U.S. patent number 3,763,385 [Application Number 05/061,148] was granted by the patent office on 1973-10-02 for modulator apparatus utilizing piezoelectric plates.
This patent grant is currently assigned to University of Illinois Foundation. Invention is credited to Judith A. Eakin, Victor G. Mossotti.
United States Patent |
3,763,385 |
Mossotti , et al. |
October 2, 1973 |
MODULATOR APPARATUS UTILIZING PIEZOELECTRIC PLATES
Abstract
A modulator and method for providing uniform increments of fluid
in a continuously pulsing manner, is disclosed. The modulator
employs the piezoelectric effect to impart peristaltic-like action
to a flexible, resilient channel causing fluid contained within
that channel to be pulsed from the channel, in the form of
substantially uniform increments or slugs. The modulator is
employed, for example, in combination with, and to feed fluid
sample to, an analytical instrument such as a flame
spectrophotometer.
Inventors: |
Mossotti; Victor G. (Urbana,
IL), Eakin; Judith A. (Urbana, IL) |
Assignee: |
University of Illinois
Foundation (Urbana, IL)
|
Family
ID: |
22033930 |
Appl.
No.: |
05/061,148 |
Filed: |
August 5, 1970 |
Current U.S.
Class: |
310/328; 356/315;
356/36 |
Current CPC
Class: |
F04B
17/003 (20130101); B05B 17/0607 (20130101); B05B
9/0426 (20130101); F04B 43/095 (20130101); B05B
9/042 (20130101) |
Current International
Class: |
B05B
17/04 (20060101); B05B 17/06 (20060101); B05B
9/04 (20060101); F04B 43/09 (20060101); F04B
43/00 (20060101); F04B 17/00 (20060101); H04r
017/00 () |
Field of
Search: |
;310/8,8.1,9,9.6,8.3,8.6
;356/36,85-87,181,187 ;417/322 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
herrmann: Fresenius' Zeitschrift Fuer Analytische Chemie, Band 212,
Heft 1, 1965 pages 1 and 12-14. .
Mavrodineanu: Spectrochimica Acta, Vol. 17, 1961 pages 1016, 1022
and 1023. .
Neu et al.: Messtechnik, July 1968, pages 154-159..
|
Primary Examiner: Schonberg; David
Assistant Examiner: Evans; F. L.
Claims
What is claimed is:
1. A modulator for providing uniform increments of fluid material,
said modulator comprising at least two piezoelectric plates, at
least one flexible, resilient tube means positioned so that an
intermediate portion of said tube means is interposed between said
plates, support means for positioning and holding said plates, said
plates being positioned and supported so that peristaltic-like
action can be imparted to said tube means when AC voltage is
applied to said plates.
2. The modulator of claim 1 wherein said flexible, resilient tube
means is a latex tube.
3. The modulator of claim 1 wherein the inlet portion of said tube
means is provided with a partial flow restriction.
4. The modulator of claim 1 wherein the outlet portion of said tube
means is provided with conduit means, said outlet portion being not
otherwise restricted.
5. The modulator of claim 1 comprising three piezoelectric plates
and two flexible, resilient, tubes.
6. A single channel modulator for providing, in a continuously
pulsing manner, increments of fluid material, said modulator
comprising a pair of piezoelectric plates, a flexible, resilient
tube positioned so that an intermediate portion of said tube is
interposed between said plates, means for applying an AC voltage to
said plates, said modulator being adapted to impart a
peristaltic-like action to said flexible, resilient tube when an AC
voltage is applied to said plates, whereby when fluid material
enters the inlet end of said tube, uniform increments of said fluid
material are provided at the outlet end of said tube.
Description
The present invention relates to a modulator for imparting certain
flow characteristics to fluid materials. In general, it concerns an
apparatus and a method for providing uniform increments of fluid
materials, to be used for example in feeding fluid samples to an
analytical instrument such as a flame spectrophotometer. More
particularly, it involves an apparatus and a method which employ
the piezoelectric effect to produce peristaltic action in a channel
containing a fluid material which peristaltic action propels or
injects, in a highly reproducible manner, the fluid material from
the channel in the form of uniform increments or slugs.
Analytical instruments suitable for use in detecting or determining
the amount of a component, i.e., analyte, present in a fluid sample
are well known. Such instruments include flame spectrophotometers,
plasma jets, gas chromatographs, and the like. These analytical
instruments all require some means or device for feeding the fluid
sample to be analyzed into the analyzing element of the analytical
instrument. For example, commercial flame spectrophotometers
generally employ atomizers to introduce a liquid sample to be
analyzed into a flame. Such atomizers are designed based upon the
important objective that the liquid sample be introduced into the
flame at a stable and reproducible rate. In practice, however,
changes or fluctuations in sample aspiration rate occur. Such
fluctuations in the rate at which sample is aspirated into the
flame, especially in view of the numerous other changes or
fluctuations which occur at other points in the analytical process,
adversely effect the reproducibility of the analytical measurement
which, of course, limits the quantitative accuracy of the
analytical instrument.
The present invention provides an apparatus as well as a method for
supplying or feeding a fluid sample to an analytical instrument
such as a flame spectrophotometer, in such a manner that the
sensitivity and detection limits of the analytical instrument are
markedly improved.
In general, the apparatus of the present invention is a modulator
which employs a piezoelectric sandwich comprising at least two
piezoelectric crystals or plates and a flexible, resilient channel
partially sandwiched between the plates.
Piezoelectric materials are well known and per se do not form the
basis of the present invention. Piezoelectric materials are
materials which when subjected to an applied voltage generate a
stress in the crystals of the material causing the material to
deform. For example, when such a material is subjected to an
alternating current (AC) voltage, it will oscillate with a
frequency and amplitude proportional to the applied AC voltage. The
present invention relies upon this piezoelectric effect to impart a
peristaltic-like action to a flexible resilient channel.
When a flexible, resilient channel, for example a latex tube, is
placed between two piezoelectric plates and an AC voltage applied
to the plates, the plates deform in a manner which imparts
wave-like contractions to the latex tube, thereby propelling and
continuously pulsing fluid material contained in the tube through
the tube and out of the tube. The fluid material leaving the tube
is in the form of uniform increments.
The present invention will be better understood by reference to the
accompanying drawings in which:
FIG. 1 is an end view in partial cross section of a single channel
modulator of the present invention attached to a "black box" which
may be, for example, an analytical instrument; and
FIG. 2 is a perspective view in partial cross section of a dual
channel modulator of the present invention attached to a dual
capillary total consumption burner suitable for use in flame
spectrophotometry; and
FIG. 3 is a graphic illustration comparing two spectrograms,
spectrogram A resulting from use of the present invention and
spectrogram B resulting from conventional practice.
Referring to FIG. 1, there is shown a single channel modulator 30
of the present invention threadably attached to a black box 31. The
modulator 30 is used to supply uniform increments of fluid material
to box 31.
Single channel modulator 30 comprises a conduit or channel 32, the
intermediate portion of which is positioned, i.e., sandwiched,
between a pair of piezoelectric plates, i.e., first piezoelectric
plate 34 and second piezoelectric plate 35. A frame or support 33
provides means for supporting, holding and positioning the
sandwiched channel. Channel 32 has an inlet 50, an outlet 51 and
consists of a flexible, resilient material, for example, a latex
tube having an inside diameter of one thirty-second of an inch and
a wall thickness of one sixty-fourth of an inch. The outlet 51 of
channel 32 is provided with a capillary 36 or other means suitable
for providing a passageway for fluid material leaving channel 32 to
enter box 31 through inlet port 42. Piezoelectric plates 34 and 35
are each provided, respectively, with a pair of electric contacts
37a-37b and 38a-38b. Electric contacts 37a-37b and 38a-38b are
attached to an AC power source (not shown). Any suitable AC power
source may be employed. One suitable AC power source which has been
found useful produces a 100 volt, 35 cycles per second signal.
A portion of channel 32 located between the inlet 50 and the
intermediate (sandwiched) portion is partially restricted by means
of flow restrictors 39 and 40. These flow restrictors offer
resistance to the flow of fluid material and thus when an
increment, or slug, or fluid is subjected to peristaltic-like
action in the intermediate (sandwiched) portion of channel 32, the
increment tends to exit from channel 32 into capillary 36, and then
into box 31 via inlet port 42. Support 33 is provided with means
such as positioning support screws 43, 44, 45 and 46 for holding
and positioning the sandwiched channel.
The operation of the single channel modulator shown in FIG. 1 will
now be described with reference to an application where black box
31 is an analytical instrument. In such an application the
modulator is used to supply a liquid or gas sample from a reservoir
(not shown) into an analytical instrument where the fluid sample is
analyzed to determine the quantity of a component, i.e., analyte,
contained in the sample. The single channel modulator feeds or
injects fluid sample into the analytical instrument in a
continuously pulsing manner. It also introduces the fluid sample
into the analytical instrument in reproducibly uniform increments.
Thus, the flow of fluid sample from the single channel modulator
into the analytical instrument may be characterized as a continuous
pulsing of uniform increments or slugs of sample. The advantages of
feeding fluid samples to certain analytical instruments in such a
manner will be exemplified and further described hereafter.
FIG. 2 shows another embodiment of the present invention wherein a
dual channel modulator 1 of the present invention is attached to a
dual capillary total consumption burner 2 which may be employed as
the burner in a flame spectrophotometer.
The dual channel modulator 1 comprises a three layer piezoelectric
sandwich 5 mounted in a frame or support 6. Piezoelectric sandwich
5 comprises first channel 3 and second channel 4 and piezoelectric
plates 7, 8 and 9. An intermediate portion of channel 4 is disposed
(sandwiched) between first piezoelectric plate 7 and second
piezoelectric plate 8 and channel 3 is similarly disposed between
second piezoelectric plate 8 and third peizoelectric plate 9.
Piezoelectric plates 7, 8 and 9 are provided with suitable electric
contacts (not shown) for applying an AC voltage to the plates. The
outlet ends of channels 3 and 4 are provided, respectively, with
first capillary 11 and second capillary 10. Piezoelectric sandwich
5 is positioned and secured within support 6 by means of
positioning support screws 12, 13, 14 and 15. Spacer members 16 and
17 prevent piezoelectric plates 7, 8 and 9 from making physical
contact with each other.
Dual capillary total consumption burner 2 is provided with inlet
ports 20 and 21 to permit support gases such as fuel and air or
oxygen to enter the burner.
As mentioned above, in the embodiment illustrated in FIG. 2, the
dual channel modulator of the present invention is used to feed a
fluid sample to the burner of a flame spectrophotometer. Flame
spectrophotometers are analytical instruments which are often
employed to determine the quantity of a metallic element present,
for example, as an impurity, in a liquid sample. One of the main
components of a flame spectrophotometer is a burner, such as the
dual capillary total consumption burner illustrated in FIG. 2. The
burner, when supplied with support gases should, under optimum
conditions, produce a steady flame. The sample to be analyzed is
prepared in a fluid state and introduced under conditions
controlled as nearly as possible into the flame causing a
characteristic radiation from the flame. The characteristic
radiation from the flame is collected, rendered monochromatic and
focused by an optical system (not shown) onto a photosensitive
detector (not shown). The intensity of the isolated radiation
striking the photosensitive detector is indicated, and generally
recorded, by a meter (not shown).
Operation of the dual channel modulator illustrated in FIG. 2 as it
is used to supply a fluid sample to the dual capillary total
consumption burner will now be described.
Before voltage is applied to the piezoelectric sandwich 5, both
channels 3 and 4 of the modulator 1 are slightly compressed by
means of positioning support screws 12, 13, 14 and 15.
Support gases are fed to the burner 2 through inlets 20 and 21 and
ignited at the outlet of the burner nozzle. Either channel 3 or
channel 4 is fed with a liquid containing solvent and the
component, i.e., analyte, of analytical interest and the other
channel is fed with pure solvent. The natural aspiration of the
burner causes these liquids to be drawn up into channels 3 and 4.
At this point, an alternating current voltage, for example a 100
volt, 35 cycles per second signal is applied to the piezoelectric
sandwich 5. During the first half cycle after the voltage is
applied, the three layer piezoelectric sandwich 5 mechanically
warps filling one channel, e.g., channel 3, with an additional
quantity of fluid while simultaneously forcing or injecting an
incremental volume of fluid out of the other channel, i.e., channel
4, into and through capillary tube 10 and into the flame. During
the second half cycle after voltage is applied, the
peristaltic-like action of channels 3 and 4 reverse. After a
stabilization cycle, the described action results in a modulation
of the analyte introduced into the flame while the net solvent
injection rate remains constant and unmodulated.
Some of the practical advantages of employing a modulator of the
present invention in flame spectrophotometry will now be
described.
The dual channel modulator and the dual capillary total consumption
burner illustrated in FIG. 2 were used, as described, in a flame
spectrophotometer. The fluid analyzed was a 95 percent ethanol
solution containing 2ppm of magnesium (Mg). The support gases for
the burner comprised premixed acetylene and nitrous oxide. The
results of the analysis were recorded as spectrograms and these
spectrograms were compared with spectrograms obtained from other
analyses wherein the same burner, support gases and conditions were
employed to analyze samples of the same fluid fed to the burner in
a conventional manner, viz, by aspiration through capillaries. FIG.
3 illustrates spectrograms representative of those obtained. As is
apparent from FIG. 3, the interpretation of spectrogram A
(resulting from use of the present invention) is vastly simplified
as compared to spectrogram B (resulting from conventional
practice). In addition, the analytical sensitivities and detection
limits of the instrument were markedly improved by use of the
present invention, as evidenced by the substantially improved
signal to noise ratio.
While the present invention has been described, in part, with
reference to analytical instruments, and more particularly in
reference to flame spectrophotometers, it is apparent that the
modulator of the present invention will have utility in other
applications where uniform increments of fluid materials need be
supplied in a continuously pulsing manner. For example, the
modulator may find utility in various fuel supply applications and
the like. Modifications of the invention apparent to those skilled
in the art are intended to be within the spirit and scope of the
invention as defined in the appended claims.
* * * * *