U.S. patent number 3,818,869 [Application Number 05/320,365] was granted by the patent office on 1974-06-25 for method of operating a combined gasification-steam generating plant.
This patent grant is currently assigned to Combustion Engineering, Inc.. Invention is credited to Henry John Blaskowski.
United States Patent |
3,818,869 |
Blaskowski |
June 25, 1974 |
METHOD OF OPERATING A COMBINED GASIFICATION-STEAM GENERATING
PLANT
Abstract
A steam generating plant is provided which includes an
entrainment, slagging, air blown atmospheric pressure coal
gasifier, a heat recovery train, atmospheric pressure
desulfurization and a steam generator designed to burn the low Btu
fuel gas produced in the gasifier. Heat recovered from the gas
produced in the gasifier is used to raise the temperature of a
portion of the steam generator feedwater, generate steam for use in
the gasifier, and to reheat the fuel gas following desulfurization.
Heat recovered from boiler flue gas is utilized in drying and
preheating the reactants to the gasifier.
Inventors: |
Blaskowski; Henry John (West
Simsbury, CT) |
Assignee: |
Combustion Engineering, Inc.
(Windsor, CT)
|
Family
ID: |
23246087 |
Appl.
No.: |
05/320,365 |
Filed: |
January 2, 1973 |
Current U.S.
Class: |
122/5; 48/206;
110/345; 110/229 |
Current CPC
Class: |
C10J
3/506 (20130101); C10J 3/845 (20130101); C10J
3/86 (20130101); C10J 3/466 (20130101); C10J
3/74 (20130101); C10J 2300/0959 (20130101); C10J
2300/0976 (20130101); C10J 2300/093 (20130101); C10J
2300/0906 (20130101); Y02P 20/124 (20151101); C10J
2300/1892 (20130101); Y02P 20/10 (20151101); C10J
2300/1807 (20130101); C10J 2300/1253 (20130101); C10J
2300/1884 (20130101); Y02P 20/129 (20151101); C10J
2300/0909 (20130101); C10J 2300/0956 (20130101) |
Current International
Class: |
C10J
3/86 (20060101); C10J 3/00 (20060101); C10J
3/46 (20060101); C10j 001/00 () |
Field of
Search: |
;122/5 ;110/31
;48/206 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Sprague; Kenneth W.
Attorney, Agent or Firm: Goettel, Jr.; Frederick A.
Claims
What is claimed is:
1. A method of operating a steam generating plant in conjunction
with a coal gasification plant which produces gaseous fuel to be
burned in the steam generating plant, comprising the steps of:
producing a low Btu gaseous fuel in said gasifier by the reaction
at high temperatures of oxygen and steam with a solid carbonaceous
fuel;
flowing the gaseous fuel from the gasifier in heat exchange
relation with a flow of water;
passing said flow of water through the walls of said gasifier to
effect the cooling thereof;
burning said gaseous fuel in said steam generating plant to produce
heat for the generation of steam therein; and
conducting the hot water exiting from said gasifier walls to the
boiler of said steam generating plant.
2. A method of operating a steam generating plant in conjunction
with a coal gasification plant which produces gaseous fuel to be
burned in the steam generating plant, comprising the steps of:
burning a first reactant stream of pulverized coal and preheated
stoichiometric air in said gasifier to produce hot product of
combustion gases;
reacting a second reactant stream of pulverized coal and steam with
said hot product of combustion gases in said gasifier to produce a
low Btu gaseous fuel therein;
flowing water through the walls of said gasifier to effect the
cooling thereof;
burning said gaseous fuel in said steam generating plant to produce
heat for the generation of steam therein; and
conducting the hot water exiting from said gasifier walls to the
boiler of said steam generating plant.
3. The method of claim 2 including the steps of flowing the hot
gaseous fuel from the gasifier in heat exchange relation with
process water to form steam; and
mixing the steam formed in the preceeding step with pulverized coal
to form said second reactant stream.
4. The method of claim 2 including the steps of: flowing the hot
flue gases from the steam generating plant in heat exchange
relation with atmospheric air to raise the temperature of said
air;
mixing a first portion of said air with pulverized coal to dry the
coal; and
mixing a second portion of said air along with said previously
mixed air and pulverized coal, to form said first reactant
stream.
5. The method of claim 2 including the steps of:
mixing a quantity of hot flue gases from the steam generating plant
with pulverized coal to lower the moisture content of the coal;
separating the dry pulverized coal from the hot flue gases;
and;
mixing the dry puvlerized coal with steam to form said second
reactant stream.
6. A method of operating a steam generating plant in conjunction
with a coal gasification plant which produces gaseous fuel to be
burned in the steam generating plant, comprising the steps of:
producing a low Btu gaseous fuel in said gasifier by the reaction
at high temperatures of oxygen and steam with a solid carbonaceous
fuel;
flowing water through the walls of said gasifier to effect the
cooling thereof;
cooling the gaseous fuel from the gasifier by passing it in heat
exchange relation with the fluid in one half of a fluid coupled
heat exchanger;
removing the H.sub.2 S from the gaseous fuel;
reheating the cleaned gas by passing it in heat exchange relation
with the fluid in the second half of said fluid coupled heat
exchanger;
burning said gaseous fuel in said steam generating plant to produce
heat for the generation of steam therein; and
conducting the hot water exiting from said gasifier walls to the
boiler of said steam generating plant.
7. The method of claim 1 wherein the step of producing a low Btu
gaseous fuel comprises the steps of:
burning a first reactant stream of pulverized coal and preheated
stoichiometric air in said gasifier to produce hot product of
combustion gases; and
reacting a second stream of pulverized coal and steam with said hot
product of combustion gases.
8. The method of claim 7 including the steps of:
flowing the hot gaseous fuel from the gasifier in heat exchange
relation with process water to form steam; and
mixing the steam formed in the preceeding step with pulverized coal
to form said second reactant stream.
9. The method of claim 8 including the steps of:
flowing the hot flue gas from the steam generating plant in heat
exchange relation with atmospheric air to raise the temperature of
the air;
mixing a first portion of said heated air with pulverized coal to
dry the coal;
mixing a second portion of said air along with said previously
mixed air and pulverized coal, to form said first reactant
stream;
mixing a quantity of hot flue gases from the steam generating plant
with pulverized coal to dry the coal;
separating the dry pulverized coal from the hot flue gases; and
using said dry pulverized coal as the coal which is mixed with
steam to form said second reactant stream.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to steam generating plants and more
particularly to a system wherein a steam generator is integrated
with an on-site coal gasification plant which provides a low Btu
gaseous fuel for the steam generator.
2. Description of the Prior Art
The electric utility industry in the United States is currently the
target of many regulatory agencies and environmental groups whose
goal is the reduction or elimination of objectionable emissions
such as sulfur oxide, nitrogen oxide, and particulate matter from
the stacks of power generating stations. Of the many solutions to
this problem now being studied one of the most promising for near
term relief is the on-site gasification and desulfurization of a
high sulfur content coal to produce a clean burning low Btu fuel
gas which may be burned in a steam generator. Various systems
making use of this idea have been proposed; however, none have
appeared particularly attractive from an economic standpoint,
primarily because of the gasification losses where as much as 20
percent of the Btu content of the coal may be lost.
BRIEF SUMMARY OF THE INVENTION
In accordance with the invention there is provided a steam
generating plant fully integrated with a coal gasification plant
which produces a gaseous fuel to be burned in the steam generating
plant. The interrelationship of the two plants is such as to take
maximum advantage of the available Btu content of the coal.
The hot gas formed in the gasifier is passed through a series of
three heat exchangers to effect cooling thereof before it is sent
to a desulfurization complex where the hydrogen sulfide present in
the gas is removed. Heat is extracted in the first of the series of
heat exchangers using water as the heat exchange fluid. The hot
water from this heat exchanger is then circulated through water
cooling passages in the walls of the gasifier itself where
additional heat is extracted. This hot water is then passed
directly to the boiler of the steam generator. Heat extracted in
the second heat exchanger is used to generate steam which is used
as a reactant in the gasifier. The third heat exchanger is one-half
of a fluid coupled heat exchanger and its function is to further
cool the gas prior to desulfurization. The desulfurized gas passing
from the desulfurization complex is then reheated in the second
half of the fluid coupled heat exchanger, prior to being burned in
the steam generator.
A gas storage capacity is included in the system in order to permit
the gas supply to more promptly respond to increases in demand from
the steam generator.
Other important features of the invention include; the use of the
steam generator air preheater to provide hot air, which is used to
dry a portion of the coal to be gasified and as a source of oxygen
in the gasification reaction, and the use of spent flue gas from
the steam generator to dry another portion of the coal.
Other objects and advantages of the invention will become apparent
upon reading the following detailed description of an illustrative
embodiment and upon reference to the drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a schematic representation of a steam generating plant
embodying the principles of the invention.
FIG. 2 is a schematic showing a representative desulfurization
complex which may be used with the system and the gas storage
system of the invention.
DESCRIPTION OF THE PREFERRED EMBODIMENT
Referring to FIG. 1 there is shown a gasifier 10 for producing a
low Btu gaseous fuel, by the reaction at high temperatures of
oxygen and steam with a solid carbonaceous fuel, and a steam
generator 12 having a boiler 14 adapted to burn the low Btu gas
produced by the gasifier 10.
With the exception that the burners (not shown) in the boiler
furnace 16 are adapted to burn a low Btu gas the steam generator 12
is of a conventional design. Air for combustion is supplied to the
boiler furnace 16 by the forced-draft fan 18, which takes
atmospheric air and forces it through the air preheater 20 and into
the furnace 16 to be burned with the low Btu gas which enters the
furnace along with the air as shown at 22. The product of
combustion gases from the furnace 16 are removed by an induced
draft fan 24 and are drawn successively through the superheater 26
where the steam temperature is raised above that existing in the
boiler, the reheater 28 where superheat is added to the steam
between power turbine stages, the economizer 30 where feedwater to
the boiler 14 is heated, and the air preheater 20, and discharged
to the stack 32.
Turning to the gasifier 10, its operation and association with the
steam generator 12 in such a way as to make maximum use of the heat
generated in both systems will now be described. The gasifier 10 is
of the entrainment, slagging, air blown atmospheric pressure type,
and makes use of the so-called two stage reaction process.
The first reaction stage, which takes place in the lower end of the
reactor involves the near complete combustion of a quantity of
pulverized coal with preheated air in stoichiometric proportions.
These reactants are injected into the gasifier through a plurality
of burner nozzles, one of which is shown schematically at 34. These
burners 34, in a typical gasifier of this type having a circular
cross section, are equally spaced about the outer circumference of
the gasifier and operate in the same manner as the burners
conventionally utilized in pulverized coal fired steam generating
boilers. Primary air and the pulverized coal are delivered to the
burner 34 through a coal pipe 36 while the balance of the air, the
secondary air is delivered through a separate conduit 38 and mixed
with the primary air and coal as it leaves the burner nozzles.
The mixture of primary air and pulverized coal is prepared in the
combustor mills 40, which may be of any well known design such as a
bowl mill or a ball mill. Coal is supplied to the combustor mills
40 from a suitable source, as represented at 42, while the primary
air is supplied through conduit 44. The air entering the mill
through conduit 44 is preferably maintained at a temperature
between about 550.degree.-600.degree. F. This temperature is
maintained by mixing, as shown at 50, a stream of hot air 46, which
has passed through the air preheater 20 of the steam generator 12,
with a stream of cooler atmospheric air 48. Both streams of air are
provided by a fan 51, the cool air being bled off from the main
stream 52 before it passes through the air preheater 20. The stream
of hot air 46 to the combustor mills is taken from the main stream
of hot air 52 as required while the balance of this air passes to
the burner 34 through the secondary air conduit 38. Such an
arrangement is typical of pulverized coal burning equipment and is
designed to reduce the moisture content of the coal to an
acceptable level and to preheat it to a temperature generally not
exceeding 180.degree. F.
The complete combustion of these reactants which occurs upon their
injection into the gasifier 10 results in the production of a very
high temperature product of combustion gas. This high temperature,
preferably 3100.degree.F or above is required for two reasons: it
is above the fusion temperature of the ash in the coal, thus
resulting in the formation of molten slag which is removed from the
lower end of the reactor by a suitable slag disposal system 54; and
it provides, in the form of the hot rising gases, a high
temperature heat source which is necessary to sustain the primarily
endothermic reduction reaction, the second stage of gasification,
which occurs in the region overlying the combustion zone.
The second reaction stage involves the reaction of a second stream
of reactants, containing pulverized coal and steam, with the hot
gases rising from the oxidation or combustion zone. As indicated
the reactions occurring here are primarily endothermic and result
in the formation of a low Btu fuel gas containing mostly carbon
monoxide and hydrogen with some methane. Hydrogen sulfide in
quantities proportionate to the initial sulfur content of the coal
is also present in the gas.
The stream of steam and coal for the second reaction stage is
injected into the gasifier at 56 and is supplied thereto by means
of a suitable conduit 58 which communicates with a mixing chamber
60. The mixing chamber 60 is in turn supplied with separate streams
of dried pulverized coal 62 and steam 64. The coal is pulverized
and dried in the reductor mills 66 which are, as were the combustor
mills 40, of conventional design. The drying of the coal in the
reductor mills 66, which is supplied from the same coal source 42
as the combustor mills, is accomplished by passing through the
mills a stream of hot flue gas 68, passing from the steam generator
economizer 30. This gas is drawn from the passage 70, through duct
72, by a suitable fan 74 and delivered to the mills 66 through duct
76. Hot flue gas, instead of hot air, is used to dry this coal in
order to insure a minimum oxygen level in the coal when it enters
the gasifier.
The dry coal/flue gas mixture from the reductor mills 66 is then
passed through a cyclone separator 78, where the coal and flue gas
are separated, and the coal is passed from the bottom of the
separator as at 62 to the mixing chamber 60. The flue gas from the
separator 78 is drawn out through conduit 80 by means of a fan 82.
This gas is at a substantially reduced temperature and a portion of
it is recirculated through duct 84 to the duct 76 which carries
flue gas to the reductor mills 66 thereby maintaining the
temperature of this gas in the range needed to accomplish
sufficient drying of the coal in the mills. The balance of the flue
gas passing from fan 82 is drawn by a second fan 86 and directed to
a wet scrubber 88 which removes any particles of pulverized coal
which may have passed with the gas through the cyclone separator 78
before directing it to the stack 32 and thence to the
atmosphere.
The gaseous fuel exiting from the gasifier is preferably at a
temperature ranging up to about 1,700.degree. F. This is
considerably cooler than the 3,100.degree. F existing in the
combustion zone, due to the endothermic nature of the reactions in
the reduction zone, however, the gas still contains a large
quantity of sensible heat which should be utilized in order to
increase the overall efficiency of the entire system. Accordingly,
the hot fuel from the gasifier 10 is passed directly, through
conduit 90, to a high pressure heat exchanger 92 where it gives up
heat to water bled through pipe 94 from the boiler feedwater supply
line 96. In a typical installation the water passing through the
high pressure heat exchanger 92 would enter at a pressure of 3,050
psia and a temperature of 487.degree. F and leave at 3,000 psia and
630.degree. F. The hot water from this heat exchanger 92 is then
passed via conduit 98 to the inlet manifold (not shown) of a water
wall cooling system in the gasifier 10. The water is circulated
through the wall cooling system where it is further heated so that
the water exiting from the system, at 99, is at a temperature and
pressure of 690.degree. F and 2,900 psia respectively. This water
is then directed through conduit 100 to the steam generator 12
where it is admitted directly to the boiler steam drum 102.
The gaseous fuel passes from the high pressure heat exchanger at a
reduced temperature of about 1,040.degree. F, and is conducted
directly through conduit 104 to a low pressure heat exchanger 106.
The heat exchange fluid in the low pressure heat exchanger is a
suitable supply of process water 108 at atmospheric pressure which
is converted to steam by the passage therethrough. The steam
generated therein typically will be at 700.degree. F and 165 psia,
and passes from the heat exchanger 106 through a suitable steam
line 110 to the mixing chamber 60, thus providing the steam supply
required to carry out the gasification reaction.
The gas passing from the low pressure heat exchanger 106 is reduced
in temperature to about 640.degree. F. It is then further cooled to
about 300.degree. F before entering the desulfurization complex 114
by passing through the first section 112 of a fluid coupled heat
exchanger 115. The fluid coupled heat exchanger 115 comprises two
heat exchange sections 112, 113 remotely located from one another
and interconnected by a flow of heat exchange fluid through closed
circuit flow path 116. Fluid flow through this circuit is
maintained by a suitable pump 117. The second section 113 of the
fluid coupled heat exchanger 115 returns to the gas the heat
removed from it in the first section 112, after the gas has been
desulfurized as will be described hereinbelow. Each of the three
heat exchangers 92, 106, 112 through which the gas passes prior to
desulfurization is provided at the bottom of the gas passage with a
hopper to collect char which may accumulate. This char is
periodically recycled back to the gasifier through recycling lines
109.
As indicated above the gas passes from the first section 112 of the
fluid coupled heat exchanger 115 to the desulfurization complex 114
where the hydrogen sulfide present in the gas is removed.
Desulfurization may be carried out by one of several known
processes such as for example solvent extraction, or dry
techniques. A typical desulfurization system is shown in FIG. 2 and
will be described in connection with a fuel storage arrangement
also illustrated therein.
Referring to FIG. 2 the gas from the first section of the fluid
coupled heat exchanger 112 passes first to a raw gas scrubber 118
where any remaining particulates are removed from the gas and it is
further cooled by adiabatic humidification. The water spray 119 to
the gas scrubber 118 saturates the gas and cools it to the dew
point. In order to preclude formation of hydrogen sulfide and the
resulting acid corrosion which would occur, a heater 120 positioned
at the top of the scrubber 118 raises the temperature of the
exiting gas to about 10.degree. F above the dew point. The gas then
flows via conduit 122, through a booster fan 124 to the absorber
126 where the H.sub.2 S is removed as a result of chemical
reactions occurring upon exposure of the H.sub.2 S in the gas with
a suitable absorption solution, which is admitted at 127.
The used solution from the absorber is pumped, by pump 128, to the
regenerator 130 where air is blown through the solution as at 132.
The air regenerates the absorbant to an oxidizing from so that it
may be returned through sulfur melt tank 134, and cooler 136 to the
absorber 126 where it is reused. Elemental sulfur is separated from
the absorbant upon passage through the sulfur melt tank 134 and the
sulfur is heated therein so that it may be conveniently removed in
a liquid form for disposal.
The desulfurized gas passing from the absorber is then conducted,
as needed, through conduits 138 and 140 (FIGS. 1 and 2) to the
second section 142 of the fluid coupled heat exchanger 116 where it
is reheated, and from there through conduit 141 to the steam
generator 12 to be burned.
In order to provide for occasional imbalance which may exist
between the gasifier output and steam generator demand a gas
compression and storage capability is provided in the system.
Referring to FIG. 2, during periods when steam generator demand is
less than gasifier output, quantities of clean gas passing from the
absorber 126 are compressed by compressor 144, further reduced in
volume by cooler 146, and then passed to storage tank 148 where it
is stored at about 150 psia. When steam generator demand
temporarily exceeds gasifier output the quantity of gas necessary
to supplement the gasifier output in order to meet the demand is
supplied from the storage tank 148. The flow of gas from the tank
148 is controlled by a throttling valve 150 which is located in the
tank storage supply conduit 152 which ties into the conduit 140
which feeds the gas to the steam generator. The throttling valve
150 also serves to let down the pressure of the gas coming from the
storage tank 148 to atmospheric pressure.
The diversion of gas to the storage tank 148 of course can only be
carried out when the tank is at less than full capacity.
Accordingly, when the tank is full and the steam generator demand
is less than maximum, the output of the gasifier must be reduced to
match the steam generator demand.
While this preferred embodiment of the invention has been shown and
described, it will be understood that it is merely illustrative and
that changes may be made without departing from the scope of the
invention as claimed.
* * * * *