U.S. patent number 3,786,552 [Application Number 05/266,749] was granted by the patent office on 1974-01-22 for method of manufacturing a composite bimetallic sleeve for a die-casting machine.
This patent grant is currently assigned to Mitsubishi Kinzoku Kogyo Kabushiki Kaisha. Invention is credited to Masanori Kimura, Yuichi Saito, Tokuzo Shikano.
United States Patent |
3,786,552 |
Saito , et al. |
January 22, 1974 |
METHOD OF MANUFACTURING A COMPOSITE BIMETALLIC SLEEVE FOR A
DIE-CASTING MACHINE
Abstract
A sleeve is composed of a relatively thin inner layer made of
such highly infusible material as molybdenum, tungsten or their
alloys, and an outer layer made of an iron-base alloy. For
manufacture, a mixture of powders compounded to form an iron-base
alloy when heated is compacted to cylindrical shape around a hollow
cylinder suitably molded of one of the listed metals and alloys.
The compact is then sintered to provide an outer layer of the
iron-base alloy solidly united with the hollow cylinder.
Inventors: |
Saito; Yuichi (Urawa,
JA), Shikano; Tokuzo (Oomiya, JA), Kimura;
Masanori (Saitama-ken, JA) |
Assignee: |
Mitsubishi Kinzoku Kogyo Kabushiki
Kaisha (Chiyoda-ku, Tokyo-to, JA)
|
Family
ID: |
12771116 |
Appl.
No.: |
05/266,749 |
Filed: |
June 27, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Jun 30, 1971 [JA] |
|
|
46/47289 |
|
Current U.S.
Class: |
419/6; 29/447;
428/553; 419/26 |
Current CPC
Class: |
B22D
17/2023 (20130101); Y10T 428/12063 (20150115); Y10T
29/49865 (20150115) |
Current International
Class: |
B22D
17/20 (20060101); B22f 003/24 () |
Field of
Search: |
;29/420.5,182.3,420,447,DIG.31 ;75/28R |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lanham; Charles W.
Assistant Examiner: Reiley, III; D. C.
Attorney, Agent or Firm: Wenderoth, Lind & Ponack
Claims
We claim:
1. In a process of manufacturing a composite bimetallic sleeve for
a die-casting machine, wherein said sleeve consists of an inner
layer made of refractory metal materials such as molybdenum,
tungsten, and alloys containing therein at least one of these
metals as the principal constituent, and an outer layer made of a
ferrous alloy, said layers being diffusion bonded at their boundary
region, the improvement which comprises compacting a mixture of
powders in a cylindrical shape around the outer periphery of a
hollow cylinder of refractory metal which constitutes the inner
layer to a thickness greater than the thickness of said hollow
cylinder, said mixture of powders being a mixture which will form
the ferrous alloy by heat-treatment, thereafter sintering said
compacted mixture of powders on said cylinder to form a composite
structure consisting of an outer ferrous alloy layer solidly
metallurgically bonded to said hollow cylinder, and finally
machining the thus produced composite structure to desired
dimensions.
2. The process according to claim 1, further including a step of
covering the outer surface of said hollow cylinder, prior to the
compacting step, with a thin layer of nickel to increase the
bonding strength between said hollow cylinder as the inner layer
and the outer layer.
3. The process according to claim 1, further comprising shrink
fitting a hollow cylindrical steel covering on said outer layer.
Description
BACKGROUND OF THE INVENTION
This invention relates generally to die-casting machines, and in
particular to an improved sleeve for use in injecting molten metal
into the mold cavity of a die-casting machine. The invention is
also directed to a novel process for the manufacture of the
improved sleeve.
The art of die-casting has been widely utilized to produce
precision-made castings of metals or alloys with a melting point of
about 1,000.degree.C or less, such alloys including those of
aluminum, zinc, magnesium, copper, tin, and lead. There are two
known types of die-casting machines, the "cold chamber" type and
the "hot chamber" type. The cold-chamber machine, to which molten
metal is supplied from a separately installed melting furnace, is
employed for the die-casting of comparatively high melting-point
metals or alloys such as aluminum-, magnesium- and copper-base
alloys. The hot-chamber machine, having a built-in furnace, is used
to produce castings of lower melting-point metals or alloys such as
zinc-, tin- and lead-base alloys. In both types, molten metal or
alloy is forced into the die cavity through a cylindrical sleeve
built into the machines.
It is accordingly the sleeve, especially that of the cold-chamber
machine, which contacts the molten metal at its highest
temperature, so that it is required to be particularly heat-, wear-
and corrosion-resisting. This is all the more so because in recent
years the application of the die-casting machines to iron-base
alloys have been seriously attempted. Heretofore, the sleeve of the
cold-chamber machine has been made of a hot-die steel. This
material is so unsatisfactory in regard to the aforementioned
properties that the sleeve has a service life of from about 1 to 3
months or so when used for die-casting of aluminum-base alloy
having a relatively low melting point. In the case of iron-base
alloy casting, the sleeve can hardly undergo from several to
several tens of shots without showing some signs of abnormality.
Moreover, the alloy steel is a comparatively expensive material as
compared with ordinary steel, and the surfaces of the sleeve made
of this material require a costly heat treatment to prolong their
life to some extent.
It is well known that such highly infusible metals as molybdenum
and tungsten, as well as alloys having these metals as the
principal constituents, can well withstand the high temperatures
produced during die-casting of copper- and even iron-base alloys.
These metals and alloys will certainly be satisfactory as sleeve
materials. However, a sleeve made solely of the metals or alloys is
so expensive that it will hardly be manufacturable on a commercial
basis. It is an added disadvantage that since these materials are
all highly heat-conductive, too much heat will be released from the
molten metal passing through the sleeve.
During a die-casting operation, only a limited portion of the
sleeve adjacent its inner surface is known to have a markedly high
temperature rise due to the heat of the molten metal passing
therethrough. Therefore, by using any of the above-mentioned
infusible metals or alloys in this limited portion alone, the
durability of the sleeve as a whole will be greatly increased.
However, it will serve no practical purposes if molten molybdenum,
tungsten or their alloys is sprayed onto the inner surface of a
conventionally available sleeve, because the coating thus formed
cannot possibly be sufficiently united with the surrounding sleeve
material. It may also be contemplated to tightly fix, as by the
process of shrinking-on, a hollow cylinder of a ferrous alloy or
the like around a thin pipe of the highly infusible metals or
alloys. As the sleeve manufactured in this manner is heated in
actual die-casting operation, however, its inner and outer layers
are certain to be displaced relative to each other.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide an improved
sleeve for use in a die-casting machine, which includes a
relatively thin inner layer made of highly infusible material and
an outer layer made of less expensive material, so that the service
life of the sleeve is greatly extended without substantially
increasing its manufacturing costs.
Another object of the invention is to provide a sleeve of the class
referred to, in which the outer layer is made of a ferrous alloy
such that heat to be released from molten metal passing
therethrough can be properly controlled.
A further object of the invention is to provide a sleeve of the
class referred to, in which the outer layer serves to protect the
inner layer, which may be less resistant to oxidation, from
deterioration due to the oxidative influence from its
periphery.
It is also an object of the invention to provide a novel process
for the manufacture of the above described sleeve, in which the
outer layer is formed by first compacting around the previously
molded inner layer a mixture of powders compounded to form a
ferrous alloy when heated, and thereafter sintering the compact, so
that no relative displacement or separation of the outer and inner
layers will take place when the sleeve is heated by molten metal.
This also prevents the overheating of the inner layer only.
According to this invention, briefly stated, there is provided a
sleeve for use in a die-casting machine, comprising an inner layer
made of material selected from the group consisting of molybdenum,
tungsten and alloys containing at least one of the metals as the
principal constituent, and an outer layer made of a ferrous alloy,
the inner layer and outer layer being solidly united with each
other.
The invention further provides a process for the manufacture of a
sleeve for use in a die-casting machine, which comprises providing
a hollow cylinder made of material selected from the group
consisting of molybdenum, tungsten and alloys containing at least
one of said metals as the principal constituent, compacting a
mixture of powders to cylindrical shape around the hollow cylinder,
the mixture of powders being compounded to form a ferrous alloy
when heated, sintering the compact to form an outer layer solidly
united with the hollow cylinder, and machining the thus-produced
composite structure to specified dimensions.
The novel features which are considered as being characteristic of
this invention are set forth in the appended claims. The invention
itself, however, together with additional objects and advantages
thereof, will be best understood from the following detailed
description taken in connection with the accompanying drawings.
BRIEF DESCRIPTION OF DRAWINGS
In the drawings:
FIG. 1 is a schematic vertical sectional view showing one form of
die-casting operation in a cold-chamber type machine by way of
explanation of this invention;
FIG. 2 is a schematic longitudinal sectional view of a two-layered
sleeve according to the invention;
FIG. 3 is a schematic longitudinal sectional view explanatory of
the way pressures are applied for compaction of an outer layer
around a previously formed inner layer;
FIG. 4 is a microscopic representation showing an example of
"diffusive junction" between the inner and outer layers of a sleeve
according to the invention;
FIG. 5 shows the dimensional specifications of an example of a
sleeve constructed according to the invention for use in an 80-ton
die-casting machine; and
FIG. 6 also shows the dimensional specifications of another sleeve
constructed according to the invention for use in a 250-ton
die-casting machine.
DETAILED DESCRIPTION
In order to fully appreciate this invention it is necessary first
to describe the configuration of a cold-chamber type die-casting
machine to which the improved sleeve of the invention is adaptable.
Referring to FIG. 1, therefore, molten metal 2 being kept at a
suitable temperature in a furnace 1 is either ladled or
automatically poured out of a vessel 3 into a sleeve 4. The molten
metal within the sleeve is then forced by a plunger 5 into a cavity
7 of a die 6, where the metal is cooled, assuming the shape
delineated by the mold cavity upon solidification. In a hot-chamber
type machine, on the other hand, which is not shown in the
drawings, the molten metal is supplied from a furnace built into
the machine to the die cavity via a sleeve coupled directly to the
furnace.
As may be apparent from the above description, the sleeve contacts
the molten metal at its highest temperature, so that it must be
made of material which is sufficiently heat-, wear- and
corrosion-resistant. Generally, this sleeve has been made of a
hot-die steel casehardened by the so-called "nitriding" process. It
must be noted, however, that the temperature of the molten metal or
alloy being cast in the cold-chamber machine is higher than the
temperature of that being cast in the hot-chamber machine. The
sleeve of the cold-chamber die-casting machine is thus placed under
particularly hard working conditions. It is an admitted fact in the
art that sleeves made of a casehardened hot-die steel cannot last
for any extended period of use when incorporated in the
cold-chamber machines.
As is well known, molybdenum, tungsten, or alloys containing one or
both of these metals as base can well withstand as high a
temperature as that of molten ferrous alloys. The present invention
provides a highly durable sleeve made, in part, of any of these
metals or alloys. FIG. 2 schematically illustrates this improved
sleeve, comprising an inner layer 4a made of one of the aforesaid
metals or alloys and an outer layer 4b made of a sintered ferrous
alloy. These layers 4a and 4b are solidly united with each other by
"diffusive junction" hereinafter described in greater detail. This
composite structure is further suitably machined for use as a
sleeve in a die-casting machine.
It will now be understood that, basically, the invention provides
an improved sleeve, and a process for the manufacture thereof,
which is composed of substantially completely integral inner and
outer layers, the inner layer being capable of withstanding the
high temperatures of the molten metal in a die-casting machine, and
the outer layer being made of inexpensive material to reduce the
overall cost of the sleeve. The thus-structured sleeve is confirmed
to be extremely durable, as hereinafter set forth in more concrete
terms. However, molybdenum, tungsten, and their alloys are very
expensive, so that these metals or alloys may preferably be used in
as small amounts as possible to further decrease the sleeve
cost.
To this end there may be used as the inner layer of the sleeve a
thin pipe of molybdenum or molybdenum-base alloy which has been
available conventionally. This pipe can considerably reduce the
thickness of the sleeve inner layer, does not cause any technical
problem in the manufacture of the two-layered sleeve, and improves
its corrosion-resistivity. The trouble, however, is the high
manufacturing cost of the pipe itself, which must undergo highly
involved steps of production, so that the sleeve cost is not
reduced as much as it is desired to be.
A thin, as-sintered pipe of molybdenum, tungsten, or alloys
containing one or both of these metals as the principal constituent
is, of course, employable as the sleeve inner layer when machined
into specific dimensions. This pipe is less expensive than the
above-described pipe of molybdenum or molybdenum-base alloy and
thus serves to reduce the sleeve cost.
It has long been considered impossible to produce, only through the
compacting and sintering processes, a long, thin pipe of exactly
specified dimensions. This difficulty is now overcome by a newly
developed method known to the art, in which powdered material is
compacted to desired shape around a sufficiently rigid, straight
core by means of a hydrostatic press. A compact in the shape of a
thin cylinder is obtained upon removal of the core. Proper
moldability of the powdered material is accordingly a prerequisite
of this method. Further, it requires considerable skill and utmost
care to attain a high degree of exactitude of the compact
dimensions.
The compact is then roasted, if necessary, and thereafter is
sintered at a temperature suitably determined according to its
composition, usually in the range of from about 1,250.degree. to
1,800.degree.C. In the case of liquid-phase sintering, however, the
dimensions of the sintered product tend to deviate from the
specifications. This is avoidable only through careful control of
such factors as the composition of the material, the placement of
the compact in the sintering furnace, and its sintering
temperature. Further, if any of the aforementioned alloys thus used
as the sleeve inner layer contains too much diffusion phase, it
will be less resistant to corrosion. For example, in case the alloy
contains too great quantities of nickel, iron, cobalt and other
constituents, with the result that about 10 percent or more by
volume of diffusion phase having a melting point considerably lower
than that of the base is produced, then it will be highly reactive
with the molten metal to be supplied for the die-casting
operation.
The cylindrical sinter obtained as above may be further subjected
to some postsintering operation to provide a product of the
prescribed dimensions. It must be noted, however, that if the
sintered metal or alloy has about 10 percent or more by volume of
fine particles of refractory oxides, nitrides, carbides or the like
dispersed therein, its strength will be considerably descreased.
The cutting and grinding operations that may be necessary for
finishing the cylindrical sinter will then be greatly hampered.
For formation of a surrounding outer layer on the thin pipe which
has been produced by the above process for use as the inner layer
of the sleeve according to this invention, a mixture of powders
capable of forming an iron-base alloy when heated is compacted, as
illustrated in FIG. 3, and thereafter is sintered in a temperature
range of from about 900.degree. to 1,300.degree.C. As indicated by
the arrows 9 in the drawing, equal pressures are simultaneously
applied from both sides of the powders, through the inner layer 4a
and through a rubber covering 8, so that the thin inner layer 4a is
not subjected to any substantial deformation.
During the sintering of the powders thus compacted to shape, the
mentioned "diffusive junction" is formed between the inner and
outer layers. The junction is further strengthened by contraction
which accompanies the sintering operation. FIG. 4 is a microscopic
representation of such a junction obtained at about 1,250.degree.C
between molybdenum-base alloy [Mo (balance) - 0.48 wt.% Ti - 0.08
wt.% Zr ] and sintered iron-base alloy [Fe (balance) - 2 wt.% Ni -
0.5 wt.% Mo - 0.5 wt.% C] . It will be clearly observed that the
porosity of the sintered iron-base alloy 11 decreases toward the
interface between the same and the molybdenum-base alloy 10, and
that these two layers are strongly united.
In general, the interface between such inner and outer layers is
known to offer a resistive pressure of from about 5 to 20 kilograms
per square millimeter against shearing. In order to obtain a proper
state of diffusive junction between these layers, it is essential
that: (1) the composition of the ferrous alloy and its sintering
temperature be well regulated so that the outer layer molded of
that ferrous alloy will contract linearly within the range of from
about 0.2 to 10 percent upon sintering; and (2) this outer layer be
compacted with as few irregularities as possible in density. While
the outer layer must contact linearly about 0.2 percent or more
upon sintering to be sufficiently united with the inner layer, the
outer layer tends to be cracked if the contraction exceeds about 10
percent. Cracks are likewise developed on the outer layer if it
suffers non-uniform length-wise contraction due to density
irregularities suggested in (2) above. Provision of a thin nickel
layer at the interface between the two layers will serve to further
strengthen their junction.
The density control of the outer layer may be effected by carefully
regulating the composition of the mixture of iron and other powders
as well as its sintering conditions, or by employing the technique
of copper impregnation. It is one of the advantages of this
invention that by the same density control of the outer layer, its
heat conductivity is regulatable so that heat to be released from
molten metal within the sleeve can be appropriately predetermined.
If desired, the inner surface of the sleeve inner layer may be
carburized to form an additional carbide layer, while the outer
layer may be further reinforced with a shrunk-on steel cylinder or
covering.
The two-layered sleeve of this invention, manufactured as
hereinabove described, was built into a die-casting machine to test
its durability when placed in contact with molten aluminum-,
copper- and iron-base alloys. No signs of abnormality were observed
in this sleeve when up to 10,000, 5,000 and 1,000 shots
respectively of these alloys were die-cast, although these figures
are subject to some variation depending upon the material of the
sleeve inner layer.
The present invention is hereinafter described more specifically in
terms of several Examples thereof, which are meant purely to
illustrate and explain and not to impose limitations upon the
invention.
EXAMPLE I
Molybdenum powder (with a particle size of 3.5.mu.) and nickel
powder (3 .mu.) were ball-milled for 24 hours. The thus-mixed
powders (1.5 wt.% Ni and Bal Mo, with 1 percent paraffin added
separately) were compacted to cylindrical shape with a hydrostatic
press at pressures up to 1.5 tons per square centimeter around a
straight, well-ground bar made of stainless steel ("SUS27"
corresponding to AISI 304). The hollow cylindrical compact thus
formed was then roasted at about 750.degree.C for 2 hours in the
presence of hydrogen and thereafter was sintered at about
1,350.degree.C for 5 hours to provide a highly dense product with
an outer diameter of 50 millimeters, an inner diameter of 36
millimeters, and a length of 260 millimeters. The outer surface of
this sintered product was machined to an outer diameter of 46
millimeters.
A mixture of powders compounded to form an iron-base alloy when
heated (2 wt.% Ni, 0.5 wt.% Mo, 0.5 wt.% C, and Bal.Fe), prepared
by use of a kneading machine, was then compacted to cylindrical
shape around the above obtained product with a hydrostatic press at
pressures up to 1.5 tons per square centimeter, and was further
sintered at about 1,250.degree.C for 1 hour to provide an outer
layer with an outer diameter of 100 millimeters. The two-layered
hollow cylinder thus obtained was machined to the dimensions set
forth in FIG. 5, for use as a sleeve in an 80-ton type die-casting
machine.
The sleeve was built into the die-casting machine, which had been
in actual operation in a plant, to test its durability. No
abnormality was exhibited at the moment when the sleeve had
undergone up to 10,000 shots during die-casting operations.
EXAMPLE II
A sleeve was manufactured in substantial accordance with Example I,
except that its inner layer was composed of molybdenum-base alloy
(further containing 1.5 wt.% nickel and 1.5 wt.% iron), and that
the sintering temperature of the inner layer was set to about
1,400.degree.C. This sleeve was built into a die-casting machine
for aluminum- and copper-base alloys. No abnormality was observed
when up to 10,000 and 1,000 shots respectively of the said alloys
were cast.
EXAMPLE III
A sleeve was manufactured in substantial accordance with Example I,
except that its inner layer (with a thickness of 3 millimeters) was
composed of tungsten-base alloy [W (balance) - 4 wt.% Ni - 4 wt.%
Mo - 2wt.% Fe], and that the sintering temperature of this inner
layer was set to about 1,450.degree.C. This sleeve was then adapted
for die-casting of aluminum- and copper-base alloys to test its
durability, with results substantially identical with those set
forth in Example II.
EXAMPLE IV
Molybdenum powder with a BET particle size of 0.2 .mu., TiH.sub.2
with a BET particle size of 0.1 .mu., and .tau.-alumina with a
specific surface area of about 100 square meters per gram were
wet-mixed for 48 hours in a ball mill. Nickel was then added to
this mixture. The thus-compounded mixture [(Mo(balance)-0.1 wt.%
Ni-0.5 wt.% Ti)-3 vol.%Al.sub.2 O.sub.3 ] was compacted to
cylindrical shape with a hydrostatic press at pressures up to 2
tons per square centimeter. The compact was then roasted at about
1,000.degree.C for 1 hour in the presence of hydrogen and was
further sintered at about 1,650.degree.C for 3 hours in a vacuum.
The outer surface only of this sinter was machined to provide a
cylindrical product of molybdenum-base alloy with an outer diameter
of 70 millimeters, an inner diameter of 54 millimeters, and a
length of 330 millimeters.
A mixture of 97.2 wt.% of iron powder, 2 wt.% of nickel powder, 0.5
wt.% of molybdenum powder, and 0.3 wt.% of graphite powder was
compacted to cylindrical shape around the above obtained product
with a hydrostatic press at pressures up to 2 tons per square
centimeter. This compact was then sintered at about 1,300.degree.C
for 1 hour in the presence of hydrogen. The outer layer thus formed
had an outer diameter of 140 millimeters.
The inner surface of the two-layered hollow cylinder produced in
this manner was cut and ground to increase the inner diameter to 60
millimeters. The product was further machined to the dimensions
specified in FIG. 6, for use as a sleeve in a 250-ton die-casting
machine. Used for die-casting of stainless steel ("18-8"), the
sleeve showed no signs of abnormality up to 1,000 shots.
EXAMPLE V
Nickel was plated to a thickness of about 1 .mu. on the outer
surface of a hollow cylinder molded of molybdenum-base alloy [Mo
(balance) - 0.48 wt.% Ti - 0.08 wt.% Zr], the hollow cylinder
having an outer diameter of 63.6 millimeters, an inner diameter of
59.6 millimeters, and a length of 330 millimeters. A mixture of
97.8 wt.% of iron powder, 2 wt.% of nickel powder, and 0.2 wt.% of
graphite powder was compacted to cylindrical shape around the above
plated cylinder with a hydrostatic press at pressures up to 2 tons
per square centimeter. The compact was then sintered at
1,050.degree.C for 2 hours in the presence of hydrogen. The outer
layer thus formed by the sintered iron-base alloy had an outer
diameter of about 90 millimeters.
After machining the surface of the outer layer to decrease its
outer diameter to 80 millimeters, a pipe of carbon steel ("S45C"
corresponding to "SAE1042") with an outer diameter of about 135
millimeters was tightly fitted on the outer layer by a shrink
fitting process. This product was further machined to the
dimensions set forth in FIG. 6, for use as a sleeve in a 250-ton
die-casting machine. No signs of abnormality were exhibited by the
sleeve when up to 1,000 and 10,000 shots respectively of cast iron
and aluminum-base alloy were die-cast by the 250-ton type
machine.
Although the present invention has been shown and described
hereinabove in terms of several specific examples thereof, it is
understood that the invention itself is not to be restricted by the
exact showing of the drawings and the description thereof, but is
considered to include a latitude of modification, substitution, and
change. It is therefore appropriate that the appended claims be
construed broadly and in a manner consistent with the fair meaning
and proper scope of the invention disclosed herein.
* * * * *