U.S. patent number 3,708,431 [Application Number 05/137,606] was granted by the patent office on 1973-01-02 for dispensing package.
Invention is credited to Samuel B. Prussin.
United States Patent |
3,708,431 |
Prussin |
January 2, 1973 |
DISPENSING PACKAGE
Abstract
Packages are described which comprise surfactant-forming acid
and surfactant-forming base compositions maintained isolated from
each other within a container with valve means communicating with
each composition. Actuation of the valve means results in
dispensing a surfactant. Through use of chemical heat generating
means within the package, the surfactant can be dispensed in a
warmed state.
Inventors: |
Prussin; Samuel B. (Los
Angeles, CA) |
Family
ID: |
22478227 |
Appl.
No.: |
05/137,606 |
Filed: |
April 26, 1971 |
Current U.S.
Class: |
222/146.3;
424/73; 222/219; 510/120; 510/372 |
Current CPC
Class: |
A61Q
5/02 (20130101); A61Q 5/10 (20130101); A61Q
9/02 (20130101); A61Q 5/08 (20130101); A61K
8/22 (20130101); A61K 9/12 (20130101); A61K
8/02 (20130101); A61K 2800/88 (20130101); A61K
2800/242 (20130101) |
Current International
Class: |
A61K
9/12 (20060101); A61Q 9/02 (20060101); C09k
003/00 () |
Field of
Search: |
;262/188.3,90,108
;222/146 ;424/73 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rosdol; Leon D.
Assistant Examiner: Schulz; William E.
Claims
I claim:
1. In combination:
a container means having at least two isolation chambers, one of
said chambers containing a surfactant-forming acid selected from
the group consisting of unsubstituted carboxylic acid having 10-18
carbons, mixtures of said acids, ethoxylated derivatives of said
acids having 5-40 ethoxy groups, alkyl benzene sulfonic acid having
10-13 carbons in the alkyl portion thereof, alkyl esters of
sulfuric acid having 10-13 carbons, alkyl sarcosinic acid having
10-13 carbons and alkyl ethers of polyethoxyesters of sulfuric acid
in which the alkyl portion contains 10-13 carbons and the
polyethoxy portion contains 5 to 40 ethoxy groups;
another of said chambers containing a surfactant-forming base
selected from the group consisting of alkali metal hydroxides,
carbonates, bicarbonates, borates and phospates, ammonimum
hydroxide, morpholine, triethanolamine and aminopropane-diol;
and,
valve means in communication with said chambers including flow
passages of predetermined size for proportioning amounts of said
surfactant-forming acid and base upon actuation of said valve means
whereby an effective cosmetic surfactant composition is formed
within said valve means and dispensed in aerosol form and wherein
at least one of said chambers contains a liquified gas having a
vapor pressure at 70.degree. F of between 12 to 85 pounds per
square inch guage.
2. The combination of claim 1 wherein said surfactant-forming base
is selected from the group consisting of triethanolamine and
morpholine.
3. The combination of claim 1 wherein one of said chambers contains
hydrogen peroxide and another of said chambers contains a hydrogen
peroxide reducing agent selected from the group consisting of
alkali metal sulfites, alkali metal bisulfites, thiourea,
1-phenyl-2-thiobarbituric acid, alkali metal sulfides, and alkali
metal thiosulfates, said hydrogen peroxide and said reducing agent
present in amounts sufficient to effect about at last a 25 percent
increase in temperature above ambient of said dispensed surfactant
composition.
4. The combination of claim 3 wherein said reducing agent is
included in said surfactant-forming base.
5. The combination of claim 3 wherein said surfactant-forming base
includes triethanolamine in solution with a member of the group
consisting of sulfur dioxide or alkali metal thiosulfates.
6. The combination of claim 5 wherein said reducing agent is
triethanolammonium sulfite.
7. The combination of claim 4 wherein said surfactant-forming base
includes a member selected from the group consisting of potassium
sulfite and sodium thiosulfate dissolved in an aqueous solution of
triethanolamine.
8. The combination of claim 1 wherein said surfactant-forming acid
is stearic acid.
9. The combination of claim 1 wherein said surfactant-forming acid
is the fatty acid fraction derived from coconut oil.
10. The combination of claim 1 wherein said surfactant-forming acid
is tridecyl benzene sulfonic acid.
11. The combination of claim 1 wherein said surfactant-forming acid
is lauryl polyoxyethylene (24) ether sulfuric acid.
12. The combination of claim 1 wherein said surfactant-forming acid
is N-cocoyl sarcosinic acid.
13. The combination of claim 3 wherein said surfactant-forming acid
is stearic acid.
14. The combination of claim 3 wherein said surfactant-forming acid
is the fatty acid fraction derived from coconut oil.
15. The combination of claim 3 wherein said surfactant-forming acid
is tridecyl benzene sulfonic acid.
16. The combination of claim 3 wherein said surfactant-forming acid
is lauryl polyoxyethylene (24) ether sulfuric acid.
Description
This invention relates to packages filled with two compositions
maintained isolated from each other within a container, such
packages adapted for the mixing of the isolated compositions and
dispensing of the resulting mixture from the container. Such
packages are particularly useful in dispensing of compositions in
aerosol form for shaving and other purposes and may in accordance
with the invention be dispensed at ambient temperatures or in a
warmed state.
Cosmetic chemists have devoted considerable efforts over the years
to develop means for producing lather compositions for shaving
purposes to eliminate the inconvenience of using a shaving brush
and a cake of shaving soap. U.S. Pat. No. 2,655,480 to J. G.
Spitzer et al. represented a considerable step forward in the art
of lather-producing compositions. This patent describes a package
filled with a mixture of an aqueous soap solution and volatile
propellant, the package being fitted with a dispensing valve means,
with actuation of the valve resulting in the dispensing of a lather
composition from a pressurized container adapted for shaving and
other cleansing purposes. Such compositions represent a
considerable step forward in the art of lather production but
suffer from a fundamental disadvantage. The soap solution and
volatile propellant are present within the pressure-tight container
in the form of a liquid emulsion. Such an emulsion cannot be
prepared with a sufficient degree of stability to eliminate the
necessity for shaking the container prior to use and all such
packages must be shaken before use to reconstitute the emulsion. As
will be readily apparent, shaking of any soap composition within
this context results in the creation of a foam. It has been found
that when packages formed in accordance with U.S. Pat. No.
2,655,480 are less than about 25 percent full, shaking of the
container tends to result in filling the entire container with foam
with elimination of any discrete liquid phase. Actuation of the
valve under such conditions results in dispensing of a lather in a
poorly foamed state, such lather collapsing virtually immediately
and being generally unsuitable for use, particularly for shaving
purposes. As a result, when packages filled in accordance with U.S.
Pat. No. 2,655,480 are less than 25 percent full, they are
generally unsuited for use and must be replaced with resulting
added cost to consumers. Accordingly, there has long been a need
for a means to create a package for dispensing of compositions in
foam form from pressurized containers where either shaking can be
eliminated, or where shaking will not create a detrimental foam
within the package, and where the entire contents of the package
can be used with optimum maintenance of specifications for the
intended purpose.
Recently, workers in the art of cosmetic chemistry have developed
self-heating compositions which can be dispensed from a pressurized
container in a warmed state, a particularly desirable condition for
shaving and certain other cosmetic purposes. Typical packages and
compositions for this purpose are described in U.S. Pats. Nos.
3,325,056; 3,326,416; and 3,341,418. In all of these patents, the
self-heating action is effectuated by chemical reaction between an
oxidizing agent such as hydrogen peroxide and reducing agents such
as alkali metal sulfites and thiourea, the oxidizing agent and
reducing agent being maintained isolated from each other within the
pressurized container. The packages described in the
above-mentioned three U.S. patents represent modifications of the
system described in the Spitzer et al. U.S. Pat., No. 2,655,480, in
that a separate compartment is provided in the package to hold the
oxidizing agent. In the compositions described in the
above-mentioned patents, the oxidizing agent is maintained in the
separate compartment at concentrations ranging from 7 percent
hydrogen peroxide in U.S. Pat. No. 3,326,416 to 30 percent hydrogen
peroxide in U.S. Pat. No. 3,325,056. Such concentrated solutions of
hydrogen peroxide have characteristics of burning and bleaching of
the skin if placed directly in contact with the skin which could
occur should the soap composition in the main body portion of the
container be exhausted or change density by foam formation within
the container while there still remains some oxidizing agent in the
separate compartment. While this problem could at least
theoretically be resolved by placing the oxidizing agent in the
main body portion of the container, this is not feasible
technically in that hydrogen peroxide is not stable in the alkaline
medium of the soap composition. There has, therefore, been a need
for the creation of packages adapted for dispensing self-heating
compositions in which the oxidizing agent is not present in a
concentration sufficiently high to be detrimental to the skin
should it be dispensed individually, and yet where efficient
dispensing of the composition can be realized without an overly
large package size.
The invention sought to be patented resides in the concept of a
package adapted for the dispensing of a surfactant composition
comprising a container with means to maintain surfactant-forming
acid and surfactant-forming base compositions isolated from each
other within the container; means to apply pressure to each of said
compositions and valve means communicating with each composition
whereby actuation of the valve means results in the mixing of
portions of each of said composition and dispensing of the mixture
from the package as a surfactant composition. Packages within the
scope of the invention can be constituted to dispense a warmed
surfactant composition by including heat generation means within
the package as will be described in detail hereinafter.
The manner and process of making and using the invention will now
be described generally so as to enable one skilled in the art of
cosmetic chemistry to make and use the same as follows:
Packages within the scope of the present invention are in the form
of a container filled with two compositions which are maintained
isolated from each other. One of these compositions comprises a
surfactant-forming acid and the other comprises a
surfactant-forming base. As used herein, the term "surfactant" is
used in the broad sense to identify and define substances which, by
themselves or with additives, form "detergents," that is to say,
among other effects they exert a cleansing action on a surface by
surface-active properties; they also, by themselves or with
additives are emulsifiers, that is to say, because of their
surface-active properties they stabilize mixtures of otherwise
immiscible materials. The term "surfactant" thus, for the purposes
of the art herein taught, embraces compositions derived from
naturally occurring substances which are commonly referred to as
soaps as well as compositions derived from substances prepared
synthetically.
Surfactant-forming acids useful in the formulation of packages
within the scope of the invention include carboxylic acids having
not less than 10 carbon atoms, for example lauric acid, palmitic
acid, stearic acid and the like, including mixtures of such acids
as the mixture of stearic and palmitic acid which constitutes
"commercial" stearic acid and coconut oil fatty acids, ethoxylated
carboxylic acids having at least 10 carbon atoms, for example
polyethoxystearic acids (in which the polyethoxyether moieties
contain 5 to 40 ethoxy groups), alkyl aryl sulfonic acids having at
least 10 carbon atoms, for example tridecyl benzene sulfonic acid,
alkyl esters of sulfuric acid having at least 10 carbon atoms, for
example lauryl sulfuric acid, alkyl ethers of polyethoxyesters of
sulfuric acid in which the alkyl portion contains at least 10
carbon atoms and the polyethoxy portion contains 5 to 40 ethoxy
groups, for example lauryl polyoxyethylene sulfuric acid, and amido
carboxylic acids having at least 10 carbon atoms in the amido
portion, for example lauroyl sarcosinic acid.
Surfactant-forming bases useful in the formulation of packages
within the scope of the invention are basic materials capable of
reacting with the surfactant-forming acid present to form a
surfactant. Useful surfactant-forming bases include alkali metal
(for example sodium and potassium) hydroxides, carbonates,
bicarbonates, borates and phosphates and surfactant-forming organic
bases such as morpholine, triethanolamine and
aminopropane-diol.
The composition comprising a surfactant forming acid is present in
the package in solution or as an aqueous emulsion in the presence
of non-soap producing emulsifiers of the type well known in the art
of emulsion technology. Typical emulsifiers include polyoxyethylene
cholesteryl ether, polyoxyethylene lauryl ether, polyoxyethylene
sorbitan monolaurate and polyethylene glycol and polypropylene
glycol copolymers. The composition may also include additives
depending upon the end use of the ultimate composition to be
dispensed from the package. Where a stable foam is desired, as for
example for use in shaving, humectants designed to minimize rate of
drying may be present such as glycerin, propylene glycol, sorbitol
and the like. For cosmetic purposes, a perfume is normally used to
impart a desired degree of fragrance to the product. Packages
prepared in accordance with the invention are useful not only for
cosmetic purposes, such as shaving, shampooing, hair dyeing and
bleaching, and general cleansing purposes, but also for dispensing
medicinal compositions for topical use such as analgesics, chest
rubs and the like and for such purpose, a medicinal agent such as
methyl salicylate, thymol, eucalyptol or other essential oil, a
local anesthetic such as benzocaine, and other topically useful
medicinal agents will be present to impart the desired medicinal
effect.
The other composition comprising a surfactant-forming base can, in
the case of a liquid base such as triethanolamine or morpholine,
consist solely of such base. Where normally solid
surfactant-forming bases are used, such as the alkali metal
hydroxides, carbonates, bicarbonates, borates or phosphates, the
base can be present in solution or suspension in water or an inert
non-aqueous liquid. Where ammonium hydroxide is used, a solution of
aqueous ammonia is useful.
As described above, the two compositions are maintained isolated
from each other within a container. Such a container is constructed
of rigid or flexible material depending upon the pressurization
means to be utilized for dispensing. A collapsible container formed
of plastic or metal is used where pressurization is effected
manually be squeezing. In accordance with the preferred embodiment
of this invention, self-pressurization is employed through use of a
liquefied propellant gas within the container in either or both of
the isolated compositions and in this case, a pressure-tight
container having sufficient wall strength to withstand the
propellant pressure is employed. The container can be formed of a
wide class of materials used in the art of aerosol packaging such
as glass, rigid plastics and metal. Such propellants must be of
such a nature that they do not destroy the surfactant or its
ingredients and thus must be fully compatible therewith. Such
propellants should have vapor pressure of approximately 12 to 85
pounds per square inch gauge at 70.degree. F using as propellants
saturated aliphatic hydrocarbons such as propane, butane,
isobutane, and the like, and/or chlorofluoralkanes containing not
more than two carbon atoms and at least one fluorine atom having
the desired vapor pressure for use in the invention. Propellant
gasses such as carbon dioxide or nitrous oxide or liquefied
propellants such as dimethyl ether with a high degree of water
solubility may also be used as pressurization means.
The two compositions, formulated as described above, are packaged
within a container in such a way as to remain isolated with each
other. Valve means are provided to communicate with each
composition such that upon actuatuion of the valve means, a
quantity of each composition is mixed and the resulting mixture is
dispensed from the package. Since the compositions comprise,
respectively, a surfactant-forming acid and a surfactant-forming
base, the product of a mixture of the two constitutes a surfactant.
It is apparent that the concentration of the respective ingredients
must be adjusted in relation to the proportioning properties of the
valve means such that a proper mixture of the two compositions
based upon the desired end use results from actuation of the valve
means.
There are many different ways in which the final package can be
constructed which will influence the selection of appropriate valve
means and the means selected for pressurization. Several such ways
are discussed hereinafter.
The package can be constructed in the form of a two-chambered
container, separated by a rigid well, with each chamber fitted with
a valve leading to a common discharge conduit. Such a structure is
illustrated in U.S. Pat. No. 2,941,696 and with such, both
compositions are pressurized. Alternately, structure as illustrated
in U.S. Pat. No. 3,295,727 can be employed in which case one of
compositions is pressurized and is present in the body portion of
the container with the second composition in the illustrated
chamber surrounding the dip tube. Pressurized vapors from the first
composition act upon the second composition in this structure. U.S.
Pat. No. 3,272,389 illustrates another form of package construction
useful in the invention. In this structure, venturi action of one
pressurized composition provides the motive force for dispensing
the second composition.
A particularly desirable form of package for dispensing a
surfactant composition in accordance with the invention is to
utilize a package having two compartments in which the two
compositions are packaged within a pressure-tight container, the
compartments being separated by a movable wall actuatable upon a
pressure differential between the two compartments when the valve
means affixed to the container are actuated. In such a system, the
movable wall can be in the form of a movable piston, for example,
as illustrated in U.S. Pat. No. 3,217,936, or in the form of a
collapsible bag as illustrated in U.S. Pat. No. 2,973,883. The
disclosures of the aforementioned patents are incorporated by
reference herein for illustrative purposes to the same extent as if
set forth at length. It is to be understood that such patents are
merely illustrative of various means to package the two
compositions of this invention within a container and to dispense
portions of both compositions to insure mixing and dispensing upon
actuation of the valve means.
Packages of this invention are filled by conventional means. Where
pressurization is brought about by a liquefied propellant included
in either or both compositions, filling can be by either
pressure-or-cold-filling techniques. If cold filling is employed, a
propellant having an atmospheric pressure boiling point temperature
of above 32.degree. F must be used to avoid freezing of the water
present in the compositions.
The above description has been with respect to the compounding of
the two compositions comprising, respectively, a surfactant-forming
acid and surfactant-forming base where the composition to be formed
on dispensing from the package is at ambient temperatures. In
accordance with a specific embodiment of this invention, dispensing
of a warmed composition is realized by the incorporation within the
package of chemical heat-generation means. Heat generation, in
accordance with this embodiment of the invention is realized by the
chemical reduction or catalytic decomposition of H.sub.2 O.sub.2 or
by the heat of solution of anhydrous magnesium chloride.
When chemical heat generation is effected by chemical reduction or
catalytic decomposition of hydrogen peroxide, the hydrogen peroxide
is most conveniently incorporated in the composition comprising the
surfactant-forming acid, the acidic pH creating an environment in
which hydrogen peroxide is completely stable. Heat generation can
be effected by chemical reduction of the hydrogen peroxide by a
reducing agent which is maintained isolated from the hydrogen
peroxide by incorporation in the composition comprising the
surfactant-forming base. Useful reducing agents include sulfur
dioxide and salts derived therefrom such as alkali metal sulfites
and bisulfites, thiourea, 1-phenyl-2-thiobarbituric acid and its
derivatives as described in U.S. Pat. No. 3,341,418, alkali metal
sulfides, alkali metal thiosulfates and the like. It has been found
that sulfur dioxide and salts derived therefrom and alkali metal
thiosulfates are particularly useful reducing agents. For example,
sulfur dioxide is soluble in surfactant-forming organic bases such
as triethanolamine and morpholine, the resulting solutions
constituting the composition comprising surfactant-forming base in
the preparation of packages of the invention where a warmed
surfactant is desired. Alternately, potassium sulfite or sodium
thiosulfate dissolved in an aqueous solution of triethanolamine
constitutes another particularly useful composition comprising
surfactant-forming base.
The relative proportions of hydrogen peroxide and reducing agent
are adjusted to be a stoichiometric mixture or within .+-. 10
percent of stoichiometric. The absolute quantities are selected
based upon the temperature rise desired, which should be at least
25.degree. F above ambient temperatures for meaningful heating.
Heat generation can also be effected by catalytic decomposition of
hydrogen peroxide, a reaction liberating heat with the formation of
water and oxygen gas. Many materials are well-known in the art as
catalyzing such decomposition, for example such metals as silver,
lead, iron, chromium, bismuth, copper, titanium, molybdenum and
silicon, oxides and salts thereof, activated carbon, enzymatic
systems such as catalase and the like. The catalyst can be in solid
form located adjacent to the valve means in the package such that
dispensing causes the mixture of surfactant-forming acid plus
hydrogen peroxide composition and surfactant-forming base
composition to pass over the catalyst prior to dispensing.
Alternately, the catalyst can be present in the surfactant-forming
base composition in solution or suspension, a particularly
advantageous means since fresh catalyst is available for contact
with the hydrogen peroxide present in the surfactant-forming acid
composition upon each actuation of the valve means. This avoids any
possibility of reduction in catalyst efficiency during the life of
the package through catalyst poisoning.
Where catalytic decomposition of hydrogen peroxide constitutes the
heat generation means, the quantity of hydrogen peroxide in the
detergent-forming acid composition is adjusted based upon the
degree of temperature rise desired, with at least a 25 percent rise
being desirable for meaningful heating.
The embodiment of this invention where a warmed detergent is
dispensed has been described with specific reference to hydrogen
peroxide as the agent which is subjected to catalytic decomposition
or reduction to liberate heat. It is apparent that other substances
of like properties can also be used, such as derivatives of
hydrogen peroxide, for example urea hydrogen peroxide and other
organic and inorganic peroxides, as well as perborates and
persulfates, all of which are the full equivalents to hydrogen
peroxide in the preparation of packages within the scope of the
invention. Where alkaline equivalents of hydrogen peroxide are
used, they are incorporated in the surfactant-forming base
composition.
Heat generation is also effected by use of the heat of solution of
anhydrous magnesium chloride in water. In accordance with this
embodiment, anhydrous magnesium chloride is incorporated in
solution or suspension in the surfactant-forming base composition
which must be free of water. The surfactant-forming acid
composition includes water and when the two compositions are mixed
during dispensing, the contact between the magnesium chloride and
the water present in the surfactant-forming acid composition
results in solution of magnesium chloride with evolution of heat.
It is apparent that other materials of like properties can be used
in lieu of magnesium chloride, for example, metallic salts such as
aluminum chloride, such materials causing the evolution of heat
upon solution in water and being the full equivalent of anhydrous
magnesium chloride in the preparation of packages in accordance
with the invention where heat generation means based upon heat of
solution are employed.
It is a particular attribute of packages of this invention where a
warmed surfactant is produced utilizing reduction or decomposition
of hydrogen peroxide as the heat generation means component is
present at low concentration in the package. For example, a
25.degree. F temperature rise can be realized with a concentration
of hydrogen peroxide comprising only 0.59 percent of the total
weight of the mixed compositions in an aqueous emulsion of
surfactant-forming acid where potassium sulfite is used as a
reducing agent and at a concentration of 2.02 percent of the total
weight of the mixed compositions where catalytic decomposition is
effected. Such concentrations of hydrogen peroxide are at a
sufficiently low level to exert no adverse action on the skin
should the surfactant-forming acid composition come into contact
with the skin.
The best mode contemplated by the inventor for carrying out his
invention will now be set forth as follows:
EXAMPLE 1
The following ingredients in the proportions indicated are heated
to 75.degree. C, mixed with stirring and cooled to room temperature
with stirring:
Parts by weight Stearic acid 11.20 Coconut Oil Fatty Acids
(primarily 12-10 2.25 16 carbon atoms) Polyoxyethylene Lauryl Ether
1.90 Polyoxyethylene Cholesteryl Ether 2.00 Water, Deionized
50.00
Water is then added to make 100 parts. The resulting composition
constitutes a composition comprising a surfactant-forming acid.
A composition comprising a surfactant-forming base is formulated to
consist of 50 percent by weight of triethanolamine and 50 percent
by weight of glycerin.
These compositions are used in preparing a package in accordance
with the invention, as follows, the ultimate package to be in the
form illustrated in U.S. Pat. No. 2,973,883:
Fill 97 parts by weight of the detergent-forming acid composition
into a pressure tight container. Fill a collapsible container
having a diameter smaller than the opening in the pressure tight
container with 14 parts by weight of the surfactant-forming base
composition. Insert collapsible container and affix valve means to
communicate individually with the two compositions, the valve means
being constructed such that actuation causes flow in the relative
proportions of 6.9 parts of acid compositions to 1 part of alkali
composition. Pressurize container with 3 parts by weight of a
mixture of 84 percent isobutane 16 percent-propane. Actuation of
the valve means results in the mixing of portions of the acid and
base compositions to yield a surfactant which is dispensed as a
creamy, cosmetically elegant foam, ideally suited for shaving
purposes. The following examples illustrate the preparation of
other compositions within the scope of the invention where the
surfactant is dispensed at room temperature:
EXAMPLE 2
A package of the type described in Example 1 is prepared with the
following compositions:
Surfactant-forming Acid Composition
Tridecyl Benzene Sulfonic Acid (97.5%) 96 parts by weight
Surfactant-forming Base Composition Parts by weight Triethanolamine
48 Sodium Hydroxide 0.50 Water 51.50
The ingredients are packaged with 104 parts of the acid in the
container and 100 parts of the base composition in the collapsible
container. Pressurization is effected with 4 parts of a mixture of
84 percent isobutane-16 percent propane. Valve means are used to
proportion the ingredients in the relative proportions of 1.08
parts of acid composition to 1 part base composition. A creamy foam
is produced upon actuation of the valve means. The package need not
be shaken prior to use.
EXAMPLE 3
A package of the type described in Example 1 is prepared with the
following compositions:
Surfactant Forming Acid Composition Parts by Weight Stearic Acid
22.73 Lauroyl Diethanolamide 22.73 Hexylene Glycol 22.73 Water,
distilled 22.73
The first three ingredients are combined and the mixture heated to
75.degree. C with mixing. The water is added and the mixture is
cooled with mixing.
Surfactant Forming Base Composition Triethanolamine 100.0 parts
The ingredients are packaged with 90.92 parts of the acid
composition in the container and 11.8 parts triethanolamine in the
collapsible container. Pressurization is effected with 9.08 parts
of a mixture of two-thirds tetrachlorodifluoroethane (propellant
114) and one-third dichlorodifluoromethane (Propellant 12). Valve
means are used which proportion the ingredients in the relative
proportions of 8.5 parts of acid composition plus propellants to 1
part triethanolamine. A creamy lather is produced. The package need
not be shaken prior to use.
EXAMPLE 4
A package of the type described in Example 1 is prepared using the
procedure set forth in Example 3, except that the following
surfactant-forming acid composition is used:
Parts by Weight Isostearic acid 22.73 Dipropylene glycol 22.73
Water 45.00 Morpholine 0.46
A creamy lather is produced upon valve actuation.
The following Examples are illustrative of packages within the
scope of the invention where a warmed detergent foam is produced
utilizing reduction of hydrogen peroxide to generate heat. In all
the Examples, a heat rise of at least 25.degree. F is attained.
EXAMPLE 5
The following ingredients in the proportions indicated are heated
to 75.degree. C, mixing with stirring, and cooled to room
temperature with stirring.
Parts by Weight Stearic Acid, Triple Pressed 11.20 Coconut Oil
Fatty Acids (Primarily 12 to 16 Carbon Atoms) 2.25 Polyoxyethylene
(23) Lauryl Ether 1.90 Polyoxyehtylene (24) Cholesteryl ether 2.00
Water, Deionized 50.00 ...At room temperature, the following is
added Hydrogen Peroxide (35 per cent) 8.00
The resulting composition constitutes a composition comprising a
surfactant-forming acid.
A composition comprising a surfactant-forming base is formulated as
follows:
Parts by Weight *Triethanolammonium sulfite 15.1 Triethanolamine
4.0 *Prepared by bubbling stoichiometric quantity of sulfur dioxide
into triethanolami ne.
These compositions are used in preparing a package according to
Example 1 with the exception that valve means are used to
proportion the ingredients in the relative proportions of 4 parts
of acid composition to 1 part base composition.
The following Examples 6-12 are illustrative of different
surfactant-forming base compositions used in lieu of that set forth
in Example 5.
EXAMPLE 6
Parts by Weight Sodium Thiosulfate 20.0 Potassium Hydroxide 7.5
Triethanolamine 28.2 Glycerin 29.7 Water, Deionized 14.6
EXAMPLE 7
Parts by Weight Sodium Thiosulfate 16.3 Potassium Hydroxide 7.5
Triethanolamine 28.2 Glycerin 29.6 Ammonium Molybdate 0.1 Water,
Deionized 18.3
EXAMPLE 8
Parts by weight Sodium Thiosulfate 20.0 Potassium Carbonate 8.0
Glycerin 29.7 Water, Deionized 14.1 Triethanolamine 28.2
EXAMPLE 9
Parts by Weight Sodium Thiosulfate 16.3 Potassium Carbonate 8.0
Glycerin 29.6 Water, Deionized 17.8 Triethanolamine 28.2 Ammonium
Molybdate 0.1
EXAMPLE 10
Parts by Weight Potassium Sulfite 36.1 Sodium Sulfite 6.0
Triethanolamine 28.2 Glycerin 29.7
EXAMPLE 11
Parts by Weight Sodium Thiosulfate 9.00 Potassium Hydroxide 3.75
Potassium Sulfite 18.05 Sodium Sulfite 3.00 Triethanolamine 28.20
Glycerin 29.70 Water, Deionized 8.30
EXAMPLE 12
Parts by WEight Sodium Thiosulfate 8.15 Potassium Hydroxide 3.75
Potassium Sulfite 18.05 Sodium Sulfite 3.00 Triethanolamine 28.20
Glycerin 29.69 Water, Deionized 9.15 Ammonium Molybdate 0.10
The following Example illustrates the use of an equivalent of
hydrogen peroxide, sodium peroxide, in the preparation of a package
to dispense a warmed surfactant:
EXAMPLE 13
The following ingredients in the proportions indicated are heated
to 75.degree. C, mixed with stirring and cooled to room temperature
with stirring:
Lauryl Polyoxyethylene (24) Ether Sulfuric Acid 40.0
Polyoxyethylene (23) Lauryl Ether 1.9 Polyoxyethylene (20)
Cholesteryl Ether 2.0 Water 30.0
25.5 grams of Anhydrous Potassium Sulfite is then added, and water
added to a total of 100 parts, thereby yielding a
surfactant-forming acid composition.
A composition comprising a surfactant-forming base is made as
follows:
Parts by Weight Light Mineral Oil 65.15 Polyoxyethylene (23) Lauryl
Ether 0.62 Sodium Lauryl Sulfate, dry 2.93 Sodium Peroxide 12.6
Anhydrous Potassium Carbonate 18.7
Disperse the Polyoxyethylene (23) Lauryl Ether in the Mineral Oil
with heat, if necessary. The other ingredients are then ball-milled
with the Mineral Oil under anhydrous conditions until the
particulate matter has been reduced to a particle size of 50
microns or less.
The compositions are packaged as described in Example 1.
The following Example illustrates the preparation of a package
adapted to dispensing a warmed surfactant where heat generation is
effected by the heat of solution of anhydrous magnesium
chloride.
EXAMPLE 14
Parts by Weight Lauryl Polyoxyethylene (24 ) Ether Sulfuric Acid
40.0 Polyoxyethylene (23) Lauryl Ether 1.9 Polyoxyethylene (20)
Cholesteryl Ether 2.0 Water, sufficient to make 100.00
The several ingredients are added to the water and the mixture
warmed with stirring until it is homogeneous and clear.
Surfactant-forming base composition:
Parts by WEight Magnesium Chloride, Anhydrous 29.20 Sodium
Carbonate, Anhydrous 29.20 Polyoxethylene (23) Lauryl Ether 0.62
Sodium Lauryl Sulfate, dry 2.93 Light Mineral Oil 38.05
The Polyoxyethylene (23) Lauryl Ether is dispersed in the Mineral
Oil with heat. The other ingredients are then ball-milled with the
Mineral Oil under anhydrous conditions until the particulate matter
has been reduced to a particle size of 50 microns or less.
The compositions are packaged as described in Example 1.
The following Example illustrates the preparation of a package for
dispensing a warmed surfactant where heat generation is effected by
heat of solution of a magnesium chloride equivalent, specifically
sodium oxide.
EXAMPLE 15
A package is prepared as described in Example 1 with the following
composition substituted for the surfactant-forming base
composition:
Light Mineral OIl 78.05 Sodium Oxide 18.4 Polyoxyethylene (23)
Lauryl Ether 0.62 Sodium Lauryl Sulfate, dry 2.93
Disperse the Polyoxyethylene (23) Lauryl Ether in the Mineral Oil
with heat. The other ingredients are then ball-milled with the
Mineral Oil under anhydrous conditions until the particulate matter
has been reduced to a particle size of 50 microns or less.
The foregoing Examples have been directed to the preparation of
packages adapted to the dispensing of a surfactant having primary
use as a shaving composition. The following examples illustrate the
preparation of packages in accordance with the invention having
specific use for other purposes. In each instance, a warmed
surfactant is produced and the compositions are packaged as
described in Example 1.
EXAMPLE 16 (Shampoo)
Parts by Weight Surfactant-forming acid: N-cocoyl (12-16 carbon
atom fatty acids) sarcosinic acid 10.0 Polyoxyethylene (23) lauryl
ether 1.9 Polyoxyethylene (24) cholesteryl ether 2.0 Water 60.0
Heat to 70.degree. C and mix with cooling Add: Hydrogen Peroxide
(35%) 8.0 water, to 100.00 parts
Surfactant-Forming Base: Parts by Weight Triethanolamine 28.2
Glycerin 29.7 Potassium Sulfite 36.1 Sodium Sulfite 6.0
EXAMPLE 17 (Shampoo)
In Example 16, substitute the following as the surfactant-forming
acid composition:
Parts by Weight Lauryl Polyoxyethylene (24) Ether Sulfuric Acid
40.0 Polyoxyethylene (23) Lauryl Ether 1.90 Polyoxyethylene (20)
Cholesteryl Ether 2.00 Water, Deionized to 100.00 Warm and stir
until clear
EXAMPLE 18 (Chest Rub Foam)
Surfactant-Forming Acid Parts by Weight Stearic Acid TP 11.20
Coconut Fatty Acids 2.25 Polyoxylethylene (23) Lauryl ether 1.90
Menthol 1.00 Eucalyptol 2.00
Polyoxyethylene (24) cholesteryl ether 2.00 Water 50.00 ...Heat A
to 75.degree. C and melt and mix. ... Heat B to 75.degree. C and
dissolve ... Combine and cool to room temperature Hydrogen Peroxide
(35%) 8.00 Water, Distilled, to 100.00
Surfactant-Forming Base Parts by Weight Triethanolamine 28.2
Glycerin 29.7 Potassium Sulfite 36.1 Sodium Sulfite 6.0
It is to be understood that the invention is not to be limited to
the exact compositions shown and described, as obvious
modifications and equivalents will be apparent to one skilled in
the art, and the invention is therefore to be limited only by the
scope of the appended claims. The subject matter which the
applicant regards as his invention is particularly pointed out and
distinctly claimed as follows.
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