U.S. patent number 3,802,845 [Application Number 05/368,899] was granted by the patent office on 1974-04-09 for dissolving and dispensing apparatus having rotary liquid receptacle.
This patent grant is currently assigned to Olin Corporation. Invention is credited to Joseph J. Tepas, Jr..
United States Patent |
3,802,845 |
Tepas, Jr. |
April 9, 1974 |
DISSOLVING AND DISPENSING APPARATUS HAVING ROTARY LIQUID
RECEPTACLE
Abstract
An apparatus for dissolving and dispensing soluble material
comprising a container having an upper and a lower chamber. The
upper chamber is separated into a first and a second compartment. A
rotary receptacle in the first compartment receives liquid through
an inlet in the first compartment and is periodically emptied,
releasing precisely the same amount of liquid each cycle. The
second compartment contains a magazine which holds soluble solids
to be dissolved by the liquid. A control valve regulates the amount
of liquid contact with the solid. The lower chamber receives the
solution from the second compartment and thru valve means releases
the solution into the liquid system to be treated. The apparatus
provides means for dispensing a wide range of concentrations of
solutions, for example, solutions containing carefully controlled
amounts of available chlorine which can be supplied to a swimming
pool.
Inventors: |
Tepas, Jr.; Joseph J. (Easton,
CT) |
Assignee: |
Olin Corporation (New Haven,
CT)
|
Family
ID: |
26963341 |
Appl.
No.: |
05/368,899 |
Filed: |
June 11, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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285714 |
Sep 1, 1972 |
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Current U.S.
Class: |
422/106;
210/167.11; 137/268; 210/206; 210/754; 222/57; 422/264 |
Current CPC
Class: |
C02F
1/688 (20130101); B01F 15/045 (20130101); B01F
1/0033 (20130101); Y10T 137/4891 (20150401); C02F
2103/42 (20130101) |
Current International
Class: |
C02F
1/68 (20060101); B01F 15/04 (20060101); B01F
1/00 (20060101); B01d 011/02 (); B01f 001/00 () |
Field of
Search: |
;23/267C,267E,269,272.7,272.8 ;210/206,169,62,198 ;137/268
;4/224,228,225 ;222/57 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Yudkoff; Norman
Assistant Examiner: Emery; S. J.
Attorney, Agent or Firm: Clements; Donald F. O'Day; Thomas
P.
Parent Case Text
This application is a continuation-in-part of co-pending
application Ser. No. 285,714, filed Sept. 1, 1972.
Claims
1. An apparatus for dissolving and dispensing soluble solid
material comprising in combination a closed container having an
upper chamber and a lower chamber and at least one first partition
separating said chambers, said upper chamber having a first and a
second compartment separated by a second partition; an inlet for
liquid in the upper part of said first compartment, a rotary
receptacle in said first compartment and attachment means therefore
comprising a pair of trunnions, said receptacle receiving said
liquid from said inlet and upon rotation periodically emptying said
receptacle; first flow control means associated with at least one
opening for controlling liquid flow between said first compartment
and said second compartment; a magazine in said second compartment
to hold soluble solids, said magazine having a pervious lower end
permitting said liquid to contact the lower portion of said solids,
at least one opening for liquid flow between said second
compartment and said lower chamber, and an outlet in said lower
chamber and second flow control means for liquid flow thru
2. The apparatus of claim 1 in which said receptacle is a tear drop
shaped
3. The apparatus of claim 2 in which said first partition
separating said upper and said lower chambers comprises an inclined
section, a
4. The apparatus of claim 3 in which said opening between said
second compartment and said lower chamber is comprised of a drain
having a liquid
5. The apparatus of claim 4 having at least one opening for
liquid
6. The apparatus of claim 5 in which said second flow control means
for
7. The apparatus of claim 6 which said magazine contains soluble
solids selected from the group consisting of a calcium
hypochlorite, dichlorocyanuric acid and salts thereof,
trichlorocyanuric acid and salts thereof, tetrachloroglycoluril,
1,3-dichloro-5,5-dimethylhydantoin, and
8. The apparatus of claim 7 in which said soluble solid is
calcium
9. The apparatus of claim 1 wherein said second partition contains
at least one opening in the lower part thereof, said opening for
liquid flow between said second compartment and said lower chamber
is a variable size orifice flow control means, and having at least
one opening for liquid
10. The apparatus of claim 9 in which said receptacle is a tear
drop shaped
11. The apparatus of claim 9 in which said receptacle is a cylinder
having
12. The apparatus of claim 9 in which said partition separating
said upper and said lower chambers comprises an inclined section, a
substantially
13. The apparatus of claim 9 in which said partition separating
said first and said second compartments is substantially vertical
having a channel in
14. The apparatus of claim 9 in which said flow control means
between said first compartment and said second compartment
comprises valve means having two concentric cylinders, an outer
hollow cylinder attached to said partition defining said upper and
said lower chamber, said outer cylinder having at least one opening
therein; an inner cylinder attached to control
15. The apparatus of claim 9 in which said flow control means
between said first compartment and said second compartment
comprises valve means having an L-shaped member with means attached
at the end of the horizontal arm of said L, said means being
transverse to said horizontal arm, said means containing a pair of
studs and pressure means for exerting an outward
16. The apparatus of claim 9 in which said flow control means
between said
17. The apparatus of claim 9 in which said flow control means
for
18. The apparatus of claim 9 in which said inlet has control
means
19. The apparatus of claim 9 in which said magazine is removable
from said
20. The apparatus of claim 9 in which said pervious end of said
magazine is
21. The apparatus of claim 9 in which said magazine is filled with
soluble solids selected from the group consisting of calcium
hypochlorite, dichlorocyanuric acid and salts thereof,
trichlorocyanuric acid and salts thereof, tetrachloroglycoluril,
1,3-dichloro-5,5-dimethylhydantoin, and
22. The apparatus of claim 21 in which said soluble solid is
calcium
23. The apparatus of claim 6 in which said first compartment has an
opening in said first partition separating said upper chamber from
said lower chamber, said second compartment having an opening in
said first partition separating said upper chamber from said lower
chamber, and flow control means for controlling liquid flow between
said opening in said first compartment and said opening in said
second compartment.
Description
This invention relates to apparatus for the preparation and
controlled feeding of aqueous solutions of solid particulate
material. More particularly, the apparatus provides means for
preparing aqueous solutions of water-soluble solids and dispensing
said solutions at controlled rates. Still more particularly, this
invention relates to apparatus for supplying solutions containing
available chlorine over a wide range of concentrations from solid
hypochlorite compositions in conveniently handled granular, pressed
or tabletted forms at accurately controlled rates for use in a
variety of chlorination and water treating applications differing
widely in the ultimate concentration of the solution required.
In the treatment of water supplies, including particularly swimming
pools, a supply of aqueous solution of an available halogen
compound, preferably a hypochlorite, is commonly metered into a
flowing body of the liquid to be treated. Sodium hypochlorite
solutions are available commerically at concentrations not
exceeding 15 percent of available chlorine but such solutions
deteriorate rapidly during shipment and storage. Solid sodium
hypochlorite compositions are not available because they are very
unstable. Calcium hypochlorite, on the other hand, can be shipped
as a relatively stable solid containing 70 percent or more of
available chlorine and can be stored for long periods without
appreciable loss of available chlorine.
In spite of the advantages of solid calcium hypochlorite over other
sources of available halogen for use as a sterilizing agent, there
is a problem in applying the solid continuously and directly to
water in such a manner that only a few parts per million of
available chlorine are ultimately present in the water. In
conventional methods of application in swimming pools, granular
calcium hypochlorite is sometimes added directly to the water in
the pool or tablets are placed in the skimmer or in dissolving
baskets around the pool. Preferably, however, solid calcium
hypochlorite is dissolved in water to form a solution of desired
concentration which is metered into the water in the circulating
system at a rate to maintain residual chlorine concentration
generally from about 0.3 to about 1.5 parts per million in the
pool.
Many devices have been devised to control dissolution of soluble
materials but which are not satisfactory for use with calcium
hypochlorite or other substances having similar solubility and
solution characteristics.
U.S. Pat. No. 1,216,051 shows a dispensing device having a
solute-containing magazine covered at one end by a perforated disk
and supported at a fixed elevation in the total stream of flowing
water to be treated. The flow of the total stream promotes
turbulence in the region of the perforated end of the magazine and
extensive wetting of undissolved solute. Contact between solute and
liquid and hence the degree of liquid treatment is dependent on
liquid pressure.
U.S. Pat. No. 2,971,825 shows a dispenser for dissolving and
dispensing solutes by passing a variably controlled portion of the
inflowing fluid into and out of a mixing chamber which contains the
solute and which is partially covered by a screen. Turbulent flow
in the region of the perforated end and extensive wetting and
mixing of solvent and undissolved solute are encouraged by the
structure of the device of this patent. The range of concentrations
for treated solutions is limited by the extent stream deflection is
permitted by the controls. The uniformity of concentrations of
treated solutions is dependent on liquid pressure.
The dispensing device of U.S. Pat. No. 3,107,156 comprises a solute
containing magazine suspended into a container into which a
constant flow of water enters. The magazine has a water soluble
plastic film at the lower end which dissolves in contact with water
and exposes the solute to the dissolving action of water. The
extent of contact of solute with water is adjusted by raising or
lowering the magazine. A siphon tube determines the upper and lower
liquid levels in the container and periodically releases a quantity
of treated water.
In contrast to the above dispensers, the apparatus of the present
invention provides for accurately controlled concentrations of
treated solutions which are independent of changes in pressure on
the liquid being introduced. The present apparatus provides
controlled turbulence in the area of liquid-solute contact and
prevents undesired contact between the liquid and the soluble
material. Continuous immersion of the soluble material in the
liquid is avoided by the apparatus of this invention. Periodic,
release of a controlled quantity of liquid from the receptacle
permits liquid-solute contact which is essentially unaffected by
changes in liquid flow rates. The present invention permits a zero
feed rate of soluble material while maintaining a continuous flow
of liquid thru the apparatus under normal operating conditions.
In the apparatus of this invention, if the flow of liquid is
stopped, the solution retained in the dispenser does not remain in
contact with the soluble material, thus the solution does not
become highly concentrated and therefore does not cause corrosion,
for example, to pumps, filters, or lines upon standing or when the
flow of solution is resumed.
In general, the apparatus of the present invention for dissolving
and dispensing soluble material comprises in combination a closed
container having an upper chamber and a lower chamber and at least
one first partition separating the chambers. The upper chamber is
divided into a first and a second compartment by a second
partition. An inlet in the upper part of the first compartment
introduces liquid from an external source into a rotary receptacle
housed in the first compartment. The receptacle is located below
the inlet and is attached to the sidewalls of the first compartment
by a pair of trunnions. Means are provided for periodically
emptying liquid from the receptacle. Liquid flow is regulated by a
first flow control means associated with at least one opening
between the first and the second compartment. A magazine in the
second compartment for holding soluble solids has a pervious lower
end permitting the liquid from the receptacle to contact the
solids. At least one opening is provided in the second compartment
permitting liquid to flow between the second compartment and the
lower chamber. An outlet in the lower chamber is equipped with a
second flow control means which permits the regulation of liquid
flow thru the outlet.
FIGS. 1-5 show various embodiments of the novel dispenser of this
invention. Corresponding parts have the same identifying numbers in
FIGS. 1-4. FIG. 5 shows a diagram utilizing the dispenser of this
invention.
FIGS. 1-4 illustrate one embodiment of the dispensing apparatus of
the present invention.
FIG. 1 is a vertical cross section of one embodiment of the
apparatus of the present invention.
FIG. 2 is a top view of the embodiment of FIG. 1 with parts broken
away.
FIG. 3 is an end view partially sectioned which is taken along the
line 3--3 of FIG. 2.
FIG. 4 is a partial perspective view of an alternate embodiment of
FIG. 3.
FIG. 5 is a diagrammatic plan of a swimming pool circulating system
incorporating the dispensing apparatus of the present
invention.
The dispensing apparatus of this invention, as shown in FIG. 1, is
divided into upper chamber 1 and lower chamber 2 by first partition
3. Upper chamber 1 is separated into first compartment 4 and second
compartment 5 by second partition 6. Liquid from an external source
enters the apparatus by way of tube 7 passing thru flow indicator 8
and inflow valve 9 into inlet 10 attached to the upper part of wall
14 of first compartment 4. Receptacle 11 is attached to the
sidewalls of first compartment 4 by means of a pair of trunnions
12. Receptacle 11 empties itself when the liquid volume reaches a
predetermined level by pivoting on trunnions 12 stopping when the
front edge of receptacle contacts protuberance 13.
Upon emptying, receptacle 11 returns to its original position,
stopping when contacting inlet 10. Liquid from receptacle 11 flows
down first partition 3 to horizontal partition 15 where first flow
control means 16 regulates the rate of liquid flow from first
compartment 4 to second compartment 5 thru channel 17. Magazine 18,
having removable cover 60 and with the lower pervious end
comprising grid 19 and supporting a liquid soluble particulate
material (not shown), is contained in second compartment 5. Dial
control 20 attached to first flow control means 16 regulates the
rate of liquid flow thru channel 17 in second partition 6 and thus
the height of the liquid column passing thru grid 19 containing the
solid soluble particulate material to form a solution of the
material. Dial control settings (not shown) are indicated on cover
61 of first compartment 4. From second compartment 5 the solution
formed passes thru drain 21 into lower chamber 2. Second flow
control means comprised of float 22 and valve 23 regulate the flow
of solution from lower chamber 2 thru outlet 24 to the body of
liquid to be treated. Overflow tube 25 allows any build-up of
liquid which might occur in first compartment 4 to flow directly
into lower chamber 2 without contacting the liquid soluble
particulate material.
FIG. 2 is a top view of the embodiment of FIG. 1. Orifice 28 in
partition 15 permits liquid to by-pass first flow control means 16
(not shown) and flow into second compartment 5. Dial control
settings are shown on cover 61 of first compartment 4. The setting
for dial control 20 determines the position of first flow control
means 16 and thus the rate of liquid flow entering second
compartment 5 and up thru grid 19. The solution formed then passes
thru drain 21 into lower chamber 2 (not shown).
FIG. 3 illustrates an embodiment of first flow control means 16
between first compartment 4 and second compartment 5 of upper
chamber 1. Hollow cylinder 27 is attached to first partition 3 and
contains openings 28 for liquid flow. Inner cylinder 29 has a
semicircular portion cut away at one end thereof and is free to
rotate. It is attached to cylinder support 30 which is attached to
rod 31 having a bushing 32 at the upper end thereof. Movement of
dial control 20 alters the position of inner cylinder 29 and thus
changes rate of liquid flow thru openings 28 of cylinder 27 and
thru channel 17.
FIG. 4 illustrates the partial perspective view of an additional
embodiment of first flow control means 39 to replace first flow
control means 16 where an L-shaped member 40 attached to first
partition 3 and second partition 6 by pivot pin 46, has tube 41
attached at the end of the horizontal arm of the L. Tube 41
contains spring 42 and studs 43. Opening 44 in second partition 6
and opening 45 in first partition 3 are counter-positioned so that
movement of member 40 increases the flow of liquid thru one opening
while decreasing the flow thru the other. The liquid from
receptacle 11 (not shown) flows down first partition 3 into channel
49, formed between first partition 3 and second partition 6. Liquid
flowing thru opening 44 in second partition 6 enters second
compartment 5 to contact the solid soluble particulate material.
Liquid flowing thru opening 45 in first partition 3 passes directly
into lower chamber 2 without containing the solid soluble
particulate material.
FIG. 9 illustrates the use of the present invention in supplying
chlorinated water to a swimming pool system including swimming pool
50, a pump 51 with its low pressure or suction side connected by
conduit 52 to pool 50 and with its high pressure or outlet side by
conduit 53 to filter 54. A portion of the water discharged from
filter 54 through conduit 55 passes through conduit 56 into
dispenser apparatus 57. For example, when magazine 18 of the
dispenser of this invention contains calcium hypochlorite and pool
water is contacted with the calcium hypochlorite contained therein,
the resulting chlorine-containing solution formed by dispenser
apparatus 57 is discharged through outlet 24 (not shown) to conduit
58 to pump 51, through conduit 53 to filter 54 and through conduit
55 to pool 50.
The dispensing apparatus of this invention is suitably fabricated
of metal or plastic depending on the solute and liquid with which
it is to be used. When solid hypochlorites, for example, calcium
hypochlorite, or solutions of hypochlorites are employed, the
materials of construction are preferably those resistant to its
action. Particularly suitable for this purpose are a considerable
number of plastic compositions, for example, Lucite which has the
additional advantage of transparency. The apparatus may also be
constructed of other resins, for example,
acrylonitrile-butadiene-styrene, Bakelite, nylon, polyethylene,
polyvinyl chloride, and polystyrene and of suitable metals
including copper, brass, stainless steels, and titanium.
The dispenser is designed to operate with liquid supplied at
suitable pressures and may be operated without controlling means or
liquid flow rates. In systems with highly variable liquid flow
rates, it may be desirable, however, to equip the inlet with means
to regulate liquid flow. In the case of treating swimming pool
water, for example, control means combining a visual flow indicator
and a valve member are useful in indicating a pressure build-up in
the filter or at the hair and lint screen or to indicate that the
check valve is functioning in case the filter pump stops. An
example of a suitable inlet liquid flow control means is a
combination of a ball flow indicator and a tee valve.
The receptacle for the liquid is self-emptying and provides for the
release of liquid on a periodic basis, controlled, for example, by
a predetermined volume or weight of liquid. It can, for example, be
shaped generally cylindrical, ellipsoidal or circular, having at
least one opening for solvent to enter and be discharged. In one
embodiment, a tear drop shaped receptacle is attached to the walls
of the container, for example, by a pair of trunnions or pivot pins
and is carefully balanced so that upon emptying the liquid it
returns to its original position. A stopping means for maintaining
the receptacle at a suitable position for filling may be provided
by the appropriate length of the inlet tube or by appropriately
located protuberances as shown in FIG. 1.
One or more openings are provided in the first compartment to
permit flow of liquid to the second compartment and/or the lower
chamber when the dispensing device is operating to produce
solutions of low concentration.
Flow of liquid from the first compartment to the second compartment
is regulated by the flow control means, for example, a valve member
selected to provide a wide range of flow rates. Suitable examples
are illustrated in FIGS. 1-4.
The supply magazine has the form, for example, of a hallow
rectangular or cylindrical solid having a pervious lower end. The
magazine is insertable into the second compartment of the upper
chamber and stop means are provided to establish the level of the
pervious lower end of the magazine at an appropriate distance above
the bottom of the compartment. The pervious lower end can be, for
example, a grid of suitable mesh attached to the magazine and made
integral therewith. The magazine can be removable from or made
integral with the second compartment. A removable cover permits the
magazine to be filled with soluble material in a form which is
suitable for dissolving in the liquid being supplied to the
apparatus of the invention. While a magazine is a preferred
embodiment for containing the soluble solids it will be recognized
that other supports or holders having suitable openings for liquid
may be used.
The lower portion of the magazine is periodically submerged in
liquid, with the volume of the submerged portion usually being no
greater than about 5 percent of the total volume of the magazine.
The extent of contact is regulated by the adjustable flow control
means.
As soluble material dissolves at the pervious end of the magazine
and is removed, the soluble material originally in the air space
above and not wetted by liquid, gradually descends to the pervious
end to replace that dissolved. Only soluble material about to be
dissolved is contacted by liquid flowing across the pervious end of
the magazine.
At least one opening is provided to permit the flow of solution
between the second compartment and the lower chamber. This may
comprise, for example, a drain with a suitable dam to maintain
liquid level near the grid. In addition, drain means suitably
notched to minimize plugging by non-dissolved particles can be
employed. If desired, drain means with a variable size orifice can
be advantageously used especially where particulate materials of
differing degrees of solubility are employed with a common
solvent.
Liquid communication means can be provided between the first
compartment and the lower chamber. A suitable example is an opening
or overflow tube which prevents the build-up of liquid in the first
compartment.
Release of solution from the lower chamber through outlet 24 to the
liquid to be treated is controlled by a second flow control means,
a float valve, for example, so arranged that air is prevented from
being drawn into the pump suction line causing undesired
introduction of air into the recirculating system.
The dispenser is designated to operate with liquid supplied at
suitable pressure and to discharge the solution at or below
atmospheric pressure into the liquid to be treated.
The rotary receptacle accumulates a volume of liquid and
periodically instantaneously releases the liquid to a dissolving
zone wherein the liquid contacts a soluble material in the lower
end of the magazine to form a solution containing a carefully
controlled amount of the soluble material. By releasing precisely
the same amount of liquid during each cycle, accurately controlled
solution concentrations are consistently obtained for a particular
setting of the dial control. A wide range of concentrations are
available, for example, when dissolving solid calcium hypochlorite
in water for swimming pool treatment, available chlorine in amounts
of from zero to greater than 4,000 grams per day can be supplied.
Currently available erosion type dispensing devices for
chlorinating swimming pools cannot provide a zero feed rate of
available chlorine while operating, nor can they feed more than
approximately 600 grams of available chlorine per day.
The device of the present invention is used particularly
advantageously when it is desired to dispense solutions of soluble
solid materials supplied to a suitable form at accurately
controlled rates. These rates are varied by controlling the volume
of liquid in contact with the soluble material. The dispenser of
this invention is particularly useful in the application of solid
hypochlorites, for example, calcium hypochlorite, to bodies of
water, for example, in treating water in swimming pools, water
plants in small municipalities, bottling plants, dairies and
cooling systems where the addition of a sterilizing agent or other
chemical is desirable. The device also can be advantageously used
in the treatment of industrial wastes to destroy color, odor, and
toxic constituents, and for odor and bacterial control in sewage
effluents. Pressed tablets of hypochlorite are especially suitable
in the present apparatus, but granular shapes and sizes of
particles are also suitable. The apparatus can be used for
dissolving and feeding other chemicals, for example, sodium
fluoride in minor amounts for water supplies, polyphosphates and
compositions containing them for water softening, soda ash
furnished as briquettes or fused soda ash for adjusting the
alkalinity of aqueous bodies, sodium chloride, alum and available
chlorine compound other than hypochlorite including, for example,
dichlorocyanuric acid and salts thereof, trichlorocyanuric acid and
salts thereof, tetrachloroglycoluril,
1,3-dichloro-5,5-dimethylhydantoin and
1-chloro-3-bromo-5,5-dimethylhydantoin.
The following examples are presented to illustrate the invention
more fully. All parts and percentages are by weight unless
otherwise specified.
EXAMPLE I
A dissolving and dispensing apparatus, substantially as shown in
FIGS. 1-2, was fabricated substantially of polymethyl methacrylate.
The tear drop shaped receptacle had a capacity of approximately one
quart of liquid. The magazine had a grid forming the pervious end
and was filled with tabletted calcium hypochlorite containing at
least 70 percent Ca(OCl).sub.2. The flow control valve between the
first and second compartment of the upper chamber is the valve
shown in FIG. 3. A loose fitting cap for the supply cartridge was
provided.
The described dispenser was connected to a test stand simulating a
swimming pool installation to test uniformity in maintaining
available chlorine levels.
The test stand consisted of a stirred tank having a capacity of 150
gallons of water.
Fresh water at a temperature of 71.degree.F. was added to the
dispensing device at the rate of 14 gallons per hour.
At a dial control setting of 1, the dispensing apparatus was
operated for a period of 7 1/2 hours with the treated solution
being retained in the stirred tank. Periodic analysis showed a
uniform available chlorine concentration of 21.6 parts per
million.
EXAMPLE II
The dissolving and dispensing apparatus of example I was used in a
25,000 gallon swimming pool installation such as illustrated in
FIG. 9. Water, having a total hardness in the range of 650-900
parts per million, was withdrawn from the pool thru a plastic
conduit, using the low pressure side of a pump. The high pressure
side of the pump forced water thru a cartridge filter and into a
plastic conduit having a smaller plastic line connected to it. This
plastic line supplied water thru the inlet of the dispensing
apparatus to a receptacle of 1 quart capacity at the rate of
approximately 1 quart per minute. The magazine of the dispensing
apparatus was filled with calcium hypochlorite tablets 3/8 inch
thick and 3/4 inch in diameter.
At a dial control setting of 2, the available chlorine residual in
the pool was maintained at 1.0 to 1.5 parts per million for a
period of greater than 90 days. The temperature of the water
averaged about 80.degree. to 85.degree.F. in the pool located in an
unshaded area and without a screened enclosure. The pump was
operated for about 12 hours per day. During the period of
operation, the dispenser apparatus required no cleaning nor other
maintenance.
* * * * *