U.S. patent number 3,755,800 [Application Number 05/270,479] was granted by the patent office on 1973-08-28 for automatic fire alarm device.
This patent grant is currently assigned to Cerberus AG. Invention is credited to Gustav Purt, Peter Weber.
United States Patent |
3,755,800 |
Purt , et al. |
August 28, 1973 |
AUTOMATIC FIRE ALARM DEVICE
Abstract
Automatic fire alarm incorporating a device for detection of
combustion gases comprising a detection cell having a cathode, an
anode accessible to the combustion gases and an electrolyte
arranged between the anode and cathode. The anode catalytically
oxidizes the carbon monoxide contained in the combustion gases
while giving off electrons. An electrical circuit is coupled with
the anode and the cathode for current detection and alarm
indicating purposes.
Inventors: |
Purt; Gustav (Rapperswil,
CH), Weber; Peter (Stafa, CH) |
Assignee: |
Cerberus AG (Mannedorf,
CH)
|
Family
ID: |
4363225 |
Appl.
No.: |
05/270,479 |
Filed: |
July 10, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Jul 15, 1971 [CH] |
|
|
10437/71 |
|
Current U.S.
Class: |
340/633;
422/94 |
Current CPC
Class: |
G01N
27/4045 (20130101); G08B 17/117 (20130101) |
Current International
Class: |
G01N
27/49 (20060101); G08B 17/10 (20060101); G08B
17/117 (20060101); G08b 021/00 () |
Field of
Search: |
;340/237R
;23/254E,255E |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Caldwell; John W.
Assistant Examiner: Myer; Daniel
Claims
What is claimed is:
1. An automatic fire alarm comprising a device for the detection of
combustion gases, said device comprising a detection cell having a
cathode, an anode accessible to the combustion gases, and an
electrolyte arranged between the anode and cathode, said anode
being capable of catalytically oxidizing carbon monoxide contained
in combustion gases while giving off electrons, and an electrical
circuit for current detection and indicating an alarm electrically
coupled with said anode and said cathode.
2. The automatic fire alarm as defined in claim 1, wherein said
electrolyte possesses basic properties and said cathode is formed
of material capable of delivering hydroxyl ions.
3. The automatic fire alarm as defined in claim 1, wherein the
electrolyte possesses acidic properties and said cathode is formed
of a material capable of taking-up hydrogen ions.
4. The automatic fire alarm as defined in claim 1, wherein the
cathode possesses a polymeric phtalocyanine of a transition
metal.
5. The automatic fire alarm as defined in claim 4, wherein said
cathode contains carbon black coated with a phtalocyanine of the
iron group.
6. The automatic fire alarm as defined in claim 1, wherein the
anode contains a catalyst selected from a metal of the platinum
group.
7. The automatic fire alarm as defined in claim 6, wherein the
anode contains as the catalyst palladium.
8. The automatic fire alarm as defined in claim 6, wherein the
anode contains nickel powder coated with a metal of the platinum
group.
9. The automatic fire alarm as defined in claim 8, wherein the
nickel powder is applied to a gas permeable membrane.
10. The automatic fire alarm as defined in claim 2, wherein the
anode contains an ion exchanger.
11. The automatic fire alarm as defined in claim 10, wherein the
ion exchanger comprises a copolymer of styrene divinybenzyl with
quaternary ammonium groups.
12. The automatic fire alarm as defined in claim 2, wherein the
electrolyte contains potassium bicarbonate.
13. The automatic fire alarm as defined in claim 2, wherein the
electrolyte contains cesium carbonate.
14. The automatic fire alarm as defined in claim 3, wherein the
electrolyte contains phosphoric acid.
15. The automatic fire alarm as defined in claim 1, further
including a porous layer arranged between the anode and cathode and
imbued with the electrolyte.
16. The automatic fire alarm as defined in claim 1, wherein the
electrolyte has added thereto an evaporation-retarding
substance.
17. The automatic fire alarm as defined in claim 16, wherein the
evaporation-retarding substance is glycerine.
18. The automatic fire alarm as defined in claim 1, wherein said
anode and cathode possesses a substantially plate-shaped
configuration and are arranged at a spacing from one another which
is less than 5 millimeters.
19. The automatic fire alarm as defined in claim 1, wherein both
the anode and cathode are designed to be accessible to the ambient
air.
20. The automatic fire alarm as defined in claim 19, wherein said
cathode is formed of very finely divided silver applied to an
oxygen pervious membrane.
21. The automatic fire alarm as defined in claim 1, wherein said
anode possesses at the side thereof confronting the electrolyte a
hydrophilic substance and at the outside a hydrophobic substance.
Description
BACKGROUND OF THE INVENTION
The present invention relates to a new and improved construction of
automatic fire alarm incorporating a device for the detection of
combustion gases.
Automatic fire alarms either resort to the use of the physical
changes arising during a combustion process, for instance the
increase in temperature or the radiation transmitted by flames for
the purpose of indicating an alarm, or attempt to detect the
products of combustion resulting during a fire. Hence, it is known
in this particular field of technology to detect the smoke which
develops during combustion processes by optical absorption- or
stray light fire alarm devices or to detect the combustion aerosols
by means of ionization fire alarms. Other state-of-the-art fire
alarm devices resort to the use of the changed conductivity of the
combustion gases (formation of ions) and the increased water vapor
content for fire detection purposes.
However, the aforementioned equipment is more or less subject to
disturbances that can be triggered by occurrences which have
nothing to do with a combustion process, for instance in the case
of optical fire alarms by disturbing light effects, in the case of
ionization fire alarms by dust, in the case of conductivity
detectors by the ionization of air or for other causes. Due to such
deception of the relevant fire detection devices in the
aforementioned manner false alarms arise with such prior art
equipment.
It has already been proposed to employ for fire detection purposes
the carbon monoxide (CO) which is produced during any undesired or
intentional combustion process. Such type equipment would operate
in a particular foolproof manner since carbon monoxide occurs
practically exclusively as a result of a combustion process, and
therefore, constitutes an infallible indicator for a fire.
Moreover, a warning concerning the presence of carbon monoxide is
extremely desirable owing to the fact that it is poisonous.
Heretofore known CO-detectors generally function on the
spectral-photometric principle or by means of a chemical reaction
and the detection of the resultant products. However, these
procedures are relatively cumbersome and the equipment operated in
accordance therewith is not useable over longer periods of time, as
such is required for automatic fire alarms. Additionally, such type
equipment is relatively complicated, expensive and requires
continuous maintenance.
SUMMARY OF THE INVENTION
Hence from what has been explained above it should be apparent that
this particular field of technology is still in need of automatic
fire alarm devices which are not associated with the aforementioned
drawbacks and limitations of the state-of-the-art proposals.
Therefore, it is a primary object of the present invention to
provide a new and improved construction of automatic fire alarm
device which affectively and reliably fulfills the existing need in
the art and overcomes the aforementioned drawbacks and limitations
of the heretofore proposed fire detection devices.
Another and more specific object of the present invention aims at
the provision of an automatic fire alarm device which overcomes the
aforementioned drawbacks and functions with increased sensitivity
and in an unmistakable operationally reliable manner over longer
periods of time.
Yet a further significant object of the present invention relates
to an improved automatic fire alarm which is relatively simple in
construction, economical to manufacture, extremely reliable in
operation, and requires minimum servicing and mainenance.
Now in order to implement these and still further objects of the
invention, which will become more readily apparent as the
description proceeds, the inventive apparatus for the detection of
combustion gases embodies an electrolytic cell having a cathode, an
anode accessible to the combustion gases and an electrolyte
arranged between the anode and cathode. The anode is capable of
catalytically oxidizing the carbon monoxide contained in the
combustion gases while giving off electrons. There is also provided
an electrical circuit connected with the anode and cathode for
current detection and alarm indicating purposes.
The invention resorts to the use of the well known experience that
it is possible by means of so-called fuel cells to directly convert
combustible liquids or gases, that is without interposing thermal
engines, into electrical energy. In such type fuel cells generally
organic substances, such as formal, formic acid or hydrazine are
catalytically oxidized, for instance at a platinum anode. Between
the anode and the cathode there thus prevails a potential
difference which can be employed for generating energy. It has
already been proposed to inversely employ the energy supply of such
fuel cells for the analysis of the content of combustible material
in liquids and gases. However, the known fuel cells are completely
unsuitable as fire detectors owing to their complicated
construction and low selective sensitivity to carbon monoxide.
Hence, in order to develop the invention it was therefore necessary
to find new materials for the individual elements and to arrive at
and select an arrangement and construction designed such that the
apparatus possessed optimum sensitivity to carbon monoxide with as
little as possible expenditure in equipment and with as great as
possible equipment life.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention will be better understood and objects other than
those set forth above, will become apparent when consideration is
given to the following detailed description above. Such description
makes reference to annexed drawings wherein:
FIG. 1 schematically illustrates the functional principles of a
fire alarm device employing a basic electrolyte;
FIG. 2 schematically illustrates the functional principles of a
fire alarm device employing an acidic electrolyte; and
FIG. 3 illustrates in sectional view the construction of the
detection device of a fire alarm designed according to the
teachings of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
Considering now the drawing in the embodiment of exemplary
apparatus depicted in FIG. 1 the ambient air has access to an anode
1. At the cathode 2 reactive oxygen ions are formed from the oxygen
molecules of the air upon delivery of electrons from the electrical
circuit 3. These reactive oxygen ions together with the water of
the basic electrolyte 4 are converted into hydroxyl ions. Hence,
the cathode 2 serves as hydroxyl-ion donor. These hydroxyl ions
migrate to the anode 1 and at that location react in the presence
of a catalyst, for instance palladium, with the carbon monoxide
contained in the air into carbonic acid and water, wherein
electrons are released which are again supplied to the electrical
current circuit 3. As long as carbon monoxide is contained in the
air a current flow will be maintained in this current circuit 3,
and this current flow can be ascertained by means of a suitable
detector 5 and employed for triggering an alarm signal in known
manner.
Now, with the equipment depicted in FIG. 2 employing an acidic, in
other words an electrolyte containing hydrogen ions, the carbon
monoxide contained in the air catalytically reacts at the anode 1
with the water contained in the electrolyte to form carbon dioxide
and hydrogen ions while giving off electrons which can flow in the
electrical current circuit 3 to the cathode 2. The hydrogen ions
are absorbed or taken up by the acidic electrolyte 4 and react at
the cathode 2 with the oxygen which has diffused-in to form water
while taking-up electrons from the current circuit 3. The
electrolyte may contain in this instance phosphoric acid.
Now in FIG. 3 there is illustrated in sectional view a practical
exemplary embodiment of the invention. Here the automatic fire
alarm or fire detection device comprises a plastic housing H formed
of two housing portions or components 6 and 7, the housing portion
7 being provided with an opening or otherwise suitably designed so
as to have one side thereof accessible to the surrounding air. At
this open side of the housing there is arranged a gas pervious
membrane or diaphragm 8, for instance a filter formed of pressed
glass wool or glass frit or the like.
At the outside of this gas permeable membrane 8 there is provided a
layer 9 formed of nickel powder coated with a noble or precious
metal. Particularly suitable for this purpose are metals of the
platinum group. In particular palladium has been found to possess
advantageous capabilities for the catalytic oxidation of the carbon
monoxide arriving at the diaphragm or membrane 8. The metal powder
is mixed with an ion exchanger and if necessary with an additional
binder, for instance polystyrene. Basically ion exchangers of the
most different composition have been found to provide favorable
results. Particularly suitable as the ion exchanger is the known
ion exchanger available on the market under the designation anion
exchanger III, which contains a copolymer of styrene divinylbenzoyl
with quaternary ammonium groups. However, the invention is in no
way to be considered limited to such type ion exchanger since other
ion exhangers have been likewise found to be suitable.
At the floor of the housing portion 6 there is located an electrode
12 which is coated at the inside with a layer of carbon, for
instance carbon black, at which there is again applied a substance
11 which gives off hydroxyl ions. Particularly suitable for this
purpose is a polymeric phtalocyanine of the transition metals, for
instance the iron group (Fe, Ni, Co), yet also of Cu, Ag, Au and
Hg.
Now, between the plate-shaped constructed electrodes there is
located a thin felt layer 10 imbued with an electrolyte, for
instance a potassium bicarbonate solution or cesium carbonate
solution. Instead of using felt it would be possible to employ a
different carrier material which can absorb the electrolyte, yet
only slightly hinders the diffusion, as such is known for instance
from electrolytic dry elements. The layer thickness amounts to only
a few millimeters, as a rule less than 5 millimeters. With such
substantially plate-shaped electrode arrangement and such slight
electrode spacing, i.e., less than 5 millimeters, the internal
resistance of the electrolytic cell is relatively small and the
diffusion within the electrolyte is sufficiently rapid so that the
current yield is sufficiently large so as to be already able to
detect the slightest quantities of combustion gas. The voltage of
the element in this case as a general rule is below 0.1 volts.
In order to reduce rate of evaporation or vaporization of the
electrolyte there can be added thereto a certain quantity of
gylcerine or a similar substance. In this way the life and useful
time of the fire alarm can be considerably improved.
A further possibility of reducing evaporation of the electrolyte
resides in designing the anode such that the outer side or face
contains a hydrophobic binder such as indicated as 9a which
prevents the escape of the electrolyte, whereas the inside or inner
face 9b contains a hydrophylic binder which ensures for the
requisite wetting or imbuing.
The sensitivity can be further increased in that the rear wall of
the housing portion 6 bearing against the cathode 12 is designed to
be pervious to air. In this way the oxygen of the air can arrive
directly at the cathode 12 without having to diffuse through the
electrolyte, for instance the cathode can be formed of very finely
divided silver, so-called Raney silver, which is applied to an
oxygen pervious membrane. At the anode there is connected a current
conductor 13 and at the cathode a current conductor 14 in order to
be able to couple the fire alarm device with the electrical circuit
3 serving for current detection and alarm sounding purposes. The
invention is not limited to any specific construction of the
current detector and alarm sounding circuitry since many different
constructional forms suitable for this purpose are wellknown in the
art. In one very simple manifestation this electric circuit 3 can
embody a relay 20 electrically coupled with the current conductors
13 and 14 as shown in FIG. 3, the relay 20 cooperating with a work
contact 22, so that upon current flow through the relay 20 the work
contact 22 is closed and a suitable alarm 24 is activated since it
is now placed in circuit with a suitable power supply, such as
battery 26.
It has been found that by observing the described measures it is
possible to produce a fire alarm which is capable of already
positively detecting a carbon monoxide content below 100 ppm and
which will not be normally excited into a state of producing a
false alarm by contaminants in the air.
While there is shown and described present preferred embodiments of
the invention, it is to be distinctly understood that the invention
is not limited thereto but may be otherwise variously embodied and
practised within the scope of the following claims.
ACCORDINGLY,
* * * * *