U.S. patent number 3,730,251 [Application Number 05/155,263] was granted by the patent office on 1973-05-01 for method of continuous casting.
This patent grant is currently assigned to General Motors Corporation. Invention is credited to Fred J. Webbere, Robert G. Williams.
United States Patent |
3,730,251 |
Webbere , et al. |
May 1, 1973 |
**Please see images for:
( Certificate of Correction ) ** |
METHOD OF CONTINUOUS CASTING
Abstract
Method involves continuously but incrementally passing molten
metal directly from a holding vessel progressively through an
open-ended mold containing three consecutive zones. The first zone
immediately adjacent the holding vessel conveys the molten metal to
the second zone without significant solidification due to its low
heat transfer capacity. A thin skin of metal forms progressively in
the second zone due to its relatively high heat transfer capacity.
This thin skin is then transferred as a segment into the third zone
in which the molten metal solidifies sufficiently to form a
self-sustaining rod.
Inventors: |
Webbere; Fred J. (Orchard Lake,
MI), Williams; Robert G. (Birmingham, MI) |
Assignee: |
General Motors Corporation
(Detroit, MI)
|
Family
ID: |
22554714 |
Appl.
No.: |
05/155,263 |
Filed: |
June 21, 1971 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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827673 |
May 26, 1969 |
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Current U.S.
Class: |
164/490; 164/138;
164/485; 164/418 |
Current CPC
Class: |
B22D
11/045 (20130101); B22D 11/047 (20130101) |
Current International
Class: |
B22D
11/047 (20060101); B22D 11/045 (20060101); B22d
011/02 () |
Field of
Search: |
;164/82,89,273,281,282,283 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Overholser; J. Spencer
Assistant Examiner: Roethel; John E.
Parent Case Text
This application is a continuation-in-part of the patent
application Ser. No. 827,673 (now abandoned) filed on May 26, 1969
and assigned to the assignee of the present application.
Claims
What is claimed is:
1. A method of continuously casting, horizontally, a continuous rod
comprising the steps of
a. continuously introducing molten metal taken from the group
consisting of ferrous metals, nickel based metals or cobalt based
metals into the inlet end of the cavity of a stationary open-ended
horizontally disposed continuous casting mold;
b. said mold including a first zone adjacent said inlet end having
a relatively low heat transfer capacity, a non-lubricated second
zone immediately adjacent said first zone having a relatively high
heat transfer capacity, and a third zone adjacent said second zone
terminating in an open outlet end;
c. advancing said molten metal into said first zone, the heat
transfer characteristics of said first zone being operative to
substantially prevent any metal solidification therein;
d. advancing said molten metal into said second zone, the high heat
transfer characteristics of said second zone being operative to
cause solidification of a thin layer of said metal at first
immediately at the junction of said first and second zone and then
progressively in the direction of said third zone whereby a
solidified thin layer of said molten metal is formed coextensively
of said second zone, the portion of said first zone immediately
adjacent said second zone being formed of a material which is
substantially inert to said molten metal and is non-adherent to
said thin layer; and
e. advancing said rod continuously but in fixed predetermined
increments at fixed predetermined time intervals, said increments
being equal to the length of said second zone whereby said thin
layer of said solidified metal formed in said second zone is
advanced progressively into said third zone and the molten metal
advancing from said first zone follows the advance of said thin
layer to progressively fill said second zone immediately behind
said advancing thin layer and to thereby progressively form a new
thin solidified layer coextensively of said second zone cavity
surface, said intervals being of sufficient duration to permit the
forward axial end of said newly formed thin layer to weld to the
solidified metal in said third zone.
2. A method of continuously casting, horizontally, a continuous rod
comprising the steps of
a. continuously introducing molten metal taken from the group
consisting of ferrous metals, nickel based metals or cobalt based
metals into the inlet end of the cavity of a stationary open-ended
horizontally disposed continuous casting mold;
b. said mold including a first zone adjacent said inlet end having
a relatively low heat transfer capacity, a non-lubricated second
zone immediately adjacent said first zone having a relatively high
heat transfer capacity, the portion of said first zone immediately
adjacent said second zone being formed of boron nitride, and a
third zone adjacent said second zone terminating in an open outlet
end;
c. advancing said molten metal into said first zone, the heat
transfer characteristics of said first zone being operative to
substantially prevent any metal solidification therein;
d. advancing said molten metal into said second zone, the high heat
transfer characteristics of said second zone being operative to
cause solidification of a thin layer of said metal at first
immediately at the junction of said first and second zone and then
progressively in the direction of said third zone whereby a thin
layer of said molten metal is formed coextensively of said second
zone; and
e. advancing said rod continuously but in fixed predetermined
increments at fixed predetermined time intervals, said increments
being equal to the length of said second zone whereby said thin
layer of said solidified metal formed in said second zone is
advanced progressively into said third zone and the molten metal
advancing from said first zone follows the advance of said thin
layer to progressively fill said second zone immediately behind
said advancing thin layer and to thereby progressively form a new
thin solidified layer coextensively of said second zone cavity
surface, said intervals being of sufficient duration to permit the
forward axial end of said newly formed thin layer to weld to the
solidified metal in said third zone.
3. A method of continuously casting horizontally, a continuous rod
comprising the steps of
a. continuously introducing molten metal taken from the group
consisting of ferrous metals, nickel based metals or cobalt based
metals into the inlet end of the cavity of a stationary open-ended
horizontally disposed continuous casting mold;
b. said mold including a first zone adjacent said inlet end having
a relatively low heat transfer capacity, a non-lubricated second
zone immediately adjacent said first zone having a relatively high
heat transfer capacity, and a third zone adjacent said second zone
terminating in an open outlet end;
c. advancing said molten metal into said first zone, the heat
transfer characteristics of said first zone being operative to
substantially prevent any metal solidification therein;
d. advancing said molten metal into said second zone, the high heat
transfer characteristics of said second zone being operative to
cause solidification of a thin layer of said metal at first
immediately at the junction of said first and second zone and then
progressively in the direction of said third zone whereby a thin
layer of said molten metal is formed coextensively of said second
zone, the portion of said first zone immediately adjacent said
second zone being formed of a material which is substantially inert
to said molten metal and is non-adherent to said thin layer;
and
e. advancing said rod continuously but in fixed increments of 0.1
to 1.5 times the diameter of the rod being cast at fixed
predetermined time intervals, said increments being equal to the
length of said second zone whereby said thin layer of said
solidified metal formed in said second zone is advanced
progressively into said third zone and the molten metal advancing
from said first zone follows the advance of said thin layer to
progressively fill said second zone immediately behind said
advancing thin layer and to thereby progressively form a new thin
solidified layer coextensively of said second zone cavity surface,
said intervals being of sufficient duration to permit the forward
axial end of said newly formed thin layer to weld to the solidified
metal in said third zone.
4. A method of continuously casting, horizontally, a continuous rod
comprising the steps of
a. continuously introducing molten metal taken from the group
consisting of ferrous metals, nickel based metals or cobalt based
metals into the inlet end of the cavity of a stationary open-ended
horizontally disposed continuous casting mold;
b. said mold including a first zone adjacent said inlet end having
a relatively low heat transfer capacity, a non-lubricated second
zone immediately adjacent said first zone having a relatively high
heat transfer capacity, and a third zone adjacent said second zone
terminating in an open outlet end;
c. advancing said molten metal into said first zone, the heat
transfer characteristics of said first zone being operative to
substantially prevent any metal solidification therein;
d. advancing said molten metal into said second zone, the high heat
transfer characteristics of said second zone being operative to
cause solidification of a thin layer of said metal at first
immediately at the junction of said first and second zone and then
progressively in the direction of said third zone whereby a thin
layer of said molten metal is formed coextensively of said second
zone, the portion of said first zone immediately adjacent said
second zone being formed of a material which is substantially inert
to said molten metal and is non-adherent to said thin layer;
and
e. advancing said rod continuously but in fixed increments of 0.1
to 1.5 times the diameter of the rod being cast at fixed cycle
timely intervals of about 0.15 to 1.10 seconds, said increments
being equal to the length of said second zone whereby said thin
layer of said solidified metal formed in said second zone is
advanced progressively into said third zone and the molten metal
advancing from said first zone follows the advance of said thin
layer to progressively fill said second zone immediately behind
said advancing thin layer and to thereby progressively form a new
thin solidified layer coextensively of said second zone cavity
surface, said rod being at rest for a time of 33 to 65 percent of
said cycle time interval to permit the forward axial end of said
newly formed thin layer to weld to the solidified metal in said
third zone.
5. The method of claim 4 wherein said metal is a ferrous metal
containing less than 2 percent by weight carbon.
6. A method of continuously casting, horizontally, a continuous rod
comprising the steps of
a. continuously introducing molten metal taken from the group
consisting of ferrous metals having a carbon content up to about 2
percent by weight, nickel based alloys or cobalt based alloys into
the inlet end of the cavity of a stationary open-ended horizontally
disposed continuous casting mold;
b. said mold including a first zone adjacent said inlet end having
a relatively low heat transfer capacity, a non-lubricated,
non-graphitic second zone immediately adjacent said first zone
having a relatively high heat transfer capacity, and a third zone
adjacent said second zone terminating in an outlet end, the mold in
said third zone having a progressively decreasing internal diameter
for at least a portion thereof and having at least a surface layer
formed of graphite;
c. advancing said molten metal into said first zone, the heat
transfer characteristics of said first zone being operative to
substantially prevent any metal solidification therein;
d. advancing said molten metal into said second zone, the heat
transfer characteristics of said second zone being operative to
cause the solidification of a thin layer of said metal initially
immediately at the junction of said first and second zones and then
progressively in the direction of said third zone whereby a thin
solidified layer of said molten metal is formed coextensively of
said second zone, the portion of said first zone immediately
adjacent said second zone being formed of a material which is
substantially inert to said molten metal and is non-adherent to
said thin layer; and
e. advancing said rod continuously but in fixed predetermined
increments at fixed predetermined time intervals, said increments
being equal to the length of said second zone whereby said thin
layer of said solidified metal formed in said second zone is
incrementally advanced into said third zone and the molten metal
advancing from said first zone follows the advance of said thin
layer to progressively fill said second zone immediately behind
said advancing thin layer and to thereby progressively form a new
thin solidified layer coextensively of said second zone cavity
surface, said intervals being of sufficient duration to permit the
said forward end of said newly formed thin layer to weld to said
solidified metal in said third zone, said solidifying and cooling
metal in said third zone gradually shrinking in diameter as the
metal solidifies and cools and the said progressively decreasing
diameter of said mold in said third zone being adapted to snugly
engage the solidifying rod as it passes through said third zone to
maintain efficient heat transmission and roundness of the rod.
Description
This invention relates to the continuous casting of round bars or
ingots in a horizontally disposed mold, and more particularly to
the continuous casting of round bars formed of relatively high
melting point metals which are unsaturated in carbon, such as
steel.
In the common practice of the continuous casting of steel, the mold
apparatus is usually of the vertical type including a vertically
positioned open-ended mold, a tundish positioned above the mold and
spaced therefrom, and a teeming ladle positioned above the tundish.
The molten metal is teemed by gravity into the tundish and thence
directly into the mold. This arrangement offers the advantage that
no molten metal is held in continuous contact with the mold wall
inasmuch as the skin of solidified metal forms progressively at the
metal mold interface and the rate of propagation of this skin is at
least equal to the withdrawal rate of the casting from the bottom
of the mold. This requires, of course, a mold material having good
thermal conductivity and adequate cooling. In most current
practice, the mold wall is made of a water cooled copper.
A further characteristic of this vertical arrangement is that the
surface of the metal being poured into the mold is exposed so that
a lubricating medium can be continuously added during the casting
operation. Various lubricants such as rapeseed oil, mineral oil,
and powdered graphite have been successfully used. Because a convex
meniscus is developed at the point of contact of the molten metal
with the mold wall, a lubricant may readily be distributed between
the solidifying skin and the mold wall as the metal passes through
the mold.
The vertical casting arrangement described above has achieved wide
industrial application in casting steel billets and slabs of
approximately eight square inches in cross-section and larger.
However, for casting billets having a diameter of three inches or
less, the teeming action becomes more difficult to control and the
linear rate of extraction becomes high. In consequence, the surface
quality and internal soundness of the casting is seriously
impaired. As a result, under the present state of technology, the
vertical casting method has not been successfully used commercially
to cast steel bars two inches or less in diameter.
Vertical casting is well adapted to casting relatively large slabs
and billets on a high volume continuous basis but requires very
substantial vertical plant space which well suits the operation of
metal producers such as steel mills. However, in view of persistent
efforts by steel users to achieve greater efficiency and economy by
the utilization of scrap metals resulting from their operation,
there is a great need for small compact casting units for
converting scrap steel into relatively small diameter useable rods
of about two inches or less in diameter, which may be conveniently
installed in existing plant facilities.
It is an object of this invention to provide a method for
continuously casting by compact horizontal means ingots formed of
relatively high temperature metals such as ferrous metals, nickel
base alloys and cobalt base alloys having melting temperatures in
excess of about 2,200.degree. F. It is a further object of this
invention to provide a method for continuously casting steel ingots
including ingots having a diameter of three inches or less which
are not saturated in carbon, as for example, low carbon steel.
These and other objects are accomplished by the provision of a
horizontally disposed open-ended mold associated with a molten
metal holding vessel or furnace, which mold includes means
providing a low heat transfer first zone immediately adjacent the
holding vessel which is effective to contain and convey the molten
metal therethrough without appreciable solidification and which is
substantially chemically inert to the molten metal, means providing
a relatively high heat transfer second zone adjacent the first zone
which effects the initial solidification in the form of a thin skin
of solidified metal progressively and coextensively, first at the
interface of the first and second zones and progressively to the
end of the second zone, and means providing a third zone adjacent
the second zone wherein the molten metal is further solidified to
form a self-sustaining rod which may be progressively withdrawn
from the mold by mechanical means. The solidified rod is
mechanically pulled from the mold continuously but intermittently
in predetermined increments of length or segments and with
predetermined time intervals between the increments of movement of
the rod. Each increment corresponds in length to the aforesaid
second or initial solidification zone so that with each incremental
pull of the rod the thin solidified skin layer or segment formed in
the second zone is advanced into the third zone thereby exposing
the second zone to the advance of the molten metal from the first
zone and the progressive solidification of a new skin layer or
segment is formed in the second zone. The time interval or dwell
time between the pulling intervals is sufficient to permit the
forward end of the newly formed skin layer in the second zone to
weld to the rod in the third zone, so that when the rod is again
pulled, it will carry with it the newly formed segment into the
third zone in a continuous rod solidification process. The method
may be used to cast ingots of various diameters including ingots up
to 5 inches or more.
Suitable apparatus for practicing the method of this invention is
disclosed and claimed in the copending patent application Ser. No.
827,747 filed May 26, 1969, now abandoned.
Other objects and advantages of the invention will be apparent from
the following description, reference being had to the drawings in
which:
FIG. 1 is a cross-sectional view of a horizontal continuous casting
apparatus;
FIG. 2 is an enlarged view of a portion of the mold shown in FIG.
1;
FIGS. 3 - 5 are fragmentary cross-sectional views of the mold at
various stages of the casting process; and
FIG. 6 is a schematic view of the mold showing variable internal
diameter dimensions.
Referring now to FIG. 1 of the drawings, the molding apparatus of
this invention consists generally of a molten metal reservoir 10
shown as a fragment thereof and a horizontally disposed open-ended
mold 12 mounted adjacent an opening 14 near the base of the
reservoir. The reservoir is of conventional construction including
an outer metal shell (not shown) having a lining 16 of a suitable
refractory material for containing molten metal such as steel. The
opening or channel 14 in the reservoir is formed in a frustoconical
refractory body 18 cemented to the lining 16. The refractory
reservoir may include heating means such as an induction heating
coil or resistance heating element for maintaining the metal at a
desired temperature.
Referring to FIG. 2, the mold 12 consists of three distinctly
different portions with different heat transfer characteristics.
The first portion immediately adjacent the reservoir includes a
nozzle portion 20 preferably formed of boron nitride having
relatively low heat transfer characteristics such that it will
contain the molten metal therein without any appreciable
solidification. The second portion 22 is positioned immediately
adjacent the nozzle 20 and is formed of a material having
relatively high heat transfer characteristics as, for example, a
beryllium-copper alloy. The third portion 24 is disposed
immediately adjacent the second portion 22 and is preferably
provided with a graphite liner 26. The third portion preferably has
somewhat lower heat transfer characteristics than the second
portion 22 for reasons which will appear hereinafter.
An important feature of the mold structure resides in the shape of
the nozzle 20 including the annular radially disposed shoulder 30
and the frustoconical axial surface 32 which mates with a
corresponding frustoconical surface 42 on the second mold portion
22. Preferably, the angle of the frustoconical surfaces with the
longitudinal axis of the mold is about five degrees for reasons to
be hereinafter explained. The mold portion 22 receives a portion of
the nozzle 20 with the frustoconical surface providing a snug fit
and with the shoulder 30 engaging a radial surface 33 of the mold
portion 22 to accurately locate the nozzle 20 with respect to the
mold portion 22. An annular refractory ring 34 is in engagement
with the nozzle 20 and is securely locked in place by a flanged
ring 36 bolted to the mold housing 35. The aperture 37 through the
ring 34 is preferably somewhat smaller than the opening 21 through
the nozzle. The ring 34 is preferably made of zirconia because of
the expensive nature of boron nitride. However, if desired, the
nozzle 20 and the ring 34 may be both formed of boron nitride.
The second mold portion 22 as well as the third mold portion 24 are
both provided with coolant passages 38. The second mold portion 22
is preferably formed of a beryllium-copper alloy because of its
high heat transmission characteristics. As will be explained
hereinafter, the molten metal contacts the surfaces of the second
mold portion 22 only in a transient manner.
After the process of this invention has been started and is in
continuous operation as hereinafter described, it is characterized
basically by the molten metal passing from the reservoir 10 through
three successive zones in the mold 12. The molten metal is conveyed
from the reservoir 10 through the first zone without exposure to
air whereby the buildup of oxide deposits in the region of zone one
is substantially prevented. No significant solidification occurs
due to a sufficiently low heat transfer capacity of the first zone.
As the metal flows into the second zone, a thin skin layer of
solidified metal is progressively formed along its length due to
the high heat transfer capacity of the second zone portion of the
mold. This skin layer is then advanced as a segment or increment
into the third zone of the mold wherein the molten metal is further
solidified to form a self-sustaining rod which is mechanically
pulled out of the mold by suitable means such as the rollers 31 of
FIG. 3. As the aforesaid skin layer is advanced from the second
zone to the third zone, a second skin layer is formed in the second
zone, which subsequently welds itself to the rod being solidified
in the third zone. This second skin layer is advanced into the
third zone as the rod is pulled incrementally whereby a continuous
rod is formed in a continuous but incremental process.
The following detailed explanation will make the nature of the
process more clear. The reservoir 10 is provided with a suitable
quantity of molten metal such as steel so that its level extends
substantially above the mold 12. The molten metal advances due to
gravity into the mold through the ring 34 and the boron nitride
nozzle 20 which constitutes the aforementioned first zone. Since
boron nitride is a material of relatively low heat conductivity,
and is not provided with any cooling means, the molten metal does
not significantly solidify therein. The use of boron nitride for
this purpose is also advantageous because the material has a high
heat shock resistance; it is not wetted by the molten metal and it
is relatively inert to the molten metal. Other materials with
similar desirable properties may be used instead of boron
nitride.
As soon as the molten metal enters the second zone, an initial
circumferential annulus solidifies against the mold surface portion
22 at the interface 25 of the nozzle element 20 and the mold
portion 22 as is shown in FIG. 2. This occurs because the mold
portion 22 is formed of a material of relatively high heat
conductivity and is cooled by means of suitable coolant, such as
water, circulating in the coolant passages 38 to provide a high
heat transfer capacity whereby a film or skin of metal 23, FIG. 3,
solidifies on the surface of the mold 22 the instant contact is
made. It is essential in the casting process of this invention that
solidification begin immediately at the interface 25 of the nozzle
20 and the mold portion 22. As the molten metal advances into the
second zone, a solidified skin layer 23 forms progressively on the
surfaces of the mold portion 22 in the downstream direction. This
progressive formation of the skin layer 23 occurs entirely within
the mold 22 portion and coextensively with zone one.
The skin layer segment 23 is then advanced as a segment into the
third zone of the mold wherein further solidification takes place
to form the self-sustaining rod.
As the skin layer 23 begins to advance into the third zone, it must
first release from the nozzle 20 at the interface 25 as shown in
FIG. 4 to form a slight space 27 between the skin 23 and the nozzle
shown in greatly exaggerated dimensions. This space is immediately
filled with molten metal flowing from the first zone to initiate
the formation of a new skin layer at the interface 25 of the nozzle
and the mold portion 22 and to closely follow the advancing skin
layer 23 and to progressively form the new skin layer 29 as shown
in FIG. 5. After the layer 23 has reached its full increment of
movement, it is permitted to remain stationary for a time
sufficient to permit the new layer 29 to weld to the layer 23 as
shown at 27 of FIG. 5. It is essential to the successful operation
of the process that the skin layer 29 part cleanly from the nozzle
20 and that skin layer 23 remain stationary for a time sufficient
to permit the new skin layer 29 to weld thereto. If either of these
process steps are not performed properly, a break will occur in the
successively formed skin layers causing molten metal to break out
and to prevent proper rod solidification. The use of boron nitride
for forming at least that portion of the nozzle adjacent the mold
portion 22 is highly advantageous because the skin layer does not
adhere to the boron nitride to thereby result in a clean
release.
The above description of the process and apparatus is applicable to
normal operational conditions and after the molding process has
commenced. The process is commenced by inserting a suitable rod
(not shown) into the exit end of the mold until it reaches
approximately to the junction of the first and second zones. The
initial molten metal flowing into the mold is permitted to flow
against the rod end and to bond thereto. This bar is then pulled
out incrementally as described above to establish the casting
process.
The axial length of the skin layer or segment 23 has practical
limitation and we have found that it should preferably be from 0.1
to 1.5 times the diameter of the rod being cast for bar diameters
up to about 5 inches. If the incremental pull or stroke is shorter,
casting rate is sacrificed and nozzle erosion is excessive. If the
stroke is longer, shrinkage porosity of the casting will be
excessive. By way of specific example, a bar about 11/2 inches in
diameter is successfully cast with the segment 23 being about 1
inch in length.
As the skin layer 23 moves into zone three, a progressively greater
radial thickness of the molten metal solidifies therein as the bar
is advanced to eventually form a self-sustaining bar which is
pulled mechanically from the zone three as shown in FIG. 3.
It will be observed from the above description that the molten
metal contacts only the first zone of the mold portion to any
substantial extent wherein it is not contaminated because of the
inert character of the boron nitride. The molten metal contacts the
primary solidification zone two portion of the mold for only an
extremely transitory period of time since solidification occurs at
virtually the instant the molten metal contacts the mold 22
portion. Since the initial solidification occurs in the metal
portion of the mold, the carbon chemistry of the metal is not
altered as would be the case if this portion of the mold were
formed of graphite. When the metal has advanced into the third
zone, the solidified layer is of substantial thickness and is
relatively cool so that no significant graphite diffusion occurs in
consequence of the graphite liner provided in the third zone of the
mold. The use of the graphite liner is advantageous because it is
relatively soft and self-lubricating and it permits the solidified
bar to be readily drawn through even though minor imperfections may
have occurred in the surface of the rod during solidification
thereof. There is no need for fluid lubricants such as rapeseed oil
which is commonly used in vertical continuous casting.
In accordance with this invention, round bar stock may be cast in
sizes of from about one to three inches in diameter with a
roundness variation of 21/2 percent or less, expressed in terms of
the difference in major and minor diameters of the rod. Both the
roundness and mean diameter variations are markedly less than the
commercial limits for hot rolled bar.
In casting stock one and one-half inches in diameter, we have
successfully used segment lengths of one inch and a cycle time of
0.25 seconds, the cycle being the sum of the time consumed in
drawing the bar one segment as above described and the dwell time,
i.e., the time the rod is permitted to remain at rest. A typical
dwell time is 0.12 seconds.
Satisfactory casting results are obtained with a variation in the
dwell time of from about 0.1 to about 0.36 seconds with the
proportion of the dwell time to the cycle time being between about
33 to 65 percent and with the cycle time accordingly being about
0.15 to 1.1 seconds.
It will be observed from FIG. 2 that the zone one consists of more
or less the refractory ring 34 and the nozzle 20. Zone two is
generally defined by the mold portion 22 and zone three includes
the balance of the mold. However, it should be recognized that the
three defined zones are process concepts and are not necessarily
coextensive with these mold portions. In particular, it should be
noted that the zone two of the process is located entirely within
the confines of the mold portion 22 extending from the interface 25
for the length of the segment 23 or the pull stroke. It is
important that this segment solidifies initially entirely within
the mold portion 22. Depending upon the length of the segment
employed, it is to be expected that in a given mold design, the
zone three will actually commence within the mold portion 22.
In practicing the process of this invention, it is preferable that
the inside diameter of the mold vary in accordance with the
progressive solidification of the rod so that the mold surfaces are
in close contact with the solidifying and shrinking rod to enhance
roundness of the rod and to effect optimum heat transfer between
the mold and the solidifying rod. FIG. 6 is a diagrammatic
representation showing a preferred design. The zone one, which
includes the refractory ring 34 and the nozzle 20, is shown to be
of constant diameter, although this is not necessary since the
metal exists in this zone only in molten form. It has been found
advantageous that the mold portion 22 have a gradually increasing
diameter over its length in the direction of the outlet end of the
mold. As shown in FIG. 6, a 5-minute taper with the longitudinal
axis in the mold wall produces desired results in the case where
the length of the mold portion 22 is about 1 inch. The reason for
the zone two portion of the mold being tapered outwardly is that it
appears to prevent molten metal breakouts through the solidified
skin. The mold in the zone three portion is provided with a
graphite liner and is gradually decreased in diameter in an amount
of 41/2 minutes to the longitudinal axis over the first 3-inch
portion. For casting a 1 17/16 inch diameter bar, this mold portion
continues to decrease in diameter in increments of 2 to 4 inches by
about 2/1000 of an inch, as shown in FIG. 6. The purpose of this
taper is to compensate for the fact that the rod is undergoing
substantial solidification as may be seen from inspection of FIG.
3. Then, for a final 26 inch interval, the diameter of the mold
remains constant. The zone three portion of the mold tapers in
accordance with the increased solidification and decreasing
temperature to compensate for shrinkage. The effect is to maintain
roundness and good heat transmission from the bar to the mold. In
the last 26 inch portion of zone three, referred to above, the
diameter is preferably maintained constant to slow down heat
transfer from the bar to the mold. This is desirable to minimize
the reheating of the bar surface and hence, cracking thereof after
the bar has emerged from the mold and to reduce frictional
resistance to the movement of the bar.
As above indicated, the method of this invention has particular
utility in casting metals which have a relatively high melting
temperature of about 2,200.degree.F. or more, and are unsaturated
in carbon so that they cannot be cast or solidified in a graphite
mold because of their tendency to absorb carbon by diffusion. Of
particular importance in this class of metals are ferrous metals
such as steel, and other ferrous metals typically containing up to
about 2 percent carbon. Illustrative of metals which may be cast in
accordance with this invention are SAE 4118 steel containing, by
weight, 0.18 percent to 0.23 percent carbon, 0.7 to 0.9 percent
manganese, 0.4 to 0.6 percent chromium, 0.08 to 0.15 percent
molybdenum, 0.04 percent maximum, phosphorus, 0.04 percent maximum,
sulphur, and the balance essentially iron; SAE 5160 steel
containing, by weight, 0.55 to 0.65 percent carbon, 0.75 to 1.0
percent manganese, 0.2 to 0.9 percent chromium, 0.04 percent
maximum, phosphorus, 0.04 percent maximum, sulphur, and the balance
essentially iron; SAE 52100 steel containing, by weight, 0.95 to
1.1 percent carbon, 0.25 to 0.45 percent manganese, 1.3 to 1.6
percent chromium, 0.25 percent maximum, phosphorus, 0.25 percent
maximum, sulphur, and the balance essentially iron. Ferrous metals
such as cast iron having a carbon content greater than 2 percent
may, of course, also be cast by the method of this invention.
Nickel based alloys and cobalt based alloys containing predominant
amounts of nickel or cobalt may also be successfully cast in
accordance with the process of this invention.
Illustrative of a nickel based alloy of this type is Inconel 610
consisting of 68.5 percent nickel, 0.2 percent carbon, 1.0 percent
manganese, 9 percent iron, 1.6 percent silicon, 0.5 percent copper,
15.5 percent chromium, columbium plus tantalum about 2 percent, and
the balance essentially nickel; and Rene 41 consisting of about 18
to 20 percent chromium, 10 to 12 percent cobalt, 9 to 10.5 percent
molybdenum, 5 percent iron, 0.09 to 0.12 percent carbon, 0.5
percent silicon, 0.1 percent manganese, 3 to 3.3 percent titanium,
1.4 to 1.6 percent aluminum, and the balance nickel. Illustrative
of a cobalt based alloy which may be cast in accordance with the
invention is Haynes 25, consisting of 0.05 to 0.15 percent carbon,
1.0 to 2 percent manganese, 19 to 21 percent chromium, 9 to 11
percent nickel, 14 to 16 percent tungsten, 3 percent iron, 1
percent silicon, and the balance essentially cobalt.
As described above, the metal solidification occurs in a metal mold
portion of the zone two so that there is no carbon source for
carbon diffusion. The skin layer 23 is well formed when it is
transferred to the graphite lined zone three so that no appreciable
carbon diffusion occurs during the casting process.
Although this invention has been described in terms of specific
examples, it is to be understood that other forms of the invention
may be readily adapted within the scope of the invention.
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