U.S. patent number 3,816,079 [Application Number 05/314,575] was granted by the patent office on 1974-06-11 for method of producing grid electrodes for electronic discharge vessels.
This patent grant is currently assigned to BBC Brown Boveri & Company Limited. Invention is credited to Robert Bachmann, Charley Buxbaum, Benno Zigerlig.
United States Patent |
3,816,079 |
Bachmann , et al. |
June 11, 1974 |
METHOD OF PRODUCING GRID ELECTRODES FOR ELECTRONIC DISCHARGE
VESSELS
Abstract
A grid electrode for an electronic discharge vessel wherein the
wire which forms the grid is first covered with a layer of an
intermetallic compound comprising a high-melting metal such as
zirconium or titanium and a metal of Group VIII of the Periodic
System, for example platinum. The intermetallic compound is applied
to the grid wire in powdered form and then sintered after which an
outer layer of a noble metal, for example platinum is then applied
electrolytically.
Inventors: |
Bachmann; Robert (Staretschwil,
CH), Buxbaum; Charley (Baden, CH),
Zigerlig; Benno (Nussbaumen, CH) |
Assignee: |
BBC Brown Boveri & Company
Limited (Baden, CH)
|
Family
ID: |
4436922 |
Appl.
No.: |
05/314,575 |
Filed: |
December 13, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Dec 29, 1971 [CH] |
|
|
19037/71 |
|
Current U.S.
Class: |
445/51; 205/183;
428/554; 428/686; 428/934; 419/9; 428/660; 428/670; 428/926 |
Current CPC
Class: |
H01J
19/30 (20130101); Y10T 428/12069 (20150115); Y10S
428/926 (20130101); H01J 2893/0019 (20130101); Y10T
428/12806 (20150115); Y10T 428/12986 (20150115); Y10T
428/12875 (20150115); Y10S 428/934 (20130101) |
Current International
Class: |
H01J
19/30 (20060101); H01J 19/00 (20060101); B22f
007/04 () |
Field of
Search: |
;75/28R ;29/182.3
;117/217,221,231,22,23 ;204/181 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Sebastian; Leland A.
Assistant Examiner: Schafer; R. E.
Attorney, Agent or Firm: Pierce, Scheffler & Parker
Claims
We claim:
1. A method of producing grid electrodes for electronic discharge
vessels which comprises the steps of
applying to the wires forming the grid an intermediate coating
consisting of a high-melting intermetallic compound constituted by
a high-melting metal and platinum, and then
covering said intermediate coating with an outer layer of
platinum.
2. A method as defined in claim 1 for producing grid electrodes for
electronic discharge vessels wherein said high-melting metal is
zirconium.
3. A method as defined in claim 2 for producing grid electrodes for
electronic discharge vessels wherein said intermetallic compound is
ZrPt.sub.3.
4. A method as defined in claim 1 for producing grid electrodes for
electronic discharge vessels wherein said intermetallic compound is
applied to the wires forming said grid in powder form and is then
sintered.
5. A method as defined in claim 1 for producing grid electrodes for
electronic discharge vessels wherein said intermetallic compound in
powder form is applied to the wires forming said grid by
electrophoresis until the thickness thereof is at least 5 .mu.,
preferably 5 to 10 .mu., and is then heated in an inert atmosphere
or in vacuo to at least 1,500.degree.C, preferably 1,500.degree. to
1,600.degree.C, to thereby sinter the same.
6. A method as defined in claim 5 for producing grid electrodes for
electronic discharge vessels wherein the sintering time is
approximately 20 minutes.
7. A method as defined in claim 1 for producing grid electrodes for
electronic discharge vessels wherein said outer platinum layer is
applied electrolytically to the intermediate coating and said grid
is then annealed in vacuo at a temperature of at least
1,000.degree.C, preferably from 1,500.degree. to
1,600.degree.C.
8. A method as defined in claim 7 for producing grid electrodes for
electronic discharge vessels wherein the thickness of the applied
platinum is at least 3 .mu. .
9. A method as defined in claim 1 for producing grid electrodes for
electronic discharge vessels wherein said high-melting metal is
titanium.
10. A grid electrode for electronic discharge vessels comprising a
base metal forming the grid wire, an intermediate layer of an
intermetallic compound comprising a high-melting metal and platinum
applied to said wire, and an outer layer of platinum applied to
said intermediate layer.
Description
The present invention relates to a method of producing grid
electrodes for electronic discharge vessels whereby an intermediate
coating consisting of a high-melting intermetallic compound is
applied to the wires forming the grid and the intermediate coating
is then covered with a layer of a noble metal, and further to a
grid electrode produced by the method.
The method is known whereby grid electrodes are coated with a noble
metal of the VIII group of the periodic system, preferably
platinum, in order to reduce thermal emission. To reduce diffusion
of the platinum into the grid wire (basic metal) and increase the
radiative capacity, it has been proposed that an intermediate
coating should be provided between the basic metal and the outer
coating. Carbides, borides or silicides of high-melting metals have
been proposed as suitable materials for the intermediate
coating.
These known methods have the disadvantage that the coating reacts
more or less quickly with the basic metal or, in the case of
several coating components, within itself, and the reaction
products can be activated by the evaporation products of the Th-W
cathode. All methods employing carbides as the intermediate coating
have the added disadvantage that in time carbides form with the
basic metal, and these carbides cause the grid to become
brittle.
The principal object of the present invention is to create a grid
electrode such that the thermal emission does not increase even at
greatly increased loading, and which at the same time possesses a
slight and reproducible secondary emission together with increased
high-voltage strength.
This object is achieved in that the intermetallic compound for the
intermediate coating comprises a high-melting metal, such as
zirconium or titanium, and a metal of group VIII of the periodic
system.
The electrode produced by the method is characterized by the fact
that the intermetallic compound comprises a high-melting metal and
a noble metal of group VIII of the periodic system. The
intermetallic compound is preferably applied to the electrode core
as a powder and then sintered. By suitably choosing the grain size
of the powder it is possible to determine exactly the surface
roughness and hence to influence the secondary emission of the
electrode as required.
EXAMPLE OF THE METHOD
Stoichiometric quantities of zirconium and platinum are melted
together in vacuo, yielding the intermetallic compound ZrPt.sub.3.
The solidified specimens of this intermetallic compound are crushed
in a mortar and then ground in a mill lined with a hard material
such as tungsten carbide until the desired grain size preferably
3.mu., is attained.
The shaped grid of a conventional transmitting tube, consisting of
wires of molybdenum or tungsten, is annealed in hydrogen at
1,000.degree. to 1,100.degree. C to remove the oxides, etc. The
grid is then covered by cataphoresis with ZrPt.sub.3, the
production of which in powder form has already been described,
preferably to a coating thickness of 5 -- 10 .mu.. The grid,
together with the applied intermediate coating, is then annealed in
vacuo or a protective gas for 20 minutes at 1,500.degree. --
1,600.degree. C, whereupon the intermediate coating sinters,
retaining its roughness. After this the grid, with its sintered
intermediate coating, is covered electrolytically with a layer of
platinum 3 .mu. thick and then degassed by annealing once more in
vacuo at a temperature of 1,500.degree. -- 1,600.degree. C. Having
been degassed, the grid is ready to be fitted.
Grids produced in this way exhibit great adhesion between the
intermediate coating and the basic metal on the one hand, and the
platinum coat on the other, resulting in increased high-voltage
strength. This high adhesion also improves the mechanical
properties of the grid, so that very fine grids, meshed grids, for
example, can be produced.
By suitably selecting the grain size of the ZrPt.sub.3 powder
applied to the grid it is possible to vary the roughness of the
grid surface, and consequently the secondary emission, in a
reproducible manner.
In addition, these grids yield higher measured radiation values and
a higher thermal load capacity, thus allowing higher electrical
loadings.
Specific radiation values from 20 W/cm.sup.2 to 29 W/cm.sup.2 can
be achieved at 1,525.degree.K, depending on the chosen roughness of
the grid surface. This corresponds to between 65 and 95 percent of
the radiation of a black body.
At the same temperature the specific primary emission is approx. 1
.mu.A/cm.sup.2. This corresponds roughly to the operating
conditions in electronic discharge vessels. This primary emission
does not increase even after prolonged thermal overloading at
1,800.degree. K.
* * * * *