optimum reactant-to-ore status progressively
upwardly within the lateral confines of the ore body. If sulphide
type ores are involved oxygen or air and water may be employed as
an in-situ solvent/reactant.
Inventors: |
Jacoby; Charles H. (Dalton,
PA) |
Assignee: |
Akzona Incorporated (Asheville,
NC)
|
Family
ID: |
23188431 |
Appl.
No.: |
05/307,144 |
Filed: |
November 16, 1972 |
Current U.S.
Class: |
299/4;
166/299 |
Current CPC
Class: |
E21B
43/283 (20130101); E21B 43/17 (20130101); E21B
43/263 (20130101) |
Current International
Class: |
E21B
43/00 (20060101); E21B 43/16 (20060101); E21B
43/28 (20060101); E21B 43/263 (20060101); E21B
43/17 (20060101); E21B 43/25 (20060101); E21b
043/28 () |
Field of
Search: |
;299/4 ;166/299 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Purser; Ernest R.
Attorney, Agent or Firm: Bean & Bean
Claims
I claim:
1. The method for extracting metalliferous values from a laminar
type impermeable metalliferous ore body comprising:
A. penetrating the ore body to provide two or more spaced apart
clear openings extending from the earth's surface and terminating
in portions of the ore body at different elevations;
B. fluid-pressure fracturing the ore body from the bottom end of
the opening terminating at the lowermost elevation upwardly to the
bottom end of another of said openings in the laiminar direction of
the ore body to provide a permeable zone underlying a higher
portion of the ore body of substantial vertical thickness, thereby
establishing a substantially closed fluid circulation system
including said openings and said permeable zone;
C. flowing a fluid type explosive under pressure less than the
fracturing pressure into said circulation system so as to fill said
permeable zone;
D. detonating said explosive so as to permeablize the ore body
thereabove; and
E. then flowing a sought-for metalliferous solvent/reactant fluid
through another of said openings downwardly and through said
circulation system so as to percolate through the permeabilized
portions of the ore body to produce a product fluid containing the
sought-for metalliferous values from the opening terminating at the
lowermost elevation.
2. A method as set forth in claim 1 wherein said openings into said
ore body are provided by two or more horizontally spaced apart bore
holes terminating at their bottom ends at different elevations.
3. A method as set forth in claim 2 wherein said base fracturing
process is repeated as many times as may be necessary to coalesce
the lower ends of at least two bore holes.
4. A method as set forth in claim 1 wherein said base fracturing
process is performed by means of a hydraulic fracturing
technique.
5. A method as set forth in claim 4 wherein said base fracturing
process is conducted initially by means of a hydraulic fracturing
technique, and is supplemented by an explosive fracturing
technique.
6. A method as set forth in claim 1 wherein said fluid type
explosive is flowed into said circulation system by means of a low
pressure pump operating to deliver explosive through the opening
hole terminating at the lowest level.
7. A method as set forth in claim 6 wherein a suction pump is
operably connected to another one of the openings to supplement
flowage of fluid explosive into said system.
8. The method for extracting metalliferous values from a laminar
type impermeable metalliferous ore body comprising:
A. penetrating the ore body to provide two or more spaced apart
clear openings extending from the earth's surface and terminating
in lower portions of the ore body at different elevations;
B. fluid-pressure fracturing the ore body from the bottom end of
the opening terminating at the lowermost elevation upwardly to the
bottom end of another of said openings in the laminar direction of
the ore body to provide a permeable zone underlying a higher
portion of the ore body of substantial vertical thickness, thereby
establishing a substantially closed fluid circulation system
including said openings and said permeable zone;
C. flowing a fluid type explosive under pressure less than the
fracturing pressure into said circulation system so as to fill said
permeable zone;
D. detonating said explosive so as to permeabilize the ore body
thereabove; and
E. then flowing a sought-for metalliferous solvent/reactant fluid
through one of said openings, upwardly and through said circulation
system so as to percolate through the permeabilized portions of the
ore body to produce a product fluid containing the sought-for
metalliferous values from an opening terminating at a higher
elevation.
Description
BACKGROUND OF THE INVENTION
Economically successful methods for the in-situ mining (as by
leaching) of ores have long been sought, as illustrated for example
by way of U.S. Pat. No. 3,574,599; but such methods have proved to
be economically and/or otherwise inadequate for various reasons.
For example, previously proposed and employed methods for
underground fracturing utilizing liquid explosives have
necessitated supply and underground distribution of the liquid
explosive under extremely high pressures (in order to overcome the
hydrostatic pressures at depths below the earth's surface) thereby
inherently rendering such operations highly hazardous, while at the
same time being inefficient from the standpoint of optimum
placement of the liquid explosives. Also, problems associated with
solution-mining gallery maintenance have heretofore rendered such
previously proposed methods economically impracticable; and it is
an object of the present invention to provide an improved method
and system whereby an ore can be reacted in-situ with a suitable
solvent and/or reactant to produce a product solution of the
sought-for mineral such as will flow continuously through a
"production-well" to the earthsurface metal recovery plant, while
leaving behind the residual insoluble gangue material. The
invention also contemplates an improved solvent/reactant solution
flow pattern through the ore body which is operatively maintained
in accordance with specific parameters as disclosed hereinafter,
and as illustrated by way of example in the accompanying drawing,
wherein:
THE DRAWING
FIG. 1 is a symbolical illustration of vertical geological section
type, illustrating a typical ore-bearing schist, gneiss, dike,
sheet, lode, lens, sill or the like which is of limited or varying
vertical thickness; and showing diagrammatically how the initial
ore-body penetration and base fracturing-propping operations are
performed;
FIG. 2 is a view corresponding to FIG. 1, illustrating how the base
fractured zone of the ore-body is subsequently loaded with a liquid
(or slurry) type explosive;
FIG. 3 illustrates how the ore deposit is then beneficially
three-dimensionally fractured so as to accommodate a
dissolution/reaction flowage system in accordance with the
invention;
FIG. 4 illustrates how a leach/ion-reaction mining and
value-recovering operation may then be carried on in accordance
with the present invention; and
FIG. 5 is a view illustrating how the system of the invention is
conducted when operating upon an ore-body of substantially greater
vertical extent than as illustrated at FIGS. 1-4.
SPECIFICATION
It is well known that many copper ore deposits of value occur at
such depths within the earth-surface's geology as to render their
exploitation by typical mechanical mining methods to be not
economically feasible; and it is a primary object of the present
invention to provide a practicable system whereby such deposits may
be economically recovered. As illustrated by the drawing herein,
the method of the present invention is applied to an inclined dike
or other type copper or manganese or the like ore deposit such as
is indicated generally at 10. Such deposits occur at various depths
and distances underground, and are only economically mined by
conventional mechanical mining methods whenever they occur
relatively close to the earth's surface and when they contain
relatively high-grade recoverable mineral values.
According to the present invention as illustrated by way of example
by the drawing herewith, the mineral deposit 10 may be intersected
by a pair of bore holes 12, 14, which extend substantially to the
lower levels of the ore-bearing body and communicate at their upper
ends with appropriate surface plant processing facilities as
indicated at 16, 18. The bore holes are preferably "cased" (as is
well known in the well drilling art) by means of casings fabricated
of or lined with material which is non-reactive relative to the
fluids to be handled. Thus, the bore holes 12, 14, provide means
for ingress to the ore deposit; and preferably the bore hole 12
which intersects the deposit at a lower level than the bore hole 14
is used as the site to "base-fracture" the ore body as indicated at
20 (FIG. 1) thereby utilizing the "uplift" effect of the hydraulic
operation to optimum advantage. The fracturing operation may be
performed in accordance with any suitable hydraulic fracturing
technique; and as previously mentioned it may be performed as
disclosed for example in my U.S. Pat. No. 3,064,957. As shown
therein, the result of such an operation provides a
solution-permeable region designated 20 extending radially from the
bottom of the bore hole 12 toward the bottom of the bore hole 14.
In the case of a copper carbonate ore the fracturing operation is
preferably performed by utilizing a dilute sulfuric acid solution
containing in suspension a fracture "propping" agent such as sand,
glass beads, or the like. Such propping devices are well known in
the art; and a passageway between the lower ends of the bore holes
for introduction of liquid or slurry type explosive is thereby
established.
In event the "base" fracturing process referred to hereinabove does
not operate to coalesce the two or more bore holes the situation
may be remedied by repeated attempts to hydraulically re-fracture
the zone between the bore holes, or by extending the propped cavity
by means of a liquid or slurry type explosive. This may be done
simply by pumping the explosive into the cavity under relatively
low pressure such as is sufficient to displace the hydraulic "frac"
liquid ahead of the explosive. By way of example, the fluid
explosive may be fed into the system by a low pressure pump through
the bore hole 12, supplemented if preferred by use of a suction
pump operatively connected to the upper end of bore hole 14.
The explosive is then detonated, thereby propagating a "base"
fracture toward the target well; but in event this operation still
does not provide an open communication between the bottom ends of
the wells the operations may be repeated as often as may be
necessary (from the same well, or alternatively from either well)
in order to complete an inter-connection between the lower ends of
the wells. The system including the propped base-fractured zone may
now be purged of the residual "frac" liquids and replaced by an
explosive material of liquid or slurry form as shown at 22 (FIG. 2)
simply by flowing it into the system under only substantially
atmospheric pressure condition. This explosive is subsequently
detonated so as to vertically fracture the valuable mineral
containing ore body thereabove, as illustrated at FIG. 3.
The mining process is then conducted by passing a solvent or
reactant liquid and/or gas through the system so as to extract the
desired mineral values from the deposit. For example, as shown at
FIG. 3 the ore-reactant fluid is preferably injected into the ore
body through the bore hole 14 which terminates at a higher
elevation than the other bore hole (s) of the system. The fluid
initially percolates through the lower level of the ore body to the
bottom of the lowermost bore hole 12 for withdrawal to the surface;
the operation being readily controlled by means of a suction pump
or the like located in conjunction with the bore hole 12, and/or a
pressure pump located in conjunction with the bore hole 14
operating to inject the solvent into the system.
The chemical content of the ore-reactant solution will of course be
prescribed and/or adjusted according to the nature of the mineral
content of the ore body from which it is required to extract the
sought-for mineral values. As the ore-reactant operation progresses
the reacting solution forms progressively enlarging voids and/or
passageways through the ore body; the leaching action operating to
"honeycomb" the ore body of the mineral values therein.
Note that the invention contemplates circulation of the
leach/reactant liquid (or gas) through the ore body commencing from
the bottom of the bore hole which stands at the highest elevation
of the group of bore holes involved; the product liquid (or gas)
being withdrawn from the bottom of the deepest bore hole involved.
By virtue of this system advantage is taken of the phenomenon that
the mineral-laden liquid (or gas) will be of higher specific
gravity than the fresh solvent/reactant and will automatically
migrate down towards the bottom of the bore hole 12, while the
fresh solvent/reactant fractions will float on top so that the
leach/reaction process automatically progresses vertically from
along the lower level of the mineral deposit upwardly therefrom and
to the top level thereof. Otherwise stated the mineral-value-laden
liquid (or gas) will automatically keep migrating toward the
entrance to the product withdrawal bore hole, while the relatively
fresh leach/reactant input is automatically disposed to percolate
through progressively higher (still mineral-value laden) levels of
the ore body.
Should the above described system operate to mine only the lower
portion of the ore body (such as in the case of an ore deposit of
substantial vertical extent as illustrated for example at FIG. 5
herein) the system may be repeated as many times as necessary to
fracture and mine successively higher levels of the ore body. To
this end the same bore holes may be employed after first mining the
lower portion of the ore body by temporarily blocking off the lower
end of the bore hole/casing system as shown at 26; perforating the
system at a substantial elevation above the blocking 26;
hydraulically fracturing a vertically intermediate portion of the
ore body as indicated at 30; and then repeating the above described
fluid explosive replacement and detonating operations so as to
shatter and permeablize the vertically intermediate portion of the
ore body.
Note that as illustrated at FIG. 5, herein, detonation of the fluid
explosive occupying the fractured zone 30 will operate to fracture
the ore body both downwardly and upwardly therefrom; the downward
fracturing effects being facilitated by reason of the previous
honeycombing of the underlying portion of the ore body as explained
hereinabove. Thus, it will be understood that in the case of an ore
body of extreme vertical extent the above described progressive
level fracturing and mining operations may be repeated until mining
of the entire ore body is completed.
* * * * *