U.S. patent number 3,792,192 [Application Number 05/319,147] was granted by the patent office on 1974-02-12 for electrical cable.
This patent grant is currently assigned to The Anaconda Company. Invention is credited to Walter J. Plate.
United States Patent |
3,792,192 |
Plate |
February 12, 1974 |
ELECTRICAL CABLE
Abstract
An electric power cable comprises extruded strand shielding and
an inner layer of rubber insulation such as ethylene-propylene
copolymer or ethylene-propylene-diene terpolymer rubber bonded by
cross-linking to an outer layer of cross-linked polyethylene
insulation.
Inventors: |
Plate; Walter J. (Rye, NY) |
Assignee: |
The Anaconda Company (New York,
NY)
|
Family
ID: |
23241052 |
Appl.
No.: |
05/319,147 |
Filed: |
December 29, 1972 |
Current U.S.
Class: |
174/102SC;
174/106SC; 174/36; 174/107; 174/120SC |
Current CPC
Class: |
H01B
13/14 (20130101); H01B 9/026 (20130101); H01B
7/0275 (20130101); H01B 9/027 (20130101) |
Current International
Class: |
H01B
13/06 (20060101); H01B 7/02 (20060101); H01B
9/02 (20060101); H01B 13/14 (20060101); H01B
9/00 (20060101); H01b 007/18 () |
Field of
Search: |
;174/12SC,12R,12SR,12SC,11AR,11S,11R,11PM,12AR,36,16SC,107 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Goldberg; E. A.
Attorney, Agent or Firm: Volk; Victor F.
Claims
I claim:
1. An electric cable comprising:
A. a metallic conductor,
B. a layer of semi-conducting strand shielding surrounding said
conductor,
C. a layer of insulation selected from the group consisting of
ethylene-propylene copolymer and ethylene-propylene-diene
terpolymer rubbers surrounding said layer of strand shielding,
D. a layer of electrically insulating cross-linked polyethylene
insulation surrounding said layer of rubber and bonding thereto,
and,
E. a polymeric jacket surrounding said layers of insulation.
2. The cable of claim 1 wherein said rubber layer comprises
ethylene-propylene copolymer.
3. The cable of claim 1 wherein said rubber layer comprises
ethylene-propylene-diene terpolymer.
4. The cable of claim 2 wherein said copolymer comprises filler
material blended therewith, thereby increasing the specific
inductive capacitance of said copolymer to a value above 3.
5. The cable of claim 3 wherein said terpolymer comprises filler
material blended therewith, thereby increasing the specific
inductive capacitance of said terpolymer to a value above 3.
6. The cable of claim 1 wherein said layers of insulation bond to
each other at their interface by molecular cross-linking.
7. The cable of claim 6 wherein said layers of insulation comprise
a common cross-linking agent.
8. The cable of claim 7 wherein said agent comprises
di-.alpha.-cumyl peroxide.
9. The cable of claim 1 wherein said jacket comprises a
semiconducting composition applied directly over said layer of
polyethylene.
10. An electric cable comprising:
A. a metallic conductor,
B. an inner layer of rubber-based insulating composition
surrounding said conductor, said composition having a 100 percent
modulus at 130.degree. C of at least 50 percent of the 100 percent
modulus of said composition at 25.degree. C,
C. an outer layer of vulcanized polymer-based insulating
composition surrounding said inner layer,
a. said outer layer bonding to said inner layer,
b. said outer layer composition having a 100 percent modulus at
room temperature substantially higher than the 100 percent modulus
at room temperature of said inner layer composition,
c. said outer layer composition having a 100 percent modulus at
130.degree. C substantially lower than said 100 percent modulus at
130.degree. C of said inner layer composition, and
d. the modulus at 130.degree. C of said outer layer composition not
exceeding one-third of the modulus at 25.degree. C of said outer
layer composition, and
e. said inner and said outer layers together totaling at least 250
mils in radial thickness.
11. The cable of claim 10 comprising a layer of semiconducting
strand shielding surrounding said conductor under said inner layer
and bonding to said inner layer.
12. The cable of claim 10 wherein said inner layer composition
comprises filler material blended therewith, thereby increasing the
specific inductive capacitance of said inner layer composition to a
value above 3, said value substantially exceeding the specific
inductive capacitance of said outer layer composition.
13. The cable of claim 10 wherein said inner and outer layer
compositions comprise a common cross-linking agent.
14. The cable of claim 12 wherein said inner and outer layer
compositions comprise a common cross-linking agent.
15. The cable of claim 10 comprising a semiconducting polymeric
jacket directly surrounding said outer layer.
16. The cable of claim 14 wherein said cross-linking agent
comprises di-.alpha.-cumyl peroxide.
Description
BACKGROUND OF THE INVENTION
It has been known to insulate electric power cables with
polyethylene incorporating a cross-linking agent, such as
di-.alpha.-cumyl peroxide, and to heat the cables so insulated so
as to form cables with non-thermoplastic polyethylene insulation.
Non-thermoplastic, cross-linked polyethylene does not evidence the
stress cracking associated with thermoplastic polyethylene and
functions satisfactorily at higher temperatures. Although millions
of feet of cross-linked polyethylene cable do operate without
fault, some deficiencies of cross-linked polyethylene have been
noted. For example, cross-linked polyethylene does not resist
corona attack as well as certain rubbers. Cross-linked polyethylene
has a high elastic modulus that makes cables having thick walls of
such insulation relatively stiff and inflexible. It expands
considerably when heated and may evidence the phenomenon of
"treeing" under the electrical stresses encountered in normal
operation.
Cables have also been successfully made with ethylene-propylene and
ethylene-propylene-diene rubbers, known respectively as EPM and
EPDM, for insulation. These materials behave like other rubbers in
having a high flexibility and retention of physical properties at
elevated temperatures and have high resistance to corona attack.
They do not expand as much upon heating as does polyethylene but
neither do they have as high a dielectric strength as the latter.
EPM and EPDM do not extrude smoothly unless they have been
compounded with a filler, such as clay, and this has the effect of
raising the specific inductive capacitance (S.I.C.) of the
composition to a value greater than that of polyethylene. While the
rubberiness or resilience of EPM and EPDM has the advantage of
making cables more flexible, polyethylene has greater toughness and
resistance to deformation at ordinary cable temperatures.
SUMMARY OF THE INVENTION
I have invented a cable that has excellent corona resistance on the
inside of the insulation, where the electrical stresses have their
highest values, and expands less on heating in this area, where the
conductor generates high temperatures. On the outside, the
insulation retains a relatively hard, tough consistency, during
installation and normal operations, characteristic of cross-linked
polyethylene. My new cable comprises a metallic conductor, a layer
of extruded strand shielding surrounding the conductor, a layer of
ethylene-propylene copolymer or ethylene-propylene-diene rubber
surrounding the layer of strand shielding, a layer of cross-linked
polyethylene insulation surrounding the layer of rubber and a
polymeric jacket surrounding the outer layer of insulation. The
rubber comprises blended filler material that increases its
specific inductive capacitance (also known as "dielectric
constant") to a value of above 3 and the rubber and polyethylene
layers bond to each other at their interface by molecular
cross-linking, accomplished by a common cross-linking agent such as
di-.alpha.-cumyl peroxide. In a preferred embodiment of my
invention the jacket comprises a semiconducting composition
extruded directly over the layer of polyethylene.
A useful embodiment of my invention comprises a metallic conductor,
preferably with a layer of semiconducting strand shielding
surrounding the conductor, and an inner layer of rubber-based
insulating composition, surrounding the conductor and any
semiconducting strand shielding, and having a 100 percent modulus
at 130.degree. C of at least 50 percent of its 100 percent modulus
at 25.degree. C. An outer layer of vulcanized polymer-based
insulating composition surrounds and bonds to the inner layer. This
outer layer composition has a 100 percent modulus at room
temperature substantially higher than the 100 percent modulus at
room temperature of the inner layer composition, and a 100 percent
modulus at 130.degree. C substantially lower than the 100% modulus
at 130.degree..varies.C of the inner layer composition. Preferably
the inner layer composition comprises filler material blended
therewith, thereby increasing its specific inductive capacitance to
a value above 3, substantially exceeding the specific inductive
capacitance of the outer layer composition. The inner and outer
layers of this cable preferably comprise a common cross-linking
agent such, for a preferred example, as di-.alpha.-cumyl peroxide,
and, in a preferred embodiment, a semiconducting polymeric jacket
directly surrounds the outer layer.
BRIEF DESCRIPTION OF THE APPENDED DRAWING
FIG. 1 shows a section of a cable of my invention.
FIG. 2 shows a section of another embodiment of the cable of my
invention.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
The cable 10 comprises a metal conductor 11 which may have a
stranded or solid configuration, surrounded by a layer 12 of
extruded semiconducting polymeric composition having a smooth
cylindrical outer surface. The layer 12 may consist of
thermoplastic or vulcanizible compositions or have partial
vulcanization as described in Arnaudin et al. U.S. Pat. No.
3479446, incorporated herein, by reference. Directly over the layer
12 I have extruded the layer 13 of a synthetic rubber composition
based on either EPM or EPDM.
The term EPM has widespread usage commercially for rubbers formed
by copolymerizing ethylene and propylene, and the term EPDM has
widespread usage commercially for terpolymers that include, in
addition to ethylene and propylene, a relatively small proportion
of a diene. U.S. Pats. No. 2933480 and 3151173, incorporated herein
by reference, enumerate a number of suitable dienes, such as
hexadienes and norbornadienes. A review of the art of EPM and EPDM
referred to generically therein by the term "polyolefin elastomers"
appeared in an article by F.P. Baldwin and G. Ver Strate in Vol.
45, No. 3, Apr. 30, 1972, of Rubber Chemistry and Technology, pp
709-881. The compositions of the layer 13 incorporate, in addition
to the usual minor compounding ingredients, a di-.alpha.-cumyl
peroxide for cross-linking and 20-60 percent by weight of filler,
such as clay filler, intimately dispersed. The filler has the
function of reducing the nerve of the rubber composition so that it
will extrude smoothly but it also has the effect of increasing the
specific inductive capacitance. As I shall explain, the higher
S.I.C. proves to have an advantage in my new cable
construction.
Over the layer 13 I have extruded a layer 14 of polyethylene
insulation also incorporating di-.alpha.-cumyl peroxide for
cross-linking. Heating for vulcanization of the insulation does not
proceed until I have extruded both layers 13 and 14, with the
results that, since they both employ the peroxide for
cross-linking, the layers cross-link together at their interface in
a firm bond. This bonding prooves to have great importance to the
superior performance of the cable 10 since the layer 14 of
polyethylene has a much higher thermal coefficient of expansion
than the rubber layer 13 and would separate from the layer upon
heating in the absence of a bond. Separation of the layers would
create voids within which corona discharges would occur when the
cable becomes highly stressed electrically. I have applied a
semiconducting layer 16, preferably formed of extruded polymeric
compound, directly over the layer 14 to constitute the insulation
shielding layer, and this has a covering of copper or aluminum
shielding tapes 17, covered, in turn, by an extruded protective
jacket 18. I can use any of a number of known cable jacketing
materials for the jacket 18 of which I consider compositions based
on polyvinyl chloride, neoprene, and butyl rubber as particularly
suitable. In FIG. 2 I have shown a similar cable 20, differing from
the cable 10 by the omission of the layers 16-18 for which I
substitute a semiconducting polymeric jacket 21 having embedded
drain wires 22, such as I have joined in describing in Plate et al.
U.S. Pat. No. 3474189.
Examples 1 and 2 respectively exemplify embodiments of the
constructions of FIGS. 1 and 2.
EXAMPLE I
35 kV Cable
Layer Diameter Thickness Inch Inch, Min. Nominal Bare copper,
compact round -- 0.481 Extruded strand shielding 0.008 0.503 EPDM
rubber 0.118 0.748 Polyethylene cross-linked 0.228 1.219 Insulation
shielding 0.030 1.289 Bare copper tapes 0.003 1.297 Polyvinyl
chloride jacket 0.080 1.468
EXAMPLE II
35 kV Cable
Layer Diameter Thickness Inch Inch, Min. Nominal Bare copper,
compact round -- 0.481 Extruded strand shielding 0.008 0.503 EPDM
rubber 0.118 0.748 Polyethylene, cross-linked 0.140 1.041 Extruded
semiconducting jacket 0.085 1.220
6 No. 17 Awg. copper drain wires
The cables of Examples I and II exhibited the S.I.C. and power
factors listed in Table I at the tabulated temperatures and
electric stresses.
TABLE I
Example I Example II volts/mil S.I.C. %p.f. S.I.C. %p.f. Room
temperature 20 2.68 0.170 2.74 0.360 40 2.68 0.208 2.74 0.361 60
2.68 0.211 2.74 0.365 80 2.68 0.215 2.74 0.369 90.degree. C 20 2.51
0.489 2.58 0.620 40 2.51 0.495 2.58 0.625 60 2.51 0.510 2.58 0.631
80 2.51 0.515 2.58 0.638 130.degree. C 20 2.38 0.830 2.43 0.931 40
2.38 0.855 2.43 0.949 60 2.38 0.871 2.43 0.965 80 2.38 0.885 2.43
0.979
the power factors of the tables of Examples I and II varied with
frequency as tabulated in Table II at the indicated
temperatures.
TABLE II
Example I Example II Hertz at room temperature S.I.C. %p.f. S.I.C.
%p.f. 60 2.82 0.240 2.82 0.350 100 2.79 0.190 2.85 0.330 1,000 2.79
0.145 2.84 0.250 10,000 2.78 0.148 2.82 0.230 100,000 2.77 0.298
2.82 0.280 Hertz at 90.degree. C 60 2.60 0.500 2.65 0.670 100 2.63
0.350 2.66 0.550 1,000 2.62 0.200 2.64 0.330 10,000 2.61 0.151 2.63
0.240 100,000 2.61 0.229 2.63 0.240 Hertz at 130.degree. C 60 2.46
0.890 2.54 1.080 100 2.50 0.630 2.55 0.770 1,000 2.48 0.285 2.53
0.370 10,000 2.47 0.170 2.51 0.235 100,000 2.46 0.160 2.51
0.265
in Table III I report the results of loading the cable of Example I
to 100.degree. C conductor temperature 8 hours each day for 100
working days in accelerated aging tests, while applying A-C voltage
equal to two times rated voltage to ground continuously throughout
the duration of the test. The table reports properties monitored
prior to current loading at the beginning of each day. ##SPC1##
Example I - current loading: 483 amperes
*A=Inception B=Extinction
Table IV tabulates the results of testing the cable of Example II
following the procedure of Table III. ##SPC2##
Example II - current loading: 514 amperes
Table V tabulates the results of immersing the cable of Example I
in water at 90.degree. C and testing at the indicated intervals.
##SPC3##
Table VI tabulates the results of immersing the cable of Example II
in water at 90.degree. C and testing at the indicated intervals.
##SPC4##
Table VII reports the results of immersing the cable of Example I
in water at 90.degree. C for two months while stressed at 34.6 kV,
A-C. ##SPC5##
Table VIII reports the results of immersing the cable of Example II
for two months in water at 90.degree. C while stressed at 34.6 kV,
A-C. ##SPC6##
A terpolymer formulation suitable for the layer 13 has the
composition of Table IX.
TABLE IX
pts. by wt. Nordel* 1040 100 carbon black 10 silicone treated clay
110 lead oxide 5 silane 1 antioxidant 1.5 zinc oxide 5 paraffinic
oil 15 paraffin 5 di-.alpha.-cumyl peroxide 3.5 *Nordel has been
registered as a trademark of E.I. du Pont de Nemours & Co.,
Inc. for ethylene-propylene-dien e terpolymers. Nordel 1040
comprises 1-4 hexadiene, according to the literature of the
supplier.
A copolymer formulation suitable for the layer 13 has the
composition of Table X.
TABLE X
pts. by wt. Vistalon* 404 100 zinc oxide 5 Translink** 110 carbon
black 10 Agerite*** Resin D 1.5 PbO.sub.2 3 silane 1
di-.alpha.-cumyl peroxide 2.7 sulphur 0.3
The copolymers and terpolymers suitable for use in the layer 13
will have molecular weight, prior to vulcanization, of 100,000 to
1,000,000 and an ethylene content between 25 and 75 mole percent.
In addition, I may blend them with as much as about 15 percent of
polyethylene but not so much as to destroy the rubbery nature of
the composition characterized by a relative retention of modulus
upon heating. In modern art usage and in this application the word
"rubber" distinguishes polymers, having a resilient property and
also exhibiting a substantially flat modulus vs temperature curve,
from thermoplastics, such as polyethylene, which, even after
cross-linking, drop sharply in modulus with increasing temperature.
Persons skilled in rubber and plastic technology employ the 100%
modulus at a given temperature as a reproducible parameter,
convenient for comparing different materials. They determine the
100% modulus as the stress in load-per-unit-section required to
elongate a specimen 100%. A chart of the 100% modulus, in pounds
per square inch, of butyl and EPM rubbers and filled and non-filled
cross-linked polyethylene over a range of temperatures appears in
IEEE Transactions on Power Apparatus and Systems, April, 1968, page
1,142, and I include this chart by reference in this application.
The chart shows polyethylene to have a substantially higher 100
percent modulus at room temperature than the rubbers, but a
substantially lower modulus,when non-filled, than the rubbers at
130.degree. C. At 130.degree. C the 100 percent modulus of
polyethylene drops to less than one-third its value at 25.degree. C
while the 100.degree. percent modulus of EPM at 130.degree. C
exceeds its value at 25.degree. C. For usefulness in the cable of
my invention the 100 percent modulus of the composition of the
rubber layer 14 should not drop more than about 50 percent between
25.degree. and 130.degree. C. Rubber compositions that retain their
modulus at increased temperature and can have utility in the
practice of this invention, may incorporate minor proportions of
polyethylene or other thermoplastic materials. Particularly up to
about 30 parts of polyethylene may be incorporated into the EPM or
EPDM compositions of my layer per hundred parts of rubber, within
the scope of my invention. Similarly, my outer layer 14 may
comprise small proportions of rubber. Particularly, a polyethylene
composition used for the layer 14 may incorporate up to about 30
parts of EPM or EPDM for 100 parts of polyethylene. An additional
terpolymer formulation suitable for the layer 13 and used as the
EPDM composition in Examples I and II appears in Table XI.
TABLE XI
pts. by wt. Nordel 1040 100.0 polyethylene 10.0 Translink 120.0
carbon black 5.0 litharge 6.0 antioxidant 1.0 paraffin 3.0
paraffinic oil 10.0 silane 1.5 di-.alpha.-cumyl peroxide 3.0
sulphur 0.3
The flat temperature modulus curve of rubbers, hereinabove noted,
has particular value for high-voltage cables with thick walls of
insulation because such insulation constitutes a heat barrier
confining heat generated by the conductor. For this reason my
invention has particular utility in cables with a radial insulation
thickness of at least 250 mils.
I determine the addition of clay or other filler to the rubber
composition by processing requirements and generally do not exceed
the quantity required for good extrusion except that I do not add
less than the quantity required to bring the S.I.C. of the
composition above 3. The S.I.C. of the composition of Table IX
tested at about 3.9, so that processing, rather than grading
requirements determine the practical filler content. Persons
skilled in rubber compounding can calculate the percentage of
filler to be added to achieve a desired S.I.C. of a rubber
composition from the known S.I.C. values of the filler material and
the uncompounded polymeric stock.
From the high initial corona inception values of Tables III and IV
it becomes clear that the bond at the interface between the inner
EPDM and outer polyethylene layers has not parted in spite of the
fact that the polyethylene has a much greater coefficient of
thermal expansion than the terpolymer. The inner layer, due to its
clay inclusion, has an S.I.C. of about 3.9 while the polyethylene
has an S.I.C. of about 2.3. My cable thus gains the advantage of
"grading" by having a greater S.I.C. material adjacent to the
conductor where the greatest stress concentration appears. In prior
art attempts to employ polymers for purposes of grading a cable
insulation, a discontinuity or void has always become evident
between the layers having different polymeric bases. A unique
feature of my invention resides in the bonding together of layers
of different polymers forming compositions of different S.I.C. by
means of a common vulcanizing agent that cross-links across the
layer interface.
For the cross-linking agent of Examples I and II I used
di-.alpha.-cumyl peroxide, but other vulcanizing agents can be used
within the scope of my invention provided only that they can affect
the cross-linking of both the rubber layer 13 and plastic layer 14
so that the two bond together. A number of suitable vulcanizing
agents for olefins have been enumerated in U.S. Pats. No. 2,888,424
and 3,036,982 which I incorporate herein, by reference.
In the manufacture of my cable I extrude four different layers over
the conductor: the strand shielding 12, the rubber insulation 13,
the polyethylene insulation 14, and the insulation shielding 16. I
may accomplish all these extrusions within one extrusion head of
appropriate known design, or may pass the core having each extruded
layer directly into another extrusion head to apply the next layer.
I may also practice combinations of such multiple and tandem
extrusions. For example, I may apply the strand shielding in one
head, and follow with a dual application of the rubber and
polyethylene insulation, followed, in turn, by tandem application
of the insulation shielding 16. The same range of choices applies
to the cable 20 with the strand shield replaced by the jacket 21. I
always apply the jacket 18, of course, in a tandem or separate
operation.
I have invented a new and useful electric cable of which I have
made the foregoing description exemplary rather than definitive,
and for which I desire an award of Letters Patent as defined in the
appended claims.
* * * * *