U.S. patent number 3,720,043 [Application Number 05/047,941] was granted by the patent office on 1973-03-13 for method for high efficiency filtering system.
Invention is credited to Julius Louis Kovach.
United States Patent |
3,720,043 |
Kovach |
March 13, 1973 |
METHOD FOR HIGH EFFICIENCY FILTERING SYSTEM
Abstract
A method for high efficiency filtration of both gaseous and
particulate radioactive contaminants characterized by a single pass
of an air stream carrying the contaminants through a single bed of
granular materials and then venting the filtered stream to the
surrounding environment. The granular bed is characterized by a
given minimum depth of adsorbent particles of a given minimum size
range which preferably is calculated on a basis dependent upon a
given minimum removal efficiency of radioactive gaseous and
particulate matter.
Inventors: |
Kovach; Julius Louis (Columbus,
OH) |
Family
ID: |
21951862 |
Appl.
No.: |
05/047,941 |
Filed: |
June 22, 1970 |
Current U.S.
Class: |
95/116 |
Current CPC
Class: |
B01D
46/30 (20130101); B01D 53/0446 (20130101); F24F
3/16 (20130101); B01D 53/0423 (20130101); B01D
2253/102 (20130101); B01D 2253/104 (20130101); B01D
2258/0283 (20130101); B01D 2257/93 (20130101); B01D
2259/40084 (20130101); B01D 2253/108 (20130101); B01D
2259/4009 (20130101) |
Current International
Class: |
B01D
46/30 (20060101); B01D 53/04 (20060101); F24F
3/16 (20060101); B01d 053/04 () |
Field of
Search: |
;55/74,387
;176/19,37 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Hart; Charles N.
Claims
I claim:
1. A process for decontamination of a gaseous stream carrying
radioactive contaminants comprising the steps of causing said
gaseous stream to pass through a bed of adsorbent particles, the
depth of said bed being at least approximately six inches or
greater and the particle size range of said adsorbent particles
being at least 8 .times. 12 mesh or greater as specified in ASTM
Standard E-11, as the depth of said bed is increased above 6
inches, the particle size of the adsorbent particles comprising
said bed is increased above above said 8 .times. 12 mesh, and
wherein the pressure drop across said bed is less than one inch
w.g. per inch depth of bed when based upon an entering gas stream
velocity of at least approximately 70 feet per minute; and
subsequently venting said filtered stream to the surrounding
environment.
2. The process defined in claim 1 wherein said adsorbent particles
are activated carbon having a size range of at least 6 .times. 12
mesh as specified in ASTM Standard E-11 and the depth of said bed
is at least 7 inches.
3. The process defined in claim 1 wherein the depth of said bed of
adsorbent particles is at least 8 inches and the particle size of
said particles is at least 4 .times. 6 mesh or greater as specified
in ASTM Standard E-11.
4. The process defined in claim 1 wherein the entering velocity of
said gaseous stream carrying said radioactive contaminants is
maintained in a range between 70 feet per minute and 200 feet per
minute in accordance with a particle size range of the adsorbent
particles comprising the bed to maintain a pressure drop across
said bed of less than one inch w.g. per inch of bed depth.
Description
The present invention relates generally to filtering systems and
particularly to a novel filtering system and process adapted for
high efficiency filtering of both particulate and gaseous
contaminants of a dangerous nature.
In nuclear reactors for example, an important feature of the design
is to provide for a high degree of safety against potential release
of radioactive contaminants to the surrounding atmosphere. During
operation of the reactor, fission products build up in the fuel
elements. Under normal operating conditions, these fission products
are retained within the cladding until the heat-producing
efficiency is spent. Then these products are removed from the
reactor and the reactor site with the spent fuel elements. The fuel
elements are located in a pressure vessel or nuclear reactor. The
reactor and certain heat transfer equipments are located within a
containment system. Therefore three barriers are established
between the radioactivity of the fissile fuel and the fission
products and the surrounding environment; namely, the cladding of
the fuel elements, the nuclear reactor pressure vessel, and the
containment system. The containment system is the last barrier and
its protective action must be maintained should a failure occur in
the other barriers.
Conventional filter systems for combined filtration of both
particulate and gaseous contaminants presently used in connection
with nuclear reactors have generally consisted of a prefilter for
large particulate matter, a mist separator to remove water droplets
from the air stream, a conventional high efficiency particulate air
filter for smaller particulate matter, referred to in the art as
HEPA, a conventional shallow bed carbon filter, and lastly another
HEPA filter. These filter systems are built up in banks from
standard size units, for example, one HEPA filter for each 1000
cubic feet of air per minute and are generally disposed in tiers in
the containment structure.
Each of these standard systems are associated with a large amount
of hardware, such as for example, holding frames, moisture
separators, gasketing surrounding each frame of each standard
filter unit, and generally cooling coils to remove heat and reduce
pressure.
In large installations, prior to the present invention, these
systems have been of the recirculating type wherein the air is
recirculated through the system until sufficient removal of
radioactive materials from the containment system is accomplished.
Once through systems have been devised but have been used only on
small nuclear reactors. Their use for large power reactors was not
feasible because of the danger of release of much larger quantities
of radioactive materials and the insufficient reliability of
conventional filter systems. This unreliability is inherent in the
construction of these systems wherein for example, the particulate
filters and moisture separators with glass fiber media are
relatively fragile and also are subject to structural weakening
with age.
Further, these conventional filter arrangements possess other
disadvantages relating to the type of accidents which may occur to
release radioactive gaseous and particulate matter into the
containment system.
For example, in a loss of coolant type accident in which the
secondary barrier fails, the primary barrier may also fail due to
overheating which results in the release of fission products into
the containment atmosphere. In water cooled reactors, large
quantities of steam and water droplets would be released into the
containment system in addition to other gaseous and particulate
matter. Therefore there is a potential for possible moisture
clogging of the HEPA filters which lowers their efficiency and
possible flooding of the shallow carbon bed filters if there is a
failure in the moisture separators located upstream in the flow
pattern.
Another type of accident which may occur is referred to in the art
as a "design basis accident" wherein a failure occurs in the
primary system. This type of failure is characterized by a release
of radioactive gaseous and particulate matter into the containment
system and is associated with both a rapid temperature and pressure
increase in the containment structure. In pressurized water and
boiling water type reactors, cooling coils, cooling sprays, or
suppression pools are employed to reduce temperature and pressure.
However, the use of this type of equipment still requires very
expensive and complicated containment apparatus to withstand the
initial pressure and temperature rise.
In general the present invention incorporates a single bed of
granular adsorbent material several times the depth employed in
conventional adsorbent filters which functions to remove both
gaseous and particulate matter from the incoming air stream.
Relatively large particle sizes are used to form the bed compared
to the small particle sizes used in prior conventional adsorbent
beds. The bed is contained in a vessel of simple construction and
preferably is horizontally disposed therein and designed for
downflow of the incoming air stream through the bed.
Preferably, the bed includes a layer of adsorbent particles of a
given size range and a given minimum depth to assure sufficient
removal of radioactive gaseous and particulate matter. However,
other non-adsorbent filter media particles can be incorporated in
conjunction with the adsorbent material either in separate layers
or in admixture with the adsorbent particles to assure sufficient
removal of particulate as well as gaseous materials. The specific
design of the bed can vary within predetermined ranges depending
upon the particular circumstances of each application and the
efficiency level desired with respect to both gaseous and
particulate removal.
It is therefore a primary object of the present invention to
provide a process for high efficiency filter systems which
increases both gaseous and particulate removal efficiency while
simplifying the construction of such systems relative to prior
methods and means.
It is another object of the present invention to provide a process
of the type described which has improved characteristics relative
to withstanding pressure shocks, avoiding flooding and
overheating.
It is still another object of the present invention to provide a
process of the type described which can be regenerated while in
place in a relatively short time and in a simple manner thereby
eliminating costly and time consuming replacement of filter
apparatus and media.
It is a further object of the present invention to provide a
process of the type described which permits the incorporation of
other filter media layered in a single bed form to substantially
increase the removal efficiency of particulate matter over a wide
particle size range including the Aitken nuclei size range.
IN THE DRAWINGS
FIG. 1 is a side elevational view in section and partially
schematic of a filter apparatus constructed in accordance with the
present invention, the section being taken along the centerline of
the apparatus;
Fig. 2 is an end elevational view in section of the apparatus shown
in FIG. 1; and
FIG. 3 is a graphic illustration of test results obtained under
specified conditions employing the principles of the present
invention.
Referring in detail to the drawings, a combined particulate nd
gaseous filter apparatus constructed in accordance with the present
invention is illustrated in FIG. 1 and includes a housing or
holding vessel, indicated generally at 20. Vessel 20 includes an
inlet 22 for the incoming contaminant-laden gas stream and an
outlet 24 for the exiting filtered stream.
A conventional blower system, not shown, is communicated to inlet
22 to provide a source of air that would carry the gaseous and
particulate contaminants through the system. Further, the entering
stream should be dispersed for substantially uniform distribution
to bed 26. There are many well-known, conventional techniques to
accomplish such uniform distribution of gaseous streams, such as
baffles or the like, which would be suitable for the purposes of
the present invention and therefore are not shown or described in
detail herein.
Bed 26 preferably comprises adsorbent materials; such as carbon,
aluminas, or zeolites for example, and is horizontally supported
between the opposing inner walls of vessel 20 by a suitable
supporting means. A simple, durable means to support bed 26 is
represented by a grating 28 fixed to the side walls of vessel 20 in
any suitable conventional manner. A conventional cloth netting or
wire mesh screen having openings smaller than the smallest
particles comprising the bed is laid over the grating 28 to prevent
the loss of the individual adsorbent particles and yet permit the
passage of liquids and gases.
It is important to point out that the adsorbent particles of bed 26
must be relatively carefully distributed to ensure that a closely
packed relationship exists between the inner walls of vessel 20 and
the particles comprising the bed. This in effect prevents leakage
of the incoming air stream around the bed and the possible release
of contaminants through outlet 24. It is also important to note
that this type of bed design is far superior to the prior art type
wherein a plurality of standard size units are placed side by side
and gasketing is required around the individual frames of each
standard unit. Such gasketing requirements are not desirable
because of the inherent potential and actual leakage problems
encountered wherein unfiltered portions of the air stream
circumvent the filtering media through faults occuring in the
gasketing.
Vessel 20 also includes a liquid drain 28 disposed in the bottom of
the vessel to provide for removal of any water or other condensed
liquid which may accumulate. An inert gas or steam line is provided
with suitable orifices is provided to permit the bed to be
regenerated periodically which eliminates the necessity for
frequent and costly replacement of filter media which is required
using conventional apparatus and techniques.
Referring now to the specific embodiment shown, the depth of bed 26
and the particle size of the adsorbent particles making up the bed
are primary considerations of the present invention and are
dependent to a degree upon one another.
For a clearer understanding of the present invention, it should be
noted that prior high efficiency type filter systems for combined
gaseous and particulate matter have used a series or train of
separate filter media as pointed out previously herein. The
adsorbent filter bed used in those trains consisted of a shallow
bed of fine adsorbent particles. It is well-known that the
efficiency of removal of gaseous and particulate matter per inch of
bed depth increases with decreasing particle size of bed material.
This has been the approach taken in the prior art filter systems;
that is, a shallow bed of filter media consisting of relatively
small particle sizes. Therefore, to obtain high efficiency of
removal of gaseous contaminants at pressures which will not rupture
the relatively fragile HEPA filters located upstream, the depth of
the bed used has been limited to about 2 inches and the maximum
particle size of the adsorbent has been limited to 8 .times. 16
mesh.
However, a novel and completely different approach is employed in
the present invention wherein the bed depth is substantially
increased and also the size of the particles in the bed are
increased. In effect, the overall efficiency of contaminant removal
is maintained and in fact increased by appropriate design. However,
the surprising results of such an approach occurs in the
elimination or substantial decrease or many of the problems and
hazards encountered using prior art systems in addition to
decreasing both installation and maintenance costs.
For example, one of the problems encountered in conventional high
efficiency filter systems used in nuclear power facilities is the
loss of efficiency of the carbon filter beds due to the rise in
temperature caused by the decay heat of deposited radioactive
iodine forms. As the temperature rises significantly, the iodine
forms tend to migrate through the bed and may escape to the
surrounding environment.
This problem is substantially reduced if not completely eliminated
using the method and apparatus of the present invention because the
larger particle sizes employed in the bed maintain a lower removal
efficiency per inch of bed depth and this distribute the fission
products and the decay heat produced therefrom in a wider band.
Therefore the temperature rise of the bed is not as great and
migration is less likely to occur. If some migration does occur,
the depth of the bed is great enough to prevent the iodine forms
from passing through the bed. In conjunction with this same
problem, the fire hazard is significantly lowered using the method
and apparatus of the present invention for the same reason, namely,
narrow band or spot overheating caused by decay heat of deposited
radioactive forms is essentially eliminated.
Narrow band or spot heating is caused in the conventional type beds
because the particles sizes employed are small and the adsorption
of fission products is concentrated in a very narrow band of
fractions of an inch at the entry face of the bed and this permits
the decay heat to be concentrated at potentially dangerous
levels.
For example, tests relating to iodine removal efficiencies show
that with an air velocity of 100 feet per minute and carbon
granules of eight by 16 mesh particle size, 99.99 percent of the
radioactive elemental iodine removed was concentrated in the first
one-half inch of the bed. However, using carbon particles of four
by 6 mesh, for example, this same percent is distributed over
approximately the first seven inches of the bed.
Another problem which is solved by the present invention is that of
flooding of the carbon bed, which results from the retention of
condensed water in the interstices between the particles. This
represents a substantial hazard in conventional systems if a
failure occurs in the moisture separators placed ahead of the
carbon filters. However, this danger is avoided in the present
invention since the larger particle sizes used permits much higher
gas velocities to be employed through the system, which in
conjunction with the greater inter-particle volume, eliminates the
potential of flooding the bed. Condensed water vapor flows through
the enlarged interstitial conduits formed between the particles in
the bed to the bottom of the vessel for simple removal through
drain outlet 28, for example.
More specifically, suitable particle sizes for the bed which work
well in the filtering system of the present invention have been
found to be in the range of approximately 12 mesh to one quarter
inch mesh as specified in ASTM Standard E-11. Beds employing any
substantial proportion of adsorbent particles having a size smaller
than 12 mesh give rise to the problems encountered in the prior art
systems, such as narrow band overheating, potential flooding, and
the requirement of much lower gas stream velocities. As the
particle size becomes much larger than one quarter inch mesh, the
bed depth required increases to a point which becomes impractical
for most applications.
The depth of the bed is a function of the specific requirements of
the system such as for example, the potential loading of
contaminants per cubic foot of air, and the particle size and shape
of the granular filter media employed. The minimum depth of at
least the adsorbent material included in the bed is approximately
six inches for most conditions in systems in which radioactive
contaminants are encountered. However, the preferred depth for
meeting most safety factors required under most present
applications is approximately twelve inches or more. The maximum
depth of the bed is only limited by practical sufficient efficiency
in contaminant removal.
As one approaches the minimum six inch depth, the particle size
employed must approach the lower limit of the size range, that is
approximately 12 mesh. For the purposes of the present invention
the minimum particle size range employed should be no smaller than
8 .times. 12 mesh in a bed approaching the minimum depth of 6
inches. However, as the depth of the adsorbent particles in the bed
increases, proportionately larger particle sizes are preferred.
A typical example of a preferred design constructed in accordance
with the present invention and meeting present government standards
for a nuclear reactor application would be illustrated by following
system conditions:
Air Flow: 10,000 SCFM Vessel, I.D.: 5.0 ft. Vessel, length: 12.0
ft. Air Velocity: 166 fpm. Carbon type: 4.times.6 mesh (4mm.
pellets) Carbon bed depth: 15 inch Pressure drop: 10 inch w.g.
It is important to point out that the bed may be constructed in
graded layers of adsorbent particles within the range noted above
and may also include layers of other non-adsorbent granular filter
media such as sand, crushed gravel and the like which can be
incorporated to enhance the particulate filtering efficiency of the
system at less cost.
However, the use of other non-adsorbent materials is not required
for particulate removal as test have shown that granular adsorbent
particles work very well and function to remove both gaseous and
particulate matter and therefore are the preferred form of bed
material. Again, however, the small particle size employed in
conventional carbon beds cannot be used to any substantial degree
without prefiltering because of the tendency of particulates and
condensate to fill the interstitial volume and restrict the air
flow or prevent passage of the air stream completely.
It should also be noted that, if desired, various types of
adsorbent materials can be layered or mixed to form the total
adsorbent bed depth required such as for example, combining alumina
and carbon in a single bed.
The gas stream velocity is substantially increased in the method of
the present invention. It has been found that in filter beds
constructed in accordance with the present invention, increased gas
stream velocity increases particulate fission product removal
efficiency without detriment to gaseous fission product removal
efficiency. Therefore, in addition to reducing the potential of
flooding of the adsorbent filter media, increasing the gas stream
velocity substantially over the velocity used in prior methods
increases the efficiency of particulate removal. Conventional
systems use air stream velocities in the range of 40 to 70 feet per
minute whereas the apparatus of the present invention permits the
filtering process to operate with air stream velocities as high as
250 feet per minute. The upper limit of air stream velocity is
determined primarily by considerations of pressure drop across the
bed. Too large a pressure drop is not desirable, however a pressure
drop in the range of 8 to 12 inches w.g. across the bed is quite
suitable for most applications and can be maintained quite easily
using the teachings of the present invention.
Referring specifically to FIG. 3, test data is graphically
illustrated and plotted on a logarithmic scale. The pressure drop
in inches of water at standard gravity per inch of bed depth is
plotted versus the air velocity of the entering air stream in feet
per minute. Tests were conducted using beds of the same depth but
employing carbon granules of different particle size or as
illustrated by lines 1 and 2 different shapes of the same particle
size.
It is readily seen that at an entering air velocity of about 70
feet per minute the pressure drop per inch of bed depth for a bed
comprising particles having a size of 8.times.16 mesh or smaller is
significantly greater than 1 inch of water at standard gravity.
A bed constructed in accordance with the present invention exhibits
a resistance to air flow of less than one inch w.g. per inch of bed
depth at an entering air stream velocity of approximately 70 feet
per second. However, a pressure drop of less than 0.7 inches w.g.
per inch of bed depth at the same entering air stream velocity is
preferred fro conditions encountered presently in the field of
application.
Therefore, in accordance with the present invention the depth of
the bed may be increased several times over the depth of
conventional adsorbent beds without encountering potentially
troublesome pressure drops across the bed at entering air stream
velocities considerably higher than possible using prior methods
and means. This, of course, leads to some of the advantages of the
present invention previously noted herein.
It should be readily apparent from the foregoing description that
the apparatus and method of the present invention eliminates or
substantially reduces most of the disadvantages of prior art
systems and techniques, increases the potential efficiency of such
systems, provides a much simpler, safer, more durable and less
expensive construction, and further requires less maintenance as
compared to prior systems.
* * * * *