U.S. patent number 3,818,105 [Application Number 05/174,231] was granted by the patent office on 1974-06-18 for composition and process for lubricating the skin.
This patent grant is currently assigned to Esso Research and Engineering Company. Invention is credited to Myron Coopersmith, Lanny G. Felty, Wayne N. Kochenderfer.
United States Patent |
3,818,105 |
Coopersmith , et
al. |
June 18, 1974 |
COMPOSITION AND PROCESS FOR LUBRICATING THE SKIN
Abstract
C.sub.12- C.sub.14 isoparaffinic hydrocarbon fractions are
effective skin lubricants and cosmetic formulation constituents.
The paraffinic oils possess a unique combination of properties,
namely, low viscosity, moderate volatility, plus the ability to
disperse dyes and/or pigments. Typically, the isoparaffinic
hydrocarbon fraction makes up less than 50 weight % of the total
cosmetic formulation and are normally admixed with water,
monoalkanols, alkyl and aryl esters, humectant compositions,
surfactants, lanolin, white oils, pigments, dyes, clays, perfumes
and mixtures thereof.
Inventors: |
Coopersmith; Myron (Livingston,
NJ), Kochenderfer; Wayne N. (Red Bank, NJ), Felty; Lanny
G. (Jackson Twp., NJ) |
Assignee: |
Esso Research and Engineering
Company (Linden, NJ)
|
Family
ID: |
22635368 |
Appl.
No.: |
05/174,231 |
Filed: |
August 23, 1971 |
Current U.S.
Class: |
514/789; 424/63;
424/73; 514/846; 514/940; 514/942; 514/943; 424/64; 514/845;
514/939; 514/941; 424/70.6; 424/70.1; 424/70.7 |
Current CPC
Class: |
A61Q
19/10 (20130101); A61Q 1/08 (20130101); A61K
8/062 (20130101); A61Q 5/12 (20130101); A61K
9/0014 (20130101); A61K 47/06 (20130101); A61Q
9/02 (20130101); A61Q 5/06 (20130101); A61K
8/31 (20130101); Y10S 514/846 (20130101); Y10S
514/942 (20130101); Y10S 514/939 (20130101); Y10S
514/845 (20130101); Y10S 514/941 (20130101); Y10S
514/94 (20130101); Y10S 514/943 (20130101) |
Current International
Class: |
A61K
47/06 (20060101); A61k 007/00 (); A61l
023/00 () |
Field of
Search: |
;424/358,70,73,63,64,168,170,171,172,355 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
wells et al., Cos. & The Skin, Reinhold Pub. N.Y., 1964, pp.
654-654. .
DeNavarre, The Chem. & Mfg. of Cos., 2nd ed, Vol. II, pp.
359-367..
|
Primary Examiner: Meyers; Albert T.
Assistant Examiner: Fagelson; Anna P.
Claims
What is claimed is:
1. A cosmetic composition for lubricating the skin comprising an
admixture of cosmetic conditioning materials in an oil and water
emulsion including 0.5 to 50 weight percent, based on the total
composition, of a lubricant C.sub.12 -C.sub.14 isoparaffinic
hydrocarbon fraction boiling in the range of about 225.degree. to
225.degree.C.
2. A process for lubricating the skin which comprises applying to
the skin a cosmetic formulation comprising an admixture of cosmetic
materials and a lubricating effective amount of from 0.5 to 50
weight percent based on total formulation of a C.sub.12 -C.sub.14
isoparaffinic hydrocarbon fraction boiling in the range of about
225.degree. to 255.degree.C.
Description
BACKGROUND OF THE INVENTION
I. Field of the Invention
This invention relates to cosmetic formulations and a method for
the beneficiation of the human body, in particular the hair, nails
and skin of the cosmetic user. More particularly, the invention
relates to cosmetic formulations comprising an effective amount of
a C.sub.12 -C.sub.14 isoparaffinic hydrocarbon fraction and to a
process for using the same.
II. Description of the Prior Art
Various types of hydrocarbon materials have been employed as
constituents in cosmetic formulations. The most commonly employed
hydrocarbon materials are the relatively high molecular weight,
high boiling, white mineral oils and petrolatums (see "Cosmetics
and The Skin" by Wells and Labowe, pp. 654-657 and "The Chemistry
and Manufacture of Cosmetics", by Maison G. DeNavarre, Volume II,
second Edition, pp. 359-367). Mineral oils and petrolatum are used
in cosmetic products primarily because of their neutral, stable,
and odorless character. These compositions are heavy, viscous
materials that are substantially non-volatile at atmospheric
conditions and which do not serve as dispersion media for dyes or
pigments in cosmetic preparations. The use of lower molecular
weight, more volatile hydrocarbon materials has also been reported
in the literature. Specifically, Kambersky in U.S. Pat. No.
3,211,618 reported that paraffins, in particular isoparaffins
(branched hydrocarbons) having a boiling range between
160.degree.-200.degree.C., could be used as a volatile constituent
for eyelash and eyebrow cosmetics. Also in U.S. Pat. No. 2,439,088,
the use of a hydrocarbon solvent for cosmetic preparations is
disclosed, specifically C.sub.11 to C.sub.13 isoparaffins having a
boiling range of 183.degree. to 222.degree.C. are taught as useful
in combination with cosmetic powders and waxes.
Such materials, because of their very high volatility, give
relatively little "duration of feel" and cosmetic materials
prepared containing the same, quickly lose effectiveness, as the
hydrocarbon constituents evaporate within a few minutes after
application.
SUMMARY OF THE INVENTION
In accordance with the present invention, it has been found that
C.sub.12 -C.sub.14 isoparaffinic fractions composed of branched
chain aliphatic and naphthenic materials are highly effective
constituents for a wide spectrum of cosmetic formulations and
topical pharmaceuticals. The preferred paraffin materials are
composed of a major amount, i.e., more than 50 weight % of
branched, noncyclic, nonsubstituted, aliphatic hydrocarbons having
from 12 to 14 carbon atoms and a minor amount, i.e., up to 50
weight % of alicyclic, nonsubstituted, naphthenic hydrocarbons. The
C.sub.12 -C.sub.14 isoparaffinic hydrocarbon fractions are
colorless, essentially odorless compositions that possess low
viscosity and moderate evaporation properties. The unique
combination of volatility and viscosity of these materials permits
the skin to be lubricated by a quick spreading, nongreasy oil that
evaporates after use and thereby does not permit residual oil
buildup. Typically, cosmetic formulations contain less than about
50 wt. % of the C.sub.12 -C.sub.14 isoparaffinic hydrocarbon
fraction and are normally employed in combination with various
types of typical cosmetic ingredients.
The isoparaffinic hydrocarbon fractions employed in this invention
are obtained by distillation of suitable fractions of motor fuel
alkylation bottoms. The C.sub.12 -C.sub.14 fraction boiling between
about 225.degree. to 255.degree.C. are then purified to cosmetic
grade quality.
As noted earlier, usable hydrocarbon fractions are C.sub.12
-C.sub.14 isoparaffinic hydrocarbon fractions. The expression
"C.sub.12 -C.sub.14 isoparaffinic hydrocarbon fraction" as used
herein is meant to encompass hydrocarbon compositions composed of a
major amount, i.e., greater than 50%, preferably from about 70 to
90%, most preferably from about 70 to 80% of branched chain,
noncyclic, nonsubstituted aliphatic hydrocarbons having from 12 to
14 carbon atoms and a minor amount of alicyclic nonsubstituted,
napthenic hydrocarbons. The useful hydrocarbon materials have a
distillation range (atmospheric boiling points) varying from about
225.degree. to 225.degree.C. as determined by ASTM Method D 86. The
properties of a typical C.sub.12 -C.sub.14 isoparaffinic
hydrocarbon fraction are as follows: Specific gravity at
20/20.degree.C. of 0.788 as determined by ASTM Method D 1217; a
kinematic viscosity of 4.6 centistokes at 20.degree.C. as
determined by ASTM Method D 445; a SSU viscosity at 100.degree.F.
of about 36; a refractive index (n.sub.D.sup.20) of 1.439 as
determined by ASTM Method D 1218; a flash point of 190.degree.F.
(COC) as determined by ASTM Method D 56; a pour point of
<-76.degree.F. as determined by ASTM Method D 97; a surface
tension of about 25.0 dynes/centimeter at 25.degree.C; and an
interfacial tension (on water) of about 53.0 dynes/centimeter at
25.degree.C.
The isoparaffinic hydrocarbon is used in admixture with one or more
additional ingredients to arrive at a final cosmetic formulation.
Typically, the isoparaffinic hydrocarbon is used in cosmetic
formulations in amounts less than about 50 wt. %, generally from
0.5 to 50 wt. %, based on total formulation. The amount of
isoparaffinic hydrocarbon employed depends primarily upon the
cosmetic type. For example, the isoparaffinic oil may make up only
about 5 wt. % of liquid make-up compositions whereas concentrations
approaching 50 wt. % of the isoparaffinic hydrocarbon may be used
in spreading bath oils.
The isoparaffinic hydrocarbon is used in cosmetic formulations in
admixture with one or more of the following substituents:
1. Water;
2. C.sub.2 -C.sub.4 monoalkanols, e.g., ethanol, isopropanol,
butanol, etc.;
3. Organic ester dispersion media, e.g., C.sub.8 -C.sub.26
aliphatic and aromatic acid esters of C.sub.2 -C.sub.6
monoalkanols, for example, diisopropyl adipate, isopropyl
myristate, butyl stearate, etc.;
4. Humectant compositions, in particular polyhydroxy compounds such
as dipropylene glycol, glycerol, polyethylene gylcol, propylene
glycol, sorbitan, butanediol, etc.;
5. Lanolin;
6. Clay minerals and inorganic silicates, for example, kaolin,
bentonite, zeolite, talc, Fullers earth, diatomaceous eath, zinc
silicate, lithium silicate, etc.;
7. Dyes and metal oxide pigments such as titanium dioxide, zinc
oxide, iron oxide, etc.;
8. Surfactant compositions, e.g., (a) sulfonated and sulfated oils
such as sulfonated normal glycerides, sulfated fatty alcohol
ethoxylates, sulfated glycol monoesters, sulfonated methyl, ethyl
and butyl fatty acid esters, etc.; (b) alkylaryl sulfonates, such
as dodecyl benzene sulfonates; (c) ammonium, calcium, magnesium,
potassium, sodium, zinc and alkanol amine derivatives of sulfated
C.sub.12 -C.sub.14 alcohols such as sodium myristyl sufate, sodium
lauryl sulfate, etc.; (d) quaternary ammonium compounds such as
lauryl- and stearyl-dimethylbenzyl ammonium chloride; (e)
alkoxylated, in particular, ethoxylated higher fatty alcohols,
higher fatty acids, fatty esters, alkylphenols, etc.;
9. Animal, vegetable and hydrocarbon waxes such as beeswax,
carnauba, jojoba, paraffin wax, microcystalline hydrocarbon wax,
etc.;
10. White oils and petrolatum; and
11. Perfume and fragrance materials.
The isoparaffinic hydrocarbon materials, can of course be used in
cosmetic formulations that contain materials other than those
specified above. The above listing is intended to indicate that the
subject C.sub.12 -C.sub.14 isoparaffinic materials can be used in a
wide range of cosmetic formulations. For example, the hydrocarbon
materials can be used in face make-up, body make-up, eye shadow,
mascara, hair coloring, dyeing preparations, lip rouge, cheek
rouge, masking preparations, eyebrow preparations, eyeliner, hand
cleaners, bath oils, as well as other types of oil and water
emulsions, water-in-oil emulsions, alcoholic emulsions, wax and oil
mixtures, soaps, wax mixtures, oil mixtures, etc. As mentioned
earlier, the hydrocarbon materials are highly effective dispersant
media for the pigment and dye materials normally employed in
cosmetic formulations. Hence, the C.sub.12 -C.sub.14 isoparaffin
hydrocarbon materials can be used in the place of typical ester
dispersion media (Item (3) above) thereby permitting the
formulation of make-up type materials without using the ester
dispersion compositions.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The utility of the isoparaffinic hydrocarbon materials as cosmetic
ingredients is shown in the following formulations:
EXAMPLE 1
A pre-electric shave lotion was prepared by admixing the following
ingredients:
Formula Weight % ______________________________________ C.sub.12
-C.sub.14 isoparaffinic fraction 17.0 Ethanol 79.7 Perfume Oil 0.3
Hexadecyl Alcohol (Branched chain) 3.0
______________________________________
EXAMPLE 2
A cationic hair conditioner was prepared from the following
materials:
Part A Weight % ______________________________________ C.sub.12
-C.sub.14 isoparaffin fraction 15.0 Hexadecyl Alcohol (Branched
chain) 5.0 Glycerol Monostearate 5.0 Stearyl Alcohol 5.0
Polyoxyethylene (20) Oleyl Ether 2.5 Dialkylaminoalkyl Palmitamide
1.0 Propyl-P-Hydroxybenzoate 0.1 Part B Weight %
______________________________________ Water, Deionized 60.6
Propylene Glycol, USP 5.0 Methyl-P-Hydroxybenzoate 0.2 Phosphoric
Acid (85 wt. %) 0.2 Part C Weight %
______________________________________ Perfume oil 0.4
______________________________________ The conditioner was
formulated by heating Part A to 70.degree.-75.degree.C. and Part B
to 65.degree.-70.degree.C. and then admixing the same with
stirring. The resulting emulsion is then permitted to cool to
25.degree.-50.degree.C. with stirring. Thereafter, Part C is added
to the mixture to secure the final formulation.
EXAMPLE 3
A hair groom and conditioner was prepared from the following
materials:
Part A Weight ______________________________________ C.sub.12
-C.sub.14 isoparaffin fraction 19.6 Mineral oil (185 SSU viscosity
4.9 at 100.degree.F.) Lanolin (anhydrous) 1.9 Ethoxylated Lanolin
1.9 Sorbitan monooleate 2.6 Polyoxyethylene (20) sorbitan
monooleate 5.3 Polyethoxylated beeswax 3.9 Polyethylene glycol
(M.W. 2000) 4.8 Propyl-p-Hydroxybenzoate 0.2 Part B Weight %
______________________________________ Water, deionized 42.3 Part C
Weight % ______________________________________ Carbopol 960
(Carboxy vinyl polymer) 0.4 Part D Weight %
______________________________________ Propylene glycol 1.9
Polyoxyethylene (12) lauryl ether 9.8 Methyl-p-hydroxybenzoate 0.2
Part E Weight % ______________________________________ Perfume Oil
0.03 ______________________________________ The product was
prepared by first mixing Part B and Part C with stirring and then
Part D with the initial B-C mixture. The B-C-D mixture is then
heated 70.degree.-75.degree.C. with stirring. Thereafter Part A is
heated to 75.degree.-80.degree.C. with stirring and mixed with the
B-C-D mixture. The A-B-C-D mixture is then cooled with stirring to
40.degree.-45.degree.C. and then mixed with Part E. The final
product is then permitted to cool to 25.degree.-30.degree.C. with
stirring and the mixture packaged.
EXAMPLE 4
An anhydrous rouge composition was prepared from the following
constituents:
Part A Weight % ______________________________________ C.sub.12
-C.sub.14 isoparaffin fraction 35.5 Mineral oil (90 SSU viscosity
at 100.degree.F.) 15.0 Microcrystalline wax 10.0 Carnauba wax 6.0
Part B Weight % ______________________________________ Talc 10.0
Titanium Dioxide 20.0 Pigment 3.0 Propyl-p-hydroxybenzoate 0.15
Part C Weight % ______________________________________ Perfume Oil
0.5 ______________________________________
The rouge is obtained by pre-blending Part B and then stirring the
same with Part A which had been previously heated to
80.degree.-85.degree.C. The mixing is desirably conducted in a
roller mill. After the mixing operation, the A-B mixture is heated
to 70.degree.-75.degree.C. with stirring and then admixed with Part
C.
EXAMPLE 5
A waterless hand cleaner composition was prepared from the
following materials:
Part A Weight % ______________________________________ C.sub.12
-C.sub.14 isoparaffin fraction 34.5 Oleic acid 10.6 Nonylphenol
(10) ethoxylate 4.3 Antioxidant 0.1 Propyl-p-hydroxybenzoate 0.1
Part B Weight % ______________________________________ Water,
deionized 41.7 Propylene Glycol 4.3 Triethanolamine 1.1
Monoethanolamine 2.6 Methyl-p-hydroxybenzoate 0.2 Part C Weight %
______________________________________ Perfume Oil 0.5
______________________________________
Part A is heated to 75.degree.-80.degree.C. and then Part B heated
to 85.degree.-90.degree.C. Parts A and B are then mixed with
stirring and the mixture cooled to 80-85.degree.C. The A-B mixture
is then admixed with Part C to obtain the final product.
EXAMPLE 6
A pre-electric shave lotion was prepared in the manner described in
Example 1 except that in place of the C.sub.12 -C.sub.14
isoparaffin fraction of the present invention, having a volatility
in the range of about 225.degree. to 255.degree.C. a C.sub.11
-C.sub.13 isoparaffin solvent having a volatility in the range of
about 180.degree. to 220.degree. was employed.
EXAMPLE 7
The pre-electric shave lotions prepared in Example 1 and Example 6
were tested by human subjects who applied each to their face and
then shaved.
The responses to the use of each lotion were as follows. The
pre-shave lotion of Example 6 proved ineffective since it
evaporated from the skin too rapidly to allow for proper
lubrication and additionally caused an overall drying effect on the
skin. The lotion prepared in accordance with Example 1 was highly
effective in providing sufficient skin lubrication and a
comfortable "after-shave" effect.
* * * * *