U.S. patent number 3,771,982 [Application Number 05/285,973] was granted by the patent office on 1973-11-13 for orifice assembly for extruding and attenuating essentially inviscid jets.
This patent grant is currently assigned to Monsanto Company. Invention is credited to Emerick J. Dobo.
United States Patent |
3,771,982 |
Dobo |
November 13, 1973 |
ORIFICE ASSEMBLY FOR EXTRUDING AND ATTENUATING ESSENTIALLY INVISCID
JETS
Abstract
An improved orifice assembly is provided for extruding filaments
from low-viscosity or essentially inviscid melts. By employing an
orifice having a nozzle like configuration in the "gas plate"
substantial increases in attenuation rates are realized. The
orifice is characterized by a convergent entry section, a throat
section and a divergent exit section.
Inventors: |
Dobo; Emerick J. (Cary,
NC) |
Assignee: |
Monsanto Company (St. Louis,
MO)
|
Family
ID: |
26952095 |
Appl.
No.: |
05/285,973 |
Filed: |
September 5, 1972 |
Current U.S.
Class: |
65/527; 164/462;
164/475; 164/489; 264/211.14; 264/211.16; 425/464 |
Current CPC
Class: |
C03B
37/02 (20130101); G11C 11/23 (20130101); C03B
37/083 (20130101); C03B 37/08 (20130101); B22D
11/005 (20130101); Y02P 40/57 (20151101) |
Current International
Class: |
B22D
11/00 (20060101); C03B 37/08 (20060101); C03B
37/00 (20060101); C03B 37/02 (20060101); C03B
37/083 (20060101); G11C 11/21 (20060101); G11C
11/23 (20060101); C03b 037/02 (); D01d
011/00 () |
Field of
Search: |
;264/176F ;164/82,86
;65/1,16 ;425/461,463,464 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lindsay, Jr.; Robert L.
Claims
I claim:
1. An improved orifice assembly for use in the formation of fibers
and filaments by extruding an essentially inviscid melt as a
filamentary stream, which comprises in combination:
a. a first plate;
b. a second plate, said second plate being spaced beneath said
first plate in a stacked relationship therewith;
c. a first orifice, said first orifice being centrally disposed in
said first plate;
d. a second orifice, said second orifice being centrally disposed
in said second plate in co-axial alignment with said first orifice,
said second orifice having a nozzle configuration with a convergent
entry section, an intermediate throat section and a divergent exit
section, with the exit section having an included angle of
divergence of between 4.degree. to 12.degree.;
e. a substantially enclosed chamber, said chamber being defined by
a gap space between the opposing faces of said first and second
plates, said gap space having a vertical distance of less than five
times the diameter of the throat section of said second plate
orifice;
f. a means for supplying an inert gas under pressure to said
substantially enclosed chamber and into said second orifice.
2. The orifice assembly of claim 1, wherein the included angle of
divergence in the divergent exit section of said second orifice is
in the range of from about 6.degree. to 8.degree..
3. The orifice assembly of claim 1, wherein the diameter of the
throat section of said second orifice is substantially equal to the
exit diameter of said first orifice.
4. The orifice assembly of claim 1, wherein the exit diameter of
said first orifice is larger than the diameter of the throat
section of said second orifice.
5. The orifice assembly of claim 1, wherein the ratio of the exit
diameter of said first orifice to the diameter of the throat
section of said second orifice is from about 1.1 : 1.0 to 1.5 :
1.0.
6. The orifice assembly of claim 1, wherein the length of said
second orifice is from about five to 100 times greater than the
exit diameter of said first orifice.
Description
BACKGROUND OF THE INVENTION
This invention is concerned with an improvement in apparatus for
carrying out an extrusion of molten materials of extremely low
viscosity to form filamentary structures. More particularly, the
invention is directed to an improved orifice assembly for forming
filamentary structures from essentially inviscid melts.
Until quite recent, it was not possible to fabricate filaments and
fibers from materials such as metals, metal alloys and ceramics by
the method of melt extrusion. The limiting factor was that the melt
viscosity of the various metals and ceramics is so low as to be
practically negligible. In other words, the melts of metals and
ceramics are essentially inviscid.
The problem presented by an inviscid melt when attempting to
extrude it to form filaments is that the surface tension of the
filamentary jet, as it issues from the shaping die, is so great in
relation to its viscosity that the molten stream breaks up before
sufficient heat can be transferred for conversion to the solid
state
This intractable problem has now yielded to a unique solution as
described in U.S. Pat. Nos. 3,216,076 and 3,658,979. In accordance
therewith, the nascent molten jet, as it issues from the shaping
die, is brought into contact with a gas capable of instant reaction
with the jet surface. The result is the formation of a thin film
which envelopes the jet surface. This thin film has been found to
be capable of holding the jet stream together until sufficient heat
can be transferred to effect solidification.
Substantial improvements in the actual practice of this promising
method have been made since it was first introduced. Perhaps, most
significant to date has been the improved orifice system as
described in U.S. Pat. No. 3,613,158. Disclosed therein is an
orifice assembly having two concentric plates disposed in a stacked
relationship, one above the other. Each plate contains a centrally
disposed orifice with the orifice of one plate being in co-axial
alignment with that of the other. The orifice of the uppermost or
first plate is of straight bore and serves as the melt shaping die
or extrusion orifice. The orifice of the second plate is larger in
diameter than that of the first and has a straight or a tapered
bore. The second plate, referred to as the "gas plate" is provided
with gas inlet ports and gas distribution means in the form of a
gap space, which defines an essentially enclosed chamber between
the opposing faces of the two plates.
In operation, a quantity of inert gas is supplied under pressure
through the inlet port of the gas plate and contacts the jet as it
emerges from the extrusion orifice in a direction perpendicular to
the jet path. The inert gas is then caused to change direction and
flow co-currently with the jet through the gas plate exit orifice
and thence, into a reactive atmosphere.
Although this improved orifice apparatus provides many advantages,
the most significant is that in its application filament
attenuation is achieved. Since the nature of essentially inviscid
materials precluded attenuation by the conventional practice of
drawing, it did not appear that it could be accomplished. With this
capability now provided, rates of productivity can be increased,
filament diameter can be controlled, and larger extrusion orifices,
which are easier to fabricate, may be utilized.
Since the advent of this ability to attenuate the jet during the
course of extrusion, filament productivity rates have been raised
to a level in the order of 1,300-1,400 feet per minute -- the
maximum attainable with known and existing equipment. Yet there has
been a desire for even higher rates of productivity in order that
over-all process economics may be further improved. To accomplish
this it must be made possible to achieve greater attenuation rates
than can be attained presently.
Accordingly, it is a principal object of this invention to provide
an improved orifice assembly by which greater attenuation rates
than previously attainable can be achieved when attenuating an
essentially inviscid molten jet prior to film stabilization.
It is a further object of the present invention to provide an
improved orifice assembly wherein the inert gas employed to effect
attenuation of an essentially inviscid molten jet can be applied at
a higher pressure to effect increased attenuation than has been
feasible heretofore.
It is a still further object of this invention to provide an
orifice assembly wherein there is a more effective utilization of
the energy contained in the inert attenuation gas than in previous
systems.
SUMMARY OF THE INVENTION
The above objects are achieved by the provision of an orifice
assembly comprised of two concentric plates stacked one above the
other. Each plate contains a centrally disposed orifice in co-axial
alignment one with the other. There is a gap space between the
opposing faces of the two plates which defines a substantially
enclosed chamber. Means are provided for supplying an inert gas
under pressure to this chamber with the gas exiting through the
orifice of the lower plate.
The first or upper-most plate contains the extrusion or filament
forming orifice. The second or "gas plate" contains a shaped
orifice having a nozzle configuration with a convergent entry
section, an intermediate throat section and a divergent exit
section. The included angle of divergence in the exit section is of
particular criticality being in the range of from about 4.degree.
to 12.degree., with from about 6.degree. to 8.degree. being
preferred for the higher attenuation rates.
It has been found that the specialized geometry of the gas plate
orifice is of paramount significance in the realization of the
results attainable by this invention.
BRIEF DESCRIPTION OF THE DRAWINGS
Other features and advantages of this invention will become
apparent in connection with the accompanying drawings in which:
FIG. 1 is a schematic vertical cross-section of a typical filament
extrusion apparatus employing an orifice assembly in accordance
with the present invention.
FIG. 2 is an enlarged, partial view of the orifice assembly of FIG.
1.
FIG. 3 is an enlarged partial view of the gas plate orifice in the
orifice assembly of FIG. 1.
DESCRIPTION
FIG. 1 depicts a crucible 10 enclosing a quantity of molten
essentially inviscid material 11. Functionally as part of the base
of crucible 10 is an orifice plate 12 having an extrusion orifice
13. Spaced beneath plate 12 is a gas plate 14 having a shaped
orifice 15 which is aligned substantially co-axial with orifice 13.
Plates 12 and 14 define an essentially enclosed chamber 16, which
may be referred to as the inert gas zone. Inert gas under pressure
is supplied to inert gas zone 16 through inert gas line 17. The
nature of the inert gas is not critical as long as the gas is inert
to the extruded materials, the orifice plate and other parts of the
extrusion apparatus. Helium and argon have been successfully
employed with helium being particularly suitable. Pedestal 18
supports the entire apparatus and also defines a cavity 19 for the
stabilization of the molten jet 20. A gas reactive with molten jet
20 is supplied to cavity 19 through reactive gas line 21. The
nature of the reactive gas is not critical so long as it is capable
of forming a film about the surface of molten jet 20. In many
instances oxidizing gases such as carbon monoxide and air have been
successfully employed.
In operation, a positive pressure is supplied to molten material 11
by an external means (not shown). The jet 20 is thus caused to
issue from the extrusion orifice 13 into chamber 16. Chamber 16 is
provided with a quantity of inert gas which is supplied under
pressure through inert gas line 17. The inert gas is constrained to
move laterally between orifice plate 12 and gas plate 14 and thus
contacts the emerging jet 20 in a direction initially normal to its
path. This flow is in a large measure self-distributing toward
symmetrical flow. The inert gas then flows co-currently with jet 20
through gas plate orifice 15 and into cavity 19.
Cavity 19 is provided with a quantity of gas reactive with jet 20
via reactive gas line 21. The reactive film-stabilizing gas
contacts jet 20 at the exit of shaped orifice 15 and is at a flow
rate sufficient to penetrate the shroud of inert gas which has been
caused to envelope the jet as it issues from gas plate orifice
15.
FIG. 2 illustrates the general geometrical relationship between
plates 12 and 14 together with their respective orifices. Although
the diameter of the throat section (most narrow section) of gas
plate orifice 15 may be larger than the exit diameter of extrusion
orifice 13, best results are obtained when it is of an equal or
lesser diameter than that of the exit of orifice 13. Particularly
good results may be obtained when the ratio of the exit diameter of
orifice 13 to the throat diameter of orifice 15 lies in the range
of from about 1.1 : 1.0 to 1.5 : 1.0. The length of orifice 15 is
generally maintained at from about five to 100 times greater than
the exit diameter of orifice 13.
The vertical distance of gap space 22 between orifice plate 12 and
gas plate 14 should be maintained at less than five times the
diameter of the throat in gas plate orifice 15. Arrows 23 and 24
illustrate the respective paths of the inert gas and the reactive
stabilization gas.
FIG. 3 illustrates gas plate 14 and its shaped orifice 15
schematically in an enlarged vertical section. The entry area or
convergent section 25 is rounded gently to reduce friction. The
extent of convergence is not critical, it being merely necessary
that the orifice walls converge in some degree at the entry. The
convergence terminates at throat section 26 from where the walls
diverge to form divergent exit section 27. The included angle of
divergence in this section should be between 4.degree. and
12.degree., with from 6.degree. to 8.degree. being of preference
for attenuation at the higher speeds. Although not critical for
operation, best results are achieved when divergent section 27 is
of greater length than convergent section 25, and particularly when
the length is from 10 to 20 times greater. Arrows 23 and 24
illustrate the respective flow paths of the inert and reactive
stabilization gases.
It has been found that when employing the orifice assembly of this
invention filament production rates can be increased in the order
of three fold or better over that obtainable by previous systems.
This is due for the most part to the unique orifice configuration
in the gas plate which permits much greater attenuations of the
extruded jet than was possible heretofore. Greater attenuations are
realized by virtue of the fact that the inert, attenuating gas can
be supplied to the gas plate orifice at substantially higher
pressure to give higher pressure drops through the orifice without
causing disruption of the molten jet stream. Moreover, the orifice
shape provides a more effective utilization of the energy contained
in the attenuation gas.
The materials which are utilized in fabricating the plates which
comprise the orifice assembly of this invention should be
essentially inert, each to the other, under the conditions employed
during extrusion. Moreover, the materials must be resistant to
thermal shock and have sufficient strength to withstand the
substantial mechanical stresses imposed by the extrusion process.
For example, in the extrusion of metals such as copper and ferrous
alloys, it may be preferable to use ceramic materials such as high
density alumina, beryllia, and zirconia. For high temperature
extrusion using ceramic charges, materials such as molybdenum and
graphite can be employed. For extrusion processes involving lower
temperatures, stainless steel assemblies have been found to perform
well.
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