U.S. patent number 3,800,111 [Application Number 05/226,048] was granted by the patent office on 1974-03-26 for electric switching device comprising insulating parts reinforced with polyvinyl alcohol fibres.
This patent grant is currently assigned to Allmanna Svenska Elektriska Aktiebolaget. Invention is credited to Goran Holmstrom.
United States Patent |
3,800,111 |
Holmstrom |
March 26, 1974 |
ELECTRIC SWITCHING DEVICE COMPRISING INSULATING PARTS REINFORCED
WITH POLYVINYL ALCOHOL FIBRES
Abstract
An electric switching device with insulating parts of mouldings,
particularly extinguishing chamber plates in an arc extinguishing
chamber, such mouldings being formed of resin binder reinforced
with fiber material which is at least primarily fibers of polyvinyl
alcohol or acetalised polyvinyl alcohol. The binder is an
unsaturated resin converted into polymerised form.
Inventors: |
Holmstrom; Goran (Vasteras,
SW) |
Assignee: |
Allmanna Svenska Elektriska
Aktiebolaget (Vasteras, SW)
|
Family
ID: |
26654156 |
Appl.
No.: |
05/226,048 |
Filed: |
February 14, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Feb 22, 1971 [SW] |
|
|
2205/71 |
Feb 19, 1972 [SW] |
|
|
563/72 |
|
Current U.S.
Class: |
218/150;
174/110V; 174/137B; 218/90 |
Current CPC
Class: |
H01B
3/447 (20130101); H01H 33/72 (20130101) |
Current International
Class: |
H01B
3/44 (20060101); H01H 33/72 (20060101); H01H
33/70 (20060101); H01h 033/04 () |
Field of
Search: |
;200/15A,144C,149A |
Other References
hackh's Chemical Dictionary, Third Edition, P. 673. .
Plastic Materials, by J. A. Brydson, London, 1969, Second Edition,
p. 229..
|
Primary Examiner: Macon; Robert S.
Claims
I claim:
1. Electric switching device having at least one insulating part of
mouldings of a resin binder reinforced with fibre material, which
is subjected to influence of electric arcs, in which the fibre
material consists essentially of fibres of polyvinyl alcohol fibres
or acetalized polyvinyl alcohol.
2. Electric switching device according to claim 1, consisting of a
high voltage circuit breaker comprising an extinguishing chamber,
in which the insulating part constitutes an extinguishing chamber
plate in the extinguishing chamber.
3. Electric switching device according to claim 2, in which the
binder consists essentially of an unsaturated polyester resin
converted into cured form and containing an acrylate or
methacrylate as monomer.
4. Electric switching device according to claim 2, in which the
binder consists essentially of a mixture of a linear acrylate
polymer and at least one monomer comprising a polyethylene glycol
dimethacrylate or polyethylene glycol diacrylate, converted into
polymerised form.
5. Electric switching device according to claim 4, in which the
content of linear acrylate polymer constitutes 10 - 35 percent and
the content of monomer 65 - 90 percent of the total weight of these
substances.
6. Electric switching device according to claim 4, in which the
binder contains an additive resin containing ethylenically
unsaturated groups which are copolymerisable with the unsaturated
groups in the polyethylene glycol dimethacrylate or diacrylate, the
quantity of additive resin being at the most 25 percent of the
total weight of acrylate polymer, monomeric acrylate compound and
additive resin.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The invention relates to an electric switching device and
especially a high voltage circuit breaker in which the insulating
parts are subjected to the influence of electric arcs during
operation.
2. The Prior Art
Insulating parts which during operation come into contact with
electric arcs are subjected to high mechanical, electrical and
thermal stresses. It is of decisive importance for the speration of
the switching means that the material in said insulating parts is
sufficiently resistant to arcs so that the material is not burnt
away to too great an extent. The material must also have such
properties that the influence of the arc does not give rise to
polluted surfaces, primarily as a result of the formation of soot,
and thus to creepage sparking. It has proved extremely difficult at
the same time to achieve sufficient mechanical strengh and also
sufficient resistance to electric arcs. Examples of switching
devices where problems of the type described arise are circuit
breakers and contactors and also isolators having extingushing
chutes.
Furthermore, the requirements are permanently increasing for short
breaking times for high voltage circuit breakers, i.e. that time
from the moment when the breaker receives an opening impulse signal
until the moment when the current is cut off. The increased
requirements for short breaking times are due to the expansion of
electric power transmission networks and thus the increasing
short-circuit powers. In order to achieve short breaking times it
is important that the voltage strength in the extinguishing chamber
is built up so quickly that so called dielectric re-ignition does
not occur. The material in the insulating parts which comes into
contact with the arc is therefore very important since a flash-over
is often caused by creepage currents along the surfaces of the
insulating parts.
Previously a great number of inorganic and organic insulating
materials have been used for said insulating parts. Recently,
however, moulded material with binders of synthetic resin have been
used to an increasing extent, such as polyester resins and epoxy
resins with powdered and fibrous fillers. In order to satisfy the
requrements of mechanical and thermal strength glass fibres have
been principally used as fibrous filler and reinforcing material.
It is also known to use mouldings of acrylate resins such as
polymethyl methacrylate without filler.
However, it has been found that there are problems in using glass
fibres as filler and reinforcing material. The problem have
probably something to do with the considerable tendency to creepage
current which heated glass fibres have and with the fact that the
glass is altered and roughened at the high temperatures of the arc,
which results in the glass retaining soot particles so that the
dielectric strength of the insulation will be very poor along the
surface.
SUMMARY OF THE INVENTION
According to the present invention it has been found possible while
retaining the good mechanical and thermal properties of the
insulating parts which can be achieved with glass fibres as
reinforcement, to considerably improve the resistance of these
insulating parts to arcs. The improvement is achieved by the use of
a fibre material in the insulating parts which consists at least
substantially of polyvinyl alcohol fibres or acetalized polyvinyl
alcohol fibres. A likely explanation of the improvement achieved is
that polyvinyl alcohol disintegrates at low temperatures to produce
gases, for instance water vapour, which effectively keeps the arc
at a distance from the surface of the insulating parts and thus
saves the surface from the direct influence of the arc. At the same
time, the gas production contributes to extinguishing the arc and
thus to shortening the duration of the arc.
The present invention relates more specifically to a switching
device having insulating parts of mouldings reinforced with fibre
material, which are subjected to the influence of electric arcs and
is characterised in that the fibre material consists at least
substantially of polyvinyl alcohol fibres or acetalized polyvinyl
alcohol fibres.
Polyvinyl alcohol fibre has been a commerical product at least
since 1950. In the following description the term polyvinyl alcohol
fibres includes not only polyvinyl alcohol fibres as such but also
acetalized polyvinyl alcohol fibres, i.e. polyvinyl alcohol fibres
which have been acetalized.
When manufacturing mouldings according to the present invention,
polyvinyl alcohol fibres can be used in the manner conventional for
glass fibres, i.e. in the form of wool, short fibres or fibre
strings, cloth and webs, together with a resinous binder. The
reinforced products can be produced by compression moulding
compounds and injection moulding compounds, by moulding impregnated
webs to laminates, by hand lay-up, fibre winding and centrifugal
casting.
The length of the fibres in moulding compounds is suitable 1 - 100
mm, preferably 3 - 50 mm and in injection moulding compounds
suitably 1 - 50 mm, preferably 1 - 10 mm. Their diameter is
suitably 1 - 50 mm.
The quantity of polyvinyl alcohol fibres in the finished mouldings
is suitably 5 - 40, preferably 10 - 25 percent of the weight of the
mouldings.
As examples of suitable binders for the moulding may be mentioned
ethylenically unsaturated polyester resins with methyl
methacrylate, other acrylates or methacrylates, such as the
monomers mentioned below having several arcylate groups, as well as
diallylphthalate or tirallyl cyanurate as ethylenically unsaturated
monomers in a quantity of 15 - 45 percent of the weight of the
polyester resin including the monomer, acrylate resins such as a
mixture of on the one hand a linear acrylate polymer, for example a
polymer of methyl methacrylate, methyl acrylate, ethyl methacrylate
or ethyl acrylate or a copolymer of two or more of these substances
and, on the other hand, a monomer having several acrylate groups,
for example ethylene glycol dimethacrylate,
1,4-butanedisldimethacrylate, neopenthyl glycol dimethacrylate,
diethylene glycol dimethacrylate, triethylene glycol
dimethacrylate, tetraethylene glycol dimethacrylate, pentaethylene
glycol dimethacrylate, hexaethylene glycol dimethacrylate and
trimethylol propane trimethacrylate or corresponding compounds in
which the methacrylate groups have been replaced by acrylate groups
and mixtures of two or more such monomers containing methcrylate or
acrylate groups, at least partially polymerised diallylphthalate,
epoxy resins with curing agents of anhydride type such as
hexahydrophthalic acid anhydride, carbamide resins and melamine
resins. Particularly preferred are the acrylate resins mentioned
and especially a mixture of a linear acrylate polymer of the type
mentioned and a monomer in the form of a monomeric acrylate
compound consisting of a polyethylene glycol dimethacrylate and/or
diacrylate such as a dimetacrylate or diacrylate of diethylene
glycol, triethylene glycol, tetraethylene glycol, pentaethylene
glycol, hexaethylene glycol and heptaethylene glycol, possibly with
an additive resin containing ethylenically unsaturated groups which
are copolymerisable with the unsaturated groups in the polyethylene
glycol dimethacrylate or diacrylate. As examples of such additive
resins may be mentioned unsaturated polyester resins, partially
polymerised allyl esters, for example diallylphthalate and
diallylmaleate, acryl-modified, preferably cycloaliphatic epoxy
resins and unsaturated polybutadiene resins, for example having a
molecular weight of 1,000 - 3,000 and containing approximately 85
percent of the unsaturated groups in 1,2 position. The quantity of
linear acrylate polymer should preferably be 10 - 25 percent and
the quantity of monomeric acrylate compound about 65 - 90 percent
of the total weight of these substances. The quantity of additive
resin should be at the most 25 percent, i.e., 0 - 25 percent of the
total weight of acrylate polymer, monomeric acrylate compound and
additive resin. The quantity of binder is suitable 15 - 70 percent,
preferably 20 - 50 percent of the weight of the moulding.
The unsaturated polyester resin may be of conventional type. It can
be produced in the normal manner by esterifying ethylenically
unsaturated and saturated, preferably aliphatio dicarboxylic acids
or corresponding anhydrides with an equivalent quantity or a slight
excess of a bifunctional alcohol. As examples of unsaturated acids
which can be used for this purpose may be mentioned maleic acid,
fumaric acid, itaconic acid as such, or in the form of anhydrides.
Examples of saturated acids which can be used are primarily adipic
acid, sebacic acid, succinic acid as such or in the form of
anhydrides. As examples of suitable bifunctional alcohols may be
mentioned glycols such as ethylene glycol, propylene glycol and
butylene glycol as well as polyglycols such as diethylene glycol,
triethylene glycol and dipropylene glycol.
The mouldings may also contain inorganic and organic powered
filler, such as chalk, kaolin, dolomite, bauxite, mica powder,
silica powder, zirconium dioxide, zirconium silicate, silicon
carbide, aluminum trihydrate, cellulose powder, polyacetal powder
(polyoxymethylene), etc. The quantity of powder filler may be at
the most 70, suitably 1 - 70 and preferably 15 - 60 percent of the
weight of the moulding, i.e. the total weight of the binder,
fibrous material and powdered filler.
Besides polyvinyl alcohol fibres the mouldings may also contain
other fibrous material such as cotton, sisal fibres and asbestos to
a total weight of less than the weight of the polyvinyl alcohol
fibres.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention will be further explained by describing a number of
embodiments by way of example with reference to the accompanying
drawing which shows schematically a high voltage circuit breaker of
minimum liquid type with transverse extinguishing chamber.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The circuit breaker shown has a cylindrical extinguishing chamber 1
and a cylinder 2 concentric with this, both of glass-fibre
reinforced plastic. At the upper end of these parts is a metallic
cover 3 provided with a current terminal 4 connected to the
stationary contact 5 of the circuit breaker. The movable contact 6
of the breaker consists of a contact plug which can be displaced
within the current collector 7 and through an arcing chamber 8 in
relation to the stationary contact 5 arranged in the upper part of
the arcing chamber. A number of extinguishing chamber plates 9 are
arranged horizontally in the arching chamber. The lower surface of
each plate is flat over the entire area of the plate. Each plate
has a central hole 12 for the movable contact and a substantially
radial groove at the top which extends from the hole 12 to an
exhaust channel 11 inside the wall of the extinguishing chamber.
Said groove thus forms a horizontal gap 10 (transverse blowing gap)
which leads from the arcing chamber 8 and opens out into the
exhaust channel 11. The thickness of the material of each plate is
greater towards the exhaust channel 11, i.e. in those parts which
surround and are higher than the radial groove than towards the
opposite end from the hole 12, so that there are open spaces
between the plates towards the latter direction, as can be seen
from the drawing. The plates are stacked on each other, in close
contact with each other where the thickness of the plates is
greatest (behind the plane shown in the drawing). In order to
protect the inner wall of the extinguishing chamber against the hot
gases blown out through the gaps 10, a cylindrical screen 17 of
moulded material reinforced with polyvinyl alcohol fibres may be
arranged inside the cylinder 1 along a part of its circumference.
The binder in this material may be of the same sort as that
mentioned for the insulating parts subjected to the influence of
electric arcs, as for the plates 9. The inner wall of the
extinguishing chamber cylinder 1 may also be protected by giving
the plates 9 of the extinguishing chamber the same diameter as the
inner diameter of the extinguishing chamber cylinder and shaping
each plate with a hole running in axial direction spaced from the
periphery and thus from the wall of the extinguishing chamber. The
holes in the plates stacked on top of each other thus together form
an exhaust channel corresponding to the exhaust channel 11 in the
drawing.
The circuit breaker is filled with liquid, for example oil, to the
level 13 in the cover. A porcelain insulator 14 is arranged around
the cylinder 2. During a breaking process the oil in the arc zone
is vaporized due to the influence of the arc and an extremely high
pressure is thus built up in the arcing chamber 8. As the
transverse blasting gaps 10 are exposed by the movable contact 6,
the arc is subjected to a powerful flow of oil and gas which cools
and deionises the arc. In order to ensure that small currents are
broken, a number of liquid pockets 15 may be arranged in the lower
part of the extinguishing chamber.
In the arrangement shown the extinguishing chamber plates 9 are
subjected to the influence of an arc. According to the present
invention these plates are made of mouldings reinforced with
polyvinyl alcohol fibres. In the following examples will be given
for their manufacture.
Example 1
A moulding compound is manufactured of the following
components:
30 parts by weight of an unsaturated polyester resin manufactured
in conventional manner from 2 mols maleic acid anhydride, 1 mol
succinic acid and 3.3 mols ethylene glycol and mixing 70 percent by
weight of the reaction product thus obtained with 30 percent by
weight methyl methacrylate. Esterifying is carried out at 165
-190.degree.C to an acid number of 35.
0.5 parts by weight benzoyl peroxide
1.5 parts by weight zinc stearate
20 parts by weight polyvinyl alcohol fibres having a length of 15
mm
95 parts by weight zirconium dioxide
The components are kneaded together to a homogenous pulp similar to
cotton waste. This is compression moulded and cured in the mould at
a pressure of 100 kg/cm.sup.2 and a temperature of 140.degree.C for
4 minutes.
Example 2
A moulding compound is manufactured of the following
components:
30 parts by weight of an acrylate resin consisting of 75 parts by
weight triethylene glycol dimethacrylate and 25 percent by weight
polymerised methyl methacrylate having a molecular weight of
140,000
0.5 parts by weight butyl perbenzoate
15 parts by weight polyvinyl alcohol fibres having a length of 15
mm
5 parts by weight cellulose powder
1.5 parts by weight zinc stearate
48 parts by weight kaolin
The moulding compound is manufactured and moulded in the same way
as the compound described in Example 1.
Example 3
An injection moulding compound is manufactured of the following
components:
36 parts by weight pre-polymerized diallylphthalate with a melting
point of 95.degree.C
4 parts by weight monomeric diallylphthalate
1 parts by weight butyl perbenzoate
10 parts by weight polyvinyl alcohol fibres having a length of 3
mm
48 parts by weight kaolin
The components are mixed well and rolled together in a rolling mill
at 80 - 90.degree.C. After cooling the rolled product is ground to
particles with a size of approximately 3 mm. The compound can be
transfer moulded and injection moulded at a temperature of
160.degree.C. A suitable pressure is 100 kg/cm.sup.2, suitable
transfer pressure 300 kg/cm.sup.2 suitable curing time 150 s and
suitable injection time 15 s.
Example 4
A compound is manufactured of the following components:
50 parts by weight of a melamin-formaldehyde resin (2 mols
formaldehyde per mol melamine)
30 parts by weight calcium carbonate
2 parts by weight zinc stearate
18 parts by weight polyvinyl alcohol fibres having a length of 15
mm
The components are kneaded together in a sigma kneader. When the
water has evaporated in the furnace at approximately 50.degree.C,
the product obtained is ground to particles having a size of
approximately 3 mm. The compound is suitable for compression
moulding, injection moulding and transfer moulding. It can be
handled under the same conditions as the compound described in
Example 3.
Example 5
A moulding compound is manufactured of the following
components:
35 parts by weight of an epoxy resin containing of a mixture of 51
percent by weight of a cycloaliphatic epoxy resin part with an
epoxy content of 6.2 equ./kg and a viscosity of 1.5 . 10.sup.5 cP
at 25.degree.C, 48.5 percent by weight of a curing agent part
consisting of a hexahydrophthalic acid anhydride and 0.5 percent by
weight of an acceleration part consisting of benzyl
dimethylamine
10 parts by weight polyvinyl alcohol fibres having a length of 10
mm
2 parts by weight zinc stearate
30 parts by weight aluminum trihydrate
23 parts by weight zirconium silicate
The components are kneaded together at around 75.degree.C. The
doughy compound thus obtained is cured at a temperature of
170.degree.C and a pressure of 100 kg/cm.sup.2.
Example 6
A moulding compound is manufactured of the following
components:
30 parts by weight of a resin consisting of 60 parts by weight of
percent tetraethylene glycol dimetacrylate, 25 percent by weight of
a copolymerisate of equal parts methyl acrylate and methyl
methacrylate having a molecular weight of 130,000 and 15 percent by
weight of an unsaturated polyester resin produced in conventional
manner from diethylene glycol and maleic acid anhydride using 1.1
mol diethylene glycol per mol maleic acid, by boiling at 165 -
190.degree.C to an acid number of 40.
0.5 parts by weight benzoyl peroxide
12 parts by weight polyvinyl alcohol fibres having a length of 25
mm
20 parts by weight cellulose powder having a particle size of
around 100 microns
The moulding compound is manufactured and moulded in the same was
as the compound described in Example 1.
Example 7
A moulding compound is manufactured and moulded in the manner
stated in Example 6 with the exception that the unsaturated
polyester resin stated there is replaced by an equal amount of
prepolymerised diallylphthalate (for example DAPON from Food
Machinery Corporation, USA).
The compounds described in Example 1 - 7 can be used not only for
manufacturing extinguishing chamber plates in high voltage circuit
breakers, but also for manufacturing other insulating parts which
are subjected to the influence of electric arcs in switching
devices of different types, such as extinguishing chutes in
contactors and isolators.
* * * * *